WO2019188119A1 - Produit cosmétique capillaire - Google Patents

Produit cosmétique capillaire Download PDF

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Publication number
WO2019188119A1
WO2019188119A1 PCT/JP2019/009324 JP2019009324W WO2019188119A1 WO 2019188119 A1 WO2019188119 A1 WO 2019188119A1 JP 2019009324 W JP2019009324 W JP 2019009324W WO 2019188119 A1 WO2019188119 A1 WO 2019188119A1
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WO
WIPO (PCT)
Prior art keywords
component
mass
hair
phosphate
hair cosmetic
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PCT/JP2019/009324
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English (en)
Japanese (ja)
Inventor
藤田範子
小川綾乃
Original Assignee
株式会社マンダム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from JP2018068810A external-priority patent/JP7004601B2/ja
Priority claimed from JP2018068809A external-priority patent/JP6868588B2/ja
Priority claimed from JP2018099375A external-priority patent/JP6949776B2/ja
Priority claimed from JP2018099374A external-priority patent/JP6909179B2/ja
Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to KR1020207006481A priority Critical patent/KR102344638B1/ko
Priority to CN201980004357.8A priority patent/CN111050744A/zh
Publication of WO2019188119A1 publication Critical patent/WO2019188119A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to hair cosmetics.
  • Hair oils mainly composed of liquid oil components are used as hair cosmetics for the purpose of supplementing oils with hair and giving gloss and smoothness.
  • An example of such a hair oil is disclosed in Patent Document 1.
  • the hair oil in addition to the main function of collecting the whole hair, for example, those having a characteristic of softening the hair and a characteristic of making the finish good as a finger without stickiness are required.
  • the present inventors tried to make hair oil contain a polyhydric alcohol such as glycerin from the viewpoint of enhancing the above-described characteristics of softening the hair or imparting water retention to the hair.
  • a hydrophilic polyhydric alcohol in the hair oil disclosed in Patent Document 1.
  • the present inventors tried to contain hydrophilic polyhydric alcohol stably by making hair oil into the oil gel containing water.
  • an object of the present invention is to provide a hair cosmetic that is an oil gel containing water and a polyhydric alcohol, imparts softness to the hair, has an excellent ability to form a hair unit, and can suppress stickiness. It is in.
  • component (A) polyoxyalkylene alkyl ether phosphoric acid and its salt, and polyoxyalkylene alkenyl ether phosphoric acid and its salt.
  • component (B) specific polyhydric alcohol
  • component (C) water
  • component (D) silicone compound having a viscosity within a specific range
  • component (E) volatile oil
  • component (F) According to hair cosmetics each containing ester oil and / or vegetable oil within a specific range, it is an oil gel containing water and a polyhydric alcohol, imparts softness to the hair, The present inventors have found that a hair cosmetic that is excellent in producing power and can suppress stickiness can be obtained. The present invention has been completed based on these findings.
  • this invention contains the following component (A), the following component (B), the following component (C), the following component (D), the following component (E), and the following component (F), ) Content of 0.1 to 5.0% by mass, the content of component (B) is 3.0 to 50.0% by mass, and the content of component (C) is 0.5 to 20.0%. Mass%, the content ratio of the component (D) is 0.3 to 20.0 mass%, the content ratio of the component (E) is 10.0 to 95.0 mass%, and the content ratio of the component (F) is Provided is a hair cosmetic composition of 0.3 to 50.0% by mass.
  • Component (A) One or more compounds selected from the group consisting of polyoxyalkylene alkyl ether phosphoric acid and salts thereof, and polyoxyalkylene alkenyl ether phosphoric acid and salts thereof
  • Component (B) glycerin, diglycerin, polyethylene glycol And one or more polyhydric alcohols selected from the group consisting of sugar alcohols
  • Component (C) Water Component (D): Silicone compound having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C.
  • the hair cosmetic composition further contains the following component (G), and the content of the component (G) is preferably 0.5 to 10.0% by mass.
  • the hair cosmetic further contains the following component (H).
  • Component (H) one or more components selected from the group consisting of glycerin mono-2-ethylhexyl ether, polyoxyethylene octyldodecyl ether, 1,2-octanediol, alkyl glucoside, propylene glycol isostearate, and octyldodecanol
  • the component (D) preferably contains the following component (D1).
  • Component (D1) Dimethiconol with a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C.
  • the component (D) preferably contains the following component (D2).
  • the component (F) preferably contains the following component (F1).
  • Component (F1) one or more ester oils selected from the group consisting of glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylate / caprate), and alkyl benzoate (C12-15)
  • the hair cosmetic preferably further contains the following component (I).
  • the component (A) is an ether phosphate ester composed of a polyoxyethylene residue having an average addition mole number of oxyethylene of 2 to 25 and a saturated aliphatic alcohol residue of 12 to 18 carbon atoms, and a salt thereof, Selected from the group consisting of a phosphoric ester of an ether composed of a polyoxyethylene residue having an average addition mole number of oxyethylene of 2 to 25 and an unsaturated aliphatic alcohol residue having a carbon number of 12 to 18 and a salt thereof.
  • a phosphoric ester of an ether composed of a polyoxyethylene residue having an average addition mole number of oxyethylene of 2 to 25 and an unsaturated aliphatic alcohol residue having a carbon number of 12 to 18 and a salt thereof.
  • One or more compounds are preferred.
  • the component (A) is composed of laureth-4-phosphate, trilaureth-4-phosphate, (C12-15) pares-3 phosphate, triceteares-4 phosphate, oleth-3 phosphate, oleth-5 phosphate, oleth It is preferably at least one component selected from the group consisting of 7-phosphate, oleth-10 phosphate, oleth-20 phosphate, and salts thereof.
  • the hair cosmetic composition of the present invention it can be made into a composition containing water and a polyhydric alcohol, imparts softness to the hair, is excellent in the ability to form a hair unit, and can suppress stickiness. Furthermore, according to the hair cosmetic composition of the present invention, in addition to the above-described effects, it is possible to suppress unnatural luster, to suppress itchiness of the hair after use, and to impart a smooth touch. .
  • a group of hairs includes both “a group of hair tips” and “a group of hairs”. Further, the “softness” of hair in the present invention means that the hair itself feels soft.
  • the hair cosmetic composition of the present invention comprises at least one compound selected from the group consisting of polyoxyalkylene alkyl ether phosphoric acid and salts thereof, and polyoxyalkylene alkenyl ether phosphoric acid and salts thereof; glycerin, diglycerin, polyethylene glycol, And at least one polyhydric alcohol selected from the group consisting of sugar alcohols; water; silicone compounds having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C .; volatile oils; and ester oils and / or vegetable oils.
  • component (A) one or more compounds selected from the group consisting of polyoxyalkylene alkyl ether phosphoric acid and salts thereof, and polyoxyalkylene alkenyl ether phosphoric acid and salts thereof are referred to as “component (A)”, glycerin,
  • component (B) One or more polyhydric alcohols selected from the group consisting of diglycerin, polyethylene glycol, and sugar alcohol are “component (B)”, water is “component (C)”, and the viscosity at 25 ° C. is 10 to 30 million mPa ⁇
  • the silicone compound of s may be referred to as “component (D)”, the volatile oil as “component (E)”, and the ester oil and / or vegetable oil as “component (F)”.
  • the hair cosmetic composition of the present invention includes at least a component (A), a component (B), a component (C), a component (D), a component (E), and a component (F).
  • the hair cosmetic composition of the present invention may contain components other than the above components (A) to (F).
  • each component contained in the hair cosmetics of this invention for example, a component (A), a component (B), a component (C), a component (D), a component (E), a component (F), and another component
  • Each component such as may be used alone or in combination of two or more.
  • Component (A) One or more compounds selected from the group consisting of polyoxyalkylene alkyl ether phosphoric acid and salts thereof, and polyoxyalkylene alkenyl ether phosphoric acid and salts thereof]
  • Component (A) is one or more compounds selected from the group consisting of polyoxyalkylene alkyl ether phosphates and salts thereof, and polyoxyalkylene alkenyl ether phosphates and salts thereof (polyoxyalkylene alkyl ether phosphates (salts)) And / or polyoxyalkylene alkenyl ether phosphoric acid (salt)).
  • the component (A) is at least selected from the group consisting of polyoxyalkylene alkyl ether phosphate, polyoxyalkylene alkyl ether phosphate, polyoxyalkylene alkenyl ether phosphate, and polyoxyalkylene alkenyl ether phosphate.
  • a component (A) may use only 1 type and may use 2 or more types.
  • the component (A), the component (B), and the component (C) are used in combination with an oil component to form an oil gel having a liquid crystal gel structure, It becomes possible to take in water and polyhydric alcohol, so that the hair cosmetic composition of the present invention softens the hair itself and imparts softness with moisture to the hair in addition to the function of the hair oil that groups the hair. be able to. Furthermore, the function of grouping hair can be further enhanced.
  • Polyoxyalkylene alkyl ether phosphoric acid is a phosphate ester of an ether (polyoxyalkylene alkyl ether) composed of a polyoxyalkylene residue and a monovalent saturated aliphatic alcohol residue.
  • Polyoxyalkylene alkenyl ether phosphoric acid is a phosphate ester of an ether (polyoxyalkylene alkenyl ether) composed of a polyoxyalkylene residue and a monovalent unsaturated aliphatic alcohol residue.
  • Examples of the oxyalkylene constituting the polyoxyalkylene residue in the polyoxyalkylene alkyl ether and the polyoxyalkylene alkenyl ether include oxyalkylene having 2 to 4 carbon atoms such as oxyethylene, oxypropylene and oxybutylene.
  • polyoxyethylene is preferable as polyoxyalkylene.
  • the polyoxyalkylene may contain only one kind of oxyalkylene, or may contain two or more kinds of oxyalkylene. Further, the average added mole number of oxyalkylene in the polyoxyalkylene is, for example, 2 to 25, preferably 2 to 20.
  • the monovalent saturated aliphatic alcohol residue constituting the polyoxyalkylene alkyl ether contains a monovalent saturated aliphatic hydrocarbon group.
  • the monovalent saturated aliphatic hydrocarbon group include saturated aliphatic hydrocarbon groups having 10 to 36 carbon atoms (preferably 12 to 18 carbon atoms) such as lauryl group, cetyl group and stearyl group.
  • the monovalent saturated aliphatic hydrocarbon group may be linear or branched.
  • the monovalent unsaturated aliphatic alcohol residue constituting the polyoxyalkylene alkenyl ether contains a monovalent unsaturated aliphatic hydrocarbon group.
  • the monovalent unsaturated aliphatic hydrocarbon group include unsaturated aliphatic hydrocarbon groups having 10 to 36 carbon atoms (preferably 12 to 18 carbon atoms) such as oleyl groups.
  • the monovalent unsaturated aliphatic hydrocarbon group may be linear or branched.
  • the polyoxyalkylene alkyl ether phosphoric acid and the polyoxyalkylene alkenyl ether phosphoric acid may be any of monoester, diester and triester, or a mixture of two or more of these.
  • Examples of the polyoxyalkylene alkyl ether phosphate and polyoxyalkylene alkenyl ether phosphate include inorganic salts, organic amine salts, basic amino acid salts, and the like.
  • Examples of the inorganic salt include alkali metal salts such as sodium salt and potassium salt; alkaline earth metal salts such as magnesium salt and calcium salt; ammonium salt; aluminum salt; zinc salt and the like.
  • Examples of the organic amine salt include a monoethanolamine salt, a diethanolamine salt, and a triethanolamine salt.
  • Examples of basic amino acid salts include arginine salts and lysine salts.
  • Examples of the component (A) include polyoxyalkylene lauryl ether phosphates such as laureth-2 phosphate, laureth-4 phosphate, dilaureth-10 phosphate, trilaureth-4 phosphate; Oxyalkylene isolauryl ether phosphate; polyoxyalkylene cetyl ether phosphate such as ceteth-10 phosphate and ceteth-20 phosphate; polyoxyalkylene stearyl ether phosphate such as steareth-2 phosphate and steareth-3 phosphate; Polyoxyalkylene cetearyl ether phosphoric acid such as triceteales-4 phosphate; Ores-3 phosphate, Ores-4 phosphate, Ores-5 phosphate, Ores-7 phosphate, Ores-8 phosphate, Ores-10 phosphate Acid, oleth-20 phosphoric acid, dioleth-8 phosphoric acid, etc.
  • polyoxyalkylene lauryl ether phosphates
  • polyoxyalkylene lauryl ether phosphoric acid polyoxyalkylene alkyl (C12-15) ether phosphoric acid, polyoxyalkylene cetearyl ether phosphoric acid, polyoxyalkylene oleyl ether phosphoric acid, and salts thereof are preferable, and more preferable.
  • the component (A) it is particularly preferable to use a combination of polyoxyalkylene alkyl ether phosphoric acid (salt) and polyoxyalkylene alkenyl ether phosphoric acid (salt).
  • the ratio of the content of polyoxyalkylene alkenyl ether phosphoric acid (salt) to the total content of polyoxyalkylene alkyl ether phosphoric acid (salt) and polyoxyalkylene alkenyl ether phosphoric acid (salt) is 10.0 to 90 0.0 mass% is preferable, more preferably 20.0 to 80.0 mass%, and still more preferably 30.0 to 70.0 mass%. When the ratio is within the above range, the oil gel is more easily crushed.
  • the content of the component (A) in the hair cosmetic of the present invention is 0.1 to 5.0% by mass, preferably 0.3 to 4.% by mass with respect to 100% by mass of the hair cosmetic of the present invention. It is 0% by mass, more preferably 0.5 to 3.0% by mass.
  • an oil gel capable of taking in water and polyhydric alcohol can be formed by using in combination with the component (B) and the component (C).
  • the content rate of the said component (A) is the sum total of the content rate of all the components (A) in the hair cosmetics of this invention.
  • Component (B) one or more polyhydric alcohol selected from the group consisting of glycerin, diglycerin, polyethylene glycol, and sugar alcohol
  • Component (B) is one or more polyhydric alcohols selected from the group consisting of glycerin, diglycerin, polyethylene glycol, and sugar alcohol. Only 1 type may be used for a component (B), and 2 or more types may be used for it.
  • the polyethylene glycol is not particularly limited, but from the viewpoint of reducing skin irritation, the number average molecular weight is preferably 50 to 10,000, more preferably 100 to 1,000.
  • the sugar alcohol is not particularly limited, and examples thereof include sorbitol, maltitol, trehalose, erythritol, arabitol, ribitol, xylitol, galactitol, mannitol and the like.
  • the content of the component (B) in the hair cosmetic of the present invention is 3.0 to 50.0% by mass, preferably 5.0 to 30.30%, with respect to 100% by mass of the hair cosmetic of the present invention. 0% by mass.
  • an oil gel capable of taking in water and polyhydric alcohol can be formed by using in combination with the component (A) and the component (C).
  • the content rate of the said component (B) is the sum total of the content rate of all the components (B) in the hair cosmetics of this invention.
  • Component (C) is water and is not particularly limited, but purified water is preferred.
  • the content of the component (C) in the hair cosmetic of the present invention is 0.5 to 20.0% by mass, preferably 1.5 to 15% with respect to 100% by mass of the hair cosmetic of the present invention.
  • the content is 0% by mass, more preferably 2.5 to 10.0% by mass.
  • Component (D) Silicone compound having a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C.
  • Component (D) is a silicone compound having a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C.
  • Component (D) can form a film on the hair after application of the hair cosmetic, suppress stickiness and unnatural glossiness of the hair, have a natural texture, and can give a light touch.
  • the hair unit can be made excellent.
  • the touch of the hair can be improved by improving the fingering of the hair or suppressing the occurrence of itching. Only 1 type may be used for a component (D), and 2 or more types may be used for it.
  • the viscosity of Component (D) at 25 ° C. is 10 to 30 million mPa ⁇ s, preferably 12 to 25 million mPa ⁇ s, from the viewpoint of exerting the above-described effects.
  • Component (D) is preferably dimethiconol or dimethylpolysiloxane. That is, the component (D) includes, among others, dimethiconol having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C. (sometimes referred to as “component (D1)”), and a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C. Preferred is dimethylpolysiloxane (dimethicone) of s (sometimes referred to as “component (D2)”).
  • the component (D) preferably includes the component (D1) and the component (D2).
  • Component (D1) Dimethiconol having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C.
  • Component (D1) is dimethiconol having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C. Dimethiconol is obtained by replacing the terminal methyl group of dimethylpolysiloxane with a hydroxyl group.
  • Ingredient (D1) forms a film on the hair after application of the hair cosmetic, suppresses stickiness and unnatural glossiness of the hair, can have a natural texture, and can give a light touch. Moreover, the hair unit can be made excellent.
  • the touch of the hair can be improved by improving the fingering of the hair or suppressing the occurrence of itching.
  • coating can be made into a soft touch.
  • Component (D1) has a viscosity at 25 ° C. of 10 to 30 million mPa ⁇ s, preferably 12 to 25 million mPa ⁇ s from the viewpoint of exerting the above-described effects.
  • D1 Commercially available components (D1) include trade name “XF49-C2499”, trade name “XF49-C2520”, trade name “XF49-C4470”, trade name “XF49-C2497”, trade name “XF49-C4996”, A trade name “XF49-C2070” (both manufactured by Momentive Performance Materials) can be mentioned.
  • Component (D2) Dimethylpolysiloxane having a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C.
  • Component (D2) is a dimethylpolysiloxane (dimethicone) having a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C. is there.
  • Ingredient (D2) forms a film on the hair after application of the hair cosmetic, suppresses stickiness and unnatural glossiness of the hair, can have a natural texture, and can give a light touch. Moreover, the hair unit can be made excellent. In addition, the touch of the hair can be improved by improving the fingering of the hair or suppressing the occurrence of itching.
  • the component (D2) does not include a component corresponding to the component (D1). Only 1 type may be used for a component (D2), and 2 or more types may be used for it.
  • Component (D2) has a viscosity at 25 ° C. of 10 to 30 million mPa ⁇ s, preferably 12 to 25 million mPa ⁇ s, from the viewpoint of exerting the above-described effects.
  • D2 Commercially available components include trade name “XF49-811”, trade name “XF49-813”, trade name “XF49-D1747”, trade name “XF49-B2317”, trade name “XF49-B1747” ( Both of them are manufactured by Momentive Performance Materials).
  • the content ratio of the component (D) in the hair cosmetic composition of the present invention is 0.3 to 20.0 mass%, preferably 1.0 to 15%, with respect to 100 mass% of the hair cosmetic composition of the present invention.
  • the content is 0% by mass, more preferably 3.0 to 10.0% by mass.
  • the component (D) forms a film on the hair after the application of the hair cosmetic, suppressing hair stickiness and unnatural gloss, It can be excellent.
  • the said content rate exceeds 20.0 mass%, it will become difficult to contain a highly viscous component (D) in hair makeup stably.
  • the content rate of the said component (D) is the sum total of the content rate of all the components (D) in the hair cosmetics of this invention.
  • the content of the component (D1) in the hair cosmetic of the present invention is preferably 0.3 to 20.0% by mass, more preferably 0.5 to 10% with respect to 100% by mass of the hair cosmetic of the present invention. 0.0 mass%, more preferably 0.8 to 7.0 mass%. When the content is 0.3% by mass or more, after applying the hair cosmetic, the hair is softened, and the hair ends are more excellently consolidated while suppressing the stickiness and unnatural luster of the hair. it can.
  • a high-viscosity component (D1) can be contained in hair makeup stably as the said content rate is 20.0 mass% or less.
  • the content rate of the said component (D1) is the sum total of the content rate of all the components (D1) in the hair cosmetics of this invention.
  • the content ratio of the component (D2) in the hair cosmetic composition of the present invention is preferably 0.3 to 20.0 mass%, more preferably 1.0 to 15 mass% with respect to 100 mass% of the hair cosmetic composition of the present invention. 0.0% by mass. When the content ratio is 0.3% by mass or more, it is possible to further improve the unitization of the hair tips while suppressing the stickiness and unnatural luster of the hair. When the content is 20.0% by mass or less, the high-viscosity component (D2) can be stably contained in the hair makeup.
  • the content rate of the said component (D2) is the sum total of the content rate of all the components (D2) in the hair cosmetics of this invention.
  • Component (E) is an oil (oil) having volatility at 25 ° C.
  • the boiling point of component (E) is, for example, 250 ° C. or lower, and preferably 230 ° C. or lower.
  • the component (E) can dissolve the component (D), the component (F), the component (G), the component (I) and the like and apply them on the hair, and volatilizes after the application. Only 1 type may be used for a component (E), and 2 or more types may be used for it.
  • component (E) examples include cyclic silicone oil, methyltrimethicone, ethyltrisiloxane, trisiloxane, caprylylmethicone, hydrocarbon oil, and dimethyl having a viscosity at 25 ° C. of 0.1 to 2.0 mm 2 / s. Polysiloxane etc. are mentioned.
  • cyclic silicone oil examples include methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and the like.
  • hydrocarbon oil examples include isoparaffin, light isoparaffin, light liquid isoparaffin, hydrogenated polyisobutene, hydrogenated (tetradecenyl / methylpentadecene), and isododecane.
  • the content ratio of the component (E) in the hair cosmetic composition of the present invention is 10.0 with respect to 100% by mass of the hair cosmetic composition of the present invention from the viewpoint of exhibiting a function as a base for dissolving other components.
  • To 95.0% by mass preferably 30.0 to 95.0% by mass, more preferably 40.0 to 90.0% by mass, and further preferably 50.0 to 85.0% by mass.
  • the content rate of the said component (E) is the sum total of the content rate of all the components (E) in the hair cosmetics of this invention.
  • Component (F) Ester oil and / or vegetable oil
  • Component (F) is ester oil and / or vegetable oil. That is, one or both of ester oil and vegetable oil.
  • Ingredient (F) gives the hair a moist feeling after application, and makes the hair unity.
  • a component (F) may use only 1 type and may use 2 or more types.
  • ester oil examples include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, octyldodecyl myristate, isopropyl isostearate, propylene glycol isostearate, 2- Cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylate / caprate), isononyl isononanoate, diisopropyl adipate, pentaerythrityl tetraoctanoate, pentaerythritol tetraisostearate, diisostearyl malate , Erythrityl triethylhexanoate, 2-ethylhexyl hydroxystearate, hexa (
  • Examples of the vegetable oil include macadamia nut oil, eucalyptus oil, palm oil, avocado oil, safflower oil, olive oil, palm oil, palm kernel oil, kukui nut oil, shea butter, cocoa butter, almond oil, sunflower oil.
  • Rosehip oil olive squalane, camelia oil, kiwi fruit seed oil, camellia oil, apricot oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, medhome oil, mint oil, argan oil, carrot oil, lavender oil , Sugar squalane, damask rose flower wax, centifolia rose flower wax, grass flower wax, camellia oil, hydrogenated products thereof (for example, hydrogenated castor oil, hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated avocado oil, hydrogen Additive soybean oil, etc.).
  • Component (F) is one or more ester oils selected from the group consisting of glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylate / caprate), and alkyl benzoate (C12-15) (“component (F1 ) ” May be included.
  • component (F1) the hair after application is given a moist feeling to make the whole hair and the unit of the hair ends better. Only 1 type may be used for a component (F1), and 2 or more types may be used for it.
  • Alkyl benzoate (C12-15) is an ester of benzoic acid and an aliphatic alcohol having 12 to 15 carbon atoms.
  • Alkyl benzoate (C12-15) is a compound represented by the INCI name: C12-15 Alkyl Benzoate.
  • the content of the component (F) in the hair cosmetic of the present invention is 0.3 to 50.0% by mass, preferably 0.3 to 10%, relative to 100% by mass of the hair cosmetic of the present invention.
  • the content is 0% by mass, more preferably 0.5 to 7.0% by mass, and still more preferably 1.0 to 5.0% by mass.
  • the said content rate is 0.3 mass% or more, a moist feeling is given to hair and the whole hair and the unit of a hair tip are made favorable.
  • the said content rate being 50.0 mass% or less, the stickiness and unnatural glossiness of hair can be suppressed, it can be set as a natural texture, and the effect that a light touch is obtained improves further.
  • the content rate of a vegetable oil is 10.0 mass% or less with respect to 100 mass% of hair cosmetics of this invention from a viewpoint of suppressing stickiness and unnatural glossiness.
  • the content rate of the said component (F) is the sum total of the content rate of all the components (F) in the hair cosmetics of this invention.
  • the content ratio of the component (F1) in the hair cosmetic composition of the present invention is preferably 0.5 to 7.0 mass%, more preferably 1.0 to 5 mass% with respect to 100 mass% of the hair cosmetic composition of the present invention. 0.0% by mass. When the content ratio is 0.5% by mass or more, the force for gathering the entire hair and the hair ends is further improved. When the content is 7.0% by mass or less, stickiness of hair and generation of unnatural gloss can be further suppressed.
  • the content rate of the said component (F1) is the sum total of the content rate of all the components (F1) in the hair cosmetics of this invention.
  • Component (G) Dimethylpolysiloxane having a viscosity of 50,000 to 100,000 mm 2 / s at 25 ° C.
  • the hair cosmetic composition of the present invention preferably further contains dimethylpolysiloxane having a viscosity of 50,000 to 100,000 mm 2 / s at 25 ° C. (sometimes referred to as “component (G)”).
  • the viscosity of the component (G) at 25 ° C. is more preferably from 100,000 to 100,000 mm 2 / s.
  • a component (G) may use only 1 type and may use 2 or more types.
  • the content ratio of the component (G) in the hair cosmetic composition of the present invention is preferably 0.5 to 10.0 mass%, more preferably 1.0 to 7 mass% with respect to 100 mass% of the hair cosmetic composition of the present invention. 0.0% by mass.
  • the content rate of the said component (G) is the sum total of the content rate of all the components (G) in the hair cosmetics of this invention.
  • Component (H) one or more components selected from the group consisting of glycerin mono-2-ethylhexyl ether, polyoxyethylene octyldodecyl ether, 1,2-octanediol, alkyl glucoside, propylene glycol isostearate, and octyldodecanol
  • the hair cosmetic composition of the present invention is further selected from the group consisting of glycerin mono-2-ethylhexyl ether, polyoxyethylene octyldodecyl ether, 1,2-octanediol, alkyl glucoside, propylene glycol isostearate, and octyldodecanol.
  • component (H) It preferably contains one or more components (sometimes referred to as “component (H)”).
  • component (H) has an appropriate polarity and is presumed to have characteristics that are easily incorporated into the liquid crystal phase formed by the components (A) to (C), but improves the fluidity of the liquid crystal phase, The viscosity of the hair cosmetic composition of the present invention can be lowered appropriately. Only 1 type may be used for a component (H), and 2 or more types may be used for it.
  • the average number of moles of oxyethylene added to the polyoxyethylene octyldodecyl ether is preferably 3 to 20, and more preferably 3 to 10.
  • alkyl glucoside examples include decyl glucoside and lauryl glucoside. Of these, decylglucoside is preferred.
  • the content of the component (H) in the hair cosmetic composition of the present invention is preferably 0.01 to 5.0 mass%, more preferably 0.1 to 3 mass% with respect to 100 mass% of the hair cosmetic composition of the present invention. 0.0% by mass.
  • the content rate of the said component (H) is the sum total of the content rate of all the components (H) in the hair cosmetics of this invention.
  • Component (I) Liquid paraffin with a flash point of 200 to 300 ° C.
  • the hair cosmetic composition of the present invention preferably further contains liquid paraffin (sometimes referred to as “component (I)”) having a flash point of 200 to 300 ° C.
  • Component (I) is a liquid paraffin having a relatively high flash point. By using it in combination with component (D1), a film is formed on the hair after the application of the hair cosmetic. The unity can be made excellent.
  • component (I) only one kind may be used, or two or more kinds may be used.
  • the content of component (I) in the hair cosmetic composition of the present invention is preferably 0.3 to 15.0 mass%, more preferably 0.3 to 8 mass%, relative to 100 mass% of the hair cosmetic composition of the present invention. It is 0.0% by mass, more preferably 0.5 to 6.0% by mass, and particularly preferably 1.0 to 6.0% by mass. When the content is 0.3% by mass or more, the unit of hair ends can be made more excellent after application of the hair cosmetic. When the content is 15.0% by mass or less, stickiness of hair and unnatural gloss can be further suppressed.
  • the content rate of the said component (I) is the sum total of the content rate of all the components (I) in the hair cosmetics of this invention.
  • Component (J) Amino-modified dimethylpolysiloxane
  • the hair cosmetic composition of the present invention preferably further contains amino-modified dimethylpolysiloxane (sometimes referred to as “component (J)”).
  • Component (J) can impart flexibility to the hair after application of the hair cosmetic. Moreover, the unit of the whole hair can be improved more.
  • a component (J) may use only 1 type and may use 2 or more types.
  • the content of the component (J) in the hair cosmetic of the present invention is preferably 0.05 to 3.0% by mass, more preferably 0.1 to 1% with respect to 100% by mass of the hair cosmetic of the present invention. 0.0% by mass.
  • flexibility can be provided with hair after application
  • the content rate of the said component (J) is the sum total of the content rate of all the components (J) in the hair cosmetics of this invention.
  • the hair cosmetic composition of the present invention may contain components (other components) other than the components (A) to (J) as long as the object of the present invention is not impaired.
  • the other components are not particularly limited, and examples include components usually used for cosmetics and quasi drugs.
  • lower alcohols such as ethanol; polyhydric alcohols other than component (B), oily components other than components (D) to (G), (I), (J); nonionic surfactants; Surfactants other than component (A) and component (H) such as anionic surfactant, cationic surfactant, amphoteric surfactant; carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, hydroxymethylcellulose, Thickeners such as hydroxypropylmethylcellulose and xanthan gum; moisturizers; bactericides; pearlizing agents; anti-inflammatory agents such as glycyrrhizic acid and its salts; refreshing agents such as menthol; phosphoric acid and its salts; citric acid and its salts; PH adjusters such as lactic acid and its salts, sodium hydroxide, triethanolamine; fragrances; UV absorbers; antioxidants; (Chelating agents); Film-forming polymer compounds such as pyrivinylpyrrolidone
  • the hair cosmetic composition of the present invention is not particularly limited and can be produced by a known or conventional method.
  • it can be produced by mixing the above components and stirring them with a homomixer, paddle mixer or the like.
  • the hair cosmetic composition of the present invention is a so-called hair oil.
  • Examples of the hair cosmetic of the present invention include out bath treatments and hair styling agents.
  • the hair cosmetic composition of the present invention is used, for example, for the purpose of suppressing the spread of the hair and putting the hair together, for the purpose of giving gloss to the hair, and for the purpose of protecting the hair from heat such as a dryer or a hair iron.
  • the usage method of the hair cosmetics of this invention is not specifically limited, For example, the following method is mentioned.
  • a suitable amount of the hair cosmetic composition of the present invention is applied to the hair in whole or in part, and dried using a dryer or the like.
  • a suitable amount of the hair cosmetic composition of the present invention is applied in whole or in part to dry hair or slightly moistened hair, and a hair iron is used as necessary to adjust the hair.
  • the hair cosmetic composition of the present invention may be used in combination with other hair styling agents.
  • the hair cosmetic composition of the present invention uses one or more compounds [component (A)] selected from the group consisting of polyoxyalkylene alkyl ether phosphates and salts thereof, and polyoxyalkylene alkenyl ether phosphates and salts thereof,
  • one or more polyhydric alcohols [component (B)] and water [component (C)] selected from the group consisting of glycerin, diglycerin, polyethylene glycol, and sugar alcohol are combined at a specific ratio, A gel (liquid crystal gel) containing a monohydric alcohol and water is formed.
  • a silicone compound [component (D)] having a viscosity of 10 to 30 million mPa ⁇ s at 25 ° C., a volatile oil [component (E)], and an ester oil And / or vegetable oil [component (F)] is each used in the specific content rate.
  • the oily component is obtained by combining the component (D) and the component (E) in a specific content ratio, so that the component (D) is dissolved in the hair cosmetic and the component (E) is applied after the hair cosmetic is applied. Volatilizes to form a film of component (D) on the hair.
  • the component (F) is used at a specific content ratio, so that the effect of using the component (D) and the component (E) is exhibited while the component (F) ), And the ability to make a hair unit can be improved.
  • component (I)] dimethiconol having a viscosity of 10 million to 30 million mPa ⁇ s at 25 ° C.
  • component (I)] liquid paraffin having a flash point of 200 to 300 ° C.
  • the compounding amount described in the table is the compounding amount of each component (that is, the compounding amount of the active ingredient in each raw material, so-called pure content), and is represented by “mass%” unless otherwise specified.
  • sample hair bundle after application The sample hair bundle after application of the hair cosmetic
  • sample hair bundle before application of the hair cosmetic is referred to as “uncoated sample hair bundle”.
  • the hair cosmetic composition (Example) of the present invention is an oil gel containing water and a polyhydric alcohol, imparts softness to the hair, is excellent in the ability to form a hair unit, and suppresses stickiness and unnatural luster. It was evaluated that it was possible. On the other hand, when at least one of the component (A), the component (B), and the component (C) is not blended (Comparative Examples 1, 2, and 4), it is evaluated as having no gel state. It was. Further, when 1,3-butylene glycol was used in place of component (B) (Comparative Example 3), it was evaluated that it did not have a gel state.
  • Formulation Example 1 Hair oil gel polyoxyethylene (20) oleyl ether phosphoric acid 0.6% by mass Polyoxyethylene (4) cetyl ether phosphoric acid 0.8% by mass Glycerin 10.0% by mass 4.0% by weight of water Dimethiconol (viscosity about 18 million mPa ⁇ s) 2.0% by mass Liquid paraffin (flash point 250 ° C) 2.0% by mass Glyceryl tri-2-ethylhexanoate 2.0% by mass Cetyl 2-ethylhexanoate 1.0% by mass Highly polymerized dimethylpolysiloxane (viscosity: about 18 million mPa ⁇ s) 4.0% by mass Dimethylpolysiloxane (viscosity 5mm 2 / s) 2.0% by mass Dimethylpolysiloxane (viscosity 10mm 2 / s) 1.0% by mass Dimethylpolysiloxane (viscosity 60000 mm 2 / s) 0.5% by
  • Formulation example 2 Hair oil gel polyoxyethylene (20) oleyl ether phosphoric acid 1.0 mass% Polyoxyethylene (4) cetyl ether phosphate 0.4% by mass Glycerin 8.0% by mass 4.0% by weight of water Dimethiconol (viscosity about 18 million mPa ⁇ s) 4.0% by mass Glyceryl tri-2-ethylhexanoate 2.0% by mass Isononyl isononanoate 1.0% by mass Highly polymerized dimethylpolysiloxane (viscosity: about 18 million mPa ⁇ s) 3.0% by mass Dimethylpolysiloxane (viscosity 1.5mm 2 / s) 2.0% by mass Dimethylpolysiloxane (viscosity 350mm 2 / s) 1.0% by mass Dimethylpolysiloxane (viscosity 60000 mm 2 / s) 0.5% by mass Amodimethicone 0.5% by mass Meadow Foam Oil 1.0% by mass Cyclo

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Abstract

L'invention concerne un produit cosmétique capillaire qui est un gel d'huile contenant de l'eau et de l'alcool polyhydrique, le produit cosmétique capillaire conférant une souplesse aux cheveux, fournissant une excellente aptitude à la mise en forme, et étant capable de supprimer l'adhésivité. Un produit cosmétique capillaire qui contient le composant (A) suivant, le composant (B) suivant, le composant (C) suivant, le composant (D) suivant, le composant (E) suivant et le composant (F) suivant, la teneur en composant (A) étant de 0,1 à 5,0 % en masse, la teneur en composant (B) étant de 3,0 à 50,0 % en masse, la teneur en composant (C) étant de 0,5 à 20,0 % en masse, la teneur en composant (D) étant de 0,3 à 20,0 % en masse, la teneur en composant (E) étant de 10,0 à 95,0 % en masse, et la teneur en composant (F) étant de 0,3 à 50,0 % en masse. Composant (A) : un ou plusieurs composés choisis dans le groupe constitué par l'acide polyoxyalkylène alkyl éther phosphorique, les sels de celui-ci, l'acide polyoxyalkylène alcényléther phosphorique, et les sels de celui-ci. Composant (B) : un ou plusieurs alcools polyhydriques choisis dans le groupe constitué par la glycérine, la diglycérine, le polyéthylène glycol et les alcools de sucre. Composant (C) : eau. Composant (D) : un composé de silicone ayant une viscosité à 25 °C de 10 000 000 à 30 000 000 mPa∙s. Composant (E) : une huile volatile. Composant (F) : une huile d'ester et/ou une huile végétale.
PCT/JP2019/009324 2018-03-30 2019-03-08 Produit cosmétique capillaire WO2019188119A1 (fr)

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CN201980004357.8A CN111050744A (zh) 2018-03-30 2019-03-08 毛发化妆料

Applications Claiming Priority (8)

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JP2018-068809 2018-03-30
JP2018068810A JP7004601B2 (ja) 2018-03-30 2018-03-30 油性毛髪化粧料
JP2018068809A JP6868588B2 (ja) 2018-03-30 2018-03-30 毛髪化粧料
JP2018-068810 2018-03-30
JP2018099375A JP6949776B2 (ja) 2018-05-24 2018-05-24 油性化粧料
JP2018-099375 2018-05-24
JP2018099374A JP6909179B2 (ja) 2018-05-24 2018-05-24 油性化粧料
JP2018-099374 2018-05-24

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Cited By (2)

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GB2581555A (en) * 2018-12-18 2020-08-26 Henkel Ag & Co Kgaa Cleansing hair oil, method for applying same, and use of same for care of keratin fibres
JP2021080210A (ja) * 2019-11-19 2021-05-27 株式会社マンダム 油性化粧料

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Publication number Priority date Publication date Assignee Title
JPH04217612A (ja) * 1990-12-18 1992-08-07 Kao Corp ゲル状毛髪化粧料
JP2008169182A (ja) * 2007-01-15 2008-07-24 Hoyu Co Ltd 毛髪化粧料組成物
JP2009184949A (ja) * 2008-02-05 2009-08-20 Shiseido Co Ltd 毛髪化粧料
JP2017137250A (ja) * 2016-02-02 2017-08-10 株式会社アリミノ 整髪用組成物

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JP2007269726A (ja) 2006-03-31 2007-10-18 Kose Corp ヘアオイル

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JPH04217612A (ja) * 1990-12-18 1992-08-07 Kao Corp ゲル状毛髪化粧料
JP2008169182A (ja) * 2007-01-15 2008-07-24 Hoyu Co Ltd 毛髪化粧料組成物
JP2009184949A (ja) * 2008-02-05 2009-08-20 Shiseido Co Ltd 毛髪化粧料
JP2017137250A (ja) * 2016-02-02 2017-08-10 株式会社アリミノ 整髪用組成物

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2581555A (en) * 2018-12-18 2020-08-26 Henkel Ag & Co Kgaa Cleansing hair oil, method for applying same, and use of same for care of keratin fibres
GB2581555B (en) * 2018-12-18 2023-05-17 Henkel Ag & Co Kgaa Cleansing hair oil, method for applying same, and use of same for care of keratin fibers
JP2021080210A (ja) * 2019-11-19 2021-05-27 株式会社マンダム 油性化粧料
JP7372121B2 (ja) 2019-11-19 2023-10-31 株式会社マンダム 油性化粧料

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