WO2015137806A1 - Procédé permettant d'améliorer le poids moléculaire d'un polyester - Google Patents

Procédé permettant d'améliorer le poids moléculaire d'un polyester Download PDF

Info

Publication number
WO2015137806A1
WO2015137806A1 PCT/NL2015/050153 NL2015050153W WO2015137806A1 WO 2015137806 A1 WO2015137806 A1 WO 2015137806A1 NL 2015050153 W NL2015050153 W NL 2015050153W WO 2015137806 A1 WO2015137806 A1 WO 2015137806A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyester
semi
end groups
range
process according
Prior art date
Application number
PCT/NL2015/050153
Other languages
English (en)
Inventor
Jeffrey John Kolstad
Gerardus Johannes Maria Gruter
Matheus Adrianus Dam
Jesper Gabriël VAN BERKEL
Robert Joseph Schiavone
Marion L. Andrews
Original Assignee
Furanix Technologies B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=50555214&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2015137806(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to AU2015230098A priority Critical patent/AU2015230098B2/en
Priority to CN201580022558.2A priority patent/CN106414548B/zh
Priority to JP2016556820A priority patent/JP7175587B2/ja
Priority to KR1020167028251A priority patent/KR20160127829A/ko
Priority to EP15715480.8A priority patent/EP3116933B1/fr
Application filed by Furanix Technologies B.V. filed Critical Furanix Technologies B.V.
Priority to BR112016021047-6A priority patent/BR112016021047B1/pt
Priority to EP18169328.4A priority patent/EP3378881B1/fr
Priority to US15/123,804 priority patent/US10072119B2/en
Priority to CA2941491A priority patent/CA2941491C/fr
Priority to SG11201607422QA priority patent/SG11201607422QA/en
Priority to ES15715480.8T priority patent/ES2682942T3/es
Publication of WO2015137806A1 publication Critical patent/WO2015137806A1/fr
Priority to AU2017202875A priority patent/AU2017202875B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/80—Solid-state polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • C08G63/866—Antimony or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88—Post-polymerisation treatment

Abstract

Le poids moléculaire d'un polyester de départ semi-cristallin comportant des motifs 2,5-furandicarboxylate d'éthylène est amélioré par chauffage du polyester de départ semi-cristallin, ayant un point de fusion Tm, à une température située dans la plage de (Tm-40°C) à la Tm pour obtenir un polyester à l'état solide, dans lequel le polyester de départ semi-cristallin possède une viscosité intrinsèque d'au moins 0,45 dL/g et une quantité de groupes terminaux d'acide carboxylique située dans la plage de 15 à 122 méq./kg.
PCT/NL2015/050153 2014-03-11 2015-03-11 Procédé permettant d'améliorer le poids moléculaire d'un polyester WO2015137806A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
ES15715480.8T ES2682942T3 (es) 2014-03-11 2015-03-11 Procedimiento destinado a aumentar el peso molecular de un poliéster
EP18169328.4A EP3378881B1 (fr) 2014-03-11 2015-03-11 Procédé permettant d'améliorer le poids moléculaire d'un polyester
JP2016556820A JP7175587B2 (ja) 2014-03-11 2015-03-11 ポリエステルの分子量を高めるための方法
KR1020167028251A KR20160127829A (ko) 2014-03-11 2015-03-11 폴리에스터의 분자량을 향상시키는 공정
EP15715480.8A EP3116933B1 (fr) 2014-03-11 2015-03-11 Procédé permettant d'améliorer le poids moléculaire d'un polyester
AU2015230098A AU2015230098B2 (en) 2014-03-11 2015-03-11 Process for enhancing the molecular weight of a polyester
BR112016021047-6A BR112016021047B1 (pt) 2014-03-11 2015-03-11 Processo para aumentar o peso molecular de um poliéster de partida semicristalino
CN201580022558.2A CN106414548B (zh) 2014-03-11 2015-03-11 用于提高聚酯的分子量的方法
US15/123,804 US10072119B2 (en) 2014-03-11 2015-03-11 Process for enhancing the molecular weight of a polyester
CA2941491A CA2941491C (fr) 2014-03-11 2015-03-11 Procede permettant d'ameliorer le poids moleculaire d'un polyester
SG11201607422QA SG11201607422QA (en) 2014-03-11 2015-03-11 Process for enhancing the molecular weight of a polyester
AU2017202875A AU2017202875B2 (en) 2014-03-11 2017-05-01 Process for enhancing the molecular weight of a polyester

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201461951229P 2014-03-11 2014-03-11
US61/951,229 2014-03-11
NL2012408 2014-03-11
NL2012408 2014-03-11

Publications (1)

Publication Number Publication Date
WO2015137806A1 true WO2015137806A1 (fr) 2015-09-17

Family

ID=50555214

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL2015/050153 WO2015137806A1 (fr) 2014-03-11 2015-03-11 Procédé permettant d'améliorer le poids moléculaire d'un polyester

Country Status (13)

Country Link
US (1) US10072119B2 (fr)
EP (2) EP3378881B1 (fr)
JP (1) JP7175587B2 (fr)
KR (1) KR20160127829A (fr)
CN (1) CN106414548B (fr)
AU (2) AU2015230098B2 (fr)
CA (2) CA3153330C (fr)
ES (2) ES2910945T3 (fr)
LT (1) LT3378881T (fr)
PT (1) PT3378881T (fr)
SG (1) SG11201607422QA (fr)
TR (1) TR201807819T4 (fr)
WO (1) WO2015137806A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017023173A1 (fr) * 2015-08-04 2017-02-09 Furanix Technologies B.V. Composition mélange maître de polyester
WO2017048119A1 (fr) * 2015-09-14 2017-03-23 Furanix Technologies B.V. Procédé de préparation d'un polyester
US20180223078A1 (en) * 2015-08-04 2018-08-09 Synvina C.V. Polyester composition
US20190023837A1 (en) * 2017-07-20 2019-01-24 Eastman Chemical Company Production of polyethylene furanoate in a retrofitted polyester plant
WO2019246034A1 (fr) 2018-06-18 2019-12-26 Archer Daniels Midland Company Stabilisation de couleur de monomères et d'autres réactifs pour former des polymères d'origine biologique
WO2020106511A1 (fr) 2018-11-20 2020-05-28 Exxonmobil Chemical Patents Inc. Polyesters modifiés par le bifuranne
WO2020106510A1 (fr) 2018-11-20 2020-05-28 Exxonmobil Chemical Patents Inc. Polyesters de bifurane
EP3347401B1 (fr) 2015-09-11 2022-02-23 Furanix Technologies B.V. Procédé d'amélioration du poids moléculaire d'un polyester par polymérisation à l'état solide

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201607430UA (en) 2014-03-11 2016-10-28 Furanix Technologies Bv Polyester and method for preparing such a polyester
US9504994B2 (en) 2014-05-08 2016-11-29 Eastman Chemical Company Furan-2,5-dicarboxylic acid purge process
US10010812B2 (en) 2014-05-08 2018-07-03 Eastman Chemical Company Furan-2,5-dicarboxylic acid purge process
US9944615B2 (en) 2014-05-08 2018-04-17 Eastman Chemical Company Purifying crude furan 2,5-dicarboxylic acid by hydrogenation and a purge zone
CN107216619B (zh) * 2017-05-24 2019-12-03 中国科学院宁波材料技术与工程研究所 一种改善聚呋喃二甲酸乙二醇酯结晶性能的方法、产品和应用
CN107778469B (zh) * 2017-09-28 2019-05-31 浙江大学 一种2,5-呋喃二甲酸基聚酯/层状硅酸盐纳米复合材料及其制备方法和应用
US10526301B1 (en) 2018-10-18 2020-01-07 Eastman Chemical Company Production of purified dialkyl-furan-2,5-dicarboxylate (DAFD) in a retrofitted DMT plant
BR112021022271A2 (pt) 2019-06-06 2021-12-28 Purac Biochem Bv Processo para fabricar hidroximetilfurfural
WO2021172215A1 (fr) * 2020-02-28 2021-09-02 東洋紡株式会社 Procédé de fabrication de polyester, et polyester fabriqué selon ce procédé
WO2022043500A1 (fr) 2020-08-27 2022-03-03 Furanix Technologies B.V. Procédé de production d'un polyester comprenant des motifs 2,5-furanedicarboxylate
CN114790282B (zh) * 2021-12-30 2023-03-21 康辉新材料科技有限公司 一种纳米微颗粒原位聚合催化剂的制备方法及其应用

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2551731A (en) 1946-11-12 1951-05-08 Celanese Corp Polyesters from heterocyclic components
US4340721A (en) 1980-05-20 1982-07-20 Rhone-Poulenc Industries Novel polyester for the packaging of comestibles
US6569479B2 (en) 1999-10-27 2003-05-27 The Coca-Cola Company Process for reduction of acetaldehyde and oxygen in beverages contained in polyester-based packaging
US20090124763A1 (en) 2005-11-07 2009-05-14 Canon Kabushiki Kaisha Polymer compound and method of synthesizing the same
WO2010077133A1 (fr) 2008-12-30 2010-07-08 Furanix Technologies B.V. Procédé pour préparer un polymère ayant un fragment 2,5-furanedicarboxylate dans le squelette du polymère et (co)polymères ainsi préparés
WO2010132740A2 (fr) 2009-05-14 2010-11-18 Archer Daniels Midland Company Oxydation de composés de furfural
WO2011043661A1 (fr) 2009-10-07 2011-04-14 Furanix Technologies B.V. Procédé de préparation d'acide 2,5-furane dicarboxylique et de préparation de l'ester dialkylique d'acide 2,5-furane dicarboxylique
WO2011043660A2 (fr) 2009-10-07 2011-04-14 Furanix Technologies B.V. Procédé de préparation d'acide 2,5-furandicarboxylique et de ses esters
WO2013062408A1 (fr) 2011-10-24 2013-05-02 Furanix Technologies B.V. Procédé pour la préparation d'un produit polymère comprenant un groupe fonctionnel de 2,5-furandicarboxylate dans le squelette de polymère destiné à être utilisé dans des applications en bouteille, en film ou en fibre
WO2013120989A2 (fr) 2012-02-17 2013-08-22 Uhde Inventa-Fischer Gmbh Procédé de préparation d'un polyester ou copolyester hétéroaromatique de poids moléculaire élevé
KR20140003167A (ko) 2012-06-29 2014-01-09 롯데케미칼 주식회사 투명성이 우수한 폴리에스터 중합체 및 이의 제조방법

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4309227A1 (de) * 1993-03-23 1994-09-29 Zimmer Ag Kontinuierliches Verfahren zur Herstellung von Polyester für Lebensmittelverpackungen
JP5233390B2 (ja) * 2007-04-24 2013-07-10 三菱化学株式会社 フラン構造を含むポリエステル樹脂の製造方法
CN102050941B (zh) * 2009-11-03 2013-12-11 东丽纤维研究所（中国）有限公司 一种高分子聚合物及其生产方法
CN102190785A (zh) * 2010-11-30 2011-09-21 中国科学院长春应用化学研究所 聚2,5-呋喃二甲酸乙二醇酯及其制备方法
JP6040549B2 (ja) * 2011-03-30 2016-12-07 東レ株式会社 液晶ポリエステル繊維およびその製造方法
JP5871574B2 (ja) * 2011-11-15 2016-03-01 株式会社クレハ 塩基性悪臭物質吸収性不織布、及び塩基性悪臭物質の低減方法
WO2014032730A1 (fr) * 2012-08-31 2014-03-06 Sa Des Eaux Minerales D'evian Saeme Bouteille, son procédé de fabrication et utilisation de monomères fdca et diol dans une telle bouteille
US20150353692A1 (en) * 2012-12-20 2015-12-10 Dow Global Technologies Llc Barrier films of fdca-based polyesters
US20160311208A1 (en) 2013-12-20 2016-10-27 E. I. Du Pont De Nemours And Company Furan-based polymeric hydrocarbon fuel barrier structures

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2551731A (en) 1946-11-12 1951-05-08 Celanese Corp Polyesters from heterocyclic components
US4340721A (en) 1980-05-20 1982-07-20 Rhone-Poulenc Industries Novel polyester for the packaging of comestibles
US4340721B1 (en) 1980-05-20 1998-12-01 Rhone Poulenc Ind Polyesters for the packaging of comestibles
US6569479B2 (en) 1999-10-27 2003-05-27 The Coca-Cola Company Process for reduction of acetaldehyde and oxygen in beverages contained in polyester-based packaging
US20090124763A1 (en) 2005-11-07 2009-05-14 Canon Kabushiki Kaisha Polymer compound and method of synthesizing the same
WO2010077133A1 (fr) 2008-12-30 2010-07-08 Furanix Technologies B.V. Procédé pour préparer un polymère ayant un fragment 2,5-furanedicarboxylate dans le squelette du polymère et (co)polymères ainsi préparés
WO2010132740A2 (fr) 2009-05-14 2010-11-18 Archer Daniels Midland Company Oxydation de composés de furfural
WO2011043661A1 (fr) 2009-10-07 2011-04-14 Furanix Technologies B.V. Procédé de préparation d'acide 2,5-furane dicarboxylique et de préparation de l'ester dialkylique d'acide 2,5-furane dicarboxylique
WO2011043660A2 (fr) 2009-10-07 2011-04-14 Furanix Technologies B.V. Procédé de préparation d'acide 2,5-furandicarboxylique et de ses esters
WO2013062408A1 (fr) 2011-10-24 2013-05-02 Furanix Technologies B.V. Procédé pour la préparation d'un produit polymère comprenant un groupe fonctionnel de 2,5-furandicarboxylate dans le squelette de polymère destiné à être utilisé dans des applications en bouteille, en film ou en fibre
WO2013120989A2 (fr) 2012-02-17 2013-08-22 Uhde Inventa-Fischer Gmbh Procédé de préparation d'un polyester ou copolyester hétéroaromatique de poids moléculaire élevé
KR20140003167A (ko) 2012-06-29 2014-01-09 롯데케미칼 주식회사 투명성이 우수한 폴리에스터 중합체 및 이의 제조방법

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters", 2003, WILEY
A.T. JACKSON; D.F. ROBERTSON: "Comprehensive Analytical Chemistry", vol. 53, 2008, ELSEVIER, article "Molecular Characterization and Analysis of Polymers", pages: 171 - 203

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2015264B1 (en) * 2015-08-04 2017-02-21 Furanix Technologies Bv Masterbatch polyester composition.
US20180223078A1 (en) * 2015-08-04 2018-08-09 Synvina C.V. Polyester composition
WO2017023173A1 (fr) * 2015-08-04 2017-02-09 Furanix Technologies B.V. Composition mélange maître de polyester
EP3347401B1 (fr) 2015-09-11 2022-02-23 Furanix Technologies B.V. Procédé d'amélioration du poids moléculaire d'un polyester par polymérisation à l'état solide
US10590235B2 (en) 2015-09-14 2020-03-17 Synvina C.V. Process for the preparation of a polyester
WO2017048119A1 (fr) * 2015-09-14 2017-03-23 Furanix Technologies B.V. Procédé de préparation d'un polyester
JP2018526521A (ja) * 2015-09-14 2018-09-13 センヴィナ・セー・フェー ポリエステルの製造方法
US20190023838A1 (en) * 2017-07-20 2019-01-24 Eastman Chemical Company Production of polyethylene furanoate in a retrofitted pet plant
US20190023837A1 (en) * 2017-07-20 2019-01-24 Eastman Chemical Company Production of polyethylene furanoate in a retrofitted polyester plant
WO2019246034A1 (fr) 2018-06-18 2019-12-26 Archer Daniels Midland Company Stabilisation de couleur de monomères et d'autres réactifs pour former des polymères d'origine biologique
WO2020106511A1 (fr) 2018-11-20 2020-05-28 Exxonmobil Chemical Patents Inc. Polyesters modifiés par le bifuranne
WO2020106510A1 (fr) 2018-11-20 2020-05-28 Exxonmobil Chemical Patents Inc. Polyesters de bifurane
US11970573B2 (en) 2018-11-20 2024-04-30 Exxonmobil Chemical Patents Inc. Bifuran-modified polyesters

Also Published As

Publication number Publication date
BR112016021047A2 (pt) 2022-12-13
KR20160127829A (ko) 2016-11-04
ES2682942T3 (es) 2018-09-24
ES2910945T3 (es) 2022-05-17
AU2015230098A1 (en) 2016-10-06
EP3116933A1 (fr) 2017-01-18
JP7175587B2 (ja) 2022-11-21
US20170015781A1 (en) 2017-01-19
CN106414548B (zh) 2018-11-16
EP3378881B1 (fr) 2022-02-09
AU2015230098B2 (en) 2017-02-02
SG11201607422QA (en) 2016-10-28
PT3378881T (pt) 2022-03-23
LT3378881T (lt) 2022-04-25
US10072119B2 (en) 2018-09-11
AU2017202875A1 (en) 2017-05-18
EP3116933B1 (fr) 2018-05-09
CA3153330A1 (fr) 2015-09-17
AU2017202875B2 (en) 2018-05-10
JP2017508047A (ja) 2017-03-23
CA3153330C (fr) 2024-03-12
TR201807819T4 (tr) 2018-06-21
CN106414548A (zh) 2017-02-15
CA2941491A1 (fr) 2015-09-17
EP3378881A1 (fr) 2018-09-26
CA2941491C (fr) 2022-05-31

Similar Documents

Publication Publication Date Title
AU2017202875B2 (en) Process for enhancing the molecular weight of a polyester
AU2015230097B2 (en) Polyester and method for preparing such a polyester
CA2941111C (fr) Procede de preparation d'un polyester dans des conditions definies d'esterification
AU2015230099B2 (en) Polyester and method for preparing such a polyester
EP3347401B1 (fr) Procédé d'amélioration du poids moléculaire d'un polyester par polymérisation à l'état solide
BR112016021047B1 (pt) Processo para aumentar o peso molecular de um poliéster de partida semicristalino

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15715480

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2941491

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 15123804

Country of ref document: US

ENP Entry into the national phase

Ref document number: 2016556820

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2015230098

Country of ref document: AU

Date of ref document: 20150311

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 20167028251

Country of ref document: KR

Kind code of ref document: A

REEP Request for entry into the european phase

Ref document number: 2015715480

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2015715480

Country of ref document: EP

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112016021047

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112016021047

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20160912

ENPW Started to enter national phase and was withdrawn or failed for other reasons

Ref document number: 112016021047

Country of ref document: BR

Kind code of ref document: A2

Free format text: PEDIDO CONSIDERADO RETIRADO EM RELACAO AO BRASIL POR NAO TER SIDO APRESENTADO O QUADRO REIVINDICATORIO COMPLETO TRADUZIDO PARA O PORTUGUES NO ATO DA ENTRADA NA FASE NACIONAL, CONFORME O ART.6O DA RESOLUCAO 77/2013.

REG Reference to national code

Ref country code: BR

Ref legal event code: B01E

Ref document number: 112016021047

Country of ref document: BR

Kind code of ref document: A2

Free format text: APRESENTE A TRADUCAO SIMPLES DA FOLHA DE ROSTO DA CERTIDAO DE DEPOSITO DAS PRIORIDADES REIVINDICADAS; OU DECLARACAO DE QUE OS DADOS DO PEDIDO INTERNACIONAL ESTAO FIELMENTE CONTIDOS NA PRIORIDADE REIVINDICADA, CONTENDO TODOS OS DADOS IDENTIFICADORES (NUMERO DA PRIORIDADE, DATA, DEPOSITANTE E INVENTORES).

ENP Entry into the national phase

Ref document number: 112016021047

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20160912