WO2016045013A1 - 绿能环控纤维、其制法及以该纤维制成的织品 - Google Patents

绿能环控纤维、其制法及以该纤维制成的织品 Download PDF

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Publication number
WO2016045013A1
WO2016045013A1 PCT/CN2014/087310 CN2014087310W WO2016045013A1 WO 2016045013 A1 WO2016045013 A1 WO 2016045013A1 CN 2014087310 W CN2014087310 W CN 2014087310W WO 2016045013 A1 WO2016045013 A1 WO 2016045013A1
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Prior art keywords
weight
fiber
green energy
oxide
energy
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PCT/CN2014/087310
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English (en)
French (fr)
Inventor
黄凯莉
陈沅德
陈沅瑢
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黄凯莉
陈沅德
陈沅瑢
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Application filed by 黄凯莉, 陈沅德, 陈沅瑢 filed Critical 黄凯莉
Priority to US15/513,876 priority Critical patent/US10562020B2/en
Priority to EP14902688.2A priority patent/EP3199673B1/en
Priority to CA2961956A priority patent/CA2961956C/en
Priority to PCT/CN2014/087310 priority patent/WO2016045013A1/zh
Priority to ES14902688T priority patent/ES2822594T3/es
Priority to JP2017516963A priority patent/JP6694878B2/ja
Priority to PT149026882T priority patent/PT3199673T/pt
Priority to PL14902688T priority patent/PL3199673T3/pl
Publication of WO2016045013A1 publication Critical patent/WO2016045013A1/zh
Priority to US16/699,118 priority patent/US20200101452A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
    • A—HUMAN NECESSITIES
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    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00—Protecting plants
    • A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0231—Tunnels, i.e. protective full coverings for rows of plants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14—Greenhouses
    • A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/20—Forcing-frames; Lights, i.e. glass panels covering the forcing-frames
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • A—HUMAN NECESSITIES
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    • A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7783—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
    • C09K11/7792—Aluminates
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    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
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    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
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    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/702—Piezoelectric or electrostrictive devices based on piezoelectric or electrostrictive fibres
    • C—CHEMISTRY; METALLURGY
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Definitions

  • the invention relates to a green energy environmental control fiber, a preparation method thereof and a fabric made of the fiber, and is applied to an organic environment control agricultural industry such as an agricultural plant green energy environmental control greenhouse and a plant green energy environmental control factory, or the like.
  • environmental control equipment such as health care green energy environmental control fabrics, indoor air quality green energy environmental control fabrics, fume green energy environmental control fabrics, geophysical green energy environmental control fabrics, defogging green energy environmental control fabrics, air clean Green energy environmental control fabrics, environmental pollution control green energy environmental control fabrics, etc.
  • green energy in the environment such as solar energy, solar thermal energy, wind energy, hydropower, geothermal energy and other renewable energy
  • the various types of green energy radiation waves in the fiber material receiving environment produce free electron effects, through the interior of the fiber composed of photovoltaic materials, Thermoelectric materials and piezoelectric materials increase the natural energy of green energy radiation waves and act on various types of catalyst materials in fabric fibers, effectively improving the various functions of the catalyst materials, so that the catalyst fibers and products can be beneficial to plant growth through green energy.
  • Patent No. 5,690,922 the fiber is added with a metal phosphate and a metal hydroxide to have a deodorizing function.
  • functional materials in the fiber can only achieve benefits in an effective space without an effective increase.
  • some manufacturers have developed LED lights to emit light that is beneficial to the growth of blue light and red light plants for planting fruits and vegetables, the use of LED lights requires electricity and is expensive, and relatively high cost, not only produces Energy consumption problems, and can not prevent pests and diseases, still have to rely on pesticides or biological control or need to install additional mesh isolation pests or nets or closed plastic sheds, glass greenhouses, etc., but still can not effectively achieve environmental control efficacy.
  • the inventors believe that it is necessary to make good use of green energy that exists in nature and is endless, and to convert green energy into a suitable crop growing environment. For example, using green energy, making good use of sunlight in green energy, converting or increasing sunlight into light waves needed for plant growth, increasing the yield of organic net crops; receiving green energy in fiber materials through the crystal band effect in fiber materials.
  • the effectiveness of the catalytic material in the post-amplifying fiber material not only converts the sunlight and increases the required light, but also reduces the humidity of the air, which is beneficial to plant growth and can prevent plant diseases and remove environmental pollutants.
  • it can be combined with the use of natural plant essential oils to prevent insect pests, thereby achieving the purpose of organic cultivation.
  • the above is the concept and research engine of the present invention, and is also an agricultural green energy environmental control material that is worthy of active research and development, and a technology that can achieve true organic agricultural planting production and environmental pollution control, and current energy consumption for organic agricultural environmental control materials and food production. Such errors and problems can be improved.
  • the first object of the present invention is to provide an environmental control fiber and a fabric thereof which use green energy to increase the growth of organic agricultural plants, and control the special material properties of the fiber to increase the light wave required for plant growth and transfer harmful light waves or increase Irradiating the light wave time, decomposing the moisture in the air to make the water molecules fine (water oxygen and anion), can absorb water more effectively, generate far infrared rays to provide plant growth light waves and remove environmental pollutants, thereby promoting sunlight and water in the environment. , air and soil increase the quality and quantity of organic plant production.
  • the fiber is made of a polyolefin-based material
  • the photoelectric material light-storing long-lasting fluorescent phosphorescent material
  • a photoelectric effect capable of generating electromagnetic radiation waves is contained therein, and has a light-converting light-storing function and can cause stress.
  • a piezoelectric material having a piezoelectric effect in which a field and an electric field are coupled, a thermoelectric material capable of receiving external thermal radiation to generate far infrared rays, and an acceleration The catalyst material for the reaction rate.
  • the fiber When the fiber receives external green energy such as solar photovoltaic energy, the desired spectrum of plant growth (400-700 nm wavelength light) is generated by the action of a photoelectric material (such as a long-lasting fluorescent phosphorescent material), which will convert harmful ultraviolet light to plants. It is the 400-700 nm wavelength light required for plant growth, and the light storage energy is used for plant growth at night to promote plant growth.
  • a photoelectric material such as a long-lasting fluorescent phosphorescent material
  • the light storage energy is used for plant growth at night to promote plant growth.
  • an infrared energy wave having a plant growth wavelength of 4 to 14 ⁇ m is generated in the environment by the action of the thermoelectric material.
  • the piezoelectric material When the fiber receives the external green energy such as wind energy, the piezoelectric material generates piezoelectricity in the environment, and the hydraulic energy of the humidity in the air is decomposed to generate water and oxygen anions, so that the rainforest ecology is generated in the environment, and the plant is provided with more effective water. Absorption.
  • the catalytic material generates resonance by photoelectric effect, thermoelectric effect and piezoelectric effect to increase the energy to activate the activity of free electrons, and to stimulate the catalytic activity of the electron hole energy level activity in the material, so that the catalytic material is more effectively produced. Act to remove environmental contaminant materials.
  • a second object of the present invention is to provide a green energy ring control fiber and a fabric thereof having the function of removing biological contaminants.
  • the technical means is that the green energy-controlled fiber inside the first object contains a catalytic material capable of removing biological pollutants in the environment. Through the arrangement of the catalyst material, the green energy-controlled fiber and its fabric have the functions of inhibiting biological pollution sources in the environment, thereby achieving the effects of inhibiting environmental pollution sources such as fungi, bacteria and viruses. purpose.
  • a third object of the present invention is to provide a green energy loop control fiber and a fabric thereof having the function of removing chemical pollutants from the environment.
  • the technical means for the first purpose of the green energy ring control fiber is internally mixed with a catalyst material having the function of removing chemical pollutants, and has the functions of removing formaldehyde HCHO, total volatile organic compounds TVOCs, carbon monoxide CO, carbon dioxide CO 2 and ozone.
  • O 3 acetic acid, acetaldehyde, ammonia, positive and negative ions (F - , Cl - , NO 3 - , PO 4 3- , SO 4 2- , NH 4 + ) and other chemical pollutants.
  • a fourth object of the present invention is to provide a green energy loop control fiber having a function of removing physical pollutants from the environment.
  • the technical means is that the fiber inside the first object contains a catalytic material having a physical pollution source in a sedimentation environment, and has a physical activity source of air in a sedimentation environment to the ground, such as pollen, PM 2.5 , PM 10 and the like.
  • a fifth object of the present invention is to provide a green energy ring-controlled fiber having fentanyl insect-repellent.
  • the technical means is that the fiber of the first four items mentioned above contains a natural plant essential oil with anti-insect effect, and the material contains the effect of avoiding insects to achieve the effect of controlling insects, and can produce fentanyl for plant growth. .
  • a sixth object of the present invention is to provide a safe green energy ring-controlled fiber having a flame-resistant and conductive antistatic function.
  • the technical means is to add materials containing fireproof materials and conductive antistatic functions to the fibers in the above five items, so that the fibers have a safety function.
  • a seventh object of the present invention is to provide a safe green energy to which the present invention is applied.
  • the fabric of the ring-controlled fiber the fabric of which can be used to assist the cultivation of agricultural plants, green energy, environmental control greenhouses, fabrics for plant green energy control plants, plant grating green energy control fabrics, used in various environments in life.
  • Figure 1 is a schematic view showing a first embodiment of the manufacturing method of the present invention.
  • FIG. 2 is a schematic view of a second embodiment of the manufacturing method of the present invention.
  • Figure 3 is a schematic view showing a third embodiment of the manufacturing method of the present invention.
  • Figure 4 is a schematic cross-sectional view showing the fiber produced by the present invention.
  • Fig. 5 is a schematic view showing the fiber woven into an agricultural net produced by the present invention and its use.
  • the green energy ring-controlled fiber developed by the invention generates energy conduction ability when the fiber receives the external green energy, generates photoelectricity through the photoelectric material, generates piezoelectricity by the piezoelectric material, and generates amplitude by the thermoelectric material (far infrared material).
  • Resonance activates the energy-stimulated excitation of the catalytic material, and increases the energy catalysis of the electron-cavity energy level, which can effectively improve the efficiency of the pollutants in the catalytic catalytic environment, and generate light of 400-700 nm wavelength (such as far-infrared rays with a wavelength of 4 to 14 ⁇ m).
  • decomposition of moisture (humidity) in the air produces water oxygen anions.
  • the fiber woven fabric 20 of the present invention has a resonance friction amplifying effect and can produce an environmental control function, and the fabric 20 can be used as an organic agricultural green energy ring control fabric or a plant grating green energy environmental control fabric for assisting planting of plants. Please refer to Figure 5 as shown.
  • the fabric made of the fiber of the invention can be further applied to the health care green energy environment control fabric, the indoor air quality green energy environment control fabric (such as the air conditioner green energy ring control network), the soot equipment green energy environment control fabric (such as removing the oil smoke green energy) Environmental control network), geophysical green-green environmental control fabrics (such as geophysical planting nets planted under the soil and planted on the soil), defogging green energy-controlled fabrics (such as washing tower defogging green energy ring control network) ), air clean green energy ring control fabric (such as air cleaner green energy ring control network), screen window green energy ring control fabric (such as screen window ventilation green energy ring control network) and environmental pollution control green energy environmental control fabric (such as washing The equipment removes screens or fabrics for industrial equipment such as TVOCS, positive and negative ions.
  • the indoor air quality green energy environment control fabric such as the air conditioner green energy ring control network
  • soot equipment green energy environment control fabric such as removing the oil smoke green energy) Environmental control network
  • the fibers of the present invention are made of a polyolefine (such as polypropylene and polyethylene, and hydrocarbons are selected to reduce environmentally harmful materials), photovoltaic materials, piezoelectric materials, thermoelectric materials, and catalysts.
  • the material is processed into a processing material by twin-screw air-cooling granulation, melt-kneading, and the processed material is made into a fiber by a melt-spinning processing technique.
  • the fabric woven by the fiber receives natural energy such as external sunlight, air flow, heat energy, fiber vibration friction, air humidity, etc., and photoelectricity of the photoelectric material, piezoelectric effect of the piezoelectric material, and thermoelectric effect of the thermoelectric material. infrared).
  • thermoelectric effect piezoelectric effect, photocatalytic effect, redox effect, free electron effect, catalytic effect and slow release effect
  • the natural energy is increased to act on the catalytic material, so that the catalytic material can fully exert its performance, and the weight of each material
  • the ratio can be adjusted according to the needs of the user.
  • the main concept of the invention is to integrate the photoelectric material, the piezoelectric material, the thermoelectric material and the catalytic material into the fiber, so that the catalyst material in the fiber can generate an increasing effect when the fiber receives the natural energy.
  • the far-infrared rays having a wavelength range of 4 to 14 ⁇ m and the moisture (humidity) in the air are generated in the environment to generate water-oxygen anions.
  • the light effect is increased to increase plant growth and limit the wavelength of sunlight at wavelengths of 400-700 nm and increase the nighttime brightness of long afterglow.
  • the third is to reduce the plant diseases caused by the suppression of biological pollution sources such as total bacteria and mold in the air.
  • Fourth achieve the removal of chemicals in the air pollution (e.g. air vaporous contaminants HCHO, TVOCs, O 3, CO , CO 2, SO X, NO X, C X H Y, HCl, CS 2, CFC S, C m H n X x , etc.) to reduce chemical pollution, or to achieve the function of sedimentation physical pollution such as airborne particulate pollen, PM 2.5 , PM 10 and other suspended particles.
  • air pollution e.g. air vaporous contaminants HCHO, TVOCs, O 3, CO , CO 2, SO X, NO X, C X H Y, HCl, CS 2, CFC S, C m H n X x , etc.
  • the fifth achieves the effect of avoiding insects and protects plants from pest damage and infectious diseases.
  • Sixth, it achieves safe green energy-controlled fiber with flameproof, antistatic and conductive functions.
  • the green energy environmental control fiber of the invention has excellent effect and can be used for weaving the fabric to be applied to the agricultural green energy environmental control greenhouse room, the plant grating green energy ring control fabric, etc. and can be applied to various environmental green energy rings.
  • Control fabric equipment such as health care green energy environmental control fabric, indoor air quality green energy environmental control fabric, fume green energy control fabric, defogging green energy environmental control fabric, geotextile green energy environmental control fabric, air clean green energy ring Control fabrics, screens, green energy-controlled fabrics and environmental pollution control green energy environmental control fabrics, etc., for agricultural, industrial, fishing, animal husbandry and the people's death.
  • the invention produces a green energy ring-controlled fiber, and the photoelectric effect of the photoelectric material used is that electromagnetic radiation wave (such as ultraviolet light) is irradiated to the material, and photon absorption excites the free electron effect, mainly for accumulating long-lasting fluorescent phosphorescent material to generate photoelectric Having a light-converting light-storing functional material; basically having Zn 2 SiO 4 , CaSiO 3 , SiO 2 , TiO 2 , (SrBaMg) 3 Si 2 O 7 , CaWO 4 , MgWO 4 , LiAl 5 O 8 : Mn 4+ , CaAl 2 O 4 :Eu 2+ , Dy 3+ , CaAl 12 O 19 :Mn 4+ , SrAl 2 O 4 :Eu 2+ , Dy 3+ , Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ , SrAl 12 O 19 :Eu 2+ , Dy 3+ , BaMg 2 Al
  • the invention produces a green energy ring-controlled fiber, and the piezoelectric effect of the piezoelectric material used is due to a special arrangement between atoms in the crystal lattice, and a coupling effect between the stress field and the electric field.
  • Piezoelectric materials are basically quartz, cadmium sulfide, zinc oxide, aluminum nitride, ferroelectric crystal, barium titanate crystal, lithium niobate, barium strontium citrate, barium strontium silicate crystal, potassium dihydrogen phosphate, ammonium dihydrogen phosphate , lead hydrogen phosphate, lead strontium phosphate crystal, barium titanate crystal, barium titanate ceramic, lead zirconate titanate PZT and the like.
  • thermoelectric material used is a far-infrared material which receives external thermal radiation and can generate far-infrared rays having a wavelength of 4-14 ⁇ m on the spectrum, and the wavelength is larger than the wavelength of visible light, and is a kind of strong heat effect.
  • "Thermal induction" can.
  • thermoelectric material composition is substantially Al 2 O 3 , ZrO 2 , MgO, TiO 2 , SiO 2 , ZrC, SiC, B 4 C, TaC, TiB 2 , ZrB 2 , CrB 2 , TiSi 2 , MoSi 2 , WSi 2 , Si 3 N 4 , TiN, Fe 2 O, high temperature bamboo charcoal, preparation of charcoal, medical stone, Guiyang stone, volcanic rock, jade.
  • the invention produces a green energy ring-controlled fiber
  • the catalyst material used is a catalyst, which can accelerate the chemical reaction rate by providing another reaction energy with lower activation energy, and the quality, composition and chemical properties of itself participate in the chemical A substance that remains unchanged before and after the reaction.
  • the catalytic material components are mainly catalytic metals such as gold, platinum, palladium, rhodium, silver, iron, copper, titanium, nickel, tungsten, zinc, manganese, lanthanum, cerium, lanthanum, cerium, lanthanum, molybdenum, chromium, lanthanum, cerium, ⁇ , ⁇ , ⁇ , carbon nanotubes, etc.
  • oxidizing metal catalysts such as cerium oxide, zinc oxide, silicon oxide, titanium oxide, aluminum oxide, iron oxide, palladium oxide, magnesium oxide, zirconium oxide, nickel oxide, tin oxide, manganese oxide , chromium oxide, cerium oxide, cerium oxide, cerium oxide, and the like.
  • the invention produces green energy circulation control fiber, and the natural plant essential oil used is tea tree oil, bitter oil, lemon oil, wintergreen oil, eucalyptus oil, clove oil, peppermint oil, case leaf oil, citronella oil, pheasant pepper oil, Sage oil, eucalyptus oil, rose oil, jasmine oil, geranium oil, rose geranium oil, ylang-ylang oil, mastic oil, hoarfrost oil, rosemary oil, permanent flower oil, thyme oil, pine oil, cedar oil , Juniper oil, sandalwood oil, basil oil, lime oil, orange oil, orange oil, bitter orange oil, bitter orange leaf oil, neroli oil, foreign citrus oil, pheasant pepper oil, myrrh oil, cattle Knee grass oil, white layer oil, ginger oil, etc.
  • the natural plant essential oil used is tea tree oil, bitter oil, lemon oil, wintergreen oil, eucalyptus oil, clove oil, peppermint oil, case leaf oil, cit
  • the invention manufactures green energy ring control fiber, and the flame retardant fireproof materials used are antimony trioxide, magnesium hydroxide, red phosphorus, molybdenum compound, zinc borate, zinc stannate, decabromodiphenyl ether, octabromo ether, silicone , carbon black and so on.
  • the invention manufactures green energy ring control fiber, and the conductive antistatic material used is polyether, quaternary ammonium salt, sulfonate, betaine, conductive carbon black, carbon fiber, metal fiber, nickel-plated metal carbon fiber, nano carbon tube.
  • the basic characteristics of the green energy ring-control fiber green energy ring-controlled fiber of the invention using polyolefine (Polyolefine), photoelectric material, piezoelectric material, thermoelectric material and catalytic material, and depending on the proportion of each material and the structural strength requirement, whether to add or not Rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM)), which is melt-kneaded together to form a polyolefin-based functional material, and then the granular polyene functionality The material is melt-spun to form a fiber having a Danny number of 50 to 50,000 den.
  • Polyolefine Polyolefine
  • photoelectric material piezoelectric material
  • thermoelectric material and catalytic material and depending on the proportion of each material and the structural strength requirement, whether to add or not Rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM)
  • EPDM Ethylene-Propylene-Diene Monomer
  • the first polyolefin may be polypropylene (melt flow rate (MFR) ranging from 0.1 to 50 g/10 min, or the first polyolefin may be polyethylene (melt flow rate (Melt flow)
  • MFR melting flow rate
  • the characteristics of the photovoltaic material are light storage (3000-0.32 mcd/m 2 ) particle size distribution: 10 to 0.1 ⁇ m; the characteristics of the piezoelectric material are: piezoelectric coefficient (10 - 12 C/N) 0.1 to 1000, particle size distribution: 10 to 0.1 ⁇ m.
  • thermoelectric material The characteristics of the thermoelectric material are: the emissivity of far-infrared rays having a wavelength range of 4 to 14 ⁇ m is 0.85 to 0.99%, and the particle size distribution is 10 to 0.1 ⁇ m, three. Ethylene propylene acrylate (EPDM) (with Mooney viscosity (ML1+4, 125 ° C) 20 to 70).
  • EPDM Ethylene propylene acrylate
  • ML1+4, 125 ° C Mooney viscosity 20 to 70.
  • at least two ribs 11 are integrally formed on the surface of the fiber 10. The length of the rib 11 extends along the axial direction of the fiber, and the top of the rib 11 extends in a curve as viewed from a cross section of the fiber. In the example of FIG. 4, the two ribs 11 are smoothly connected to each other.
  • the curvature 12 of the curvature when the fiber receives the outside sunlight, the interaction of the photovoltaic material 30, the piezoelectric material 31, the thermoelectric material 32 and the catalytic material 33 in the fiber converts the daylight Color light required for plant growth, by the curvature of the ribs 11 and is scattered out of the irradiation to the plant, in order to promote plant growth.
  • the basic feature of the method for producing the green energy-controlled fiber of the present invention to achieve the above first to fourth objects is mainly to prepare 70% to 95% by weight of a poly-thick material such as poly.
  • a poly-thick material such as poly.
  • Propylene chips or polyethylene chips (Melt flow rate (MFR) ranging from 0.1 to 50 g/10 min) (the following respective examples of the present invention have a melt flow rate of 5 g/10 min and account for 70% or 80%) % by weight of polypropylene as an example), 1% to 10% by weight of photovoltaic material (the following examples of the invention are 10% by weight of photovoltaic material, particle size distribution: 0.3 ⁇ m, for example) 1% to 5% by weight of piezoelectric material (the following embodiments of the invention are 2% by weight of piezoelectric material, particle size distribution: 1 ⁇ m, for example), and 1% to 5% by weight of thermoelectricity Materials (the following embodiments of the invention are 2% by weight of thermoelectric
  • the granulation temperature is increased from 160 ° C to 250 ° C; when the polyethylene is a substrate, the granulation temperature is 260 ° C to 350 ° C. Further, a plurality of granular base materials are formed (the average particle diameter of the granular base material is smaller than 2-10mm), the plurality of granular base materials are passed through a single screw extruder to make the processed material by spinning, cooling, heat stretching and heat setting, wherein the polypropylene is used as a substrate, and the wire is drawn. The temperature is raised from 160 ° C to 250 ° C; when the polyethylene is used as the substrate, the spinning temperature is 260 ° C to 350 ° C.
  • the subsequent cooling temperature is -20 to 50 ° C
  • the draw ratio is 3 to 8 times
  • the hot water is extended.
  • the temperature is 80-120 ° C
  • the take-up speed is 40-180 rpm.
  • Propylene is used as a substrate, and its granulation processing temperature is 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C, and its fiber spinning temperature is 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C
  • the cooling temperature is 25 ° C
  • the hot water extension temperature is 100 ° C
  • the drafting ratio is 6 times
  • the winding speed is 120 rpm.
  • the aforementioned melt drawing is the addition
  • the material is heated and melted, and the molten material is extruded from the spinning hole into the cooling water, and is cooled at a constant speed while being cooled in the cooling water, and then hot-rolled at a multiple speed of hot water, and the material melt is fine at this stage.
  • Simultaneous solidification forms fibers and winds the fibers.
  • the spinnable polymer obtained in the polymerization step is extruded from the pores of the spinneret at a temperature higher than the melting point, cooled and refined into a filamentous solid, and simultaneously wound.
  • the basic characteristics of the method for producing the green energy ring control fiber of the present invention to achieve the green energy control fiber containing the insect-repellent effect of the fifth item mainly preparing 65% to 94% by weight.
  • Percentage of the polyolefin material (the corresponding embodiment of the present invention is exemplified by a melt flow rate of 5 g/10 min and 80% by weight of polypropylene), and secondly, a photovoltaic material is prepared in an amount of 1 to 5% by weight.
  • the basic feature of the method for manufacturing the safe green energy ring control fiber to achieve the foregoing sixth object (safe green energy ring control fiber with flameproof and conductive antistatic function), mainly preparing 55%. ⁇ 92% by weight of the polyolefin material (the corresponding examples of the present invention below are exemplified by a melt flow rate of 5 g/10 min and 70% by weight of polypropylene).
  • the photoelectric material 1 to 5% by weight of the piezoelectric material, 1 to 5% by weight of the thermoelectric material, 1 to 5% by weight of the catalytic material, and depending on the fiber ductility, strength and hardness.
  • rubber elastic material 1 to 5% by weight of 5% to 25% by weight in the embodiment of the invention, 2% by weight of the photoelectric material, particle size distribution: 0.3 ⁇ m; piezoelectric material 2% by weight , particle size distribution: 1 ⁇ m; thermoelectric material 2% by weight, particle size distribution: 1 ⁇ m; catalytic material accounted for 3% by weight, particle size distribution: 0.3 ⁇ m
  • rubber elastic material such as EPDM-Ethylene-Propylene- Diene Monomer (EPDM) accounts for 3% by weight (its Mooney viscosity is 60), that is, 12% by weight of photoelectric materials, piezoelectric materials, thermoelectric materials, catalytic materials and rubber elastic materials (EPDM) are used as examples.
  • thermoelectric material containing alumina Al 2 O 3 35.92%, magnesium oxide MgO 33.86%, Iron oxide Fe 2 O16.10%, titanium dioxide TiO 2 12.26% and silica SiO 2 2.86% oxide
  • catalyst material gold 30% / titanium oxide 30% / Zinc oxide 40%
  • the above materials are cooled and granulated by twin-screw mixing air (granulation temperature: 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to make a plurality of granular base materials as a kneading material. (average particle size is about 5mm), and the processed material of the granular base material is subjected to single-screw mixing temperature of 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C, and then the molten material is drawn.
  • the fibers were cooled by cooling at 25 ° C, hot stretching at 100 ° C, and winding at 120 rpm.
  • the test results of the present invention are as follows.
  • Example 1 For the tensile strength and tear strength test results of Example 1, please refer to Table 1: As the photoelectric material, piezoelectric material, thermoelectric material, catalytic material and EPDM content are more, the tensile strength will gradually decrease, but The required strength is still maintained, so that the photoelectric material, the piezoelectric material, the thermoelectric material, the catalytic material and the EPDM added by the present invention account for 20-30% of the total weight (the example of Table 1 is added by 20%). The light storage effect (Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ blue-green light 488 nm) has a benefit of 956 minutes.
  • the wavelength of 400-520 nm increased the growth of plant roots and stems, and absorbed the most chlorophyll and carotenoids, and had the greatest impact on photosynthesis.
  • the wavelength of 610 to 720 nm promotes photosynthesis and plant growth rate (CaAl 12 O 19 : Mn 4 + red light 656 nm).
  • the results of the far-infrared emissivity test of Example 1 are shown in Table 2.
  • the average emissivity of the far-infrared rays at 50 ° C of 3-15 ⁇ m was 0.968.
  • the average emissivity of the far-infrared rays of 3-15 ⁇ m in the environment of 5 ° C is 0.918.
  • Example 4 The results of the negative ion experiment of Example 1 are shown in Table 4: the fiber woven fabric of the present invention was tested; under dynamic friction, 2858 negative ions (/cc) in the air were increased.
  • the washing fastness test results of the first embodiment are shown in Table 5: the washing fastness test, the good fastness is maintained before and after the test, and the amount of negative ions generated is not reduced by washing.
  • test results of the green energy-controlled fiber fabric of the first embodiment for the removal of contaminants are shown in Table 6, Table 7, and Table 8.
  • Example 1 The antibacterial test result of Example 1 was 99.9% inhibition rate (R%), as shown in Table 9.
  • the processed material is then melted by a single screw (mixing temperature of 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is cooled, cooled at 25 ° C
  • the fiber was formed by heat stretching at 100 ° C and winding at 120 rpm.
  • the repellent test result repellent rate (90.3%), please refer to Table 12:
  • Example 13 The results of the essential oil component-gas chromatography mass spectrometer (GC/MS) of Example 2 are shown in Table 13.
  • the tested product is placed in a 1 cubic meter sealed test box, and the tested product is turned on for 1 hour.
  • the essential oil components of this product are shown in Table 13.
  • Test method connected to gas chromatography mass spectrometer (GC/MS) detection.
  • the processed material is then melted by a single screw (mixing temperature of 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is cooled, cooled at 25 ° C
  • the fiber was formed by heat stretching at 100 ° C and winding at 120 rpm.
  • the toxic gas content test result of the third embodiment in compliance with the regulations.
  • For toxic gas content please refer to Table 15: The Toxic Gas value in this report refers to the toxic gas content produced by the combustion test for 4 minutes.
  • the smoke concentration test result of the third embodiment in compliance with the regulations. Please refer to Table 18: D m is the maximum value of the measured smoke concentration within 4 minutes of the test time of the test sample. ABD0031 (2005) Issue: F specification requires that, under flaming or flameless test conditions, the maximum smoke concentration within 4 minutes of the test time should not exceed the specifications listed in Table 19.

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Abstract

一种绿能环控纤维、其制法及以该纤维制成的织品，其采用聚烯烃类材料、光电材料、热电材料、压电材料及触媒材料，经熔融混炼及熔融抽丝而制成纤维。织品由纤维织成。织品应用于各式环境控制品或有机农业环控制品。运用绿色能源如太阳光能、太阳热力能、风力能、水力能、地热能等再生能源激发织品的纤维内特殊材料的效能，以改善或去除环境中污染物而产生自净功能，达到改善环境状态或促进植物生长的目的。

Description

绿能环控纤维、其制法及以该纤维制成的织品 【技术领域】
本发明有关一种绿能环控纤维、其制法及以该纤维制成的织品，应用于有机环境控制农作产业如农业植物绿能环控温室及植物绿能环控工厂等，或应用于生活中环境控制设备如健康照护绿能环控织品、室内空气品质绿能环控织品、油烟绿能环控织品、地工植生绿能环控织品、除雾绿能环控织品、空气清净绿能环控织品、环境污染防治绿能环控织品等。运用环境中绿色能源，如太阳光能、太阳热能、风力能、水力能、地热能等再生能源，纤维材料接收环境中各式绿能辐射波产生自由电子效应，通过纤维内部组成有光电材料、热电材料及压电材料对绿能辐射波自然能量产生增幅作用进而作用于织品纤维中各类触媒材料，有效提升触媒材料的各类机能，使触媒纤维及制品通过绿能产生对植物生长有利的生长光线、水氧负离子、远红外线生长波、防治病虫害及对生长环境污染物去除沉降分解及洁净。
【先前技术】
因应人口增加所产生的粮食需求大增及粮食危机，人类想尽各种农作方法如基因改质、使用化学农药、化学肥料及生长激素、微生物肥料等来增加粮食产量。为了解决粮食需求大增及粮食危机的问题，目前所采用前述的农作方法也伴随着大量农药使用，以致环境污染日趋严重，恶劣的污染环境直接对人体健康造成伤害，而日后随着气候变迁及新的病虫害增加，反而更使农作物产量减少，土壤酸化恶性循环之下，粮食危机问题始终无法从根本解除。产量增加及有机栽种的需求，产生了农业环境及农作物的质与量，亟待解决及克服的课题。良好的自然环境资源有限，为了农业永续发展，根本上解决人类粮食缺乏的问题及提升食的安全与健康，人类应该学习大自然环境生生不息的自然循环原理。善加利用永续不断的绿色能源，将转换绿色能源发挥最大效益，运用材料特性及与绿色能源自然交互作用原理，以自然方式创造出合适有机环境控制的农业生产，才有机会根本解决前述现今农作方法所造成的恶性循环问题，以满足粮食需求及提供农作物食用上的安全。
虽然已知技术中，有在织物上添加触媒等机能性材料，藉触媒材料的作用而产生除臭及抗菌的功能。然而，已知技术一种方式是在织物表面涂覆机能性材料，不仅机能性材料在未能有效增幅下，而无法发挥其效 能，而且经一段时间使用便会脱落，此种技术的经济效益并不高。其他技术，例如美国第4,784,909号专利案，是在纤维内添加铜而有抗菌除臭的功能。例如美国第6,540,807号专利案，在织品中添加热塑性塑胶树脂及抗菌剂而具有抗菌功能。例如美国第5,690,922号专利案，是纤维添加金属磷酸盐及金属氢氧化物而具除臭功能。然而，前述的那些已知技术，纤维中的机能性材料在未能有效增幅下只能在有效空间内达到效益。再者，虽然有业者开发以LED灯来发射出有利于蓝光及红光植物生长的光线以供种植蔬果之用，惟使用LED灯因为需电力，且器具贵，相对地成本较高，不仅产生耗能问题，而且并无法防治病虫害，仍必须依赖农药或生物防治或需另外加装利用网目隔离虫害护网或采用密闭式塑胶棚、玻璃温室等方式，但仍无法有效做到环境控制的功效。
因此为达有效的环控农业生产及节能控制，本发明人等认为必须善用自然界存在且源源不绝的绿色能源，将绿色能源转换而创造出合适的农作物生长环境。例如采用绿色能源，善用绿色能源中的阳光，将阳光转换或增幅成植物生长所需要的光波，来增加有机网室农作物的产量；通过纤维材料中晶体能带效应，在纤维材料接收绿色能源后增幅纤维材料中的触媒材料的效能，不仅将阳光转换及增加所需的光线、将空气湿度细小化，有利于植物生长而且能防治植物病害及去除环境中污染物。再者，更可配合运用天然植物精油对虫害产生趋避功效，进而达到有机大量栽培的目的。以上就是本发明的概念及研发动机，也是值得积极投入研发的农业绿能环控材料，及可达到真正有机农业栽种生产及环境污染控制的技术，对于目前有机农业环境控制材料及粮食生产能源消耗等缺失与问题实能加以改善。
【发明内容】
本发明的第一目的，在于提供一种运用绿能以增加有机农业植物生长的环境控制纤维及其织品，通过该环境控制纤维的特殊材料性能来增加植物生长所需光波及转移有害光波或增加照射光波时间、将空气中湿气分解使水分子细小化(水氧负离子)而能更有效吸收水份、产生远红外线以提供植物生长光波及去除环境中污染物，藉以促进环境中阳光、水、空气及土壤对有机植物生产的质与量的提升。其技术手段是纤维以聚烯类材料为基材，而在内部混含包括有能产生电磁辐射波的光电效应的光电材料(蓄光长余晖萤光磷光材料)具有光转换蓄光机能、能致使应力场与电场产生耦合的压电效应的压电材料、能接收到外在热辐射而产生远红外线的热电材料及能加快化 学反应速率的触媒材料。当纤维接收外界的绿色能量如太阳光电能，则通过光电材料(如蓄光长余晖萤光磷光材料)的作用而产生植物生长所需光谱(400-700nm波长光线)，将对植物有害紫外线光转换为植物生长所需的400-700nm波长光线，并且蓄光能源供植物夜间生长，以促进植物生长。当纤维接收外界的绿色能量如太阳光热能或地热能，则通过热电材料的作用而在环境中产生促进植物生长波长为4～14μm的红外线能量波幅。当纤维接收外界的绿色能量如风力能，则通过压电材料于环境中产生压电性，分解空气中湿度的水力能以产生水氧负离子，使环境中产生雨林生态，提供植物更有效的水份吸收。触媒材料通过光电效应、热电效应及压电效应产生共振而将能量增幅以活化自由电子的活跃性，激发材料中电子电洞能阶活动的催化作用的增加，而使触媒材料更为有效地产生作用以去除环境污染物材料。
本发明的第二目的，在于提供一种具去除生物性污染物功能的绿能环控纤维及其织品。其技术手段为上述第一目的的绿能环控纤维内部混含能去除环境中生物性污染物的触媒材料。通过该种触媒材料的设置而使绿能环控纤维及其织品具有抑制环境中生物性污染源等机能，进而达到抑制环境中生物性污染源，如真菌类、细菌类及病毒类等污染源的功效与目的。
本发明的第三目的，在于提供一种具去除环境中化学性污染物功能的绿能环控纤维及其织品。其技术手段为上述第一目的的绿能环控纤维内部混含具有去除化学性污染物机能的触媒材料，具有去除环境中甲醛HCHO、总挥发性有机化合物TVOCs、一氧化碳CO、二氧化碳CO2、臭氧O3、醋酸、乙醛、氨气、正负离子(F-、Cl-、NO3 -、PO4 3-、SO4 2-、NH4 +)等化学性污染物机能。
本发明的第四目的，在于提供一种具去除环境中物理性污染物功能的绿能环控纤维。其技术手段为上述第一目的中的纤维内部混含具有沉降环境中物理性污染源的触媒材料，具有沉降环境中空气物理性污染源至地上，如花粉、PM2.5、PM10等悬浮微粒机能。
本发明的第五目的，在于提供一种具有芬多精防虫的绿能环控纤维。其技术手段为上述前四项目的的纤维内部混含具有趋避虫类功效的天然植物精油，材料中含有趋避虫类功效而达到防治虫类功效，并能产生植物芬多精，以利植物生长。
本发明的第六目的，在于提供一种具耐燃及导电抗静电功能的安全绿能环控纤维。其技术手段为上述五项目的中的纤维增加混含防火材料及导电抗静电功能的材料，而使纤维具有安全功能。
本发明的第七目的，在于提供一种应用有本发明的安全绿能 环控纤维的织品，其织品可为辅助培植农业植物绿能环控温室之用的织品、植物绿能环控工厂之用的织品、植物光栅绿能环控织品，应用于生活中各类环境控制设备之用的织品、健康照护绿能环控织品、室内空气品质绿能环控织品、油烟绿能环控织品、地工植生绿能环控织品、除雾绿能环控织品、空气清净绿能环控织品、或环境污染防治绿能环控织品。
【图式简单说明】
图1为本发明制造方法的第一种实施例示意图。
图2为本发明制造方法的第二种实施例示意图。
图3为本发明制造方法的第三种实施例示意图。
图4为本发明所制成纤维的一种断面结构示意图。
图5为本发明所制成纤维织成农业用网暨其使用示意图。
【实施方式】
本发明所研发的绿能环控纤维，当纤维接收外界的绿色能量时，纤维产生能量传导能力，通过光电材料产生光电性、压电材料产生压电性及热电材料(远红外线材料)产生波幅共振将能量增幅活化激发触媒材料，产生电子电洞能阶活动催化作用增加，可以有效提升激发触媒催化环境中污染物效能，并且产生400-700nm波长的光线(如波长4～14μm的远红外线)及分解空气中水份(湿度)产生水氧负离子。因此，本发明纤维织成的织品20具有共振摩擦增幅效果而能产生环境控制功能效果，其织品20可作为用以辅助培植植物的有机农业绿能环控织品或植物光栅绿能环控织品，请配合参看图5所示。本发明纤维制成的织品更可应用于健康照护绿能环控织品、室内空气品质绿能环控织品(如空调绿能环控网)、油烟设备绿能环控织品(如去除油烟绿能环控网)、地工植生绿能环控织品(如铺于泥土下方而于泥土上种植植物的地工植生网)、除雾绿能环控织品(如洗涤塔除雾绿能环控网)、空气清净绿能环控织品(如空气清净机绿能环控网)、纱窗绿能环控织品(如纱窗换气绿能环控网)及环境污染防治绿能环控织品(如水洗设备去除TVOCS、正负离子等工业设备用滤网或织品)。其基本特征的技术，为本发明的纤维由聚烯类材料(Polyolefine)(如聚丙烯及聚乙烯等，选择碳氢化合物减少对环境污染材料)、光电材料、压电材料、热电材料及触媒材料，经双螺杆风冷式造粒熔融混练制成加工材料，再将该加工材料经融熔抽丝加工技术制成纤维。使纤维所织成的织品，接收外界阳光照射、空气流动、热能、纤维震动摩擦、空气 湿度等自然能量，通过光电材料产生光电性、压电材料的压电效应及热电材料的热电效应(远红外线)。通过热电效应、压电效应、光催化效应、氧化还原效应、自由电子效应、触媒效应及缓释效应以对自然能量增幅而作用于触媒材料，使触媒材料充份发挥其效能，各材料的重量配比可依使用者的需求而调整，本发明主要概念是整合光电材料、压电材料、热电材料及触媒材料应用于纤维，使纤维接收自然能源时，其内的触媒材料能产生增幅功效。首先使环境中产生波长范围4～14μm的远红外线及分解空气中水份(湿度)，产生水氧负离子。其次达到光效应增加植物生长及限制阳光波长在400-700nm波长光线并且增加长余晖夜间亮度。第三达到抑制生物污染源如空气中总细菌及霉菌等减少植物病害。第四达到去除空气中化学污染源(如空气中汽状污染物HCHO、TVOCs、O3、CO、CO2、SOX、NOX、CXHY、HCl、CS2、CFCS、CmHnXx等)以减少化学污染，或达到沉降物理性污染如空气中粒状污染物花粉、PM2.5、PM10等悬浮微粒的机能。第五达到趋避虫类功效使植物免于虫害危害及传染病菌。第六达到具有耐燃及抗静电、导电功能的安全绿能环控纤维。本发明绿能环控纤维具有效果极佳的机能性，可供织造成织品以应用于农业绿能环控温室网室、植物光栅绿能环控织品等并且可应用于各类环境绿能环控织品设备如健康照护绿能环控织品、室内空气品质绿能环控织品、油烟绿能环控织品、除雾绿能环控织品、地工植生绿能环控织品、空气清净绿能环控织品、纱窗绿能环控织品及环境污染防治绿能环控织品等，供农、工、渔、牧产业及民生广泛使用。
本发明制造绿能环控纤维，所采用的光电材料的光电效应是电磁辐射波(如紫外线光)照射到材料，而产生光子吸收激发自由电子效应，主要为蓄光长余晖萤光磷光材料产生光电性具有光转换蓄光机能材料；基本上有Zn2SiO4、CaSiO3、SiO2、TiO2、(SrBaMg)3Si2O7、CaWO4、MgWO4、LiAl5O8:Mn4+、CaAl2O4:Eu2+,Dy3+、CaAl12O19:Mn4+、SrAl2O4:Eu2+,Dy3+、Sr4Al14O25:Eu2+,Dy3+、SrAl12O19:Eu2+,Dy3+、BaMg2Al16O27、CeMgAl11O19、MgAl2O4、GdAlO3、Y2O3、YVO4、SrB4O7F、MgGa2O4、MgGa2O4、BeO、MgO、Al2O3、MgAl2O4、GeO2SnO2ZnO、Sc2O3、La2O3、Sm2O3、Gd2O3、Dy2O3、ZrO2、CdS及WO3等。
本发明制造绿能环控纤维，所采用的压电材料的压电效应是因晶格内原子间特殊排列方式，而有应力场与电场的耦合效应。压电材料基本上有石英、硫化镉、氧化锌、氮化铝、铁电晶体、钛酸钡晶体、铌酸锂、铌酸钽、铌酸锶钡晶体、磷酸二氢钾、磷酸二氢铵、磷酸氢铅、磷酸氘铅晶体、钛酸铋晶体、钛酸钡陶瓷、锆钛酸铅PZT等。
本发明制造绿能环控纤维，所采用的热电材料为远红外线材料接收到外在热辐射可产生光谱上4-14μm波长的远红外线，波长大于可见光的波长，是一种具有强热作用的“热感应“能。热电材料成分基本上为Al2O3、ZrO2、MgO、TiO2、SiO2、ZrC、SiC、B4C、TaC、TiB2、ZrB2、CrB2、TiSi2、MoSi2、WSi2、Si3N4、TiN、Fe2O、高温竹炭、备长炭、麦饭石、桂阳石、火山岩、玉石。
本发明制造绿能环控纤维，所采用的触媒材料为催化剂，是能透过提供另一活化能较低的反应途径，而加快化学反应速率，而本身的质量、组成和化学性质在参加化学反应前后保持不变的物质。触媒材料成分主要为触媒金属如金、铂、钯、铑、银、铁、铜、钛、镍、钨、锌、锰、锗、铋、钌、锇、铱、钼、铬、镧、铈、镨、钕、钷、纳米碳管等及氧化金属触媒如氧化锗、氧化锌、氧化硅、氧化钛、氧化铝、氧化铁、氧化钯、氧化镁、氧化锆、氧化镍、氧化锡、氧化锰、氧化铬、氧化铈、氧化钕、氧化钇等。
本发明制造绿能环控纤维，所采用的天然植物精油有茶树油、苦炼油、柠檬油、冬青油、樟树油、丁香油、薄荷油、案叶油、香茅油、山鸡椒油、鼠尾草油、尤加利油、玫瑰油、茉莉油、天竺葵油、玫瑰天竺葵油、依兰油、乳香油、广霍香油、迷迭香油、永久花油、百里香油、松树油、雪松油、杜松油、檀香油、萝勒油、莱姆油、桔油、甜橙油、苦橙油、苦橙叶油、橙花油、洋柑橘油、山鸡椒油、没药油、牛膝草油、白千层油、姜油等。
本发明制造绿能环控纤维，所采用的阻燃防火材料有三氧化二锑、氢氧化镁、红磷、钼化合物、硼酸锌、锡酸锌、十溴二苯醚、八溴醚、有机硅、炭黑等。
本发明制造绿能环控纤维，所采用的导电抗静电材料有聚醚类、季铵盐类、磺酸盐、甜菜碱类、导电炭黑、碳纤维、金属纤维、镀镍金属碳纤维、纳米碳管。
本发明绿能环控纤维绿能环控纤维的基本特征：采用聚烯类(Polyolefine)、光电材料、压电材料、热电材料及触媒材料，并视各材料比例多寡及结构强度需求决定是否添加橡胶弹性材料(如三元乙丙胶(Ethylene-Propylene-Diene Monomer，EPDM))，将该等材料一起熔融混练制成聚烯类功能性材料后，再将颗粒状的聚烯类功能性材料，熔融抽丝制成丹尼数为50～50000den的纤维。其中，第一聚烯类可以是聚丙烯(其熔融流率(Melt flow rate,MFR)范围为0.1～50g/10min，或是第一聚烯类可以是聚乙烯(其熔融流率(Melt flow rate,MFR)范围为0.1～50g/10min。光电材 料的特性为蓄光性(3000-0.32mcd/m2)粒径分布：10～0.1μm；压电材料的特性为：压电系数(10-12C/N)0.1～1000，粒径分布：10～0.1μm。热电材料的特性为：波长范围4～14μm的远红外线的放射率0.85～0.99％，粒径分布：10～0.1μm、三元乙丙胶(EPDM)(其门尼粘度(ML1+4,125℃)20～70)。如图4所示，一种较佳实施例中，该纤维10表面一体成形有至少两个凸条11，该凸条11长度沿着该纤维的轴向延伸，且由该纤维横断面观察，该凸条11顶部呈曲线延伸，图4示例中两个凸条11之间滑顺地相接有一具曲度的凹陷12，当纤维接收外界日光，纤维中的光电材料30、压电材料31、热电材料32及触媒材料33的交互作用而将日光转换为植物生长所需的颜色光线，经由凸条11的曲度而散射出来而照射至植物，以促进植物生长。
请配合参看图1所示，本发明制造绿能环控纤维达到前述第一至第四目的的方法的基本特征，主要是准备70％～95％重量百分比作为基材的聚稀类材料如聚丙烯碎片或聚乙烯碎片(熔融流率(Melt flow rate,MFR)范围为0.1～50g/10min)(本发明以下各对应的实施例，为以熔融流率为5g/10min且占70％或80％重量百分比的聚丙烯为例做说明)、1％～10％重量百分比的光电材料(本发明以下各项实施例以光电材料10％重量百分比，粒径分布：0.3μm，为例做说明)、1％～5％重量百分比的压电材料(本发明以下各项实施例以压电材料2％重量百分比，粒径分布：1μm，为例做说明)、1％～5％重量百分比的热电材料(本发明以下各项实施例以热电材料2％重量百分比，粒径分布：1μm，为例做说明)及1％～5％重量百分比的触媒材料(本发明以下各项实施例以触媒材料占3％重量百分比，粒径分布：0.3μm，为例做说明)，并视纤维延展性、强度及硬度需要选择是否添加橡胶弹性材料(如三元乙丙橡胶(Ethylene-Propylene-Diene Monomer，EPDM)1％～5％重量百分比(本发明以下各项实施例以EPDM占3％重量百分比(门尼粘度60)为例做说明)。将前述的材料混合以风冷式双螺杆混练造粒，其中聚丙烯为基材时，其制粒温度160℃～250℃增温；聚乙烯为基材时，其制粒温度260℃～350℃。进而制成复数个颗粒状母材(该颗粒状母材的平均粒径小于2-10mm)，将该复数个颗粒状母材透过单螺杆押出机使该加工材料经抽丝、冷却、热延伸、加热定型制成纤维。其中，聚丙烯为基材时，其抽丝温度160℃～250℃增温；聚乙烯为基材时，其抽丝温度为260℃～350℃。其后冷却温度为-20～50℃，牵伸倍率为3～8倍，热水延伸温度为80～120℃，卷取速度为40～180rpm。本发明具体操作的实施例中以聚丙烯为基材，其制粒加工温度180℃/200℃/210℃/220℃/230℃/240℃，其纤维抽丝温度200℃/210℃/220℃/230℃/240℃/250℃，冷却温度25℃，热水延伸温度100℃，牵伸倍率为6倍，卷取速度120rpm。前述熔融抽丝是将该加 工材料加热熔融，熔融从喷丝孔挤出进入冷却水中，在冷却水中冷却的同时，以一定速度卷取，再进行热水热拉伸数倍速度卷取，在该阶段加工材料熔体细化的同时凝固即形成纤维，将纤维卷绕。熔融抽丝工程，是将在聚合工序制得的具有可纺性的聚合物在其熔点以上的温度从喷丝板细孔挤出，冷却细化成丝状固体，同时进行卷绕。
请配合参看图2所示，本发明制造绿能环控纤维达成前述第五项目的(含有趋避虫类功效的绿能环控纤维)的方法的基本特征，主要是准备65％～94％重量百分比的聚烯类材料(本发明以下各项对应的实施例以熔融流率为5g/10min，且占80％重量百分比的聚丙烯为例做说明)，其次准备光电材料1～5％重量百分比、压电材料1～5％重量百分比、热电材料1～5％重量百分比、触媒材料1～5％重量百分比及视纤维延展性、强度及硬度需要选择是否添加橡胶弹性材料1～5％重量百分比共占5％～25％重量百分比(本发明实施例中以光电材料占2％重量百分比，粒径分布：0.3μm；压电材料占2％重量百分比，粒径分布：1μm；热电材料占2％重量百分比，粒径分布：1μm；触媒材料占3％重量百分比，粒径分布：0.3μm，橡胶弹性材料(如三元乙丙橡胶(Ethylene-Propylene-Diene Monomer，EPDM)占3％重量百分比(其门尼粘度60)。即光电材料、压电材料、热电材料、触媒材料及EPDM共占12％重量百分比，为具例做说明)，天然植物精油1～10％(本发明以下各项试验以天然植物精油8％重量百分比为例做说明)。
请配合参看图3所示，本发明制造安全绿能环控纤维以达成前述第六目的(具耐燃及导电抗静电功能的安全绿能环控纤维)的方法的基本特征，主要是准备55％～92％重量百分比的聚烯类材料(本发明以下各项对应的实施例以熔融流率为5g/10min，且占70％重量百分比的聚丙烯为例做说明)。其次准备光电材料1～5％重量百分比、压电材料1～5％重量百分比、热电材料1～5％重量百分比、触媒材料1～5％重量百分比及，并视纤维延展性、强度及硬度需要选择是否添加橡胶弹性材料1～5％重量百分比共占5％～25％重量百分比(本发明实施例中，以光电材料2％重量百分比，粒径分布：0.3μm；压电材料2％重量百分比，粒径分布：1μm；热电材料2％重量百分比，粒径分布：1μm；触媒材料占3％重量百分比，粒径分布：0.3μm，橡胶弹性材料(如三元乙丙橡胶(Ethylene-Propylene-Diene Monomer，EPDM)占3％重量百分比(其门尼粘度60)。即光电材料、压电材料、热电材料、触媒材料及橡胶弹性材料(EPDM)共占12％重量百分比为例做说明)。并准备天然植物精油1～5％重量百分比(本发明以下各项试验以天然植物精油3％重量百分比为例做说明)。准备防火材料1～10％重量百分比，粒径分布：10～0.1μm(本发明以下各项对应的实施例以防 火材料10％重量百分比为例做说明)。准备导电抗静电材料1～5％重量百分比，其粒径分布：10～0.1μm(本发明以下各项对应的实施例以导电抗静电材料占5％重量百分比为例做说明)。
本发明的实施例一，取80％重量百分比的聚丙烯(熔融流率5g/10min)、10％重量百分比的光电材料(Sr4Al14O25:Eu2+,Dy3+)粉末(粒径0.3μm)、2％重量百分比的压电材料(钛酸钡陶瓷)粉末(粒径1μm)、2％重量百分比的热电材料(含有氧化铝Al2O335.92％、氧化镁MgO 33.86％、氧化铁Fe2O16.10％、二氧化钛TiO2 12.26％及二氧化硅SiO2 2.86％等氧化物)粉末(粒径1μm)、3％重量百分比的触媒材料(金30％/氧化钛30％/氧化锌40％)粉末(粒径0.3μm)，及EPDM占3％重量百分比(其门尼粘度60)。将前述材料以双螺杆混练风冷却造粒(造粒温度为180℃/200℃/210℃/220℃/230℃/240℃)而制成复数个颗粒状母材做为混练加工材料(平均粒径约5mm)，再将颗粒状母材的加工材料以单螺杆混练温度为200℃/210℃/220℃/230℃/240℃/250℃，再将熔融加工材料经抽丝、冷却25℃、热延伸100℃、卷绕120rpm制成纤维。本发明的试验结果如下。
实施例一的抗拉强度及撕裂强度试验结果，请参看表1所示：随着光电材料、压电材料、热电材料、触媒材料及EPDM含量越多，其抗拉强度将逐渐下降，但仍保有要求的强度，因而本发明所添加的光电材料、压电材料、热电材料、触媒材料及EPDM占整体重量的20-30％为较佳(表1实例共添加20％做说明)。蓄光效果(Sr4Al14O25:Eu2+,Dy3+蓝绿光488nm)有956分钟效益。400～520nm波长有增加植物根、茎部位发展，对叶绿素与类胡萝卜素吸收最大，对光合作用影响最大。610～720nm波长促进对光合作用与植物生长速度(CaAl12O19:Mn4+红光656nm)。
Figure PCTCN2014087310-appb-000001
实施例一的远红外线放射率试验结果，请参看表2所示：远红外线放射率试验中，在50℃远红外线3-15μm的平均放射率为0.968。在5℃环境下其远红外线3-15μm平均放射率为0.918。
Figure PCTCN2014087310-appb-000002
实施例一的远红外线实验结果，请参看表3所示；以本发明所 制纤维织成织品的远红外线人体生理实验；使用在健康照护织品上具有30分钟后升温2.9℃。
Figure PCTCN2014087310-appb-000003
实施例一的负离子实验结果，请参看表4所示：以本发明所制纤维织成织品进行试验；动态摩擦下可增加空气中2858负离子(个/cc)。
Figure PCTCN2014087310-appb-000004
实施例一的水洗牢度试验结果，请参看表5所示：水洗牢度试验，测试前后仍维持良好的坚牢度，负离子的产生量并未因水洗而减少。
Figure PCTCN2014087310-appb-000005
实施例一的绿能环控纤维织品对于污染物去除的测试结果如表6、表7及表8所示。其测试方式：风道中织品材料两侧的入风口及出风口位置测试，织品的样品外框尺寸(英吋)＝24”*24”*2”；织品材料面积:(4片)*1M2，风速：1M/S；温度26℃；湿度62％RH。
实施例一的空气中总挥发有机物去除测试结果，请参看表6所 示。
Figure PCTCN2014087310-appb-000006
实施例一的室内空气品质(污染物去除测试)结果，请参看表7所示。测试仪器请参看表7-1所示。
Figure PCTCN2014087310-appb-000007
Figure PCTCN2014087310-appb-000008
实施例一的空气中正负离子污染物去除测试效率结果，请参看表8所示。
Figure PCTCN2014087310-appb-000009
实施例一的抗菌测试结果99.9％抑菌率(R％)，请参看表9所示。
Figure PCTCN2014087310-appb-000010
实施例一的防霉测试结果(0:没有滋生霉菌)，请参看表10所示。
Figure PCTCN2014087310-appb-000011
本发明的实施例二，取80％重量百分比的聚丙烯(熔融流率5g/10min)、2％重量百分比的光电材料(Sr4Al14O25:Eu2+,Dy3+)粉末(平均粒径0.3μm)、2％重量百分比的压电材料(钛酸钡陶瓷)粉末(平均粒径1μm)、2％重量百分比的热电材料(含有氧化铝Al2O335.92％、氧化镁MgO 33.86％、氧化铁Fe2O16.10％、二氧化钛TiO2 12.26％及二氧化硅SiO2 2.86％重量百分比等氧化物)粉末(平均粒径1μm)、3％重量百分比的触媒材料(金30％/氧化钛30％/氧化锌40％重量百分比)粉末(平均粒径0.3μm)、EPDM占3％重量百分比(门尼粘度60)及8％重量百分比的植物精油材料(尤加利20％、柠檬30％及茶树精油50％)，将前述全部材料以双螺杆混练风冷却造粒(造粒温度为180℃/200℃/210℃/220℃/230℃/240℃)而制成复数个颗粒状母材(平均粒径约5mm)做为加工材料。再将加工材料以单螺杆混练(混练温度为200℃/210℃/220℃/230℃/240℃/250℃)而形成熔融加工材料，再将熔融加工材料经抽丝、25℃冷却、100℃热延伸及以120rpm转速卷绕而制成纤维。
实施例二的织品的物理性，请参看表11所示：
Figure PCTCN2014087310-appb-000012
实施例二的尘螨忌避试验结果忌避率(90.3％)，请参看表12所示：
Figure PCTCN2014087310-appb-000013
实施例二的精油成分-气相层析质谱仪(GC/MS)检测结果，请参看表13所示。将受测产品架设于1立方米的密闭测试箱中，并开启受测产品运转1小时测试。可得本商品精油成分如表13。测试方法：连接气相层析质谱仪(GC/MS)检测。
Figure PCTCN2014087310-appb-000014
本发明的实施例三，取70％重量百分比的聚丙烯(熔融流率5g/10min)、2％重量百分比的光电材料(Sr4Al14O25:Eu2+,Dy3+)粉末(平均粒径0.3μm)、2％重量百分比的压电材料(钛酸钡陶瓷)粉末(平均粒径1μm)、2％重量百分比的热电材料(含有氧化铝Al2O335.92％、氧化镁MgO 33.86％、氧化铁Fe2O16.10％、二氧化钛TiO2 12.26％及二氧化硅SiO2 2.86％等氧化物)、3％重量百分比的触媒材料(金30％/氧化钛30％/氧化锌40％)粉末(平均粒径0.3μm)、EPDM占3％重量百分比(门尼粘度60)、3％重量百分比的植物精油材料(尤加利20％、柠檬30％及茶树精油50％重量百分比)、10％重量百分比的防火材料(氢氧化镁90％及三氧化二锑10％重量百分比，粒径0.5μm)及5％重量百分比的导电抗静电材料 (导电炭黑，粒径0.2μm)，将前述全部材料以双螺杆混练风冷却造粒(造粒温度为180℃/200℃/210℃/220℃/230℃/240℃)而制成复数个颗粒状母材(平均粒径约5mm)做为加工材料。再将加工材料以单螺杆混练(混练温度为200℃/210℃/220℃/230℃/240℃/250℃)而形成熔融加工材料，再将熔融加工材料经抽丝、25℃冷却、100℃热延伸及以120rpm转速卷绕而制成纤维。
实施例三的毒性气体含量测试结果:符合规定。毒性气体含量，请参看表15所示：本报告Toxic Gas值，指燃烧测试4分钟产生的毒性气体含量。ABD0031(2005)ISSUE：F的要求：已检知管(Detection tube)量测HF<100，HCl<150，HCN<150，SO2<100，XO2<100，CO<1000。
Figure PCTCN2014087310-appb-000015
实施例三的水平燃烧测试结果测试结果:符合规定。请参看表16所示。FAR 25.853(b)(Amdt.25-116,2004)&Appendix F Par I(a)(1)(ii)。火焰时间(Flame Time)：≦15Sec；滴灌火焰时间(Drip Flame Time)：≦5Sec；燃烧长度(Burn Length)：≦8in(203.2mm)。
Figure PCTCN2014087310-appb-000016
实施例三的垂直燃烧测试结果测试结果:符合规定。请参看表17所示。FAR 25.853附录Appendix F Amdt.25-111。te(10)＝te(11.5)-te(1.5)。
Figure PCTCN2014087310-appb-000017
实施例三的烟浓度测试结果:符合规定。请参看表18所示：Dm为测试样品在测试时间4分钟内，所测得烟浓度的最大值。ABD0031(2005)Issue：F规范要求：在有焰或无焰的测试条件下，测试时间4分钟内的最大烟浓度不应超 过表19所列的规范值。
Figure PCTCN2014087310-appb-000018
Figure PCTCN2014087310-appb-000019
实施例三的导电抗静电测试结果:R＝5.8x105Ω，请参看表20所示。
Figure PCTCN2014087310-appb-000020
以上所述，仅为本发明的一可行实施例，并非用以限定本发明的专利范围，凡举依据下列请求项所述的内容、特征以及其精神而为之其他变化的等效实施，皆应包含于本发明的专利范围内。本发明所具体界定于请求项的结构特征，未见于同类物品，且具实用性与进步性，已符合创作专利要件，爰依法具文提出申请，谨请审查员依法核予专利，以维护本申请人合法的权益。
【符号说明】
纤维10；凸条11；凹陷12；织品20；光电材料30；压电材料31；热电材料32；触媒材料33。

Claims (10)

  1. 一种绿能环控纤维的制法，其采用作为基材的聚烯类材料、能产生电磁辐射波的光电效应的光电材料、能致使应力场与电场产生耦合的压电效应的压电材料、能接收到外在热辐射而产生远红外线的热电材料及能加快化学反应速率的触媒材料为一配方材料，将所述配方材料熔融混练之后再熔融抽丝制成纤维。
  2. 如请求项1所述的制法，其中，所述聚烯类材料占70～95％重量百分比，其熔融流率范围为0.1～50g/10min；所述光电材料占1％～10％重量百分比的、所述压电材料占1％～5％重量百分比的、所述热电材料占1％～5％重量百分比、所述触媒材料占1％～5％重量百分比，且配合添加橡胶弹性材料占1％～5％重量百分比。
  3. 如请求项1所述的制法，其中，所述配方材料更包含1～10％重量百分比的具趋避虫类功效的天然植物精油及1％～5％重量百分比的橡胶弹性材料；所述聚烯类材料占65～94％重量百分比，其熔融流率范围为0.1～50g/10min；所述光电材料占1％～5％重量百分比；所述压电材料占1％～5％重量百分比；所述热电材料占1％～5％重量百分比；所述触媒材料占1％～5％重量百分比。
  4. 如请求项1所述的制法，其中，所述配方材料更包含有占1～5％重量百分比的具趋避虫类功效的天然植物精油、占1～10％重量百分比的防火材料、占1～5％重量百分比的导电抗静电材料及1％～5％重量百分比的橡胶弹性材料；所述聚烯类材料占55～92％重量百分比；所述光电材料占1％～5％重量百分比；所述压电材料占1％～5％重量百分比；所述热电材料占1％～5％重量百分比；所述触媒材料占1％～5％重量百分比。
  5. 如请求项4所述的制法，其中，所述防火材料选自氢氧化镁、三氧化二锑、红磷、钼化合物、硼酸锌、锡酸锌、十溴二苯醚、八溴醚、有机硅及炭黑至少其中一种；所述导电抗静电材料选自导电炭黑、聚醚类、季铵盐类、磺酸盐、甜菜碱类、碳纤维、金属纤维、镀镍金属碳纤维及纳米碳管至少其中一种。
  6. 如请求项1～5任一项所述的制法，其中，所述聚烯类材料选自聚丙烯及聚乙烯其中一种；所述光电材料选自Zn2SiO4、CaSiO3、SiO2、TiO2、 (SrBaMg)3Si2O7、CaWO4、MgWO4、LiAl5O8:Mn4+、CaAl2O4:Eu2+,Dy3+、CaAl12O19:Mn4+、SrAl2O4:Eu2+,Dy3+、Sr4Al14O25:Eu2+,Dy3+、SrAl12O19:Eu2+,Dy3+、BaMg2Al16O27、CeMgAl11O19、MgAl2O4、GdAlO3、Y2O3、YVO4、SrB4O7F、MgGa2O4、MgGa2O4、BeO、MgO、Al2O3、MgAl2O4、GeO2SnO2ZnO、Sc2O3、La2O3、Sm2O3、Gd2O3、Dy2O3、ZrO2、CdS及WO3至少其中一种；所述压电材料选自石英、硫化镉、氧化锌、氮化铝、铁电晶体、钛酸钡晶体、铌酸锂、铌酸钽、铌酸锶钡晶体、磷酸二氢钾、磷酸二氢铵、磷酸氢铅、磷酸氘铅晶体、钛酸铋晶体、钛酸钡陶瓷及锆钛酸铅至少其中一种；所述热电材料选自Al2O3、ZrO2、MgO、TiO2、SiO2、ZrC、SiC、B4C、TaC、TiB2、ZrB2、CrB2、TiSi2、MoSi2、WSi2、Si3N4、Fe2O、高温竹炭、备长炭、麦饭石、桂阳石、火山岩及玉石至少其中一种；所述触媒材料选自金、铂、钯、铑、银、铁、铜、钛、镍、钨、锌、锰、锗、铋、钌、锇、铱、钼、铬、镧、铈、镨、钕、钷、纳米碳管、氧化锗、氧化锌、氧化硅、氧化钛、氧化铝、氧化铁、氧化钯、氧化镁、氧化锆、氧化镍、氧化锡、氧化锰、氧化铬、氧化铈、氧化钕及氧化钇至少其中一种。
  7. 一种以如请求项1所述的制法所制成的绿能环控纤维，所述纤维以所述聚烯类材料为基材，而于内部混含有所述光电材料、所述压电材料、所述热电材料及所述触媒材料；当所述纤维接收外界的能量时，通过所述光电材料产生光电效应、所述压电材料产生压电效应及所述热电材料产生波幅共振而将能量增幅以活化激发所述触媒材料，增进所述触媒材料的效能。
  8. 如请求项7所述的纤维，其中，所述纤维的丹尼数为50～50000den。
  9. 如请求项7所述的纤维，其中，所述纤维表面一体成形有至少两个凸条，所述凸条长度沿着所述纤维的轴向延伸，且由所述纤维横断面观察，所述凸条顶部呈曲线延伸。
  10. 一种以如请求项7所述的纤维制成的织品，所述织品选自辅助培植农业植物绿能环控温室之用的织品、植物绿能环控工厂之用的织品、植物光栅绿能环控织品，应用于生活中各类环境控制设备之用的织品、健康照护绿能环控织品、室内空气品质绿能环控织品、油烟绿能环控织品、地工植生绿能环控织品、除雾绿能环控织品、空气清净绿能环控织品、环境污染防治绿能环控织品其中一种。
PCT/CN2014/087310 2014-09-24 2014-09-24 绿能环控纤维、其制法及以该纤维制成的织品 WO2016045013A1 (zh)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245127A (zh) * 2016-08-03 2016-12-21 三德亿顺商贸(深圳)有限公司 一种天然纳米矿物石粉功能纤维及一种功能性热能棉
CN108193325A (zh) * 2017-12-27 2018-06-22 江西嘉捷信达新材料科技有限公司 含锆耐高温碳化硅纤维及其制备方法
JP2020528100A (ja) * 2017-07-26 2020-09-17 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ 蛍光体および組成物
JP2020528486A (ja) * 2017-07-26 2020-09-24 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ 組成物

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2930592A1 (en) * 2015-05-22 2016-11-22 Delta M Incorporated Decomposable air filter and method for manufacturing same
US11122752B1 (en) 2015-11-24 2021-09-21 Tree Defender, Llc Plant cover with insect resistant bag for enclosing a plant
US20180235155A1 (en) * 2016-02-29 2018-08-23 Sharp Kabushiki Kaisha Plant cultivation method and plant cultivation device
JP2021512228A (ja) * 2018-02-05 2021-05-13 ザ・ボード・オブ・トラスティーズ・オブ・ザ・リーランド・スタンフォード・ジュニア・ユニバーシティ 受動的放射性屋外個人冷却用のスペクトル選択的織物
CN110180498A (zh) * 2019-05-23 2019-08-30 江苏省农业科学院 载镧磁性水热生物炭吸附剂的制备方法及应用
WO2021099233A1 (en) * 2019-11-18 2021-05-27 Merck Patent Gmbh Method for fabricating a particle
WO2021110999A1 (en) * 2019-12-06 2021-06-10 Solvay Sa Use of aluminates in a greenhouse film for plant growth
JP7506398B2 (ja) 2020-07-31 2024-06-26 住江織物株式会社 光照射により防蚊可能な布帛及び該光照射による防蚊可能な布帛を用いた防蚊方法
US20240081152A1 (en) * 2021-01-25 2024-03-07 Sabic Global Technologies B.V. Piezoelectric textiles produced via electrospinning
CN113115791A (zh) * 2021-04-20 2021-07-16 工谷环保科技(浙江)有限公司 一种负载Ag/ZnO纳米粒子的竹炭杀菌材料及其制备方法
CN114797767A (zh) * 2022-03-21 2022-07-29 珠江水利委员会珠江水利科学研究院 一种改性叶生物炭及其制备方法和应用
CN115354415B (zh) * 2022-09-01 2024-02-20 陈培忠 一种抗静电功能纤维及其制备方法
KR102638895B1 (ko) * 2023-03-23 2024-02-20 강선아 기능성 섬유의 제조 방법
CN118543355B (zh) * 2024-07-30 2024-10-01 生态环境部华南环境科学研究所(生态环境部生态环境应急研究所) 一种Ce-Cu复合生物质炭基催化臭氧氧化催化剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020014716A1 (en) * 2000-04-04 2002-02-07 Seok Mi Soo Method of producing fiber having functional mineral powder and fiber produced therefrom
CN1766184A (zh) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 一种功能性聚丙烯纤维及其制备方法
CN102380980A (zh) * 2011-07-27 2012-03-21 江南大学 一种自净化纺织品及其加工方法
CN102676082A (zh) * 2011-03-11 2012-09-19 艾普特佩克股份有限公司 纤维、纤维聚集体以及具有所述纤维聚集体的粘着剂

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61282419A (ja) * 1985-05-31 1986-12-12 Kanebo Ltd 難燃性ポリエチレンフイラメント
DE3923086A1 (de) * 1989-07-13 1991-01-24 Hoechst Ag Antistatisches kern-mantel-filament
JPH0827624A (ja) * 1994-07-06 1996-01-30 Suzuki Sogyo Co Ltd 害虫忌避・脱臭・抗菌繊維及びその使用方法
JP3514333B2 (ja) * 1994-11-01 2004-03-31 根本特殊化学株式会社 蓄光性蛍光を有する繊維製品
JP3215318B2 (ja) * 1995-02-15 2001-10-02 武田薬品工業株式会社 消臭性繊維およびその製造方法
AU692049B2 (en) * 1995-02-15 1998-05-28 Japan Envirochemicals, Ltd. Deodorizable fibers and method of producing the same
JPH11228323A (ja) * 1998-02-18 1999-08-24 Sumitomo Chem Co Ltd 衣料用防虫剤
JP3054866B1 (ja) * 1998-12-14 2000-06-19 キョーワ株式会社 建設工事現場に展張するメッシュシート用難燃剤とこれを用いた建設工事現場に展張する防炎メッシュシート
KR100396340B1 (ko) * 2000-12-19 2003-09-02 주식회사 글로얀 축광특성을 갖는 합성섬유사 및 이의 제조방법
JP3656732B2 (ja) * 2000-04-21 2005-06-08 日産自動車株式会社 エネルギー変換繊維体および吸音材
US6855422B2 (en) * 2000-09-21 2005-02-15 Monte C. Magill Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof
JP2003253261A (ja) * 2001-12-28 2003-09-10 Sony Corp 蛍光性物質、複合材料、コート材料、塗料、インク、人工皮膚、人工皮膚の接触情報処理方法、人工発光皮膚、人工発光毛髪、発光素子、電子装置、発光システム、表示システム、フレキシブル発光材料、超音波発光性物質、交通標識、発光方法、複合材料の製造方法および発光素子の製造方法
US20040043174A1 (en) * 2002-03-22 2004-03-04 Schnurer John H. Polymeric fiber composition and method
US8231968B2 (en) * 2006-05-03 2012-07-31 Noveko Trading 2008 Llc Natural tourmaline anion fiber and filter and producing method
CN101595255A (zh) * 2007-01-29 2009-12-02 株式会社Y.G.K 发光性复合纱线
EA201000586A1 (ru) * 2007-11-07 2010-10-29 Новеко Трейдинг 2008 Ллк Функциональное волокно, способ его изготовления и изготовленная из него ткань
JP2010114349A (ja) * 2008-11-10 2010-05-20 Konica Minolta Holdings Inc 複合発電装置
JP5365469B2 (ja) * 2009-10-28 2013-12-11 トヨタ自動車株式会社 リチウム空気電池
WO2012044352A2 (en) * 2010-10-01 2012-04-05 Tessenderlo Kerley Inc. Method of increasing photosynthesis and reducing ozone
CN102380908A (zh) * 2011-07-29 2012-03-21 中铁五局（集团）有限公司 无砟轨道板张拉防漏检方法
JP5931807B2 (ja) * 2012-07-11 2016-06-08 富士フイルム株式会社 熱電変換材料、これを用いた熱電変換素子及び熱電発電用物品、並びに熱電変換素子の製造方法
ES2492215B1 (es) * 2013-02-06 2015-06-29 Jesús CANDEL FABREGAS Polvo cerámico fotocatalítico y de emisión infrarroja, aplicable a fibras textiles y procedimiento de obtención de dicho polvo
EP2980184B1 (en) * 2013-03-29 2018-08-01 Sakai Chemical Industry Co., Ltd. Use of a mechanoluminescent material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020014716A1 (en) * 2000-04-04 2002-02-07 Seok Mi Soo Method of producing fiber having functional mineral powder and fiber produced therefrom
CN1766184A (zh) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 一种功能性聚丙烯纤维及其制备方法
CN102676082A (zh) * 2011-03-11 2012-09-19 艾普特佩克股份有限公司 纤维、纤维聚集体以及具有所述纤维聚集体的粘着剂
CN102380980A (zh) * 2011-07-27 2012-03-21 江南大学 一种自净化纺织品及其加工方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245127A (zh) * 2016-08-03 2016-12-21 三德亿顺商贸(深圳)有限公司 一种天然纳米矿物石粉功能纤维及一种功能性热能棉
JP2020528100A (ja) * 2017-07-26 2020-09-17 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ 蛍光体および組成物
JP2020528486A (ja) * 2017-07-26 2020-09-24 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ 組成物
CN108193325A (zh) * 2017-12-27 2018-06-22 江西嘉捷信达新材料科技有限公司 含锆耐高温碳化硅纤维及其制备方法

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