WO2016101773A1 - 一种聚丙烯酸共聚物乳液、有机无机复合防水涂层及其制备方法、防水卷材 - Google Patents
一种聚丙烯酸共聚物乳液、有机无机复合防水涂层及其制备方法、防水卷材 Download PDFInfo
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- WO2016101773A1 WO2016101773A1 PCT/CN2015/096120 CN2015096120W WO2016101773A1 WO 2016101773 A1 WO2016101773 A1 WO 2016101773A1 CN 2015096120 W CN2015096120 W CN 2015096120W WO 2016101773 A1 WO2016101773 A1 WO 2016101773A1
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- 239000002131 composite material Substances 0.000 title claims abstract description 50
- 229920002125 Sokalan® Polymers 0.000 title claims abstract description 38
- 239000004584 polyacrylic acid Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title abstract description 19
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- 239000000853 adhesive Substances 0.000 claims abstract description 29
- 230000001070 adhesive effect Effects 0.000 claims abstract description 29
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- 239000002313 adhesive film Substances 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 118
- 239000010954 inorganic particle Substances 0.000 claims description 95
- 239000002245 particle Substances 0.000 claims description 69
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 62
- 229920000642 polymer Polymers 0.000 claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
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- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 19
- 239000006184 cosolvent Substances 0.000 claims description 19
- 239000002270 dispersing agent Substances 0.000 claims description 19
- 239000003755 preservative agent Substances 0.000 claims description 19
- 230000002335 preservative effect Effects 0.000 claims description 19
- 239000000080 wetting agent Substances 0.000 claims description 19
- 239000002518 antifoaming agent Substances 0.000 claims description 18
- 239000005871 repellent Substances 0.000 claims description 18
- 239000000049 pigment Substances 0.000 claims description 17
- 238000009826 distribution Methods 0.000 claims description 13
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 11
- 238000004078 waterproofing Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003429 antifungal agent Substances 0.000 claims description 9
- 229940121375 antifungal agent Drugs 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- 229910001570 bauxite Inorganic materials 0.000 claims description 7
- 230000002902 bimodal effect Effects 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 5
- 235000019362 perlite Nutrition 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 4
- -1 styrene-ethylene-butylene-styrene Chemical class 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 230000001680 brushing effect Effects 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229920005549 butyl rubber Polymers 0.000 claims description 3
- 229910021532 Calcite Inorganic materials 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 239000010455 vermiculite Substances 0.000 claims description 2
- 229910052902 vermiculite Inorganic materials 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000005062 Polybutadiene Substances 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 239000004567 concrete Substances 0.000 abstract description 18
- 239000004568 cement Substances 0.000 abstract description 7
- 238000006703 hydration reaction Methods 0.000 abstract description 5
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- 239000011707 mineral Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 6
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
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- 239000011247 coating layer Substances 0.000 description 4
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 4
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- 230000002940 repellent Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
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- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
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- 239000004408 titanium dioxide Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 206010013647 Drowning Diseases 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
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- 150000007942 carboxylates Chemical class 0.000 description 1
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- 239000013530 defoamer Substances 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
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- 239000010881 fly ash Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4501—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with preformed sheet-like elements
- C04B41/4503—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with preformed sheet-like elements having an adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
Definitions
- the invention belongs to the technical field of waterproof coil materials, and particularly relates to a polyacrylic acid copolymer emulsion, an organic-inorganic composite waterproof coating, a preparation method thereof and a waterproof coiled material.
- the polymer self-adhesive film waterproofing membrane (also called waterproof membrane) is a multi-layer composite waterproofing membrane, which is used for the post-casting concrete, that is, the structural concrete is fully viscous and waterproof.
- a typical polymer self-adhesive film waterproofing membrane comprises a main waterproof layer (also referred to as a main waterproof sheet) and a pressure-sensitive adhesive layer. Among them, the pressure-sensitive adhesive layer can form a complete continuous bond with the post-cast concrete after it is cured.
- the commercially available pressure-sensitive adhesive layer further comprises a peelable separator for preventing adhesion and separation of the pressure-sensitive adhesive layer when the waterproof web is rolled up
- the membrane must be removed before the next step of construction, thus causing some waste.
- Another commercially available waterproofing membrane is a waterproof membrane with a particle coating, wherein the particles are usually silica, hydrated white cement particles, and the waterproof membrane has the disadvantage that it often drops particles in the application, which is easy to cause The concrete is not firmly bonded, resulting in water-repellent layer water-repellent and waterproof failure.
- a prior art Chinese patent CN01814107.2 discloses a particle coating bonding system for casting a hydratable cement composition and a manufacturing method thereof, the coated article having at least one body for carrying a surface of the particle, the surface comprising a pressure sensitive adhesive or elastomer, and the particles are inorganic particles reactive with a hydroxide solution formed by a hydration reaction of concrete or mortar, or the particles comprise a coagulant effective to increase the rate of hydration reaction,
- the inorganic particles include (a) alumina trihydrate; (b) silica; (c) fly ash; (d) blast furnace slag; (e) fumed silica; (f) alkali or alkaline earth metal nitrite , nitrates, halides, sulfates, hydroxides, carboxylates, a silicate, or an aluminate, or a mixture thereof.
- Chinese patent CN201080063366.3 discloses a waterproof membrane which is adhered to and joined with concrete.
- the waterproofing membrane comprises a flexible carrier sheet, a pressure sensitive adhesive, and reflective particles on the surface of the adhesive.
- the average diameter of the reflective particles should be equal to or greater than the thickness of the pressure sensitive adhesive.
- the reflective particles are preferably ground white cement or ground hydrated white cement.
- the waterproofing membrane does not have a removable release layer that is typically used to prevent the adhesive portion of the waterproofing membrane from sticking to the carrier sheet or other portions of the film when the film is rolled up.
- the waterproof membrane is easy to lose particles in the application, and the concrete is not firmly bonded to the concrete soil, which is liable to cause water leakage problem of the waterproof layer.
- the invention aims at the problem that the existing waterproof membrane is easy to lose particles in the application, and provides an organic-inorganic composite waterproof coating, a preparation method thereof and a waterproof coiled material.
- the polyacrylic acid copolymer emulsion comprises the following components in parts by weight: 19-26 parts of water, 0.5-5 parts of a cosolvent, 0.1-0.5 parts of a dispersing agent, 0.1-0.5 parts of a wetting agent, and acrylic acid. 28-30 parts of emulsion, 0.1-1 part of film-forming auxiliary agent, 0.2-0.3 part of preservative, 0.5-0.6 part of silane coupling agent, 0.5-0.6 part of ultraviolet absorber, 40-45 parts of pigment, anti-mold agent 0.1- 0.5 parts, 0.1-0.2 parts of antifoaming agent, 0.1-0.8 parts of leveling agent.
- the polyacrylic acid copolymer emulsion comprises the following components in parts by weight:
- the polyacrylic acid copolymer emulsion further comprises one or more of a polyethylene vinyl acetate copolymer and a styrene butadiene rubber.
- the invention also provides a preparation method of the above polyacrylic acid copolymer emulsion, comprising the following steps:
- the invention also provides an organic-inorganic composite waterproof coating comprising a pressure-sensitive adhesive layer composed of a pressure-sensitive adhesive sequentially formed on a substrate from bottom to top, an inorganic particle layer composed of inorganic particles, a polymer layer,
- the polymer layer is formed by curing a polyacrylic acid copolymer emulsion, and the polyacrylic acid copolymer emulsion comprises the following components in parts by weight:
- the substrate comprises a main waterproof sheet.
- the inorganic particles in the inorganic particle layer cover the pressure-sensitive adhesive layer
- the cover ratio is 70-100%
- the thickness of the polymer layer is 1-100 ⁇ m
- the particle size of the inorganic particles is 500-700 ⁇ m.
- the inorganic particles in the inorganic particle layer have a coverage of 85-95% for the pressure-sensitive adhesive layer, the polymer layer has a thickness of 25-100 ⁇ m, and the inorganic particles have a particle diameter of 500 or 700. Micron.
- the inorganic particles are selected from the group consisting of calcite, quartz, zeolite, vermiculite, bauxite, shale, feldspar, perlite, silicate and aluminate.
- the copolymer emulsion further comprises one or more of a polyethylene vinyl acetate copolymer and a styrene butadiene rubber.
- the pressure sensitive adhesive is selected from the group consisting of a butyl rubber based adhesive, a polyisobutylene based adhesive, a butyl based adhesive, an acrylic based adhesive, and a styrene-isoprene-styrene based adhesive.
- a butyl rubber based adhesive a polyisobutylene based adhesive, a butyl based adhesive, an acrylic based adhesive, and a styrene-isoprene-styrene based adhesive.
- a styrene-ethylene-butylene-styrene based adhesive a styrene-butadiene-styrene based adhesive
- a styrene-butadiene rubber based adhesive a styrene-butadiene rubber based adhesive.
- the pressure-sensitive adhesive layer has an average thickness ranging from 50 to 500 ⁇ m;
- the inorganic particles have a particle diameter of 100-1000 micrometers, and the particle size distribution of the inorganic particles has a bimodal distribution, and the volume percentage accounts for 30-50% of the difference between the inorganic particle diameter and the thickness of the pressure-sensitive adhesive layer within 25%. , the volume percentage accounts for 50-70% of the inorganic particle diameter is at least 25% larger than the thickness of the pressure-sensitive adhesive layer, and the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 70-100%;
- the polymer layer has a thickness of from 1 to 100 ⁇ m, and the polymer layer has a coverage of the inorganic particle layer of from 10 to 50%.
- the pressure-sensitive adhesive layer has a thickness ranging from 150 to 350 ⁇ m;
- the inorganic particles have a particle diameter of 200-700 ⁇ m; the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 85-95%;
- the coverage of the polymer layer on the surface of the inorganic particles is 25-35%.
- the pressure-sensitive adhesive layer has a thickness ranging from 200 to 325 ⁇ m.
- the inorganic particles are selected from the group consisting of bauxite particles, and the two peaks of the particle size distribution of the bauxite particles are 250 micrometers and 480 micrometers, respectively;
- the inorganic particles are selected from shale particles, and the two peaks of the particle size distribution of the shale particles are 320 microns and 650 microns, respectively.
- the invention also provides a preparation method of an organic-inorganic composite waterproof coating, comprising the following steps:
- the pressure sensitive adhesive is heated at 75-90 ° C to a viscosity of 25000-40000 cps, applied to the substrate to form a pressure-sensitive adhesive layer;
- the inorganic particles are sprinkled on the pressure-sensitive adhesive layer, and then coated by a pressure roller, and the excess inorganic particles are removed by one or more methods of gravity, vacuum and brushing to form an inorganic particle layer;
- the polyacrylic acid copolymer emulsion is coated on the surface of the inorganic particles and dried at a temperature of 60 to 80 ° C for 1-2 minutes to obtain a polymer layer; thus, the preparation of the organic-inorganic composite water-repellent coating layer is completed.
- the polyacrylic acid copolymer emulsion comprises the following components in parts by weight:
- the invention also provides a polymer self-adhesive film waterproofing membrane, comprising a substrate and the above-mentioned organic-inorganic composite waterproof coating, wherein the organic-inorganic composite waterproof coating comprises a bottom-to-surface sequential formation on a substrate a pressure-sensitive adhesive layer composed of a pressure-sensitive adhesive, an inorganic particle layer composed of inorganic particles, a polymer layer,
- the polymer layer is formed by curing a polyacrylic acid copolymer emulsion, and the polyacrylic acid copolymer emulsion comprises the following components in parts by weight:
- the inorganic composite waterproof coating of the invention adopts a method of compounding organic and inorganic particles, wherein the organic coating (polymer layer) locks the inorganic particles, and prevents the inorganic particles from being granulated in a long-term application, and the partially exposed inorganic particles can also participate.
- Cement hydration reaction Increasing the bonding strength with the post-cast concrete; at the same time, the hybridization of the polymer and the inorganic particles can significantly improve the environmental adaptability and weather resistance; in addition, the inorganic composite waterproof coating of the present invention does not require a barrier layer, and the anti-adhesive separator is omitted. Paper, reducing waste and environmental pollution at the construction site.
- the organic-inorganic composite waterproof coating of the invention is used for the polymer self-adhesive film waterproofing membrane, which can make the coil material properly exposed before pouring concrete, and provides a non-stick surface for the construction workers to walk.
- the adhesive strength of the organic-inorganic composite waterproof coating of the present invention can still reach 2.0 N/mm or more after being placed outdoors for 8 weeks.
- Example 1 is a picture of a particle of a water-repellent coating of Example 1 which is not subjected to an organic coating;
- Example 2 is a microscopic picture after the water-repellent coating of Example 1 is covered with organic matter.
- the "acrylic emulsion" in the present invention means an emulsion formed by dispersing a polyacrylic substance in water, and a commercially available product can be used.
- the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 70-100
- the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 70-100
- one layer of inorganic particles is uniformly spread on the pressure-sensitive adhesive layer, but when the amount of the inorganic particles is insufficient to completely cover the surface of the pressure-sensitive adhesive layer
- the coverage of the polymer layer on the surface of the inorganic particles is 25-35
- the polymer layer is formed on the inorganic particles, but since the particle size of the inorganic particles may be larger than the polymer layer, some inorganic particles may be exposed. Polymer layer.
- This embodiment provides an organic-inorganic composite waterproof coating, and the preparation method is as follows:
- the butyl rubber-based adhesive of TOP BEST-KJ FLEX model produced by Shanghai Kejian Chemical Co., Ltd. is warmed at 75 ° C to make the viscosity at 40,000 cps.
- the pressure-sensitive adhesive layer has a thickness of 400 ⁇ m;
- the polyacrylic acid copolymer emulsion is then uniformly coated on the surface of the inorganic particle layer by spraying, and dried in a drying apparatus at 60 ° C for 2 minutes, and the coating thickness is 0.05-0.1 mm.
- the polymer layer was obtained; thus, the preparation of the organic-inorganic composite waterproof coating was completed.
- the inorganic composite waterproof coating of the present embodiment adopts a method of compounding organic and inorganic particles, wherein the organic coating (polymer layer) locks the inorganic particles, preventing the inorganic particles from being granulated in a long-term application, and grading the size of the inorganic particles. It has a bimodal distribution, which can effectively solve the problem of drowning in underground engineering. Inorganic particles can also participate in cement hydration reaction and increase the bonding strength with post-cast concrete. At the same time, the hybridization of polymer and inorganic particles can significantly improve the environment.
- the inorganic composite waterproof coating of the present invention does not require a barrier layer, eliminating the release barrier film/paper, reducing waste and environmental pollution at the construction site.
- the organic-inorganic composite waterproof coating of the invention is used for the polymer self-adhesive film waterproofing membrane, which can make the coil material properly exposed before pouring concrete, and provides a non-stick surface for the construction workers to walk.
- the adhesive strength of the organic-inorganic composite waterproof coating of the present invention can still reach 2.0 N/mm or more after being placed outdoors for 8 weeks.
- This embodiment provides an organic-inorganic composite waterproof coating, and the preparation method is as follows:
- the temperature of the P073-9 type styrene-ethylene-butylene-styrene (SEBS) based adhesive produced by Shanghai Shisheng Technology Co., Ltd. is heated at 90 ° C to make the viscosity at 25000 cps.
- SEBS styrene-ethylene-butylene-styrene
- the polyacrylic acid copolymer emulsion is then uniformly coated on the surface of the inorganic particle layer by brush coating, and dried in a drying apparatus at 80 ° C for 1 minute, and the coating thickness is 0.025-0.1 mm. A polymer layer is obtained; thus, the preparation of the organic-inorganic composite waterproof coating is completed.
- the polyisobutylene-based adhesive temperature is heated at 80 ° C, so that the viscosity is 30,000 cps, applied to the main waterproof sheet to form a pressure-sensitive adhesive layer, the thickness of the pressure-sensitive adhesive layer is 500 microns;
- the polyethylene vinyl acetate copolymer emulsion is then uniformly coated on the surface of the inorganic particle layer by brush coating, and dried in a drying apparatus at 70 ° C for 2 minutes, and the coating thickness is 0.05. -0.1mm.
- the polyacrylic acid copolymer emulsion, the polyvinyl acetate copolymer and the styrene-butadiene rubber are mixed, uniformly coated on the surface of the inorganic particles by brush coating, and dried in a drying apparatus at 70 ° C, and dried.
- the time is 1 minute and the coating thickness is 0.05-0.1 mm, a polymer layer is obtained; thus, the preparation of the organic-inorganic composite waterproof coating is completed.
- Example 1 and Example 2 The organic-inorganic composite water-repellent coating layers of Example 1 and Example 2 were poured and concrete were poured, and the peel strength test was performed after being placed outdoors for 4 weeks and 8 weeks, respectively.
- the water repellent coatings of Comparative Example 1 and Comparative Example 2 were prepared, wherein the water repellent coating of Comparative Example 1 was prepared in a similar manner to Example 1, except that the water repellent coating of Comparative Example 1 was not coated with a polymer.
- the preparation method of the water-repellent coating of Comparative Example 2 was similar to that of Example 2 except that the water-repellent coating of Comparative Example 2 was not coated with a polymer layer.
- the organic-inorganic composite water-repellent coating layers of Comparative Examples 1 and 2 were subjected to concrete post-casting as described above, and then subjected to peel strength test.
- the waterproof coating after the composite of the shale particle layer and the polymer layer and the waterproof coating after the composite of the perlite particle layer and the polymer layer can still have a peeling strength of 2.0N after being placed outdoors for 8 weeks. Above /mm, it can be seen that the hybridization of the polymer layer and the inorganic particles significantly improves the environmental adaptability and weather resistance of the organic-inorganic composite waterproof coating.
- Example 1 The properties of the organic-inorganic composite water-repellent coating layer coated by the method of Example 1 using the polyacrylic acid copolymer emulsion prepared in Example 5 or 6 were similar to those in Example 1.
- the embodiment provides an organic-inorganic composite waterproof coating, and the preparation method thereof is similar to that in the first embodiment.
- the difference between the embodiment 7 and the embodiment 1 is as follows:
- the pressure-sensitive adhesive layer has an average thickness ranging from 150 ⁇ m;
- the particle size distribution of the inorganic particles is bimodal, the particle size of the 30% inorganic particles is close to 150 microns, the particle size of the 70% inorganic particles is 200, and the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 70%;
- the thickness of the polymer layer was 1 micrometer, and the coverage of the polymer layer to the inorganic particle layer was 10%.
- the embodiment provides an organic-inorganic composite waterproof coating, and the preparation method thereof is similar to that in the first embodiment.
- the difference between the embodiment 8 and the embodiment 1 is:
- the pressure-sensitive adhesive layer has an average thickness ranging from 350 ⁇ m;
- the particle size distribution of the inorganic particles is bimodal, 50% inorganic particle diameter is 350 microns, 50% inorganic particle diameter is 700 microns, and the coverage of the inorganic particles to the pressure-sensitive adhesive layer is 100%;
- the thickness of the polymer layer was 100 ⁇ m, and the coverage of the polymer layer to the inorganic particle layer was 50%.
- the embodiment provides an organic-inorganic composite waterproof coating, and the preparation method thereof is similar to that in the first embodiment.
- the difference between the embodiment 9 and the embodiment 1 is that:
- the inorganic particles are selected from the group consisting of bauxite particles having bimodal distribution particle sizes of 250 microns and 480 microns, respectively.
- the embodiment provides an organic-inorganic composite waterproof coating, and the preparation method thereof is similar to that in the first embodiment.
- the difference between the embodiment 10 and the embodiment 1 is that:
- the inorganic particles are selected from shale particles, and the shale particles have a bimodal distribution particle size of 320 microns and 650 microns, respectively.
- the specific embodiments of the above embodiments may also be subjected to many changes; for example, the specific parts by weight of each raw material of the polyacrylic acid copolymer emulsion may be adjusted and changed, or the specific type or model of the pressure-sensitive adhesive may be adjusted according to actual conditions.
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Abstract
Description
Claims (15)
- 一种聚丙烯酸共聚物乳液,其特征在于,按重量份数,包括以下组分:水10-50份、助溶剂0-60份、分散剂0-5份、润湿剂0-5份、丙烯酸类乳液5-50份、成膜助剂0-5份、防腐剂0-5份、硅烷偶联剂0-5份、紫外吸收剂0-1.0份、颜料5-70份、防霉剂0-5份、消泡剂0-2份、流平剂0-5份。
- 根据权利要求1所述的聚丙烯酸共聚物乳液,其特征在于,按重量份数,包括以下组分:水19-26份、助溶剂0.5-5份、分散剂0.1-0.5份、润湿剂0.1-0.5份、丙烯酸类乳液28-30份、成膜助剂0.1-1份、防腐剂0.2-0.3份、硅烷偶联剂0.5-0.6份、紫外吸收剂0.5-0.6份、颜料40-45份、防霉剂0.1-0.5份、消泡剂0.1-0.2份、流平剂0.1-0.8份。
- 根据权利要求2所述的聚丙烯酸共聚物乳液,其特征在于,按重量份数,包括以下组分:水19份、助溶剂1.5份、分散剂0.5份、润湿剂0.2份、丙烯酸类乳液30份、成膜助剂1份、防腐剂0.2份、硅烷偶联剂0.5份、紫外吸收剂0.6份、颜料45份、防霉剂0.5份、消泡剂0.2份、流平剂0.8份;或者水26份、助溶剂1.5份、分散剂0.4份、润湿剂0.2份、丙烯酸类乳液28份、成膜助剂1份、防腐剂0.3份、硅烷偶联剂0.6份、紫外吸收剂0.5份、颜料40份、防霉剂0.5份、消泡剂0.2份、流平剂0.8份。
- 根据权利要求1所述的聚丙烯酸共聚物乳液,其特征在于,还包括聚乙烯乙酸乙烯酯共聚物和丁苯橡胶中的一种或者多种。
- 一种有机无机复合防水涂层,其特征在于,包括由底到面依次形成在基材上的由压敏胶粘剂构成的压敏胶粘剂层,由无机颗粒构成的无机颗粒层,聚合物层,其中,所述聚合物层由聚丙烯酸共聚物乳液固化形成,所述聚丙烯酸共聚物乳液按重量份数,包括以下组分:水10-50份、助溶剂0-60份、分散剂0-5份、润湿剂0-5份、丙烯酸类乳液5-50份、成膜助剂0-5份、防腐剂0-5份、硅烷偶联剂0-5份、紫外吸收剂0-1.0份、颜料5-70份、防霉剂0-5份、消泡剂0-2份、流平剂0-5份。
- 根据权利要求5所述的有机无机复合防水涂层,其特征在于,所述无机颗粒层中的无机颗粒对压敏胶粘剂层的覆盖率为70-100%,所述聚合物层的厚度为1-100微米,所述无机颗粒的粒径为500-700微米。
- 根据权利要求6所述的有机无机复合防水涂层,其特征在于,所述无机颗粒层中的无机颗粒对压敏胶粘剂层的覆盖率为85-95%,所述聚合物层的厚度为25-100微米,所述无机颗粒的粒径为500或700微米。
- 根据权利要求5所述的有机无机复合防水涂层,其特征在于,所述无机颗粒选自方解石、石英石、沸石、蛭石、铝矾土、页岩、长石、珍珠岩、硅酸盐、铝酸盐中的一种或多种混合物。
- 根据权利要求5所述的有机无机复合防水涂层,其特征在于,所述压敏胶粘剂选自丁基橡胶基粘合剂、聚异丁烯基粘合剂、丁基系粘合剂、丙烯酸基粘合剂、苯乙烯-异戊二烯-苯乙烯基粘合剂、苯乙烯-乙烯-丁烯-苯乙烯基粘合剂、苯乙烯-丁二烯-苯乙烯基粘合剂、苯乙烯-丁二烯橡胶基粘合剂中的一种或多种。
- 根据权利要求5所述的有机无机复合防水涂层,其特征在于,所述压敏胶粘剂层的厚度范围是50-500微米;所述无机颗粒的粒径在100-1000微米,且无机颗粒的粒径级配呈双峰分布,体积百分比占30-50%无机颗粒粒径与压敏胶粘剂层的厚度的差别在25%以内,体积百分比占50-70%无机颗粒粒径至少比压敏胶粘剂层的厚度大25%以上,所述无机颗粒对压敏胶粘剂层的覆盖率为70-100%;所述聚合物层的厚度在1-100微米,所述聚合物层对无机颗粒层的覆盖率为10-50%。
- 根据权利要求10所述的有机无机复合防水涂层,其特征在于,所述压敏胶粘剂层的厚度范围为150-350微米;所述无机颗粒的粒径在200-700微米;所述无机颗粒对压敏胶粘剂层的覆盖率为85-95%;所述聚合物层对无机颗粒表面的覆盖率为25-35%。
- 根据权利要求11所述的有机无机复合防水涂层,其特征在于,所述压敏胶粘剂层的厚度范围为200-325微米。
- 根据权利要求12所述的有机无机复合防水涂层,其特征在于,所述无机颗粒选自铝矾土颗粒,所述铝矾土颗粒的粒径分布的两个峰值分别为250微米和480微米;或者所述无机颗粒选自页岩颗粒,所述页岩颗粒的粒径分布的两个峰值分别为320微米和650微米。
- 一种有机无机复合防水涂层的制备方法,其特征在于,包括以下步骤:将压敏胶粘剂在75-90℃下温热,使之粘度在25000-40000cps时,涂覆至基材上形成压敏胶粘剂层;将无机颗粒撒布于压敏胶粘剂层上,然后采用压力辊辊涂,通过重力、真空和扫刷方法中的一种或多种方法组合去除多余的无机颗粒,形成无机颗粒层;将聚丙烯酸共聚物乳液,涂布在无机颗粒层表面上,并在60-80℃的温度下干燥1-2分钟,得到聚合物层;其中,所述聚丙烯酸共聚物乳液按重量份数,包括以下组分:水10-50份、助溶剂0-60份、分散剂0-5份、润湿剂0-5份、丙烯酸类乳液5-50份、成膜助剂0-5份、防腐剂0-5份、硅烷偶联剂0-5份、紫外吸收剂0-1.0份、颜料5-70份、防霉剂0-5份、消泡剂0-2份、流平剂0-5份。
- 一种高分子自粘胶膜防水卷材,其特征在于,包括基材和有机无机复合防水涂层,所述有机无机复合防水涂层包括由底到面依次形成在基材上的由压敏胶粘剂构成的压敏胶粘剂层,由无机颗粒构成的无机颗粒层,聚合物层,其中,所述聚合物层由聚丙烯酸共聚物乳液固化形成,所述聚丙烯酸共聚物乳液按重量份数,包括以下组分:水10-50份、助溶剂0-60份、分散剂0-5份、润湿剂0-5份、丙烯酸类乳液5-50份、成膜助剂0-5份、防腐剂0-5份、硅烷偶联剂0-5份、紫外吸收剂0-1.0份、颜料5-70份、防霉剂0-5份、消泡剂0-2份、流平剂0-5份。
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AU2015371876A AU2015371876B2 (en) | 2014-12-22 | 2015-12-01 | Acrylic Copolymer Emulsion, Organic-Inorganic Composite Waterproof Coating, Preparation Method thereof and Waterproof Coiled Material |
SG11201705060TA SG11201705060TA (en) | 2014-12-22 | 2015-12-01 | Polyacrylic acid copolymer emulsion, organic-inorganic composite waterproof coating,preparation method thereof and waterproof coiled material |
EP15871842.9A EP3239266B1 (en) | 2014-12-22 | 2015-12-01 | Polyacrylic acid copolymer emulsion, organic-inorganic composite waterproof coating ,preparation method thereof and waterproof coiled material |
MYPI2017702246A MY197661A (en) | 2014-12-22 | 2015-12-01 | Polyacrylic acid copolymer emulsion, organic-inorganic composite waterproof coating, preparation method thereof and waterproof coiled material |
US15/539,069 US10487215B2 (en) | 2014-12-22 | 2015-12-01 | Polyacrylic acid copolymer emulsion, organic-inorganic composite waterproof coating, preparation method thereof and waterproof coiled material |
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US10487215B2 (en) | 2019-11-26 |
AU2015371876A1 (en) | 2017-07-13 |
EP3239266B1 (en) | 2022-07-06 |
MY197661A (en) | 2023-06-30 |
AU2015371876B2 (en) | 2018-10-04 |
EP3239266A4 (en) | 2017-12-13 |
CN104479580B (zh) | 2016-08-24 |
CN104479580A (zh) | 2015-04-01 |
US20180030283A1 (en) | 2018-02-01 |
EP3239266A1 (en) | 2017-11-01 |
SG11201705060TA (en) | 2017-07-28 |
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