WO2016101159A1 - Compositions cosmétiques de soin de la peau à rincer et procédés cosmétiques les utilisant - Google Patents

Compositions cosmétiques de soin de la peau à rincer et procédés cosmétiques les utilisant Download PDF

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Publication number
WO2016101159A1
WO2016101159A1 PCT/CN2014/094761 CN2014094761W WO2016101159A1 WO 2016101159 A1 WO2016101159 A1 WO 2016101159A1 CN 2014094761 W CN2014094761 W CN 2014094761W WO 2016101159 A1 WO2016101159 A1 WO 2016101159A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
oil
composition according
cosmetic
weight
Prior art date
Application number
PCT/CN2014/094761
Other languages
English (en)
Inventor
Yi Deng
Xinrong LIN
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to PCT/CN2014/094761 priority Critical patent/WO2016101159A1/fr
Priority to CN201480084329.9A priority patent/CN107106435A/zh
Publication of WO2016101159A1 publication Critical patent/WO2016101159A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention concerns cosmetic compositions, preferably used as rinse-off skin care masks.
  • the invention also relates to a skin care cosmetic method using these cosmetic compositions.
  • Another aim of the invention is to provide a cosmetic composition which leaves a deposition after being rinsed-off, in particular leading to a good skin feeling.
  • Another aim of the invention is to provide a cosmetic composition leading to a moisturizing effect, a slippery effect, a hydrophobic effect on the skin and softness of the skin, after application.
  • Another aim of the invention is to provide a rinse-off skin care composition, which is especially suitable for applying on the skin during shower.
  • Another aim of the invention is to provide a cosmetic rinse-off composition, which can be applied on the skin during shower, and allows a perceived deposition on the skin.
  • the invention relates to a cosmetic composition
  • a cosmetic composition comprising, in a physiologically acceptable medium:
  • the deposition involves an improved skin feeling after the removal of the composition according to the invention.
  • the good skin feeling is characterized by a hydrophobic and slippery effect on the skin, the softness of the skin and a moisturizing effect of the skin. This is particularly surprising for a rinsing-off cosmetic composition, in particular compared to a leave-on cosmetic composition.
  • the cosmetic composition of the invention is a rinse-off cosmetic composition.
  • This gelling agent may more particularly be chosen from acrylic polymers described as follows:
  • the crosslinking agents may be chosen from the polyolefinically unsaturated compounds commonly used for crosslinking polymers obtained by free-radical polymerization.
  • X + denotes a proton, an alkali metal cation, an alkaline-earth metal cation or the ammonium ion, not more than 10 mol% of the cations X + possibly being protons H + ;
  • a polymer of this type that may especially be mentioned is the crosslinked and neutralized 2-acrylamido-2-methylpropanesulfonic acid homopolymer sold by the company Clariant under the trade name AMPS (CTFA name: ammonium polyacryldimethyltauramide) .
  • a crosslinked copolymer that is particularly preferred in the context of the implementation of the present invention corresponds to the one prepared in Example 1 of patent application EP-A-0 503 853 mentioned above, and which is then in the form of a water-in-oil inverse emulsion. More precisely, this copolymer is formed from 60 mol% of acrylamide and 40 mol% of the sodium salt of and it is crosslinked with methylenebisacrylamide in a proportion of 0.22 mmol per mole of the total monomer mixture.
  • the final water-in-oil inverse emulsion preferably contains about 40% by weight of crosslinked copolymer as defined above and about 4% by weight of an ethoxylated fatty alcohol with an HLB of about 12.5.
  • hydrophilic acrylic polymers that may be used according to the invention, mention may also be made of:
  • a hydrophobic copolymer in accordance with the invention may have a weight-average molecular weight ranging from 50 000 to 10 000 000, in particular from 100 000 to 8 000 000 and more particularly from 100 000 to 7 000 000.
  • the number of moles of oxyalkylene units may generally range from 1 to 30 mol, more particularly from 2 to 25 mol and even more particularly from 3 to 20 mol.
  • amphiphilic polymers that are suitable for use in the invention, mention may be made of:
  • crosslinked or noncrosslinked, neutralized or non-neutralized copolymers comprising from 15% to 60% by weight of units and from 40% to 85% by weight of (C 8 -C 16 ) alkyl (meth) acrylamide units or of (C 8 -C 16 ) alkyl (meth) acrylate units relative to the polymer, such as those described in patent application EP-A-0 750 899;
  • amphiphilic polymers that are suitable for use in the invention, mention may be made of polyoxyethylenated (crosslinked or noncrosslinked) copolymers of and of alkyl methacrylates, and mixtures thereof.
  • crosslinked or noncrosslinked amphiphilic copolymers comprising, or even formed from:
  • X may be a proton, an alkali metal cation, an alkaline-earth metal cation or an ammonium ion;
  • n and p independently of each other, denote a number of moles and range from 0 to 30, in particular from 1 to 25 and more particularly from 3 to 20, with the proviso that n + p is less than or equal to 30, in particular less than 25 and more particularly less than 20;
  • R 29 denotes a linear or branched alkyl radical comprising m carbon atoms, m ranging from 7 to 22 and preferably from 12 to 20.
  • amphiphilic polymers may be obtained according to the standard free-radical polymerization processes in the presence of one or more initiators such as, for example, azobisisobutyronitrile (AIBN) , azobisdimethylvaleronitrile, 2, 2-azobis [2-amidinopropane] hydrochloride (ABAH) , organic peroxides such as dilauryl peroxide, benzoyl peroxide, tert-butyl hydroperoxide, etc., mineral peroxide compounds such as potassium persulfate or ammonium persulfate, or H 2 O 2 optionally in the presence of reducing agents.
  • initiators such as, for example, azobisisobutyronitrile (AIBN) , azobisdimethylvaleronitrile, 2, 2-azobis [2-amidinopropane] hydrochloride (ABAH)
  • organic peroxides such as dilauryl peroxide, benzoyl peroxide, tert-but
  • amphiphilic polymers may be obtained by free-radical polymerization in tert-butanol medium, in which they precipitate.
  • the reaction may also be performed under inert atmosphere, and preferably under nitrogen.
  • the molar percentage concentration of the units of formula (2) and of the units of formula (3) in an amphiphilic polymer according to the invention may vary as a function of the desired cosmetic application, the nature of the emulsion (oil-in-water or water-in-oil emulsion) and the rheological properties of the desired formulation.
  • noncrosslinked copolymers LNC or SNC
  • LNC noncrosslinked copolymers
  • acrylic polymers that may be combined with a combination in accordance with the invention, mention may also be made of neutralized crosslinked acrylic homopolymers or copolymers.
  • -partially neutralized crosslinked sodium polyacrylates that are in the form of an inverse emulsion comprising at least one polar oil, for example the product sold under the name EM sold by the company BASF, and
  • the composition of the present invention comprises acrylamide/2-acrylamido-2-methylpropanesulfonic acid copolymers, polyacrylic acid/alkyl acrylate copolymers of Pemulen type, and modified or unmodified carboxyvinyl polymers.
  • They may be of animal, plant, mineral or synthetic origin.
  • non-volatile oil means an oil that remains on the skin or the keratin fibre at room temperature and atmospheric pressure. More specifically, a non-volatile oil has an evaporation rate strictly less than 0.01 mg/cm 2 /min.
  • volatile oil means any non-aqueous medium that is capable of evaporating on contact with the skin or the lips in less than one hour, at room temperature and atmospheric pressure.
  • the volatile oil is a cosmetic volatile oil, which is liquid at room temperature. More specifically, a volatile oil has an evaporation rate of between 0.01 and 200 mg/cm 2 /min, limits included.
  • silicone oils with a viscosity of less than or equal to 8 centistokes, and preferably containing from 2 to 10 silicon atoms and in particular from 2 to 7 silicon atoms, these silicone oils optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms;
  • the amount of the silicone oil is comprised between 1% and 15% by weight, preferably between 1% and 7% by weight in respect to the total weight of the cosmetic composition.
  • the cosmetic composition further comprises at least one cosmetic active agent, preferably selected from moisturizing agents, healing agents, and/or anti-ageing agents, more particularly among moisturizing agents.
  • the composition further comprises at least one moisturizing agent (also called a humectant) .
  • at least one moisturizing agent also called a humectant
  • humectants or moisturizers mention may notably be made of sorbitol, polyhydric alcohols preferably C 2 -C 8 alcohols, and even more preferably C 3 -C 6 alcohols, such as preferably glycerol, propylene glycol, 1, 3-butylene glycol, dipropylene glycol, diglycerol, and mixtures thereof, glycerol and its derivatives, urea and its derivatives, lactic acids, hyaluronic acids, sodium hyaluronate, AHAs, BHAs, sodium pidolate, xylitol, serine, sodium lactate, ectoine and its derivatives, chitosan and its derivatives, collagen, plankton, an extract of Imperata cylindra marked under the name of Moist 24 by Sederma, acrylic acid homopolymers like from NOF Corporation beta-glucan and in particular sodium carboxymethyl beta-glucan from Mibelle-AG-Biochemistry; a mixture of pass
  • the composition according to the invention comprises an aqueous phase.
  • the aqueous phase of the composition according to the invention may comprise water.
  • the aqueous phase of the composition according to the invention represents at least 50%, preferably at least 70% by weight in relation to the total weight of said composition.
  • the composition according to the invention comprises at least 60% by weight of water, particularly between 60% and 90% by weight of water in relation to the total weight of said composition.
  • the aqueous phase may also comprise water-miscible organic solvents (at ambient temperature -25°C) such as for example mono-alcohols having 2 to 6 carbon atoms such as ethanol, isopropanol; polyols having particularly 2 to 20 carbon atoms, preferably having 2 to 10 carbon atoms, and preferentially having 2 to 6 carbon atoms, such as glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylylglycol, dipropylene glycol, diethylene glycol; glycol ethers (having particularly 3 to 16 carbon atoms) such as mono, di-or tripropylene glycol alkyl (C 1 -C 4 ) ether, mono, di-or triethylene glycol alkyl (C 1 -C 4 ) ethers, and mixtures thereof.
  • water-miscible organic solvents at ambient temperature -25°C
  • mono-alcohols having 2 to
  • the aqueous phase of the compositions according to the invention comprises water, glycerin and ethyl alcohol or a mixture thereof.
  • the aqueous phase may also include any water-soluble or water-dispersible compound compatible with an aqueous phase, such as gelling agents, film-forming polymers, thickeners, surfactants and mixtures thereof.
  • the composition according to the invention comprises an oil phase.
  • the oil phase of the composition according to the invention may comprise at least one additional oil.
  • the additional oil (s) of the compositions according to the invention comprise (s) at least one volatile oil and/or at least one non-volatile oil.
  • the volatile oils may be chosen from hydrocarbon oils having 8 to 16 carbon atoms, and particularly branched C 8 -C 16 alkanes (also known as isoparaffins or isoalkanes) , such as isododecane (also known as 2, 2, 4, 4, 6-pentamethylheptane) , isodecane, isohexadecane, and, for example, the oils sold under the trade names or
  • volatile silicones such as, for example, volatile linear or cyclic silicone oils, in particular those having a viscosity below or equal to 8 centistokes (cst) (8 x 10 -6 m 2 /s) , and having, in particular, 2 to 10 silicon atoms, and in particular, 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxyl groups having 1 to 10 carbon atoms.
  • silicone oils having 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxyl groups having 1 to 10 carbon atoms.
  • the oil phase of the compositions according to the invention comprises at least one additional non-volatile oil as defined above.
  • the oil phase of the compositions according to the invention may comprise an additional mixture of a plurality of non-volatile oils.
  • the additional non-volatile oils may, in particular, be chosen from non-volatile hydrocarbon, fluorinated and/or silicone oils.
  • non-volatile hydrocarbon oil mention may be made of:
  • phytostearyl esters for instance phytostearyl oleate, phytostearyl isostearate and lauroyl/octyldodecyl/phytostearyl glutamate (AJINOMOTO, ELDEW PS203)
  • triglycerides constituted of glycerol and fatty acid esters, in particular in which the fatty acids may have chain lengths ranging from C 4 to C 36 , and in particular from C 18 to C 36 , these oils may be linear or branched, saturated or unsaturated; these oils may in particular be heptanoic or octanoic triglycerides, shea oil, alfalfa oil, poppy seed oil, pumpkin oil, millet oil, barley oil, quinoa oil, rye oil, candlenut oil, passionflower oil, shea butter, aloe oil, sweet almond oil, peach kernel oil, groundnut oil, argan oil, avocado oil, baobab
  • John′sWort oil monoi oil, hazelnut oil, apricot kernel oil, walnut oil, olive oil, evening primrose oil, palm oil, blackcurrant seed oil, kiwi seed oil, grape seed oil, pistachio oil, pumpkin oil, winter squash oil, musk rose oil, sesame oil, soybean oil, sunflower oil, castor oil and watermelon oil, and mixtures thereof, or alternatively caprylic/capric acid triglycerides, such as those sold by STEARINERIE DUBOIS or those sold under the names MIGLYOL and by DYNAMIT NOBEL,
  • hydrocarbons of mineral or synthetic origin such as liquid paraffins and derivatives thereof, petroleum jelly, polydecenes, polybutenes, hydrogenated polyisobutene such as Parleam, squalane;
  • -synthetic ethers having 10 to 40 carbon atoms such as dicaprylether;
  • oils having the formula R 1 COOR 2 wherein R 1 represents a linear or branched fatty acid residue comprising 1 to 40 carbon atoms, and R 2 represents a hydrocarbon chain, particularly branched containing 1 to 40 carbon atoms provided that the sum of the number of carbon atoms of the chains R 1 and R 2 is greater than or equal to 10.
  • the esters may particularly be chosen from fatty alcohol and acid esters, such as for example: cetostearyl octanoate, isopropyl alcohol esters, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl stearate or isostearate, isostearyl isostearate, octyl stearate, hydroxylated esters, such as isostearyl lactate, octyl hydroxystearate, diisopropyl adipate, heptanoates, particularly isostearyl heptanoate, alcohol or polyalcohol octanoates, decanoates or ricinoleates, such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, 2-ethylhexyl 4-
  • -C 12 -C 22 higher fatty acids such as oleic acid, linoleic acid, linolenic acid, and mixtures thereof;
  • -fluorinated oils optionally partially hydrocarbon-based and/or silicone-based, such as fluorosilicone oils, fluorinated polyethers or fluorinated silicones, as described in document EP-A-847 752; , and
  • said additional oil is C 13 -C 14 isoparaffin.
  • the composition of the present invention comprises, in a physiologically acceptable medium, by weight ratio relative to the total weight of the composition:
  • the cosmetic composition of the invention may further comprise at least one physiologically acceptable additive.
  • a cosmetic composition according to the invention may thus further comprise any additive normally used in the field in question, for example chosen from gums, resins, dispersants, polymers, antioxidants, essential oils, preservatives, fragrances, neutralizing agents, antiseptic agents, anti-UV protective agents, and mixtures thereof.
  • a person skilled in the art can adjust the type and amount of additives present in the compositions according to the invention by means of routine operations, so that the cosmetic properties and the stability properties sought for these compositions are not affected by the additives.
  • compositions according to the invention are cosmetic compositions intended for skincare. These compositions are thus intended to be applied onto the skin.
  • the invention also relates to the use of the cosmetic composition as defined above, as a skin mask.
  • the composition as defined above is applied on at least one zone of the skin, for example without working the composition onto the skin, and after an application time, said composition is removed by rinsing with water.
  • application time it may be understood a sufficient time for the cosmetic composition to have an effect on the skin such as a good feeling effect, a moisturizing effect or a hydrophobic or slippery effect on the skin. In one embodiment, the application time is comprised between 5 minutes and 10 minutes.
  • the composition as defined above is used as a body or face mask, preferably a face mask and more particularly a moisturizing face mask.
  • the viscosity of a gel according to the invention may be measured via any process known to those skilled in the art, thus, the measurement can be carried out at 25°C using a Rheomat 180 viscometer equipped with a spindle rotating at 200 rpm.
  • a Rheomat 180 viscometer equipped with a spindle rotating at 200 rpm.
  • the spindle for measuring the viscosity from the spindles M1, M2, M3 and M4 on the basis of their general knowledge, so as to be able to perform the measurement.
  • the viscosity of the present invention is measured using the spindle M4 with a speed of 200 rpm, and the viscosity is read after 10 minutes.
  • the viscosity of the gel according to the invention is inferior or equal to 80 UD using a spindle M4. More preferably the viscosity of the gel according to the present invention is 20 UD to 80 UD with the spindle M4.
  • the method further comprises after applying the cosmetic composition as defined above on at least one zone of skin, an application time as defined above, and then rinsing off the cosmetic composition.
  • the composition is rinsed off during shower.
  • compositions according to the invention are prepared according to well-known techniques by the man skilled in the art.
  • compositions are prepared using routine cosmetic composition formulation methods.
  • Invention A is a face mask according to the present invention
  • Comparative B is a face mask outside the scope of the present invention.
  • the comparative composition B does not contain sodium isostearoyl lactylate.
  • composition according to the invention A and the comparative composition B were formulated by mixing glycerin, acrylates/C 10-30 alkyl acrylate crosspolymer, carbomer, fragrance, preservative in water at 75°C, adding dimethicone, dimethiconol and sodium isostearoyl lactylate (if present) to the mixture, mixing and cooling down to room temperature, until a translucent gel cream was formed.
  • composition A and the composition B were stable over time.
  • composition according to the invention A has an improved perceived skin feeling, i.e., a moisturizing, slippery and hydrophobic skin feeling after being rinsed off, in comparison with the composition B.
  • composition A can be applied on the skin during shower, and allows a perceived deposition on the skin, whereas composition B has no perceived deposition.
  • composition A is thus particularly useful as a rinse-off skin mask, especially suitable for applying on the skin during shower.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique de soin de la peau qui comprend du lactylate isostéaroyle de sodium, au moins un agent gélifiant hydrophile, et au moins une huile dans un milieu physiologiquement acceptable. La composition est de préférence utilisée en tant que masque à rincer. Un procédé cosmétique de soin de la peau comprend les étapes consistant à appliquer la composition et à la rincer.
PCT/CN2014/094761 2014-12-24 2014-12-24 Compositions cosmétiques de soin de la peau à rincer et procédés cosmétiques les utilisant WO2016101159A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/CN2014/094761 WO2016101159A1 (fr) 2014-12-24 2014-12-24 Compositions cosmétiques de soin de la peau à rincer et procédés cosmétiques les utilisant
CN201480084329.9A CN107106435A (zh) 2014-12-24 2014-12-24 化妆品冲洗式皮肤护理组合物和使用其的化妆方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/094761 WO2016101159A1 (fr) 2014-12-24 2014-12-24 Compositions cosmétiques de soin de la peau à rincer et procédés cosmétiques les utilisant

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WO2016101159A1 true WO2016101159A1 (fr) 2016-06-30

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Publication number Priority date Publication date Assignee Title
WO2023212908A1 (fr) * 2022-05-06 2023-11-09 L'oreal Composition de soin pour matériaux kératiniques et masque la contenant

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WO1999019433A1 (fr) * 1997-10-10 1999-04-22 Avon Products, Inc. Savon pour la douche et le rasage
WO2001087232A2 (fr) * 2000-05-12 2001-11-22 Alwyn Company, Inc. Crème pour la peau contenant de l'allantoïne
WO2004037177A2 (fr) * 2002-10-21 2004-05-06 Eveready Battery Company, Inc. Formulations de mousse/gel de rasage antibacteriennes

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JP2000256188A (ja) * 1999-03-10 2000-09-19 Nikko Chemical Co Ltd 乳化組成物
US6440432B1 (en) * 1999-03-18 2002-08-27 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Skin cosmetic compositions containing dextran or maltodextrin and a weak carboxylic acid
AU1784601A (en) * 1999-11-19 2001-05-30 Procter & Gamble Company, The Personal care articles comprising a hydrophilic conditioning agent exhibiting a defined leaching value
KR100655834B1 (ko) * 2000-11-22 2006-12-08 오츠카 세이야쿠 가부시키가이샤 Ｏ／ｗ형 유화 조성물 및 그의 조제 방법
US20050049172A1 (en) * 2003-08-28 2005-03-03 Lukenbach Elvin R. Mild and effective cleansing compositions
ITVA20110008A1 (it) * 2011-03-25 2012-09-26 Lamberti Spa Composizioni detergenti
KR20140146047A (ko) * 2011-09-23 2014-12-24 에이미 뉴버거 튼살방지 스킨크림, 이에 대한 제법 및 사용법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999019433A1 (fr) * 1997-10-10 1999-04-22 Avon Products, Inc. Savon pour la douche et le rasage
WO2001087232A2 (fr) * 2000-05-12 2001-11-22 Alwyn Company, Inc. Crème pour la peau contenant de l'allantoïne
WO2004037177A2 (fr) * 2002-10-21 2004-05-06 Eveready Battery Company, Inc. Formulations de mousse/gel de rasage antibacteriennes

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