WO2014104862A1 - 광학 소자 - Google Patents

광학 소자 Download PDF

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WO2014104862A1
WO2014104862A1 PCT/KR2013/012419 KR2013012419W WO2014104862A1 WO 2014104862 A1 WO2014104862 A1 WO 2014104862A1 KR 2013012419 W KR2013012419 W KR 2013012419W WO 2014104862 A1 WO2014104862 A1 WO 2014104862A1
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Prior art keywords
optical
layer
degrees
axis
change
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PCT/KR2013/012419
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English (en)
French (fr)
Korean (ko)
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김신영
박문수
신부건
윤혁
Original Assignee
주식회사 엘지화학
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Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to CN201380068371.7A priority Critical patent/CN104884982B/zh
Priority to EP13868206.7A priority patent/EP2940496B1/de
Priority to US14/649,850 priority patent/US9599833B2/en
Priority to JP2015546404A priority patent/JP6354106B2/ja
Publication of WO2014104862A1 publication Critical patent/WO2014104862A1/ko

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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/28—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising
    • G02B27/281—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising used for attenuating light intensity, e.g. comprising rotatable polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/13363—Birefringent elements, e.g. for optical compensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/02—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of crystals, e.g. rock-salt, semi-conductors
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/12—Optical coatings produced by application to, or surface treatment of, optical elements by surface treatment, e.g. by irradiation
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3083—Birefringent or phase retarding elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528—Polarisers
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528—Polarisers
    • G02F1/133531—Polarisers characterised by the arrangement of polariser or analyser axes
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/13363—Birefringent elements, e.g. for optical compensation
    • G02F1/133631—Birefringent elements, e.g. for optical compensation with a spatial distribution of the retardation value

Definitions

  • the present application relates to an optical element and an optical panel.
  • An optical element such as a retardation film or a polarizing plate may be used in various applications including, for example, for adjusting the characteristics of light in a display device or for a window or shade such as a building or an automobile.
  • a polymer film such as a PVA (poly (vinyl alcohol)) film or the like
  • a film produced using a liquid crystal compound and a dichroic dye or optically imparted by stretching The film etc. which provided optical anisotropy using the film or the liquid crystal compound which were used are known.
  • Patent Document 1 Korean Patent Publication No. 2008-0077975
  • Patent Document 2 Korean Registered Patent No. 0264504
  • Patent Document 3 US Patent No. 5,707,566
  • the present application provides an optical element and an optical panel.
  • Exemplary optical elements may include an optical layer.
  • optical layer in the present application may include all kinds of layers formed to be capable of optically required functions, for example, to delay a phase of incident light or to change states such as polarization states.
  • the optical layer may include a region where the direction of the optical axis or the light absorption axis changes in one direction (hereinafter, may be referred to as a change region).
  • the term optical axis in the present application may mean a slow axis or a fast axis in the anisotropic region.
  • the change in the direction of the optical axis or the light absorption axis in the change region of the optical layer may occur continuously. Continuous change in the direction of the optical axis or light absorption axis may mean that the angle formed by the optical axis or light absorption axis increases or decreases along one direction.
  • FIG. 1 is a diagram schematically showing an upper shape of an exemplary optical layer, in which both arrows indicate the optical axis or light absorption axis of the optical layer.
  • the angle formed by the optical axis or the light absorption axis increases along one direction (the upper to lower direction in FIG. 1) when measured in a counterclockwise direction.
  • the average rate of change of the optical axis or the light absorption axis in the change region may be determined according to Equation 1 below.
  • V 360 / P
  • Equation 1 V is the average rate of change, P is the pitch of the change area.
  • the pitch of the change region is a region in which the angle formed by the optical axis or the light absorption axis is continuously increased or decreased along one direction, so that the optical axis or the light absorption axis is required to complete the rotation of 360 degrees. It is a length measured along the said one direction. Unless otherwise specified in the present application, the unit of length may be millimeters (mm). Therefore, in Equation 1, the unit of average change rate V may be degrees / mm.
  • FIG. 2 shows an area where the angle of the optical axis or the light absorption axis continuously decreases along one direction (upward to downward direction in FIG. 2) when measured in a clockwise direction, and the pitch, that is, the optical axis Or the distance measured along the one direction in which the light absorption axis is required to complete a 360 degree rotation.
  • the pitch is either clockwise or counterclockwise with respect to the optical axis or light absorption axis at the point where the change area starts.
  • the angle A at which the optical axis or the light absorption axis is rotated and the length L of the change area can be obtained by substituting Equation 2 below.
  • Equation 2 P is the pitch of the change region, L is the length of the change region, and A is the change region measured in either the clockwise or counterclockwise direction with respect to the optical axis or the light absorption axis of the starting point of the change region. The angle at which the optical axis or the light absorption axis is rotated.
  • the average rate of change determined by Equation 1 in the change region is greater than 0 and may be 5 or less. In another example, the average change rate may be 4.5 or less, 4 or less, 3.5 or less, 3 or less, 2.5 or less, 2.0 or less, 1.5 or less, 1.0 or less, or 0.7 or less.
  • the average rate of change can also be at least 0.1, at least 0.2 or at least 0.2.
  • the optical layer may be a single layer.
  • the term monolayer is used in the concept of excluding a layer formed by assembling or stacking two or more layers.
  • a layer formed by assembling two or more layers having different optical axes or light absorption axes to achieve a changing optical axis or light absorption axis, or by laminating a polarizing layer and a retardation layer may be a category of the single layer.
  • a boundary may not be observed between regions in which the optical axis or the light absorption axis is different in the change region of the optical layer. That is, in the optical layer, the change in the optical axis or the light absorption axis is substantially completely continuous, and the domain may not be observed.
  • the boundary is not observed between regions in which the optical axis or the optical absorption is different in the change region of the optical layer may mean a case where the change in the optical axis or the light absorption axis of the change region satisfies Equation 3 below.
  • Equation 3 X is a distance measured according to one direction from which the change of the optical axis or light absorption axis occurs from the start point of the change region, and Y is an optical axis at the X point measured based on the optical axis or light absorption axis of the start point of the change region. Or an angle at which the light absorption axis is rotated, and a is a number within a range exceeding 0 and being 5 or less.
  • the rotation angle Y of the optical axis or the light absorption axis is 0 degrees of the optical axis or the light absorption axis of the point where the change region starts, and is either clockwise or counterclockwise based on the 0 degree.
  • a may be 4.5 or less, 4 or less, 3.5 or less, 3 or less, 2.5 or less, 2.0 or less, 1.5 or less, 1.0 or less, or 0.7 or less in another example.
  • a may be 0.1 or more, 0.2 or more, or 0.2 or more.
  • a change in the optical axis or the light absorption axis satisfies Equation 3 above, and continuously occurs so that an optical element suitable for the intended use can be provided.
  • the rotation angle of the change region may be determined according to Equation 4 below.
  • Equation 4 ⁇ is a rotation angle, V is an average rate of change, and L is the length of the change region.
  • Equation 4 the average rate of change (V) may be measured according to Equation 1.
  • the range of the rotation angle of the change region may be determined in consideration of the application to which the optical element is applied, and is not particularly limited, but may be, for example, about 10 degrees or more, 20 degrees or more, 30 degrees or more, 40 degrees or more, or 50 degrees.
  • the upper limit of the rotation angle is also not particularly limited as determined according to the intended use, but may be, for example, about 1,000 degrees or less, about 900 degrees or less, or about 800 degrees or less.
  • the optical layer of the optical element comprises only one of the above-mentioned change regions, if necessary, includes two or more change regions, or other regions other than the change region, for example, an optical axis or a light absorption axis in one direction. It may include a region that is formed uniformly only, or a region where a change in the optical axis or light absorption axis occurs discontinuously.
  • the optical layer may be a phase retardation layer or a polarization layer.
  • the optical layer may have an optical axis having the above-described shape
  • the optical layer may have a light absorption axis having the above-described shape.
  • the retardation or the polarization efficiency in the case where the optical layer is a polarizing layer is not particularly limited and can be freely adjusted by selecting an appropriate raw material in consideration of the intended use.
  • the optical layer may be a liquid crystal polymer layer.
  • the term liquid crystal polymer layer may refer to a layer formed by polymerizing a polymerizable liquid crystal compound (a liquid crystal compound called RM (reactive mesogen)).
  • RM reactive mesogen
  • the liquid crystal polymer layer can be formed by polymerizing in a state where the polymerizable liquid crystal compound is oriented on the alignment film as described later.
  • the liquid crystal polymer layer may further include known additional components, for example, a non-polymerizable liquid crystal compound, a polymerizable non-liquid crystalline compound, a non-polymerizable non-liquid crystalline compound, a surfactant or a leveling agent.
  • a polymerizable liquid crystal compound which forms a liquid crystal polymer layer an appropriate kind can be selected according to the objective.
  • the liquid crystal compound a compound exhibiting a smectic phase, a nematic phase, or a cholesteric phase can be used.
  • liquid crystal compound having such characteristics, it is possible to more efficiently form the optical layer of the desired form.
  • polymeric liquid crystal compound As said polymeric liquid crystal compound, the polymeric liquid crystal compound of following General formula (1) can be used, for example.
  • A is a single bond, -COO- or -OCO-
  • R 1 to R 10 are each independently hydrogen, halogen, alkyl group, alkoxy group, alkoxycarbonyl group, cyano group, nitro group, -OQP or A substituent of Formula 2 or a pair of two adjacent substituents of R 1 to R 5 or a pair of two adjacent substituents of R 6 to R 10 are connected to each other to form a benzene substituted with -OQP, wherein R 1 to At least one of R 10 is -OQP or a substituent of Formula 2 below, or at least one pair of two adjacent substituents of R 1 to R 5 or two adjacent substituents of R 6 to R 10 are connected to each other to form -OQP To form a benzene substituted, wherein Q is an alkylene group or an alkylidene group, and P is an alkenyl group, epoxy group, cyano group, carboxyl group, acryloyl
  • B is a single bond, -COO- or -OCO-
  • R 11 to R 15 are each independently hydrogen, halogen, alkyl group, alkoxy group, alkoxycarbonyl group, cyano group, nitro group or -OQP, or A pair of adjacent two substituents of R 11 to R 15 are connected to each other to form a benzene substituted with -OQP, wherein at least one of R 11 to R 15 is -OQP or two adjacent ones of R 11 to R 15 The pair of substituents are connected to each other to form benzene substituted with -OQP, wherein Q is an alkylene group or an alkylidene group, and P is an alkenyl group, epoxy group, cyano group, carboxyl group, acryloyl group, methacrylo It is a polymerizable functional group, such as a diary, acryloyloxy group, or methacryloyloxy group.
  • two adjacent substituents may be linked to each other to form a benzene substituted with -OQP, which may mean that two adjacent substituents are connected to each other to form a naphthalene skeleton substituted with -OQP as a whole. .
  • single bond means a case where no separate atom is present in a portion represented by A or B.
  • A is a single bond in Formula 1
  • benzene on both sides of A may be directly connected to form a biphenyl structure.
  • halogen in the formula (1) and (2) for example, chlorine, bromine or iodine and the like can be exemplified.
  • alkyl group unless otherwise specified, for example, a straight or branched chain alkyl group having 1 to 20 carbon atoms, 1 to 16 carbon atoms, 1 to 12 carbon atoms, 1 to 8 carbon atoms or 1 to 4 carbon atoms. It may mean, or may mean, for example, a cycloalkyl group having 3 to 20 carbon atoms, 3 to 16 carbon atoms, or 4 to 12 carbon atoms.
  • the alkyl group may be optionally substituted by one or more substituents.
  • alkoxy group may mean, for example, an alkoxy group having 1 to 20 carbon atoms, 1 to 16 carbon atoms, 1 to 12 carbon atoms, 1 to 8 carbon atoms, or 1 to 4 carbon atoms. Can be.
  • the alkoxy group may be linear, branched or cyclic.
  • the alkoxy group may be optionally substituted by one or more substituents.
  • alkylene group or "alkylidene group” means, for example, an alkylene group or an alkylidene group having 1 to 12 carbon atoms, 4 to 10 carbon atoms or 6 to 9 carbon atoms, unless otherwise specified. Can be.
  • the alkylene group or alkylidene group may be, for example, linear, branched or cyclic.
  • the alkylene group or alkylidene group may be optionally substituted by one or more substituents.
  • alkenyl group means, for example, an alkenyl group having 2 to 20 carbon atoms, 2 to 16 carbon atoms, 2 to 12 carbon atoms, 2 to 8 carbon atoms, or 2 to 4 carbon atoms, unless otherwise specified. can do.
  • the alkenyl group may be, for example, linear, branched or cyclic.
  • the alkenyl group may be optionally substituted by one or more substituents.
  • P is, for example, acryloyl group, methacryloyl group, acryloyloxy group or methacryloyloxy group; Acryloyloxy group or methacryloyloxy group; Or acryloyloxy group.
  • an alkyl group, an alkoxy group, an alkenyl group, an epoxy group, an oxo group, an oxetanyl group, a thiol group, a cyano group, a carboxyl group, acryloyl group, a methacryloyl group, Acryloyloxy group, methacryloyloxy group or an aryl group may be exemplified, but is not limited thereto.
  • At least one of -OQP or a residue of formula (2), which may be present in Formulas (1) and (2), may, for example, be present at a position of R 3 , R 8, or R 13 .
  • the substituents connected to each other to constitute benzene substituted with -OQP may be, for example, R 3 and R 4 or R 12 and R 13 .
  • substituents other than -OQP or residues of the formula (2) in the compound of the formula (1) or the residue of the formula (2) or substituents other than the substituents connected to each other to form benzene are, for example, hydrogen, halogen, straight chain of 1 to 4 It may be a branched alkyl group, an alkoxycarbonyl group containing a straight or branched chain alkoxy group having 1 to 4 carbon atoms, a cycloalkyl group having 4 to 12 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a cyano group or a nitro group, in another example, chlorine Or an alkoxycarbonyl group or cyano group comprising a straight or branched chain alkyl group having 1 to 4 carbon atoms, a cycloalkyl group having 4 to 12 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a straight or branched chain alkoxy group having 1 to 4 carbon atoms have.
  • the polymerizable liquid crystal compound which may also be represented by Formula 1 may include, for example, one, two or more, one to ten, one to eight, one to one polymerizable functional group (P in Formula 1 or 2). To 6, 1 to 5, 1 to 4, 1 to 3 or 1 to 2 may include.
  • the optical layer may be a liquid crystal polymer layer including a dichroic dye or a Lyotropic Liquid Crystal (LLC) layer.
  • an optical layer is formed by polymerizing the polymerizable liquid crystal compound in a state in which a layer containing a polymerizable liquid crystal compound and a dichroic dye is aligned on an alignment film described later, or shearing force in a desired direction on a breast liquid crystal.
  • the above-mentioned optical layer can be formed by applying a force) to form a layer.
  • the type of the polymerizable liquid crystal compound forming the polymer layer may be appropriately selected in consideration of the performance of the desired polarizing layer. kind can be used.
  • the liquid crystal polymer layer which is an optical layer, may include a dichroic dye.
  • the term dye may refer to a material capable of intensively absorbing and / or modifying light in at least part or the entire range within the visible light region, for example, in the 400 nm to 800 nm wavelength range, the term dichroic The dye may refer to a material capable of anisotropic absorption of light in at least part or the entire range of the visible light region.
  • dichroic dyes in principle all kinds of dyes having a maximum absorbance in the visible region, for example, 400 nm to 800 nm can be used. Such dyes are known, for example, as azo dyes or anthraquinone dyes.
  • azo dyes F355 registered trademark
  • F357 registered trademark
  • F593 registered trademark
  • dyes of a kind known to exhibit the same effect as the above, etc. may be used. It is possible, but not limited to.
  • dichroic dye for example, all kinds of dyes known to have properties as described above and having properties that can be oriented according to the orientation of the liquid crystal compound can be used.
  • the optical element may further include a base layer.
  • the optical element may further include a base layer, and the optical layer may be formed on at least one surface of the base layer.
  • the optical layer may be formed on both surfaces of a base material layer as needed.
  • 3 is a schematic view of one example of the optical element, showing a form in which the base layer 10 and the optical layer 20 are sequentially formed.
  • a base material layer a well-known raw material can be used without a restriction
  • inorganic films such as a glass plate, a crystalline or amorphous silicon film, a quartz, or an Indium Tin Oxide (ITO) film, a plastic film, etc. can be used.
  • the optically isotropic base material layer and the optically anisotropic base material layer can be used.
  • plastic substrate layer examples include triacetyl cellulose (TAC); COP (cyclo olefin copolymer) such as norbornene derivatives; Poly (methyl methacrylate); PC (polycarbonate); PE (polyethylene); PP (polypropylene); PVA (polyvinyl alcohol); DAC (diacetyl cellulose); Pac (Polyacrylate); PES (poly ether sulfone); PEEK (polyetheretherketon PPS (polyphenylsulfone), PEI (polyetherimide); PEN (polyethylenemaphthatlate); PET (polyethyleneterephtalate); PI (polyimide); PSF (polysulfone); PAR (polyarylate) or amorphous fluorine resin
  • the substrate layer may include a coating layer of a silicon compound such as gold, silver, silicon dioxide or silicon monoxide, or a coating layer such as an antireflection layer, if necessary.
  • the optical element may further include an alignment layer.
  • the alignment layer may be formed in contact with the above-described optical layer.
  • the alignment layer may be present between the base layer and the optical layer.
  • any kind can be used as long as the alignment of adjacent optical layers, for example, the above-described liquid crystal compound or dichroic dye, can be appropriately adjusted, and for example, a photoalignment film can be used.
  • the alignment film may include an alignment compound, for example, a photoalignment compound.
  • a photoalignment compound may refer to a compound which is aligned in a predetermined direction through irradiation of light and orientates adjacent liquid crystal compounds and the like in the alignment direction in a predetermined direction.
  • the alignment compound may be a monomolecular compound, a monomeric compound, an oligomeric compound, or a high molecular compound.
  • the photoalignable compound may be a compound including a photosensitive moiety.
  • Various photo-alignment compounds that can be used for the alignment of the liquid crystal compound are known.
  • Photo-alignment compounds include, for example, compounds aligned by trans-cis photoisomerization; Compounds aligned by photo-destruction, such as chain scission or photo-oxidation; Compounds ordered by photocrosslinking or photopolymerization such as [2 + 2] addition cyclization ([2 + 2] cycloaddition), [4 + 4] addition cyclization or photodimerization; Compounds aligned by photo-Fries rearrangement or compounds aligned by ring opening / closure reaction may be used.
  • azo compounds or stilbenes such as sulfated diazo dyes or azo polymers
  • cyclobutane tetracarboxylic dianhydride cyclobutane-1,2,3,4-tetracarboxylic dianhydride
  • aromatic polysilane or polyester polystyrene or polyimide and the like
  • polystyrene or polyimide and the like can be exemplified.
  • a compound aligned by photocrosslinking or photopolymerization a cinnamate compound, a coumarin compound, a cinnanam compound, a tetrahydrophthalimide compound, a maleimide compound , Benzophenone compounds, diphenylacetylene compounds, compounds having chalconyl residues (hereinafter referred to as chalconyl compounds) or compounds having anthracenyl residues (hereinafter referred to as anthracenyl compounds) as photosensitive residues;
  • chalconyl compounds compounds having chalconyl residues
  • anthracenyl compounds compounds having anthracenyl residues
  • examples of the compounds aligned by the optical freeze rearrangement include aromatic compounds such as benzoate compounds, benzoamide compounds, and methacrylamidoaryl methacrylate compounds.
  • the compound aligned by the ring-opening / ring-closure reaction such as a spiropyran A [4 + 2] ⁇ electron system ([4 + 2] ⁇ electronic system), but may be exemplified by compounds such as sorting by a ring opening / ring-closure reaction of, without being limited thereto.
  • the photo-alignment compound may be a monomolecular compound, a monomeric compound, an oligomeric compound, or a high molecular compound, or may be in the form of a blend of the photo-alignment compound and the polymer.
  • the oligomeric or polymeric compound as described above may have a residue derived from the above-described photoalignable compound or a photosensitive residue described above in the main chain or in the side chain.
  • Polymers having residues or photosensitive residues derived from photo-alignment compounds or that can be mixed with the photo-alignment compounds include polynorbornene, polyolefins, polyarylates, polyacrylates, poly (meth) acrylates, poly Examples include mead, poly (amic acid), polymaleimide, polyacrylamide, polymethacrylamide, polyvinyl ether, polyvinyl ester, polystyrene, polysiloxane, polyacrylonitrile or polymethacrylonitrile It may be, but is not limited thereto.
  • Polymers that may be included in the oriented compound include, for example, polynorbornene cinnamate, polynorbornene alkoxy cinnamate, polynorbornene allylyloxy cinnamate, polynorbornene fluorinated cinnamate, polynorbornene chlorinated cinnamate or Polynorbornene discinnamate and the like can be exemplified, but is not limited thereto.
  • the orientation compound has a reversibility, for example, an alignment direction determined by an alignment treatment such as irradiation of linearly polarized light is further another alignment treatment, for example, irradiation of linearly polarized light polarized in another direction. It may mean that it has a characteristic that can be changed under the influence.
  • the optical element may be formed using an alignment layer formed by including a step of irradiating a plurality of linearly polarized light polarized in different directions to the same site.
  • Compounds having the above reversibility can be used.
  • the present application relates to an optical panel.
  • the optical panel may include, for example, at least two optical elements described above.
  • the two optical elements may be disposed to face each other, and the relative positions of the optical elements disposed to face each other may be changed.
  • the transmittance or polarization state of the light can be adjusted.
  • the transmittance of the optical panel can be adjusted to the minimum, and the optical absorption axes are parallel to each other.
  • permeability of an optical panel can be maximized.
  • the optical elements are arranged such that the angles formed by the respective light absorption axes are within a range of more than 0 degrees and less than 90 degrees, a range of transmittances may be realized between the maximum and minimum transmittances.
  • the polarization state or transmittance of the transmitted light may be adjusted by adjusting the relationship between the respective optical axes as described above.
  • FIG. 4 is an example in which optical elements are arranged such that each optical axis or light absorption axis of the optical element 30 is perpendicular to each other.
  • FIG. 5 is an example in which the axes are arranged parallel to each other. In this case, the optical elements are arranged such that the angles formed by the axes are within a range of more than 0 degrees and less than 90 degrees.
  • the distance between the opposingly disposed optical elements and the manner of arranging the elements so that the relative positions between the optical elements can be changed are not particularly limited.
  • the present application relates to a polarizing mask.
  • the polarization mask of the present application may be used, for example, in the manufacturing process of the optical device, specifically, in the exposure process of the alignment layer for manufacturing the optical device.
  • the polarization mask may include a polarization line including a plurality of polarization regions disposed adjacently along a predetermined direction (hereinafter, referred to as a first direction).
  • the polarization lines may be adjacent to each other along a direction perpendicular to the first direction (hereinafter, referred to as a second direction).
  • the term vertical is substantially vertical, and an angle in the range of about 70 degrees to 120 degrees, about 80 degrees to 100 degrees, or about 85 degrees to 95 degrees may also be included in the category of substantially vertical.
  • FIG. 7 is a diagram schematically illustrating a case where the polarizing mask is observed from above, in which the vertical direction is the first direction, and the horizontal direction is the second direction.
  • the first polarization regions 1011, 1012, 1013, 1014, and 1015 disposed adjacent to each other in the first direction form the first polarization line 101 and are formed in the same manner.
  • Polarization lines 102, 103, 104 and 105 are arranged adjacent along the second direction.
  • At least one polarization line among the plurality of polarization lines included in the polarization mask may include polarization regions having different transmission axis directions.
  • FIG. 8 the angle of the transmission axis formed in each of the polarization regions 1011 to 1015, 2011 to 2015, 3011 to 3015, 4011 to 4015 and 5011 to 5015 of the polarization mask of FIG. 7 is described (FIG. A number in each polarization region of 8).
  • the angle sets the angle of the polarization region of any one of the polarization regions of the polarization mask to 0 degrees, and clockwise or half with respect to the 0 degrees.
  • the angle measured in one of clockwise directions may be referred to.
  • the second to fourth polarization lines 102 to 104 include at least two polarization regions having different transmission axis directions from each other.
  • At least one polarization line in the polarization mask has a first polarization region having a transmission axis formed in a predetermined direction (hereinafter referred to as a first direction) and a second polarization region having a transmission axis formed in a second direction different from the first direction.
  • the first and second polarization regions may be disposed adjacent to each other.
  • the second polarization line 102 and the second polarization region 1022 and the third polarization region 1023 have transmission axes formed in different directions and are disposed adjacent to each other. .
  • the angle formed by the direction of the transmission axis of the first polarization region (first direction) and the direction of the transmission axis of the second polarization region (second direction) is, for example, about 15 degrees to 30 degrees and about 16 degrees.
  • At least two polarization lines among the polarization lines in the polarization mask may have different average transmission axes.
  • the term average transmission axis may mean an average value of angles of transmission axes of all polarization regions included in the polarization line. For example, referring to FIG. 8, the average transmission axis of the first polarization line is 0 degrees, the average transmission axis of the second polarization line is 4.5 degrees, the average transmission axis of the third polarization line is 9, and The average transmission axis is 13.5, and the average transmission axis of the fifth polarization line is 22.5.
  • the polarization mask may include a first polarization line having an average transmission axis formed in a predetermined direction (hereinafter, a first direction) and a second polarization line having an average transmission axis formed in a second direction different from the first direction. have.
  • the first and second polarization lines may be adjacent to each other.
  • first to fifth polarization lines 101 to 105 having an average transmission axis of 0 degrees, 4.5 degrees, 9 degrees, 13.5 degrees, and 22.5 degrees, respectively, are disposed adjacent to each other along the horizontal direction. This is an example of the case.
  • an angle formed between the direction of the average transmission axis of the first polarization line (first direction) and the direction of the average transmission axis of the second polarization line (second direction) may be, for example, about 1 to 20 degrees. .
  • the angle may be at least about 2 degrees, at least about 3 degrees, or at least about 3.5 degrees in another example.
  • the angle may be about 19 degrees or less, about 18 degrees or less, about 17 degrees or less, about 16 degrees or less, or about 15 degrees or less in another example.
  • the polarization mask may include an increasing area or a decreasing area in which the average transmission axis of the polarization lines increases along the second direction.
  • the mask is formed with polarization lines A to D in which the average transmission axis increases 72 degrees, 76.5 degrees, 81 degrees and 90 degrees from left to right in the drawing. And a decrease region formed by the polarization lines D to H, where the increase region is reduced and the average transmission axis is reduced by 90 degrees, 85.5 degrees, 81 degrees, 76.5 degrees and 67.5 degrees.
  • the increase or decrease rate in such an increase or decrease region may be determined according to Equation 7 below.
  • R is the increase or decrease rate
  • Q is the increase or decrease of the average transmission axis and the average transmission axis of the polarization line in which the average transmission axis starts to increase or decrease in the increase area or the decrease area disposed along the second direction. Is an angle formed by the average transmission axis of the polarization line to be terminated, and N is the number of polarization lines included in the increase or decrease region.
  • the increase or decrease of the average transmission axis in the increase area or the decrease area may be determined based on either the clockwise direction or the counterclockwise direction.
  • region which consist of polarization lines D-H are 4.5.
  • the increase rate R or the decrease rate R may be, for example, within a range of about 1-10. In another example, the increase rate R or decrease rate R may be about 2 or more, 3 or more, 4 or more, or 4.5 or more. In another example, the increase rate R or decrease rate R may be about 9 or less, 8 or less, 7 or less, 6 or less, or about 5.5 or less.
  • Equation 7 Q may be in a range of about 70 degrees to 120 degrees, about 80 degrees to 100 degrees, or about 85 degrees to 95 degrees.
  • N in Equation 7 may be in the range of about 5 to 30.
  • N may be in the range of 7 to 28, 9 to 26, 11 to 24, or 13 to 22 degrees.
  • the width (dimension measured along the second direction) and the length (dimension measured along the first direction) of the polarization line in the polarization mask are not particularly limited and may be determined according to the intended use.
  • the width may be in the range of about 1 mm to 20 mm.
  • the length may also be in the range of about 30 mm to 70 mm, for example.
  • each polarization line of the polarization mask is not particularly limited, and may be appropriately selected within the range of about 2 to 10, in consideration of the desired orientation efficiency and the like.
  • the method of manufacturing such a polarizing mask is not particularly limited, and for example, a PVA (poly (vinyl alcohol)) polarizing plate, a WGP (Wire Grid Polarizer), or the like may be manufactured in combination.
  • a PVA poly (vinyl alcohol)
  • WGP Wireless Grid Polarizer
  • the mask may be maintained to form a curved surface.
  • the surface of the irradiated object of the exposure process using the mask is kept curved, it may be necessary to keep the polarization mask curved.
  • the term roll-to-roll process may include all processes including a process of irradiating light while continuously transporting an object using a roll such as a guide roll, a transfer roll, or a winding roll.
  • the process of irradiating light onto the irradiated object may be performed, for example, while the irradiated object is wound on a roll.
  • FIG. 10 exemplarily illustrates a process of irradiating light onto the irradiated object 50 through the polarization mask 40 in a roll-to-roll process.
  • the irradiated object 50 is wound on the roll 60 so that the surface is kept curved, and light may be irradiated in this state.
  • the shape of the mask held in the curved shape for example, the radius of curvature of the mask is not particularly limited and may be selected so that appropriate irradiation of light can be performed on the irradiated object.
  • the radius of curvature of the mask can be adjusted to be equivalent to the radius of curvature of the irradiated object held in a curved shape.
  • the translucent support structure of the mask when the mask is kept curved may have a radius of curvature of about 10 mm to about 500 mm.
  • the present application also relates to a light irradiation apparatus or an apparatus for manufacturing an optical element comprising the polarizing mask.
  • the optical element manufactured by the said manufacturing apparatus may be the above-mentioned optical element.
  • the manufacturing apparatus may include, for example, a mounting means provided to allow the polarization mask and the irradiated object to be mounted.
  • the polarization mask and the mounting means may be configured such that the relative position of the irradiated object with respect to the polarization mask can be moved along the first direction, that is, along the longitudinal direction of the polarization line.
  • the type of mounting means in the apparatus is not particularly limited, and may include all kinds of equipment designed to stably maintain the subject during light irradiation.
  • the mounting means may be equipment that can be mounted while maintaining the surface of the object to be curved.
  • equipment may include, but are not limited to, rolls in the roll-to-roll process described above.
  • the equipment on which the subject is mounted is a device that can be mounted while maintaining the surface of the subject in a curved state
  • the mask may also be included in the apparatus in a state of being kept in a curved state.
  • the curved surface of the mask may be included in the device so as to correspond to the curved surface of the equipment on which the object is mounted.
  • the apparatus may further include a light source capable of irradiating light with the polarization mask.
  • a light source capable of irradiating light with the polarization mask.
  • a light source as long as it can irradiate light in the direction of a polarization mask, it can use without a restriction
  • a light source as a light source, as a light source which can irradiate an ultraviolet-ray, a high pressure mercury ultraviolet lamp, a metal halide lamp, or a gallium ultraviolet lamp And the like can be used.
  • the apparatus may further comprise one or more light collecting plates for the adjustment of the amount of light emitted from the light source.
  • the light collecting plate may be included in the apparatus, for example, after the light irradiated from the light source is incident on the light collecting plate and collected, the collected light can be irradiated with a polarization mask.
  • the light collecting plate if it is formed so as to collect light irradiated from the light source, a constitution commonly used in this field can be used.
  • As the light collecting plate a lenticular lens layer and the like can be exemplified.
  • the device may include, for example, a light source, a light collecting plate, a polarizing mask, and a mounting means that are sequentially arranged. Accordingly, the light irradiated from the light source may be first incident on the light collecting plate, collected, and then incident on the polarizing mask, then transmitted therethrough, and may be irradiated onto the surface of the irradiated object.
  • the present application relates to a light irradiation method or a manufacturing method of an optical element.
  • An exemplary method can be performed using the apparatus described above.
  • the method may include, for example, disposing an alignment layer, for example, a photoalignment layer under the polarization mask, and irradiating light to the alignment layer through the polarization mask.
  • the process may be performed by changing a relative position of the alignment layer with respect to the polarization mask along a first direction (the length direction of the polarization line).
  • an alignment layer capable of implementing the above-described optical device may be provided. For example, this will be described with reference to FIG. 9.
  • region of the alignment film which passes the lower part of polarization line A, respectively may be 67.5 degrees, It is sequentially exposed to linearly polarized light polarized at 67.5 degrees, 90 degrees, 67.5 degrees and 67.5 degrees.
  • the regions of the alignment layer passing through the lower portions of the polarization lines B to H are sequentially exposed to linearly polarized light polarized at an angle corresponding to the transmission axis direction of each polarization region.
  • the average transmission axes of the polarization lines are different from each other, the average transmission axes are arranged with a predetermined rule, so that the region of the alignment film passing through the lower portion of each polarization line is arranged in the arrangement and average transmission axes of the polarization regions of each polarization line. Therefore, the alignment direction is changed, and thus the optical axis or the light absorption axis of the optical layer formed thereon may be implemented in the above-mentioned structure.
  • the change speed of the relative position along the first direction between the alignment layer and the polarization mask is not particularly limited as long as proper alignment can be made.
  • the speed may be determined in a range of about 5 m / min or less.
  • the speed may, in another example, be about 4 m / min or less or about 3 m / min or less.
  • the speed may be, for example, about 0.5 m / min or more and about 1 m / min or more.
  • the exposure process may be performed while maintaining the surface of the alignment layer as the irradiated body as a curved surface.
  • An optical device may be manufactured by forming an optical layer on the alignment film formed as described above.
  • the method for forming the optical layer is not particularly limited, and for example, a layer containing the above-mentioned polymerizable liquid crystal compound and / or a dichroic dye or the like is formed on the alignment film, and aligned, followed by irradiation of light or application of heat. It can be formed by applying energy in the manner of.
  • the method of forming a layer containing a liquid crystal compound and / or a dichroic dye and the like above and aligning the alignment treatment, that is, the alignment pattern of the lower alignment layer, or polymerizing the aligned liquid crystal compound is not particularly limited.
  • the alignment can be carried out in such a manner as to maintain at an appropriate temperature that can be aligned depending on the type of liquid crystal compound and / or dichroic dye.
  • polymerization may be performed by irradiating light or applying heat at a level at which appropriate crosslinking or polymerization may be induced depending on the type of liquid crystal compound.
  • an optical element including an optical layer in which a change in an optical axis or light absorption axis occurs continuously is provided.
  • the optical element of the present application is used in an area requiring adjustment of heat, light or glare, for example, a window or shade of a building or an automobile, or other continuous change of the optical axis or light absorption axis is required. It can be effectively used in various devices.
  • 1-3 are conceptual diagrams illustrating exemplary optical devices.
  • 4 to 6 are conceptual diagrams showing an arrangement of an exemplary optical panel.
  • FIG. 10 shows the form of an exemplary device.
  • 11 and 12 are diagrams for explaining the polarization mask used in the embodiment.
  • FIG. 13 and 14 are views showing optical axis changes of the optical layer manufactured in Example.
  • optical device and the like will be described in detail with reference to Examples, but the scope of the optical device and the like is not limited by the following examples.
  • a conventional WGP (Wire Grid Polarizer) was cut to have a length of 10 mm in width and length, respectively, to prepare a WGP to form a polarization area. Thereafter, five WGPs (polarization regions) were attached so as to form one polarization line, thereby producing a polarization mask.
  • positioning of the polarization area of a polarization mask was set like FIG. 11 and FIG. 11 and 12 represent the angles of the transmission axis of each region. That is, referring to FIG. 11, there are five WGPs arranged to have a transmission axis of 0 degrees at the lowermost side, and all 16 polarized lines exist in the upper direction.
  • the polarizing mask was finally manufactured by attaching the upper end of the mask of FIG. 11 and the lower end of the mask of FIG. 12 to each other.
  • oriented compound a mixture of polynorbornene having a cinnamate group as disclosed in Korean Patent No. 1064585 with an appropriate amount of photoinitiator (Igacure 907) is added to the toluene solvent so that the solid content concentration of the oriented compound is 2% by weight. It melt
  • photoinitiator Igacure 907
  • the alignment layer was formed by irradiating ultraviolet (1,200 mJ / cm 2 ) from the upper part of the polarizing mask while moving the dried layer to pass through the lower part of the manufactured polarizing mask. Referring to FIGS. 11 and 12, the alignment film was moved from the right side to the left side of the drawing, and the moving speed was maintained at about 2.5 m / min.
  • FIG. 13 is a view showing an optical axis distribution of an optical layer formed in the above manner
  • FIG. 14 is a horizontal direction of the optical layer as the X axis (TD axis), and an angle of the optical axis (ground axis) as the Y axis ( It is a graph shown in retardation orientation.
  • the unit of the Y axis is degrees
  • the unit of the X axis is mm. It can be seen from the figure that the boundary between the regions is not observed and an optical layer in which the optical axis changes uniformly is formed.
  • An optical device was manufactured by forming an optical layer in the same manner as in Example 1 except that the moving speed of the alignment film was changed to about 1 m / min when irradiated with UV light for forming the alignment film.
  • a graph showing the horizontal direction of such an optical layer as the X axis and the angle of the optical axis (ground axis) as the Y axis is shown with the result of Example 1.
  • FIG. 14 the graph is almost overlapped with the result of Example 1, and from this, it can be seen that an optical layer is formed in which the optical axis is uniformly changed without the boundary between the regions being observed.
  • Example 1 Except for using the coating liquid containing the azo dichroic dye which oriented according to the orientation of a polymeric liquid crystal compound to the coating liquid containing a polymeric liquid crystal compound, and mix
  • An optical device was manufactured in the same manner as in Example 1. In such an optical element, an optical layer having a light absorption axis continuously changing in a manner corresponding to the optical axis distribution in Example 1 was formed by the dichroic dye.
  • Example 2 Except for using the coating liquid containing the azo dichroic dye which oriented according to the orientation of a polymeric liquid crystal compound to the coating liquid containing a polymeric liquid crystal compound, and mix
  • An optical device was manufactured in the same manner as in Example 2. In such an optical element, an optical layer having a light absorption axis continuously changing in a manner similar to the optical axis distribution in Example 2 was formed by the dichroic dye.

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