WO2017186929A1 - Zusammensetzung zur verminderung des beizabtrags beim beizen von metallischen oberflächen enthaltend blanken und/oder verzinkten stahl - Google Patents

Zusammensetzung zur verminderung des beizabtrags beim beizen von metallischen oberflächen enthaltend blanken und/oder verzinkten stahl Download PDF

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Publication number
WO2017186929A1
WO2017186929A1 PCT/EP2017/060227 EP2017060227W WO2017186929A1 WO 2017186929 A1 WO2017186929 A1 WO 2017186929A1 EP 2017060227 W EP2017060227 W EP 2017060227W WO 2017186929 A1 WO2017186929 A1 WO 2017186929A1
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WO
WIPO (PCT)
Prior art keywords
pickling
composition
formula
range
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2017/060227
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German (de)
English (en)
French (fr)
Inventor
Anna Verena MOHR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemetall GmbH
Original Assignee
Chemetall GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES17721118T priority Critical patent/ES2795655T3/es
Priority to JP2018556914A priority patent/JP6968825B2/ja
Priority to EP17721118.2A priority patent/EP3449040B1/de
Priority to PL17721118T priority patent/PL3449040T3/pl
Priority to BR112018071497-6A priority patent/BR112018071497B1/pt
Priority to KR1020187030705A priority patent/KR102369545B1/ko
Priority to RU2018140856A priority patent/RU2747720C2/ru
Priority to MX2018013233A priority patent/MX385665B/es
Application filed by Chemetall GmbH filed Critical Chemetall GmbH
Priority to CN201780024275.0A priority patent/CN109072454B/zh
Priority to US16/097,134 priority patent/US11124884B2/en
Publication of WO2017186929A1 publication Critical patent/WO2017186929A1/de
Anticipated expiration legal-status Critical
Priority to ZA2018/07922A priority patent/ZA201807922B/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00—Etching metallic material by chemical means
    • C23F1/10—Etching compositions
    • C23F1/14—Aqueous compositions
    • C23F1/16—Acidic compositions
    • C23F1/28—Acidic compositions for etching iron group metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/068—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors compounds containing a C=C bond
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08—Iron or steel
    • C23G1/081—Iron or steel solutions containing H2SO4
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/19—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
    • C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors

Definitions

  • the invention relates to an aqueous composition for reducing pickling during pickling of metallic surfaces containing bare and / or galvanized steel and to a process for pickling a corresponding metallic surface with reduced pickling.
  • Atmospheric corrosion or heat treatment e.g., heat generation during forming or welding
  • pickling means the dissolution of these oxide layers in mineral acid solutions in order to achieve a metallically clean surface for further processing.
  • This essentially serves to remove oxide films of rust - FeO, Fe 2 O 3 , Fe 3 O 4 and iron oxide hydrates - or zinc oxide from the surface, which in turn increases the adhesive strength and uniformity of subsequent coatings, in particular a conversion coating on the surface.
  • the object of the invention was therefore to provide a composition for reducing pickling during pickling of metallic surfaces containing bare and / or galvanized steel and a method for pickling a corresponding metallic surface with reduced pickling removal, which or which completely with a subsequent Conversion treatment is compatible and toxicologically less harmful and less harmful to the environment.
  • the formation of the conversion coating are not adversely affected as well as a water-wettable surface are available.
  • the service life of a corresponding pickling bath should preferably be increased by the reduced pickling removal.
  • This object is achieved by a composition according to claim 1, a concentrate according to claim 7, a method according to claim 8 and a use according to claim 15.
  • Advantageous embodiments are each described in the dependent claims.
  • the aqueous composition according to the invention for reducing pickling during pickling of metallic surfaces containing bare and / or galvanized steel contains a mixture of a compound of the formula I.
  • an "aqueous composition” is to be understood to mean one which contains water, for the most part, ie more than 50% by weight, as the solvent / dispersant,
  • the aqueous composition is a solution, more preferably about a solution containing only water as a solvent.
  • the "galvanized steel” may in the present case be both electrolytically galvanized and hot-dip galvanized steel.
  • Compounds of Formula I act as physical corrosion inhibitors adsorbed to the metallic surface by van der Waals forces, forming a monomolecular, homogeneous, densely packed layer thereon. By means of said layer, the metallic surface is physically at least partially shielded from a proton attack and thus the pickling removal of the surface is prevented or at least reduced. It was surprisingly found that the use of certain mixtures of different compounds of the formula I, a significant synergy effect can be achieved with respect to a reduction of pickling.
  • the aqueous composition according to the invention is essentially free from ⁇ , ⁇ '-diethylthiourea, N, N'-di (o-tolyl) thiourea, ⁇ , ⁇ '-dibutylthiourea and hexamethylenetetraamine.
  • Substantially free means that the abovementioned compounds were not deliberately added to the composition, that is to say they are at most impurities in the starting materials used
  • the total content of these compounds in the composition according to the invention is preferably below 5 mg / l, more preferably below 1 mg / l.
  • The% by weight mixing ratio of the compound of formula I in which R 1 and R 2 are both H and the compound of formula I wherein R 1 and R 2 are each independently HO- (CH 2 ) W Group with w> 2 is preferably in the range of 0.5: 1 to 2: 1, more preferably in the range of 0.75: 1 to 1, 75: 1 and most preferably in the range 1: 1 to 1, 5: 1 (calculated as 2-butyne-1, 4-diol and 2-butyne-1, 4-diol-bis (2-hydroxyethyl ether)).
  • the sum of x and y is 2 to 5. More preferably, the aqueous composition contains a mixture of 2-butyne-1, 4-diol and 2-butyne-1, 4-diol bis (2-hydroxyethylether).
  • the mixing ratio based on% by weight is again preferably in the range from 0.5: 1 to 2: 1, more preferably in the range from 0.75: 1 to 1:75: 1 and most preferably in the range 1: 1 to 1, 5: 1.
  • the composition additionally contains at least one compound of formula II
  • the at least one compound of the formula II is preferably HO-CH 2 -S-CH 2 .
  • the aqueous composition according to the invention can be obtained from the concentrate according to the invention by dilution with a suitable solvent and / or dispersion medium, preferably with water, and optionally adjusting the pH.
  • the dilution factor when adding the concentrate to the pickling solution in step ii) is preferably in the range from 1:23 to 1: 225.
  • the dilution factor when adding the concentrate to the rinse solution in step iii) is preferably in the range from 1: 225 to 1: 2250.
  • the surface is formed in successive process steps i) optionally cleaned and / or rinsed,
  • iii) is brought into contact with an aqueous rinsing composition, wherein the pickling composition in step ii) and / or the rinsing composition in step iii) at least one composition according to the invention as described above.
  • the pickling composition ii) preferably contains at least one compound selected from the group consisting of phosphonates, condensed phosphates and citrate and / or at least one mineral acid selected from the group consisting of sulfuric acid, hydrochloric acid, hydrofluoric acid and nitric acid, more preferably it contains at least one mineral acid selected from the group consisting of sulfuric acid, hydrochloric acid, hydrofluoric acid and nitric acid, most preferably it contains sulfuric acid.
  • the pH of the rinsing composition in step iii) is preferably strongly acidic, neutral or slightly alkaline, more preferably in the range from 2 to 8.
  • the pickling composition in step ii) is a composition according to the invention as described above.
  • the total concentration of the mixture of the two compounds of the formula I in the mordant composition is preferably in the range from 31 to 620 mg / l, particularly preferably in the range from 31 to 310 mg / l (calculated as 2-butyne-1, 4-diol).
  • the use of the mixture of the two compounds of the formula I in the pickling composition has the advantage of particularly effectively reducing pickling.
  • the rinsing composition in step iii) is a composition according to the invention as described above.
  • the total concentration of the mixture of the two compounds of the formula I in the rinsing composition is preferably in the range from 3 to 62 mg / l, particularly preferably in the range from 3 to 31 mg / l (calculated as 2-butyne-1,4-diol).
  • the pickling composition in step ii) and the rinsing composition in step iii) are each a composition according to the invention as described above. In the mixing of the two compounds of the formula I in the pickling composition and in the rinsing composition may be the same or a different mixture.
  • the total concentration of the mixture of the two compounds of formula I in the pickling composition is again preferably in the range from 31 to 620 mg / l, more preferably in the range from 31 to 310 mg / l (calculated as 2-butyne-1, 4-diol ) and in the rinsing composition preferably in the range of 3 to 62 mg / l, more preferably in the range of 3 to 31 mg / l (calculated as 2-butyne-1, 4-diol).
  • metallic surface containing bare and / or galvanized steel to the surface of a metallic component / workpiece, such as a steel pipe, of wires or screws (general cargo).
  • the pickled with the inventive method metallic surface is therefore preferably used in the field of parts treatment.
  • the pickled and rinsed metallic surface is preferably first conversion treated.
  • For the conversion treatment is preferably a acid aqueous composition containing zinc phosphate, manganese phosphate and optionally nickel ions (so-called zinc phosphating).
  • an acidic aqueous composition which comprises a titanium, zirconium and / or hafnium compound and optionally copper ions and / or a compound which liberates copper ions, if appropriate a polymer and / or copolymer and, if appropriate, one Organoalkoxysilane and / or a hydrolysis and / or a condensation product thereof.
  • a base coat which is preferably a cathodic electrodeposition paint (KTL), more preferably a (meth) acrylate- or epoxy-based KTL, is applied, and then a top coat is applied.
  • KTL cathodic electrodeposition paint
  • a lubricant containing salts, polymers and / or soaps is applied to the pickled and rinsed metallic surface.
  • the present invention is to be illustrated by the following - not to be limited - embodiments.
  • Aqueous pickling solutions A to E were prepared, each containing 20% by weight of H 2 SO 4 , 50 g / L of Fe 2+ and optionally one or two pickling inhibitors.
  • Test panels of CRS cold rolled steel were each weighed before treatment with one of the pickling solutions.
  • pickling inhibitors of pickling solutions B and C thus each had an excellent inhibition of 96%.
  • the inhibition values of the individual inhibitors but-2-yn-1,4-diol (pickling solution D) and 2-butyne-1,4-diol bis (2-hydroxyethyl ether) (pickling solution E) remained significant at 85% and 92%, respectively behind it.
  • the inhibition value of the mixture according to the invention of the latter two pickling inhibitors was surprisingly high at 97% and even exceeded that of the abovementioned pickling inhibitors to be avoided.
  • the sheets were subsequently zinc-phosphated.
  • the pickling solutions B and F were added to the phosphating bath in increasing amounts.
  • the appearance of the metal sheets was evaluated.
  • the layer weights in g / m 2 calculated from P2O 5 were determined by means of RFA.
  • the mixture according to the invention not only reduces the pickling rate, but also leads to no disruption of film formation in a subsequent phosphating step, for example as a result of the carryover of the pickling solution.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)
  • ing And Chemical Polishing (AREA)
PCT/EP2017/060227 2016-04-29 2017-04-28 Zusammensetzung zur verminderung des beizabtrags beim beizen von metallischen oberflächen enthaltend blanken und/oder verzinkten stahl Ceased WO2017186929A1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
RU2018140856A RU2747720C2 (ru) 2016-04-29 2017-04-28 Композиция для уменьшения удаления материала путем травления при травлении металлических поверхностей, включающих оцинкованную и/или непокрытую сталь
EP17721118.2A EP3449040B1 (de) 2016-04-29 2017-04-28 Zusammensetzung zur verminderung des beizabtrags beim beizen von metallischen oberflächen enthaltend blanken und/oder verzinkten stahl
PL17721118T PL3449040T3 (pl) 2016-04-29 2017-04-28 Kompozycja do zmniejszania ubytku wskutek trawienia podczas trawienia powierzchni metalowych zawierających stal niepowlekaną i/lub ocynkowaną
BR112018071497-6A BR112018071497B1 (pt) 2016-04-29 2017-04-28 Composição aquosa, concentrado, processo para decapagem de uma superfície metálica, e, uso da superfície metálica decapada.
KR1020187030705A KR102369545B1 (ko) 2016-04-29 2017-04-28 아연도금 및/또는 비아연도금 강철을 포함하는 금속 표면의 피클링에서 피클링에 의한 재료의 제거를 감소시키기 위한 조성물
ES17721118T ES2795655T3 (es) 2016-04-29 2017-04-28 Composición para la reducción de la retirada de material por decapado durante el decapado de superficies metálicas que contienen acero brillante y/o galvanizado
US16/097,134 US11124884B2 (en) 2016-04-29 2017-04-28 Composition for reducing the removal of material by pickling in the pickling of metal surfaces that contain galvanized and/or ungalvanized steel
MX2018013233A MX385665B (es) 2016-04-29 2017-04-28 Composicion para reducir la remocion corrosiva de material en el decapado de superficies metalicas que comprenden acero desnudo y/o galvanizado.
CN201780024275.0A CN109072454B (zh) 2016-04-29 2017-04-28 用于在包含镀锌和/或未镀锌钢的金属表面酸洗中减少材料的酸洗去除的组合物
JP2018556914A JP6968825B2 (ja) 2016-04-29 2017-04-28 裸鋼および／または亜鉛めっき鋼を含む金属表面の酸洗いにおける材料の腐食除去を減少させるための組成物
ZA2018/07922A ZA201807922B (en) 2016-04-29 2018-11-23 Composition for reducing the removal of material by pickling in the pickling of metal surfaces that contain galvanized and/or ungalvanized steel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102016207429 2016-04-29
DE102016207429.6 2016-04-29

Publications (1)

Publication Number Publication Date
WO2017186929A1 true WO2017186929A1 (de) 2017-11-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/060227 Ceased WO2017186929A1 (de) 2016-04-29 2017-04-28 Zusammensetzung zur verminderung des beizabtrags beim beizen von metallischen oberflächen enthaltend blanken und/oder verzinkten stahl

Country Status (12)

Country Link
US (1) US11124884B2 (enExample)
EP (1) EP3449040B1 (enExample)
JP (1) JP6968825B2 (enExample)
KR (1) KR102369545B1 (enExample)
CN (1) CN109072454B (enExample)
DE (1) DE102017207232A1 (enExample)
ES (1) ES2795655T3 (enExample)
MX (1) MX385665B (enExample)
PL (1) PL3449040T3 (enExample)
RU (1) RU2747720C2 (enExample)
WO (1) WO2017186929A1 (enExample)
ZA (1) ZA201807922B (enExample)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
RU2812508C1 (ru) * 2023-05-04 2024-01-30 Федеральное государственное автономное образовательное учреждение высшего образования "Российский университет дружбы народов имени Патриса Лумумбы" (РУДН) Состав для чистки стрелкового оружия

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Publication number Priority date Publication date Assignee Title
BR112019011273A2 (pt) * 2016-12-02 2019-10-08 Ecolab Usa Inc método para inibir corrosão em uma superfície, uso de uma composição anticorrosão, composto, e, composição anticorrosão.
WO2019028400A1 (en) 2017-08-03 2019-02-07 Ecolab Usa Inc. THIOL ADDITION PRODUCTS FOR INHIBITING CORROSION
EP3724371A1 (de) 2017-12-12 2020-10-21 Chemetall GmbH Borsäurefreie zusammensetzung zur entfernung von kryolithhaltigen ablagerungen

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US20090032057A1 (en) * 2007-02-01 2009-02-05 Henkel Corporation Acid inhibitor compositions for metal cleaning and/or pickling
DE102015005521A1 (de) * 2014-04-30 2015-11-05 Rio Verwaltungs Ag Behandlungvorrichtung und Behandlungsverfahren zum Beizen und Phosphatieren von Metallteilen

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