WO2018180316A1 - Produit cosmétique émulsifié - Google Patents

Produit cosmétique émulsifié Download PDF

Info

Publication number
WO2018180316A1
WO2018180316A1 PCT/JP2018/008848 JP2018008848W WO2018180316A1 WO 2018180316 A1 WO2018180316 A1 WO 2018180316A1 JP 2018008848 W JP2018008848 W JP 2018008848W WO 2018180316 A1 WO2018180316 A1 WO 2018180316A1
Authority
WO
WIPO (PCT)
Prior art keywords
component
mass
emulsified cosmetic
elasticity
content
Prior art date
Application number
PCT/JP2018/008848
Other languages
English (en)
Japanese (ja)
Inventor
真樹 松尾
Original Assignee
株式会社マンダム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to CN201880002663.3A priority Critical patent/CN109414375A/zh
Priority to JP2019509124A priority patent/JP6687809B2/ja
Priority to KR1020187035960A priority patent/KR20190008302A/ko
Publication of WO2018180316A1 publication Critical patent/WO2018180316A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/553—Phospholipids, e.g. lecithin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to an emulsified cosmetic.
  • emulsified cosmetics are known as skin care cosmetics for the purpose of moisturizing skin, and for example, emulsified cosmetics having a viscosity comparable to that of lotion are known (Patent Document 1).
  • the present inventor has studied to impart elasticity to the cosmetic in order to impart a new tactile sensation to the cosmetic.
  • As a method for imparting elasticity to cosmetics there is a method of crosslinking with a hydrophobic group bond using an alkyl-modified acrylic polymer.
  • the stability of the emulsified cosmetic is impaired and separation or the like occurs.
  • the stability can be improved by blending a large amount of the above-mentioned polymer, in that case, the elasticity becomes too high, causing twisting (coating unevenness) at the time of application, and poor skin familiarity at the time of application. I also found out.
  • An object of the present invention is to provide an emulsified cosmetic that has moderate elasticity and has a new property and feel different from those of conventional cosmetics. Moreover, it is to provide an emulsified cosmetic excellent in stability and usability.
  • the present invention contains the following component A, component B, component C, component D, and component E, the content of component A is 0.1 to 1.0% by mass, and the content of component B is 0 .4 mass% or less, the content of component C is 0.3 mass% or less, the content of component D is 4.0 mass% or less, and the mass ratio of component B to component A (component B / Component A) is 0.10 or more, the mass ratio of component C to component A (component C / component A) is 0.02 or more, and the mass ratio of component D to component A (component D / component A) is It is related with emulsified cosmetics which are 0.4 or more and 7.0 or less.
  • Component A (Acrylates / Beheneth-25 methacrylate) copolymer
  • Component B Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer
  • Component C Xanthan gum
  • Component D Phospholipid
  • Component E Water
  • the present invention it is possible to provide an emulsified cosmetic that has moderate elasticity and has a new property and feel different from conventional cosmetics. Furthermore, according to the present invention, it is possible to provide an emulsified cosmetic excellent in stability and usability.
  • the emulsified cosmetic of the present invention contains at least an (acrylates / Beheneth-25 methacrylate) copolymer; a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer; a xanthan gum; a phospholipid; and water.
  • the “(acrylates / behenes-25 methacrylate) copolymer” is referred to as “component A”; the “carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer” as “component B”; and the “xanthan gum” as described above.
  • component C the “phospholipid”
  • the “water” may be referred to as “component E”.
  • the mechanism by which the emulsified cosmetic of the present invention exhibits the above-mentioned excellent effects is unknown, but is considered as follows.
  • elasticity is considered to be imparted by the interaction of the alkyl chain.
  • the stability of the system tends to decrease.
  • component A is blended to such an extent that sufficient stability can be obtained, the elasticity becomes too high and the desired tactile sensation is obtained. Not only will it disappear, it will cause kinking during application, and skin familiarity may worsen.
  • the gel network is formed by using the component B and the component C together, and the interaction of the alkyl chain is physically weakened, and further, the component D interacts with the alkyl chain.
  • the system is adjusted to an appropriate elasticity, and the emulsified cosmetic is considered to have a desirable tactile sensation.
  • the amount of each of components B to D can be suppressed, so that adverse effects due to these components can be suppressed.
  • Component A is “(Acrylates / Beheneth-25 Methacrylate) Copolymer”, ie, one or more monomers selected from among esters of methacrylic acid and behenes-25 and acrylic acid, methacrylic acid or simple esters thereof. INCI name (International Cosmetic Ingredient Dictionary and Handbook) “ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER (Acrolates / Beheneth-25 Methacrylate Compound)”.
  • Component A functions as a component that increases the elasticity of the emulsified cosmetic.
  • Component A also functions as a component that increases the viscosity of the emulsified cosmetic.
  • Examples of commercially available components A include, for example, “Aculin 28” manufactured by Dow Chemical Co., Ltd.
  • Component A is usually used after neutralization with a basic substance.
  • the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide, and potassium hydroxide, and basic amino acids such as arginine.
  • the addition amount of the basic substance is an amount sufficient to neutralize component A, and may be appropriately blended according to the amount of component A used.
  • the content of component A in 100% by mass of the emulsified cosmetic of the present invention is 0.1% by mass or more, preferably 0.2% by mass from the viewpoint of enhancing the elasticity of the emulsified cosmetic and imparting a characteristic tactile sensation.
  • Component B is “carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer”.
  • component B By blending component B, an excessive increase in elasticity due to component A can be mitigated.
  • component B when it is going to reduce the elasticity of the component A enough only with the component B, a film
  • the carboxyvinyl polymer is mainly a polymer of acrylic acid
  • the alkyl-modified carboxyvinyl polymer is a copolymer of mainly acrylic acid and alkyl methacrylate (preferably alkyl has 10 to 30 carbon atoms).
  • alkyl-modified carboxyvinyl polymer include (acrylates / alkyl acrylate (C10-30)) crosspolymer.
  • Component B may use only 1 type and may use 2 or more types.
  • Component B can be obtained as a commercial product.
  • carboxyvinyl polymers include “Carbopol 934”, “Carbopol 940”, “Carbopol 941”, “Carbopol 980”, “Carbopol 981”, “Carbopol 1342”, “Carbopol”. 2984 ”,“ Carbopol Ultrez 10 ”,“ Carbopol ETD 2050 ”(all Japan Lubrizol Corporation);“ AQUPEC HV-501 ”,“ AQUPEC HV-504 ”,“ AQUPEC HV-505 ”,“ Hibiswako ” 104 ”,“ Hibiswako 105 ”(all of which are Wako Pure Chemical Industries, Ltd.).
  • Examples of commercially available alkyl-modified carboxyvinyl polymers include “PEMULEN TR-1”, “PEMULEN TR-2”, “Carbopol ETD 2020”, “Carbopol ULTREZ 20” (Nippon Lubrizol Corporation), etc. Is mentioned.
  • the content of Component B in 100% by mass of the emulsified cosmetic of the present invention is 0.4% by mass or less, preferably 0.3% by mass, from the viewpoint of suppressing the film feeling and the tension after application of the emulsified cosmetic. % Or less, and more preferably 0.25% by mass or less.
  • the lower limit of the content of component B may be a value that satisfies a mass ratio with component A described later, but is preferably 0.01% by mass or more, for example.
  • the content of component B is the total amount of all components B contained in the emulsified cosmetic of the present invention.
  • the mass ratio of component B to component A is 0.10 or more, preferably 0.21 or more, from the viewpoint of alleviating an excessive increase in elasticity.
  • Component C is the above “xanthan gum”.
  • Xanthan gum is a chain polysaccharide composed of repeating units of 2 glucose molecules, 2 mannose molecules and glucuronic acid.
  • component C a commercially available product can be used.
  • examples of commercially available components C include “Echo Gum T” (manufactured by DSP Gokyo Food & Chemical Co., Ltd.), “Nom Coat ZZ” (manufactured by Nisshin Oilio Group Co., Ltd.), and the like.
  • the content of component C in 100% by mass of the emulsified cosmetic of the present invention is 0.3% by mass or less, preferably 0.25% by mass or less, from the viewpoint of suppressing a decrease in skin familiarity and preventing nullification. More preferably, it is 0.2 mass% or less.
  • the lower limit of the content of component C may be a value that satisfies a mass ratio with component A described later, but is preferably 0.01% by mass or more, for example.
  • the mass ratio of component C to component A is 0.02 or more, preferably 0.03 or more, from the viewpoint of alleviating excessive elasticity increase.
  • Component D is “phospholipid”. By blending component D, an excessive increase in elasticity due to component A can be mitigated. In addition, when it is going to reduce the elasticity of the component A enough only with the component D, an emulsified cosmetic will change in odor over time, stability will be bad, and a usability
  • Component D is a complex lipid containing a phosphate residue, and includes natural phospholipids, synthetic phospholipids, hydrogenated phospholipids in which unsaturated carbon chains of naturally derived phospholipids are saturated with hydrogen, and the like.
  • Specific examples of component D include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, lysophosphatidylcholine, sphingomyelin, egg yolk lecithin, soybean lecithin, and other natural phospholipids; dilauroylphosphatidylcholine, dimyristoylphosphatidylcholine, dipalmitoylphosphatidylcholine, Examples include synthetic phospholipids such as stearoyl phosphatidylcholine, dioleoylphosphatidylcholine, palmitoyl oleoylphosphatidylcholine; hydrogenated phospholipid
  • the content of component D in 100% by mass of the emulsified cosmetic of the present invention is 4.0% by mass or less, preferably 3.0% by mass or less, from the viewpoint of suppressing odor change over time of the emulsified cosmetic. More preferably, it is 2.0 mass% or less.
  • the lower limit of the content of component D may be a value that satisfies a mass ratio with component A described later, but is preferably 0.3% by mass or more, for example.
  • the content of component D is the total amount of all components D contained in the emulsified cosmetic of the present invention.
  • the mass ratio of the component D to the component A is 0.4 or more, preferably 0.85 or more, from the viewpoint of alleviating excessive elasticity increase. More preferably, it is 1.0 or more, and is 7.0 or less, preferably 4.5 or less, more preferably 3. from the viewpoint of preventing the elasticity from being excessively lowered and achieving a characteristic feel. 5 or less.
  • Component E is “water”.
  • Component E has a role as a medium of an emulsified cosmetic for forming an emulsified system. By making cosmetics into an emulsifying system, freshness and emollient effects are exhibited.
  • the content of component E in 100% by mass of the emulsified cosmetic of the present invention is preferably 55.0% by mass or more, more preferably 65.0% by mass or more, preferably from the viewpoint of containing other components. Is 95.0 mass% or less, more preferably 90.0 mass% or less.
  • the emulsified cosmetic of the present invention can further contain an “oil agent” as component F from the viewpoint of making the dosage form an emulsifying system.
  • component F examples include higher aliphatic alcohols, higher fatty acids, fats and oils, hydrocarbon oils, ester oils, silicone oils, waxes, and the like.
  • component F examples include monovalent branched aliphatic alcohols having 12 to 24 carbon atoms such as octyldodecanol, decyltetradecanol, and isostearyl alcohol; monovalent branched alcohols having 12 to 22 carbon atoms such as oleyl alcohol.
  • Linear unsaturated aliphatic alcohols such as cetyl alcohol, stearyl alcohol, behenyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid , Higher fatty acids such as undecylenic acid, lanolinic acid, isostearic acid; coconut oil, palm oil, hydrogenated palm oil, avocado oil, sesame oil, olive oil, kukui nut oil, grape particle oil, safflower oil, almond oil, corn oil, cottonseed oil , Sunflower seed oil, grape seed oil, hazelnut , Oils such as macadamia nut oil, meadow foam oil, rosehip oil; hydrocarbon oils such as olefin oligomer, light liquid isoparaffin, squalane, liquid paraffin, liquid isoparaffin, petrolatum; ethyl oleate, isopropyl my
  • the content of component F in 100% by mass of the emulsified cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, from the viewpoint of functionality such as an emollient effect. More preferably, it is 1.0% by mass or more, and from the viewpoint of use feeling such as stickiness suppression, it is preferably 50.0% by mass or less, more preferably 40.0% by mass or less, and further preferably 30%. 0.0 mass% or less.
  • the content of component F is the total amount of all components F contained in the emulsified cosmetic of the present invention when a plurality of components F are used.
  • the emulsified cosmetic of the present invention may further optionally contain other components other than those described above.
  • other components include surfactants (cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, etc.), lower alcohols, polyhydric alcohols, ultraviolet absorbers, powders, antioxidants Agents, preservatives, fragrances, coloring agents, chelating agents, refreshing agents, vitamins, neutralizing agents, amino acids, pH adjusters, whitening agents, anti-inflammatory agents, deodorants, animal and plant extracts, sequestering agents An additive etc. are mentioned. Only 1 type may be used for said other component, and 2 or more types may be used for it.
  • the pH of the emulsified cosmetic of the present invention is, for example, preferably 4.5 to 7.5 at 25 ° C., more preferably 5.0 to 7.0.
  • the emulsified cosmetic of the present invention has a consistency at 25 ° C. of preferably 5.0 to 100.0 gf, more preferably 10.0 to 80.0 gf, from the viewpoint of having the characteristic properties of the present invention. More preferably, it is 25.0 to 70.0 gf.
  • the “consistency at 25 ° C.” is a value measured using a consistency meter equipped with a 17 ⁇ flat adapter at 25 ° C., a speed of 60 mm / min, and a stroke of 20 mm.
  • An example of such a consistency meter is “RHEO METER” manufactured by Sun Kagaku Co., Ltd.
  • An example of the dosage form of the emulsified cosmetic of the present invention is gel cream.
  • the emulsified cosmetic of the present invention has no fluidity and has elasticity. Moreover, it has the property of flowing when a shearing force is applied. For this reason, even if it takes out in the shape of a sphere or a cylinder from a container, for example, the shape can be maintained, and if vibration is added, it will shake like a jelly. In addition, it has a soft jelly-like appearance. In addition, when applying to a skin or the like by applying a shearing force, it can be applied without resistance.
  • the emulsified cosmetic of the present invention can be a reversible structure that can easily return to the original structure even if the structure is broken by a physical action. For this reason, even if the emulsified cosmetic filled in the container or the like is scraped off with a finger or the like, the scratched marks are automatically repaired, and the surface of the filled cosmetic becomes a flat surface.
  • the emulsified cosmetic composition of the present invention exhibits new properties and a feeling of use (feel of skin) that are different from those of conventional cosmetic compositions.
  • Examples of the emulsified cosmetic of the present invention include skin care cosmetics such as cleansing cosmetics, moisturizing cosmetics, whitening cosmetics, acne care cosmetics, and anti-aging cosmetics (for example, for the purpose of suppressing wrinkles and sagging). Fees: sunscreen cosmetics and the like.
  • the emulsified cosmetic of the present invention is preferably used as a skin cosmetic.
  • the emulsified cosmetic of the present invention may be any of cosmetics, quasi drugs, pharmaceuticals, and miscellaneous goods, for example.
  • the parts to which the emulsified cosmetic of the present invention is applied include the face (for example, forehead, eyes, eyes, cheeks, mouth), arms, elbows, back of hands, fingertips, feet, knees, heels, neck, armpits, and back. Can be mentioned.
  • Examples of the method for preparing the emulsified cosmetic of the present invention include a method in which the above-described components are mixed and a known method, for example, a method using a homomixer, and the like.
  • aqueous phase Component A, Component B, Component C, Component E, BG, glycerin, methyl paraben, and potassium hydroxide were mixed and heated to 85 ° C.
  • oil phase Component D, Component F, glyceryl behenate, polyglyceryl octastearate-6, and glyceryl stearate were mixed and heated to 85 ° C.
  • water phase and the oil phase were mixed, emulsified by stirring with a homomixer at a rotational speed of 6000 rpm for 5 minutes, and cooled to 35 ° C. to prepare a gel cream emulsified cosmetic.
  • the pH of the emulsified cosmetic of Example 1 at 25 ° C. was about 6.4, and the consistency at 25 ° C. was 40 gf.
  • dimethicone Trade name “SH200C 10CS-JASU”, Toray Dow Made by Corning Glyceryl tea tearate (glyceryl monostearate): trade name “CUTINA GMS-V”, glyceryl behenate and polyglyceryl octastearate-6 manufactured by BASF Corporation: trade name “TAISET SC50”, Taiyo Kagaku BG (1,3- Butylene glycol): Trade name “1,3-butylene glycol”, Daicel carbomer: Trade name “Carbopol 981”, LUBRIZOL shea fat: Trade name “Star Shear butter refined”, IMCD Group BV. Made
  • the emulsified cosmetic of the present invention has moderate elasticity, and can be used as a cosmetic having new properties and feel different from conventional cosmetics.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Biophysics (AREA)
  • Molecular Biology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne un produit cosmétique émulsifié contenant les composants A à E, la teneur en composant A étant de 0,1 à 1,0 % en masse, la teneur en composant B étant de 0,4 % en masse ou moins, la teneur en composant C étant de 0,3 % en masse ou moins, la teneur en composant D est de 4,0 % en masse ou moins, le rapport en masse (composant B/composant A) du composant B au composant A est de 0,10 ou plus, le rapport de masse (composant C/composant A) du composant C au composant A est de 0,02 ou plus, et le rapport en masse (composant D/composant A) du composant D au composant A est de 0,4 à 7,0, inclus. Composant A : copolymère (acrylate/béhénéth-25 méthacrylate). Composant B : polymère carboxyvinylique et/ou polymère carboxyvinylique modifié par alkyle. Composant C : gomme xanthane. Composant D : phospholipide. Composant E : eau.
PCT/JP2018/008848 2017-03-28 2018-03-07 Produit cosmétique émulsifié WO2018180316A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201880002663.3A CN109414375A (zh) 2017-03-28 2018-03-07 乳化化妆料
JP2019509124A JP6687809B2 (ja) 2017-03-28 2018-03-07 乳化化粧料
KR1020187035960A KR20190008302A (ko) 2017-03-28 2018-03-07 유화 화장료

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017063671 2017-03-28
JP2017-063671 2017-03-28

Publications (1)

Publication Number Publication Date
WO2018180316A1 true WO2018180316A1 (fr) 2018-10-04

Family

ID=63677353

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/008848 WO2018180316A1 (fr) 2017-03-28 2018-03-07 Produit cosmétique émulsifié

Country Status (4)

Country Link
JP (1) JP6687809B2 (fr)
KR (1) KR20190008302A (fr)
CN (1) CN109414375A (fr)
WO (1) WO2018180316A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022124385A1 (fr) 2020-12-07 2022-06-16 L'oreal Composition d'émulsion huile dans l'eau
FR3118702A1 (fr) 2021-01-12 2022-07-15 L'oreal Composition d’émulsion huile-dans-eau

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004091360A (ja) * 2002-08-30 2004-03-25 Kanebo Ltd 化粧料
WO2005044216A1 (fr) * 2004-10-26 2005-05-19 Shiseido Co., Ltd. Preparation pour la peau a usage externe
JP2008291014A (ja) * 2007-04-27 2008-12-04 Fancl Corp 乳液状化粧料
JP2016216403A (ja) * 2015-05-22 2016-12-22 株式会社マンダム 整髪剤組成物
JP2017057180A (ja) * 2015-09-18 2017-03-23 株式会社マンダム 日焼け止め化粧料

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5203618B2 (ja) 2007-03-22 2013-06-05 株式会社ファンケル 乳化化粧料
US9857371B2 (en) * 2012-05-08 2018-01-02 New York University Biomimetic emulsions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004091360A (ja) * 2002-08-30 2004-03-25 Kanebo Ltd 化粧料
WO2005044216A1 (fr) * 2004-10-26 2005-05-19 Shiseido Co., Ltd. Preparation pour la peau a usage externe
JP2008291014A (ja) * 2007-04-27 2008-12-04 Fancl Corp 乳液状化粧料
JP2013227353A (ja) * 2007-04-27 2013-11-07 Fancl Corp 乳液状化粧料
JP2016216403A (ja) * 2015-05-22 2016-12-22 株式会社マンダム 整髪剤組成物
JP2017057180A (ja) * 2015-09-18 2017-03-23 株式会社マンダム 日焼け止め化粧料

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022124385A1 (fr) 2020-12-07 2022-06-16 L'oreal Composition d'émulsion huile dans l'eau
FR3118702A1 (fr) 2021-01-12 2022-07-15 L'oreal Composition d’émulsion huile-dans-eau

Also Published As

Publication number Publication date
KR20190008302A (ko) 2019-01-23
JP6687809B2 (ja) 2020-04-28
JPWO2018180316A1 (ja) 2019-06-27
CN109414375A (zh) 2019-03-01

Similar Documents

Publication Publication Date Title
JP6209438B2 (ja) 水中油型乳化組成物
JP6530236B2 (ja) 皮膚用クリーム
JP6687809B2 (ja) 乳化化粧料
JP2018016583A (ja) 水中油型乳化化粧料
JP6982697B2 (ja) 皮膚化粧料用組成物
JP6747763B2 (ja) 乳化化粧料
WO2019188119A1 (fr) Produit cosmétique capillaire
JP2019178107A (ja) 毛髪化粧料
WO2020218547A1 (fr) Composition d'émulsion huile/eau à viscosité élevée contenant du phosphate d'adénosine
JP6674878B2 (ja) 乳化化粧料
JP2022086863A (ja) 水中油型乳化化粧料
JP2020147538A (ja) 乳液状皮膚化粧料
JP2020128345A (ja) 水中油型乳化組成物
JP6792632B2 (ja) 乳化化粧料
JP6336313B2 (ja) 水中油型乳化組成物
JP2018052849A (ja) 皮膚用乳化組成物
JP7309400B2 (ja) 乳化化粧料組成物
JP7359436B2 (ja) 入浴剤組成物
JP2019156753A (ja) クレンジング化粧料
JP7372658B2 (ja) 液状水中油型乳化化粧料
JP5185574B2 (ja) 水中油型乳化整髪剤組成物
JP6927833B2 (ja) 水中油型皮膚化粧料
JP2018080139A (ja) 化粧料
JP6829637B2 (ja) 乳液状皮膚化粧料
JP6786360B2 (ja) 美容方法および皮膚化粧料キット

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2019509124

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18776904

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 20187035960

Country of ref document: KR

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18776904

Country of ref document: EP

Kind code of ref document: A1