WO2017101687A1 - 有机发光显示器件及显示装置 - Google Patents

有机发光显示器件及显示装置 Download PDF

Info

Publication number
WO2017101687A1
WO2017101687A1 PCT/CN2016/108389 CN2016108389W WO2017101687A1 WO 2017101687 A1 WO2017101687 A1 WO 2017101687A1 CN 2016108389 W CN2016108389 W CN 2016108389W WO 2017101687 A1 WO2017101687 A1 WO 2017101687A1
Authority
WO
WIPO (PCT)
Prior art keywords
ring
organic light
layer
display device
group
Prior art date
Application number
PCT/CN2016/108389
Other languages
English (en)
French (fr)
Inventor
李维维
刘嵩
谢静
闵超
赵菲
高松
Original Assignee
昆山工研院新型平板显示技术中心有限公司
昆山国显光电有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 昆山工研院新型平板显示技术中心有限公司, 昆山国显光电有限公司 filed Critical 昆山工研院新型平板显示技术中心有限公司
Priority to EP16874744.2A priority Critical patent/EP3392911B1/en
Priority to KR1020187018243A priority patent/KR102103874B1/ko
Priority to JP2018529288A priority patent/JP6661015B2/ja
Priority to US15/781,446 priority patent/US20200203618A1/en
Publication of WO2017101687A1 publication Critical patent/WO2017101687A1/zh

Links

Images

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30—Devices specially adapted for multicolour light emission
    • H10K59/38—Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/12—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising dopants
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/12—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising dopants
    • H10K50/121—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising dopants for assisting energy transfer, e.g. sensitization
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/654—Aromatic compounds comprising a hetero atom comprising only nitrogen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1059—Heterocyclic compounds characterised by ligands containing three nitrogen atoms as heteroatoms
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/10—Triplet emission
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/20—Delayed fluorescence emission
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/30—Highest occupied molecular orbital [HOMO], lowest unoccupied molecular orbital [LUMO] or Fermi energy values
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/40—Interrelation of parameters between multiple constituent active layers or sublayers, e.g. HOMO values in adjacent layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/15—Hole transporting layers
    • H10K50/156—Hole transporting layers comprising a multilayered structure
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/16—Electron transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17—Carrier injection layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17—Carrier injection layers
    • H10K50/171—Electron injection layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/18—Carrier blocking layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/18—Carrier blocking layers
    • H10K50/181—Electron blocking layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10—OLED displays
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H10K85/636—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising heteroaromatic hydrocarbons as substituents on the nitrogen atom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6574—Polycyclic condensed heteroaromatic hydrocarbons comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes

Definitions

  • the present invention relates to the field of flat panel display technologies, and in particular, to an organic light emitting display device and a display device.
  • organic light emitting display devices are classified into a single body device and a dual body device.
  • a single-host device generally has a problem of low current efficiency and short life.
  • the dual-body device is more advantageous for the regulation of carrier balance in the device than the single-body device, and the device performance is better.
  • the dual-body device has high requirements on process stability, and the slight fluctuation of the ratio of the two main components in the dual-body device will greatly change the performance of the device, which is a big challenge to the yield of the product in the production line.
  • An organic light emitting display device comprising:
  • the functional structure layer includes a hole injection layer, a first hole transport layer sequentially stacked on the first electrode a second hole transport layer, an organic light emitting layer, an electron transport layer, and an electron injection layer;
  • the highest occupied orbital energy level of the first material constituting the first hole transporting layer is smaller than the highest occupied orbital energy level of the second material constituting the second hole transporting layer;
  • the triplet energy level is greater than 2.5 eV;
  • the organic light emitting layer includes a light emitting material including a thermally activated delayed fluorescent material.
  • the second material constituting the second hole transport layer is selected from the compounds represented by Formula 1.
  • Structure 1-1 is:
  • Structure 1-2 is:
  • -L a is selected from an aromatic ring having 6 to 25 ring carbon atoms or an aromatic hetero ring having 5 to 25 ring atoms
  • - Ar d is selected from ring carbon atoms of 6 to 25 aryl group, or hetero ring atoms is 5 to 25 aromatic group
  • n is selected from 2 or 3, a plurality -Ar d each may be the same or different;
  • Structural formula 1-3 is:
  • L b is selected from the group consisting of an arylene group having 6 to 25 ring carbon atoms or a heteroarylene group having 5 to 25 ring atoms; L b is bonded to a ring to which R 1 is attached;
  • R 1 and R 2 are each independently selected from an alkyl group having 1 to 15 carbon atoms, an alkenyl group having 2 to 15 carbon atoms, a cycloalkyl group having 3 to 15 ring carbon atoms, and a ring-constituting carbon atom.
  • X is selected from CR 3 R 4 , NR 5 , O or S, and R 3 , R 4 and R 5 are each independently selected from an alkyl group having 1 to 15 carbon atoms or a ring-constituting carbon number of 6 ⁇ 25 aryl;
  • Ar c is selected from an aryl group having 6 to 50 ring carbon atoms or a heteroaryl group having 5 to 25 ring atoms, or a structure represented by Structural Formula 1-1, Structural Formula 1-2 or Structural Formula 1-3. .
  • the second hole transport layer has a thickness of 20 to 50 nm.
  • the second hole transport layer has a thickness of 35 to 45 nm.
  • the luminescent host material comprises a green photothermally activated delayed fluorescent material.
  • the luminescent host material is selected from the group consisting of compounds represented by Formula 2,
  • the structure of the ring A is as shown in the structural formula 2-1.
  • Structure 2-1 is:
  • Ring A is fused to an adjacent ring;
  • X is selected from N or CH, wherein at least one X is selected from N;
  • Ar 1 , Ar 2 , and Ar 3 are each independently selected from a non-fused ring aromatic hydrocarbon substituent, or are not thick.
  • R is selected from a H atom or a monovalent substituent.
  • the luminescent host material is selected from the group consisting of compounds of the formula
  • the luminescent host material comprises a red light thermally activated delayed fluorescent material.
  • the first hole transport layer has a thickness of 1 to 40 nm.
  • the present invention also provides a display device comprising the organic light emitting display device provided by the present invention.
  • the organic light-emitting display device of the present invention adopts two layers of hole transport layers, wherein the second hole transport layer functions as an electron blocking layer and an optical compensation layer, and is delayed from thermal activation in the organic light-emitting layer
  • the combination of fluorescent materials enhances the current efficiency and lifetime of the organic light-emitting display device.
  • FIG. 1 is a schematic structural view of an organic light emitting display device according to a preferred embodiment of the present invention.
  • FIG. 2 is a schematic structural view of an organic light emitting display device of Comparative Example 1.
  • an organic light emitting display device 100 includes a first electrode 110, a second electrode 120, and a functional structure layer 130 between the first electrode 110 and the second electrode 120.
  • the first electrode 110 is an indium tin oxide electrode
  • the second electrode 120 is a silver electrode.
  • the first electrode 110 and the second electrode 120 are not limited to the above electrodes, and may be He electrodes.
  • the organic light-emitting display device 100 in the present embodiment is a top emission, and in order to further optimize the performance, a circular polarizer layer 190 is further disposed on a side of the second electrode 120 away from the functional structure layer 130.
  • the circular polarizer layer 190 may not be provided.
  • the functional structure layer 130 includes a hole injection layer 131 sequentially stacked on the first electrode 110, a first hole transport layer 1321, a second hole transport layer 1322, an organic light emitting layer 133, an electron transport layer 134, and Electron injection layer 135.
  • the material and thickness of the hole injection layer 131, the electron transport layer 134, and the electron injection layer 135 are not particularly limited, and materials and thicknesses well known to those skilled in the art may be used, and details are not described herein.
  • the primary role of the first hole transporting layer 1321 is hole transport, and the second hole transporting layer 1322 serves as an electron blocking layer and an optical compensation layer in addition to hole transport.
  • the material of the second hole transport layer 1322 has a triplet energy level greater than 2.5 eV.
  • the highest occupied orbital energy level of the material of the second hole transport layer 1322 is greater than the highest occupied orbital energy level of the material of the first hole transport layer 1321.
  • the material of the first hole transport layer 1321 is selected from the group consisting of NPB.
  • the material of the first hole transport layer 1321 is not limited to NPB, and may be other hole transport materials.
  • the first hole transport layer 1321 has a thickness of 1 to 40 nm, more preferably 5 to 20 nm.
  • the material of the second hole transport layer 1322 is an aryl tertiary amine compound.
  • the material of the second hole transport layer is selected from the compounds represented by Formula 1.
  • Structure 1-1 is:
  • Structure 1-2 is:
  • -Ar d is selected from a self-substituted or unsubstituted aryl group having 6 to 25 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 25 ring atoms;
  • n is selected from 2 or 3, a plurality of -Ar d They can be the same or different;
  • Structural formula 1-3 is:
  • -L b is selected from substituted or unsubstituted arylene groups having 6 to 25 ring carbon atoms or substituted or unsubstituted heteroarylene groups having 5 to 25 ring atoms; L b and R 1 The connected ring is connected by a single button;
  • R 1 and R 2 are each independently selected from an alkyl group having 1 to 15 carbon atoms, an alkenyl group having 2 to 15 carbon atoms, a cycloalkyl group having 3 to 15 ring carbon atoms, and a ring-constituting carbon atom.
  • X is selected from CR 3 R 4 , NR 5 , O or S, and R 3 , R 4 and R 5 are each independently selected from a substituted or unsubstituted alkyl group having 1 to 15 carbon atoms or substituted or An unsubstituted aryl group having 6 to 25 ring carbon atoms;
  • Ar c is selected from substituted or unsubstituted aryl groups having 6 to 50 ring carbon atoms, or substituted or unsubstituted heteroaryl groups having 5 to 25 ring atoms, or structural formula 1-1, structural formula 1-2 or structural formula 1-3.
  • the material of the second hole transporting layer is preferably a compound of the following formula:
  • the second hole transport layer 1322 has a thickness of 20 to 50 nm, more preferably 35 to 45 nm.
  • the organic light-emitting layer 133 comprises a light-emitting host material, and the light-emitting host material is a heat-activated delayed fluorescent material.
  • the organic light-emitting display device of the present invention is preferably a green light device, that is, the light-emitting host material is a green light-thermally-activated delayed fluorescent material.
  • the luminescent host material is selected from the compounds represented by Formula 2,
  • the structure of the ring A is as shown in the structural formula 2-1.
  • Structure 2-1 is:
  • Ring A is fused to an adjacent ring;
  • X is selected from N or CH, wherein at least one X is selected from N; and
  • Ar 1 , Ar 2 , and Ar 3 are each independently selected from substituted or unsubstituted non-fused ring aromatic hydrocarbons.
  • R is selected from a H atom or a monovalent substituent.
  • the luminescent host material is selected from one of the compounds of the following structural formula
  • the luminescent host material is not limited to the compound of the above formula, and may also be a compound of the following formula:
  • the organic light-emitting layer 133 generally also includes a dye.
  • Dyes may be selected from dyes well known to those skilled in the art.
  • the organic light-emitting layer has a thickness of 10 to 40 nm.
  • the organic light emitting display device of the present invention is not limited to a green light device, and may be a red light device or a blue light device.
  • the above organic light-emitting display device employs two layers of hole transport layers, wherein the second hole transport layer functions as an electron blocking layer and an optical compensation layer, and is matched with a thermally activated delayed fluorescent material in the organic light-emitting layer, thereby improving the organic light-emitting display.
  • Current efficiency and lifetime of the device And there is no increase in difficulty in the process relative to the prior art.
  • the present invention also provides a display device comprising the organic light emitting display device provided by the present invention.
  • a top-emitting green single-body device as shown in FIG. 1, includes a first electrode 110, a hole injection layer 131, a first hole transport layer 1321, and a second hole transport layer 1322 in order from bottom to top.
  • the first electrode 110 is an indium tin oxide electrode and has a thickness of 40 nm.
  • the material of the hole injection layer 131 is HAT and has a thickness of 10 nm.
  • the material of the first hole transport layer 1321 is NPB and has a thickness of 20 nm.
  • the material of the second hole transport layer 1322 is a material of the following structural formula and has a thickness of 40 nm.
  • the material of the organic light-emitting layer 133 is a material of the following structural formula and has a thickness of 30 nm.
  • the electron transport layer 134 is a co-evaporated layer of Bphen and Liq having a thickness of 30 nm.
  • the material of the electron injecting layer 135 is a silver alloy and has a thickness of 2 nm.
  • the second electrode 120 is a silver electrode and has a thickness of 16 nm.
  • the material of the optical coupling layer 190 is Alq 3 and has a thickness of 65 nm.
  • the top-emitting green single-body device 100' has only one hole transport layer 132, and the material of the hole transport 132 and the second hole transport layer of Embodiment 1. The materials are the same.
  • the hole injection layer has two layers, that is, a first hole injection layer 1311 and a second hole injection layer 1312.
  • the second hole injecting layer serves as an optical compensation layer and has a thickness of 35 nm.
  • the material of the second hole injecting layer was 4,4,4-tris(N-3-methylphenyl-N-phenyl-amino)-triphenylamine (m-MTDATA).
  • Comparative Example 1 The difference from Comparative Example 1 is that the material of the hole transport layer is NPB.
  • the life decay test was performed at an initial luminance of 10 Knit, and the brightness was attenuated to the initial 97%.
  • Example 1 The devices of Example 1 and Comparative Example 1-2 were subjected to voltage, current efficiency, CIE-x, CIE-y, and lifetime detection, respectively, and the test structure is shown in Table 1.
  • the device of Example 1 has a significant improvement over the device of Comparative Example 1 or 2 regardless of current efficiency, CIE-x, CIE-y, and lifetime.
  • the device current efficiency of Example 1 was 11.2% higher than that of the device of Comparative Example 2, the lifetime was improved by 225 hours, and the lifetime was almost doubled.
  • the device current efficiency of Example 1 was 10% higher than that of the device of Comparative Example 1, the lifetime was improved by 165 hours, and the lifetime was almost doubled.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Optics & Photonics (AREA)
  • Organic Chemistry (AREA)
  • Electroluminescent Light Sources (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

一种有机发光显示器件（100），该有机发光显示器件（100）的功能结构层（130）包括顺序地层叠在第一电极（110）上的空穴注入层（131）、第一空穴传输层（1321）、第二空穴传输层（1322）、有机发光层（133）、电子传输层（134）、以及电子注入层（135）；第一空穴传输层（1321）的材料的最高已占轨道能级小于所述第二空穴传输层（1322）的最高已占轨道能级；第二空穴传输层（1322）的材料的三线态能级大于2.5eV；有机发光层（133）包括发光主体材料，该发光主体材料包括热激活延迟荧光材料。上述有机发光显示器件（100），采用两层空穴传输层，其中第二空穴传输层（1322）作为电子阻挡层以及光学补偿层，并且与有机发光层（133）中的热激活延迟材料搭配，从而提升了有机发光显示器件（100）的电流效率以及寿命。

Description

有机发光显示器件及显示装置 技术领域
本发明涉及平板显示技术领域，特别是涉及一种有机发光显示器件及显示装置。
背景技术
目前，有机发光显示器件分为单主体器件和双主体器件。其中，单主体器件一般存在电流效率低、寿命短的问题。而双主体器件相对于单主体器件更利于器件中载流子平衡的调节，器件性能上更好。但是双主体器件对工艺稳定性要求高，双主体器件中两主体成分比例微弱的波动就会对器件性能造成大的改变，这对在量产线对产品的良率是个大的挑战。
发明内容
基于此，有必要针对现有的单主体器件的电流效率低、寿命短问题，提供一种电流效率高、寿命长的有机发光显示器件。
一种有机发光显示器件，包括：
第一电极；
第二电极；以及
功能结构层，其位于所述第一电极和所述第二电极之间，其中，所述功能结构层包括顺序地层叠在所述第一电极上的空穴注入层、第一空穴传输层、第二空穴传输层、有机发光层、电子传输层、以及电子注入层；
其中，构成所述第一空穴传输层的第一材料的最高已占轨道能级小于构成所述第二空穴传输层的第二材料的最高已占轨道能级；所述第二材料的三线态能级大于2.5eV；
所述有机发光层包括发光材料，所述发光材料包括热激活延迟荧光材料。
在其中一个实施例中，构成所述第二空穴传输层的所述第二材料选自通式1所表示的化合物，
通式1为：
Figure PCTCN2016108389-appb-000001
其中，—Ara的结构如结构式1-1或1-2所示，
结构式1-1为：
Figure PCTCN2016108389-appb-000002
结构式1-2为：
Figure PCTCN2016108389-appb-000003
其中，—La选自成环碳原子数为6～25的芳香族环、或成环原子数为5～25的芳香族杂环；—Ard选自成环碳原子数为6～25的芳基、或成环原子数为5～25的杂芳基；n选自2或3，多个—Ard分别可以相同也可以不同；
—Arb的结构如结构式1-3所示，
结构式1-3为：
Figure PCTCN2016108389-appb-000004
其中，—Lb选自成环碳原子数为6～25的亚芳基或成环原子数为5～25的杂亚芳基；Lb与R1所连接的环单键连接；
R1和R2分别独立地选自碳原子数为1～15的烷基、碳原子数为2～15的烯基、成环碳原子数为3～15的环烷基、成环碳原子数为6～25的芳基、成环原子数为5～25的杂芳基、由碳原子数为1～15的烷基形成的三烷基甲硅烷基、由成环碳原子数为6～25的芳基形成的三芳基甲硅烷基、由碳原子数为1～15的烷基和成环碳原子数为6～25的芳基形成的烷基芳基甲硅烷基、咔唑基、卤素原子或氰基，o选自0～3的整数，p选自0～4的整数，相邻 的多个R1之间和R2之间、以及R1和R2可以相互键合而形成环，X选自CR3R4、NR5、O或S，R3、R4和R5分别独立地选自碳原子数为1～15的烷基或成环碳原子数为6～25的芳基；
Arc选自成环碳原子数为6～50的芳基、或成环原子数为5～25的杂芳基，或由结构式1-1、结构式1-2或结构式1-3表示的结构。
在其中一个实施例中，所述第二空穴传输层的厚度为20～50nm。
在其中一个实施例中，所述第二空穴传输层的厚度为35～45nm。
在其中一个实施例中，所述发光主体材料包括绿光热激活延迟荧光材料。
在其中一个实施例中，所述发光主体材料选自通式2所表示的化合物，
通式2为：
Figure PCTCN2016108389-appb-000005
其中，环A的结构如结构式2-1所示，
结构式2-1为：
Figure PCTCN2016108389-appb-000006
环A与相邻的环稠连；X选自N或CH，其中至少一个X选自N；Ar1、Ar2、Ar3分别独立选自非稠环芳香基碳氢取代基，或非稠环芳香基杂环取代基，其中Ar2和Ar3不排除通过一个包含杂原子的芳环形成稠连结构；R选自H原子或一价的取代基。
在其中一个实施例中，所述发光主体材料选自如下结构式的化合物中的一种
Figure PCTCN2016108389-appb-000007
在其中一个实施例中，所述发光主体材料包括红光热激活延迟荧光材料。
在其中一个实施例中，所述第一空穴传输层的厚度为1～40nm。
本发明还提供了一种显示装置，其包括本发明所提供的有机发光显示器件。
与现有技术相比，本发明的有机发光显示器件，通过采用两层空穴传输层，其中第二空穴传输层作为电子阻挡层以及光学补偿层，并且与有机发光层中的热激活延迟荧光材料搭配，从而提升了有机发光显示器件的电流效率以及寿命。
附图说明
图1为本发明一优选实施方式的有机发光显示器件的结构示意图。
图2为对比例1的有机发光显示器件的结构示意图。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合附图及实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
参见图1，一种有机发光显示器件100，包括第一电极110、第二电极120、以及位于第一电极110和第二电极120之间的功能结构层130。
在本实施方式中，第一电极110为氧化铟锡电极，第二电极120为银电极。当然，第一电极110和第二电极120并不局限于上述电极，也可以是其 他电极。
本实施方式中的有机发光显示器件100为顶发光，为了进一步优化其性能，在第二电极120上远离功能结构层130的一侧还设有圆偏光镜层190。当然，也可以不设圆偏光镜层190。
其中，功能结构层130包括顺序地层叠在第一电极110上的空穴注入层131、第一空穴传输层1321、第二空穴传输层1322、有机发光层133、电子传输层134、以及电子注入层135。
其中，空穴注入层131、电子传输层134以及电子注入层135的材料以及厚度没有特殊限制，可以采用本领域技术人员所公知的材料和厚度，在此不再赘述。
在本发明中，第一空穴传输层1321的主要作用是空穴传输，而第二空穴传输层1322除了空穴传输之外，同时还作为电子阻挡层以及光学补偿层。
第二空穴传输层1322的材料的三线态能级大于2.5eV。第二空穴传输层1322的材料的最高已占轨道能级大于第一空穴传输层1321的材料的最高已占轨道能级。
优选地，第一空穴传输层1321的材料选自NPB。当然，第一空穴传输层1321的材料并不局限于NPB，亦可以是其它空穴传输材料。
优选地，第一空穴传输层1321的厚度为1～40nm，更优选为5～20nm。
优选地，第二空穴传输层1322的材料为芳基叔胺化合物。
更优选地，所述第二空穴传输层的材料选自通式1所表示的化合物，
通式1为：
Figure PCTCN2016108389-appb-000008
其中，—Ara的结构如结构式1-1或1-2所示，
结构式1-1为：
Figure PCTCN2016108389-appb-000009
结构式1-2为：
Figure PCTCN2016108389-appb-000010
其中，—La选自成取代或未取代的环碳原子数为6～25的芳香族环、或取代或未取代的成环原子数为5～25的芳香族杂环；—Ard选自取代或未取代的成环碳原子数为6～25的芳基、或取代或未取代的成环原子数为5～25的杂芳基；n选自2或3，多个—Ard分别可以相同也可以不同；
—Arb的结构如结构式1-3所示，
结构式1-3为：
Figure PCTCN2016108389-appb-000011
其中，—Lb选自取代或未取代的成环碳原子数为6～25的亚芳基或者取代或未取代的成环原子数为5～25的杂亚芳基；Lb与R1所连接的环单键连接；
R1和R2分别独立地选自碳原子数为1～15的烷基、碳原子数为2～15的烯基、成环碳原子数为3～15的环烷基、成环碳原子数为6～25的芳基、成环原子数为5～25的杂芳基、由碳原子数为1～15的烷基形成的三烷基甲硅烷基、由成环碳原子数为6～25的芳基形成的三芳基甲硅烷基、由碳原子数为1～15的烷基和成环碳原子数为6～25的芳基形成的烷基芳基甲硅烷基、咔唑基、卤素原子或氰基，o选自0～3的整数，p选自0～4的整数，相邻的多个R1之间和R2之间、以及R1和R2可以相互键合而形成环，X选自CR3R4、NR5、O或S，R3、R4和R5分别独立地选自取代或未取代的碳原子数为1～15的烷基或者取代或未取代的成环碳原子数为6～25的芳基；
Arc选自的取代或未取代的成环碳原子数为6～50的芳基、或取代或未取 代的成环原子数为5～25的杂芳基，或由结构式1-1、结构式1-2或结构式1-3表示。
所述第二空穴传输层的材料优选选取如下结构式的化合物：
Figure PCTCN2016108389-appb-000012
优选地，第二空穴传输层1322的厚度为20-50nm，更优选为35-45nm。
其中，有机发光层133包括发光主体材料，所述发光主体材料为热激活延迟荧光材料。
本发明的有机发光显示器件优选为绿光器件，也即所述发光主体材料为绿光热激活延迟荧光材料。
优选地，所述发光主体材料选自通式2所表示的化合物，
通式2为：
Figure PCTCN2016108389-appb-000013
其中，环A的结构如结构式2-1所示，
结构式2-1为：
Figure PCTCN2016108389-appb-000014
环A与相邻的环稠连；X选自N或CH，其中至少一个X选自N；Ar1、Ar2、Ar3分别独立选自取代或未取代的非稠环芳香基碳氢取代基，或取代或未取代的非稠环芳香基杂环取代基，其中Ar2和Ar3不排除通过一个包含杂原子的芳环形成稠连结构；R选自H原子或一价的取代基。
更优选地，所述发光主体材料选自如下结构式的化合物中的一种
Figure PCTCN2016108389-appb-000015
当然，所述发光主体材料并不局限于上述结构式的化合物，还可以是如下结构式的化合物：
Figure PCTCN2016108389-appb-000016
在实际应用中，有机发光层133一般还包括染料。染料可以选用本领域技术人员所公知的染料。
优选地，有机发光层的厚度为10-40nm。
当然，本发明的有机发光显示器件并不局限为绿光器件，也可以是红光器件，亦或是蓝光器件。
上述有机发光显示器件，采用两层空穴传输层，其中第二空穴传输层作为电子阻挡层以及光学补偿层，并且与有机发光层中的热激活延迟荧光材料搭配，从而提升了有机发光显示器件的电流效率以及寿命。且相对于现有技术在工艺上没有增加难度。
本发明还提供了一种显示装置，该显示装置包括本发明所提供的有机发光显示器件。
以下结合具体实施例对本发明做进一步的阐述。
实施例1
一顶发光绿光单主体器件，如图1所示，其从下到上依次包括第一电极110、空穴注入层131、第一空穴传输层1321、第二空穴传输层1322、有机发光层133、电子传输层134、电子注入层135、第二电极120、以及圆偏光 镜层190。
第一电极110为氧化铟锡电极，厚度为40nm。
空穴注入层131的材料为HAT，厚度为10nm。
第一空穴传输层1321的材料为NPB，厚度为20nm。
第二空穴传输层1322的材料为如下结构式的材料，厚度为40nm。
Figure PCTCN2016108389-appb-000017
有机发光层133的材料为如下结构式的材料，厚度为30nm。
Figure PCTCN2016108389-appb-000018
电子传输层134为Bphen和Liq的共蒸镀层，厚度为30nm。
电子注入层135的材料为美银合金，厚度为2nm。
第二电极120为银电极，厚度为16nm。
光学耦合层190的材料为Alq3，厚度为65nm。
对比例1
参见图2，与实施例1所不同的是，顶发光绿光单主体器件100’只有一层空穴传输层132，所述空穴传输132的材料与实施例1的第二空穴传输层的材料相同。
空穴注入层有两层，即第一空穴注入层1311以及第二空穴注入层1312。其中，第二空穴注入层作为光学补偿层，厚度为35nm。第二空穴注入层的材料为4，4，4-三(N-3-甲基苯基-N-苯基-氨基)-三苯基胺(m-MTDATA)。
对比例2
与对比例1所不同的是，所述空穴传输层的材料为NPB。
性能测试：
CIE-x、CIE-y的测试：
采用PR705光谱仪进行测试，在1931CIE下的色度值。
寿命的测试：
采用寿命测试仪，在初始亮度为10Knit下进行寿命衰减测试，亮度衰减到初始的97％所需要的时间。
将实施例1以及对比例1-2的器件分别进行电压、电流效率、CIE-x、CIE-y、以及寿命检测，测试结构见表1。
表1
Figure PCTCN2016108389-appb-000019
从表1可以看出，无论电流效率、CIE-x、CIE-y以及寿命，实施例1的器件相对于对比例1或2的器件都有了大幅提升。实施例1的器件电流效率相对于对比例2的器件提升了11.2％，寿命提升了225h，寿命几乎提升接近2倍。实施例1的器件电流效率相对于对比例1的器件提升了10％，寿命提升了165h，寿命几乎提升接近1倍。
以上所述实施例的各技术特征可以进行任意的组合，为使描述简洁，未对上述实施例中的各个技术特征所有可能的组合都进行描述，然而，只要这些技术特征的组合不存在矛盾，都应当认为是本说明书记载的范围。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对发明专利范围的限制。应当指出的是，对于本 领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。

Claims (12)

  1. 一种有机发光显示器件，包括：
    第一电极；
    第二电极；以及
    功能结构层，其位于第一电极和第二电极之间，其中，所述功能结构层包括顺序地层叠在所述第一电极上的空穴注入层、第一空穴传输层、第二空穴传输层、有机发光层、电子传输层、以及电子注入层；
    其中，构成所述第一空穴传输层的第一材料的最高已占轨道能级小于构成所述第二空穴传输层的第二材料的最高已占轨道能级；所述第二材料的三线态能级大于2.5eV；
    所述有机发光层包括发光主体材料，所述发光主体材料包括热激活延迟荧光材料。
  2. 根据权利要求1所述的有机发光显示器件，其特征在于，所述第二空穴传输层的材料选自通式1所表示的化合物，
    通式1为：
    Figure PCTCN2016108389-appb-100001
    其中，—Ara的结构如结构式1-1或1-2所示，
    结构式1-1为：
    Figure PCTCN2016108389-appb-100002
    结构式1-2为：
    Figure PCTCN2016108389-appb-100003
    其中，—La选自成环碳原子数为6～25的芳香族环、或成环原子数为5～25的芳香族杂环；—Ard选自成环碳原子数为6～25的芳基、或成环原子数为5～25的杂芳基；n选自2或3，多个—Ard分别可以相同也可以不同；
    —Arb的结构如结构式1-3所示，
    结构式1-3为：
    Figure PCTCN2016108389-appb-100004
    其中，—Lb选自成环碳原子数为6～25的亚芳基或成环原子数为5～25的杂亚芳基；Lb与R1所连接的环单键连接；
    R1和R2分别独立地选自碳原子数为1～15的烷基、碳原子数为2～15的烯基、成环碳原子数为3～15的环烷基、成环碳原子数为6～25的芳基、成环原子数为5～25的杂芳基、由碳原子数为1～15的烷基形成的三烷基甲硅烷基、由成环碳原子数为6～25的芳基形成的三芳基甲硅烷基、由碳原子数为1～15的烷基和成环碳原子数为6～25的芳基形成的烷基芳基甲硅烷基、咔唑基、卤素原子或氰基，o选自0～3的整数，p选自0～4的整数，相邻的多个R1之间和R2之间、以及R1和R2可以相互键合而形成环，X选自CR3R4、NR5、O或S，R3、R4和R5分别独立地选自碳原子数为1～15的烷基或成环碳原子数为6～25的芳基；
    Arc选自成环碳原子数为6～50的芳基、或成环原子数为5～25的杂芳基，或由结构式1-1、结构式1-2或结构式1-3表示的结构。
  3. 根据权利要求1所述的有机发光显示器件，其特征在于，所述第二空穴传输层的厚度为20～50nm。
  4. 根据权利要求1所述的有机发光显示器件，其特征在于，所述第二空穴传输层的厚度为35～45nm。
  5. 根据权利要求1所述的有机发光显示器件，其特征在于，所述发光主体材料包括绿光热激活延迟荧光材料。
  6. 根据权利要求5所述的有机发光显示器件，其特征在于，所述发光主 体材料选自通式2所表示的化合物，
    通式2为：
    Figure PCTCN2016108389-appb-100005
    其中，环A的结构如结构式2-1所示，
    结构式2-1为：
    Figure PCTCN2016108389-appb-100006
    环A与相邻的环稠连；X选自N或CH，其中至少一个X选自N；Ar1、Ar2、Ar3分别独立选自非稠环芳香基碳氢取代基，或非稠环芳香基杂环取代基，其中Ar2和Ar3不排除通过一个包含杂原子的芳环形成稠连结构；R选自H原子或一价的取代基。
  7. 根据权利要求6所述的有机发光显示器件，其特征在于，所述发光主体材料选自如下结构式的化合物中的一种
    Figure PCTCN2016108389-appb-100007
  8. 根据权利要求1所述的有机发光显示器件，其特征在于，所述发光主体材料包括红光热激活延迟荧光材料。
  9. 根据权利要求1-8中任一项所述的有机发光显示器件，其特征在于，所述第一空穴传输层的厚度为1～40nm。
  10. 根据权利要求1-8中任一项所述的有机发光显示器件，其特征在于， 在所述第二电极上远离所述功能结构层130的一侧还设有圆偏光镜层190。
  11. 根据权利要求1-8中任一项所述的有机发光显示器件，其特征在于，所述有机发光层的厚度为10～40nm。
  12. 一种显示装置，其特征在于，包括权利要求1-8中任一项所述的有机发光显示器件。
PCT/CN2016/108389 2015-12-15 2016-12-02 有机发光显示器件及显示装置 WO2017101687A1 (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP16874744.2A EP3392911B1 (en) 2015-12-15 2016-12-02 Organic light-emitting display device and display apparatus
KR1020187018243A KR102103874B1 (ko) 2015-12-15 2016-12-02 유기 발광 디스플레이 기기 및 디스플레이 장치
JP2018529288A JP6661015B2 (ja) 2015-12-15 2016-12-02 有機発光表示デバイス及び表示装置
US15/781,446 US20200203618A1 (en) 2015-12-15 2016-12-02 Organic light-emitting display device and display apparatus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510937461.6A CN106887444B (zh) 2015-12-15 2015-12-15 有机发光显示器件及显示装置
CN201510937461.6 2015-12-15

Publications (1)

Publication Number Publication Date
WO2017101687A1 true WO2017101687A1 (zh) 2017-06-22

Family

ID=59055791

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2016/108389 WO2017101687A1 (zh) 2015-12-15 2016-12-02 有机发光显示器件及显示装置

Country Status (7)

Country Link
US (1) US20200203618A1 (zh)
EP (1) EP3392911B1 (zh)
JP (1) JP6661015B2 (zh)
KR (1) KR102103874B1 (zh)
CN (1) CN106887444B (zh)
TW (1) TW201733107A (zh)
WO (1) WO2017101687A1 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659442A (zh) * 2018-12-13 2019-04-19 云谷（固安）科技有限公司 一种有机电致发光器件和显示装置
CN110911572A (zh) * 2019-11-25 2020-03-24 Tcl华星光电技术有限公司 一种有机发光显示器件及其制备方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3598516B1 (en) * 2017-03-15 2024-01-31 Hodogaya Chemical Co., Ltd. Organic electroluminescent element
KR102172580B1 (ko) * 2018-02-13 2020-11-02 주식회사 엘지화학 헤테로고리 화합물 및 이를 포함하는 유기 발광 소자
CN114072511B (zh) 2018-07-26 2024-04-12 株式会社大熊制药 具有固醇生产能力的重组酵母菌株、其制备方法及用途
CN111384280B (zh) * 2018-12-29 2021-05-18 Tcl科技集团股份有限公司 一种量子点发光二极管及其制备方法
CN111662312B (zh) * 2020-06-08 2023-08-11 武汉天马微电子有限公司 一种化合物、热激活延迟荧光材料及其应用
CN111943961B (zh) * 2020-08-26 2021-07-27 山西穿越光电科技有限责任公司 基于吩嗪-噻吩-二氰基的有机电致发光化合物及应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104505464A (zh) * 2014-12-31 2015-04-08 昆山工研院新型平板显示技术中心有限公司 一种有机电致发光器件
CN104659268A (zh) * 2015-01-20 2015-05-27 北京鼎材科技有限公司 一种顶发射白光有机电致发光器件
CN104835916A (zh) * 2015-04-11 2015-08-12 吉林大学 一种基于荧光掺杂发光层的高效有机电致发光器件

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040209115A1 (en) * 2003-04-21 2004-10-21 Thompson Mark E. Organic light emitting devices with wide gap host materials
TW201129546A (en) * 2009-11-16 2011-09-01 Idemitsu Kosan Co Aromatic amine derivative, and organic electroluminescent element comprising same
KR101317923B1 (ko) * 2009-12-07 2013-10-16 고쿠리쓰다이가쿠호진 규슈다이가쿠 유기 발광 재료 및 유기 발광 소자
JP5964328B2 (ja) * 2011-02-11 2016-08-03 ユニバーサル ディスプレイ コーポレイション 有機発光素子及び該有機発光素子に使用されるための材料
US9627625B2 (en) * 2012-02-15 2017-04-18 Toray Industries, Inc. Light-emitting device material and light-emitting device
JP6113993B2 (ja) * 2012-10-03 2017-04-12 出光興産株式会社 有機エレクトロルミネッセンス素子
US10297761B2 (en) * 2012-12-10 2019-05-21 Idemitsu Kosan Co., Ltd. Organic electroluminescent element
ES2661409T3 (es) * 2013-03-29 2018-03-28 Kyulux, Inc. Dispositivo electroluminiscente orgánico
WO2014166572A1 (de) * 2013-04-08 2014-10-16 Merck Patent Gmbh Organische lichtemittierende vorrichtung mit verzögerter fluoreszenz
WO2015174640A1 (ko) * 2014-05-13 2015-11-19 삼성에스디아이 주식회사 화합물, 이를 포함하는 유기 광전자 소자 및 표시장치
JP6727762B2 (ja) * 2014-05-30 2020-07-22 株式会社半導体エネルギー研究所 発光装置及び電子機器

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104505464A (zh) * 2014-12-31 2015-04-08 昆山工研院新型平板显示技术中心有限公司 一种有机电致发光器件
CN104659268A (zh) * 2015-01-20 2015-05-27 北京鼎材科技有限公司 一种顶发射白光有机电致发光器件
CN104835916A (zh) * 2015-04-11 2015-08-12 吉林大学 一种基于荧光掺杂发光层的高效有机电致发光器件

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3392911A4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659442A (zh) * 2018-12-13 2019-04-19 云谷（固安）科技有限公司 一种有机电致发光器件和显示装置
CN110911572A (zh) * 2019-11-25 2020-03-24 Tcl华星光电技术有限公司 一种有机发光显示器件及其制备方法

Also Published As

Publication number Publication date
US20200203618A1 (en) 2020-06-25
JP6661015B2 (ja) 2020-03-11
KR102103874B1 (ko) 2020-04-24
CN106887444B (zh) 2020-01-10
JP2019501527A (ja) 2019-01-17
EP3392911B1 (en) 2021-04-21
EP3392911A1 (en) 2018-10-24
TW201733107A (zh) 2017-09-16
KR20180087372A (ko) 2018-08-01
CN106887444A (zh) 2017-06-23
EP3392911A4 (en) 2018-12-05

Similar Documents

Publication Publication Date Title
WO2017101687A1 (zh) 有机发光显示器件及显示装置
CN109716549B (zh) 包含电子缓冲层和电子传输层的有机电致发光装置
TWI613273B (zh) 有機ｅｌ多色發光裝置
CN116396282A (zh) 用于有机电气元件的化合物、使用所述化合物的有机电气元件及其电子装置
WO2017107749A1 (zh) 一种有机电致发光器件
JP2020509584A (ja) 有機エレクトロルミネッセンスデバイス
US20190013484A1 (en) Organic light-emitting element and display apparatus
WO2013175747A1 (ja) 有機エレクトロルミネッセンス素子
CN117202755A (zh) 有机电元件
US20130240859A1 (en) Tandem organic electroluminescence device
CN104871334A (zh) 有机发光元件
KR101947201B1 (ko) 유기 일렉트로루미네선스 소자
CN105190928A (zh) 白色有机发光器件
TWI537253B (zh) 具有吖啶滿環結構之化合物及有機電致發光元件
CN114478415A (zh) 用于有机电子元件的化合物、使用所述化合物的有机电子元件及其电子装置
CN114207859A (zh) 有机电子器件
KR102407152B1 (ko) 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
CN105489787A (zh) 有机电致发光装置
CN115552651A (zh) 包含用于有机电子元件的化合物的有机电子元件及其电子装置
KR20220062169A (ko) 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
KR20180028179A (ko) 유기전계발광소자용 화합물 및 그를 포함하는 유기전계발광소자
KR102395818B1 (ko) 유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
KR102093186B1 (ko) 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
WO2011033978A1 (ja) 有機エレクトロルミネッセンス素子
CN115777242A (zh) 包含用于有机电子元件的化合物的有机电子元件及其电子装置

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16874744

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2018529288

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20187018243

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2016874744

Country of ref document: EP