WO2013190020A1 - Moule à chauffage et refroidissement rapides - Google Patents

Moule à chauffage et refroidissement rapides Download PDF

Info

Publication number
WO2013190020A1
WO2013190020A1 PCT/EP2013/062817 EP2013062817W WO2013190020A1 WO 2013190020 A1 WO2013190020 A1 WO 2013190020A1 EP 2013062817 W EP2013062817 W EP 2013062817W WO 2013190020 A1 WO2013190020 A1 WO 2013190020A1
Authority
WO
WIPO (PCT)
Prior art keywords
mold
carcass
molding zone
inductors
mold according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2013/062817
Other languages
English (en)
French (fr)
Inventor
Alexandre GUICAHRD
José FEIGENBLUM
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RocTool SA
Original Assignee
RocTool SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA2875235A priority Critical patent/CA2875235C/fr
Priority to IN10743DEN2014 priority patent/IN2014DN10743A/en
Priority to BR112014031686-4A priority patent/BR112014031686B1/pt
Priority to RU2015101237A priority patent/RU2630256C2/ru
Priority to MX2014015702A priority patent/MX374091B/es
Priority to EP13730563.7A priority patent/EP2862415B1/fr
Priority to JP2015517754A priority patent/JP6318150B2/ja
Priority to CN201380032277.6A priority patent/CN104412705B/zh
Application filed by RocTool SA filed Critical RocTool SA
Priority to ES13730563T priority patent/ES2769450T3/es
Priority to US14/408,827 priority patent/US9248598B2/en
Priority to KR1020147036195A priority patent/KR102142976B1/ko
Publication of WO2013190020A1 publication Critical patent/WO2013190020A1/fr
Anticipated expiration legal-status Critical
Priority to US14/976,203 priority patent/US10052803B2/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B29C45/73—Heating or cooling of the mould
    • B29C45/7312—Construction of heating or cooling fluid flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B29C45/73—Heating or cooling of the mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C9/00—Moulds or cores; Moulding processes
    • B22C9/06—Permanent moulds for shaped castings
    • B22C9/065—Cooling or heating equipment for moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • B29C33/06—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means using radiation, e.g. electro-magnetic waves, induction heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B29C45/73—Heating or cooling of the mould
    • B29C45/7331—Heat transfer elements, e.g. heat pipes
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00—Heating by electric, magnetic or electromagnetic fields
    • H05B6/02—Induction heating
    • H05B6/36—Coil arrangements
    • H05B6/42—Cooling of coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B29C45/73—Heating or cooling of the mould
    • B29C2045/7368—Heating or cooling of the mould combining a heating or cooling fluid and non-fluid means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/26—Moulds
    • B29C45/27—Sprue channels ; Runner channels or runner nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/38—Cutting-off equipment for sprues or ingates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2827/00—Use of polyvinylhalogenides or derivatives thereof as mould material
    • B29K2827/12—Use of polyvinylhalogenides or derivatives thereof as mould material containing fluorine
    • B29K2827/18—PTFE, i.e. polytetrafluorethene, e.g. ePTFE, i.e. expanded polytetrafluorethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2905/00—Use of metals, their alloys or their compounds, as mould material
    • B29K2905/08—Transition metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2905/00—Use of metals, their alloys or their compounds, as mould material
    • B29K2905/08—Transition metals
    • B29K2905/10—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2907/00—Use of elements other than metals as mould material
    • B29K2907/04—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2909/00—Use of inorganic materials not provided for in groups B29K2803/00 - B29K2807/00, as mould material

Definitions

  • Document EP 1 894 442 in the name of the applicant, describes a mold equipped with an induction heating device and a cooling device by circulation of a heat transfer fluid.
  • This device of the prior art comprises a mold consisting of a fixed part and a movable part. Each of the parts is capable of receiving an induction heating circuit and a cooling circuit. Each of these parts consists of a carcass on which is reported a piece constituting the molding surface is which gives its final shape to the part made in this mold.
  • the molding surface is the surface to be heated and cooled, which surface is in contact with the material constituting the part.
  • the inductors are placed in cavities that extend below said molding surface.
  • the cooling device comprises a cavity (341, 342) which cavity is filled with a material capable of changing phase for a given temperature, this phase change being accompanied by the absorption of high latent heat.
  • the phase change is a merger or vaporization.
  • Said material is, for example, water.
  • Section SS according to a longitudinal sectional view, the injection duct (542) is oriented so that the direction of the fluid jet in the cavity of the inductor has a component parallel to the longitudinal direction.
  • efficient cooling is obtained by a turbulence circulation of the gas along the inductor (132).

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Electromagnetism (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • General Induction Heating (AREA)
  • Coils Or Transformers For Communication (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
PCT/EP2013/062817 2012-06-19 2013-06-19 Moule à chauffage et refroidissement rapides Ceased WO2013190020A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
JP2015517754A JP6318150B2 (ja) 2012-06-19 2013-06-19 迅速加熱冷却金型
BR112014031686-4A BR112014031686B1 (pt) 2012-06-19 2013-06-19 Molde de aquecimento e resfriamento rápidos
RU2015101237A RU2630256C2 (ru) 2012-06-19 2013-06-19 Пресс-форма с быстрым нагревом и охлаждением
MX2014015702A MX374091B (es) 2012-06-19 2013-06-19 Molde con calentamiento y enfriamiento rapidos.
EP13730563.7A EP2862415B1 (fr) 2012-06-19 2013-06-19 Moule à chauffage et refroidissement rapides
CN201380032277.6A CN104412705B (zh) 2012-06-19 2013-06-19 快速加热和冷却的模具
ES13730563T ES2769450T3 (es) 2012-06-19 2013-06-19 Molde para calentamiento y enfriamiento rápidos
CA2875235A CA2875235C (fr) 2012-06-19 2013-06-19 Moule a chauffage et refroidissement rapides
IN10743DEN2014 IN2014DN10743A (enExample) 2012-06-19 2013-06-19
US14/408,827 US9248598B2 (en) 2012-06-19 2013-06-19 Quick heating and cooling mold
KR1020147036195A KR102142976B1 (ko) 2012-06-19 2013-06-19 신속 가열 및 냉각 주형
US14/976,203 US10052803B2 (en) 2012-06-19 2015-12-21 Quick heating and cooling mold

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1255756 2012-06-19
FR1255756 2012-06-19

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US14/408,827 A-371-Of-International US9248598B2 (en) 2012-06-19 2013-06-19 Quick heating and cooling mold
US14/976,203 Continuation US10052803B2 (en) 2012-06-19 2015-12-21 Quick heating and cooling mold

Publications (1)

Publication Number Publication Date
WO2013190020A1 true WO2013190020A1 (fr) 2013-12-27

Family

ID=48670558

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/062817 Ceased WO2013190020A1 (fr) 2012-06-19 2013-06-19 Moule à chauffage et refroidissement rapides

Country Status (12)

Country Link
US (2) US9248598B2 (enExample)
EP (1) EP2862415B1 (enExample)
JP (1) JP6318150B2 (enExample)
KR (1) KR102142976B1 (enExample)
CN (1) CN104412705B (enExample)
BR (1) BR112014031686B1 (enExample)
CA (1) CA2875235C (enExample)
ES (1) ES2769450T3 (enExample)
IN (1) IN2014DN10743A (enExample)
MX (1) MX374091B (enExample)
RU (1) RU2630256C2 (enExample)
WO (1) WO2013190020A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016055607A (ja) * 2014-09-12 2016-04-21 株式会社イケックス工業 金型及びその製造方法
WO2016071653A1 (fr) * 2014-11-07 2016-05-12 Compagnie Plastic Omnium Dispositif et procédé de régulation de la température d'un moule par faisceau laser
WO2016151127A1 (fr) * 2015-03-24 2016-09-29 Roctool Dispositif et procédé pour le formage du verre
JP2017513745A (ja) * 2013-12-31 2017-06-01 ロックツール 金型の成形面を加熱するための装置
FR3072768A1 (fr) * 2017-10-25 2019-04-26 Roctool Procede et dispositif de moulage notamment d’un verre metallique
WO2024261113A1 (fr) 2023-06-21 2024-12-26 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procédé de fabrication d'un module photovoltaïque par thermoformage d'un empilement multicouche

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BR112014031686B1 (pt) * 2012-06-19 2021-12-14 Roctool Molde de aquecimento e resfriamento rápidos
US9616482B2 (en) * 2013-11-05 2017-04-11 Martinrea Industries, Inc. Hot forming metal die with improved cooling system
US10350672B2 (en) * 2014-12-02 2019-07-16 Halliburton Energy Services, Inc. Mold assemblies that actively heat infiltrated downhole tools
JP6559495B2 (ja) * 2015-07-29 2019-08-14 株式会社キャステム ロストワックス法を用いた鋳造品の製造方法
DE102015114880A1 (de) 2015-09-04 2017-03-09 Diehl Aircabin Gmbh Induktiv beheizbares Formwerkzeug
DE102015221758A1 (de) * 2015-11-05 2017-05-11 Coperion Gmbh Schneckenmaschine und Verfahren zur Aufbereitung von aufzubereitendem Material
CN106670432A (zh) * 2015-11-11 2017-05-17 成都兴宇精密铸造有限公司 一种铸造模具温度控制装置
FR3050390B1 (fr) * 2016-04-26 2020-01-24 Roctool Procede et dispositif pour le moulage en coquille d’un alliage metallique
FR3051136A1 (fr) * 2016-05-10 2017-11-17 Roctool Procede et dispositif pour le chauffage d’un moule
FR3051135B1 (fr) * 2016-05-10 2019-05-31 Roctool Dispositif et procede pour le moulage et la consolidation d’une preforme textile
WO2018023168A1 (en) * 2016-08-04 2018-02-08 Modi Consulting And Investments Pty Ltd A multi material laminated tool having improved thermal coupling
US10464244B2 (en) * 2017-02-15 2019-11-05 Fca Us Llc Injection mold for ultra thin wall components
US11225047B2 (en) 2017-03-15 2022-01-18 International Automotive Components Group North America, Inc. Skin-foam-substrate structure via induction heating
CN106862491A (zh) * 2017-03-29 2017-06-20 福建工程学院 一种趋形加热冷却模具及其加工和使用方法
US11008453B2 (en) 2018-01-16 2021-05-18 Arkema France Polymeric composite articles comprising the heterogeneous surface/bulk distribution of discrete phase
US11413802B2 (en) * 2018-03-22 2022-08-16 Honda Motor Co., Ltd. Reusable mold for injection molding and molding method
CN108672656A (zh) * 2018-08-08 2018-10-19 溧阳市新力机械铸造有限公司 一种涡轮叶片铸造装置及涡轮叶片的铸造方法
CN109158573A (zh) * 2018-10-17 2019-01-08 江苏盛航精密制造有限公司 一种自预热的铝镁合金压铸模具
US10987831B2 (en) * 2019-05-24 2021-04-27 The Boeing Company Dies for forming a part and associated systems and methods
IT201900021714A1 (it) * 2019-11-20 2021-05-20 Form S R L Stampo per pressocolata e relativo procedimento di pressocolata
CN111361132B (zh) * 2020-03-13 2022-02-18 淮阴工学院 一种用于汽车地毯生产的模具及其使用方法
CN115255245B (zh) * 2022-07-21 2024-02-02 江苏辰顺精密科技有限公司 一种用于提高热锻效率的铝件热锻模具
CN120901248A (zh) * 2025-10-13 2025-11-07 内蒙古一机集团富成锻造有限责任公司 一种对开结构高强铝合金轮毂一体模锻成形组合模具结构

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JPS6378720A (ja) * 1986-09-24 1988-04-08 Sekisui Chem Co Ltd 成形金型
JPH05337997A (ja) * 1992-06-09 1993-12-21 Ricoh Co Ltd プラスチック成形用金型の冷却装置
WO2006112571A1 (en) * 2005-03-24 2006-10-26 Myung-Ho Kang Mold for injection molding machine
WO2008039485A1 (en) * 2006-09-27 2008-04-03 Johnson & Johnson Vision Care, Inc. Chilled injection molding during ophthalmic lens manufacture
EP2199057A1 (en) * 2008-12-19 2010-06-23 Chung Yuan Christian University Coaxial cooling/heating coil structure and the mold configured with the same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017513745A (ja) * 2013-12-31 2017-06-01 ロックツール 金型の成形面を加熱するための装置
JP2016055607A (ja) * 2014-09-12 2016-04-21 株式会社イケックス工業 金型及びその製造方法
WO2016071653A1 (fr) * 2014-11-07 2016-05-12 Compagnie Plastic Omnium Dispositif et procédé de régulation de la température d'un moule par faisceau laser
FR3028203A1 (fr) * 2014-11-07 2016-05-13 Plastic Omnium Cie Dispositif de regulation de la temperature d'un moule par faisceau laser
WO2016151127A1 (fr) * 2015-03-24 2016-09-29 Roctool Dispositif et procédé pour le formage du verre
FR3034093A1 (fr) * 2015-03-24 2016-09-30 Roctool Dispositif et procede pour le formage du verre
US20180057389A1 (en) * 2015-03-24 2018-03-01 Roctool Glass forming device and method
US11505488B2 (en) 2015-03-24 2022-11-22 Roctool Glass forming device and method
FR3072768A1 (fr) * 2017-10-25 2019-04-26 Roctool Procede et dispositif de moulage notamment d’un verre metallique
WO2019081687A1 (fr) 2017-10-25 2019-05-02 Rotool Procédé et dispositif de moulage notamment d'un verre métallique
WO2024261113A1 (fr) 2023-06-21 2024-12-26 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procédé de fabrication d'un module photovoltaïque par thermoformage d'un empilement multicouche
FR3150135A1 (fr) 2023-06-21 2024-12-27 Commissariat A L’Energie Atomique Et Aux Energies Alternatives Procédé de fabrication d’un module photovoltaïque par thermoformage d’un empilement multicouche

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US20150165665A1 (en) 2015-06-18
CA2875235A1 (fr) 2013-12-27
BR112014031686B1 (pt) 2021-12-14
RU2630256C2 (ru) 2017-09-06
JP2015521551A (ja) 2015-07-30
KR102142976B1 (ko) 2020-08-10
KR20150022891A (ko) 2015-03-04
US20160101551A1 (en) 2016-04-14
US9248598B2 (en) 2016-02-02
CN104412705A (zh) 2015-03-11
MX374091B (es) 2025-03-05
JP6318150B2 (ja) 2018-04-25
US10052803B2 (en) 2018-08-21
CN104412705B (zh) 2016-09-14
RU2015101237A (ru) 2016-08-10
CA2875235C (fr) 2021-06-22
EP2862415B1 (fr) 2019-11-06
ES2769450T3 (es) 2020-06-25
MX2014015702A (es) 2015-07-23
BR112014031686A2 (pt) 2017-06-27
EP2862415A1 (fr) 2015-04-22

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