WO2013170596A1 - Détergent et procédé de préparation et application associés - Google Patents

Détergent et procédé de préparation et application associés Download PDF

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Publication number
WO2013170596A1
WO2013170596A1 PCT/CN2012/084845 CN2012084845W WO2013170596A1 WO 2013170596 A1 WO2013170596 A1 WO 2013170596A1 CN 2012084845 W CN2012084845 W CN 2012084845W WO 2013170596 A1 WO2013170596 A1 WO 2013170596A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent
group
detergent according
agents
branched
Prior art date
Application number
PCT/CN2012/084845
Other languages
English (en)
Chinese (zh)
Inventor
刘欣
Original Assignee
北京京东方光电科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 北京京东方光电科技有限公司 filed Critical 北京京东方光电科技有限公司
Publication of WO2013170596A1 publication Critical patent/WO2013170596A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds

Definitions

  • Embodiments of the present disclosure relate to detergents that can be used to wash antistatic appliances, and to methods and applications for the preparation of such detergents.
  • antistatic gloves In the electronics manufacturing industry, workers must use anti-static gloves when working to prevent damage and aging of electronic components caused by static electricity. In the petrochemical industry, antistatic gloves are also used to prevent the burning and explosion caused by static electricity. Antistatic gloves are made of a material composed of rayon and conductive fibers. Some ESD gloves also contain a resin coating on the fingers and palms. Therefore, it is possible to reduce the service life of a general detergent.
  • An aspect of the present disclosure provides a detergent which can be used for washing an antistatic appliance which can quickly and thoroughly remove contaminants and the like attached to an antistatic appliance.
  • the specific plan is as follows.
  • a detergent comprising, by mass percentage, 10% to 30% cationic surfactant, 50% to 80% nonionic surfactant, and 5% to 20% auxiliary.
  • the total amount of the cationic surfactant, the nonionic surfactant, and the auxiliary agent is, for example, 100%.
  • the cationic surfactant is an ester quaternary ammonium salt type cationic surfactant, and the ester quaternary ammonium salt type cationic surfactant has the following formula:
  • each R is the same or different and represents a linear or branched saturated or unsaturated hydrocarbon group having 8 to 19 carbon atoms, and preferably a linear alkyl group having 16 to 18 carbon atoms.
  • a straight or branched alkylene group having 1 to 4 carbon atoms such as an anthracenylene group, an ethylene group, a propylene group, and a butylene group
  • a linear or branched alkyl group having 1 to 4 atoms such as an anthracenyl group, an ethyl group, a propyl group and a butyl group.
  • R 2 and R 3 each represent a single bond or a linear or branched alkylene group having 1 to 4 carbon atoms, and are, for example, an anthranylene group, an ethylene group, a propylene group, and a butylene group.
  • X represents a halogen anion or an oxyacid anion such as chloride, bromide, c3 ⁇ 4so 4 .
  • the nonionic surfactant is selected from one or more selected from the group consisting of fatty alcohol polyoxyethylene ethers and alkylphenol polyoxyethylene acids.
  • the fatty alcohol polyoxyethylene ether has the formula CH 2 CH 2 0) n H, wherein R 1 represents a linear or branched saturated or unsaturated hydrocarbon group having 12 to 18 carbon atoms, and n is 3 ⁇ 9.
  • R 1 represents a linear or branched saturated or unsaturated hydrocarbon group having 12 to 18 carbon atoms
  • n is 3 ⁇ 9.
  • Examples of the fatty alcohol polyoxyethylene ether include AE07 and AE09.
  • the alkylphenol ethoxylate has the formula R 2 C 6 3 ⁇ 40-(CH 2 CH 2 0) m H, wherein R 2 represents a linear or branched alkyl group having 8 to 10 carbon atoms, m It is 8 ⁇ 12.
  • the auxiliary agent is one or more selected from the group consisting of a chelating agent, an antistatic agent, a conditioning agent, a stabilizer, an anti-deposition agent, a foam stabilizer, and a thickener.
  • a chelating agent an antistatic agent, conditioner, stabilizer, anti-deposition agent, foam stabilizer and thickener, those generally used in the art can be used.
  • the adjuvant contains at least a polyalcohol (e.g., polyethylene glycol), a fatty alkyl sodium sulfate (e.g., sodium dodecyl sulphate), and disodium edetate.
  • a polyalcohol e.g., polyethylene glycol
  • a fatty alkyl sodium sulfate e.g., sodium dodecyl sulphate
  • disodium edetate e.g., sodium dodecyl sulphate
  • the detergent of the present disclosure preferably contains 15% to 25% cationic surfactant, 60% to 70% nonionic surfactant, and 15% to 20% auxiliary. More preferably, it contains 15% to 25% of bis(alkyl ester) hydroxyethyl decyl ammonium sulfonate, 60% to 70% of fatty alcohol ethoxylate and 15% to 20%.
  • Another aspect of the present disclosure also provides a method of preparing the above detergent, comprising the steps of:
  • yet another aspect of the present disclosure is also directed to the use of the above detergent in washing an antistatic appliance.
  • the antistatic tool includes an antistatic glove, an antistatic suit, and an antistatic sleeve.
  • the detergent of the present disclosure can quickly and thoroughly remove contaminants and the like attached to the antistatic tool, and the damage thereof is small, so that the service life of the antistatic tool can be improved. Moreover, the antistatic appliance washed with the detergent of the present disclosure maintains a good antistatic function.
  • the specific embodiments are not limited to the following embodiments. It should be noted that “parts" of each substance described below means “parts by weight”.
  • the B value (whiteness retention ratio) is the evaluation index of the washing effect. When B > 1.0, the detergent detergency is qualified; when B ⁇ 1.0, the detergent detergency is unqualified.
  • Test samples included JB-01 (carbon black oil stain), JB-02 (protein stain), JB-03 (serum stain). Washing conditions: The detergent concentration in the washing liquid is 0.2% by mass, the washing temperature is 30 ° C, the washing time is 20 min, and the water hardness is 250 mg/kg.
  • the antistatic gloves were washed with the detergents prepared in Examples 1 to 3, and as a result, the contaminants attached to the antistatic gloves were quickly and thoroughly removed, and the damage was small.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne un détergent et un procédé de préparation et une application associés. Le détergent comprend, en pourcentage en masse, un tensioactif cationique représentant 10 % à 30 %, un tensioactif non ionique représentant 50 % à 80 % et un assistant représentant 5 % à 20 %. Le détergent de la présente invention peut éliminer rapidement et en profondeur des contaminants et similaires fixés sur un appareil antistatique et provoquer peut de dommage à l'appareil antistatique, ce qui permet de prolonger la durée de vie de l'appareil antistatique.
PCT/CN2012/084845 2012-05-14 2012-11-19 Détergent et procédé de préparation et application associés WO2013170596A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210148981.5 2012-05-14
CN 201210148981 CN102676319B (zh) 2012-05-14 2012-05-14 洗涤剂及其制备方法和应用

Publications (1)

Publication Number Publication Date
WO2013170596A1 true WO2013170596A1 (fr) 2013-11-21

Family

ID=46808875

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2012/084845 WO2013170596A1 (fr) 2012-05-14 2012-11-19 Détergent et procédé de préparation et application associés

Country Status (2)

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CN (1) CN102676319B (fr)
WO (1) WO2013170596A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676319B (zh) * 2012-05-14 2013-12-25 北京京东方光电科技有限公司 洗涤剂及其制备方法和应用
CN107821423B (zh) * 2017-10-18 2021-04-02 福建恒安集团有限公司 一种防腐剂

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4443363A (en) * 1980-12-23 1984-04-17 Hoechst Aktiengesellschaft Detergent composition for cleaning hard surfaces and method of using the same
US20030228991A1 (en) * 2002-05-31 2003-12-11 Johnson Andress Kirsty Premix compositions suitable for the preparation of aqueous or semi-aqueous cleaning and degreasing formulations with low VOCs.
US20080188397A1 (en) * 2005-01-25 2008-08-07 Akzo Nobel N.V. Use of a Quaternary Ammonium Compound as a Hydrotrope and a Composition Containing the Quaternary Ammonium Compound
CN102643722A (zh) * 2011-11-18 2012-08-22 北京京东方光电科技有限公司 洗涤剂及其制备方法
CN102676319A (zh) * 2012-05-14 2012-09-19 北京京东方光电科技有限公司 洗涤剂及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1240472A (zh) * 1996-10-18 2000-01-05 普罗格特-甘布尔公司 包含阳离子、阴离子和非离子表面活性剂的混合物的洗涤剂组合物
CN101514309A (zh) * 2009-03-19 2009-08-26 厦门市捷瑞静电设备有限公司 一种防静电无尘布洗涤剂及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4443363A (en) * 1980-12-23 1984-04-17 Hoechst Aktiengesellschaft Detergent composition for cleaning hard surfaces and method of using the same
US20030228991A1 (en) * 2002-05-31 2003-12-11 Johnson Andress Kirsty Premix compositions suitable for the preparation of aqueous or semi-aqueous cleaning and degreasing formulations with low VOCs.
US20080188397A1 (en) * 2005-01-25 2008-08-07 Akzo Nobel N.V. Use of a Quaternary Ammonium Compound as a Hydrotrope and a Composition Containing the Quaternary Ammonium Compound
CN102643722A (zh) * 2011-11-18 2012-08-22 北京京东方光电科技有限公司 洗涤剂及其制备方法
CN102676319A (zh) * 2012-05-14 2012-09-19 北京京东方光电科技有限公司 洗涤剂及其制备方法和应用

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CN102676319A (zh) 2012-09-19
CN102676319B (zh) 2013-12-25

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