WO2017081798A1 - 半導体装置、半導体検出器並びにそれらの製造方法、半導体チップまたは基板 - Google Patents
半導体装置、半導体検出器並びにそれらの製造方法、半導体チップまたは基板 Download PDFInfo
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- WO2017081798A1 WO2017081798A1 PCT/JP2015/081891 JP2015081891W WO2017081798A1 WO 2017081798 A1 WO2017081798 A1 WO 2017081798A1 JP 2015081891 W JP2015081891 W JP 2015081891W WO 2017081798 A1 WO2017081798 A1 WO 2017081798A1
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- H01L2224/81898—Press-fitting, i.e. pushing the parts together and fastening by friction, e.g. by compression of one part against the other
- H01L2224/81899—Press-fitting, i.e. pushing the parts together and fastening by friction, e.g. by compression of one part against the other using resilient parts in the bump connector or in the bonding area
Definitions
- the present invention relates to a semiconductor device, a semiconductor detector, a manufacturing method thereof, a semiconductor chip or a substrate used in the medical field, the industrial field, and the nuclear field.
- flip chip bonding in which the electrodes of the semiconductor chip and the electrodes on the signal readout substrate face each other and are electrically connected via conductive bumps (bump electrodes), has a structure as shown in FIG. is there.
- This structure includes a signal readout substrate 101, a semiconductor chip 102, a pixel electrode 103, a conductive bump 104, and an insulating layer 105.
- the signal readout substrate 101 is a signal readout substrate such as a CMOS integrated circuit in which the pixel electrodes 103 are arranged in a two-dimensional matrix, for example. Note that a substrate represented by a counter substrate or the like may be used instead of the semiconductor chip.
- the pixel electrode 103 is formed on the signal readout substrate 101.
- the conductive bump 104 is formed on the semiconductor chip 102 as a counter pixel electrode at a position facing the pixel electrode 103.
- the flip chip bonding shown in FIG. 7 is used for a photodetector and a radiation detector, detects light and radiation, and takes out a signal obtained by detection.
- flip-chip bonding includes adhesive bonding methods such as conductive resin bonding, which uses organic materials, and anisotropic conductive member bonding.
- the present invention can also be applied to the case where both substrates are used as bonding targets (see, for example, Patent Document 1).
- the conventional flip chip connection has the following problems. That is, if the pitch of the electrodes (corresponding to the pixel pitch) is 50 ⁇ m or more, connection is possible without any problem. However, if the pitch is 20 ⁇ m or less, the bump size becomes fine, and a uniform bump is formed and connected. There is a problem that it becomes difficult.
- the present invention has been made in view of such circumstances, and an object thereof is to provide a semiconductor device, a semiconductor detector, a manufacturing method thereof, a semiconductor chip, or a substrate that can be reliably connected. .
- the present invention has the following configuration.
- a first electrode is formed on one semiconductor chip or substrate
- a second electrode is formed on the other semiconductor chip or substrate at a position facing the first electrode
- a cylindrical electrode is formed on the second electrode, and the first electrode of the one semiconductor chip or substrate and the cylindrical electrode of the other semiconductor chip or substrate are mechanically and electrically connected to each other. It is structured to be connected.
- the cylindrical electrode has a cylindrical shape, the pressure applied to the semiconductor chip or the substrate can be reduced because the bonding area is smaller than that of the conventional bump-shaped bump electrode. Further, since the bonding area is reduced, the diameter of the electrode can be formed with good reproducibility, and the connection can be reliably performed.
- the cylindrical electrode is directed inward so that an inner diameter and an outer diameter on the side connected to the first electrode gradually decrease with respect to an inner diameter and an outer diameter on the second electrode side. Is a curved tube.
- the side of the cylindrical electrode that is connected to the first electrode is slightly crushed inward, so that contact can be made more reliably.
- the second electrode and the cylindrical electrode are integrally formed of the same material.
- the manufacturing process can be simplified, and a reliable electrical connection can be maintained without a problem of separation between the second electrode and the cylindrical electrode.
- a plurality of the second electrodes and the cylindrical electrodes are formed in association with one of the first electrodes.
- the cylindrical electrode when the height of the cylindrical electrode is t and the diameter of the cylindrical electrode is d, the condition of t / d ⁇ 1/2 is satisfied. With this configuration, the cylindrical electrode can be reliably formed.
- a semiconductor detector has the structure of the semiconductor device described above, and any one of the semiconductor chips or the substrate detects light or radiation, and any signal obtained by detection is detected. It is structured to be taken out from the other semiconductor chip or substrate.
- a method of manufacturing a semiconductor device includes a step of forming a second electrode on the other semiconductor chip or substrate at a position opposite to the first electrode formed on one semiconductor chip or substrate.
- a cylindrical electrode forming step including a step of forming a cylindrical electrode on the second electrode.
- the step of forming the second electrode and the step of forming the cylindrical electrode include a step of applying a resist, a step of exposing the resist to form an opening, and the opening The step of depositing a portion to be the second electrode on the bottom surface of the opening and depositing the portion to be the cylindrical electrode on the inner wall of the opening and removing the resist Process.
- the opening is curved inward so that the diameter of the opening connected to the first electrode gradually decreases with respect to the diameter of the second electrode.
- the step of forming the first electrode on the one semiconductor chip or substrate, the first electrode formed on the one semiconductor chip or substrate, and the other semiconductor chip or substrate An electrode contact step of aligning and bonding the electrodes of both the semiconductor chip or the substrate so that the cylindrical electrodes formed on each other are in contact with each other; and the first electrode and the cylindrical electrode At least one is provided with an electrode joining step in which both electrodes are joined to each other mechanically and electrically by applying pressure, heat or ultrasonic energy.
- the vapor deposition is sputter vapor deposition.
- the cylindrical electrode is cylindrical, the diameter of the electrode is also formed with high reproducibility as the junction area is reduced. Connection can be made reliably.
- SEM scanning electron microscope
- FIG. 1 is a schematic cross-sectional view of a semiconductor detector (radiation detector) according to the embodiment.
- FIG. 2 is a specific example of a signal readout substrate and a counter substrate of the semiconductor detector (radiation detector) according to the embodiment.
- FIG. 3 is a schematic cross-sectional view showing a configuration, and FIG. 3 is an equivalent circuit per unit pixel of a signal readout substrate of a semiconductor detector (radiation detector) according to the embodiment.
- the semiconductor detector is used as a radiation detector.
- the counter pixel electrode and the wall bump electrode are not shown.
- the radiation detector includes a signal readout substrate 1 and an opposing substrate 2 disposed so as to face the signal readout substrate 1.
- the signal readout substrate 1 includes each pixel electrode 11 (corresponding to a first electrode) arranged in a two-dimensional matrix and a pixel arrangement layer for arranging them.
- the counter substrate 2 is formed by stacking a common electrode 21 and a photoelectric conversion semiconductor layer 23 in this order. The surface of the counter substrate 2 on the photoelectric conversion semiconductor layer 23 side is electrically connected to each pixel electrode 11 of the signal readout substrate 1 for each pixel.
- the pixel electrode 11 and the counter substrate 2 of the signal readout substrate 1 are formed by a counter pixel electrode 33 (corresponding to a second electrode) and a wall bump electrode 34 (corresponding to a cylindrical electrode) formed by sputter deposition described later.
- the photoelectric conversion semiconductor layer 23 is bonded to face each other.
- the signal readout substrate 1 is formed of a glass substrate. On the signal readout substrate 1, in addition to the pixel electrode 11 described above, a pixel capacitor 12 and a switching transistor 13 are formed in a two-dimensional matrix, and a scanning line 14 (see FIG. 3) and a signal readout line 15 (see FIG. 3). Pattern) is formed vertically and horizontally in the row and column directions.
- the reference electrode 12 a of the pixel capacitor 12 and the gate electrode 13 a of the switching transistor 13 are stacked on the signal readout substrate 1 and covered with an interlayer insulating film 31.
- the capacitor electrode 12b of the pixel capacitor 12 is stacked on the interlayer insulating film 31 so as to face the reference electrode 12a with the interlayer insulating film 31 interposed therebetween, and the source electrode 13b and the drain electrode 13c of the switching transistor 13 are stacked. Then, except for the portion where the pixel electrode 11 exists, it is covered with the sealing material 32.
- the capacitor electrode 12b and the source electrode 13b are electrically connected to each other.
- the capacitor electrode 12b and the source electrode 13b may be integrally formed simultaneously.
- the reference electrode 13a is grounded.
- plasma SiN is used for the interlayer insulating film 31.
- the scanning line 14 is electrically connected to the gate electrode 13a of the switching transistor 13 (see FIG. 2), and the signal readout line 15 is connected to the drain electrode 13c of the switching transistor 13 (see FIG. 2). ) Is electrically connected.
- the scanning line 14 extends in the row direction of each pixel, and the signal readout line 15 extends in the column direction of each pixel.
- the scanning line 14 and the signal readout line 15 are orthogonal to each other.
- Reference numeral 23 in FIG. 3 is an equivalent circuit of the photoelectric conversion semiconductor layer.
- the pixel capacitor 12, the switching transistor 13, and the interlayer insulating film 31 including the scanning line 14 and the signal readout line 15 are patterned as a pixel array layer on the surface of the signal readout substrate 1 using a semiconductor thin film manufacturing technique or a fine processing technique. Is formed.
- the photoelectric conversion semiconductor layer 23 is formed of CdTe (cadmium telluride), ZnTe (zinc telluride), CdZnTe (cadmium zinc telluride), GaAs (gallium arsenide), or the like.
- the pixel electrode 11 of the signal readout substrate 1 and the photoelectric conversion semiconductor layer 23 of the counter substrate 2 are bonded to face each other.
- Au gold
- Cu copper
- Al aluminum
- Ni nickel
- In indium
- Pb lead
- Zn zinc
- the pixel electrode 11 of the signal readout substrate 1 and the photoelectric conversion semiconductor layer 23 of the counter substrate 2 Adhere to each other.
- each pixel electrode 11 corresponds to each pixel, by converting the signal charges read corresponding to the pixel electrode 11 into pixel values, the pixel values corresponding to the pixels are arranged two-dimensionally.
- a two-dimensional image (a radiation image having a two-dimensional distribution) can be acquired.
- FIG. 4 is a schematic cross-sectional view illustrating a process of forming the counter pixel electrode and the wall bump electrode according to the embodiment. Note that illustration of the photoelectric conversion semiconductor layer is omitted in FIG.
- FIG. 4 shows a process in the case of forming a wall bump electrode of Au (gold) having a diameter: ⁇ 3 ⁇ m and a height: 3 ⁇ m.
- a resist R having a thickness of 3 ⁇ m is applied to the common electrode 21 (hereinafter, collectively referred to as “support substrate”) on which the photoelectric conversion semiconductor layer 23 (see FIGS. 1 and 2) is formed. Apply.
- the resist R is exposed to form an opening O having a diameter of ⁇ 3 ⁇ m.
- a resist is selected so that the upper part of the opening O is narrower than the lower part.
- the counter pixel electrode 33 is deposited on the bottom surface in O, and the others are not deposited on the bottom surface in the opening O, and most of them are attached to the inner wall of the opening O to form side walls.
- the cylindrical electrode of the side wall is formed on the counter pixel electrode 33 so as to adhere to the inner wall of the opening O.
- this cylindrical electrode is referred to as a “wall bump electrode”.
- an Au layer M is formed on the resist R as shown in FIG.
- the shape of the wall bump electrode 34 shown in FIG. For example, when the shape of the opening O is substantially cylindrical, the wall bump electrode 34 is also substantially cylindrical, and when the shape of the opening O is substantially rectangular, the wall bump electrode 34 is also substantially rectangular. It becomes.
- the shapes of the opening O and the wall bump electrode 34 are not particularly limited.
- the shape of the opening O is directed inward so that the diameter of the side connected to the pixel electrode 11 (upper side in the figure) gradually decreases with respect to the diameter of the counter pixel electrode 33 side (lower side in the figure). It is curved. That is, the opening O is narrower on the upper side than on the lower side. Therefore, the wall bump electrode 34 is formed in a cylindrical shape curved inward so that the inner diameter and outer diameter on the side connected to the pixel electrode 11 gradually decrease with respect to the inner diameter and outer diameter on the counter pixel electrode 33 side. Is done.
- a radiation detector having a structure as shown in FIG. 4D is formed. That is, the counter pixel electrode 33 and the wall bump electrode 34 are integrally formed of Au which is the same material. As shown in FIG. 1, the pixel electrode 11 of the signal readout substrate 1 and the photoelectric conversion semiconductor layer 23 of the counter substrate 2 are bonded to each other so that the pixel electrode 11 of the signal readout substrate 1 as shown in FIG. 1 is bonded. Thus, a radiation detector having a structure in which the wall bump electrode 34 of the counter substrate 2 is mechanically and electrically connected to each other is formed.
- both electrodes are applied by applying pressure, heat, or ultrasonic energy to at least one of the pixel electrode 11 and the wall bump electrode 34. 11 and 34 are joined together and mechanically and electrically connected.
- the wall bump electrode 34 is slightly crushed inward on the side in contact with the pixel electrode 11, so that the inner wall of the cylinder is on the inner side. It becomes the structure bent in.
- the wall bump electrodes 34 as shown in FIG. 4D can be formed uniformly. Further, the height of the wall bump electrode 34 is substantially determined by the resist thickness.
- FIG. 5 shows a scanning electron microscope (SEM: Scanning Electron Microscope) photograph in which an Au wall bump electrode having a pitch of 20 ⁇ m, an opening diameter of 3 ⁇ m, and a height of 3 ⁇ m is actually formed.
- 5A is a plane SEM having a magnification of 500 times
- FIG. 5B is a plane SEM having a magnification of 4000 times
- FIG. 5C is a cross-sectional SEM having a magnification of 7000 times.
- the wall bump electrode is formed with good reproducibility, and as described above, the height of the wall bump electrode is almost determined by the resist thickness. In the case of FIG. 5, the height variation is about 0.2 ⁇ m. It is.
- Examples of the material of the wall bump electrode including the counter pixel electrode include Cu, Al, Ni and the like as described above in addition to Au described in FIG.
- a relatively soft semiconductor such as CdTe, In, Pb, Zn, etc. as described above can be used as soft bump materials.
- the aspect ratio t / d preferably satisfies the condition of t / d ⁇ 1/2.
- the resist thickness ( ⁇ bump height) t is low, or the bump diameter d is large, and it is difficult to maintain the shape of the wall bump electrode. Accordingly, if the condition of t / d ⁇ 1/2 is satisfied, the higher t / d is more preferable. However, if t / d is too high, the wall bump electrode is not formed on the counter pixel electrode, or the counter pixel electrode itself is not formed.
- the resist thickness ( ⁇ bump height) t is not too high.
- the above range is more preferable. Note that if the condition of t / d ⁇ 1/2 is satisfied, the specific range of a suitable resist thickness ( ⁇ bump height) t varies depending on the size of the bump diameter d.
- the wall bump electrode 34 is cylindrical, so that the bonding area is smaller than that of the conventional bump-shaped bump electrode, so that the semiconductor chip or the substrate In this embodiment, the pressure applied to the signal readout substrate 1 can be reduced. Further, since the bonding area is reduced, the diameter of the electrode can be formed with good reproducibility, and the connection can be reliably performed.
- the side of the wall bump electrode 34 that is in contact with the pixel electrode 11 is slightly crushed inward, so that the contact can be made more reliably.
- the counter pixel electrode 33 and the wall bump electrode 34 are integrally formed of the same material. In this case, the manufacturing process can be simplified, and a reliable electrical connection can be maintained without a problem of peeling between the counter pixel electrode 33 and the wall bump electrode 34.
- the radiation detector according to the present embodiment has the structure shown in FIG. 1 described above, and one of the semiconductor chips or the substrate (the counter substrate 2 in the present embodiment) detects and detects the radiation.
- the obtained signal is structured so as to be taken out from one of the other semiconductor chips or the substrate (in this embodiment, the signal reading substrate 1).
- the pixel electrode 11, the counter pixel electrode 33, and the wall bump electrode 34 are arranged one-dimensionally or two-dimensionally (two-dimensional in this embodiment) so that the pixel pitch is less than 50 ⁇ m (in this embodiment, 20 ⁇ m).
- one counter pixel electrode 33 and a wall bump electrode 34 are formed in one pixel electrode.
- the manufacturing method of the radiation detector in the process of FIG. 4 corresponding to the cylindrical electrode forming process, it is formed on one semiconductor chip or the substrate (in this embodiment, the signal readout substrate 1).
- a plurality of pixel electrodes 11 are formed on one semiconductor chip or substrate (signal reading substrate 1 in the present embodiment).
- the electrode contact step the pixel electrode 11 formed on one semiconductor chip or substrate (signal readout substrate 1) and the wall bump electrode 34 formed on the other semiconductor chip or substrate (counter substrate 2 in this embodiment).
- the electrodes (electrodes 11 and 34 in this embodiment) of both semiconductor chips or substrates (substrates 1 and 2 in this embodiment) are aligned and bonded together.
- the electrode joining step by applying pressure, heat or ultrasonic energy to at least one of the pixel electrode 11 and the wall bump electrode 34, both the electrodes 11 and 34 are joined to each other and mechanical / electrical. Connect.
- the present invention is not limited to the above embodiment, and can be modified as follows.
- the semiconductor detector is used as a radiation detector, but may be used as a photodetector for detecting light.
- one of the semiconductor chips or the substrate detects light and is applied to a photodetector having a structure in which a signal obtained by the detection is extracted from the other semiconductor chip or substrate.
- the semiconductor device is used for a radiation detector, but it is not necessarily used for a semiconductor detector such as a radiation detector or a photodetector.
- a semiconductor detector such as a radiation detector or a photodetector.
- applications other than semiconductor detectors such as the above-described flip chip bonding may be used.
- the target for forming the counter pixel electrode and the cylindrical electrode (wall bump electrode) is the substrate (the counter substrate 2 in the embodiment), and the target for forming the pixel electrode is the substrate (the embodiment).
- a semiconductor chip may be used as a bonding target instead of the substrate.
- one of the bonding targets may be a substrate and the other of the bonding targets may be a semiconductor chip.
- the semiconductor chip is made of a compound semiconductor, and the material of the compound semiconductor includes CdTe, ZnTe, CdZnTe, GaAs, etc., as in the photoelectric conversion semiconductor layer of the above-described embodiment.
- the semiconductor chip / substrate forming the counter pixel electrode and the cylindrical electrode detects radiation and light, and forms a pixel electrode from the detected signal. Although it was taken out from the semiconductor chip / substrate, it may be reversed. In other words, the semiconductor chip / substrate forming the pixel electrode detects radiation and light, and signals detected are taken out from the semiconductor chip / substrate forming the counter pixel electrode and the cylindrical electrode (wall bump electrode). Also good.
- the pixel electrode, the counter pixel electrode, and the cylindrical electrode (wall bump electrode) are two-dimensionally arranged so that the pixel pitch is less than 50 ⁇ m (in the embodiment, 20 ⁇ m).
- the present invention can also be applied to a semiconductor device having a structure in which a pixel electrode, a counter pixel electrode, and a cylindrical electrode (wall bump electrode) are arranged one-dimensionally.
- one counter pixel electrode and a cylindrical electrode are formed in one pixel electrode.
- a plurality of pixels are provided in one pixel electrode.
- the counter pixel electrode and the cylindrical electrode (wall bump electrode) may be formed. That is, a plurality of second electrodes (opposite pixel electrode 33 in the embodiment) and cylindrical electrodes (wall bump electrodes) are formed in association with one first electrode (pixel electrode 11 in the embodiment).
- An example in which three opposing pixel electrodes and wall bump electrodes are formed in one pixel electrode is shown in the schematic plan view of FIG.
- the counter pixel electrode and the cylindrical electrode are formed by sputtering vapor deposition, but the wall bump electrode may be formed by vapor deposition other than sputtering vapor deposition.
- the wall bump electrode may be formed by vapor deposition other than sputtering vapor deposition.
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Abstract
Description
本発明の好ましい実施形態による半導体装置は、一方の半導体チップまたは基板に第1の電極が形成され、他方の半導体チップまたは基板に前記第1の電極に対向する位置に第2の電極、および前記第2の電極の上に筒状電極が形成され、前記一方の半導体チップまたは基板の前記第1の電極と、前記他方の半導体チップまたは基板の前記筒状電極とが互いに機械的・電気的に接続されるよう構造されている。
11 … 画素電極
2 … 対向基板
33 … 対向画素電極
34 … ウォールバンプ電極
Claims (12)
- 一方の半導体チップまたは基板に第1の電極が形成され、
他方の半導体チップまたは基板に前記第1の電極に対向する位置に第2の電極、および前記第2の電極の上に筒状電極が形成され、
前記一方の半導体チップまたは基板の前記第1の電極と、前記他方の半導体チップまたは基板の前記筒状電極とが互いに機械的・電気的に接続されるよう構造されている、半導体装置。 - 請求項1に記載の半導体装置において、
前記筒状電極は、前記第1の電極に接続される側の内径および外径が、前記第2の電極側の内径および外径に対して漸減するように内側に向けて湾曲した筒状である、半導体装置。 - 請求項1に記載の半導体装置において、
前記第2の電極および前記筒状電極が同一材料により一体形成されている、半導体装置。 - 請求項1に記載の半導体装置において、
1つの前記第1の電極に対応付けて、複数の前記第2の電極および前記筒状電極が形成される、半導体装置。 - 請求項1に記載の半導体装置において、
前記筒状電極の高さをt、前記筒状電極の径をdとしたとき、t/d≧1/2の条件を満足する、半導体装置。 - 請求項1から請求項5のいずれかに記載の半導体装置の構造を有し、
いずれか一方の前記半導体チップまたは基板が、光または放射線を検出し、検出されて得られた信号を、いずれか他方の前記半導体チップまたは基板から取り出すよう構造されている、半導体検出器。 - 一方の半導体チップまたは基板に形成された第1の電極に対向する位置に、他方の半導体チップまたは基板に第2の電極を形成する工程と、前記第2の電極の上に筒状電極を形成する工程とを含む筒状電極形成工程
を備える、半導体装置の製造方法。 - 請求項7に記載の半導体装置の製造方法において、
前記第2の電極を形成する工程および前記筒状電極を形成する工程は、
レジストを塗布する工程と、
前記レジストに露光して開口部を形成する工程と、
前記開口部に蒸着を行うことにより、前記開口部の底面に前記第2の電極となる部分が堆積され、前記開口部の内壁に前記筒状電極となる部分が堆積される工程と、
前記レジストを除去する工程とを含む、半導体装置の製造方法。 - 請求項8に記載の半導体装置の製造方法において、
前記開口部が、前記第1の電極に接続される側の径が、前記第2の電極側の径に対して漸減するように内側に向けて湾曲している、半導体装置の製造方法。 - 請求項7に記載の半導体装置の製造方法において、
前記一方の半導体チップまたは基板に前記第1の電極を形成する工程と、
前記一方の半導体チップまたは基板に形成された前記第1の電極と、前記他方の半導体チップまたは基板に形成された前記筒状電極とが互いに接触するように、両方の前記半導体チップまたは基板の各電極の位置合わせを行って貼り合わせる電極接触工程と、
前記第1の電極および前記筒状電極の少なくとも一方に、圧力、熱または超音波のエネルギーを加えることにより、両方の電極を互いに接合して機械的・電気的に接続する電極接合工程と
を備える、半導体装置の製造方法。 - 請求項8に記載の半導体装置の製造方法において、
前記蒸着がスパッタ蒸着である、半導体装置の製造方法。 - 第1の電極が形成された他の半導体チップまたは基板に接続される、半導体チップまたは基板であって、
前記前記第1の電極に対向する位置に第2の電極が形成され、
前記第2の電極の上に筒状電極がさらに形成されており、
前記筒状電極が、前記第1の電極と機械的・電気的に接続されるよう構造されている、半導体チップまたは基板。
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