WO2014092220A1 - 이온성 액체를 이용한 은 나노와이어 제조방법 - Google Patents
이온성 액체를 이용한 은 나노와이어 제조방법 Download PDFInfo
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- WO2014092220A1 WO2014092220A1 PCT/KR2012/010921 KR2012010921W WO2014092220A1 WO 2014092220 A1 WO2014092220 A1 WO 2014092220A1 KR 2012010921 W KR2012010921 W KR 2012010921W WO 2014092220 A1 WO2014092220 A1 WO 2014092220A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0547—Nanofibres or nanotubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/062—Fibrous particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/06—Alloys based on silver
Definitions
- the present invention relates to a method for producing silver nanowires, and more particularly, using a silver salt precursor, a reducing solvent, a capping agent and an ionic liquid additive, having an aspect ratio of 100 or more (eg, a diameter of less than 100 nanometers). And having a length of 10 microns or more).
- touch screen panels have been used as core components of various types of electrical, electronic and communication devices including smart phones and tablet computers.
- the core material of the touch screen panel is a transparent electrode film, which generally has a surface resistivity of 500 ⁇ / ⁇ or less and a light transmittance of 90% or more relative to the light transmittance of the base film.
- Film is used.
- the most commonly used transparent electrode material is indium tin oxide (ITO), which mainly has a surface resistance of 50-500 ⁇ by forming an ITO thin film on the surface of glass or transparent polymer film by sputtering. It is possible to manufacture a transparent electrode film having a light transmittance of 90% or more compared to the light transmittance of the base film.
- ITO indium tin oxide
- the ITO transparent thin film has a high manufacturing cost due to the vacuum process, and the ITO thin film is easily damaged due to a difference in thermal expansion rate or thermal contraction rate between the base film and the ITO thin film.
- the ITO thin film formed on the polymer film has a very high brittleness, and when it is used as a transparent electrode film of a touch screen panel, cracks are generated due to mechanical and physical deformation.
- Silver nanowires are described in US 2005/0056118, Science 298, 2176, 2002, Chem. Mater. 14, 4736, 2002, etc. can be prepared by a synthetic method known as the so-called polyol process, reducing solvents such as silver precursor (metal precursor), ethylene glycol (ethylene glycol, EG) ), And a method of synthesizing silver nanowires having a one-dimensional shape in solution using a capping agent such as polyvinylpyrolidone (PVP).
- PVP polyvinylpyrolidone
- a method of synthesizing silver nanowires using an ionic liquid instead of PVP has been reported. (Angewandte Chemie, 121, 3864, 2009)
- Korean Patent Publication No. 10-2010-0055983 a method of preparing nanowires through a polyol reduction reaction was introduced by mixing and reacting a metal salt and a reducing solvent in the presence of an ionic liquid.
- An object of the present invention is to produce a reproducible, uniformly reproducible, non-nanomorphic silver nanowire having an aspect ratio of 100 or more, i.e., less than 100 nanometers in diameter and 10 microns or more in length, in a polyol reduction reaction using a metal salt as a precursor. It is to provide the technology that can be done.
- a method for uniformly preparing silver nanowires having a high aspect ratio of 100 nanometers in diameter and 10 microns in length by using an imidazolium-based ionic liquid as an additive in synthesizing silver nanowires using the polyol method will be.
- silver nanowires were prepared by mixing and reacting an imidazolium based ionic liquid as an additive in a polyol reaction including a silver salt precursor, a reducing solvent, and a capping agent.
- a silver salt precursor for example, AgNO 3
- a reducing solvent for example, ethylene glycol
- a capping agent for example, polyvinylpyrrolidone
- the silver salt is dissociated in a solvent and then converted to silver metal through a reduction reaction.
- the reducing solvent is a polar solvent capable of dissolving a silver salt, and refers to a solvent such as diol, polyol, or glycol having at least two hydroxyl groups in a molecule. Specific examples thereof include ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, glycerin, glycerol, diethyl glycol, and the like.
- the reducing solvent not only serves as a solvent for dissolving the silver salt but also serves to generate a silver metal element by inducing a reduction reaction of the silver cation above a certain temperature.
- the capping agent is adsorbed only on a specific crystal surface by interaction with the silver nanoparticles generated in the initial stage of the synthesis reaction (hereinafter referred to as capping), and serves to allow one-dimensional growth of the silver nanoparticles. It refers to polyvinylpyrollidone (PVP) or polyvinylalcohol (PVA).
- the imidazolium-based ionic liquid is a compound in the form of a monomer or a polymer composed of an organic cation and an organic or inorganic anion containing an imidazolium group as shown in the following formulas (1) and (2).
- chloride (Cl -) anion or bromide (Br -) of imidazolium based ionic When using a liquid as an additive, when the silver salt is converted to the metal by the polyol reduction reaction of silver ion or silver metal and chemical interaction It is possible to grow the silver metal uniformly in one dimension, thereby achieving a better effect of uniformly forming silver nanowires with a high aspect ratio of less than 100 nanometers in length and more than 10 microns in length. Indicates.
- the aspect ratio of the silver nanowire is at least 100, but the upper limit thereof is not determined as a specific ratio, but may be applied to the maximum aspect ratio that can be present as the silver nanowire by adjusting the content of the ionic liquid. If the aspect ratio of the silver nanowire is too large, it may be difficult to exist in the form of wire and may be entangled like a thread. If necessary, the content of the ionic liquid may be adjusted to produce a silver nanowire with a large aspect ratio and uniformity. have.
- R 1 , R 2 and R 3 are the same or different and represent hydrogen or a hydrocarbon group of 1 to 16 carbon atoms, respectively, selected from oxygen, sulfur, nitrogen, phosphorus, fluorine, chlorine, bromine, iodine and silicon It may optionally include one or more hetero atoms.
- X ⁇ is a halogen anion containing Cl ⁇ or Br ⁇ as the anion of the ionic liquid.
- n represents a repeating unit and is a natural number.
- ionic liquid cation in the monomer form represented by Formula 1 include 1,3-dimethylimidazolium, 1,3-diethylimidazolium, 1-ethyl-3-methylimidazolium (EMIM), 1-butyl-3-methylimidazolium (BMIM), 1-hexyl-3-methylimidazolium (HMIM), 1-octyl-3-methylimidazolium (OMIM), 1-decyl-3-methyl Midazolium, 1-dodecyl-3-methylimidazolium, 1-tetradecyl-3-methylimidazolium, and the like
- specific examples of the ionic liquid cation of the polymer form represented by Chemical Formula 2 include poly (1 -Vinyl-3-alkylimidazolium), poly (1-allyl-3-alkylimidazolium), poly (1- (meth) acryloyloxy-3-alkylimidazolium) and the like.
- Specific manufacturing method of the silver nanowire of the present invention is as follows.
- the silver salt precursor, the reducing solvent, the capping agent, and the ionic liquid are mixed at an appropriate ratio, and then stirred at room temperature for a certain time.
- Silver nanowires are then prepared by reacting the mixture for 30 minutes-7 days at a temperature of 50-180 degrees Celsius. When the reaction temperature is low, the reaction time is long because the silver nanowires take a long time to grow, whereas when the reaction temperature is high, the silver nanowires are formed in a relatively fast time.
- the content ratio of each mixed component is important, and it is preferable to maintain the capping agent at 1 to 2 mol and the imidazolium-based ionic liquid at a ratio of 0.001 to 0.2 mol based on 1 mol of the silver salt precursor. Do.
- the content of the capping agent is 1 mol and the content of the ionic liquid is too low, less than 0.001 mol, there is a problem that the nanowires are not uniformly formed and are manufactured in a mixture of nanowires and nanoparticles, and the capping agent content is 2 If the molar and ionic liquid content is too high, exceeding 0.2 mole, the diameter of the nanowire becomes larger than 100 nanometers or three-dimensional silver particles are formed, making it difficult to produce uniform silver nanowires. do.
- the content of the ionic liquid is advantageous for the production of more uniform silver nanowires using 0.005 to 0.02 mol.
- the silver nanowires prepared by the above-described technique are obtained by filtration using a filtration apparatus after the preparation, followed by washing with a solvent such as water or alcohol.
- the silver nanowire filtrate obtained as described above may be prepared as a silver nanowire dispersion by dispersing it in a solvent, and water and an aqueous solvent are preferably used as the dispersion solvent of the silver nanowires used.
- the aqueous solvent include alcohol solvents such as water, methanol, ethanol, n-propyl alcohol, isopropyl alcohol, normal butanol, isobutanol, hexanol, benzyl alcohol, diacetone alcohol, ethylene glycol, propylene glycol, glycerol, and the like.
- THF tetrahydrofuran
- a silver nanowire dispersion is prepared by dispersing 0.1-5% by weight of silver nanowires of the present invention in 95-99.9% by weight of the solvent, and the dispersion further contains a dispersant and a thickener to improve the dispersibility of silver nanowires. It may include.
- the content of silver nanowires is less than 0.1 wt%, the silver nanowires are too small to have high surface resistance or high wet coating thickness, which is disadvantageous due to problems such as poor coating properties.
- the content of the nanowires is so high that it is difficult to coat thinly or rather disadvantageous due to problems such as poor light transmittance by using more than necessary silver nanowires.
- the dispersant is adsorbed on the surface of the silver nanowires so that the silver nanowires can be stably dispersed in the solvent by electrostatic repulsion or steric hindrance, and the thickener plays a role in controlling the rheology of the silver nanowire dispersion.
- the content of the dispersant and the thickener is effective to mix 0.01 to 10 parts by weight with respect to 100 parts by weight of the silver nanowire dispersion. If the content of the dispersion is less than 0.01 parts by weight, there is almost no dispersing effect, and if it is 10 parts by weight or more, the dispersant is too large, which causes the dispersant to come out to the surface and lower the surface resistance or the surface becomes too slippery. The problem is rather disadvantageous.
- dispersant examples include polyoxyethylene fatty ether, polyoxyethylene phenyl ether, polyimine, alkyl phosphate, alkyl ammonium salt, alkylol ammonium salt of polyester, alkylol ammonium salt of polyacrylate, polydimethylsilane, polyacrylic acid, polysulfonic acid, polyvinyl At least one selected from pyrrolidone, more specifically Triton X-100, Triton X-200, Pluronic P123, F127, F68, L64, BYK-181, 184, 191, 192, 194, Disperbyk- 181, 184, 190, Tego 710, 720W, 730W, Zonyl FSN, FSO, FSP, cetyltrimethylammonium bromide (CTAB), cetyltrimethylammonium chloride (CTAC), tetrabutylammonium bromide (TBAB), tetrabutylammonium chloride (TBAC t
- the thickener is not limited and, for example, a combination of one or more of a urethane-associated thickener, an acrylic thickener, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, and the like. It is possible to use.
- silver nanowires prepared using the technology of the present invention and silver nanowire dispersions prepared using the same are applied to a base film and dried, silver nanowires having a diameter of 100 nanometers or less and a length of 10 microns or more are formed on the base film surface. It is possible to manufacture a transparent electrode film formed in a three-dimensional network.
- the base film is not limited as a commonly used transparent film, and includes, for example, polyethylene terephthalate, polyester naphthalate, polycarbonate, polymethyl methacrylate, polyacrylate, polyacrylonitrile, polystyrene, and the like. .
- an adhesion enhancing layer on the surface of the base film, or by using a surface treatment such as corona treatment, plasma treatment on the surface of the base film or silver through a primer treatment The adhesion between the nanowires and the base film can be enhanced.
- a coating method for applying the silver nanowires to the base film all known techniques may be used. Generally, dip coating, spin coating, bar coating, gravure, reverse gravure, offset printing, inkjet printing, spray coating, and slot die Coating and the like can be used, the coating method is not particularly limited.
- the silver nanowire transparent electrode film has a surface resistance of 10 1 -10 3 ⁇ / ⁇ , and has a light transmittance of 90% or more relative to the light transmittance of the base film.
- silver nanowires less than 100 nanometers in diameter and at least 10 microns in length can be produced uniformly in solution.
- the silver nanowire of the present invention has an aspect ratio of 100 or more, when the three-dimensional network is formed on the surface of the base film by using the same, there is an effect of simultaneously realizing low surface resistance and high light transmittance.
- Example 3 is a scanning electron microscope photograph of silver nanowires according to Example 1 of the present invention.
- Example 4 is a scanning electron microscope photograph of silver nanowires according to Example 2 of the present invention.
- Example 5 is a scanning electron microscope photograph of silver nanowires according to Example 3 of the present invention.
- FIG. 6 is a scanning electron microscope photograph of silver nanowires and nanoparticles according to Comparative Example 2.
- silver nanowires of about 90-120 nanometers in diameter and 5-20 microns in length were formed, but the diameters of the silver nanowires were observed to be somewhat large and not uniform.
- silver nanoparticles having a size of about 0.5 to 5 microns are simultaneously formed.
- Example 2 is identical to Example 1 except that 0.001 mole of 1-butyl-3-methylimidazolium chloride (BMIM-Cl) was used as the ionic liquid additive. As shown in the photograph of FIG. 4, it was observed that silver nanowires having a diameter of 55-65 nanometers were formed uniformly. In addition, as in the result of Example 1, silver nanoparticles of other shapes than silver nanowires were not found. Comparing the results of Examples 1 and 2, it was observed that there was no or very small change of the silver nanowire shape with the length of the alkyl group in imidazolium, which is a cation of ionic liquid.
- BMIM-Cl 1-butyl-3-methylimidazolium chloride
- Example 3 is the same as Example 2 except that 0.001 mol of 1-butyl-3-methylimidazolium bromide (BMIM-Br) was used as the ionic liquid. As shown in the photograph of FIG. 5, it was observed that silver nanowires having a diameter of about 30 nanometers were formed uniformly. Comparing the results of Examples 2 and 3, it can be seen that the shape and diameter of the silver nanowires change depending on the anion of the ionic liquid.
- BMIM-Br 1-butyl-3-methylimidazolium bromide
- Comparative Example 2 is the same as Example 2 except that 1-butyl-3-methylimidazolium methylsulfate (BMIM-MeSO 4 ) was used as the ionic liquid.
- BMIM-MeSO 4 1-butyl-3-methylimidazolium methylsulfate
- Examples 2 and 3 when the anion of the ionic liquid is Cl ⁇ or Br ⁇ , silver nanowires are formed, whereas in the case of Comparative Example 2, when the anion of the ionic liquid is CH 3 SO 4 ⁇ , As shown in the photo, it can be seen that one-dimensional silver nanowires are not formed, but three-dimensional silver nanoparticles are formed.
- Silver nanowires prepared in Example 2 0.7 parts by weight, 98.8 parts by weight of isopropyl alcohol, 0.5 parts by weight of cellulose-based thickeners were mixed, and then a silver nanowire dispersion was prepared through ultrasonic dispersion.
- a silver nanowire transparent conductive film was prepared by applying the silver nanowire dispersion liquid using a bar coater to a polyethylene terephthalate film (thickness: 125 microns) to which an acrylic adhesion promoting layer was applied, and then drying at a temperature of about 100 degrees for 1 minute. It was.
- the surface resistance of the silver nanowire transparent conductive film was measured using a four-terminal method (AIT Co., Ltd.).
- the light transmittance of the film was measured using a UV-Vis-NIR spectrophotometer (Cary 5000), the light transmittance compared to the light transmittance of the base film was measured as 94.7%.
- the silver nanowire according to the present invention is used as a core material of touch screen panels, which are the core components of various types of electric, electronic and communication devices, including display devices such as smartphones, tablet computers, and televisions. It is possible.
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Description
Claims (15)
- 은염 전구체, 환원용매, 및 캡핑제를 포함한 혼합용액을 폴리올 환원 반응시켜 은 나노와이어를 제조하는 방법에 있어서,상기 혼합용액에 첨가제로서 이온성 액체를 더 첨가하여 폴리올 환원 반응시키는 것을 특징으로 하는 은 나노와이어 제조 방법.
- 제 1항에 있어, 상기 이온성 액체는 이미다졸륨 그룹을 포함하는 유기 양이온 및 유기 또는 무기 음이온으로 구성된 화합물로서 하기 화학식 1로 나타낸 단량체 형태 또는 하기 화학식 2로 나타낸 고분자 형태임을 특징으로 하는 은 나노와이어 제조방법.[화학식 1][화학식 2]상기 화학식에서, R1, R2 및 R3는 동일하거나 상이하고, 각각 수소 또는 탄소수 1 내지 16의 탄화수소기를 나타낸 것으로, 산소, 황, 질소, 인, 불소, 염소, 브롬, 요오드, 실리콘에서 선택되는 헤테로 원자를 하나 이상 선택적으로 포함할 수 있다. 또한 X-는 음이온을 나타내는 것으로서 클로라이드(Cl-) 또는 브로마이드(Br-)의 할로겐 이온을 포함한 유기 또는 무기 화합물임을 나타낸다. n은 반복 단위체를 나타내며 자연수 이다.
- 제 2항에 있어서, 상기 이온성 액체에 있어서,상기 단량체 형태의 이온성 액체 양이온으로는 1,3-다이메틸이미다졸륨, 1,3-다이에틸이미다졸륨, 1-에틸-3-메틸이미다졸륨, 1-부틸-3-메틸이미다졸륨, 1-헥실-3-메틸이미다졸륨, 1-옥틸-3-메틸이미다졸륨, 1-데실-3-메틸이미다졸륨, 1-도데실-3-메틸이미다졸륨, 1-테트라데실-3-메틸이미다졸륨이 사용되고, 그리고상기 고분자 형태의 이온성 액체 양이온으로는 폴리(1-비닐-3-알킬이미다졸륨), 폴리(1-알릴-3-알킬이미다졸륨), 또는 폴리(1-(메트)아크릴로일록시-3-알킬이미다졸륨)이 사용되는 것을 특징으로 하는 은 나노와이어 제조방법.
- 제 3항에 있어서, 은염 전구체, 캡핑제, 및 이온성 액체의 혼합비율은 은염 전구체 1몰 기준으로 캡핑제 1 내지 2 몰 및 이온성 액체 0.001 내지 0.2 몰 비율임을 특징으로 하는 은 나노와이어 제조방법.
- 제 4항에 있어서, 은 나노와이어 합성을 위한 반응 온도가 섭씨 50-180도임을 특징으로 하는 은 나노와이어 제조방법.
- 제 1항 내지 제 5항 중 어느 한 항에 있어서, 상기 은염 전구체는 은 양이온 및 유기 또는 무기 음이온으로 이루어진 것으로서, AgNO3, AgClO4, AgBF4, AgPF6, CH3COOAg, AgCF3SO3, Ag2SO4, CH3COCH=COCH3Ag에서 선택된 1종 또는 2종 이상을 포함하는 것을 특징으로 하는 은 나노와이어 제조 방법.
- 제 1항 내지 제 6항 중 어느 한 항에 있어서, 상기 환원용매는 분자 내에 히드록시기를 적어도 2개 이상 가지는 다이올, 폴리올 또는 글리콜을 포함하는 용매인 것을 특징으로 하는 은 나노와이어 제조 방법.
- 제 1항 내지 제 7항 중 어느 한 항에 있어서, 상기 캡핑제는 폴리비닐피롤리돈 (polyvinylpyrollidone: PVP) 또는 폴리비닐알콜(polyvinylalcohol, PVA)인 것을 특징으로 하는 은 나노와이어 제조 방법.
- 제 1항 내지 제 8항 중 어느 하나의 방법을 통해 제조되며 종횡비가 100 이상임을 특징으로 하는 은 나노와이어.
- 제 9항의 은 나노와이어 0.1-5 중량%를 용매 95-99.9 중량%로 분산시킨 은 나노와이어 분산액.
- 제 10항에 있어서, 상기 분산용매로는 물, 메탄올, 에탄올, n-프로필알코올, 이소프로필알코올, 노르말부탄올, 이소부탄올, 헥산올, 벤질 알콜, 디아세톤 알콜을 포함하는 알콜계 용매, 에틸렌글리콜, 프로필렌글리콜, 글리세롤을 포함하는 폴리올계 용매, 1,4-디옥산, 테트라하이드로푸란(THF), 에틸렌글리콜 모노메틸에테르, 에틸렌글리콜 모노에틸에테르, 에틸렌글리콜 디메틸에테르, 프로필렌글리콜 모노메틸에테르, 프로필렌글리콜 모노에틸에테르, 프로필렌그리콜디메틸에테르를 포함하는 에테르계 용매, N,N-디메틸포름아미드, N-메틸포름아미드, N,N-디메틸아세트아미드 (DMA)를 포함하는 아미드계 용매, 아세토니트릴을 포함하는 니트릴계 용매, 아세트알데히드를 포함하는 알데히드계 용매, N-메틸-2-피롤리돈, 2-피롤리돈, N-비닐-2-피롤리돈, 디메틸설폭사이드, n-부티로락톤, 니트로메탄, 에틸락테이트를 포함하며, 이를 1종 또는 2종 이상을 조합하여 사용하는 것을 특징으로 하는 은 나노와이어 분산액.
- 제 11항에 있어서, 상기 은 나노와이어 분산액 100 중량부에 대하여 분산제 및 증점제를 각각 0.01 내지 10 중량부를 더 포함하는 것을 특징으로 하는 은 나노와이어 분산액.
- 제 12항에 있어서,상기 분산제는 폴리옥시에틸렌지방에테르, 폴리옥시에틸렌페닐에테르, 폴리이민, 알킬포스페이트, 알킬암모늄염, 폴리에스터산알킬올암모늄염, 폴리아크릴산알킬올암모늄염, 폴리디메틸실란, 폴리아크릴산, 폴리술폰산, 폴리비닐피롤리돈으로부터 선택되는 1종 이상을 포함하며, 그리고상기 증점제는 우레탄회합형 증점제, 아크릴계 증점제, 메틸셀룰로오즈, 에틸셀룰로오즈, 히드록시에틸셀룰로오즈, 히드록시메틸셀룰로오즈, 히드록시프로필셀룰로오즈, 히드록시프로필메틸셀룰로오즈로부터 선택되는 1종 이상 포함하는 것,을 특징으로 하는 은 나노와이어 분산액.
- 제 1항 내지 8항의 방법을 통해 제조된 은 나노와이어를 포함하는 은 나노와이어 분산액이 기저 필름 표면에 도포된 은 나노와이어 투명전도성 필름.
- 제 14항에 있어서, 상기 은 나노와이어 투명전도성 필름은 101-103Ω/□범위의 표면저항(surface resistivity)과 기저 필름 대비 90% 이상의 광투과도(light transmittance)를 나타내는 것을 특징으로 하는 은 나노와이어 투명전도성 필름.
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US14/652,084 US20150321257A1 (en) | 2012-12-14 | 2012-12-14 | Method for manufacturing silver nanowires using ionic liquid |
CN201280077717.5A CN104870361A (zh) | 2012-12-14 | 2012-12-14 | 使用离子液体制备银纳米线的方法 |
JP2015547825A JP2016507640A (ja) | 2012-12-14 | 2012-12-14 | イオン性液体を用いた銀ナノワイヤの製造方法 |
TW102100441A TW201422536A (zh) | 2012-12-14 | 2013-01-07 | 用以使用離子液體產生銀奈米線的方法 |
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JP2016507640A (ja) | 2016-03-10 |
US20150321257A1 (en) | 2015-11-12 |
CN104870361A (zh) | 2015-08-26 |
TW201422536A (zh) | 2014-06-16 |
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