WO2019013223A1 - プリント配線板用樹脂組成物、プリプレグ、樹脂シート、積層板、金属箔張積層板、プリント配線板、及び多層プリント配線板 - Google Patents
プリント配線板用樹脂組成物、プリプレグ、樹脂シート、積層板、金属箔張積層板、プリント配線板、及び多層プリント配線板 Download PDFInfo
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- WO2019013223A1 WO2019013223A1 PCT/JP2018/026093 JP2018026093W WO2019013223A1 WO 2019013223 A1 WO2019013223 A1 WO 2019013223A1 JP 2018026093 W JP2018026093 W JP 2018026093W WO 2019013223 A1 WO2019013223 A1 WO 2019013223A1
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- Prior art keywords
- printed wiring
- group
- wiring board
- resin composition
- resin
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- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- MQVCTPXBBSKLFS-UHFFFAOYSA-N tri(propan-2-yloxy)-propylsilane Chemical compound CCC[Si](OC(C)C)(OC(C)C)OC(C)C MQVCTPXBBSKLFS-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- 125000004360 trifluorophenyl group Chemical group 0.000 description 1
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/092—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4028—Isocyanates; Thioisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4042—Imines; Imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4085—Curing agents not provided for by the groups C08G59/42 - C08G59/66 silicon containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
Definitions
- the present invention relates to a resin composition for a printed wiring board, a prepreg, a resin sheet, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board.
- Patent Document 1 Japanese Patent Laid-Open No. 2014-473408
- Patent Document 2 Japanese Patent Laid-Open No. 2015-147869
- a resin composition containing a branched polysiloxane having a specific structure together with a thermosetting resin etc. Discloses a technique for producing a prepreg.
- the present invention is a resin composition for printed wiring board which has good varnish compatibility and can form a printed wiring board having a low coefficient of thermal expansion and excellent peel strength to copper foil. And a prepreg, a resin sheet, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board using the same.
- R is selected from substituted or unsubstituted monovalent hydrocarbon groups having 1 to 12 carbon atoms.
- X represents a monovalent organic group containing an epoxy group.
- Said silicon All R and X in the contained polymer (A) may be all the same or different.
- ⁇ 2> The resin composition for a printed wiring board according to ⁇ 1>, wherein the epoxy equivalent of the silicon-containing polymer (A) is 500 to 4000 g / eq.
- ⁇ 3> The resin composition for a printed wiring board according to ⁇ 1> or ⁇ 2>, wherein R in the bonds (a) to (d) is a methyl group or a phenyl group.
- R in the bonds (a) to (d) is a methyl group or a phenyl group.
- ⁇ 4> The printed wiring according to any one of ⁇ 1> to ⁇ 3>, wherein the proportion of substituted or unsubstituted phenyl group in all R of the silicon-containing polymer (A) is 50 mol% to 75 mol%.
- Resin composition for plates ⁇ 5> The resin composition for a printed wiring board according to any one of ⁇ 1> to ⁇ 4>, wherein the weight average molecular weight of the silicon-containing polymer (A) is 5,000 to 20,000.
- N 7 represents an integer of 1 or more.
- a maleimide compound (C) is 100 to 1000 parts by mass with respect to 100 parts by mass of the resin solid content.
- the silicon-containing polymer (A) has a terminal selected from R, X, and an alkoxy group. Composition.
- a prepreg comprising: a substrate; and the resin composition for a printed wiring board according to any one of the above ⁇ 1> to ⁇ 12>, which is impregnated or applied to the substrate.
- a resin sheet comprising: a support; and the resin composition for a printed wiring board according to any one of the above ⁇ 1> to ⁇ 12>, disposed on the surface of the support.
- a laminated board comprising a plurality of one or two or more selected from the group consisting of the prepreg according to ⁇ 13> and the resin sheet according to ⁇ 14>.
- the metal foil tension laminate board provided with 1 type, or 2 or more types selected from the group which consists of a prepreg as described in ⁇ 16> said ⁇ 13> and the resin sheet as described in said ⁇ 14>, and metal foil.
- a printed wiring board comprising: an insulating layer containing the resin composition for a printed wiring board according to any one of ⁇ 1> to ⁇ 12>; and a conductor layer formed on the surface of the insulating layer. .
- a resin composition for printed wiring board having good varnish compatibility, low thermal expansion coefficient, and capable of forming a printed wiring board excellent in peel strength to copper foil, and use thereof It is possible to provide a prepreg, a resin sheet, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board.
- the present embodiment modes for carrying out the present invention (hereinafter, referred to as “the present embodiment”) will be described in detail.
- the present invention is not limited to this, and various modifications are possible without departing from the scope of the invention.
- the resin composition for printed wiring board of the present embodiment (hereinafter sometimes simply referred to as “resin composition”) is a silicon-containing polymerization containing the following bonds (a), (b), (c) and (d) A substance (A), a cyanate ester compound (B), an epoxy resin (D), and a filler (E).
- R is selected from substituted or unsubstituted monovalent hydrocarbon groups having 1 to 12 carbon atoms.
- X represents a monovalent organic group containing an epoxy group. Said silicon All R and X in the contained polymer (A) may be all the same or different.
- the silicon-containing polymer (A) has a bond (d) in addition to the bonds (a), (b) and (c).
- the bond (a) and the bond (d) are trivalent bond groups, and the silicon-containing polymer (A) can have a three-dimensional structure.
- a silicon-containing polymer consisting of constituent units of bond (a) and bond (b) has poor compatibility with other resin components, but the silicon-containing polymer has a "monovalent organic group containing an epoxy group" When the constituent unit is contained, the compatibility with other resin components is improved.
- the composition has a high varnish compatibility and has a thermal expansion of the cured product when cured to produce a prepreg or the like, as compared with a composition using a silicon-containing polymer having no bond (d).
- the rate is low, and excellent peel strength can be exhibited even when a metal foil-clad laminate or the like is formed.
- Silicon-containing polymer (A) The silicon-containing polymer (A) contains bonds (a), (b), (c) and (d).
- R is selected from substituted or unsubstituted monovalent hydrocarbon groups having 1 to 12 carbon atoms.
- X represents a monovalent organic group containing an epoxy group. Said silicon All R and X in the contained polymer (A) may be all the same or different.
- R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 12 carbon atoms, and examples thereof include a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group and an isobutyl group.
- Alkyl groups such as t-butyl, pentyl, hexyl, heptyl, octyl and 2-ethylhexyl; alkenyls such as vinyl, allyl, butenyl, pentenyl and hexenyl; phenyl Examples thereof include aryl groups such as tolyl group, xylyl group, naphthyl group and biphenyl group; and aralkyl groups such as benzyl group and phenethyl group. Among them, methyl group or phenyl group is preferable.
- the bonds (a) to (c) preferably has a substituted or unsubstituted phenyl group, and the bond (a) has a substituted or unsubstituted phenyl group Is more preferred.
- the ratio of substituted or unsubstituted phenyl groups in all R of the silicon-containing polymer (A) is different from that of other thermosetting resin components (thermosetting resin components other than the silicon-containing polymer (A)) From the viewpoint of compatibility, 50 mol% to 75 mol% is preferable.
- the ratio of substituted or unsubstituted phenyl group in all R of the silicon-containing polymer (A) is more preferably 70 mol% to 75 mol%.
- X is a monovalent organic group containing an epoxy group, for example, 2,3-epoxypropyl group, 3,4-epoxybutyl group, 4,5-epoxypentyl group, 2-glycidoxyethyl group, 3-glycidoxypropyl group, 4-glycidoxybutyl group, 2- (3,4-epoxycyclohexyl) ethyl group, 3- (3,4-epoxycyclohexyl) propyl group, etc. Among them, 3-glycidoxypropyl group is preferable.
- the silicon-containing polymer (A) may have other bonds other than the bonds (a) to (d). Other bonds include, for example, bonds in which R or X in the bonds (a) to (d) is a hydrogen atom.
- the terminal of the silicon-containing polymer (A) is not particularly limited, and may be a hydrogen atom, a phenoxy group or the like in addition to the substituent selected from R, X, a hydroxyl group and an alkoxy group as described above.
- the end of the silicon-containing polymer (A) is preferably any one of R, X and an alkoxy group from the viewpoint of storage stability of the polymer. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group and a butoxy group.
- the epoxy equivalent of the silicon-containing polymer (A) is not particularly limited, but is preferably in the range of 500 to 4000 g / eq, more preferably 1000 to 2500 g / eq, and still more preferably 1000 to 2000 g from the viewpoint of enhancing varnish compatibility. / Eq is particularly preferred.
- the softening point of the silicon-containing polymer (A) is not particularly limited, but from the viewpoint of the dispersibility of the silicon-containing polymer (A) and the mechanical strength of the cured product of the obtained resin composition for printed wiring boards, 40 ° C. to 120 ° C. is preferable, and 50 ° C. to 100 ° C. is more preferable.
- the softening point of the silicon-containing polymer (A) can be appropriately adjusted, for example, by the molecular weight of the silicon-containing polymer (A), the constituent bonding unit (eg, the content ratio of (a) to (d)), and the like.
- the weight average molecular weight (Mw: polystyrene conversion in gel permeation chromatography (GPC) measurement) of the silicon-containing polymer (A) is 3,000 or more from the viewpoint of reducing the elasticity of the resin composition and suppressing the occurrence of bleed out.
- Mw polystyrene conversion in gel permeation chromatography
- 5,000 to 20,000 are more preferable, and 6,500 to 16,000 are particularly preferable.
- the silicon-containing polymer (A) is preferably a random copolymer.
- the method for producing the silicon-containing polymer (A) can be produced by a known method without particular limitation. For example, they are obtained by (co) hydrolyzing / condensing organochlorosilanes, organoalkoxysilanes, siloxanes, or partial hydrolytic condensates thereof which can form the above-mentioned bonds (a) to (d) by a hydrolysis condensation reaction. be able to.
- Examples of the compound capable of forming the bond (a) include methyltrimethoxysilane, methyltriethoxysilane, methyltriisopropoxysilane, ethyltrimethoxysilane, Ethyltriethoxysilane, ethyltriisopropoxysilane, propyltrimethoxysilane, propyltriethoxysilane, propyltriisopropoxysilane, phenyltrimethoxysilane, phenyltriethoxysilane, vinyltrimethoxysilane, allyltrimethoxysilane and the like. .
- Examples of compounds capable of forming the bond (b) include dimethyldimethoxysilane, dimethyldiethoxysilane, methylethyldimethoxysilane, diethyldimethoxysilane, diethyldiethoxysilane, Methylpropyldimethoxysilane, methylpropyldiethoxysilane, diisopropyldimethoxysilane, phenylmethyldimethoxysilane, vinylmethyldimethoxysilane and the like can be mentioned.
- Examples of compounds capable of forming a bond (c) include ⁇ -glycidoxypropylmethyldimethoxysilane, ⁇ -glycidoxypropylmethyldiethoxysilane, ⁇ - Examples include (3,4-epoxycyclohexyl) ethylmethyldimethoxysilane and the like.
- Examples of the compound capable of forming a bond (d) include ⁇ -glycidoxypropyltrimethoxysilane, ⁇ -glycidoxypropyltriethoxysilane, ⁇ - ( And 3,4-epoxycyclohexyl) ethyltrimethoxysilane.
- T unit is 50 or more and less than 100 (Si mol%) and D unit is more than 0 with respect to a total of 100 (Si mol%) of bonds (a) It is preferably 50 or less [Si mol%], and from the viewpoint of solubility in a solvent and low thermal expansion, T units are 70 or more and 85 or less [Si mol%] and D units are 15 or more and 30 or less [Si mol%] It is more preferable that T unit is 80 or more and 85 or less [
- the silicon-containing polymer (A) can be prepared, for example, using each of the above-mentioned compounds (a) to (d) in any proportion so that each bond falls within the above-mentioned range.
- the above-mentioned Si mol% is a ratio to the total Si mol, and in the case of a monomer, the molecular weight is 1 mol, and in the case of a dimer, the number obtained by dividing the average molecular weight by 2 is 1 mol It is.
- the silicon-containing polymer (A) may have other bonds within the range not inhibiting the effects of the present invention.
- the silicon-containing polymer (A) (co) is a raw material containing the compounds (a) to (d) (hereinafter sometimes simply referred to as "a mixture of the compounds (a) to (d)”) by a known method It can be synthesized by hydrolysis and condensation.
- a mixture of compounds (a) to (d) is (co) hydrolyzed with water having a pH of 1 to 7.5, preferably 2 to 7.
- metal oxide fine particles such as silica fine particles are dispersed in water may be used.
- the amount of water used can be in the range of 20 to 3,000 parts by mass with respect to 100 parts by mass in total of the compounds (a) to (d), storage stability, scratch resistance, From the viewpoint of crack resistance, it can be 50 parts by mass or more and 150 parts by mass or less.
- the hydrolysis can be carried out by dropping or charging water into the mixture of compounds (a) to (d), or by dropping or charging the mixture of compounds (a) to (d) into water.
- an organic solvent may be used, it can also be synthesized without containing an organic solvent.
- the weight average molecular weight in terms of polystyrene in the GPC analysis of the silicon-containing polymer (A) obtained by hydrolysis tends to be small.
- the above-mentioned hydrolysis is followed by a condensation reaction.
- the condensation may be carried out continuously following the hydrolysis, and usually, from the viewpoint of suppressing the gelation, the condensation is carried out under heating at a liquid temperature of normal temperature or 100 ° C. or less. Furthermore, condensation can be promoted by distilling off the alcohol formed by hydrolysis at 80 ° C. or higher under normal pressure or reduced pressure. Furthermore, in order to promote condensation, a condensation catalyst such as a basic compound, an acidic compound or a metal chelate compound may be added.
- an organic solvent may be added for the purpose of adjusting the progress and concentration of condensation, or metal oxide fine particles such as silica fine particles dispersed in water or an organic solvent You may add.
- metal oxide fine particles such as silica fine particles dispersed in water or an organic solvent You may add.
- the silicon-containing polymer (A) becomes high molecular weight, and the solubility in water and the formed alcohol decreases, so as the organic solvent to be added, the silicon-containing polymer (A) And a relatively polar organic solvent having a boiling point of 80.degree. C. or higher.
- organic solvents include alcohols such as isopropyl alcohol, n-butanol, isobutanol, t-butanol and diacetone alcohol; ketones such as methyl propyl ketone, diethyl ketone, methyl isobutyl ketone and cyclohexanone; Ethers such as propyl ether, dibutyl ether, anisole, dioxane, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate; Esters such as propyl acetate, butyl acetate and cyclohexyl acetate It can be mentioned.
- alcohols such as isopropyl alcohol, n-butanol, isobutanol, t-butanol and diacetone alcohol
- ketones such as methyl propyl ketone, diethyl ketone, methyl
- the content of the silicon-containing polymer (A) is not particularly limited, but from the viewpoints of varnish compatibility, heat resistance, and chemical resistance, 9 to 100 parts by weight of resin solid content. 25 parts by weight is preferred.
- resin solid content when it calls “resin solid content”, unless there is particular notice, the total amount of the component in the resin composition except the solvent and the filler (E) is meant.
- the resin composition in the present embodiment contains a cyanate ester compound (B).
- the cyanate ester compound (B) is not particularly limited as long as it is a compound having an aromatic moiety substituted by at least one cyanato group (cyanate group) in the molecule.
- the resin composition using a cyanate ester compound has excellent properties of glass transition temperature, low thermal expansion, plating adhesion and the like when it is a cured product.
- cyanate ester compounds include, but are not limited to, those represented by the following formula (1).
- Ar 1 represents a benzene ring, a naphthalene ring or a single benzene ring. When there are two or more, they may be the same or different.
- Ra each independently represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, an alkyl group having 1 to 6 carbon atoms, and 6 to 12 carbon atoms A group to which an aryl group is bonded is shown.
- the aromatic ring in Ra may have a substituent, and the substituent in Ar 1 and Ra can be selected at any position.
- p represents the number of cyanato groups bonded to Ar 1 and each is independently an integer of 1 to 3.
- q represents the number of Ra to bind to Ar 1, when Ar 1 is 4-p, naphthalene ring when the benzene ring when those 6-p, 2 one benzene ring is a single bond is 8-p .
- t represents an average number of repetition and is in the range of 0 to 50.
- the cyanate ester compound may be a mixture of compounds different in t.
- a divalent organic group having 1 to 50 carbon atoms a hydrogen atom may be substituted with a hetero atom
- Organic group eg, -NRN- (wherein R represents an organic group)
- carbonyl group -CO-
- -SO 2- sulfonyl
- the alkyl group in Ra of Formula (1) may have any of a linear or branched chain structure and a cyclic structure (for example, a cycloalkyl group etc.). Further, a hydrogen atom in an alkyl group in Ra and an aryl group in Ra of Formula (1) is substituted with a halogen atom such as a fluorine atom or a chlorine atom, an alkoxyl group such as a methoxy group or a phenoxy group, or a cyano group May be Specific examples of the alkyl group include, but are not limited to, methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, isobutyl group, tert-butyl group, n-pentyl group, 1-ethylpropyl group, Examples include 2,2-dimethylpropyl group, cyclopentyl group, hexyl group, cyclohexyl group, and trifluoromethyl
- aryl group examples include, but are not limited to, phenyl group, xylyl group, mesityl group, naphthyl group, phenoxyphenyl group, ethylphenyl group, o-, m- or p-fluorophenyl group, dichlorophenyl group, dicyano A phenyl group, a trifluorophenyl group, a methoxyphenyl group, an o-, m- or p-tolyl group and the like can be mentioned.
- alkoxyl group examples include, but are not limited to, a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, an n-butoxy group, an isobutoxy group, and a tert-butoxy group.
- divalent organic group having 1 to 50 carbon atoms in X in the formula (1) include, but are not limited to, methylene group, ethylene group, trimethylene group, cyclopentylene group, cyclohexylene group, trimethyl.
- Examples thereof include a cyclohexylene group, a biphenylyl methylene group, a dimethyl methylene-phenylene-dimethyl methylene group, a fluorenediyl group, and a phthalide diyl group.
- the hydrogen atom in the divalent organic group may be substituted by a halogen atom such as a fluorine atom or a chlorine atom, an alkoxyl group such as a methoxy group or a phenoxy group, a cyano group or the like.
- Examples of the divalent organic group having 1 to 10 nitrogen atoms as X in the above-mentioned formula (1) include, but are not limited to, an imino group, a polyimide group and the like.
- Ar 2 represents a benzenetetrayl group, a naphthalenetetrayl group or a biphenyltetrayl group, and when u is 2 or more, they may be identical to or different from each other.
- Rf and Rg each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms, an trifluoromethyl group, or an aryl group having at least one phenolic hydroxy group
- Each of Rd and Re is independently selected from any one of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a hydroxy group
- U is an integer of 0 to 5, but u may be a mixture of different compounds.
- Ar 3 represents a benzenetetrayl group, a naphthalenetetrayl group or a biphenyltetrayl group, and when v is 2 or more, they may be the same or different from each other.
- Ri and Rj Each independently represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms, a benzyl group, an alkoxyl group having 1 to 4 carbon atoms, a hydroxy group, a trifluoromethyl group or a cyanato group And at least one substituted aryl group, wherein v represents an integer of 0 to 5, but may be a mixture of compounds different in v).
- R k independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.
- two carbon atoms shown in Formula (2) or two oxygen atoms shown in Formula (3) are 1,4 A benzenetetrayl group bonded to the position 1, 3 or 3, the two carbon atoms or the two oxygen atoms are 4, 4 ', 2, 4', 2, 2 ', 2, 3' And the biphenyltetrayl group bonded to the 3,3'-position or the 3,4'-position, and the two carbon atoms or the two oxygen atoms are 2,6, 1,5,1,6. And a naphthalenetetrayl group bonded to the 1, 8, 1, 3, 1, 4, or 2,7 position.
- the alkyl group and aryl group in Rb, Rc, Rd, Re, Rf and Rg in Formula (2), and Ri and Rj in Formula (3) have the same meanings as in Formula (1).
- cyanato-substituted aromatic compounds represented by the above formula (1) include, but are not limited to, cyanatobenzene, 1-cyanato-2-1, 1-cyanato-3-, or 1-cyanato-4. -Methylbenzene, 1-cyanato-2-, 1-cyanato-3-, or 1-cyanato-4-methoxybenzene, 1-cyanato-2,3-, 1-cyanato-2,4-, 1-cyanato- 2,5-, 1-Cyanato-2,6-, 1-Cyanato-3,4- or 1-Cyanato-3,5-dimethylbenzene, Cyanatoethylbenzene, Cyanatobutylbenzene, Cyanatooctylbenzene, Cyanato Nonylbenzene, 2- (4-cyanaphenyl) -2-phenylpropane (cyanate of 4- ⁇ -cumylphenol), 1-cyanato-4-cyclohexylbenzene, 1-cyana -4-vinylbenz
- phenol novolac resin and cresol novolac resin phenol, alkyl substituted phenol or halogen substituted phenol by a known method
- Formaldehyde compounds such as formalin and paraformaldehyde are reacted in an acidic solution
- trisphenol novolak resin reaction of hydroxybenzaldehyde and phenol in the presence of an acidic catalyst
- fluorene novolac resin fluorenone compound
- 9,9-bis (hydroxyaryl) fluorenes in the presence of an acidic catalyst phenolaralkyl resin, cresolaralkyl resin, naphtholaralkyl resin and biphenylaralkyl resin (known methods)
- Ar 4 - (CH 2 Y ) 2 More, Ar 4 - (CH 2 Y ) 2 (.
- Ar 4 represents a phenyl group
- Y represents a halogen atom and the same in this paragraph.
- cyanate ester compounds can be used singly or in combination of two or more.
- the cyanate ester compound includes at least one selected from the group consisting of a bisphenol-type cyanate ester compound, a naphthol aralkyl-type cyanate ester compound, and a phenol novolac-type cyanate ester compound.
- the cyanate ester compound contains a naphthol aralkyl type cyanate ester compound.
- naphthol aralkyl type cyanate ester compounds examples include naphthol aralkyl type cyanate ester compounds represented by the following formula (CN).
- each R 7 independently represents a hydrogen atom or a methyl group.
- N 7 represents an integer of 1 or more.
- the content of the cyanate ester compound can be appropriately set according to the desired characteristics, and is not particularly limited, but from the viewpoint of heat resistance and chemical resistance, 5 to 60 parts by mass with respect to 100 parts by mass of resin solid content.
- the content is preferably part, more preferably 10 to 50 parts by mass, and still more preferably 20 to 30 parts by mass.
- the resin composition of the present embodiment may optionally contain a maleimide compound (C).
- the maleimide compound (C) is not particularly limited as long as it is a compound having one or more maleimide groups in the molecule, and examples thereof include N-phenyl maleimide, N-hydroxyphenyl maleimide, bis (4-maleimidophenyl) methane, 2,2-bis ⁇ 4- (4-maleimidophenoxy) -phenyl ⁇ propane, bis (3,5-dimethyl-4-maleimidophenyl) methane, bis (3-ethyl-5-methyl-4-maleimidophenyl) methane And bis (3,5-diethyl-4-maleimidophenyl) methane, maleimide compounds represented by the following formula (4), prepolymers of these maleimide compounds, or prepolymers of maleimide compounds and amine compounds.
- the maleimide compound (C) contains at least one selected from the group consisting of maleimide compounds represented by the following formula (4).
- each R 5 independently represents a hydrogen atom or a methyl group, preferably a hydrogen atom.
- n 1 represents an integer of 1 or more, preferably 10 or less, and more preferably 7 or less.
- the content of the maleimide compound (C) in the present embodiment is preferably 10 to 50 parts by mass, more preferably 10 to 30 parts by mass, still more preferably 15 to 50 parts by mass with respect to 100 parts by mass of the resin solid content. 20 parts by mass.
- the content of the maleimide compound (C) is in the above range, the thermal expansion coefficient of the obtained cured product is further reduced, and the heat resistance tends to be further improved.
- Epoxy resin (D) The resin composition of the present embodiment contains an epoxy resin (D).
- an epoxy resin having two or more epoxy groups in one molecule is preferable, and known ones can be appropriately used.
- the kind of epoxy resin (D) is not specifically limited, It differs from the silicon-containing polymer (A) mentioned above.
- the epoxy resin (D) include bisphenol A epoxy resin, bisphenol E epoxy resin, bisphenol F epoxy resin, bisphenol S epoxy resin, phenol novolac epoxy resin, bisphenol A novolac epoxy resin, Glycidyl ester type epoxy resin, aralkyl novolac type epoxy resin, biphenylaralkyl type epoxy resin, naphthalene ether type epoxy resin, cresol novolac type epoxy resin, polyfunctional phenol type epoxy resin, naphthalene type epoxy resin, anthracene type epoxy resin, naphthalene skeleton Modified novolac epoxy resin, phenol aralkyl epoxy resin, naphthol aralkyl epoxy resin, dicyclopentadiene epoxy resin, biphe Epoxy resin, alicyclic epoxy resin, polyol type epoxy resin, phosphorus-containing epoxy resin, glycidyl amine, glycidyl ester, compound obtained by epoxidizing double bond such as butadiene, reaction of hydroxyl group-containing silicone
- epoxy resins biphenylaralkyl type epoxy resins, naphthylene ether type epoxy resins, polyfunctional phenol type epoxy resins, and naphthalene type epoxy resins are preferable in view of flame retardancy and heat resistance. These epoxy resins can be used singly or in combination of two or more.
- an epoxy resin having a naphthalene structure is preferable from the viewpoint of heat resistance, chemical resistance, and thermal expansion coefficient, and a cresol / naphthol novolac epoxy resin represented by the following formula (NE) Particularly preferred.
- the compound represented by the following (NE) is a random copolymer of a constitutional unit of cresol novolac epoxy and a constitutional unit of naphthol novolac epoxy, and both cresol epoxy and naphthol epoxy can be terminated.
- n and n indicate an integer of 1 or more.
- M and n in the formula (NE) each represent an integer of 1 or more.
- an epoxy resin (D) can be suitably set according to the desired characteristic and it is not limited in particular, it is a resin solid from a viewpoint of flexibility, copper foil peel strength, chemical resistance, and desmear resistance.
- the amount is preferably 20 to 50 parts by mass, more preferably 25 to 45 parts by mass, and still more preferably 30 to 40 parts by mass with respect to 100 parts by mass of each component.
- the resin composition of the present embodiment can further include one or more selected from the group consisting of a phenol resin, an oxetane resin, a benzoxazine compound, and a compound having a polymerizable unsaturated group.
- phenol resin generally known phenol resins can be used as long as they have two or more hydroxy groups in one molecule. Specific examples thereof include bisphenol A type phenol resin, bisphenol E type phenol resin, bisphenol F type phenol resin, bisphenol S type phenol resin, phenol novolac resin, bisphenol A novolac type phenol resin, glycidyl ester type phenol resin, aralkyl novolac type Phenol resin, biphenylaralkyl type phenol resin, cresol novolac type phenol resin, polyfunctional phenol resin, naphthol resin, naphthol novolak resin, polyfunctional naphthol resin, anthracene type phenol resin, naphthalene skeleton modified novolac type phenol resin, phenolaralkyl type phenol resin Naphthol aralkyl type phenol resin, dicyclopentadiene type phenol resin, biphenyl type phenol resin Nord resins, alicyclic phenol
- phenol resins biphenylaralkyl type phenol resins, naphtholaralkyl type phenol resins, phosphorus-containing phenol resins, and hydroxyl group-containing silicone resins are preferable in view of flame retardancy. These phenol resins can be used singly or in combination of two or more.
- oxetane resin As the oxetane resin, those generally known can be used. For example, alkyl oxetanes such as oxetane, 2-methyl oxetane, 2,2-dimethyl oxetane, 3-methyl oxetane, 3, 3-dimethyl oxetane, 3-methyl 3-methoxymethyl oxetane, 3, 3-di (trifluoro) Methyl) perfluoxetane, 2-chloromethyl oxetane, 3,3-bis (chloromethyl) oxetane, biphenyl type oxetane, OXT-101 (trade name of Toho Gosei Co., Ltd.), OXT-121 (trade name of Toho Gosei Co., Ltd.), etc. Although it may be mentioned, it is not particularly limited. These oxetane resins can be used alone or in combination
- benzoxazine compound As the benzoxazine compound, generally known compounds can be used as long as they are compounds having two or more dihydrobenzoxazine rings in one molecule.
- bisphenol A type benzoxazine BA-BXZ (trade name of Konishi Chemical) bisphenol F type benzooxazine BF-BXZ (trade name of Konishi Chemical), bisphenol S type benzooxazine BS-BXZ (trade name of Konishi Chemical), P Examples thereof include -d-type benzoxazine (trade name of Shikoku Kasei Kogyo Co., Ltd.) and F-a type benzoxazine (trade name of Shikoku Kasei Kogyo Co., Ltd.) and the like, but not limited thereto. These benzoxazine compounds can be used alone or in combination of two or more.
- compounds having a polymerizable unsaturated group generally known compounds can be used.
- vinyl compounds such as ethylene, propylene, styrene, divinylbenzene and divinylbiphenyl, methyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, polypropylene glycol di (meth) acrylate, (Meth) acrylates of monohydric or polyhydric alcohols such as trimethylolpropane di (meth) acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylate, bisphenol Epoxy (meth) acrylates such as A-type epoxy (meth) acrylate, bisphenol F-type epoxy (meth)
- the resin composition of the present embodiment contains a filler (E).
- the filler (E) include inorganic fillers and organic fillers. These may be used alone or in combination of two or more. A well-known thing can be used suitably as a filler (E), The kind is not specifically limited. In particular, fillers commonly used in laminate applications can be suitably used as the filler (E).
- the inorganic filler include, but are not limited to, natural silica, fused silica, synthetic silica, amorphous silica, silica such as aerosil, hollow silica, white carbon, titanium white, titanium white, zinc oxide, magnesium oxide, zirconium oxide And other oxides, boron nitride, agglomerated boron nitride, silicon nitride, aluminum nitride, barium sulfate, aluminum hydroxide, aluminum hydroxide heat-treated products (aluminum hydroxide is heat-treated to reduce part of water of crystallization)
- Metal hydrates such as boehmite and magnesium hydroxide, molybdenum compounds such as molybdenum oxide and zinc molybdate, zinc borate, zinc stannate, alumina, clay, kaolin, talc, calcined clay, calcined kaolin, calcined talc, mica , E-glass, A-glass,
- inorganic fillers can be used individually by 1 type or in combination of 2 or more types.
- the inorganic filler one or more selected from the group consisting of silica, aluminum hydroxide, boehmite, magnesium oxide and magnesium hydroxide are preferable.
- the use of these inorganic fillers tends to further improve the properties such as thermal expansion properties, dimensional stability and flame retardancy of the resin composition.
- the content of the filler (E) in the resin composition of the present embodiment can be appropriately set according to the desired characteristics, and is not particularly limited, but from the viewpoint of the moldability of the resin composition, the resin solid content 100
- the amount is preferably 40 to 1000 parts by mass, more preferably 100 to 1000 parts by mass, still more preferably 100 to 750 parts by mass, and particularly preferably 100 to 300 parts by mass.
- content of a filler (E) means the total amount of an inorganic filler and an organic filler.
- the content of the inorganic filler in the resin composition of the present embodiment can be appropriately set according to the desired characteristics, and is not particularly limited, but from the viewpoint of the moldability of the resin composition, 100 parts by mass of resin solid content
- the amount is preferably 40 to 1000 parts by mass, more preferably 100 to 750 parts by mass, and still more preferably 100 to 300 parts by mass.
- the organic filler examples include styrene-type, butadiene-type and acrylic-type rubber powders, core-shell rubber powders, silicone resin powders, silicone rubber powders, silicone composite powders and the like.
- Use of the organic filler tends to further improve the characteristics such as the coefficient of thermal expansion, the flexibility, and the flame retardancy of the resin composition.
- the content of the organic filler in the resin composition of the present embodiment can be appropriately set according to the desired characteristics, and is not particularly limited.
- the thermal expansion coefficient, the flexibility, the flame retardance, etc. of the resin composition From the viewpoint of the characteristics of (1), it is preferably 0 to 25 parts by mass, more preferably 10 to 25 parts by mass, with respect to 100 parts by mass of the resin solid content.
- the resin composition of the present embodiment can use the filler (E) in combination with a silane coupling agent or a wetting and dispersing agent.
- a silane coupling agent what is generally used for the surface treatment of an inorganic substance can be used suitably, The kind in particular is not limited.
- silane coupling agent examples include, but are not limited to, aminosilanes such as, but not limited to, ⁇ -aminopropyltriethoxysilane, N- ⁇ - (aminoethyl) - ⁇ -aminopropyltrimethoxysilane, ⁇ -glycid Epoxysilanes such as xylpropyltrimethoxysilane, ⁇ - (3,4-epoxycyclohexyl) ethyltrimethoxysilane, vinylsilanes such as ⁇ -methacryloxypropyltrimethoxysilane, vinyl-tri ( ⁇ -methoxyethoxy) silane, N Cationic silane systems, such as - ⁇ - (N-vinylbenzylaminoethyl) - ⁇ -aminopropyltrimethoxysilane hydrochloride, as well as phenylsilane systems.
- aminosilanes such as, but not limited to,
- the silane coupling agent can be used singly or in combination of two or more.
- a wetting and dispersing agent what is generally used for paints can be used suitably, The kind in particular is not limited.
- a copolymer-based wetting and dispersing agent is preferably used, and may be a commercially available product. Specific examples of commercially available products include, but are not limited to, Disperbyk-110, 111, 161, 180, BYK-W 996, BYK-W 9010, BYK-W 903, BYK-W 940, etc., manufactured by Big Chemie Japan Ltd. Be The wetting and dispersing agents can be used alone or in combination of two or more.
- the resin composition of the present embodiment may contain a curing accelerator for appropriately adjusting the curing rate.
- a curing accelerator for appropriately adjusting the curing rate.
- this hardening accelerator what is generally used as hardening accelerators, such as a cyanate ester compound and an epoxy resin, can be used suitably, The kind is not specifically limited.
- the curing accelerator include zinc octylate, zinc naphthenate, cobalt naphthenate, copper naphthenate, iron acetylacetonate, nickel octylate, organic acid salts such as manganese octylate, phenol, xylenol, cresol, resorcinol, catechol Phenols such as octylphenol and nonylphenol, alcohols such as 1-butanol and 2-ethylhexanol, 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, 1-cyanoethyl-2-phenylimidazole, Imidazoles such as 1-cyanoethyl-2-ethyl-4-methylimidazole, 2-phenyl-4,5-dihydroxymethylimidazole, 2-phenyl-4-methyl-5-hydroxymethylimidazole and the like; Derivatives such as adduct
- various polymer compounds such as other thermosetting resins, thermoplastic resins and their oligomers, elastomers, and flame retardant compounds as long as the desired properties are not impaired. And various additives etc. can be used in combination. These are not particularly limited as long as they are generally used.
- Specific examples of flame retardant compounds include, but are not limited to: bromine compounds such as 4,4'-dibromobiphenyl, phosphate esters, melamine phosphates, phosphorus-containing epoxy resins, nitrogen compounds such as melamine and benzoguanamine, oxazines Examples thereof include ring-containing compounds and silicone compounds.
- additives although it is not limited to the following, for example, an ultraviolet light absorber, an antioxidant, a photopolymerization initiator, a fluorescent whitening agent, a photosensitizer, a dye, a pigment, a thickener, a flow control agent Lubricants, antifoaming agents, dispersants, leveling agents, brighteners, polymerization inhibitors and the like. These can be used singly or in combination of two or more, as desired.
- the resin composition of this embodiment can contain the organic solvent as needed.
- the resin composition of the present embodiment can be used as an aspect (solution or varnish) in which at least part, preferably all, of the various resin components described above are dissolved or compatible with the organic solvent.
- known solvents can be appropriately used so long as at least a part, preferably all of the various resin components described above can be dissolved or compatible, and the type thereof is not particularly limited. .
- organic solvent examples include ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone, cellosolve solvents such as propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate, methyl lactate, methyl acetate, ethyl acetate, butyl acetate and isoamyl acetate And ester solvents such as ethyl lactate, methyl methoxypropionate and methyl hydroxyisobutyrate; polar solvents such as amides such as dimethylacetamide and dimethylformamide; and nonpolar solvents such as aromatic hydrocarbons such as toluene and xylene. Be These can be used singly or in combination of two or more.
- ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone
- cellosolve solvents such as propylene glycol monomethyl ether and propylene glycol monomethyl
- the resin composition of the present embodiment can be prepared according to a conventional method, and the silicon-containing polymer (A), cyanate ester compound (B), epoxy resin (D), filler (E) and filler (E) in the present embodiment
- the preparation method is not particularly limited as long as it is a method that can obtain a resin composition uniformly containing the other optional components described above.
- the resin composition of the present embodiment can be easily prepared by sequentially blending each component in the present embodiment with a solvent and sufficiently stirring.
- the well-known process for dissolving or disperse
- the dispersibility with respect to the resin composition is enhanced by performing the stirring and dispersing treatment using a stirring tank provided with a stirrer having an appropriate stirring ability.
- the above-mentioned stirring, mixing, and kneading processing can be appropriately performed using, for example, a device intended for mixing such as a ball mill and a bead mill, or a known device such as a mixing device of revolution and rotation type.
- the resin composition of the present embodiment can be used as a constituent material of a prepreg, a resin sheet, a laminate, a metal foil-clad laminate, a printed wiring board, a multilayer printed wiring board, and a semiconductor package.
- a prepreg can be obtained by impregnating or coating a base material with a solution in which the resin composition of the present embodiment is dissolved in a solvent, and drying.
- a film obtained by dissolving the resin composition of the present embodiment in a solvent is applied to the plastic film and dried using the peelable plastic film as a substrate to obtain a build-up film or dry film solder resist. be able to.
- the solvent can be dried by drying at a temperature of 20 ° C. to 150 ° C. for 1 to 90 minutes.
- the resin composition of this embodiment can also be used in the unhardened state which dried the solvent, and can also be used in the state of semi-hardening (B stage formation) as needed.
- the prepreg of the present embodiment comprises a substrate and the resin composition impregnated or coated on the substrate.
- the method for producing the prepreg of the present embodiment is not particularly limited as long as it is a method of producing a prepreg by combining the resin composition of the present embodiment and a substrate. Specifically, after impregnating or applying the resin composition of the present embodiment to a substrate, the resin composition is semi-cured by a method such as drying in a dryer at 120 to 220 ° C. for about 2 to 15 minutes.
- the prepreg of the embodiment can be manufactured.
- the adhesion amount of the resin composition to the substrate that is, the content of the resin composition (including the filler (E)) with respect to the total amount of the semi-cured prepreg is in the range of 20 to 99% by mass. Is preferred.
- a base material used when manufacturing the prepreg of this embodiment the well-known thing used for various printed wiring board materials may be used.
- a substrate for example, glass fibers such as E glass, D glass, L glass, S glass, T glass, Q glass, UN glass, NE glass, spherical glass, inorganic fibers other than glass such as quartz, Examples thereof include organic fibers such as polyimide, polyamide and polyester, and woven fabrics such as liquid crystal polyester, but are not particularly limited thereto.
- woven fabrics, non-woven fabrics, rovings, chopped strand mats, surfacing mats and the like are known, and any of these may be used.
- a base material can be used individually by 1 type or in combination of 2 or more types as appropriate.
- woven fabrics in particular, woven fabrics which have been subjected to super-opening treatment and filling treatment are preferable from the viewpoint of dimensional stability.
- a glass woven fabric surface-treated with a silane coupling agent such as epoxysilane treatment or aminosilane treatment is preferable from the viewpoint of moisture absorption heat resistance.
- a liquid crystal polyester woven fabric is preferable from the viewpoint of electrical characteristics.
- the thickness of the substrate is not particularly limited, but in the case of laminated plate applications, the range of 0.01 to 0.2 mm is preferable.
- the resin sheet of the present embodiment refers to a support and the resin composition layer (laminated sheet) disposed on the surface of the support, and only the resin composition layer from which the support has been removed (single-layer sheet ) Also refers. That is, the resin sheet of this embodiment has at least the resin composition of this embodiment.
- the laminated sheet can be obtained by applying a solution obtained by dissolving the above-described resin composition in a solvent on a support and drying.
- the support used herein is not particularly limited.
- a polyethylene film, a polypropylene film, a polycarbonate film, a polyethylene terephthalate film, an ethylene tetrafluoroethylene copolymer film, and a surface of these films are coated with a release agent.
- An organic film substrate such as a mold release film and a polyimide film, a conductor foil such as copper foil and aluminum foil, a glass plate, a SUS plate, and a plate-like inorganic film such as FRP.
- a coating method for example, a solution obtained by dissolving the above-mentioned resin composition in a solvent is coated on a support by a bar coater, a die coater, a doctor blade, a baker applicator or the like to obtain a support and a resin composition layer.
- a method of producing a laminated sheet in which Moreover, a single layer sheet can also be obtained by peeling or etching a support body from the resin sheet obtained by drying after application
- a solution obtained by dissolving or dissolving the resin composition of the present embodiment in a solvent is supplied into a mold having a sheet-like cavity and dried to form a sheet, thereby forming a support.
- a single layer sheet can also be obtained without using
- the drying conditions for removing the solvent are not particularly limited, but it is preferable to dry at a temperature of 20 ° C. to 200 ° C. for 1 to 90 minutes.
- the temperature is 20 ° C. or more, the remaining of the solvent in the resin composition can be further prevented, and when the temperature is 200 ° C. or less, the progress of curing of the resin composition can be suppressed.
- the thickness of the resin layer in the resin sheet or single layer sheet of this embodiment can be adjusted with the density
- the above-described prepreg and resin sheet can be used as a laminate including a plurality of one or two or more selected from these groups.
- the metal foil-clad laminate of this embodiment has the above-described prepreg or resin sheet laminated on at least one sheet, and a metal foil disposed on one side or both sides of the prepreg or resin sheet.
- a metal foil such as copper or aluminum is disposed on one side or both sides of one of the above-described prepreg and resin sheet, or one obtained by stacking a plurality of prepregs and resin sheets. It can be produced by molding.
- the metal foil used here is not particularly limited as long as it is used for a printed wiring board material, but a copper foil such as a rolled copper foil and a copper foil is preferable.
- the thickness of the metal foil is not particularly limited, but is preferably 1 to 70 ⁇ m, and more preferably 1.5 to 35 ⁇ m.
- a method used at the time of producing a laminate for a general printed wiring board and a multilayer board can be adopted. For example, using a multi-stage press, multi-stage vacuum press, continuous molding machine, autoclave molding machine, etc., laminate molding is performed under conditions of temperature 180 to 350 ° C., heating time 100 to 300 minutes, and surface pressure 20 to 100 kg / cm 2 Thus, the metal foil-clad laminate of the present embodiment can be manufactured.
- a multilayer board can also be produced by carrying out lamination molding of the above-mentioned prepreg and the wiring board for inner layers produced separately and combining them.
- a multilayer board for example, copper foils of 35 ⁇ m are disposed on both sides of one of the above-described prepregs, and laminated under the above conditions, an inner layer circuit is formed, and the circuit is blackened. Forming an inner layer circuit board. Further, the inner layer circuit board and the above-mentioned prepreg are alternately arranged one by one, and a copper foil is further arranged at the outermost layer, and laminated and formed preferably under vacuum under the above conditions. Thus, a multilayer board can be produced.
- the metal foil-clad laminate of this embodiment can be suitably used as a printed wiring board by further forming a pattern.
- the printed wiring board can be manufactured according to a conventional method, and the manufacturing method is not particularly limited. Hereinafter, an example of the manufacturing method of a printed wiring board is shown. First, the metal foil-clad laminate described above is prepared. Next, the surface of the metal foil-clad laminate is subjected to etching to form an inner circuit, whereby an inner substrate is produced. If necessary, the inner layer circuit surface of the inner layer substrate is subjected to a surface treatment to increase the adhesive strength, and then, the required number of the above-described prepregs is superimposed on the inner layer circuit surface.
- a metal foil for the outer layer circuit is laminated on the outer side, and heat and pressure are integrally molded.
- a multilayer laminate is produced in which an insulating layer composed of a cured product of the base material and the resin composition is formed between the inner layer circuit and the metal foil for the outer layer circuit.
- a plated metal film is formed on the wall surfaces of the holes so that the inner layer circuit and the outer layer circuit metal foil are conducted.
- the printed wiring board is manufactured by etching the metal foil for the outer layer circuit to form the outer layer circuit.
- the printed wiring board obtained in the above-described production example has an insulating layer and a conductor layer formed on the surface of the insulating layer, and the insulating layer is configured to include the resin composition of the present embodiment described above. That is, the prepreg (the base material and the resin composition of the present embodiment impregnated or coated with the same) of the present embodiment described above, the layer of the resin composition of the metal foil-clad laminate of the present embodiment described above (the present embodiment The layer consisting of the resin composition of (1) is comprised as an insulating layer containing the resin composition of this embodiment.
- the printed wiring board of the present embodiment includes the first insulating layer formed of at least one selected from the group consisting of the above-described prepreg and resin sheet laminated on at least one or more sheets; A plurality of insulating layers consisting of a second insulating layer formed of at least one selected from the group consisting of the above-described prepreg and resin sheet laminated on at least one sheet in the direction of one surface of the first insulating layer; An aspect having a first conductor layer disposed between each of a plurality of insulating layers, and a plurality of conductor layers consisting of a second conductor layer disposed on the surface of the outermost layer of the plurality of insulating layers Is preferable.
- the ordinary laminated board is a multilayer printed wiring board in which another prepreg is laminated in the both surface direction of one core substrate, but the prepreg of this embodiment is the first insulation It can be suitably used for the production of a coreless type multilayer printed wiring board (multilayer coreless substrate) in which another prepreg forming a second insulating layer is laminated only in one direction of one prepreg forming a layer.
- a multilayer printed wiring board has, for example, a configuration in which two second insulating layers are laminated on one first insulating layer (that is, a configuration in which the plurality of insulating layers is three). It may be.
- the first conductor layer and the second insulating layer may each be one layer or two or more layers.
- Synthesis Example 1 Synthesis of polysilsesquioxane (silicon-containing polymer) Synthesis of polysilsesquioxanes 1 to 4 (PO1 to 4) was performed as follows. In a 2 L flask, as described in Table 1 below, phenyltrimethoxysilane (the following unit structure A), dimethyldimethoxysilane (the following unit structure B), ⁇ -glycidoxypropylmethyldimethoxysilane (the following unit structure C), ⁇ -Glycidoxypropyltrimethoxysilane (the following unit structure D) was charged, and the solution was cooled to about 10 ° C.
- the solution 1 was added dropwise over 300 hours to a solution of 300 g of 0.93 mol of cyanogen chloride in chloroform, and the mixture was stirred for 30 minutes after completion of the dropwise addition. Thereafter, a mixed solution of 0.1 mol of triethylamine and 30 g of chloroform was further added dropwise to the obtained solution, and the reaction was completed by stirring for 30 minutes. After filtering off the by-produced triethylamine hydrochloride from the reaction solution, the obtained filtrate was washed with 500 ml of 0.1 N hydrochloric acid, and then washing with 500 ml of water was repeated four times.
- ⁇ -naphthol aralkyl type cyanate ester compound was analyzed by infrared absorption spectrum, absorption of a cyanate ester group was confirmed in the vicinity of 2264 cm ⁇ 1 .
- Example 1 The following composition was mixed and diluted with methyl ethyl ketone to obtain a varnish. ⁇ composition ⁇ 10 parts by mass of polysilsesquioxane 2 (PO2) obtained in Synthesis Example 1 30 parts by mass of ⁇ -naphthol aralkyl type cyanate ester resin (SN 495 VCN) obtained in Synthesis Example 2 Novolak maleimide (Daiwa Kasei Kogyo Co., Ltd.
- Example 2 Example except using 15 parts by mass of polysilsesquioxane 2 (PO2), 28 parts by mass of ⁇ -naphthol aralkyl type cyanate ester resin, 19 parts by mass of novolac maleimide, and 38 parts by mass of cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- PO2 polysilsesquioxane 2
- ⁇ -naphthol aralkyl type cyanate ester resin 19 parts by mass of novolac maleimide
- cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- Example 3 Example except using 20 parts by mass of polysilsesquioxane 2 (PO2), 27 parts by mass of ⁇ -naphthol aralkyl type cyanate ester resin, 18 parts by mass of novolac maleimide, and 35 parts by mass of cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- PO2 polysilsesquioxane 2
- 27 parts by mass of ⁇ -naphthol aralkyl type cyanate ester resin 18 parts by mass of novolac maleimide
- 35 parts by mass of cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- Example 4 Example except using 25 parts by mass of polysilsesquioxane 2 (PO2), 25 parts by mass of ⁇ -naphthol aralkyl type cyanate ester resin, 17 parts by mass of novolac maleimide, and 33 parts by mass of cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- PO2 polysilsesquioxane 2
- ⁇ -naphthol aralkyl type cyanate ester resin 17 parts by mass of novolac maleimide
- 33 parts by mass of cresol / naphthol novolac epoxy A varnish was obtained in the same manner as in 1.
- Example 5 A varnish was obtained in the same manner as in Example 2 except that 15 parts by mass of polysilsesquioxane 1 (PO1) was used in place of polysilsesquioxane 2 (PO2).
- Example 6 A varnish was obtained in the same manner as in Example 2 except that 15 parts by mass of polysilsesquioxane 3 (PO3) was used in place of polysilsesquioxane 2 (PO2).
- PO3 polysilsesquioxane 3
- Comparative Example 2 The same as Example 2, except that 15 parts by mass of AY 42-119 (polysilsesquioxane (epoxy-modified): Toray Dow Corning Co., Ltd.) was used in place of polysilsesquioxane 2 (PO2). The varnish was obtained.
- AY 42-119 polysilsesquioxane (epoxy-modified): Toray Dow Corning Co., Ltd.
- Comparative Example 3 A varnish was obtained in the same manner as in Example 2 except that 15 parts by mass of polysilsesquioxane 4 (PO4) was used in place of polysilsesquioxane 2 (PO2).
- PO4 polysilsesquioxane 4
- Comparative Example 4 A varnish was prepared in the same manner as in Example 2 except that 15 parts by mass of terminal amino-modified silicone (Shin-Etsu Chemical Co., Ltd., product name: X-22-161B) was used instead of polysilsesquioxane 2 (PO2). I got
- the thermal expansion coefficient of the glass cloth in the longitudinal direction of the insulating layer of the laminate was measured by the TMA method (Thermo-mechanical analysis) specified in JlS C 6481, and the value was determined. .
- Copper foil peel strength Copper foil peel strength: With respect to the obtained copper-clad laminate, using a test piece (30 mm ⁇ 150 mm ⁇ 0.8 mm) with a 12 ⁇ m metal foil according to JIS C6481, the peel strength of the copper foil in the number of tests is 3 It measured, and made the average value of the lower limit the measured value. The relative value (% vs comparative example 1) in case the measured value in comparative example 1 is set to 100 is shown.
- the varnish of the example using the silicon-containing polymer containing the bond (d) is excellent in compatibility, and compared to Comparative Example 1 in which the silicon-containing polymer is not used, the copper foil peels The reduction in strength was suppressed, and an excellent peel strength of 80% or more was shown. Also, it can be seen that the thermal expansion coefficient is lower than that of Comparative Example 1.
- Comparative Examples 2 and 3 using the silicon-containing polymer not containing the bond (d) had a slightly higher coefficient of thermal expansion and a peel strength of less than 80%, which was inferior to those of Examples.
- Comparative Example 4 in which the terminal amino-modified silicone was used was inferior in varnish compatibility, and bleeding was generated, so that a coated film could not be formed.
- the resin composition of the present invention has industrial applicability as a material such as a prepreg, a metal foil-clad laminate, a resin sheet, a printed wiring board and the like.
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Abstract
Description
<1> 下記結合(a),(b),(c)及び(d)を含むケイ素含有重合物(A)と、シアン酸エステル化合物(B)と、エポキシ樹脂(D)と、充填材(E)と、を含有するプリント配線板用樹脂組成物。
(結合(a)~(d)において、Rは炭素数1~12の置換又は非置換の1価の炭化水素基から選ばれる。Xはエポキシ基を含む1価の有機基を示す。前記ケイ素含有重合物(A)中の全R及びXは全てが同一であってもよいし、異なっていてもよい。)
<2> 前記ケイ素含有重合物(A)のエポキシ当量が、500~4000g/eqである前記<1>に記載のプリント配線板用樹脂組成物。
<3> 前記結合(a)~(d)におけるRが、メチル基又はフェニル基である前記<1>又は<2>に記載のプリント配線板用樹脂組成物。
<4> 前記ケイ素含有重合物(A)の全Rにおける置換又は非置換のフェニル基の割合が50mol%~75mol%である前記<1>~<3>のいずれか一つに記載のプリント配線板用樹脂組成物。
<5> 前記ケイ素含有重合物(A)の重量平均分子量が、5,000~20,000である前記<1>~<4>のいずれか一つに記載のプリント配線板用樹脂組成物。
<6> 前記ケイ素含有重合物(A)の含有量が、樹脂固形分100質量部に対して9~25質量部である前記<1>~<5>のいずれか一つに記載のプリント配線板用樹脂組成物。
<7> 前記エポキシ樹脂(D)がナフタレン構造を有する前記<1>~<6>のいずれか一つに記載のプリント配線板用樹脂組成物。
<8> 前記エポキシ樹脂(D)が下記式(NE)で示されるクレゾール/ナフトールノボラック型エポキシ樹脂である前記<1>~<7>のいずれか一つに記載のプリント配線板用樹脂組成物。
(ここでm,nは1以上の整数を示す。)
<9> 前記シアン酸エステル化合物(B)が、下記式(CN)で示されるナフトールアラルキル型シアン酸エステル化合物である前記<1>~<8>のいずれか一つに記載のプリント配線板用樹脂組成物。
(ここで、R7は、各々独立に水素原子又はメチル基を示す。n7は1以上の整数を示す。)
<10> さらに、マレイミド化合物(C)を含有する前記<1>~<9>のいずれか一つに記載のプリント配線板用樹脂組成物。
<11> 前記充填材(E)の含有量が、樹脂固形分100質量部に対して、100~1000質量部である前記<10>に記載のプリント配線板用樹脂組成物。
<12> 前記ケイ素含有重合物(A)は、末端がR、X、及びアルコキシ基から選ばれる置換基である前記<1>~<11>のいずれか一つに記載のプリント配線板用樹脂組成物。
<13> 基材と、前記基材に含浸又は塗布された前記<1>~<12>のいずれか一つに記載のプリント配線板用樹脂組成物と、を有するプリプレグ。
<14> 支持体と、前記支持体の表面に配された前記<1>~<12>のいずれか一つに記載のプリント配線板用樹脂組成物と、を有する樹脂シート。
<15> 前記<13>に記載のプリプレグ及び前記<14>に記載の樹脂シートからなる群より選択される一種又は二種以上を、複数備える積層板。
<16> 前記<13>に記載のプリプレグ及び前記<14>に記載の樹脂シートからなる群より選択される一種又は二種以上と、金属箔と、を備える金属箔張積層板。
<17> 前記<1>~<12>のいずれか一つに記載のプリント配線板用樹脂組成物を含む絶縁層と、前記絶縁層の表面に形成された導体層と、を備えるプリント配線板。
<18> 少なくとも1枚以上積層された前記<13>に記載のプリプレグ、及び、前記<14>に記載の樹脂シートからなる群より選択される少なくとも1種で形成された第1の絶縁層、及び、前記第1の絶縁層の片面方向に少なくとも1枚以上積層された前記<13>に記載のプリプレグ、及び、前記<14>に記載の樹脂シートからなる群より選択される少なくとも1種で形成された第2の絶縁層からなる複数の絶縁層と、前記複数の絶縁層の各々の間に配置された第1の導体層、及び、前記複数の絶縁層の最外層の表面に配置された第2の導体層からなる複数の導体層と、を有する多層プリント配線板。
本実施形態のプリント配線板用樹脂組成物(以下、単に“樹脂組成物”と称することがある)は、下記結合(a),(b),(c)及び(d)を含むケイ素含有重合物(A)と、シアン酸エステル化合物(B)と、エポキシ樹脂(D)と、充填材(E)と、を含有する。
(結合(a)~(d)において、Rは炭素数1~12の置換又は非置換の1価の炭化水素基から選ばれる。Xはエポキシ基を含む1価の有機基を示す。前記ケイ素含有重合物(A)中の全R及びXは全てが同一であってもよいし、異なっていてもよい。)
ケイ素含有重合物(A)は、結合(a),(b),(c)及び(d)を含む。
(結合(a)~(d)において、Rは炭素数1~12の置換又は非置換の1価の炭化水素基から選ばれる。Xはエポキシ基を含む1価の有機基を示す。前記ケイ素含有重合物(A)中の全R及びXは全てが同一であってもよいし、異なっていてもよい。)
尚、ケイ素含有重合物(A)は、結合(a)~(d)以外の他の結合を有していてもよい。その他の結合としては例えば、結合(a)~(d)におけるR又はXが水素原子である結合等が挙げられる。
上述のSiモル%は全Siモル中の割合であり、Siモルとは、モノマーであればその分子量が1モルであり、2量体であればその平均分子量を2で割った数が1モルである。
ケイ素含有重合物(A)は、本発明の効果を阻害しない範囲で他の結合を有していてもよい。
本実施形態における樹脂組成物はシアン酸エステル化合物(B)を含む。シアン酸エステル化合物(B)としては、シアナト基(シアン酸エステル基)で少なくとも1個置換された芳香族部分を分子内に有する化合物であれば、特に限定されない。シアン酸エステル化合物を用いた樹脂組成物は、硬化物とした際に、ガラス転移温度、低熱膨張性、めっき密着性等に優れた特性を有する。
また、式(1)のRaにおけるアルキル基及びRaにおけるアリール基中の水素原子は、フッ素原子、塩素原子等のハロゲン原子、メトキシ基、フェノキシ基等のアルコキシル基、又はシアノ基等で置換されていてもよい。
アルキル基の具体例としては、以下に限定されないが、メチル基、エチル基、プロピル基、イソプロピル基、n-ブチル基、イソブチル基、tert-ブチル基、n-ペンチル基、1-エチルプロピル基、2,2-ジメチルプロピル基、シクロペンチル基、ヘキシル基、シクロヘキシル基、及びトリフルオロメチル基が挙げられる。
アリール基の具体例としては、以下に限定されないが、フェニル基、キシリル基、メシチル基、ナフチル基、フェノキシフェニル基、エチルフェニル基、o-,m-又はp-フルオロフェニル基、ジクロロフェニル基、ジシアノフェニル基、トリフルオロフェニル基、メトキシフェニル基、及びo-,m-又はp-トリル基等が挙げられる。
アルコキシル基としては、以下に限定されないが、例えば、メトキシ基、エトキシ基、プロポキシ基、イソプロポキシ基、n-ブトキシ基、イソブトキシ基、及びtert-ブトキシ基が挙げられる。
前記式(1)のXにおける炭素数1~50の2価の有機基の具体例としては、以下に限定されないが、メチレン基、エチレン基、トリメチレン基、シクロペンチレン基、シクロヘキシレン基、トリメチルシクロヘキシレン基、ビフェニルイルメチレン基、ジメチルメチレン-フェニレン-ジメチルメチレン基、フルオレンジイル基、及びフタリドジイル基等が挙げられる。該2価の有機基中の水素原子は、フッ素原子、塩素原子等のハロゲン原子、メトキシ基、フェノキシ基等のアルコキシル基、シアノ基等で置換されていてもよい。
前記式(1)のXにおける窒素数1~10の2価の有機基の例としては、以下に限定されないが、イミノ基、ポリイミド基等が挙げられる。
(前記式(2)中、Ar2はベンゼンテトライル基、ナフタレンテトライル基又はビフェニルテトライル基を示し、uが2以上の場合、互いに同一であっても異なっていてもよい。Rb、Rc、Rf、及びRgは各々独立に、水素原子、炭素数1~6のアルキル基、炭素数6~12のアリール基、トリフルオロメチル基、又はフェノール性ヒドロキシ基を少なくとも1個有するアリール基を示す。Rd及び、Reは各々独立に、水素原子、炭素数1~6のアルキル基、炭素数6~12のアリール基、炭素数1~4のアルコキシル基、又はヒドロキシ基のいずれか一種から選択される。uは0~5の整数を示すが、uが異なる化合物の混合物であってもよい。)
(式(3)中、Ar3はベンゼンテトライル基、ナフタレンテトライル基又はビフェニルテトライル基を示し、vが2以上の場合、互いに同一であっても異なっていてもよい。Ri、及びRjは各々独立に、水素原子、炭素数1~6のアルキル基、炭素数6~12のアリール基、ベンジル基、炭素数1~4のアルコキシル基、ヒドロキシ基、トリフルオロメチル基、又はシアナト基が少なくとも1個置換されたアリール基を示す。vは0~5の整数を示すが、vが異なる化合物の混合物であってもよい。)
式(2)のRb、Rc、Rd、Re、Rf及びRg、並びに式(3)のRi、Rjにおけるアルキル基及びアリール基は、前記式(1)におけるものと同義である。
本実施形態の樹脂組成物は任意でマレイミド化合物(C)を含んでいてもよい。マレイミド化合物(C)としては、分子中に1個以上のマレイミド基を有する化合物であれば特に限定されないが、例えば、N-フェニルマレイミド、N-ヒドロキシフェニルマレイミド、ビス(4-マレイミドフェニル)メタン、2,2-ビス{4-(4-マレイミドフェノキシ)-フェニル}プロパン、ビス(3,5-ジメチル-4-マレイミドフェニル)メタン、ビス(3-エチル-5-メチル-4-マレイミドフェニル)メタン、ビス(3,5-ジエチル-4-マレイミドフェニル)メタン、下記式(4)で表されるマレイミド化合物、これらマレイミド化合物のプレポリマー、若しくはマレイミド化合物とアミン化合物のプレポリマーが挙げられる。これらの中でも、2,2’-ビス{4-(4-マレイミドフェノキシ)-フェニル}プロパン、ビス(3-エチル-5-メチル-4-マレイミドフェニル)メタン及び下記式(4)で表されるマレイミド化合物からなる群より選択される少なくとも1種が好ましい。このようなマレイミド化合物(C)を含むことにより、得られる硬化物の熱膨張率がより低下し、ガラス転移温度がより優れたものとなる傾向にある。同様の観点から、マレイミド化合物(C)が、下記式(4)で表されるマレイミド化合物からなる群より選択される少なくとも1種を含有することがより好ましい。
本実施形態の樹脂組成物はエポキシ樹脂(D)を含む。エポキシ樹脂(D)としては、1分子中に2個以上のエポキシ基を有するエポキシ樹脂が好ましく、公知のものを適宜使用することができる。エポキシ樹脂(D)の種類は特に限定されないが、上述したケイ素含有重合物(A)とは相違するものである。エポキシ樹脂(D)としては、具体的には、ビスフェノールA型エポキシ樹脂、ビスフェノールE型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、ビスフェノールS型エポキシ樹脂、フェノールノボラック型エポキシ樹脂、ビスフェノールAノボラック型エポキシ樹脂、グリシジルエステル型エポキシ樹脂、アラルキルノボラック型エポキシ樹脂、ビフェニルアラルキル型エポキシ樹脂、ナフチレンエーテル型エポキシ樹脂、クレゾールノボラック型エポキシ樹脂、多官能フェノール型エポキシ樹脂、ナフタレン型エポキシ樹脂、アントラセン型エポキシ樹脂、ナフタレン骨格変性ノボラック型エポキシ樹脂、フェノールアラルキル型エポキシ樹脂、ナフトールアラルキル型エポキシ樹脂、ジシクロペンタジエン型エポキシ樹脂、ビフェニル型エポキシ樹脂、脂環式エポキシ樹脂、ポリオール型エポキシ樹脂、リン含有エポキシ樹脂、グリシジルアミン、グリシジルエステル、ブタジエンなどの二重結合をエポキシ化した化合物、水酸基含有シリコーン樹脂類とエピクロルヒドリンとの反応により得られる化合物などが挙げられる。これらのエポキシ樹脂のなかでは、ビフェニルアラルキル型エポキシ樹脂、ナフチレンエーテル型エポキシ樹脂、多官能フェノール型エポキシ樹脂、ナフタレン型エポキシ樹脂が難燃性、耐熱性の面で好ましい。これらのエポキシ樹脂は、1種を単独で又は2種以上を組み合わせて用いることができる。
フェノール樹脂としては、1分子中に2個以上のヒドロキシ基を有するフェノール樹脂であれば、一般に公知のものを使用できる。その具体例としては、ビスフェノールA型フェノール樹脂、ビスフェノールE型フェノール樹脂、ビスフェノールF型フェノール樹脂、ビスフェノールS型フェノール樹脂、フェノールノボラック樹脂、ビスフェノールAノボラック型フェノール樹脂、グリシジルエステル型フェノール樹脂、アラルキルノボラック型フェノール樹脂、ビフェニルアラルキル型フェノール樹脂、クレゾールノボラック型フェノール樹脂、多官能フェノール樹脂、ナフトール樹脂、ナフトールノボラック樹脂、多官能ナフトール樹脂、アントラセン型フェノール樹脂、ナフタレン骨格変性ノボラック型フェノール樹脂、フェノールアラルキル型フェノール樹脂、ナフトールアラルキル型フェノール樹脂、ジシクロペンタジエン型フェノール樹脂、ビフェニル型フェノール樹脂、脂環式フェノール樹脂、ポリオール型フェノール樹脂、リン含有フェノール樹脂、水酸基含有シリコーン樹脂類等が挙げられるが、特に限定されるものではない。これらのフェノール樹脂の中では、ビフェニルアラルキル型フェノール樹脂、ナフトールアラルキル型フェノール樹脂、リン含有フェノール樹脂、水酸基含有シリコーン樹脂が難燃性の点で好ましい。これらのフェノール樹脂は、1種を単独で又は2種以上を組み合わせて用いることができる。
オキセタン樹脂としては、一般に公知のものを使用できる。例えば、オキセタン、2-メチルオキセタン、2,2-ジメチルオキセタン、3-メチルオキセタン、3,3-ジメチルオキセタン等のアルキルオキセタン、3-メチル-3-メトキシメチルオキセタン、3,3-ジ(トリフルオロメチル)パーフルオキセタン、2-クロロメチルオキセタン、3,3-ビス(クロロメチル)オキセタン、ビフェニル型オキセタン、OXT-101(東亞合成製商品名)、OXT-121(東亞合成製商品名)等が挙げられるが、特に限定されるものではない。これらのオキセタン樹脂は、1種又は2種以上混合して用いることができる。
ベンゾオキサジン化合物としては、1分子中に2個以上のジヒドロベンゾオキサジン環を有する化合物であれば、一般に公知のものを用いることができる。例えば、ビスフェノールA型ベンゾオキサジンBA-BXZ(小西化学製商品名)ビスフェノールF型ベンゾオキサジンBF-BXZ(小西化学製商品名)、ビスフェノールS型ベンゾオキサジンBS-BXZ(小西化学製商品名)、P-d型ベンゾオキサジン(四国化成工業製商品名)、F-a型ベンゾオキサジン(四国化成工業製商品名)等が挙げられるが、特に限定されるものではない。これらのベンゾオキサジン化合物は、1種又は2種以上混合して用いることができる。
重合可能な不飽和基を有する化合物としては、一般に公知のものを使用できる。例えば、エチレン、プロピレン、スチレン、ジビニルベンゼン、ジビニルビフェニル等のビニル化合物、メチル(メタ)アクリレート、2-ヒドロキシエチル(メタ)アクリレート、2-ヒドロキシプロピル(メタ)アクリレート、ポリプロピレングリコールジ(メタ)アクリレート、トリメチロールプロパンジ(メタ)アクリレート、トリメチロールプロパントリ(メタ)アクリレート、ペンタエリスリトールテトラ(メタ)アクリレート、ジペンタエリスリトールヘキサ(メタ)アクリレート等の1価又は多価アルコールの(メタ)アクリレート類、ビスフェノールA型エポキシ(メタ)アクリレート、ビスフェノールF型エポキシ(メタ)アクリレート等のエポキシ(メタ)アクリレート類、及びベンゾシクロブテン樹脂、が挙げられるが、特に限定されるものではない。これらの不飽和基を有する化合物は、1種又は2種以上混合して用いることができる。なお、前記「(メタ)アクリレート」は、アクリレート及びそれに対応するメタクリレートを包含する概念である。
本実施形態の樹脂組成物は、充填材(E)を含有する。前記充填材(E)としては、無機充填材や有機充填材が挙げられる。これらは各々単独で用いてもよいし、複数種を併用してもよい。
充填材(E)としては、公知のものを適宜使用することができ、その種類は特に限定されない。特に、積層板用途において一般に使用されている充填材を、充填材(E)として好適に用いることができる。
無機充填材の具体例としては、以下に限定されないが、天然シリカ、溶融シリカ、合成シリカ、アモルファスシリカ、アエロジル、中空シリカ等のシリカ類、ホワイトカーボン、チタンホワイト、酸化亜鉛、酸化マグネシウム、酸化ジルコニウム等の酸化物、窒化ホウ素、凝集窒化ホウ素、窒化ケイ素、窒化アルミニウム、硫酸バリウム、水酸化アルミニウム、水酸化アルミニウム加熱処理品(水酸化アルミニウムを加熱処理し、結晶水の一部を減じたもの)、ベーマイト、水酸化マグネシウム等の金属水和物、酸化モリブデンやモリブデン酸亜鉛等のモリブデン化合物、ホウ酸亜鉛、錫酸亜鉛、アルミナ、クレー、カオリン、タルク、焼成クレー、焼成カオリン、焼成タルク、マイカ、E-ガラス、A-ガラス、NE-ガラス、C-ガラス、L-ガラス、D-ガラス、S-ガラス、M-ガラスG20、ガラス短繊維(Eガラス、Tガラス、Dガラス、Sガラス、Qガラス等のガラス微粉末類を含む。)、中空ガラス、球状ガラスが挙げられる。これらの無機充填材は、1種を単独で又は2種以上を組み合わせて用いることができる。
これらの中でも、無機充填材としては、シリカ、水酸化アルミニウム、ベーマイト、酸化マグネシウム及び水酸化マグネシウムからなる群から選択される1種又は2種以上が好適である。これらの無機充填材を使用することで、樹脂組成物の熱膨張特性、寸法安定性、難燃性などの特性がより向上する傾向にある。
本実施形態の樹脂組成物における無機充填材の含有量は、所望する特性に応じて適宜設定することができ、特に限定されないが、樹脂組成物の成形性の観点から、樹脂固形分100質量部に対して、40~1000質量部とすることが好ましく、より好ましくは100~750質量部であり、さらに好ましくは100~300質量部である。
有機充填材を用いると、樹脂組成物の熱膨張率、柔軟性付与、難燃性などの特性がより向上する傾向にある。
本実施形態の樹脂組成物における有機充填材の含有量は、所望する特性に応じて適宜設定することができ、特に限定されないが、樹脂組成物の熱膨張率、柔軟性付与、難燃性などの特性の観点から、樹脂固形分100質量部に対して、0~25質量部が好ましく、より好ましくは10~25質量部である。
また、本実施形態の樹脂組成物は、硬化速度を適宜調節するための硬化促進剤を含有していてもよい。この硬化促進剤としては、シアン酸エステル化合物やエポキシ樹脂等の硬化促進剤として一般に使用されているものを好適に用いることができ、その種類は特に限定されない。硬化促進剤の具体例としては、オクチル酸亜鉛、ナフテン酸亜鉛、ナフテン酸コバルト、ナフテン酸銅、アセチルアセトン鉄、オクチル酸ニッケル、オクチル酸マンガン等の有機金属塩類、フェノール、キシレノール、クレゾール、レゾルシン、カテコール、オクチルフェノール、ノニルフェノール等のフェノール化合物、1-ブタノール、2-エチルヘキサノール等のアルコール類、2-メチルイミダゾール、2-エチル-4-メチルイミダゾール、2-フェニルイミダゾール、1-シアノエチル-2-フェニルイミダゾール、1-シアノエチル-2-エチル-4-メチルイミダゾール、2-フェニル-4,5-ジヒドロキシメチルイミダゾール、2-フェニル-4-メチル-5-ヒドロキシメチルイミダゾール等のイミダゾール類及びこれらのイミダゾール類のカルボン酸若しくはその酸無水類の付加体等の誘導体、ジシアンジアミド、ベンジルジメチルアミン、4-メチル-N,N-ジメチルベンジルアミン等のアミン類、ホスフィン系化合物、ホスフィンオキサイド系化合物、ホスホニウム塩系化合物、ダイホスフィン系化合物等のリン化合物、エポキシ-イミダゾールアダクト系化合物、ベンゾイルパーオキサイド、p-クロロベンゾイルパーオキサイド、ジ-t-ブチルパーオキサイド、ジイソプロピルパーオキシカーボネート、ジ-2-エチルヘキシルパーオキシカーボネート等の過酸化物、又はアゾビスイソブチロニトリル等のアゾ化合物、N,N-ジメチルアミノピリジンが挙げられる。硬化促進剤は、1種を単独で又は2種以上を組み合わせて用いることができる。
さらに、本実施形態の樹脂組成物は、所期の特性が損なわれない範囲において、他の熱硬化性樹脂、熱可塑性樹脂及びそのオリゴマー、エラストマー類などの種々の高分子化合物、難燃性化合物、並びに各種添加剤等を併用することができる。これらは一般に使用されているものであれば、特に限定されるものではない。難燃性化合物の具体例としては、以下に限定されないが、4,4’-ジブロモビフェニル等の臭素化合物、リン酸エステル、リン酸メラミン、リン含有エポキシ樹脂、メラミン及びベンゾグアナミンなどの窒素化合物、オキサジン環含有化合物、並びに、シリコーン系化合物等が挙げられる。また、各種添加剤としては、以下に限定されないが、例えば、紫外線吸収剤、酸化防止剤、光重合開始剤、蛍光増白剤、光増感剤、染料、顔料、増粘剤、流動調整剤、滑剤、消泡剤、分散剤、レベリング剤、光沢剤、重合禁止剤等が挙げられる。これらは、所望に応じて1種を単独で又は2種以上を組み合わせて用いることができる。
なお、本実施形態の樹脂組成物は、必要に応じて、有機溶剤を含有することができる。この場合、本実施形態の樹脂組成物は、上述した各種樹脂成分の少なくとも一部、好ましくは全部が有機溶剤に溶解又は相溶した態様(溶液又はワニス)として用いることができる。有機溶剤としては、上述した各種樹脂成分の少なくとも一部、好ましくは全部を溶解又は相溶可能なものであれば、公知のものを適宜用いることができ、その種類は特に限定されるものではない。有機溶剤の具体例としては、アセトン、メチルエチルケトン、メチルイソブチルケトン等のケトン類、プロピレングリコールモノメチルエーテル、プロピレングリコールモノメチルエーテルアセテート等のセロソルブ系溶媒、乳酸メチル、酢酸メチル、酢酸エチル、酢酸ブチル、酢酸イソアミル、乳酸エチル、メトキシプロピオン酸メチル、ヒドロキシイソ酪酸メチル等のエステル系溶媒、ジメチルアセトアミド、ジメチルホルムアミド等のアミド類などの極性溶剤類、トルエン、キシレン等の芳香族炭化水素等の無極性溶剤が挙げられる。これらは、1種を単独で又は2種以上を組み合わせて用いることができる。
また、基材として剥離可能なプラスチックフィルムを用い、本実施形態の樹脂組成物を溶剤に溶解させた溶液を、そのプラスチックフィルムに塗布し乾燥することでビルドアップ用フィルム又はドライフィルムソルダーレジストを得ることができる。ここで、溶剤は、20℃~150℃の温度で1~90分間乾燥することで乾燥できる。
また、本実施形態の樹脂組成物は溶剤を乾燥しただけの未硬化の状態で使用することもできるし、必要に応じて半硬化(Bステージ化)の状態にして使用することもできる。
以下、本実施形態のプリプレグについて詳述する。本実施形態のプリプレグは、基材と、該基材に含浸又は塗布された前記樹脂組成物とを有するものである。本実施形態のプリプレグの製造方法は、本実施形態の樹脂組成物と基材とを組み合わせてプリプレグを製造する方法であれば、特に限定されない。具体的には、本実施形態の樹脂組成物を基材に含浸又は塗布させた後、120~220℃の乾燥機中で、2~15分程度乾燥させる方法等によって半硬化させることで、本実施形態のプリプレグを製造することができる。このとき、基材に対する樹脂組成物の付着量、すなわち半硬化後のプリプレグの総量に対する樹脂組成物の含有量(充填材(E)を含む。)は、20~99質量%の範囲であることが好ましい。
本実施形態の樹脂シートは、支持体と、その支持体の表面に配された、前記樹脂組成物層(積層シート)とを指し、また支持体を取り除いた樹脂組成物層のみ(単層シート)も指す。すなわち、本実施形態の樹脂シートは、少なくとも、本実施形態の樹脂組成物を有するものである。この積層シートは、上述の樹脂組成物を溶剤に溶解させた溶液を支持体に塗布し乾燥することで得ることができる。ここで用いる支持体としては、特に限定されないが、例えば、ポリエチレンフィルム、ポリプロピレンフィルム、ポリカーボネートフィルム、ポリエチレンテレフタレートフィルム、エチレンテトラフルオロエチレン共重合体フィルム、並びにこれらのフィルムの表面に離型剤を塗布した離型フィルム、ポリイミドフィルム等の有機系のフィルム基材、銅箔、アルミ箔等の導体箔、ガラス板、SUS板、FRP等の板状の無機系のフィルムが挙げられる。塗布方法としては、例えば、上述の樹脂組成物を溶剤に溶解させた溶液を、バーコーター、ダイコーター、ドクターブレード、ベーカーアプリケーター等で支持体上に塗布することで、支持体と樹脂組成物層が一体となった積層シートを作製する方法が挙げられる。また、塗布後、さらに乾燥して得られる樹脂シートから支持体を剥離又はエッチングすることで、単層シートを得ることもできる。なお、上述の本実施形態の樹脂組成物を溶剤に溶解又は相溶させた溶液を、シート状のキャビティを有する金型内に供給し乾燥する等してシート状に成形することで、支持体を用いることなく単層シートを得ることもできる。
上述のプリプレグ及び樹脂シートは、これらの群より選択される一種又は二種以上を、複数備える積層板として用いることができる。
本実施形態の金属箔張積層板は、少なくとも1枚以上積層された上述のプリプレグ乃至樹脂シートと、そのプリプレグ又は樹脂シートの片面又は両面に配された金属箔とを有するものである。具体的には、前述のプリプレグや樹脂シート1枚に対して、又はプリプレグや樹脂シートを複数枚重ねたものに対して、その片面又は両面に銅やアルミニウムなどの金属箔を配置して、積層成形することにより作製することができる。ここで用いられる金属箔は、プリント配線板材料に用いられているものであれば、特に限定されないが、圧延銅箔及び解銅箔等の銅箔が好ましい。また、金属箔の厚さは、特に限定されないが、1~70μmであると好ましく、1.5~35μmであるとより好ましい。成形条件としては、通常のプリント配線板用積層板及び多層板の作製時に用いられる手法を採用できる。例えば、多段プレス機、多段真空プレス機、連続成形機、又はオートクレーブ成形機などを用い、温度180~350℃、加熱時間100~300分、面圧20~100kg/cm2の条件で積層成形することにより本実施形態の金属箔張積層板を製造することができる。また、上述のプリプレグと、別途作製した内層用の配線板とを組み合わせて積層成形することにより、多層板を作製することもできる。多層板の製造方法としては、例えば、上述したプリプレグ1枚の両面に35μmの銅箔を配置し、前記条件にて積層形成した後、内層回路を形成し、この回路に黒化処理を実施して内層回路板を形成する。さらに、この内層回路板と上述のプリプレグとを交互に1枚ずつ配置し、さらに最外層に銅箔を配置して、前記条件にて好ましくは真空下で積層成形する。こうして、多層板を作製することができる。
本実施形態の金属箔張積層板は、更にパターン形成することにより、プリント配線板として好適に用いることができる。プリント配線板は、常法に従って製造することができ、その製造方法は特に限定されない。以下、プリント配線板の製造方法の一例を示す。まず、上述した金属箔張積層板を用意する。次に、金属箔張積層板の表面にエッチング処理を施して内層回路を形成することにより、内層基板を作製する。この内層基板の内層回路表面に、必要に応じて接着強度を高めるための表面処理を施し、次いで、その内層回路表面に上述したプリプレグを所要枚数重ねる。さらに、その外側に外層回路用の金属箔を積層し、加熱加圧して一体成形する。このようにして、内層回路と外層回路用の金属箔との間に、基材及び樹脂組成物の硬化物からなる絶縁層が形成された多層の積層板が製造される。次いで、この多層の積層板にスルーホールやバイアホール用の穴あけ加工を施した後、この穴の壁面に内層回路と外層回路用の金属箔とを導通させるめっき金属皮膜を形成する。さらに、外層回路用の金属箔にエッチング処理を施して外層回路を形成することで、プリント配線板が製造される。
上述のように、本実施形態のプリント配線板は、少なくとも1枚以上積層された上述のプリプレグ及び樹脂シートからなる群より選択される少なくとも1種で形成された第1の絶縁層、及び、前記第1の絶縁層の片面方向に少なくとも1枚以上積層された上述のプリプレグ及び樹脂シートからなる群より選択される少なくとも1種で形成された第2の絶縁層からなる複数の絶縁層と、前記複数の絶縁層の各々の間に配置された第1の導体層、及び、前記複数の絶縁層の最外層の表面に配置された第2の導体層からなる複数の導体層と、を有する態様であると好適である。本発明者らの知見によれば、通常の積層板は、一のコア基板の両面方向に別のプリプレグが積層された多層プリント配線板であるが、本実施形態のプリプレグは、第1の絶縁層を形成する一のプリプレグの片面方向にのみ、第2の絶縁層を形成する別のプリプレグが積層されたコアレスタイプの多層プリント配線板(多層コアレス基板)の製造に好適に用いることができる。なお、このような多層プリント配線板は、例えば、1層の第1の絶縁層に第2の絶縁層が2層積層されている構成(つまり、複数の絶縁層が3層である構成)であってもよい。第1の導体層及び第2の絶縁層は、各々、1層でも2層以上であってもよい。
次のようにしてポリシルセスキオキサン1~4(PO1~4)の合成を行った。2Lのフラスコに、下記表1の記載に従って、フェニルトリメトキシシラン(下記単位構造A)、ジメチルジメトキシシラン(下記単位構造B)、γ-グリシドキシプロピルメチルジメトキシシラン(下記単位構造C)、γ-グリシドキシプロピルトリメトキシシラン(下記単位構造D)を仕込み、液温が約10℃になるよう冷却した。冷却後、スノーテックス(日産化学工業(株)製:水分散シリカ微粒子、平均粒子径15~20nm、SiO220質量%含有品)211g、0.25Nの酢酸水溶液93gを滴下し、内温が40℃を超えないように冷却しながら加水分解を行った。滴下終了後、40℃以下で1時間、次いで、60℃にて3時間撹拌し、加水分解を完結させた。
その後、シクロヘキサノン300gを投入し、加水分解で生成したメタノールを、常圧にて液温が92℃になるまで加熱留去すると共に、縮合させた後、希釈剤としてイソプロパノール400g、レベリング剤(信越化学工業(株)製:KP-341)0.5g、酢酸1.6g、及び25質量%テトラメチルアンモニウムヒドロキシド(TMAH)水溶液1.6gを加え、撹拌した後、濾紙濾過を行い、無色透明のポリシルセスキオキサンの溶液を得た。また、各ポリシルセスキオキサンについて、標準ポリスチレンを基準としたGPC分析による重量平均分子量を表1に示す。また、表1において比較用に用いたポリシルセスキオキサンAY-42-119の組成を示す。
α-ナフトールアラルキル樹脂(SN495V、OH基当量:236g/eq.、新日鐵化学(株)製:ナフトールアラルキルの繰り返し単位数nは1~5のものが含まれる。)0.47モル(OH基換算)を、クロロホルム500mlに溶解させ、この溶液にトリエチルアミン0.7モルを添加して、溶液1を調製した。温度を-10℃に保ちながら、当該溶液1を0.93モルの塩化シアンのクロロホルム溶液300gに1.5時間かけて滴下し、滴下終了後、30分撹拌した。その後さらに、得られた溶液に対し、0.1モルのトリエチルアミンとクロロホルム30gの混合溶液を滴下し、30分間撹拌して反応を完結させた。副生したトリエチルアミンの塩酸塩を反応液から濾別した後、得られた濾液を0.1N塩酸500mlで洗浄した後、水500mlでの洗浄を4回繰り返した。これを硫酸ナトリウムにより乾燥した後、75℃でエバポレートし、さらに90℃で減圧脱気することにより、褐色固形の上述の式(2)で表される(式中のR7はすべて水素原子、n=1~5)α-ナフトールアラルキル型シアン酸エステル化合物を得た。得られたα-ナフトールアラルキル型シアン酸エステル化合物を赤外吸収スペクトルにより分析したところ、2264cm-1付近にシアン酸エステル基の吸収が確認された。
下記組成を混合しメチルエチルケトンで希釈することでワニスを得た。
〔組成〕
・合成例1で得られたポリシルセスキオキサン2(PO2)10質量部
・合成例2で得られたα-ナフトールアラルキル型シアン酸エステル樹脂(SN495VCN)30質量部
・ノボラックマレイミド(大和化成工業社製、製品名:BMI-2300)20質量部、・クレゾール/ナフトールノボラックエポキシ(DIC(株)製、製品名:HP-9540,エポキシ当量:242g/eq.)40質量部
・スラリーシリカ(アドマテックス製、製品名:SC-2050MB)140質量部
・スラリーシリカ(アドマテックス製、製品名:SC-5050MOB)60質量部
・シリコーン複合パウダー(信越化学工業(株)製、製品名:KMP-600)25質量部
・シランカップリング剤(信越化学工業(株)製、製品名:KBM-403)5.0質量部
・湿潤分散剤(ビッグケミージャパン(株)製、製品名:disperbyk-161)1質量部
・湿潤分散剤(ビッグケミージャパン(株)製、製品名:BYK-111)1質量部
・トリフェニルイミダゾール(TPIZ:2,4,5-Triphenylimidazole,東京化成工業(株)製)0.5質量部
・オクチル酸マンガン(OCt-Mn(重合触媒):日本化学産業(株)製、製品名:ニッカオクチックスマンガン)0.05質量部
ポリシルセスキオキサン2(PO2)を15質量部、α-ナフトールアラルキル型シアン酸エステル樹脂を28質量部、ノボラックマレイミドを19質量部、クレゾール/ナフトールノボラックエポキシを38質量部用いた以外は実施例1と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)を20質量部、α-ナフトールアラルキル型シアン酸エステル樹脂を27質量部、ノボラックマレイミドを18質量部、クレゾール/ナフトールノボラックエポキシを35質量部用いた以外は実施例1と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)を25質量部、α-ナフトールアラルキル型シアン酸エステル樹脂を25質量部、ノボラックマレイミドを17質量部、クレゾール/ナフトールノボラックエポキシを33質量部用いた以外は実施例1と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)に代えて、ポリシルセスキオキサン1(PO1)を15質量部用いた以外は実施例2と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)に代えて、ポリシルセスキオキサン3(PO3)を15質量部用いた以外は実施例2と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)を用いず、α-ナフトールアラルキル型シアン酸エステル樹脂を33質量部、ノボラックマレイミドを22質量部、クレゾール/ナフトールノボラックエポキシを45質量部用いた以外は実施例1と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)に代えて、AY42-119(ポリシルセスキオキサン(エポキシ変性):東レ・ダウコーニング(株)製)を15質量部用いた以外は実施例2と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)に代えて、ポリシルセスキオキサン4(PO4)を15質量部用いた以外は実施例2と同様にしてワニスを得た。
ポリシルセスキオキサン2(PO2)に代えて、末端アミノ変性シリコーン(信越化学工業(株)、製品名:X-22-161B)を15質量部用いた以外は実施例2と同様にしてワニスを得た。
得られたワニスを厚さ0.05mmのEガラスクロスに含浸塗工し、乾燥機(耐圧防爆型スチーム乾燥機、(株)高杉製作所製))を用いて165℃、4分間加熱乾燥し、樹脂含有量73vol%のプリプレグを得た。このプリプレグ2枚を重ね、両面に12μm銅箔(3EC-M3-VLP、三井金属鉱業(株)製)を配置し、圧力40kg/cm2、温度220℃で80分間真空プレスを行い、厚さ0.16mmの12μm銅張り積層板を得た。
100mLのガラスサンプル管にて、得られたワニスを常温(25℃)で24時間保管した。保管後、ガラスサンプル管内の液界面の分離状態を目視により観察し、ワニス相溶性を以下の基準に従って評価した。
〔基準〕
A:成分の分離は確認できなかった。
C:成分の分離が確認された(シリコーン成分由来の無色透明の界面が形成されていた)。
得られた銅張り積層板に対し、JlS C 6481に規定されるTMA法(Thermo-mechanical analysis)により積層板の絶縁層についてガラスクロスの縦方向の熱膨張係数を測定し、その値を求めた。具体的には、前記で得られた銅張り積層板の両面の銅箔をエッチングにより除去した後に、熱機械分析装置(TAインスツルメント製)で40℃から340℃まで毎分10℃で昇温し、60℃から120℃における線熱膨張係数(ppm/℃)を測定した。同測定を5回行い、平均値(n=5の平均値)を“熱膨張率”として下記表3に示した。
銅箔ピール強度:得られた銅張り積層板について、JIS C6481に準じて、12μm金属箔付きの試験片(30mm×150mm×0.8mm)を用い、試験数3で銅箔の引き剥がし強度を測定し、下限値の平均値を測定値とした。比較例1における測定値を100とした場合における相対値(% vs 比較例1)を示す。
また、明細書に記載された全ての文献、特許出願、及び技術規格は、個々の文献、特許出願、及び技術規格が参照により取り込まれることが具体的かつ個々に記された場合と同程度に、本明細書中に参照により取り込まれる。
Claims (18)
- 前記ケイ素含有重合物(A)のエポキシ当量が、500~4000g/eqである請求項1に記載のプリント配線板用樹脂組成物。
- 前記結合(a)~(d)におけるRが、メチル基又はフェニル基である請求項1又は2に記載のプリント配線板用樹脂組成物。
- 前記ケイ素含有重合物(A)の全Rにおける置換又は非置換のフェニル基の割合が50mol%~75mol%である請求項1~3のいずれか一項に記載のプリント配線板用樹脂組成物。
- 前記ケイ素含有重合物(A)の重量平均分子量が、5,000~20,000である請求項1~4のいずれか一項に記載のプリント配線板用樹脂組成物。
- 前記ケイ素含有重合物(A)の含有量が、樹脂固形分100質量部に対して9~25質量部である請求項1~5のいずれか一項に記載のプリント配線板用樹脂組成物。
- 前記エポキシ樹脂(D)がナフタレン構造を有する請求項1~6のいずれか一項に記載のプリント配線板用樹脂組成物。
- さらに、マレイミド化合物(C)を含有する請求項1~9のいずれか一項に記載のプリント配線板用樹脂組成物。
- 前記充填材(E)の含有量が、樹脂固形分100質量部に対して、100~1000質量部である請求項1~10のいずれか一項に記載のプリント配線板用樹脂組成物。
- 前記ケイ素含有重合物(A)は、末端がR、X、及びアルコキシ基から選ばれる置換基である請求項1~11のいずれか一項に記載のプリント配線板用樹脂組成物。
- 基材と、前記基材に含浸又は塗布された請求項1~12のいずれか一項に記載のプリント配線板用樹脂組成物と、を有するプリプレグ。
- 支持体と、前記支持体の表面に配された請求項1~12のいずれか一項に記載のプリント配線板用樹脂組成物と、を有する樹脂シート。
- 請求項13に記載のプリプレグ及び請求項14に記載の樹脂シートからなる群より選択される一種又は二種以上を、複数備える積層板。
- 請求項13に記載のプリプレグ及び請求項14に記載の樹脂シートからなる群より選択される一種又は二種以上と、金属箔と、を備える金属箔張積層板。
- 請求項1~12のいずれか一項に記載のプリント配線板用樹脂組成物を含む絶縁層と、前記絶縁層の表面に形成された導体層と、を備えるプリント配線板。
- 少なくとも1枚以上積層された請求項13に記載のプリプレグ、及び、請求項14に記載の樹脂シートからなる群より選択される少なくとも1種で形成された第1の絶縁層、及び、前記第1の絶縁層の片面方向に少なくとも1枚以上積層された請求項13に記載のプリプレグ、及び、請求項14に記載の樹脂シートからなる群より選択される少なくとも1種で形成された第2の絶縁層からなる複数の絶縁層と、
前記複数の絶縁層の各々の間に配置された第1の導体層、及び、前記複数の絶縁層の最外層の表面に配置された第2の導体層からなる複数の導体層と、
を有する多層プリント配線板。
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JP2014047348A (ja) * | 2012-09-04 | 2014-03-17 | Sumitomo Bakelite Co Ltd | プリプレグおよび金属張積層板 |
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JP2017008146A (ja) * | 2015-06-17 | 2017-01-12 | 株式会社ダイセル | ポリオルガノシルセスキオキサン、ハードコートフィルム、接着シート、積層物及び装置 |
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