WO2014030398A1 - 鋳型砂の再生装置 - Google Patents
鋳型砂の再生装置 Download PDFInfo
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- WO2014030398A1 WO2014030398A1 PCT/JP2013/063021 JP2013063021W WO2014030398A1 WO 2014030398 A1 WO2014030398 A1 WO 2014030398A1 JP 2013063021 W JP2013063021 W JP 2013063021W WO 2014030398 A1 WO2014030398 A1 WO 2014030398A1
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- WIPO (PCT)
- Prior art keywords
- sand
- valley
- shaped
- mountain
- shaped cover
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/10—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by dust separating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
- B02C23/10—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/20—Adding fluid, other than for crushing or disintegrating by fluid energy after crushing or disintegrating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B4/00—Separating by pneumatic tables or by pneumatic jigs
- B03B4/06—Separating by pneumatic tables or by pneumatic jigs using fixed and inclined tables ; using stationary pneumatic tables, e.g. fluidised beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B4/00—Separating solids from solids by subjecting their mixture to gas currents
- B07B4/08—Separating solids from solids by subjecting their mixture to gas currents while the mixtures are supported by sieves, screens, or like mechanical elements
Definitions
- the present invention relates to an apparatus for reclaiming mold sand by peeling the binder on the surface layer of used mold sand (for example, self-hardening mold sand).
- a molding sand recycling apparatus for the purpose of removing dust generated when the molding sand is regenerated, air is blown into the molding sand containing dust to form a fluidized bed, and to a dust hood for performing classification. It is publicly known to classify using the difference between the soaking speed and the sedimentation speed (see, for example, Japanese Patent No. 3329757).
- a slit 101 for ejecting air upward is provided on the slit plate 100, and sand particles accumulated around the air drop when blowing is stopped.
- a structure has been used that stops at the backup plate 102 provided at the lower portion of the slit 101, and then blows out from the slit 101 together with air when the air flow is resumed thereafter.
- the structure of the fluidized bed described above has a problem that periodic cleaning is necessary because sand particles entering the slit 101 are entangled to cause bridges and clogging 103.
- the present invention has been made in view of the above problems, and an object of the present invention is to provide a molding sand recycling apparatus having a fluidized bed that can prevent clogging of slits.
- the molding sand regeneration apparatus of the present invention comprises a regeneration treatment tank for reclaiming the molding sand by peeling the binder on the surface layer of the molding sand, and an upper part on the upstream side of the regeneration treatment tank.
- a fluidized tank that communicates with the lower part of the fluidized tank and conveys the regenerated sand and fine powder falling from the regeneration treatment tank, and a lower part that communicates with the upper part on the downstream side of the fluidized tank to collect the fine powder in the fluidized tank.
- a fluidized bed in the fluidized tank wherein the fluidized bed includes a plurality of mountain-shaped cover members and a plurality of valley-shaped floor members, and the mountain-shaped cover members are disposed above the valleys.
- the floor-shaped floor members are arranged alternately in the horizontal direction so that the gap between the end of the mountain-shaped cover member and the end of the valley-shaped floor member is an inclined slit for supplying air. It is characterized by being.
- the mountain-shaped cover member and the valley-shaped floor member are arranged so that the mountain-shaped cover member is above the cross section of the fluidized tank perpendicular to the conveying direction of the recycled sand and fine powder.
- the valley-shaped floor members are alternately arranged in the horizontal direction so as to be on the bottom.
- the mountain-shaped cover member and the valley-shaped floor member are arranged so that the mountain-shaped cover member is above the valley-shaped in the conveying direction of the recycled sand and fine powder in the fluidized tank.
- the floor members are alternately arranged in the horizontal direction so as to be on the bottom.
- the molding sand recycling apparatus of the present invention is characterized in that a rectifying member is disposed in a valley space of the valley-shaped floor member.
- the molding sand recycling apparatus of the present invention is characterized in that the rectifying member is a round bar.
- the molding sand recycling apparatus of the present invention has a regeneration treatment tank for reclaiming the molding sand by peeling the binder at the surface layer portion of the molding sand, and an upper part on the upstream side is connected to the lower part of the regeneration treatment tank.
- Mold sand comprising: a regenerating sand falling from a regenerating treatment tank and a fluid tank for conveying fine powder; and a dust hood in which a lower part is connected to the upper part on the downstream side of the fluid tank and collects the fine powder in the fluid tank.
- the fluidized bed in the fluidized tank includes a plurality of mountain-shaped cover members and a plurality of valley-shaped floor members, and the mountain-shaped cover members are on the top and the valley-shaped floor members are on the bottom.
- the gaps between the end portions of the mountain-shaped cover members and the end portions of the valley-shaped floor members are inclined slits for supplying air. There are various effects such as prevention of clogging.
- FIG. 2 is an AA arrow view in FIG. 1. It is the elements on larger scale of the fluidized bed in FIG. It is the elements on larger scale of the fluidized bed in FIG. 2, Comprising: It is a figure for demonstrating the air flow from the opposing slit at the time of arrange
- FIG. 1 the code
- a gate 2 is disposed at the lower end of the recovered sand hopper 1, and the gate 2 is opened and closed by an open / close cylinder 11 (see FIG. 2).
- a regeneration treatment tank 3 is connected to the lower part of the recovered sand hopper 1, and in the regeneration treatment tank 3, the charged self-hardening mold sand rubs against each other, so that the surface layer portion of the self-hardening mold sand is rubbed.
- the binder is peeled off to regenerate the self-hardening mold sand.
- “connected” includes a case where another member or the like is sandwiched between two connected members.
- An upper part on the upstream side of the fluid tank 4 is connected to the lower part of the regeneration tank 3, and the sand that falls from the regeneration tank 3 (regenerated self-hardening mold sand) is connected to the fluid tank 4. And fine powder is conveyed.
- a lower part of the dust hood 5 is connected to the upper part on the downstream side of the fluid tank 4, and the upper end of the dust hood 5 is connected to a dust collector (not shown). When the dust collector is operated, the fine powder in the fluid tank 4 is collected by the dust hood 5.
- upstream and “downstream” refer to “upstream” and “downstream” in the moving direction of the self-hardening mold sand to be processed, reclaimed sand, peeled fine powder, or the like.
- a fluidized bed 6 is disposed in the lower part of the fluidized tank 4.
- An air chamber 7 is provided below the fluidized bed 6, and a fluidized portion 8 is formed on the fluidized bed 6.
- a sand discharge port 9 for discharging the recycled sand is provided at the downstream end of the fluidized bed 6.
- a duct 10 is connected to the lower portion of the air chamber 7, and the duct 10 is connected to a blower 12 (see FIG. 2).
- the fluidized bed 6 includes a plurality of chevron-shaped cover members 13 and a plurality of valley-shaped floor members 14 formed of equilateral chevron steel, and the chevron-shaped cover members 13 are arranged on the upper side.
- the floor-shaped floor members 14 are alternately arranged in the horizontal direction so as to be on the bottom.
- the “mountain cover member 13” is a member in which the corners of the angle iron are located in the upper part and both sides extend obliquely downward.
- the “valley-shaped floor member 14” is a member in which the corners of the angle steel are located in the lower part and both sides extend obliquely upward.
- “so that the mountain-shaped cover member 13 is on the top and the valley-shaped floor member 14 is on the bottom” means that the side of the “mountain-shaped cover member 13” is located above the side of the “floor member 14”. To do.
- the tip side portion (referred to as “end portion”) 13a of the side of the chevron-shaped cover member 13 and the end portion 14a of the valley-shaped floor member 14 are wrapped (overlapped) with a gap secured in the vertical direction.
- the secured vertical gap is an inclined slit 15 for supplying air to the fluidized portion 8.
- a round bar 16 made of iron or the like as a rectifying member for rectifying the air injected from the slit 15 secures a gap with the inner surface of the floor member 14. It is arranged.
- the mountain-shaped cover member 13 and the valley-shaped floor member 14 are cross sections orthogonal to the transport direction of the recycled sand and fine powder (the direction of the arrow Y1 in FIG. 1) in the fluidized tank 4. 2), the mountain-shaped cover members 13 are alternately arranged in the horizontal direction so that the valley-shaped floor members 14 are on the bottom.
- the mountain-shaped cover member 13 and the valley-shaped floor member 14 are disposed almost entirely in the longitudinal direction, and gradually become lower toward the downstream end. It is inclined and arranged.
- the round bar 16 is not shown in FIG. 1, the longitudinal bar 16 is disposed almost entirely in the longitudinal direction, similarly to the mountain-shaped cover member 13 and the valley-shaped floor member 14. It is disposed so as to be gradually lowered toward the front end.
- the gate 2 is opened for a predetermined time by the open / close cylinder 11, whereby a predetermined amount of used self-hardening mold sand stored in the recovered sand hopper 1 is put into the regeneration treatment tank 3.
- the self-hardening mold sand is polished by rubbing the charged self-hardening mold sand. Thereby, the binder of the surface layer part of this self-hardening mold sand is peeled, and this self-hardening mold sand is regenerated.
- the fine powder generated by polishing the self-hardening mold sand, that is, the peeled binder, and the regenerated self-hardening mold sand, that is, the regenerated sand fall from the reprocessing tank 3, and the fluidized tank. 4 into the fluidized part 8.
- air is continuously supplied to the air chamber 7 through the duct 10 by the operation of the blower 12.
- the air in the air chamber 7 is continuously blown out to the flow part 8 through the slit 15.
- the fine powder and the regenerated sand in the fluidized part 8 are floated by the upward airflow generated by the air from the slits 15 toward the downstream side of the fluidized bed 6 disposed in an inclined manner (see FIG. 1) (in the direction of arrow Y1 in FIG. 1).
- "conveyance" includes the case where fine powder and recycled sand move toward the lower side of the slope while floating.
- the fluidized bed 6 in the fluidized tank 4 includes a plurality of mountain-shaped cover members 13 and a plurality of valley-shaped floor members 14, and the mountain-shaped cover member 13 is above and the valley-shaped floor member 14 is The gaps between the end portions 13a of the mountain-shaped cover members 13 and the end portions 14a of the valley-shaped floor members 14 are alternately arranged in the horizontal direction so as to be in the inclined slits 15 for supplying air. Has been.
- a plurality of slanted slits 15 for supplying air to the flow part 8 can be formed, and the opening on the flow part 8 side of the slit 15 is directed downward from the horizontal. For this reason, even if the blower 12 is stopped while the fine powder and the regenerated sand are floating in the fluidized portion 8, the fine powder and the regenerated sand fall to the fluidized portion 8 side, that is, the valley portion of the floor member 14. Therefore, there is an advantage that it is possible to prevent the slit 15 from being clogged due to fine powder or recycled sand entering the slit 15. As a result, after stopping the regeneration process in the regeneration treatment tank 3, the blower 12 is stopped without waiting for the fine powder in the fluidizing section 8 to be collected and the regenerated sand to be completely discharged. This also has the advantage of saving power.
- the rectifying member (the round bar 16 in the present embodiment) is disposed in the valley space of the valley-shaped floor member 14, but the present invention is not limited to this, and the rectifying member is omitted. May be. However, it is more preferable to arrange this rectifying member, and this point will be described in detail.
- the air blown out from the facing slit 15 may collide to cause turbulent flow.
- the flow straightening member is disposed in the valley space of the valley shaped floor member 14
- the air blown from the facing slit 15 collides with the flow straightening member and changes its direction, so that the blown out air does not collide with each other. become.
- the turbulent flow can be reduced and the airflow can be adjusted, and this has the advantage that the fine powder removing effect is improved.
- the rectifying member is disposed in the valley space of the valley-shaped floor member 14 in a state where a gap with the inner surface of the floor member 14 is ensured, but the present invention is not limited to this.
- the rectifying member and the inner surface of the floor member 14 may be brought into contact with each other.
- the round bar 16 is used as the rectifying member, but the rectifying member is not limited to this, and other examples of the rectifying member include a square bar, a hexagonal bar, and a pentagonal bar. . However, it is more preferable to use a round bar 16 as the rectifying member, which will be described in detail.
- the mountain-shaped cover member 13 and the valley-shaped floor member 14 are orthogonal to the direction in which the regenerated sand and fine powder are conveyed in the fluidized tank 4 (the direction of the arrow Y1 in FIG. 1).
- the mountain-shaped cover members 13 are alternately arranged in the horizontal direction so that the valley-shaped floor members 14 are on the bottom.
- the present invention is not limited to this, and the mountain-shaped cover member 13 and the valley-shaped floor member 14 are in the conveying direction of the regenerated sand and fine powder in the fluidized tank 4 (the direction of the arrow Y1 in FIG. 1). That is, in the cross section of FIG. 1, the mountain-shaped cover members 13 may be alternately arranged in the horizontal direction so that the valley-shaped floor members 14 are on the bottom.
- fine powder and reclaimed sand will travel over the mountain-shaped portions of the cover member 13 in order, and it takes time for the reclaimed sand to be completely discharged. Since the number of times of collision with the chevron increases, the effect that the fine powder adhering to the sand particles is knocked down is also increased. For this reason, fine powder and recycled sand can be more reliably separated (classified).
- the mountain-shaped cover member 13 and the valley-shaped floor member 14 are made of equilateral angle steel, and the mountain angle A1 and the valley angle A2 (see FIG. 5) are set to 90 degrees. Yes.
- the present invention is not limited to this, and the mountain-shaped cover member 13 and the valley-shaped floor member 14 may be manufactured by bending an iron plate, and the mountain angle A1 and the valley angle A2 are also limited to 90 degrees. Is not to be done.
- an example of regenerating the self-hardening mold sand used in the alkali phenol self-hardening process is shown, but the present invention is not limited to this.
- the present invention can be applied not only to organic self-hardening processes but also to regeneration of self-hardening mold sand used in inorganic self-hardening processes.
- organic self-hardening processes such as the alkali phenol mentioned above, furan, phenol urethane, are mentioned, for example.
- an inorganic self-hardening process using water glass can be mentioned.
- the present invention is not limited to the regeneration of self-hardening mold sand, but also for the regeneration of mold sand such as green sand, mold sand using an organic binder, and mold sand using an inorganic binder. Can be applied.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Combined Means For Separation Of Solids (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Casting Devices For Molds (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Abstract
Description
また、本発明は以下の詳細な説明により更に完全に理解できるであろう。しかしながら、詳細な説明および特定の実施例は、本発明の望ましい実施の形態であり、説明の目的のためにのみ記載されているものである。この詳細な説明から、種々の変更、改変が、当業者にとって明らかだからである。
出願人は、記載された実施の形態のいずれをも公衆に献上する意図はなく、開示された改変、代替案のうち、特許請求の範囲内に文言上含まれないかもしれないものも、均等論下での発明の一部とする。
本明細書あるいは請求の範囲の記載において、名詞及び同様な指示語の使用は、特に指示されない限り、または文脈によって明瞭に否定されない限り、単数および複数の両方を含むものと解釈すべきである。本明細書中で提供されたいずれの例示または例示的な用語(例えば、「等」)の使用も、単に本発明を説明し易くするという意図であるに過ぎず、特に請求の範囲に記載しない限り本発明の範囲に制限を加えるものではない。
1 回収砂ホッパ
3 再生処理槽
4 流動槽
5 ダストフッド
6 流動床
13 山形のカバー部材
13a 山形のカバー部材の端部
14 谷形のフロア部材
14a 谷形のフロア部材の端部
15 スリット
16 整流部材
Y1 流動槽における再生砂及び微粉の搬送方向
Claims (5)
- 鋳型砂の表層部の粘結剤を剥離させて該鋳型砂を再生する再生処理槽と、上流側上部が該再生処理槽の下部に連通連結され、該再生処理槽から落下する再生砂及び微粉を搬送する流動槽と、下部が該流動槽の下流側上部に連通連結され、該流動槽内の前記微粉を集塵するダストフッドと、を具備する鋳型砂の再生装置であって、
前記流動槽における流動床が、複数の山形のカバー部材と複数の谷形のフロア部材を備え、該山形のカバー部材が上で該谷形のフロア部材が下になるように水平方向に交互に配置され、該山形のカバー部材の端部と該谷形のフロア部材の端部の隙間がエアーを供給するための傾斜状のスリットにされていることを特徴とする鋳型砂の再生装置。 - 前記山形のカバー部材と前記谷形のフロア部材が、前記流動槽における前記再生砂及び微粉の搬送方向と直交する断面において、前記山形のカバー部材が上で前記谷形のフロア部材が下になるように水平方向に交互に配置されることを特徴とする、
請求項1記載の鋳型砂の再生装置。 - 前記山形のカバー部材と前記谷形のフロア部材が、前記流動槽における前記再生砂及び微粉の搬送方向において、前記山形のカバー部材が上で前記谷形のフロア部材が下になるように水平方向に交互に配置されることを特徴とする
請求項1記載の鋳型砂の再生装置。 - 前記谷形のフロア部材の谷部空間に整流部材を配設したことを特徴とする
請求項1~3のいずれかに記載の鋳型砂の再生装置。 - 前記整流部材が丸棒であることを特徴とする
請求項4記載の鋳型砂の再生装置。
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13831775.5A EP2851143B1 (en) | 2012-08-23 | 2013-05-09 | Molding sand regeneration device |
JP2014531521A JP6213471B2 (ja) | 2012-08-23 | 2013-05-09 | 鋳型砂の再生装置 |
BR112014030963-9A BR112014030963B1 (pt) | 2012-08-23 | 2013-05-09 | Aparelho para a recuperação de areia para fundição |
KR1020147034457A KR102000247B1 (ko) | 2012-08-23 | 2013-05-09 | 주형사의 재생장치 |
ES13831775.5T ES2624410T3 (es) | 2012-08-23 | 2013-05-09 | Dispositivo de regeneración de arena de moldeo |
MX2014015151A MX361638B (es) | 2012-08-23 | 2013-05-09 | Un aparato para recuperar arena de fundicion. |
CN201380030840.6A CN104379275B (zh) | 2012-08-23 | 2013-05-09 | 型砂的再生装置 |
RU2014150349A RU2618977C2 (ru) | 2012-08-23 | 2013-05-09 | Устройство для регенерации формовочной смеси |
US14/407,306 US10052681B2 (en) | 2012-08-23 | 2013-05-09 | Apparatus for reclaiming foundry sand |
Applications Claiming Priority (2)
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JP2012183748 | 2012-08-23 | ||
JP2012-183748 | 2012-08-23 |
Publications (1)
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WO2014030398A1 true WO2014030398A1 (ja) | 2014-02-27 |
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PCT/JP2013/063021 WO2014030398A1 (ja) | 2012-08-23 | 2013-05-09 | 鋳型砂の再生装置 |
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US (1) | US10052681B2 (ja) |
EP (1) | EP2851143B1 (ja) |
JP (1) | JP6213471B2 (ja) |
KR (1) | KR102000247B1 (ja) |
CN (1) | CN104379275B (ja) |
BR (1) | BR112014030963B1 (ja) |
ES (1) | ES2624410T3 (ja) |
MX (1) | MX361638B (ja) |
RU (1) | RU2618977C2 (ja) |
WO (1) | WO2014030398A1 (ja) |
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GB0807214D0 (en) | 2008-04-21 | 2008-05-28 | Belfast Health And Social Care | Biomarkers |
GB201210587D0 (en) * | 2012-06-14 | 2012-08-01 | Belfast Health And Social Care Trust | Predictive biomarker |
GB201210571D0 (en) | 2012-06-14 | 2012-08-01 | Belfast Health And Social Care Trust | Predictive biomarker |
KR20180018569A (ko) * | 2015-06-11 | 2018-02-21 | 신토고교 가부시키가이샤 | 주형사의 재생 방법 및 재생 설비 |
US11566236B2 (en) | 2018-02-05 | 2023-01-31 | Vertex Pharmaceuticals Incorporated | Materials and methods for treatment of hemoglobinopathies |
CN113815231B (zh) * | 2021-08-25 | 2023-11-03 | 共享智能装备有限公司 | 一种增材制造设备用清粉装置 |
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JP5297731B2 (ja) * | 2007-09-12 | 2013-09-25 | 花王株式会社 | 再生鋳物砂の製造方法 |
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2013
- 2013-05-09 RU RU2014150349A patent/RU2618977C2/ru active
- 2013-05-09 KR KR1020147034457A patent/KR102000247B1/ko active IP Right Grant
- 2013-05-09 MX MX2014015151A patent/MX361638B/es active IP Right Grant
- 2013-05-09 WO PCT/JP2013/063021 patent/WO2014030398A1/ja active Application Filing
- 2013-05-09 BR BR112014030963-9A patent/BR112014030963B1/pt active IP Right Grant
- 2013-05-09 US US14/407,306 patent/US10052681B2/en active Active
- 2013-05-09 ES ES13831775.5T patent/ES2624410T3/es active Active
- 2013-05-09 JP JP2014531521A patent/JP6213471B2/ja active Active
- 2013-05-09 CN CN201380030840.6A patent/CN104379275B/zh active Active
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Also Published As
Publication number | Publication date |
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EP2851143A4 (en) | 2016-01-13 |
US10052681B2 (en) | 2018-08-21 |
KR102000247B1 (ko) | 2019-07-15 |
CN104379275A (zh) | 2015-02-25 |
JPWO2014030398A1 (ja) | 2016-07-28 |
BR112014030963B1 (pt) | 2019-04-16 |
JP6213471B2 (ja) | 2017-10-18 |
EP2851143A1 (en) | 2015-03-25 |
KR20150048091A (ko) | 2015-05-06 |
MX2014015151A (es) | 2015-03-05 |
RU2014150349A (ru) | 2016-10-10 |
US20150183025A1 (en) | 2015-07-02 |
EP2851143B1 (en) | 2017-04-05 |
CN104379275B (zh) | 2016-05-25 |
BR112014030963A2 (pt) | 2017-06-27 |
ES2624410T3 (es) | 2017-07-14 |
RU2618977C2 (ru) | 2017-05-11 |
MX361638B (es) | 2018-12-13 |
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