WO2018168487A1 - Composition de résine aqueuse pour flocage, et article floqué - Google Patents

Composition de résine aqueuse pour flocage, et article floqué Download PDF

Info

Publication number
WO2018168487A1
WO2018168487A1 PCT/JP2018/007723 JP2018007723W WO2018168487A1 WO 2018168487 A1 WO2018168487 A1 WO 2018168487A1 JP 2018007723 W JP2018007723 W JP 2018007723W WO 2018168487 A1 WO2018168487 A1 WO 2018168487A1
Authority
WO
WIPO (PCT)
Prior art keywords
flocking
resin composition
aqueous resin
meth
mass
Prior art date
Application number
PCT/JP2018/007723
Other languages
English (en)
Japanese (ja)
Inventor
まり子 綱島
伊藤　弘行
Original Assignee
Dic株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dic株式会社 filed Critical Dic株式会社
Priority to CN201880015653.3A priority Critical patent/CN110382617B/zh
Priority to JP2018560689A priority patent/JP6485724B2/ja
Publication of WO2018168487A1 publication Critical patent/WO2018168487A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
    • C08K5/353—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/12—Applying particulate materials
    • B05D1/14—Flocking
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof

Definitions

  • the present invention relates to an aqueous resin composition used for a flocked product.
  • the flocking process is a processing method in which short fibers are attached to a base material coated with a binder by electrostatic force, and is used for various purposes, mainly household goods, for heat insulation and texture.
  • a binder an aqueous resin is generally used, and among these, an acrylic emulsion is often used.
  • the self-crosslinking acrylic emulsion has low adhesive strength with short fibers and a sufficient flocking strength cannot be obtained, improvement in strength and durability by adding a water-soluble crosslinking agent has been studied.
  • an aqueous acrylic resin composition comprising a water-dispersible acrylic copolymer, a water-soluble or water-dispersible polymer compound, and a water-soluble polymer compound containing an oxazoline group has been proposed.
  • this acrylic resin aqueous composition does not provide sufficient adhesion to vinyl chloride, which is often used as a base material for flocking, and has insufficient stability over time, such as thickening and changes in physical properties. There was a problem.
  • the problem to be solved by the present invention is to provide an aqueous resin composition for flocking processing that provides a flocked product that is excellent in stability over time, excellent in flocking strength and substrate adhesion.
  • the present inventors have found that the aqueous resin composition for flocking processing containing a specific neutralized acrylic resin, a resin having an oxazoline group, and an aqueous medium is the above.
  • the present inventors have found that the problems can be solved and completed the present invention.
  • the present invention relates to an acrylic resin (C) in which a polymer (A) having a carboxyl group is neutralized with a basic compound (B) containing a metal hydroxide (b1) as an essential component, and a polyoxazoline compound.
  • the present invention relates to an aqueous resin composition for flocking processing comprising (D) and an aqueous medium (E).
  • the aqueous resin composition for flocking processing according to the present invention provides a flocked processed product having excellent flocking strength and substrate adhesion, and thus can be used in various applications including, for example, gloves, automobile interior materials, electric parts and the like. Can be used.
  • the aqueous resin composition for flocking processing of the present invention comprises an acrylic resin (C) in which a polymer (A) having a carboxyl group is neutralized with a basic compound (B) containing a metal hydroxide (b1) as an essential component. ), A polyoxazoline compound (D), and an aqueous medium (E).
  • the polymer (A) having a carboxyl group can be obtained by copolymerizing a monomer (a1) having a carboxyl group and another monomer (a2).
  • Examples of the monomer (a1) having a carboxyl group include unsaturated monocarboxylic acids such as (meth) acrylic acid and crotonic acid; unsaturated acids such as itaconic acid (anhydride), maleic acid (anhydride), and fumaric acid. And dicarboxylic acid. These monomers (a1) can be used alone or in combination of two or more.
  • (meth) acrylic acid refers to one or both of acrylic acid and methacrylic acid
  • (meth) acrylate refers to one or both of acrylate and methacrylate
  • acid (Anhydride) refers to one or both of an acid and an acid anhydride.
  • Examples of the other monomer (a2) include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, n-butyl (meth) acrylate, i-butyl (meth) acrylate, t- Alkyl (meth) acrylates such as butyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, isobornyl (meth) acrylate; 2-hydroxyethyl ( (Meth) acrylates having hydroxyl groups such as (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate; N, N-dimethylaminoethyl (Meth) acryl
  • the monomer (a1) is used in an amount of 0.3 to 5% by mass in the monomer component used as the raw material of the polymer (A) because the flocking strength and the flexibility of the film are further improved.
  • the range is preferable, and the range of 0.5 to 3% by mass is more preferable.
  • acrylonitrile in the range of 4 to 10% by mass in the monomer component used as the raw material of the polymer (A).
  • the acid value of the polymer (A) is preferably in the range of 2 to 40 and more preferably in the range of 2 to 20 because the flocking strength and the flexibility of the film are further improved.
  • Examples of the method for producing the polymer (A) include an emulsion polymerization method using water as a solvent, a solution polymerization method using an organic solvent as a solvent, and the like. An aqueous dispersion of the polymer (A) is more simply used. The emulsion polymerization method is preferred because it is obtained.
  • Examples of the emulsion polymerization method include radical polymerization of the monomer (a1) and the monomer (a2) at a temperature of 40 to 100 ° C. in the presence of a polymerization initiator and a surfactant in an aqueous medium. A method is mentioned.
  • polymerization initiator examples include azo compounds such as 2,2′-azobis (isobutyronitrile), 2,2′-azobis (2-methylbutyronitrile), azobiscyanovaleric acid; tert-butylperoxy Organic peroxides such as pivalate, tert-butylperoxybenzoate, tert-butylperoxy-2-ethylhexanoate, di-tert-butyl peroxide, cumene hydroperoxide, benzoyl peroxide, tert-butyl hydroperoxide Oxides; inorganic peroxides such as hydrogen peroxide, ammonium persulfate, potassium persulfate, sodium persulfate and the like. These polymer initiators can be used alone or in combination of two or more. In addition, the polymerization initiator is preferably used in a range of 0.1 to 10% by mass with respect to the total amount of monomers that are raw materials for the polymer (A).
  • azo compounds such
  • the polymerization initiator can be used in combination with a reducing agent.
  • a reducing agent examples include sodium bisulfite, sodium metabisulfite, formaldehyde sulfooxylate, ferrous chloride, ascorbic acid, erythorbic acid, and salts thereof.
  • surfactant examples include nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polycyclic phenyl ether, polyoxyethylene-polyoxypropylene block copolymer, sorbitan fatty acid ester and the like.
  • Agent Higher alcohol sulfate ester, alkylbenzene sulfonate, alkyl diphenyl ether disulfonate, polyoxyethylene alkylphenyl ether sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene polycyclic phenyl ether sulfate, Polyoxyethylene alkyl sulfonate, alkyl ether phosphate, alkenyl sulfosuccinate, dialkyl sulfosuccinate, monoalkyl sulfoco Anionic surfactants such as succinates; Cationic surfactants such as tertiary amine carboxylates and quaternary ammonium salts such as N, N-dimethyllaurylamine and N, N-dimethyloctadecylamine Agent: Compound having both anionic group and double bond such as carboxylate group, sulfate group, sulfonate group, phosphate group
  • surfactants can be used alone or in combination of two or more. Moreover, it is preferable to use the said surfactant in 15 mass% or less with respect to the sum total of the monomer used as the raw material of the said polymer (A), and the range of 10 mass% or less is more preferable.
  • the basic compound (B) is used as a neutralizing agent for the carboxyl group of the polymer (A), but for imparting excellent substrate adhesion to the obtained flocked product, metal hydroxide is used. It is important to contain the product (b1). Furthermore, since the balance between the substrate adhesion and the flocking strength is further improved, the content of the metal hydroxide (b1) is 10 to 80 mol% of the carboxyl group of the polymer (A). The amount to be summed is preferred, the amount to neutralize 30 to 70 mol% is more preferred, and the amount to neutralize 40 to 60 mol% is more preferred.
  • metal hydroxide (b1) examples include sodium hydroxide and potassium hydroxide, and sodium hydroxide is preferable because the adhesion to the substrate is further improved. These metal hydroxides (b1) can be used alone or in combination of two or more.
  • other basic compounds (b2) other than the metal hydroxide (b1) can be used in combination.
  • the other basic compounds (b2) for example, monomethyl Alkylamines such as amine, dimethylamine, trimethylamine, monoethylamine, diethylamine, triethylamine, monopropylamine, dipropylamine, tripropylamine; monoethanolamine, diethanolamine, monoisopropanolamine, diisopropanolamine, N-methylethanolamine, Alkanol alcohols such as N, N-dimethylethanolamine, N, N-diethylethanolamine, 2-amino-2-methylpropanol, 2- (dimethylamino) -2-methylpropanol, N-methyldiethanolamine Down ethylenediamine, diethylenetriamine, triethylenetetramine, organic amine or ammonia (water), such as a polyvalent amine such as tetraethylene pentamine and the like.
  • These neutralizing agents (b2) for example, mono
  • the acrylic resin (C) is obtained by neutralizing the polymer (A) having the carboxyl group with a basic compound (B).
  • a basic compound (B) for example, the aqueous dispersion of the polymer (A) and the polymer It can be easily obtained by mixing with the basic compound (B).
  • polyoxazoline compound (D) those easily dissolved or dispersed in an aqueous medium are preferable.
  • These polyoxazoline compounds (D) can be used alone or in combination of two or more.
  • Examples of the aqueous medium (E) include water, organic solvents miscible with water, and mixtures thereof.
  • the organic solvent miscible with water include alcohols such as methanol, ethanol, n-propanol and isopropanol; ketones such as acetone and methyl ethyl ketone; polyalkylene glycols such as ethylene glycol, diethylene glycol and propylene glycol; alkyl ethers of polyalkylene glycols And lactams such as N-methyl-2-pyrrolidone.
  • only water may be used, a mixture of water and an organic solvent miscible with water may be used, or only an organic solvent miscible with water may be used. From the viewpoint of safety and load on the environment, water alone or a mixture of water and an organic solvent miscible with water is preferable, and it is particularly preferable to use only water.
  • the aqueous resin composition for flocking processing of the present invention contains the acrylic resin (C), the polyoxazoline compound (D), and the aqueous medium (E).
  • the acrylic resin It can be easily obtained by mixing an aqueous dispersion of C) and the polyoxazoline compound (D).
  • the amount of the polyoxazoline compound (D) used is more stable over time, flocking strength and substrate adhesion, and the balance of flexibility is further improved, so that 1 mol of the carboxyl group of the acrylic resin (C),
  • the oxazoline group of the polyoxazoline compound (D) is preferably in the range of 0.1 to 5 mol, more preferably in the range of 0.3 to 2 mol.
  • the water-based resin composition for hair transplantation processing of this invention is other than the said acrylic resin (C), the said polyoxazoline compound (D), and the said aqueous medium (E). It is preferable to contain an acrylic thickener (F) as a component.
  • the acrylic thickener (F) preferably has an acid value in the range of 150 to 500 mgKOH / g and more preferably in the range of 200 to 400 mgKOH / g because workability, flocking strength and substrate adhesion are further improved. Are more preferred.
  • the aqueous resin composition for flocking processing of the present invention includes other thickeners, pigments, fillers, flame retardants, leveling agents, dispersants, wetting agents, antifoaming agents, and anti-aging components other than those described above.
  • Additives such as additives, ultraviolet absorbers and preservatives can also be mixed.
  • the base material to which the aqueous resin composition for flocking treatment of the present invention is applied is not particularly limited, but a vinyl chloride base material is preferable because adhesion is further improved.
  • a flocked product having a coating film of the aqueous resin composition for flocking processing of the present invention is excellent in flocking strength and substrate adhesion, and thus, for example, gloves, packaging materials, clothing items, shoes, air conditioners, kotatsu, etc. It is suitably used for air conditioning equipment parts, electrical equipment parts such as cameras, automobile interior materials, tile carpets and the like.
  • the aqueous dispersion of the acrylic resin (C-1) having a nonvolatile content of 50.0% was neutralized with 18.0 parts by mass of a 10% by mass aqueous sodium hydroxide solution and 1.5 parts by mass of 25% by mass ammonia water.
  • Sodium hydroxide in the basic compound used as a neutralizing agent was 67% by mass.
  • the content of sodium hydroxide was an amount that neutralized 47 mol% of the carboxyl group of the polymer.
  • Synthesis Example 2 Synthesis of acrylic resin (RC-1)) Synthesis Example 1 except that 18.0 parts by mass of the 10% by mass aqueous sodium hydroxide solution used in Synthesis Example 1 and 1.5 parts by mass of 25% by mass ammonia water were changed to 3.0 parts by mass of 25% by mass ammonia water. Similarly, an aqueous dispersion of acrylic resin (RC-1) having a nonvolatile content of 50.0% was obtained. The basic compound used as a neutralizing agent did not contain a metal hydroxide.
  • Example 1 Preparation and evaluation of aqueous resin composition (1) for flocking
  • a container equipped with a stirrer was charged with 100 parts by mass of the aqueous dispersion of the acrylic resin (C-1) obtained in Synthesis Example 1 and 40.0 parts by mass of ion-exchanged water, and stirred until uniform.
  • 2.5 parts by mass of acrylic thickener (F-1) was added, and the pH was adjusted to 8.0 with 25% by mass aqueous ammonia.
  • aqueous resin composition was filtered through a 200 mesh wire net to obtain an aqueous resin composition (1) for flocking.
  • aqueous resin composition (R2) for flocking An aqueous resin composition (R2) for flocking was obtained in the same manner as in Example 1, except that the acrylic resin (C-1) used in Example 1 was changed to an acrylic resin (RC-1).
  • the aqueous resin composition for flocking processing obtained above was applied on a vinyl chloride substrate so as to have a film thickness of 100 ⁇ m, and an electrostatic flocking machine (“Small and High Voltage Power Supply GT80N” manufactured by Green Techno Co., Ltd.) Using an electric flocking experiment apparatus), flocking was performed. Then, it dried at 160 degreeC for 10 minute (s), and the flocked product was obtained.
  • the aqueous resin composition for flocking processing obtained above was applied on a vinyl chloride substrate so as to have a film thickness of 100 ⁇ m and dried at 160 ° C. for 10 minutes to obtain a test piece for evaluating substrate adhesion.
  • a check terminal was affixed on the test piece using an adhesive (“Aron Alpha” manufactured by Toa Gosei Co., Ltd.). After the adhesive was solidified, a tensile test was performed in the 180 ° direction using an autograph (“AG-X plus 1 kN” manufactured by Shimadzu Corporation) to measure the peel strength.
  • Table 1 shows the evaluation of the aqueous resin composition for flocking processing obtained in the above Examples and Comparative Examples.
  • Example 1 of the present invention obtained a flocked product having excellent temporal stability and excellent flocking strength and substrate adhesion.
  • Comparative Example 1 was an example in which no cross-linking agent was used, but it was confirmed that the flocking strength of the flocked product was inferior.
  • Comparative Example 2 is an example in which a metal hydroxide was not used as a basic compound, but it was confirmed that the flocking strength and substrate adhesion of the flocked product were inferior.
  • Comparative Example 3 was an example using a polycarbodiimide compound instead of the polyoxazoline compound, but it was confirmed that the stability over time was inferior.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Polarising Elements (AREA)
  • Formation And Processing Of Food Products (AREA)

Abstract

L'invention fournit une composition de résine aqueuse pour flocage qui est caractéristique en ce qu'elle comprend : une résine acrylique (C) dans laquelle un polymère (A) possédant un groupe carboxyle est neutralisé au moyen d'un composé basique (B) ayant un hydroxyde métallique pour composant indispensable ; un composé polyoxazoline (D) ; et un milieu aqueux (E). Cette composition de résine aqueuse pour flocage présente une excellente stabilité au cours du temps, et permet d'obtenir un article floqué doté d'excellentes propriétés de résistance de flocage ainsi que d'adhérence à un matériau de base, permettant ainsi une mise en œuvre de manière adéquate dans divers articles floqués.
PCT/JP2018/007723 2017-03-17 2018-03-01 Composition de résine aqueuse pour flocage, et article floqué WO2018168487A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201880015653.3A CN110382617B (zh) 2017-03-17 2018-03-01 植绒加工用水性树脂组合物和植绒加工品
JP2018560689A JP6485724B2 (ja) 2017-03-17 2018-03-01 植毛加工用水性樹脂組成物及び植毛加工品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017052756 2017-03-17
JP2017-052756 2017-03-17

Publications (1)

Publication Number Publication Date
WO2018168487A1 true WO2018168487A1 (fr) 2018-09-20

Family

ID=63522126

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/007723 WO2018168487A1 (fr) 2017-03-17 2018-03-01 Composition de résine aqueuse pour flocage, et article floqué

Country Status (4)

Country Link
JP (1) JP6485724B2 (fr)
CN (1) CN110382617B (fr)
TW (1) TWI768004B (fr)
WO (1) WO2018168487A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01292179A (ja) * 1988-05-16 1989-11-24 Nippon Shokubai Kagaku Kogyo Co Ltd 有機繊維用繊維加工用樹脂
JPH10251474A (ja) * 1997-03-07 1998-09-22 Nippon Carbide Ind Co Inc アクリル系樹脂水性組成物
JP2002302876A (ja) * 2001-04-06 2002-10-18 Nippon Carbide Ind Co Inc 繊維加工用水分散性樹脂組成物
JP2003096148A (ja) * 2001-09-27 2003-04-03 Dainippon Ink & Chem Inc 重合体水性分散液およびその製造方法
JP2011526953A (ja) * 2008-06-30 2011-10-20 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー アイオノマー、およびポリアミンまたは第３級ポリアミドを含有するゴルフボール
WO2015186733A1 (fr) * 2014-06-03 2015-12-10 ユニチカ株式会社 Dispersion aqueuse, et stratifié

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3875760B2 (ja) * 1997-03-10 2007-01-31 株式会社クラレ 塩素化芳香族化合物の製造方法
US20090143524A1 (en) * 2005-09-29 2009-06-04 Yoshifumi Nakayama Fiber-Reinforced Thermoplastic Resin Composition, Method for Producing the Same, and Carbon Fiber for Thermoplastic Resin
JP5123539B2 (ja) * 2007-03-06 2013-01-23 大日精化工業株式会社 共重合体およびその使用
EP2591010B1 (fr) * 2010-07-09 2014-12-03 Lubrizol Advanced Materials, Inc. Mélanges d'épaississants de type copolymères acryliques
IN2014MN01422A (fr) * 2011-12-16 2015-07-03 Mitsui Chemicals Tohcello Inc
CN102827518A (zh) * 2012-06-01 2012-12-19 安徽省金盾涂料有限责任公司 一种水性涂料组合物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01292179A (ja) * 1988-05-16 1989-11-24 Nippon Shokubai Kagaku Kogyo Co Ltd 有機繊維用繊維加工用樹脂
JPH10251474A (ja) * 1997-03-07 1998-09-22 Nippon Carbide Ind Co Inc アクリル系樹脂水性組成物
JP2002302876A (ja) * 2001-04-06 2002-10-18 Nippon Carbide Ind Co Inc 繊維加工用水分散性樹脂組成物
JP2003096148A (ja) * 2001-09-27 2003-04-03 Dainippon Ink & Chem Inc 重合体水性分散液およびその製造方法
JP2011526953A (ja) * 2008-06-30 2011-10-20 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー アイオノマー、およびポリアミンまたは第３級ポリアミドを含有するゴルフボール
WO2015186733A1 (fr) * 2014-06-03 2015-12-10 ユニチカ株式会社 Dispersion aqueuse, et stratifié

Also Published As

Publication number Publication date
TWI768004B (zh) 2022-06-21
CN110382617A (zh) 2019-10-25
JPWO2018168487A1 (ja) 2019-03-28
TW201842100A (zh) 2018-12-01
CN110382617B (zh) 2021-08-17
JP6485724B2 (ja) 2019-03-20

Similar Documents

Publication Publication Date Title
EP2514790B1 (fr) Dispersion de copolymère pour revêtements résistants au blanchiment par l'eau
KR20180015155A (ko) 친수화 처리제, 친수 피막 형성방법 및 친수 피막
JP6950182B2 (ja) 水性樹脂分散体
JP5451025B2 (ja) 建設機械用又は産業機械用の１液型水性塗料組成物
KR20190101394A (ko) 수성 중합체 조성물
JP6485724B2 (ja) 植毛加工用水性樹脂組成物及び植毛加工品
US11384188B2 (en) Aqueous resin dispersion
JPWO2019112039A1 (ja) 水性樹脂分散体、水性樹脂分散体の製造方法、水性塗料、接着剤
CN109312010B (zh) 水性树脂分散体的制造方法
JP2007297491A (ja) 硬化型水性樹脂組成物
JPWO2020085260A1 (ja) 水性樹脂組成物、その製造方法およびその利用
JP5569905B2 (ja) 不燃性塗料、不燃性塗膜の形成方法及び不燃性塗膜
JP2015218232A (ja) 水性塗料組成物用合成樹脂エマルション
JP6094115B2 (ja) 水性粘着剤及び粘着シート
JP4644576B2 (ja) アルカリ脱膜型水系接着剤
JP6866628B2 (ja) 発泡体用水性樹脂組成物及び発泡体
JP2011089014A (ja) プラスチック塗料用樹脂組成物、水性重合体の製造方法、及びプラスチック塗料
GB2413330A (en) Vinyl graft polymer composition
WO2024065575A1 (fr) Composition antimicrobienne aqueuse
JP2013170211A (ja) 重合体エマルションの製造方法
JP2005008661A (ja) 塗料用水性プライマー組成物
JP2006219551A (ja) 接着剤用水性樹脂組成物
JP2014122270A (ja) アクリル系水性樹脂エマルション組成物

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2018560689

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18766770

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18766770

Country of ref document: EP

Kind code of ref document: A1