WO2014010520A1 - 熱伝導性シート - Google Patents
熱伝導性シート Download PDFInfo
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- WO2014010520A1 WO2014010520A1 PCT/JP2013/068475 JP2013068475W WO2014010520A1 WO 2014010520 A1 WO2014010520 A1 WO 2014010520A1 JP 2013068475 W JP2013068475 W JP 2013068475W WO 2014010520 A1 WO2014010520 A1 WO 2014010520A1
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- conductive sheet
- fibrous filler
- thermally conductive
- sheet
- heat
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3733—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon having a heterogeneous or anisotropic structure, e.g. powder or fibres in a matrix, wire mesh, porous structures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3737—Organic materials with or without a thermoconductive filler
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/02—Polysilicates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- the present invention relates to a heat conductive sheet.
- the heating element In order to prevent a failure of a heating element such as an IC chip that generates heat during driving, the heating element is brought into close contact with a radiator such as a radiation fin via a heat conductive sheet.
- a radiator such as a radiation fin
- the fibrous filler in the layered thermosetting resin composition in which the fibrous filler is dispersed in the thermosetting resin is used in the thickness direction of the layer. It has been proposed to produce a thermally conductive sheet by orienting using a magnetic field generator and then curing a thermosetting resin (Patent Document 1).
- the end of 50 to 100% of the fibrous filler of the total fibrous filler is exposed on the surface of the sheet, and when applied between the heating element and the heat dissipation element, the fibrous sheet The exposed end of the filler is configured to be immersed in the heat conductive sheet.
- An object of the present invention is to solve the above-mentioned problems of the prior art, and is a thermally conductive sheet having a high frequency in which fibrous fillers are in contact with each other, and the ends of exposed fibrous fillers.
- a thermal conductive sheet that does not need to be immersed in the sheet, and that does not need to be loaded with a load that interferes with their normal operation when placed between the heating element and the radiator.
- the present inventors examined the orientation state of the fibrous filler under the assumption that arranging the fibrous filler in the thickness direction of the thermal conductive sheet is the main cause causing the problems of the prior art. As a result, the inventors found that the above-mentioned object can be achieved by setting the ratio of the fibrous filler not oriented in the thickness direction of the thermally conductive sheet in the total fibrous filler to a relatively high predetermined range. Was completed.
- the present invention is a thermally conductive sheet containing a fibrous filler and a binder resin, the proportion of the fibrous filler not oriented in the thickness direction of the thermally conductive sheet in the total fibrous filler, Provide a thermally conductive sheet that is 45-95%.
- the proportion of the fibrous filler not oriented in the thickness direction of the thermally conductive sheet in the total fibrous filler is 45 to 95%. For this reason, the frequency with which the fibrous filler is mutually contacting within a heat conductive sheet becomes high, and thermal resistance falls. In addition, the end of the exposed fibrous filler does not dip into the sheet, and when it is placed between the heating element and the heat dissipation body, it is necessary to apply a load that hinders their normal operation. Nor. Moreover, generation
- the present invention is a thermally conductive sheet containing a fibrous filler and a binder resin, and the proportion of the fibrous filler not oriented in the thickness direction of the thermally conductive sheet is 45 to 45%. It is a 95% heat conductive sheet.
- the fibrous filler constituting the thermally conductive sheet is for efficiently conducting heat from the heating element to the radiator.
- a fibrous filler if the average diameter is too small, there is a concern that the specific surface area becomes excessive and the viscosity of the resin composition at the time of preparing the heat conductive sheet becomes too high. Since the surface unevenness of the conductive sheet becomes large, and there is a concern that the adhesiveness to the heat generating body and the heat radiating body is lowered, it is preferably 8 to 12 ⁇ m.
- the aspect ratio (length / diameter) is too small, the viscosity of the composition for forming a heat conductive sheet tends to be too high, and if it is too large, the compression of the heat conductive sheet tends to be inhibited.
- the fiber length is 15 to 800 ⁇ m, and the more preferred fiber length is 40 to 250 ⁇ m.
- the fibrous filler are preferably carbon fiber, metal fiber (for example, nickel, iron, etc.), glass fiber, ceramic fiber (for example, oxide (for example, aluminum oxide, silicon dioxide, etc.), nitride (for example, boron nitride, aluminum nitride, etc.), borides (eg, aluminum boride, etc.), carbides (eg, silicon carbide, etc., etc., nonmetallic inorganic fibers) can be mentioned.
- the fibrous filler is selected according to characteristics such as mechanical properties, thermal properties, and electrical properties required for the heat conductive sheet.
- characteristics such as mechanical properties, thermal properties, and electrical properties required for the heat conductive sheet.
- pitch-based carbon fibers can be preferably used from the viewpoints of high elastic modulus, good thermal conductivity, high conductivity, radio wave shielding, low thermal expansion, and the like.
- the content in the heat conductive sheet is preferably 16 to 40% by volume, More preferably, the content is 20 to 30% by volume, and preferably 120 to 300 parts by mass, and more preferably 130 to 250 parts by mass with respect to 100 parts by mass of a binder resin described later constituting the heat conductive sheet.
- a plate-like filler, a scale-like filler, a spherical filler, or the like can be used in combination as long as the effects of the present invention are not impaired.
- a preferable range of spherical fillers preferably spherical alumina or spherical aluminum nitride
- a diameter of 0.1 to 5 ⁇ m is: 30 to 60% by volume, more preferably 35 to 50% by volume, and preferably 100 to 900 parts by weight are used in combination with 100 parts by weight of the fibrous filler.
- the binder resin holds the fibrous filler in the heat conductive sheet, and is selected according to characteristics such as mechanical strength, heat resistance, and electrical properties required for the heat conductive sheet.
- a resin selected from a thermoplastic resin, a thermoplastic elastomer, and a thermosetting resin can be employed.
- Thermoplastic resins include polyethylene, polypropylene, ethylene- ⁇ olefin copolymers such as ethylene-propylene copolymer, polymethylpentene, polyvinyl chloride, polyvinylidene chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, Fluoropolymers such as polyvinyl alcohol, polyvinyl acetal, polyvinylidene fluoride and polytetrafluoroethylene, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polystyrene, polyacrylonitrile, styrene-acrylonitrile copolymer, acrylonitrile-butadiene-styrene copolymer Polymer (ABS) resin, polyphenylene-ether copolymer (PPE) resin, modified PPE resin, aliphatic polyamides, aromatic polyamides, polyimide, Polymethacrylates such
- thermoplastic elastomer examples include styrene-butadiene block copolymer or hydrogenated product thereof, styrene-isoprene block copolymer or hydrogenated product thereof, styrene-based thermoplastic elastomer, olefin-based thermoplastic elastomer, vinyl chloride-based thermoplastic elastomer. Polyester thermoplastic elastomer, polyurethane thermoplastic elastomer, polyamide thermoplastic elastomer, and the like.
- thermosetting resin examples include crosslinked rubber, epoxy resin, phenol resin, polyimide resin, unsaturated polyester resin, diallyl phthalate resin and the like.
- crosslinked rubber examples include natural rubber, acrylic rubber, butadiene rubber, isoprene rubber, styrene-butadiene copolymer rubber, nitrile rubber, hydrogenated nitrile rubber, chloroprene rubber, ethylene-propylene copolymer rubber, chlorinated polyethylene rubber, Examples include chlorosulfonated polyethylene rubber, butyl rubber, halogenated butyl rubber, fluorine rubber, urethane rubber, and silicone rubber.
- the heat conductive sheet can contain various additives as required in addition to the fibrous filler and the binder resin.
- the proportion of the fibrous filler not oriented in the thickness direction in the total fibrous filler is 45 to 95%, preferably 60 to 90%. If the proportion is less than 45%, there is a concern that the thermal conductivity in the thickness direction of the sheet will be insufficient, and if it exceeds 95%, the proportion of fibrous fillers that contact each other is small, There is a tendency for thermal conductivity to be insufficient.
- the fibrous filler not oriented in the thickness direction of the sheet is a fibrous filler in which the major axis direction of the fibrous filler is not parallel to the thickness direction.
- the ratio of the fibrous filler not oriented in the thickness direction in the total fibrous filler is obtained by observing the fibrous filler contained in the unit cube (0.5 mm square) under a microscope and counting the number thereof. be able to. Specifically, when observing one cross section of the heat conductive sheet, “the number of fibrous fillers arranged in the thickness direction and confirming a predetermined length” is expressed as “the fibrous shape oriented in the thickness direction”. It can be calculated from a value obtained by determining the ratio to the total number of fibrous fillers. In that case, the number of cross-sections to be observed can be at least two directions (vertical and horizontal) or more, and the average value obtained from them can be calculated as a reference.
- the heat conductive sheet of the present invention can be manufactured by a manufacturing method having the following steps (A) to (C). Each process will be described in detail.
- a composition for forming a heat conductive sheet is prepared by dispersing a fibrous filler in a binder resin. This preparation can be performed by uniformly mixing the fibrous filler, the binder resin, and various additives and volatile solvents blended as necessary by a known method.
- a molded body block is formed from the prepared composition for forming a heat conductive sheet by an extrusion molding method or a mold molding method.
- the extrusion molding method and the mold molding method are not particularly limited, and are required for the viscosity of the heat conductive sheet forming composition and the heat conductive sheet from among various known extrusion molding methods and mold molding methods. It can be appropriately employed depending on the characteristics and the like.
- the binder resin flows and flows.
- Some fibrous fillers are oriented along the direction, but many are randomly oriented.
- the fibrous filler tends to be easily oriented in the center with respect to the width direction of the extruded formed body block.
- the fibrous filler tends to be randomly oriented in the peripheral portion with respect to the width direction of the formed body block due to the influence of the slit wall.
- the size and shape of the molded body block can be determined according to the required size of the heat conductive sheet. For example, a rectangular parallelepiped having a vertical size of 0.5 to 15 cm and a horizontal size of 0.5 to 15 cm can be given. The length of the rectangular parallelepiped may be determined as necessary.
- the formed molded body block is sliced into sheets. Thereby, a heat conductive sheet is obtained.
- the fibrous filler is exposed on the surface (slice surface) of the sheet obtained by slicing.
- a method of slicing According to the magnitude
- the slicing direction of the molded body block when the molding method is an extrusion molding method, some of the molding block is oriented in the extrusion direction, and therefore, 60 to 120 degrees, more preferably 70 to 100 degrees with respect to the extrusion direction.
- the direction is particularly preferably 90 degrees (vertical).
- the slice thickness is not particularly limited and can be appropriately selected depending on the purpose of use of the heat conductive sheet.
- the sliced surface of the obtained heat conductive sheet can be pressed.
- the surface of a heat conductive sheet can be smooth
- a heat conductive sheet can be compressed and the frequency of contact between fibrous fillers can be increased. Thereby, it becomes possible to reduce the thermal resistance of a heat conductive sheet.
- a pair of pressing devices including a flat plate and a press head having a flat surface can be used. Moreover, you may press with a pinch roll.
- the thermal resistance tends to be the same as when the pressing is not performed, and when it is too high, the sheet tends to stretch, preferably 2 to 8 kgf / cm 2 , more preferably 3 ⁇ 7 kgf / cm 2 .
- Such a press is preferably performed at a temperature equal to or higher than the glass transition temperature of the binder resin in order to enhance the press effect and shorten the press time.
- the sheet thickness after pressing is reduced by compression, but if the sheet compression ratio [ ⁇ (sheet thickness before pressing ⁇ sheet thickness after pressing) / sheet thickness before pressing ⁇ ⁇ 100] is too small, the thermal resistance does not decrease. If the sheet is too large, the sheet tends to be stretched. Therefore, pressing is performed so that the compression rate is 2 to 15%.
- the surface of the sheet can be smoothed by pressing.
- the degree of smoothness can be evaluated by the surface glossiness. If the surface gloss is too low, the thermal conductivity is lowered. Therefore, it is preferable to perform pressing so that the surface gloss (gloss value) measured with a gloss meter at an incident angle of 60 degrees and a reflection angle of 60 degrees is 0.2 or more. .
- Such a heat conductive sheet can provide a thermal device having a structure arranged between them in order to release heat generated in the heating element to the heat radiating body.
- the heating element include an IC chip and an IC module
- the heat dissipation element include a heat sink formed from a metal material such as stainless steel.
- Example 1 Silicone A solution (organopolysiloxane having a vinyl group), Silicone B solution (organopolysiloxane having a hydrogensilyl group), alumina particles (average particle size 3 ⁇ m), and spherical aluminum nitride (average particle size 1 ⁇ m) And a pitch-based carbon fiber (average major axis length 150 ⁇ m, average axis diameter 8 ⁇ m) were uniformly mixed at a ratio (volume part) shown in Table 1 to prepare a silicone resin composition for forming a heat conductive sheet. .
- the molded resin block was prepared by pouring the silicone resin composition for forming a heat conductive sheet into a mold having a rectangular parallelepiped internal space and curing by heating in a 100 ° C. oven for 6 hours.
- a release polyethylene terephthalate film was attached to the inner surface of the mold so that the release treatment surface was inside.
- the obtained molded body block was sliced with an ultrasonic cutter to a thickness of 0.5 mm to obtain a sheet.
- a part of the fibrous filler was exposed to the surface by the shearing force at the time of slicing, and minute irregularities were formed on the sheet surface.
- it pressed in accordance with the conventional method so that it might become the compression rate of Table 1.
- the pitch-based carbon fibers were oriented in various longitudinal, lateral, and diagonal directions with respect to the thickness direction of the thermally conductive sheet, and the thickness of the thermally conductive sheet was further increased. The ratio of pitch-based carbon fibers not oriented in the direction to the total pitch-based carbon fibers was counted. The obtained results are shown in Table 1.
- Examples 2 to 11 Except for preparing a silicone resin composition for forming a heat conductive sheet according to the formulation in Table 1, a molded body block and a heat conductive sheet were prepared by the same operation as in Example 1. Further, the ratio of pitch-based carbon fibers not oriented in the thickness direction of the heat conductive sheet to the total pitch-based carbon fibers was counted. The obtained results are shown in Table 1.
- Comparative Examples 1 to 4 A silicone resin composition for forming a heat conductive sheet was prepared according to the formulation in Table 1, and a heat conductive sheet was prepared by the extrusion method disclosed in JP 2012-23335 A. (Ii) The central part, which is easily oriented, was cut out. Furthermore, it observed with the electron microscope and the ratio in the all pitch-type carbon fiber of the pitch-type carbon fiber which is not oriented in the thickness direction was counted. The obtained results are shown in Table 1.
- the ratio of the carbon fibers not oriented in the thickness direction of the heat conductive sheet in the total carbon fibers was 45 to 95%, so a preferable low value. (0.2 K / W or less (0.65 K ⁇ cm 2 / W or less)). From the results of Examples 8 to 11, good results were obtained even when the average fiber length of the carbon fibers was 40 to 250 ⁇ m.
- the ratio of the carbon fibers not oriented in the thickness direction of the heat conductive sheet in the total carbon fibers was 5 to 40%. It was over 0.2 K / W (0.65 K ⁇ cm 2 / W).
- the proportion of the fibrous filler not oriented in the thickness direction in the total fibrous filler is 45 to 95%. For this reason, the frequency with which the fibrous filler is mutually contacting within a heat conductive sheet becomes high, and thermal resistance falls. In addition, the end of the exposed fibrous filler does not immerse into the sheet, and when it is placed between the heating element and the heat dissipation body, it is necessary to apply a load that hinders their normal operation. Nor. Therefore, the heat conductive sheet of the present invention is useful as a heat conductive sheet for disposing between a heat generator such as an IC chip or an IC module and a heat radiator.
- a heat generator such as an IC chip or an IC module and a heat radiator.
Abstract
Description
まず、繊維状フィラーをバインダ樹脂に分散させることにより熱伝導性シート形成用組成物を調製する。この調製は、繊維状フィラーとバインダ樹脂と必要に応じて配合される各種添加剤や揮発性溶剤とを公知の手法により均一に混合することにより行うことができる。
<工程(B)>
次に、調製された熱伝導性シート形成用組成物から、押出し成形法又は金型成形法により成形体ブロックを形成する。
次に、形成された成形体ブロックをシート状にスライスする。これにより熱伝導性シートが得られる。スライスにより得られるシートの表面(スライス面)には、繊維状フィラーが露出する。スライスする方法としては特に制限はなく、成形体ブロックの大きさや機械的強度により公知のスライス装置(好ましくは超音波カッタ)の中から適宜選択することができる。成形体ブロックのスライス方向としては、成形方法が押出し成形法である場合には、押出し方向に配向しているものもあるために押出し方向に対して60~120度、より好ましくは70~100度の方向である。特に好ましくは90度(垂直)の方向である。
必要により、得られた熱伝導性シートのスライス面をプレスすることができる。これにより熱伝導性シートの表面を平滑化して、発熱体や放熱体への密着性を向上させることができる。また、熱伝導性シートを圧縮して、繊維状フィラー同士の接触の頻度を増大させることができる。これにより、熱伝導性シートの熱抵抗を低減させることが可能となる。プレスの方法としては、平盤と表面が平坦なプレスヘッドとからなる一対のプレス装置を使用することができる。また、ピンチロールでプレスしてもよい。
シリコーンA液(ビニル基を有するオルガノポリシロキサン)と、シリコーンB液(ヒドロジェンシリル基を有するオルガノポリシロキサン)と、アルミナ粒子(平均粒子径3μm)と、球状の窒化アルミニウム(平均粒子径1μm)と、ピッチ系炭素繊維(平均長軸長150μm、平均軸径8μm)とを、表1に示す割合(体積部)で均一に混合することにより熱伝導性シート形成用シリコーン樹脂組成物を調製した。
表1の配合に従って熱伝導性シート形成用シリコーン樹脂組成物を調製すること以外、実施例1と同様の操作により成形体ブロック、更に熱伝導性シートを作成した。更に、熱伝導性シートの厚さ方向に配向していないピッチ系炭素繊維の全ピッチ系炭素繊維中の割合をカウントした。得られた結果を表1に示す。
表1の配合に従い熱伝導性シート形成用シリコーン樹脂組成物を調整し、更に、特開2012-23335号公報の押出し成形法により熱伝導性シートを作成し、ピッチ系炭素繊維が(厚さ方向に)配向しやすいその中央部を切り出した。更に、電子顕微鏡で観察し、厚さ方向に配向していないピッチ系炭素繊維の全ピッチ系炭素繊維中の割合をカウントした。得られた結果を表1に示す。
得られた熱伝導性シートに対し、1kgf/cm2の荷重をかけ、表1の圧縮率となった時点の熱抵抗(K/W)をASTM-D5470に準拠した熱抵抗測定装置を用いて測定した。得られた結果を表1に示す。熱抵抗は0.2(K/W)以下、面積換算した値では0.65(K・cm2/W)以下であることが望まれる。
Claims (7)
- 繊維状フィラーとバインダ樹脂とを含有する熱伝導性シートであって、熱伝導性シートの厚さ方向に配向していない繊維状フィラーの全繊維状フィラー中の割合が、45~95%である熱伝導性シート。
- 繊維状フィラーの平均径が8~12μmで、アスペクト比が2~50である請求項1記載の熱伝導性シート。
- 繊維状フィラーがピッチ系炭素繊維である請求項1又は2記載の熱伝導性シート。
- 繊維状フィラーの熱伝導性シート中の含有量が、16~40体積%である請求項1~3のいずれかに記載の熱伝導性シート。
- 非繊維状フィラーを更に含有する請求項1~4のいずれかに記載の熱伝導性シート。
- 非繊維状フィラーが、球状の酸化アルミニウム又は窒化アルミニウムである請求項1~5のいずれかに記載の熱伝導性シート。
- バインダ樹脂が、シリコーン樹脂である請求項1~6のいずれかに記載の熱伝導性シート。
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US14/401,954 US10106672B2 (en) | 2012-07-07 | 2013-07-05 | Heat conductive sheet |
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KR20210150605A (ko) | 2021-12-10 |
US10106672B2 (en) | 2018-10-23 |
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