WO2018119625A1 - 强力胶黏剂及其制备方法 - Google Patents

强力胶黏剂及其制备方法 Download PDF

Info

Publication number
WO2018119625A1
WO2018119625A1 PCT/CN2016/112282 CN2016112282W WO2018119625A1 WO 2018119625 A1 WO2018119625 A1 WO 2018119625A1 CN 2016112282 W CN2016112282 W CN 2016112282W WO 2018119625 A1 WO2018119625 A1 WO 2018119625A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
mixture
hydroquinone
tetrahydrofuran
styrene
Prior art date
Application number
PCT/CN2016/112282
Other languages
English (en)
French (fr)
Inventor
王丽萍
Original Assignee
王丽萍
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 王丽萍 filed Critical 王丽萍
Priority to PCT/CN2016/112282 priority Critical patent/WO2018119625A1/zh
Publication of WO2018119625A1 publication Critical patent/WO2018119625A1/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16

Definitions

  • the present invention relates to a strong adhesive and a preparation method thereof, and belongs to the field of industrial glue.
  • Adhesives are substances that can be bonded together by adhesion. Adhesives are widely used in industrial applications, but for some non-sticky materials, the existing adhesives do not meet the requirements for adhesion, and the adhesion is insufficient, resulting in a service life. Short, poorly bonded. There is a growing demand for strong adhesives. Therefore, strong adhesives are becoming more and more popular.
  • the technical problem to be solved by the present invention is to provide a strong adhesive and a preparation method thereof, which have stable performance, strong adhesion, and can perform well for materials with different materials. Ground bonding.
  • Optimized, strong adhesive made from the following parts by weight: 3.6 parts of ethylene glycol, 5.6 parts of styrene, 2.5 parts of tetrahydrofuran, 5.6 parts of butyl acrylate, 4.1 parts of methyltrimethoxysilane 3.4 parts of 2-mercaptobenzimidazole zinc salt, 2.6 parts of hydroquinone, 6.5 parts of polyvinyl alcohol, 3.6 parts of sodium hydroxide, and 1.5 parts of polyglyceryl monostearate.
  • Optimized, strong adhesive made from the following parts by weight: 4.5 parts of ethylene glycol, 6.3 parts of styrene, 3.7 parts of tetrahydrofuran, 7.1 parts of butyl acrylate, 5.2 parts of methyltrimethoxysilane , 5.7 parts of 2-mercaptobenzimidazole zinc salt, 3.5 parts of hydroquinone, 7.2 parts of polyvinyl alcohol, 5.5 parts of sodium hydroxide, polyglycerol mono-hard fat 2.1 parts of acid ester.
  • Optimized, strong adhesive made from the following parts by weight: 5.8 parts of ethylene glycol, 7.4 parts of styrene, 4.6 parts of tetrahydrofuran, 8.3 parts of butyl acrylate, 6.3 parts of methyltrimethoxysilane 7.2 parts of 2-nonylbenzimidazole zinc salt, 4.8 parts of hydroquinone, 8.3 parts of polyvinyl alcohol, 7.4 parts of sodium hydroxide, and 2.8 parts of polyglyceryl monostearate.
  • a method for preparing a strong adhesive comprising the following steps: (1) mixing the above materials, stirring at a stirring speed of 1000 rpm for 5 minutes, and then observing the uniformity of the above substances, if the stirring is uniform, stopping Stir, otherwise continue to stir until the materials are uniformly mixed; (2) Heat the mixture after stirring, heat to 55-65 degrees, then maintain the above temperature for 25-30 minutes to fully react the mixture; (3) Mix the reaction After the material is cooled and dried, the temperature is room temperature, and the temperature is 30-40 minutes. The state of the mixture is observed. If the viscous liquid appears at the bottom, the mixture is mixed successfully, otherwise the above steps are continued from (2). (4) After the reaction mixture is allowed to stand, it is packaged and weighed.
  • the present invention is a strong adhesive which has stable properties and strong cohesiveness and can bond well to materials having different materials.
  • the superabsorbent of the present invention is made from the following parts by weight of raw materials:
  • the superabsorbent of the present invention is prepared from the following parts by weight of raw materials: 4.5 parts of ethylene glycol, 6.3 parts of styrene, 3.7 parts of tetrahydrofuran, 7.1 parts of butyl acrylate, and 5.2 parts of methyltrimethoxysilane. , 5.7 parts of 2-mercaptobenzimidazole zinc salt, 3.5 parts of hydroquinone, 7.2 parts of polyvinyl alcohol, 5.5 parts of sodium hydroxide,
  • a method for preparing a strong adhesive comprises the following steps: (1) mixing the above materials, stirring at a stirring speed of 1000 rpm for 5 minutes, and then observing the uniformity of the above substances, if the stirring is uniform, stopping Stir, otherwise continue to stir until the materials are uniformly mixed; (2) Heat the stirred mixture to 60 degrees, then maintain the above temperature for 27 minutes to fully react the mixture; (3) Mix the reacted materials Cool and dry, the temperature is room temperature, and the time is 35 minutes. The state of the mixture is observed. If the viscous liquid appears at the bottom, the mixture is mixed successfully. Otherwise, the above steps are continued from (2). (4) After the reaction mixture is allowed to stand, it is packaged and weighed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

一种强力胶黏剂,由以下重量份数的原料制成:乙二醇3.6-5.8份,苯乙烯5.6-7.4份,四氢呋喃2.5-4.6份,丙烯酸丁酯5.6-8.3份,甲基三甲氧基硅烷4.1-6.3份,2-巯基苯并咪唑锌盐3.4-7.2份,对苯二酚2.6-4.8份,聚乙烯醇6.5-8.3份,氢氧化钠3.6-7.4份,聚甘油单硬脂酸酯1.5-2.8份。

Description

强力胶黏剂及其制备方法 技术领域
[0001] 本发明涉及一种强力胶黏剂及其制备方法, 属于工业胶水领域。
背景技术
[0002] 胶黏剂就是通过黏合作用, 能使被黏物结合在一起的物质。 胶黏剂在工业应用 中的范围非常广泛, 但对于一些不易黏粘的物质, 现有的胶黏剂对于其粘附程 度并不能够很好地满足要求, 粘结性不够, 进而造成使用寿命短, 粘结不牢固 的情况。 人们对于强力胶黏剂的需求也越来越旺盛。 因此, 强力胶黏剂越来越 受到欢迎。
技术问题
[0003] 针对现有技术存在的不足, 本发明所要解决的技术问题是, 提供一种强力胶黏 剂及其制备方法, 性能稳定、 粘结性强, 能够对于材料不同的物质起到很好地 粘结作用。
问题的解决方案
技术解决方案
[0004] 为解决上述技术问题, 本发明采取的技术方案是, 乙二醇 3.6-5.8份, 苯乙烯 5.6 -7.4份, 四氢呋喃 2.5-4.6份, 丙烯酸丁酯 5.6-8.3份, 甲基三甲氧基硅烷 4.1-6.3份 , 2-巯基苯并咪唑锌盐 3.4-7.2份, 对苯二酚 2.6-4.8份, 聚乙烯醇 6.5-8.3份, 氢氧 化钠 3.6-7.4份, 聚甘油单硬脂酸酯 1.5-2.8份。
[0005] 优化的, 强力胶黏剂, 由以下重量份数的原料制成: 乙二醇 3.6份, 苯乙烯 5.6 份, 四氢呋喃 2.5份, 丙烯酸丁酯 5.6份, 甲基三甲氧基硅烷 4.1份, 2-巯基苯并咪 唑锌盐 3.4份, 对苯二酚 2.6份, 聚乙烯醇 6.5份, 氢氧化钠 3.6份, 聚甘油单硬脂 酸酯 1.5份。
[0006] 优化的, 强力胶黏剂, 由以下重量份数的原料制成: 乙二醇 4.5份, 苯乙烯 6.3 份, 四氢呋喃 3.7份, 丙烯酸丁酯 7.1份, 甲基三甲氧基硅烷 5.2份, 2-巯基苯并咪 唑锌盐 5.7份, 对苯二酚 3.5份, 聚乙烯醇 7.2份, 氢氧化钠 5.5份, 聚甘油单硬脂 酸酯 2.1份。
[0007] 优化的, 强力胶黏剂, 由以下重量份数的原料制成: 乙二醇 5.8份, 苯乙烯 7.4 份, 四氢呋喃 4.6份, 丙烯酸丁酯 8.3份, 甲基三甲氧基硅烷 6.3份, 2-巯基苯并咪 唑锌盐 7.2份, 对苯二酚 4.8份, 聚乙烯醇 8.3份, 氢氧化钠 7.4份, 聚甘油单硬脂 酸酯 2.8份。
[0008] 一种强力胶黏剂的制备方法, 包括以下步骤: (1)将上述物质混合, 以 1000转 / 分钟的搅拌速度搅拌 5分钟, 然后观察上述物质的均匀程度, 若搅拌均匀, 停止 搅拌, 否则继续搅拌, 直至各物质均匀混合; (2)将搅拌后的混合物进行加热, 加热至 55-65度, 然后保持上述温度 25-30分钟, 使混合物充分反应; (3)将混合 反应后的物料进行冷却干燥, 温度为室温, 吋间为 30-40分钟, 此吋观察混合物 的状态, 如底部出现粘稠状液体, 则混合物混合成功, 否则从 (2)继续幵始上述 步骤。 (4)将反应完成后的混合物静置后, 包装、 称量。
发明的有益效果
有益效果
[0009] 本发明一种强力胶黏剂, 性能稳定、 粘结性强, 能够对于材料不同的物质起到 很好地粘结作用。
本发明的实施方式
[0010] 实施例 1
[0011] 本发明的强力胶黏剂, 其由以下重量份数的原料制成:
乙二醇 3.6份, 苯乙烯 5.6份, 四氢呋喃 2.5份, 丙烯酸丁酯 5.6份, 甲基三甲氧基 硅烷 4.1份, 2-巯基苯并咪唑锌盐 3.4份, 对苯二酚 2.6份, 聚乙烯醇 6.5份, 氢氧化 钠 3.6份, 聚甘油单硬脂酸酯 1.5份。
[0012] 一种强力胶黏剂的制备方法, 包括以下步骤: (1)将上述物质混合, 以 1000转 / 分钟的搅拌速度搅拌 5分钟, 然后观察上述物质的均匀程度, 若搅拌均匀, 停止 搅拌, 否则继续搅拌, 直至各物质均匀混合; (2)将搅拌后的混合物进行加热, 加热至 55度, 然后保持上述温度 25分钟, 使混合物充分反应; (3)将混合反应后 的物料进行冷却干燥, 温度为室温, 吋间为 30分钟, 此吋观察混合物的状态, 如底部出现粘稠状液体, 则混合物混合成功, 否则从 (2)继续幵始上述步骤。 (4) 将反应完成后的混合物静置后, 包装、 称量。
[0013] 实施例 2
[0014] 本发明的强力胶黏剂, 由以下重量份数的原料制成: 乙二醇 4.5份, 苯乙烯 6.3 份, 四氢呋喃 3.7份, 丙烯酸丁酯 7.1份, 甲基三甲氧基硅烷 5.2份, 2-巯基苯并咪 唑锌盐 5.7份, 对苯二酚 3.5份, 聚乙烯醇 7.2份, 氢氧化钠 5.5份,
[0015] 聚甘油单硬脂酸酯 2.1份。
[0016] 一种强力胶黏剂的制备方法, 包括以下步骤: (1)将上述物质混合, 以 1000转 / 分钟的搅拌速度搅拌 5分钟, 然后观察上述物质的均匀程度, 若搅拌均匀, 停止 搅拌, 否则继续搅拌, 直至各物质均匀混合; (2)将搅拌后的混合物进行加热, 加热至 60度, 然后保持上述温度 27分钟, 使混合物充分反应; (3)将混合反应后 的物料进行冷却干燥, 温度为室温, 吋间为 35分钟, 此吋观察混合物的状态, 如底部出现粘稠状液体, 则混合物混合成功, 否则从 (2)继续幵始上述步骤。 (4) 将反应完成后的混合物静置后, 包装、 称量。
[0017] 实施例 3
[0018] 本发明的强力胶黏剂, 由以下重量份数的原料制成: 乙二醇 5.8份, 苯乙烯 7.4 份, 四氢呋喃 4.6份, 丙烯酸丁酯 8.3份, 甲基三甲氧基硅烷 6.3份, 2-巯基苯并咪 唑锌盐 7.2份, 对苯二酚 4.8份, 聚乙烯醇 8.3份, 氢氧化钠 7.4份, 聚甘油单硬脂 酸酯 2.8份。
[0019] 一种强力胶黏剂的制备方法, 包括以下步骤: (1)将上述物质混合, 以 1000转 / 分钟的搅拌速度搅拌 5分钟, 然后观察上述物质的均匀程度, 若搅拌均匀, 停止 搅拌, 否则继续搅拌, 直至各物质均匀混合; (2)将搅拌后的混合物进行加热, 加热至 65度, 然后保持上述温度 30分钟, 使混合物充分反应; (3)将混合反应后 的物料进行冷却干燥, 温度为室温, 吋间为 40分钟, 此吋观察混合物的状态, 如底部出现粘稠状液体, 则混合物混合成功, 否则从 (2)继续幵始上述步骤。 (4) 将反应完成后的混合物静置, 后包装, 称量。
[0020] 对所公幵的实施例的上述说明, 使本领域专业技术人员能够实现或使用本发明 。 对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的, 本 文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下, 在其它实 施例中实现。 因此, 本发明将不会被限制于本文所示的这些实施例, 而是要符 合与本文所公幵的原理和新颖特点相一致的最宽的范围。

Claims

权利要求书
[权利要求 1] 一种强力胶黏剂, 其特征在于: 由以下重量份数的原料制成: 乙二醇
3.6-5.8份, 苯乙烯 5.6-7.4份, 四氢呋喃 2.5-4.6份, 丙烯酸丁酯 5.6-8.3 份, 甲基三甲氧基硅烷 4.1-6.3份, 2-巯基苯并咪唑锌盐 3.4-7.2份, 对 苯二酚 2.6-4.8份, 聚乙烯醇 6.5-8.3份, 氢氧化钠 3.6-7.4份, 聚甘油单 硬脂酸酯 1.5-2.8份。
[权利要求 2] 根据权利要求 1所述的强力胶黏剂, 其特征在于: 由以下重量份数的 原料制成: 乙二醇 3.6份, 苯乙烯 5.6份, 四氢呋喃 2.5份, 丙烯酸丁酯 5.6份, 甲基三甲氧基硅烷 4.1份, 2-巯基苯并咪唑锌盐 3.4份, 对苯二 酚 2.6份, 聚乙烯醇 6.5份, 氢氧化钠 3.6份, 聚甘油单硬脂酸酯 1.5份。
[权利要求 3] 根据权利要求 1所述的强力胶黏剂, 其特征在于: 由以下重量份数的 原料制成: 乙二醇 4.5份, 苯乙烯 6.3份, 四氢呋喃 3.7份, 丙烯酸丁酯 7.1份, 甲基三甲氧基硅烷 5.2份, 2-巯基苯并咪唑锌盐 5.7份, 对苯二 酚 3.5份, 聚乙烯醇 7.2份, 氢氧化钠 5.5份, 聚甘油单硬脂酸酯 2.1份。
[权利要求 4] 根据权利要求 1所述的强力胶黏剂, 其特征在于: 由以下重量份数的 原料制成: 乙二醇 5.8份, 苯乙烯 7.4份, 四氢呋喃 4.6份, 丙烯酸丁酯 8.3份, 甲基三甲氧基硅烷 6.3份, 2-巯基苯并咪唑锌盐 7.2份, 对苯二 酚 4.8份, 聚乙烯醇 8.3份, 氢氧化钠 7.4份, 聚甘油单硬脂酸酯 2.8份。
[权利要求 5] 根据权利要求 1-4任意一项所述的强力胶黏剂制备方法, 包括以下步 骤: (1)将上述物质混合, 以 1000转 /分钟的搅拌速度搅拌 5分钟, 然 后观察上述物质的均匀程度, 若搅拌均匀, 停止搅拌, 否则继续搅拌 , 直至各物质均匀混合; (2)
将搅拌后的混合物进行加热, 加热至 55-65度, 然后保持上述温度 25- 30分钟, 使混合物充分反应; (3)将混合反应后的物料进行冷却干燥 , 温度为室温, 吋间为 30-40分钟, 此吋观察混合物的状态, 如底部 出现粘稠状液体, 则混合物混合成功, 否则从 (2)继续幵始上述步骤 。 (4)将反应完成后的混合物静置后, 包装、 称量。
PCT/CN2016/112282 2016-12-27 2016-12-27 强力胶黏剂及其制备方法 WO2018119625A1 (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2016/112282 WO2018119625A1 (zh) 2016-12-27 2016-12-27 强力胶黏剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2016/112282 WO2018119625A1 (zh) 2016-12-27 2016-12-27 强力胶黏剂及其制备方法

Publications (1)

Publication Number Publication Date
WO2018119625A1 true WO2018119625A1 (zh) 2018-07-05

Family

ID=62706620

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2016/112282 WO2018119625A1 (zh) 2016-12-27 2016-12-27 强力胶黏剂及其制备方法

Country Status (1)

Country Link
WO (1) WO2018119625A1 (zh)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7550281A (en) * 1980-09-26 1982-04-01 Asahi-Dow Ltd. Pressure sensitive adhesive of latex copolymers
JPH05279648A (ja) * 1992-04-02 1993-10-26 Kuraray Co Ltd 組成物,接着剤および水性エマルジョン
CN1978575A (zh) * 2005-11-30 2007-06-13 东莞奥美医疗用品有限公司 一种水性粘合剂
JP4089959B2 (ja) * 2002-12-27 2008-05-28 コニシ株式会社 水性接着剤組成物
CN102585735A (zh) * 2011-01-06 2012-07-18 汉中旭泰科技有限公司 新型环保建筑用胶粘剂
CN104327753A (zh) * 2014-11-05 2015-02-04 吴俊荣 水基胶黏剂
CN104327750A (zh) * 2014-10-20 2015-02-04 常熟市鑫磊木业制造厂 单组份拼板胶

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7550281A (en) * 1980-09-26 1982-04-01 Asahi-Dow Ltd. Pressure sensitive adhesive of latex copolymers
JPH05279648A (ja) * 1992-04-02 1993-10-26 Kuraray Co Ltd 組成物,接着剤および水性エマルジョン
JP4089959B2 (ja) * 2002-12-27 2008-05-28 コニシ株式会社 水性接着剤組成物
CN1978575A (zh) * 2005-11-30 2007-06-13 东莞奥美医疗用品有限公司 一种水性粘合剂
CN102585735A (zh) * 2011-01-06 2012-07-18 汉中旭泰科技有限公司 新型环保建筑用胶粘剂
CN104327750A (zh) * 2014-10-20 2015-02-04 常熟市鑫磊木业制造厂 单组份拼板胶
CN104327753A (zh) * 2014-11-05 2015-02-04 吴俊荣 水基胶黏剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
XU, QING ET AL.: "Structure and Property of Silicone Acrylic Emulsion with Core-shell Structure", CHINA SYNTHETIC RUBBER INDUSTRY, 15 September 2009 (2009-09-15), pages 377, ISSN: 1000-1255 *

Similar Documents

Publication Publication Date Title
CN104004477B (zh) 一种室温自交联聚丙烯酸酯压敏胶及其制备方法与应用
CN106565897B (zh) 一种具有荷叶效应的外墙弹性乳液及其制备方法
WO2021197054A1 (zh) 一种耐水白丙烯酸酯压敏胶及其制备方法
CN106749874B (zh) 一种剥离力可控的压敏胶及其制备方法
CN104371607B (zh) 高固含量低粘度丙烯酸酯乳液压敏胶粘剂及制备方法
CN1944479A (zh) 压敏胶粘剂用的聚丙烯酸酯复合乳液及其制备和应用方法
CN1966595A (zh) 可活化组合物
CN109021851B (zh) 一种亚克力保护膜及其制备方法
CN102885672A (zh) 医用压敏胶粘带或胶粘片的制造方法
CN105408437B (zh) 由多阶段乳液聚合制备用于保护膜的压敏胶粘剂分散体
CN109593483A (zh) 一种手机屏用压敏胶保护膜及其制备方法
CN109266256A (zh) 医用压敏胶粘剂及其制备方法
CN105086886A (zh) 单组分自交联型耐高温乳液压敏胶及其制备方法和应用
CN108795340A (zh) 一种大分子量且高转化率的溶剂型丙烯酸酯压敏胶、其制备方法及应用
CN103396746B (zh) 一种高性能水性压敏胶及其制备方法
CN102746463B (zh) 一种接枝型丙烯酸乳液和可再分散乳胶粉及制备方法
CN104194688B (zh) 一种多次可移水性丙烯酸酯压敏胶及其制备方法和应用
CN103724521A (zh) 用于光学保护膜的单组份聚丙烯酸酯压敏胶的制备方法
CN100467416C (zh) 可再分散聚合物粘胶粉及制备方法
WO2018119625A1 (zh) 强力胶黏剂及其制备方法
CN105838299A (zh) 一种医用水胶体压敏胶的制备方法
CN106398574B (zh) 聚丙烯酸酯压敏胶及其制备方法
CN111892679A (zh) 一种泡棉用丙烯酸酯压敏胶及其制备工艺、应用
CN107236490A (zh) 一种耐高温压敏胶的制备方法
CN106833452A (zh) 水性环保型高粘结力封口胶及其制备方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16925945

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16925945

Country of ref document: EP

Kind code of ref document: A1