WO2013189055A1 - Composition cosmétique et procédé d'utilisation associé - Google Patents

Composition cosmétique et procédé d'utilisation associé Download PDF

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Publication number
WO2013189055A1
WO2013189055A1 PCT/CN2012/077291 CN2012077291W WO2013189055A1 WO 2013189055 A1 WO2013189055 A1 WO 2013189055A1 CN 2012077291 W CN2012077291 W CN 2012077291W WO 2013189055 A1 WO2013189055 A1 WO 2013189055A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
ranging
composition
hydrophobic silica
μηι
Prior art date
Application number
PCT/CN2012/077291
Other languages
English (en)
Inventor
Haiquan LU
Yue Wang
Xinrong LIN
Jerome Senee
Liang Zhang
Veronique Burnier
Original Assignee
L'oreal
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Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to CN201910141620.XA priority Critical patent/CN109966162A/zh
Priority to PCT/CN2012/077291 priority patent/WO2013189055A1/fr
Priority to BR112014031962A priority patent/BR112014031962A2/pt
Priority to CN201280074076.8A priority patent/CN104394830A/zh
Publication of WO2013189055A1 publication Critical patent/WO2013189055A1/fr
Priority to ZA2014/09028A priority patent/ZA201409028B/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0279—Porous; Hollow
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8188—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bonds, and at least one being terminated by a bond to sulfur or by a hertocyclic ring containing sulfur; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system

Definitions

  • the invention relates to a cosmetic composition for keratin materials, especially the skin and the lips, the hair and the nails.
  • the invention also relates to a cosmetic method for treating keratin materials using said composition.
  • waxes are generally accompanied by a dry, rough feel and a lack of comfort that is unacceptable for the user.
  • high concentration of the waxes leads to the composition unstable due to the growth of the size of the crystals over time.
  • Fatty acids are also widely used as a mattifying agent because they make it possible to obtain a soft feel on the skin, but they must be used at a relatively high content in order to have the mattifying effect, which constitutes a restraint in the choice of the texture, the stability of the composition, and moreover the cost of the formulation.
  • one subject of the present invention is a cosmetic composition
  • a cosmetic composition comprising a mixture of:
  • hydrophobic silica aerogel particles having a specific surface area per unit of mass (S M ) ranging from 500 to 1500 m 2 /g and a size expressed as the volume-average diameter (D[0.5]) ranging from 1 to 1500 ⁇ ; and - at least a inorganic base or an organic base, or a mixture thereof.
  • the mixture thereof makes it possible to obtain compositions that are comfortable and soft on application, having mattifying and soft -focus properties. It also meets the demand of stability over time.
  • the mixture thereof maybe any type of cosmetic composition such as a foundation, a face powder, an eye shadow, a concealer product, a blusher, a lipstick, a lip balm, a lip gloss, a lip pencil, an eye pencil, an eyeliner, a mascara, a body makeup product, a skin colouring product, a care product such as a care cream, a tinted cream or an antisun product, preferably a care product such as a care cream.
  • a care product such as a care cream, a tinted cream or an antisun product, preferably a care product such as a care cream.
  • the mixture of the invention is advantageously in the form of gel or cream.
  • Another subject of the present invention is a cosmetic method for making up and/or caring for keratin materials comprising a step of applying a composition as defined above to said materials.
  • the wax under consideration in the context of the present invention is generally a lipophilic compound that is solid at room temperature (25 ' ⁇ ), with a solid/liquid reversible change of state, having a melting point of greater than or equal to 30 which may be up to 200 ' ⁇ and in particular up to 120°C.
  • the waxes that are suitable for the invention may have a melting point of greater than or equal to 45 ⁇ and in particular greater than or equal to 55 ' ⁇ .
  • the waxes that may be used in the compositions according to the invention are chosen from waxes that are solid at room temperature of animal, plant, mineral or synthetic origin, and mixtures thereof.
  • waxes that are suitable for the invention, mention may be made especially of hydrocarbon-based waxes, for instance beeswax, lanolin wax, Chinese insect waxes, rice bran wax, carnauba wax, candelilla wax, ouricury wax, esparto grass wax, berry wax, shellac wax, Japan wax and sumach wax; montan wax, orange wax and lemon wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, the waxes obtained by Fischer-Tropsch synthesis and waxy copolymers, and also esters thereof.
  • hydrocarbon-based waxes for instance beeswax, lanolin wax, Chinese insect waxes, rice bran wax, carnauba wax, candelilla wax, ouricury wax, esparto grass wax, berry wax, shellac wax, Japan wax and sumach wax; montan wax, orange wax and lemon wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxe
  • fatty acids obtained by catalytic hydrogenation of animal or plant oils containing linear or branched C 8 -C 32 fatty chains, preferably Ci 6 or Ci 8 chains.
  • fatty acids used in the current invention are commercially available under the trade names, for example, AEC Stearic Acid sold by A & E Connock (Perfumery & Cosmetics) Ltd., Emersol sold by Emery Oleochemical LLC, Palmitic Acid PC sold by Protameen Chemicals, Inc.
  • silicone waxes C30-45 alkyl dimethicone
  • fluoro waxes C30-45 alkyl dimethicone
  • waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol sold under the names Phytowax ricin 16L64 ® and 22L73 ® by the company Sophim, may also be used. Such waxes are described in patent application FR-A-2 792 190.
  • a wax that may be used is a C 2 o-C 4 o alkyl (hydroxystearyloxy)stearate (the alkyl group containing from 20 to 40 carbon atoms), alone or as a mixture.
  • Such a wax is especially sold under the names Kester Wax K 82 P ® , Hydroxypolyester K 82 P ® and Kester Wax K 80 P ® by the company Koster Keunen.
  • the composition according to the invention comprises at least one wax chosen fro m fatty acids having 16 or 18 carbon atoms, or a mixture thereof .
  • a composition of the invention may comprise from 6% to 12% by weight and preferably from 7% to 9% by weight of wax(es) relative to the total weight of the said composition.
  • a polymeric agent in accordance with the invention is a thickening agent and advantageously emulsifying polymer.
  • polymeric thickening agent means a polymer which, when introduced as an aqueous 0.05% (by weight) solution, makes it possible to reduce the surface tension of water at 25 ⁇ to a value of less than 50 mN/m and preferably less than 40 mN/m.
  • a polymeric thickening agent in accordance with the invention may be chosen from polymers derived from 2-acrylamidomethylpropanesulfonic acid (AMPS ® ), polymers derived from acrylamide, polymers derived from acrylic acid and polyether derivatives, and mixtures thereof.
  • AMPS ® 2-acrylamidomethylpropanesulfonic acid
  • acrylamide polymers derived from acrylic acid and polyether derivatives, and mixtures thereof.
  • the polymeric agents in accordance with the invention especially the polymers derived from AMPS ® and the polymers derived from acrylic acid, generally have a weight-average molar mass ranging from 50 000 to 10 000 000, more preferentially from 100 000 to 8 000 000 and even more preferentially from 200 000 to 3 000 000.
  • the polymers in accordance with the invention are preferentially partially or totally neutralized with a mineral base (for instance sodium hydroxide, potassium hydroxide or aqueous ammonia) or with an organic base such as monoethanolamine, diethanolamine, triethanolamine, aminomethylpropanediol, N-methylglucamine, or basic amino acids, for instance arginine and lysine, and mixtures thereof.
  • a mineral base for instance sodium hydroxide, potassium hydroxide or aqueous ammonia
  • organic base such as monoethanolamine, diethanolamine, triethanolamine, aminomethylpropanediol, N-methylglucamine, or basic amino acids, for instance arginine and lysine, and mixtures thereof.
  • the polymeric agents according to the invention especially the polymers derived from AMPS ® and the polymers derived from acrylic acid, may or may not be crosslinked.
  • AMPS ® AcrylamidoMethylPropaneSulfonic
  • amphiphilic water-soluble or water-dispersible polymer according to the invention is especially a polymer derived from AMPS ® (AcrylamidoMethylPropaneSulfonic)
  • the polymers derived from AMPS comprise:
  • AMPS ® _ 2-acrylamido-2-methylpropanesulfonic acid
  • X + is a proton, an alkali metal cation, an alkaline-earth metal cation or an ammonium ion
  • n and p independently of each other, denote a number of moles and ranges from 0 to 30 and preferably from 1 to 20, with the proviso that n + p is less than or equal to 30, preferably less than 25 and better still less than 20;
  • Ri denotes a hydrogen atom or a linear or branched Ci-C 6 alkyi radical (preferably methyl) and R 3 denotes a linear or branched alkyi comprising m carbon atoms, with m ranging from 6 to 30 and preferably from 10 to 25.
  • the polymers are obtained especially by free-radical polymerization in tert-butanol medium from which they precipitate. Using polymerization in tert-butanol, it is possible to obtain a size distribution of the polymer particles that is particularly favourable for its uses.
  • the polymerization reaction may be performed at a temperature of between 0 and ⁇ ⁇ ' ⁇ , preferably between 20 and 100 °C, either at atmospheric pressure or under reduced pressure. It may also be performed under inert atmosphere, and preferably under nitrogen.
  • the polymer of current invention is a copolymer of AMPS and of a Ci 6 -Ci 8 alcohol methacrylate comprising from 6 to 25 mol of oxyethylene groups, obtained from methacrylic acid or a methacrylic acid salt and from a Ci 6 -Ci 8 alcohol oxyethylenated with 6 to 25 mol of ethylene oxide.
  • the polymer may also be a copolymer of AMPS ® and of a Ci 2 -Ci 4 alcohol methacrylate comprising from 6 to 25 mol of oxyethylene groups, obtained from methacrylic acid or a methacrylic acid salt and from a Ci 2 -Ci 4 alcohol oxyethylenated with 6 to 25 mol of ethylene oxide.
  • the crosslinked copolymer obtained from 96.45 mol% of AMPS ® and 3.55 mol% of a Ci 6 -Ci 8 alcohol methacrylate comprising 25 oxyethylene groups (Genapol T-250 ® ), the crosslinking agent is trimethylolpropane triacrylate,
  • AMPS ® the acrylamide/sodium 2-methyl-2-[(1 -oxo-2-propenyl)amino]-1 -propanesulfonate copolymer such as Simulgel 600 ® in the form of an emulsion containing polysorbate 80 as surfactant and containing isohexadecane as oil phase, sold by the company SEPPIC, or alternatively Simulgel EG ® , Simulgel A ® and Simulgel 501 ® sold by the same company.
  • Simulgel 600 ® in the form of an emulsion containing polysorbate 80 as surfactant and containing isohexadecane as oil phase, sold by the company SEPPIC, or alternatively Simulgel EG ® , Simulgel A ® and Simulgel 501 ® sold by the same company.
  • Simulgel 600 ® is described especially in document FR 2 785 801 . It is more specifically a reverse latex.
  • the AMPS ® polyelectrolyte is 2-methyl-2-[(1 -oxo-2-propenyl)amino]-1 - propanesulfonic acid partially or totally salified especially in sodium salt or ammonium salt form, to a proportion of from 30 mol% to 50 mol% in the mixture comprising the AMPS and an acrylamide, which is itself in a proportion of 50% to 70%.
  • the polymeric agents according to the invention may also be chosen from acrylic acid or methacrylic acid derivatives. These polymers may comprise:
  • X + is a proton, an alkali metal cation, an alkaline-earth metal cation or an ammonium ion
  • R 4 denotes a linear or branched alkyl comprising m carbon atoms with m ranging from 6 to 30 and preferably from 10 to 25.
  • non-crosslinked copolymer obtained from (meth)acrylic acid, aminoacrylate and C 10- C30 alkyl PEG 20 itaconate, sold under the name Structure Plus ® by the company National Starch,
  • the polymer derived from acrylic acid is in particular a non-crosslinked copolymer obtained from (meth)acrylic acid, methyl acrylate and ethoxylated alcohol dimethyl meta-isopropenyl benzyl isocyanate.
  • the thickening polymeric agents according to the invention may also be chosen from polyether derivatives.
  • polyether derivatives encompass the polyethyleneglycol-based copolymers.
  • the preferred polyether derivatives are water-soluble polyurethanes and especially polyethylene glycol compounds (for example containing from 45 to 160 ethylene oxide units) bearing at the ends a C 8 -C 2 o alkyl chain via a urethane bond.
  • the polymers derived from polyether may also bear fatty chains free of urethane bonds, for instance the product Pure Thix HH ® sold by the company Sud Chemie.
  • polymers derived from polyether may also be chosen from copolymers containing ethylene oxide and propylene oxide blocks, having the following formula:
  • x, y and z are integers such that x+z ranges from 2 to 100 and y ranges from 14 to 60, and more particularly from the block copolymers of the preceding formula with an HLB value ranging from 7 to 16.
  • block copolymers may be chosen especially from polyethylene glycol/polypropylene glycol/polyethylene glycol triblock polycondensates and especially from those sold under the names:
  • polymeric thickening agents in accordance with the invention, the following are preferably used:
  • copolymers derived from polyether especially such as Nuvis FX1 100 from Elementis; and mixtures thereof.
  • the polymeric thickening agent is in a liquid form at room temperature.
  • AMPS/acrylamide copolymers especially such as Simulgel® sold by the company SEPPIC.
  • the polymeric thickening agents of is chosen among the polymers derived from AMPS ® (AcrylamidoMethylPropaneSulfonic), and more particularly from the acrylamide/sodium 2-methyl-2-[(1 -oxo-2-propenyl)amino]-1 - propanesulfonate (AMPS ® ) copolymer such as Simulgel 600 ® sold by the company SEPPIC.
  • AMPS ® AcrylamidoMethylPropaneSulfonic
  • polymeric thickening agents required according to the invention with at least one surfactant other than the said polymer, so as to facilitate the emulsification of the associated fatty phase.
  • a surfactant having at 25 ⁇ an HLB (hydrophilic-lipophilic balance), in the Griffin sense, of greater than or equal to 10 and in particular greater than or equal to 12 may be used.
  • a composition according to the invention may advantageously comprise a surfactant with a low HLB value, i.e. less than 12, in particular with an HLB value of between 1 and 10.
  • Such a surfactant can stabilize the emulsion and facilitate the application to the keratin material of the solid anhydrous composition according to the invention containing it when the said composition is applied after having been combined beforehand with an aqueous phase.
  • Such a surfactant will preferably be liquid at room temperature to facilitate its use and its availability after addition of the aqueous phase.
  • Such a surfactant may be present in the composition according to the invention in a proportion of from 0.1 % to 10% by weight and preferably from 1 % to 5% by weight relative to the total weight of the said composition.
  • the Griffin HLB value is defined in J. Soc. Cosm. Chem. 1954 (volume 5), pages 249-256.
  • the co-surf actant(s) will be selected from nonionic surfactants.
  • a composition according to the invention may comprise from 0.5% to 3% by weight, preferably from 1 % to 2.5% by weight and better still 2% by weight of polymeric thickening agent(s) relative to the total weight of the said composition.
  • Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air.
  • sol-gel processes are generally synthesized via a sol-gel process in liquid medium and then dried, usually by extraction of a supercritical fluid; the one most commonly used being supercritical C0 2 .
  • This type of drying makes it possible to avoid shrinkage of the pores and of the material.
  • the sol -gel process and the various drying processes are described in detail in Brinker CJ., and Scherer G.W., Sol-Gel Science: New York: Academic Press, 1990.
  • the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit of mass (S M ) ranging from 500 to 1500 m 2 /g, preferably from 600 to 1200 m 2 /g and better still from 600 to 800 m 2 /g, and a size expressed as the mean volume diameter (D[0.5]), ranging from 1 to 30 ⁇ , preferably from 5 to 25 ⁇ , better still from 5 to 20 ⁇ and even better still from 5 to 15 ⁇ .
  • the specific surface area per unit of mass may be determined via the BET (Brunauer-Emmett- Teller) nitrogen absorption method described in the Journal of the American Chemical Society, vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (appendix D).
  • the BET specific surface area corresponds to the total specific surface area of the particles under consideration.
  • the size of the silica aerogel particles may be measured by static light scattering using a commercial granulometer such as the MasterSizer 2000 machine from Malvern.
  • the data are processed on the basis of the Mie scattering theory.
  • This theory which is exact for isotropic particles, makes it possible to determine, in the case of non -spherical particles, an "effective" particle diameter. This theory is especially described in the publication by Van de Hulst, H.C., "Light Scattering by Small Particles," Chapters 9 and 10, Wiley, New York, 1957.
  • the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit of mass (S M ) ranging from 600 to 800 m 2 /g and a size expressed as the mean volume diameter (D[0.5]) ranging from 5 to 20 ⁇ and better still from 5 to 15 ⁇ .
  • the silica aerogel particles used in the present invention may advantageously have a tamped density r) ranging from 0.04 g/cm 3 to 0.10 g/cm 3 and preferably from 0.05 g/cm 3 to 0.08 g/cm 3 .
  • this density known as the tamped density, may be assessed according to the following protocol:
  • the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit of volume S v ranging from 5 to 60 m 2 /cm 3 , preferably from 10 to 50 m 2 /cm 3 and better still from 15 to 40 m 2 /cm 3 .
  • the hydrophobic silica aerogel particles according to the invention have an oil - absorbing capacity, measured at the wet point, ranging from 5 to 18 ml/g, preferably from 6 to 15 ml/g and better still from 8 to 12 ml/g.
  • the oil-absorbing capacity measured at the wet point, noted Wp corresponds to the amount of water that needs to be added to 100 g of particle in order to obtain a homogeneous paste.
  • An amount 2 g of powder is placed on a glass plate, and the oil (isononyl isononanoate) is then added dropwise. After addition of 4 to 5 drops of oil to the powder, mixing is performed using a spatula, and addition of oil is continued until a conglomerate of oil and powder has formed. At this point, the oil is added one drop at a time and the mixture is then triturated with the spatula. The addition of oil is stopped when a firm, smooth paste is obtained. This paste must be able to be spread on the glass plate without cracking or forming lumps. The volume Vs (expressed in ml) of oil used is then noted. The oil uptake corresponds to the ratio Vs/m.
  • the aerogels used according to the present invention are hydrophobic silica aerogels, preferably of silylated silica (INCI name: silica silylate).
  • hydrophobic silica means any silica whose surface is treated with silylating agents, for example halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH groups with silyl groups Si-Rn, for example trimethylsilyl groups.
  • silylating agents for example halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes
  • hydrophobic silica aerogels particles surface-modified with trimethylsilyl groups Use will be made in particular of hydrophobic silica aerogels particles surface-modified with trimethylsilyl groups .
  • hydrophobic silica aerogels that may be used in the invention, examples that may be mentioned include the aerogel sold under the name VM-2260 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m 2 /g.
  • the silica aerogel particles in accordance with the invention are preferably present in the cosmetic composition in an amount of active material ranging from 0.1 % to 2% by weight and more preferentially from 0.2% to 1 % by weight relative to the total weight of the composition.
  • the presence of the bases in the composition of the current invention helps to control the percentage of the fatty acid which will be neutralized, as what we want to claim, 5% - 20% of fatty acid should be neutralized.
  • Suitable bases used in the present invention are inorganic and organic bases that are used commonly in cosmetic compositions.
  • Organic bases may be pyridines, methyl amines, imidazoles, benzimidazoles, histidines, phosphazene bases, and hydroxides of organic cations.
  • alkanolamines are preferably according to one embodiment of the current invention.
  • Inorganic bases may be hydroxides or carbonates of alkaline earths and alkali metals. They are very commonly used in cosmetic compositions to date. Mention may be made of alkali hydroxides, according to the embodiment of the present invention.
  • Preferred bases of the current invention may be TEA, which is commercially available, for example, under the trade name Tealan sold by Rita Corporation, or Triethanolamine sold by BASF Corporation, and KOH, which is commercially available under the trade name Naturagel sold by Active Concepts LLC, or SC-1000 Gemtek Products.
  • the bases in accordance with the invention are preferably present in the cosmetic composition in an amount of active material ranging from 5% to 20% by weight and more preferentially from 10% to 15% by weight relative to the total weight of the composition.
  • the composition of the invention may also contain adjuvants that are common in cosmetics and/or dermatology, such as active agents, preserving agents, antioxidants, complexing agents, pH modifiers (acidic or basic), fragrances, fillers, bactericides, odour absorbers, colorants (pigments and dyes), film-forming polymers, emulsifiers such as fatty acid esters of polyethylene glycol, fatty acid esters of glycerol and fatty acid esters of sorbitan, which are optionally polyoxyethylenated, polyoxyethylenated fatty alcohols and fatty acid esters or ethers of sugars such as sucrose or glucose; thickeners and/or gelling agents, in particular polyacrylamides, acrylic homopolymers and copolymers, and acrylamidomethylpropanesulphonic acid homopolymers and copolymers, and also lipid vesicles.
  • adjuvants that are common in cosmetics and/or dermatology, such as active agents,
  • these various adjuvants are those conventionally used in the field under consideration, for example from 0.5% to 3% of the total weight of the composition. Depending on their nature, these adjuvants may be introduced into the fatty phase, into the aqueous phase and/or into the lipid vesicles.
  • phase B additive phase B into phase A, keep the temperature for 15 minutes
  • phase B additive phase B into phase A, keep the temperature for 15 minutes
  • phase B additive phase B into phase A, keep the temperature for 15 minutes
  • Example 5 cream for greasy skin
  • phase B additive phase B into phase A, keep the temperature for 15 minutes
  • the invention of example 5 exhibits good anti-shine performance, while at the same time stable over time.

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Abstract

La présente invention concerne une composition cosmétique pour matières kératiniques, notamment la peau et les lèvres, les cheveux et les ongles. La composition cosmétique comprend un mélange d'au moins une cire contenant au moins un acide gras ayant de 16 à 18 atomes de carbone, ou un mélange de ceux-ci ; au moins un agent épaississant polymère ; des particules d'aérogel de silice hydrophobe ayant une aire de surface spécifique par unité de masse dans la plage de 500 à 1500 m²/g et une taille exprimée comme le diamètre moyen en volume dans la plage de 1 à 1500 µm ; et au moins une base inorganique ou une base organique, ou un mélange de celles-ci.
PCT/CN2012/077291 2012-06-21 2012-06-21 Composition cosmétique et procédé d'utilisation associé WO2013189055A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201910141620.XA CN109966162A (zh) 2012-06-21 2012-06-21 化妆品组合物及其使用方法
PCT/CN2012/077291 WO2013189055A1 (fr) 2012-06-21 2012-06-21 Composition cosmétique et procédé d'utilisation associé
BR112014031962A BR112014031962A2 (pt) 2012-06-21 2012-06-21 composição cosmética e método para o seu uso
CN201280074076.8A CN104394830A (zh) 2012-06-21 2012-06-21 化妆品组合物及其使用方法
ZA2014/09028A ZA201409028B (en) 2012-06-21 2014-12-09 Cosmetic composition and method for using thereof

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PCT/CN2012/077291 WO2013189055A1 (fr) 2012-06-21 2012-06-21 Composition cosmétique et procédé d'utilisation associé

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WO2013189055A1 true WO2013189055A1 (fr) 2013-12-27

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BR (1) BR112014031962A2 (fr)
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ZA (1) ZA201409028B (fr)

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WO2016187874A1 (fr) * 2015-05-28 2016-12-01 L'oreal Composition de soin pour la peau, procédé et utilisation de celle-ci

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Publication number Priority date Publication date Assignee Title
FR3060307B1 (fr) * 2016-12-16 2019-01-25 L'oreal Composition cosmetique comprenant des corps gras solides et un polymere gelifiant

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EP1541115A1 (fr) * 2002-07-11 2005-06-15 Catalysts & Chemicals Industries Co., Ltd. Produit cosmetique
WO2007068358A1 (fr) * 2005-12-16 2007-06-21 Unilever Plc Préparation avantageuse pour la peau et méthode d'utilisation
WO2012084781A2 (fr) * 2010-12-21 2012-06-28 L'oreal Composition cosmétique comprenant des particules d'aérogel de silice et des huiles hydrocarbonées

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