WO2014103468A1 - ダイシングシート用基材フィルムおよびダイシングシート - Google Patents
ダイシングシート用基材フィルムおよびダイシングシート Download PDFInfo
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- WO2014103468A1 WO2014103468A1 PCT/JP2013/077503 JP2013077503W WO2014103468A1 WO 2014103468 A1 WO2014103468 A1 WO 2014103468A1 JP 2013077503 W JP2013077503 W JP 2013077503W WO 2014103468 A1 WO2014103468 A1 WO 2014103468A1
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- dicing
- resin layer
- styrene
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- base film
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L21/6836—Wafer tapes, e.g. grinding or dicing support tapes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2405/00—Adhesive articles, e.g. adhesive tapes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2309/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
- C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/046—Presence of homo or copolymers of ethene in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2425/00—Presence of styrenic polymer
- C09J2425/006—Presence of styrenic polymer in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
- C09J2433/006—Presence of (meth)acrylic polymer in the substrate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
Definitions
- the present invention relates to a dicing sheet to which a cut object such as a semiconductor wafer is cut and separated into element pieces and a base film used for the dicing sheet.
- Semiconductor wafers such as silicon and gallium arsenide and various packages (hereinafter, these may be collectively referred to as “objects to be cut”) are manufactured in a large diameter state. It is cut and separated (diced).
- the object to be cut subjected to this dicing process is a dicing comprising a base film and a pressure-sensitive adhesive layer provided thereon for the purpose of ensuring the handleability of the object to be cut and chips in the dicing process and subsequent processes.
- the sheet is attached in advance to the surface of the workpiece on the side opposite to the side on which the cutting tool for cutting is close.
- a polyolefin film or a polyvinyl chloride film is usually used as a base film.
- full-cut dicing as a specific method of the dicing process, an object to be cut is cut by a rotating round blade.
- the pressure-sensitive adhesive layer is cut beyond the material to be cut and the part of the base film is also cut so that the material to be cut with the dicing sheet attached is surely cut over the entire surface.
- dicing waste made of the material constituting the pressure-sensitive adhesive layer and the base film may be generated from the dicing sheet, and the resulting chip may be contaminated by the dicing waste.
- One form of such dicing waste is thread-like dicing waste that adheres on the dicing line or near the cross section of the chip separated by dicing.
- the workpiece to be cut after the dicing process is then subjected to a cleaning process, an expanding process, and a pick-up process. Therefore, the dicing sheet is also required to have excellent expandability in the expanding process.
- Patent Document 1 discloses an invention in which a polyolefin film irradiated with an electron beam or a ⁇ (gamma) ray of 1 to 80 Mrad is used as a base film of a dicing sheet. Is disclosed. In the said invention, it is thought that resin which comprises a base film bridge
- Patent Document 1 polyethylene, polypropylene, polymethylpentene, ethylene-vinyl acetate copolymer, ethylene- (meth) acrylic acid copolymer, ethylene- ( Examples thereof include resins such as a (meth) methyl acrylate copolymer, an ethylene- (meth) ethyl acrylate copolymer, an ethylene-ionomer copolymer, an ethylene-vinyl alcohol copolymer, and polybutene.
- resins such as a (meth) methyl acrylate copolymer, an ethylene- (meth) ethyl acrylate copolymer, an ethylene-ionomer copolymer, an ethylene-vinyl alcohol copolymer, and polybutene.
- the base film is composed of at least two layers, and the resin of the layer in contact with the adhesive layer of the base film
- the styrene / butadiene copolymer hydrogenated product is 20 to 400 parts by mass with respect to 100 parts by mass of the polypropylene resin having a melting point of 130 to 240 ° C. and at least one layer in contact with the lower surface of the layer in contact with the adhesive layer.
- the adhesive composition tape for semiconductor dicing characterized by being the resin composition layer which consists of a part is illustrated.
- Patent Document 3 discloses a dicing film in which an adhesive layer is laminated on a base material layer containing random propylene and an olefin elastomer as a film imparted with expandability in an expanding process.
- the present invention has been made in view of the above-described actual situation, and does not give physical energy such as an electron beam or ⁇ -ray, and is generated during dicing of an object to be cut, in particular, thread-like dicing waste.
- An object of the present invention is to provide a dicing sheet base film having sufficient expandability (expandability) in the expanding step and a dicing sheet comprising such a dicing sheet base film.
- the present invention provides a substrate film for a dicing sheet comprising a resin layer (A), and the resin layer (A) has a density of 0.900 g / cm at 23 ° C. 3 or more polyethylene (a1) and a styrene-type elastomer (a2) are contained, and content of the said polyethylene (a1) is 50 mass% or more with respect to all the resin components contained in the said resin layer (A).
- a substrate film for a dicing sheet wherein the content is 90% by mass or less, and the content of the styrene-based elastomer (a2) is 10% by mass or more and 50% by mass or less (Invention 1).
- the “dicing sheet” in the present invention includes a dicing die bonding sheet, and also includes a substrate having another base material and an adhesive layer for attaching the ring frame.
- the “sheet” in the present invention includes the concept of “tape”.
- the “styrene elastomer (a2)” in the present invention is a copolymer including a structural unit derived from styrene or a derivative thereof (also referred to as “styrene compound” in the present specification), and includes a temperature including normal temperature. In the region, it means a material having rubber-like elasticity and thermoplasticity.
- the resin layer (A) contains the polyethylene (a1) and the styrene-based elastomer (a2), so that generation of thread-like debris during dicing is suppressed, and sufficient expansion is achieved in the expanding process.
- a substrate film having properties can be obtained. Therefore, it is possible to effectively reduce dicing waste generated during dicing of the workpiece without applying physical energy such as an electron beam or ⁇ -ray.
- a base film having sufficient expandability in the expanding step can be obtained.
- the styrene elastomer (a2) is preferably composed of a styrene-conjugated diene copolymer (Invention 2).
- the styrene elastomer (a2) contains at least one selected from the group consisting of a styrene-butadiene copolymer and a styrene-isoprene copolymer (Invention 3).
- the styrene elastomer (a2) preferably has a styrene content of 5% by mass or more and 50% by mass or less (Invention 4).
- the styrene elastomer (a2) is preferably a hydrogenated styrene-conjugated diene copolymer (Invention 5).
- the resin layer (B) preferably contains at least one of polypropylene, an ethylene- (meth) acrylic acid ester copolymer, and an ethylene- (meth) acrylic acid copolymer (Invention). 7).
- this invention was equipped with the base film for dicing which concerns on either of the said invention (1 to 7), and the adhesive layer arrange
- a characteristic dicing sheet is provided (Invention 8).
- the substrate film for dicing sheet and the dicing sheet according to the present invention dicing debris generated during dicing of an object to be cut can be effectively reduced without applying physical energy such as electron beams and ⁇ rays. Furthermore, a base film having sufficient expandability in the expanding step can be obtained.
- the base film for dicing sheet and the dicing sheet are easy to produce because they do not require electron beam or ⁇ ray processing.
- a dicing sheet 1 includes a base film 2 and an adhesive layer 3 disposed on the base film 2 as a basic configuration.
- This base film 2 includes a resin layer (A), and further includes a resin layer (B) in another embodiment (FIG. 2) as described later.
- Resin layer (A) As long as the base film 2 includes the resin layer (A), it may be a single layer or a plurality of layers. When the base film 2 consists of a single layer resin layer, the resin layer (A) becomes the base film 2 with a single layer. When the base film 2 is composed of a plurality of resin layers, the position of the resin layer (A) is not particularly limited, but at least one of the main surfaces of the base film 2 is the surface of the resin layer (A). It is preferable. In this case, when forming the adhesive layer 3 on the base film 2 and forming the dicing sheet 1, it is preferable that the adhesive layer 3 is formed on the resin layer (A). By doing in this way, the dicing waste generated at the time of dicing of a to-be-cut object can be reduced effectively.
- the resin layer (A) contains polyethylene (a1) having a density of 0.900 g / cm 3 or more at 23 ° C. and a styrene-based elastomer (a2).
- the content of polyethylene (a1) is preferably 50% by mass or more and 60% by mass or more with respect to all the resin components contained in the resin layer (A). It is more preferable that the content be 70% by mass or more.
- the content of polyethylene (a1) is preferably 90% by mass or less, more preferably 85% by mass or less, and more preferably 80% by mass with respect to all resin components contained in the resin layer (A). The following is particularly preferable.
- the content of polyethylene (a1) is less than 50% by mass, good expandability cannot be obtained, and sagging and blocking may occur.
- the resin layer (A) included in the base film 2 according to the present embodiment contains a styrene-based elastomer (a2) in addition to polyethylene (a1).
- a2 styrene-based elastomer
- the content of the styrene elastomer (a2) in the resin layer (A) is preferably 10% by mass or more, and more preferably 20% by mass or more.
- the content of the styrene-based elastomer (a2) is preferably 50% by mass or less, more preferably 45% by mass or less, based on all resin components contained in the resin layer (A). It is especially preferable to set it as the mass% or less.
- the component which comprises a resin layer (A) is demonstrated in detail.
- (1-1) Polyethylene (a1) The polyethylene (a1) contained in the resin layer (A) according to the present embodiment has a density of 0.900 g at 23 ° C. among polyethylene which is a thermoplastic resin mainly composed of a polymer having ethylene as a monomer. / Cm 3 or more.
- the polyethylene (a1) satisfies the above-mentioned density condition, thereby improving the handling property of the base film 2 (specifically, suppressing the dicing sheet 1 from being excessively adhered to the dicing table, For example, it is possible to suppress the occurrence of slack during conveyance and to prevent blocking.)
- density at 23 ° C. Polyethylene (a1), is preferably 0.910 g / cm 3 or more, 0.920 g / cm 3 or more More preferably, it is 0.950 g / cm 3 or more.
- Polyethylene (a1) from the viewpoint of handling property, usually, preferably 1.000 g / cm 3 or less, more preferably 0.990 g / cm 3 or less, 0.980 g / Cm 3 or less is more preferable.
- the polymer constituting the polyethylene (a1) may be one type or a blend of a plurality of types of polymers. .
- the polyethylene (a1) may be a homopolymer of ethylene or a copolymer, but is preferably a homopolymer.
- the ethylene content in polyethylene is preferably 20% by mass or more, more preferably 50% by mass or more, and 90% by mass or more. Further preferred.
- polyethylene (a1) may have a crosslinked structure.
- the kind of the crosslinking agent that brings about the crosslinked structure is arbitrary.
- the crosslinked structure may be crosslinked between one type of polymer constituting polyethylene (a1), or may be crosslinked between different types of polymers.
- the polyethylene (a1) contained in the resin layer (A) according to this embodiment has a melt flow rate value of 0.1 g / 10 min or more at a temperature of 230 ° C. and a load of 2.16 kgf in accordance with JIS K7210: 1999. It is preferable from the viewpoint of suppressing the generation of dicing waste. From the viewpoint of stably realizing the generation of dicing waste, the melt flow rate of polyethylene (a1) is 0.5 g / 10 min or more and 10 g / 10 min or less, and 2.0 g / 10 min or more and 7 g / 10 min or less. More preferred. The tensile modulus of elasticity of polyethylene (a1) at 23 ° C.
- the tensile elastic modulus in this specification is based on JIS K7161: 1994 and JIS K7127: 1999 using a tensile tester (specifically, Autograph AG-IS 500N manufactured by Shimadzu Corporation) The value measured at 23 ° C.
- the fluidization temperature of polyethylene (a1) is not particularly limited, but it is usually preferably 100 ° C. or higher and 180 ° C. or lower.
- the resin layer (A) included in the base film 2 according to the present embodiment contains a styrene elastomer (a2).
- the “styrene elastomer (a2)” is a copolymer including a structural unit derived from styrene or a derivative thereof (styrene compound), and has rubber-like elasticity in a temperature range including normal temperature. In addition, it means a material having thermoplasticity.
- the styrene elastomer (a2) examples include styrene-conjugated diene copolymers and styrene-olefin copolymers.
- the styrene elastomer (a2) preferably contains a styrene-conjugated diene copolymer, and is composed of a styrene-conjugated diene copolymer. It is more preferable.
- styrene-conjugated diene copolymers include styrene-butadiene copolymers, styrene-butadiene-styrene copolymers (SBS), styrene-butadiene-butylene-styrene copolymers, styrene-isoprene copolymers, styrene.
- SBS styrene-butadiene-styrene copolymers
- SBS styrene-butadiene-styrene copolymers
- styrene-isoprene copolymers styrene-isoprene copolymers
- styrene-conjugated diene copolymers such as isoprene-styrene copolymer (SIS) and styrene-ethylene-isoprene-styrene copolymer; styrene-ethylene / propylene-styrene copolymer (SEPS, styrene-isoprene) -Hydrogenated styrene-conjugated diene copolymers such as -styrene copolymer water additives) and styrene-ethylene-butylene-styrene copolymers (SEBS, hydrogenated styrene-butadiene copolymers).
- SIS isoprene-styrene copolymer
- SEPS styrene-ethylene / propylene-styrene copolymer
- SEBS hydrogenated styrene-butad
- Tufprene (Asahi Kasei), Clayton (Clayton Polymer Japan), Sumitomo TPE-SB (Sumitomo Chemical), Epofriend (Daicel Chemical Industries), Lavalon (Mitsubishi Chemical) ), Septon (manufactured by Kuraray), Tuftec (manufactured by Asahi Kasei), and the like.
- the styrene elastomer (a2) may be a hydrogenated product or an unhydrogenated product.
- a hydrogenated product the compatibility with polyethylene (a1) is improved, and the total light transmittance of the resin layer (A) is improved. Therefore, when the pressure-sensitive adhesive layer included in the dicing sheet according to this embodiment includes an ultraviolet curable pressure-sensitive adhesive, the styrene elastomer (a2) is preferably a hydrogenated product.
- hydrogenated products examples include styrene-ethylene-butylene-styrene copolymers (SEBS, hydrogenated products of styrene-butadiene copolymers), styrene-ethylene / propylene-styrene copolymers (SEPS, styrene-isoprene copolymers).
- SEBS hydrogenated products of styrene-butadiene copolymers
- SEPS styrene-ethylene / propylene-styrene copolymers
- Hydrogenated styrene-conjugated diene copolymers such as The styrene elastomer (a2) is particularly preferably such a hydrogenated styrene-conjugated diene copolymer.
- the styrene-based elastomer (a2) has a mass ratio (also referred to as “styrene content” in this specification) of monomers composed of a styrene-based compound among all monomers used to form the elastomer. It is 5 mass% or more and 50 mass% or less.
- the styrene content is preferably 5% by mass or more, and more preferably 10% by mass or more.
- the styrene content is preferably 50% by mass or less, more preferably 40% by mass or less, and particularly preferably 25% by mass or less.
- the lower limit of the styrene content is usually 5% by mass or more.
- the styrene elastomer (a2) may be composed of one kind of resin or a mixture of plural kinds of resins.
- the physical properties of the styrene elastomer (a2) are not particularly limited. Preferred properties include rubber behavior as physical properties at room temperature.
- the resin layer (A) may contain other components in addition to the polyethylene (a1) and the styrene elastomer (a2).
- other components include thermoplastic elastomer resins such as isoprene rubber, nitrile rubber, acrylic rubber, urethane rubber, butadiene rubber, and copolymers thereof (excluding styrene elastomer (a2)), polypropylene, and the like.
- various additives such as pigments, flame retardants, plasticizers, antistatic agents, lubricants, fillers, etc., of olefin-based thermoplastic resins (excluding polyethylene (a1)).
- the base film 2 further includes a resin layer (B) in addition to the resin layer (A).
- the position of the resin layer (A) is not particularly limited, but at least one of the main surfaces of the base film 2 is preferably the surface of the resin layer (A).
- the base film 2 includes at least one resin layer (B) disposed on one surface side of the resin layer (A), and the dicing sheet 1 is The base film 2 and the pressure-sensitive adhesive layer 3 are preferably laminated so that the pressure-sensitive adhesive layer 3 is directly disposed on the resin layer (A) of the base film 2.
- the base film 2 is a multilayer formed by laminating the resin layer (A) and the resin layer (B), the expandability of the base film 2 can be improved.
- Examples of the resin constituting the resin layer (B) include olefin resins that are resins based on polymers containing structural units derived from olefin compounds; polyesters such as polyethylene terephthalate and polyethylene naphthalate; polyurethanes; polyvinyl chlorides; polyamides Is mentioned.
- an olefin resin is preferable as the resin constituting the resin layer (B).
- the resin constituting the resin layer (B) is an olefin resin
- the adhesion of the resin layer (B) to the resin layer (A) containing the polyethylene (a1) and the styrene elastomer (a2) described above is Highly, the possibility of delamination between the resin layer (A) and the resin layer (B) can be more stably reduced.
- olefin resins examples include polyethylene, polypropylene, polybutene, ethylene-propylene copolymer, ethylene-butene copolymer, ethylene- (meth) acrylic acid copolymer, ethylene-vinyl acetate copolymer, ethylene- Examples include (meth) acrylic acid ester copolymers.
- One type of olefin resin may be used, or two or more types of polymers may be mixed.
- (meth) acrylic acid in the present specification means both acrylic acid and methacrylic acid.
- the “ethylene- (meth) acrylic acid copolymer” may be an ethylene-acrylic acid copolymer, an ethylene-methacrylic acid copolymer, or an ethylene-acrylic acid-methacrylic acid copolymer. It may be a coalescence.
- the resin layer (B) having excellent toughness is easily obtained, and the adhesion of the resin layer (B) to the resin layer (A) containing polyethylene (a1) and styrene elastomer (a2).
- the resin constituting the resin layer (B) contains at least one of polypropylene, an ethylene- (meth) acrylic acid ester copolymer, and an ethylene- (meth) acrylic acid copolymer. Is preferred.
- the ethylene- (meth) acrylic acid copolymer contains structural units derived from other compounds as long as the effects of the present invention are not impaired, in addition to structural units derived from ethylene, acrylic acid and / or methacrylic acid. May be.
- examples of such other compounds include ⁇ -olefins such as propylene; (meth) acrylic acid esters such as methyl (meth) acrylate and ethyl (meth) acrylate.
- the mass ratio of the monomer composed of such other compounds may be less than 10 mass%. preferable.
- the polymer according to the resin layer (B) is composed of the above polypropylene, ethylene- (meth) acrylic acid ester copolymer and ethylene- (meth) acrylic acid copolymer with respect to the whole resin constituting the resin layer (B). It is preferable to contain at least 70% by mass, more preferably 80% by mass or more, and still more preferably 90% by mass or more.
- the resin layer (B) preferably has a tensile elastic modulus of 50 MPa or more and 500 MPa or less and a breaking elongation of 100% or more. If the tensile modulus and elongation at break are in the above ranges, the resin layer (B) is excellent in flexibility and expandability, and therefore a base film in which the resin layer (A) and the resin layer (B) are laminated. 2 can be imparted with excellent expanding performance.
- the tensile elastic modulus of the resin layer (B) exceeds 500 MPa, the flexibility of the resin layer (B) becomes low and the resin layer (B) is easily broken, so that the expanding performance of the base film 2 is lowered. Is concerned.
- the tensile elastic modulus of the resin layer (B) is less than 50 MPa, the handling property may be lowered.
- a more preferable tensile elastic modulus of the resin layer (B) is 55 MPa or more and 400 MPa or less, a further preferable tensile elastic modulus is 60 MPa or more and 300 MPa or less, and a particularly preferable tensile elastic modulus is 65 MPa or more and 200 MPa or less.
- the resin layer (B) is easily broken when the dicing sheet 1 is expanded, and the expandability of the base film 2 is lowered. There is a concern to do.
- the more preferable breaking elongation of the resin layer (B) is 200% or more, and the particularly preferable breaking elongation is 300% or more.
- the upper limit of the elongation at break of the resin layer (B) is not particularly limited, but is generally 1000% or less and may be about 800% or less.
- the resin layer (B) may contain components other than the above-mentioned resin as long as the effects of the present invention are not impaired.
- components include various additives such as pigments, flame retardants, plasticizers, antistatic agents, lubricants and fillers.
- pigments include titanium dioxide and carbon black.
- filler include organic materials such as melamine resin, inorganic materials such as fumed silica, and metal materials such as nickel particles.
- the resin layer (B) is composed of a single resin layer, but the resin layer (B) may have a structure composed of a plurality of resin layers. An intervening layer such as an adhesive layer may exist between the resin layer (A) and the resin layer (B).
- base film 2 is resin layer (A) independent, resin layer (A) (namely, base film 2)
- the thickness is usually from 10 ⁇ m to 500 ⁇ m, preferably from 40 ⁇ m to 300 ⁇ m, more preferably from 60 ⁇ m to 200 ⁇ m.
- the thickness of the base film 2 is usually 20 ⁇ m or more and 600 ⁇ m. Or less, preferably 40 ⁇ m or more and 300 ⁇ m or less, more preferably 60 ⁇ m or more and 200 ⁇ m or less.
- the thickness of the resin layer (A) that is the resin layer on the side in contact with the pressure-sensitive adhesive layer 3 is usually 10 ⁇ m or more and 300 ⁇ m, preferably 20 ⁇ m or more and 120 ⁇ m or less Preferably they are 30 micrometers or more and 100 micrometers or less.
- the thickness of the resin layer (B) is usually from 10 ⁇ m to 300 ⁇ m, preferably from 40 ⁇ m to 120 ⁇ m, particularly preferably from 50 ⁇ m to 100 ⁇ m.
- the tensile elasticity modulus (tensile elasticity modulus at 23 degreeC) of the base film 2 in this embodiment is 50 MPa or more and 1000 MPa or less, and 80 MPa or more and 1000 MPa or less.
- the handleability of the base film 2 may worsen that a tensile elasticity modulus is less than 50 Mpa.
- the tensile elastic modulus of the base film 2 exceeds 1000 MPa, the base film 2 is broken in the expanding process, or the load applied during the expanding process is increased, so that the dicing sheet 1 itself is peeled off from the ring frame. May cause problems.
- the manufacturing method of the base film 2 is not specifically limited. Examples include melt extrusion methods such as a T-die method and a round die method; calendar methods; solution methods such as a dry method and a wet method, and any method may be used. Considering that both the polyethylene (a1) and the styrene-based elastomer (a2) contained in the resin layer (A) are thermoplastic resins, it is preferable to employ a melt extrusion method or a calender method. Among these, in the case of producing by a melt extrusion method, the components constituting the resin layer (A) are kneaded, and after producing pellets directly from the obtained kneaded material or once using a known extruder. What is necessary is just to form a film.
- the production method is not particularly limited and is arbitrary. An appropriate method may be adopted in accordance with the composition and purpose of the resin layer (B).
- the resin layer (A) and the resin layer (B) may be laminated by coextrusion molding, or individually produced resin layers may be adhered and laminated with an adhesive or the like.
- Dicing sheet A dicing sheet is provided with the adhesive layer arrange
- the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer 3 is not particularly limited, and those usually used as dicing sheets can be used.
- those usually used as dicing sheets can be used.
- rubber-based, acrylic-based, epoxy-based, silicone-based Polyvinyl ether-based pressure-sensitive adhesives are used, and energy ray-curable pressure-sensitive adhesives (including UV-curable pressure-sensitive adhesives) and heat-curable pressure-sensitive adhesives can also be used.
- an adhesive, a thermoplastic adhesive, a B stage adhesive, etc. that simultaneously have a wafer fixing function and a die bonding function. Is used.
- the thickness of the pressure-sensitive adhesive layer 3 is usually about 3 to 100 ⁇ m, preferably about 5 to 80 ⁇ m.
- the adhesive layer 3 may be laminated with a release sheet.
- a release sheet for protecting the pressure-sensitive adhesive layer 3 is optional. It does not specifically limit as a peeling sheet, For example, what has the peeling layer by which the peeling process was carried out with the release agent on a base material can be used.
- the base material for the release sheet examples include glassine paper, coated paper, polyethylene film, polypropylene film, polybutene film, polybutadiene film, polymethylpentene film, polyvinyl chloride film, vinyl chloride copolymer film, polyethylene terephthalate film, Polyethylene naphthalate film, polybutylene terephthalate film, polyurethane film, ethylene vinyl acetate film, ionomer resin film, ethylene- (meth) acrylic acid copolymer film, ethylene- (meth) acrylic acid ester copolymer film, polystyrene film, You may use a polycarbonate film, a polyimide film, a fluororesin film, or these crosslinked films. Furthermore, a laminated film in which a plurality of these films are laminated may be used.
- release agent used for the release treatment examples include alkyd, silicone, fluorine, unsaturated polyester, polyolefin, and wax release agents.
- the thickness of the release sheet is not particularly limited, and is usually about 20 to 150 ⁇ m.
- the manufacturing method of the dicing sheet 1 which consists of laminated bodies, such as said base film 2 and the adhesive layer 3, and a peeling sheet used as needed, is not specifically limited.
- the manufacturing method of the dicing sheet 1 are as follows.
- (I) The pressure-sensitive adhesive layer 3 is formed on the release sheet, and the base film 2 is pressure-bonded and laminated on the pressure-sensitive adhesive layer 3.
- the formation method of the adhesive layer 3 is arbitrary.
- An example of a method for forming the pressure-sensitive adhesive layer 3 is as follows. A coating agent containing the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer 3 and optionally a solvent is prepared. On one main surface constituted by the resin layer (A) in the base film 2 by a coating machine such as a roll coater, knife coater, roll knife coater, air knife coater, die coater, bar coater, gravure coater, curtain coater, etc. Apply.
- the pressure-sensitive adhesive layer 3 is formed by drying the layer made of the coating agent on the base film 2.
- the pressure-sensitive adhesive layer 3 is formed on the substrate film 2, and a release sheet is further laminated as necessary.
- the formation method of the adhesive layer 3 at this time is arbitrary as described above.
- a pressure-sensitive adhesive layer 3 separately formed in a sheet shape may be attached to the base film 2.
- Example 1 Preparation of base film
- 70 parts by mass of low density polyethylene manufactured by Sumitomo Chemical Co., Ltd., product name: Sumikasen (registered trademark) L705, density 0.919 g / cm 3 at 23 ° C.
- polyethylene a1
- styrene as styrene elastomer
- SEBS -Hydrogenated butadiene copolymer
- Extrusion raw material for resin layer (A) is extruded with a small T-die extruder (Toyo Seiki Seisakusho Co., Ltd., Labo Plast Mill), and the substrate has a single layer structure consisting of a resin layer (A) having a thickness of 100 ⁇ m A film was obtained.
- the obtained energy ray-curable pressure-sensitive adhesive composition was applied to the release-treated surface of a silicone-treated release sheet (Lintec Corporation, SP-PET38111 (S)) so that the film thickness after drying was 10 ⁇ m.
- a pressure-sensitive adhesive layer is formed by drying at 100 ° C. for 1 minute, and the pressure-sensitive adhesive layer is transferred onto the base film by sticking it to the surface of the base film on the resin layer (A) side. It was.
- Examples 2 to 7, Comparative Examples 1 to 5 A dicing sheet was produced in the same manner as in Example 1 except that the material of the resin layer (A) was changed to that shown in Table 1.
- Example 8 Preparation of base film
- 70 parts by mass of low density polyethylene manufactured by Sumitomo Chemical Co., Ltd., product name: Sumikasen (registered trademark) L705, density 0.919 g / cm 3 at 23 ° C.
- polyethylene a1
- styrene as styrene elastomer
- SEBS -Hydrogenated butadiene copolymer
- SEBS styrene as styrene elastomer
- SEBS -Hydrogenated butadiene copolymer
- Tuftec registered trademark
- H1221 styrene content: 12% by mass
- 30 parts by mass of a twin-screw kneader manufactured by Toyo Seiki Seisakusho
- Laboplast Mill Laboplast Mill
- An ethylene-methacrylic acid copolymer (manufactured by Sumitomo Chemical Co., Ltd., product name: ACLIFT (registered trademark) W201) is melt-kneaded with a twin-screw kneader (manufactured by Toyo Seiki Seisakusho Co., Ltd., product name: Labo Plast Mill), and resin An extrusion raw material for layer (B) was obtained.
- the extrusion raw material for the resin layer (A) and the extrusion raw material for the resin layer (B) are coextruded by a small T-die extruder (manufactured by Toyo Seiki Seisakusho, product name: Labo Plast Mill), A base film having a two-layer structure composed of a resin layer (A) having a thickness of 40 ⁇ m and a resin layer (B) having a thickness of 60 ⁇ m was obtained. A dicing sheet was produced in the same manner as in Example 1 using the obtained base film.
- Example 9 In Example 8, dicing was performed in the same manner as in Example 8 except that the type of resin for forming the resin layer (B) was changed to another random polypropylene (manufactured by Nippon Polypro Co., Ltd., product name: Novatec PP FX4E). A sheet was produced.
- Table 1 summarizes the compositions of the above Examples and Comparative Examples. The numerical value in Table 1 means the mass part of each component.
- tip was peeled by irradiating an ultraviolet-ray (160mJ / cm ⁇ 2 >) from the base film side.
- an ultraviolet-ray 160mJ / cm ⁇ 2 >
- the number of filamentous scraps having a length of 100 ⁇ m or more generated in one vertical line and one horizontal line near the center of each was measured using a digital microscope (VHX-100, Keyence Corporation, magnification: 100). Times).
- the measurement results were evaluated according to the following criteria. The evaluation results are shown in Table 2.
- Test Example 3 (Handling evaluation) In carrying out the test example 1 (observation of dicing waste), dicing was performed with a fully automatic dicing apparatus (DFD-651 manufactured by DISCO). The handling property from sample introduction to collection at this time was evaluated according to the following criteria. The evaluation results are shown in Table 2.
- the dicing sheets produced in the examples are less likely to generate dicing waste during the dicing process, have excellent expandability during the expanding process, and are excellent in handling characteristics during the dicing process. It was.
- the substrate film for dicing sheet and the dicing sheet according to the present invention are suitably used for dicing semiconductor wafers and various packages.
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Abstract
Description
1.基材フィルム
図1に示されるように、本発明の一実施形態に係るダイシングシート1は、基本構成として、基材フィルム2およびこの基材フィルム2上に配置された粘着剤層3を備える。この基材フィルム2は樹脂層(A)を備え、後述するように別の一形態(図2)では樹脂層(B)をさらに備える。
基材フィルム2は、樹脂層(A)を備える限り、単層であっても複数層であってもよい。基材フィルム2が単層の樹脂層からなる場合には、樹脂層(A)が単層のまま基材フィルム2となる。基材フィルム2が複数の樹脂層からなる場合には、樹脂層(A)の位置は特に限定されないが、基材フィルム2の主面の少なくとも一方が上記の樹脂層(A)の面となっていることが好ましい。この場合には、基材フィルム2上に粘着剤層3を形成してダイシングシート1を形成するにあたり、樹脂層(A)上に粘着剤層3が形成されることが好ましい。このようにすることで、被切断物のダイシング時に発生するダイシング屑を効果的に低減することができる。
(1-1)ポリエチレン(a1)
本実施形態に係る樹脂層(A)が含有するポリエチレン(a1)は、エチレンを単量体とする高分子を主成分とする熱可塑性樹脂であるポリエチレンのうち、23℃における密度が0.900g/cm3以上のものである。ポリエチレン(a1)が上記の密度上の条件を満たすことにより、基材フィルム2のハンドリング性を向上させること(具体的には、ダイシングシート1がダイシングテーブルに過度に密着することを抑制すること、搬送時の弛みの発生を抑制すること、ブロッキングを生じにくくすることなどが例示される。)ができる。樹脂層(A)のハンドリング性をより安定的に向上させる観点から、ポリエチレン(a1)の23℃における密度は、0.910g/cm3以上であることが好ましく、0.920g/cm3以上であることがより好ましく、0.950g/cm3以上であることがさらに好ましい。ポリエチレン(a1)の23℃における密度の上限は特に制限はないが、ハンドリング性の点から、通常、1.000g/cm3以下が好ましく、0.990g/cm3以下がより好ましく、0.980g/cm3以下がさらに好ましい。
ポリエチレン(a1)の23℃における引張弾性率は特に限定されないが、という観点から、通常、1.0GPa以下であり、0.4GPa以下であることが好ましく、0.2GPa以下であればより好ましい。なお、本明細書における引張弾性率は、JIS K7161:1994およびJIS K7127:1999に準拠して、引張試験機(具体的には、島津製作所製のオートグラフAG-IS 500N)を使用して、23℃にて測定した値とする。
また、ポリエチレン(a1)の流動化温度は、特に限定されないが、通常100℃以上180℃以下であることが好ましい。
本実施形態に係る基材フィルム2が備える樹脂層(A)は、スチレン系エラストマー(a2)を含有する。本明細書において「スチレン系エラストマー(a2)」とは、スチレンまたはその誘導体(スチレン系化合物)に由来する構造単位を含む共重合体であって、常温を含む温度域ではゴム状の弾性を有するとともに、熱可塑性を有する材料を意味する。樹脂層(A)はスチレン系エラストマー(a2)を含有することにより、切削片の発生が抑制され、エキスパンド性も向上する。
樹脂層(A)は上記のポリエチレン(a1)およびスチレン系エラストマー(a2)に加えて、他の成分を含有してもよい。そのような他の成分として、イソプレンゴムやニトリルゴム、アクリルゴム、ウレタンゴム、ブタジエンゴム、またはその共重合体などの熱可塑性エラストマー樹脂(ただし、スチレン系エラストマー(a2)を除く。)、ポリプロピレン等のオレフィン系熱可塑性樹脂(ただし、ポリエチレン(a1)を除く。)、顔料、難燃剤、可塑剤、帯電防止剤、滑剤、フィラー等の各種添加剤などが例示される。
基材フィルム2が複層からなる場合には、基材フィルム2は上記の樹脂層(A)の他に、樹脂層(B)をさらに備える。この場合、樹脂層(A)の位置は特に限定されないが、基材フィルム2の主面の少なくとも一方が樹脂層(A)の面となっていることが好ましい。具体的には、図2に示すように、基材フィルム2は、樹脂層(A)の一方の面側に配置された、少なくとも一層からなる樹脂層(B)を備え、ダイシングシート1は、その基材フィルム2の樹脂層(A)上に直接粘着剤層3が配置されるように、基材フィルム2と粘着剤層3とが積層されてなることが好ましい。
図1に示されるように、基材フィルム2が、樹脂層(A)単独である場合には、樹脂層(A)(すなわち、基材フィルム2)の厚さは、通常、10μm以上500μm以下であり、好ましくは40μm以上300μm以下であり、より好ましくは60μm以上200μm以下である。
基材フィルム2の製造方法は特に限定されない。Tダイ法、丸ダイ法等の溶融押出法;カレンダー法;乾式法、湿式法等の溶液法などが例示され、いずれの方法でもよい。樹脂層(A)に含まれるポリエチレン(a1)およびスチレン系エラストマー(a2)がいずれも熱可塑性樹脂であることを考慮し、溶融押出法またはカレンダー法を採用することが好ましい。これらのうち、溶融押出法により製造する場合には、樹脂層(A)を構成する成分を混練し、得られた混練物から直接、または一旦ペレットを製造したのち、公知の押出機を用いて製膜すればよい。
ダイシングシートは、基材フィルム上に配置された粘着剤層を備える。より具体的には、ダイシングシート1は、基材フィルム2の樹脂層(A)上に粘着剤層3が配置されていることが好ましい。樹脂層(A)上に粘着剤層3が形成されることで、被切断物のダイシング時に発生するダイシング屑を効果的に低減することができる。
粘着剤層3を構成する粘着剤としては、特に限定されず、ダイシングシートとして通常用いられるものを使用することができ、例えば、ゴム系、アクリル系、エポキシ系、シリコーン系、ポリビニルエーテル系等の粘着剤が用いられ、エネルギー線硬化型粘着剤(紫外線硬化型粘着剤を含む)や加熱硬化型粘着剤を用いることもできる。また、本実施形態におけるダイシングシート1がダイシング・ダイボンディングシートとして使用される場合には、ウェハ固定機能とダイ接着機能とを同時に兼ね備えた粘接着剤、熱可塑性接着剤、Bステージ接着剤等が用いられる。
粘着剤層3の厚さは、通常は3~100μm、好ましくは5~80μm程度である。
粘着剤層3には、剥離シートが積層されていてもよい。粘着剤層3を保護するための剥離シートは任意である。
剥離シートとして、特に限定されず、例えば、基材上に剥離剤により剥離処理された剥離層を有するものを用いることができる。剥離シート用の基材としては、例えば、グラシン紙、コート紙、ポリエチレンフィルム、ポリプロピレンフィルム、ポリブテンフィルム、ポリブタジエンフィルム、ポリメチルペンテンフィルム、ポリ塩化ビニルフィルム、塩化ビニル共重合体フィルム、ポリエチレンテレフタレートフィルム、ポリエチレンナフタレートフィルム、ポリブチレンテレフタレートフィルム、ポリウレタンフィルム、エチレン酢酸ビニルフィルム、アイオノマー樹脂フィルム、エチレン-(メタ)アクリル酸共重合体フィルム、エチレン-(メタ)アクリル酸エステル共重合体フィルム、ポリスチレンフィルム、ポリカーボネートフィルム、ポリイミドフィルム、フッ素樹脂フィルム、または、これらの架橋フィルムを用いてもよい。さらに、これらのフィルムの複数が積層された積層フィルムであってもよい。
なお、剥離シートの厚さについては特に限定されず、通常20~150μm程度である。
上記の基材フィルム2および粘着剤層3、ならびに必要に応じて用いられる剥離シート等の積層体からなるダイシングシート1の製造方法は特に限定されない。
(i)剥離シート上に粘着剤層3を形成し、その粘着剤層3上に基材フィルム2を圧着して積層する。このとき、粘着剤層3の形成方法は任意である。
粘着剤層3の形成方法の一例を挙げれば次のようになる。粘着剤層3を構成する粘着剤と、所望によりさらに溶媒とを含有する塗布剤を調製する。ロールコーター、ナイフコーター、ロールナイフコーター、エアナイフコーター、ダイコーター、バーコーター、グラビアコーター、カーテンコーター等の塗工機によって、基材フィルム2における樹脂層(A)により構成される一方の主面に塗布する。基材フィルム2上の塗布剤からなる層を乾燥させることにより、粘着剤層3が形成される。
上記(i)、(ii)の方法以外の例として、別途シート状に形成した粘着剤層3を基材フィルム2に貼付してもよい。
(基材フィルムの作製)
ポリエチレン(a1)としての低密度ポリエチレン(住友化学社製,製品名:スミカセン(登録商標)L705,23℃における密度0.919g/cm3)70質量部と、スチレン系エラストマー(a2)としてのスチレン-ブタジエン共重合体の水素添加物(SEBS,旭化成社製,製品名:タフテック(登録商標)H1221,スチレン含有率:12質量%)30質量部とを、二軸混練機(東洋精機製作所社製、ラボプラストミル)にて溶融混練し、樹脂層(A)用の押出用原材料を得た。
樹脂層(A)用の押出用原材料を、小型Tダイ押出機(東洋精機製作所社製,ラボプラストミル)によって押出成形し、厚さ100μmの樹脂層(A)からなる単層構造の基材フィルムを得た。
一方、n-ブチルアクリレート95質量部およびアクリル酸5質量部を共重合してなる共重合体(Mw:500,000)100質量部、ウレタンアクリレートオリゴマー(Mw:8000)120質量部、イソシアネート系硬化剤(日本ポリウレタン社、コロネートL)5質量部、光重合開始剤(チバスペシャリティケミカルズ社製、イルガキュア184)4質量部とを混合し、エネルギー線硬化型粘着剤組成物を得た。
樹脂層(A)の材料を表1に記載のものに変更したことを除き、実施例1と同様にして、ダイシングシートを製造した。
(基材フィルムの作製)
ポリエチレン(a1)としての低密度ポリエチレン(住友化学社製,製品名:スミカセン(登録商標)L705,23℃における密度0.919g/cm3)70質量部と、スチレン系エラストマー(a2)としてのスチレン-ブタジエン共重合体の水素添加物(SEBS,旭化成社製,製品名:タフテック(登録商標)H1221,スチレン含有率:12質量%)30質量部とを、二軸混練機(東洋精機製作所社製、ラボプラストミル)にて溶融混練し、樹脂層(A)用の押出用原材料を得た。
エチレン-メタクリル酸共重合体((住友化学社製,製品名:アクリフト(登録商標)W201)を二軸混練機(東洋精機製作所社製,製品名:ラボプラストミル)にて溶融混練し、樹脂層(B)用の押出用原材料を得た。
樹脂層(A)用の押出用原材料と、樹脂層(B)用の押出用原材料とを、小型Tダイ押出機(東洋精機製作所社製,製品名:ラボプラストミル)によって共押出成形し、厚さ40μmの樹脂層(A)と、厚さ60μmの樹脂層(B)とからなる2層構造の基材フィルムを得た。得られた基材フィルムを用いて、実施例1と同様にしてダイシングシートを製造した。
実施例8において、樹脂層(B)を形成するための樹脂の種類を他のランダムポリプロピレン(日本ポリプロ社製,製品名:ノバテックPP FX4E)に変更する以外は、実施例8と同様にしてダイシングシートを製造した。
<樹脂層(A)>
・低密度ポリエチレン(住友化学社製,製品名:スミカセン(登録商標)L705,23℃における密度0.919g/cm3,23℃における引張弾性率140MPa)
・直鎖状低密度ポリエチレン(プライムポリマー社製,製品名:エボリュー(登録商標)SP3505,23℃における密度0.936g/cm3)
・高密度ポリエチレン(日本ポリエチレン社製,製品名:ノバテックHF560,23℃における密度0.963g/cm3)
・超低密度ポリエチレン(住友化学社製,製品名:エクセレンVL200,23℃における密度0.905g/cm3)
・超低密度ポリエチレン(住友化学社製,製品名:エクセレンEUL731,23℃における密度0.895g/cm3)
・スチレン-エチレン-ブチレン-スチレン共重合体(スチレン-ブタジエン共重合体の水素添加物)(SEBS,旭化成社製,製品名:タフテック(登録商標)H1041,スチレン含有率:30質量%)
・スチレン-エチレン-ブチレン-スチレン共重合体(スチレン-ブタジエン共重合体の水素添加物)(SEBS,旭化成社製,製品名:タフテック(登録商標)H1221,スチレン含有率:12質量%)
・スチレン-エチレン/プロピレン-スチレン共重合体(スチレン-イソプレン共重合体の水素添加物)(SEPS、クレイトンポリマージャパン社製,製品名:クレイトン(登録商標)G1730,スチレン含有率:21質量%)
・エチレン-メタクリル酸メチル共重合体(住友化学社製,製品名:アクリフト(登録商標)W201,23℃における引張弾性率65MPa)
・ランダムポリプロピレン(日本ポリプロ社製,製品名:ノバテックPP FX4E)
実施例および比較例で製造したダイシングシートの粘着剤層を切断されていないBGA型パッケージモジュールに貼付した後、ダイシング装置(DISCO社製DFD-651)にセットし、以下の条件でダイシングを行った。
・ワーク(被着体):シリコンウエハ
・ワークサイズ:6インチ径,厚さ350μm
・ダイシングブレード:ディスコ社製 27HEEE
・ブレード回転数:50,000rpm
・ダイシングスピード:10mm/秒
・切り込み深さ:基材フィルムを粘着剤層の界面より20μmの深さまで切り込み
・ダイシングサイズ:10mm×10mm
A:糸状屑の個数が0~10個
B:11~15個
C:16個以上
実施例および比較例で製造したダイシングシートの粘着剤層に6インチシリコンウェハを貼付した後、当該ダイシングシートをフラットフレームに装着し、20μm厚のダイヤモンドブレードにより、ウェハを10mm角のチップにフルカットした。次に、エキスパンディング冶具(NECマシナリー社製ダイボンダーCSP-100VX)を用いて、ダイシングシートを600mm/分で10mmで引き落とした。このときのダイシングシートの破断の有無について確認を行った。その結果を次の基準で評価した。評価結果を表2に示す。
A:2条件ともに破断が確認されない場合
B:いずれかの条件で破断が確認された場合
C:両条件共に破断が確認された場合
上記の試験例1(ダイシング屑観察)を実施するにあたり、フルオートのダイシング装置(DISCO社製DFD-651)にてダイシングを行った。このときのサンプル投入から回収までの間のハンドリング性に関し、次の基準で評価した。評価結果を表2に示す。
A:特段の問題が生じなかった場合
A1:わずかに不具合は生じたが、実用上問題なかった場合
B:(1)ダイシングシート用基材フィルムの状態で巻き取り、繰り出しを行った際、ブロッキングなどの不具合が発生した、(2)搬送エラーが生じた場合、および(3)ウェハカセットに再度装着された際、ダイシングシートがたわみ、下の段に設置してある別のダイシングシートと触れた、の少なくとも一つの不具合が発生した場合
2…基材フィルム(樹脂層(A)/樹脂層(B))
3…粘着剤層
Claims (8)
- 樹脂層(A)を備えるダイシングシート用基材フィルムであって、
当該樹脂層(A)は、23℃における密度が0.900g/cm3以上のポリエチレン(a1)と、スチレン系エラストマー(a2)とを含有し、
前記樹脂層(A)に含有される全樹脂成分に対して、前記ポリエチレン(a1)の含有量は50質量%以上90質量%以下であり、前記スチレン系エラストマー(a2)の含有量は10質量%以上50質量%以下であることを特徴とするダイシングシート用基材フィルム。 - 前記スチレン系エラストマー(a2)が、スチレン-共役ジエン共重合体からなる、請求項1に記載のダイシングシート用基材フィルム。
- 前記スチレン系エラストマー(a2)が、スチレン-ブタジエン共重合体およびスチレン-イソプレン共重合体からなる群から選ばれる少なくとも一種を含む、請求項2に記載のダイシングシート用基材フィルム。
- 前記スチレン系エラストマー(a2)は、スチレン含有率が5質量%以上50質量%以下である、請求項1から3のいずれか一項に記載のダイシングシート用基材フィルム。
- 前記スチレン系エラストマー(a2)は、水添スチレン-共役ジエン共重合体である、請求項1から4のいずれか一項に記載のダイシングシート用基材フィルム。
- 前記樹脂層(A)の一方の面側に配置された、少なくとも一層からなる樹脂層(B)を備える、請求項1から5のいずれか一項に記載のダイシングシート用基材フィルム。
- 前記樹脂層(B)は、ポリプロピレン、エチレン-(メタ)アクリル酸エステル共重合体およびエチレン-(メタ)アクリル酸共重合体の少なくとも一方を含む、請求項6に記載のダイシングシート用基材フィルム。
- 請求項1から7のいずれかに記載されるダイシング用基材フィルムと、当該フィルムの前記樹脂層(A)上に配置された粘着剤層とを備えたことを特徴とするダイシングシート。
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US14/654,967 US20150348820A1 (en) | 2012-12-28 | 2013-10-09 | Dicing sheet base film and dicing sheet |
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JP2021024949A (ja) * | 2019-08-05 | 2021-02-22 | 日東電工株式会社 | 粘着シート |
JP2021024950A (ja) * | 2019-08-05 | 2021-02-22 | 日東電工株式会社 | 粘着シート |
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WO2016052444A1 (ja) * | 2014-09-29 | 2016-04-07 | リンテック株式会社 | 半導体ウエハ加工用シート用基材、半導体ウエハ加工用シート、および半導体装置の製造方法 |
JP6204640B1 (ja) * | 2016-03-30 | 2017-09-27 | 三井化学東セロ株式会社 | 半導体装置の製造方法 |
CN110178203B (zh) * | 2016-12-27 | 2023-05-23 | 三井—陶氏聚合化学株式会社 | 切割膜基材及切割膜 |
CN111696907A (zh) * | 2020-06-28 | 2020-09-22 | 苏州佰霖新材料科技有限公司 | 一种led外延芯片加工用pvc划片膜 |
CN112048253B (zh) * | 2020-09-04 | 2022-04-12 | 浙江洁美电子科技股份有限公司 | 一种自粘型保护膜 |
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CN104756236A (zh) | 2015-07-01 |
TW201425518A (zh) | 2014-07-01 |
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EP2940716A4 (en) | 2016-09-14 |
KR20150099769A (ko) | 2015-09-01 |
MY171858A (en) | 2019-11-05 |
EP2940716A1 (en) | 2015-11-04 |
JPWO2014103468A1 (ja) | 2017-01-12 |
US20150348820A1 (en) | 2015-12-03 |
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CN104756236B (zh) | 2017-10-13 |
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