WO2013132739A1 - 発光デバイスの製造方法および発光デバイス - Google Patents
発光デバイスの製造方法および発光デバイス Download PDFInfo
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- WO2013132739A1 WO2013132739A1 PCT/JP2013/000469 JP2013000469W WO2013132739A1 WO 2013132739 A1 WO2013132739 A1 WO 2013132739A1 JP 2013000469 W JP2013000469 W JP 2013000469W WO 2013132739 A1 WO2013132739 A1 WO 2013132739A1
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- Prior art keywords
- light emitting
- emitting layer
- opening
- mask
- light
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 69
- 238000001228 spectrum Methods 0.000 claims abstract description 44
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 238000000059 patterning Methods 0.000 claims description 6
- 230000007261 regionalization Effects 0.000 claims description 2
- 101100127891 Caenorhabditis elegans let-4 gene Proteins 0.000 claims 1
- 239000010410 layer Substances 0.000 description 252
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- 230000005525 hole transport Effects 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 230000008021 deposition Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/08—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a plurality of light emitting regions, e.g. laterally discontinuous light emitting layer or photoluminescent region integrated within the semiconductor body
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
- H10K59/351—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels comprising more than three subpixels, e.g. red-green-blue-white [RGBW]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/166—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2933/00—Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
- H01L2933/0008—Processes
- H01L2933/0025—Processes relating to coatings
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
- H10K50/125—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light
- H10K50/13—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
- H10K59/352—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels the areas of the RGB subpixels being different
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
- H10K59/353—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels characterised by the geometrical arrangement of the RGB subpixels
Definitions
- the present invention relates to a method for manufacturing a light emitting device and a light emitting device.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2011-165581
- Patent Document 2 Japanese Patent Application Laid-Open No. 2010-40529
- a method for manufacturing a light-emitting device wherein a mask having a first opening and at least one second opening disposed along a longitudinal direction of the first opening is disposed on a substrate.
- the longitudinal direction of the first opening is shorter than the width of the first opening in the longitudinal direction of the first opening and is equal to or longer than the width of at least one second opening in the longitudinal direction of the first opening.
- a second mask different from the first spectrum through the first opening and at least one second opening of the mask after the first mask moving step and the first mask moving step.
- the second light-emitting material which emits light Le and a second pattern forming step of patterning on the substrate.
- the distance between the centers of two adjacent second openings of at least one second opening arranged at equal intervals is approximately a half distance.
- the mask may be moved in the longitudinal direction of the first opening.
- a second mask moving step of moving the mask in the longitudinal direction of the first opening; and after the second mask moving step, the first spectrum and the second spectrum via the first opening and at least one second opening of the mask; May further include a third pattern forming step of patterning with a third light emitting material that emits light of a different third spectrum.
- the longitudinal direction of the first opening is a distance that is approximately 1/3 of the distance between the centers of two adjacent second openings of at least one second opening.
- the mask may be moved in the longitudinal direction of the first opening by a distance that is approximately 1/3 of the center-to-center distance.
- the mask is moved in the short direction of the first opening by a distance longer than the sum of the width of the first opening and the width of at least one second opening in the short direction of the first opening.
- a fourth mask moving step, and a fourth pattern forming step of forming a pattern on the substrate with the first light emitting material through the first opening of the mask and at least one second opening after the fourth mask moving step. May be included.
- the distance is equal to or longer than the width of at least one second opening in the longitudinal direction of the first opening, which is shorter than the width of the first opening in the longitudinal direction of the first opening.
- a fifth pattern forming step of forming a pattern may be further included.
- a light-emitting device includes a first electrode layer and a second electrode layer, and a light-emitting material layer disposed between the first electrode layer and the second electrode layer.
- the first light-emitting layer formed of the first light-emitting material that emits light of the first spectrum has substantially the same shape as the first light-emitting layer, and is predetermined in the plane direction with respect to the first light-emitting layer.
- the second light emitting material is formed of a second light emitting material that emits light of a second spectrum different from the first spectrum, and is stacked in a range from the first light emitting layer to the same plane as the first light emitting layer with a distance shift. 2 light emitting layers.
- the light emitting material layer includes a third light emitting layer formed of the first light emitting material in a first region in the same plane as the first light emitting layer, and a second in the same plane as the first light emitting layer.
- the region may further include a fourth light emitting layer formed of the second light emitting material, and the distance between the centers of the third light emitting layer and the fourth light emitting layer may be a predetermined distance.
- the third light emitting layer and the fourth light emitting layer may be arranged along the longitudinal direction of the first light emitting layer and the second light emitting layer.
- the third light emitting layer and the fourth light emitting layer may be disposed adjacent to a region where the first light emitting layer and the second light emitting layer overlap.
- the light emitting material layer has substantially the same shape as the first light emitting layer and the second light emitting layer, and is shifted from the second light emitting layer by a predetermined distance in the plane direction with respect to the second light emitting layer.
- a fifth light-emitting layer formed of a third light-emitting material that is stacked in the same plane as the first light-emitting layer and emits light of a third spectrum different from the first spectrum and the second spectrum; You may have.
- the light emitting material layer may further include a sixth light emitting layer formed of the third light emitting material in a third region in the same plane as the first light emitting layer.
- the sixth light emitting layer may be arranged alongside the third light emitting layer and the fourth light emitting layer along the longitudinal direction of the first light emitting layer, the second light emitting layer, and the fifth light emitting layer. Good.
- the sixth light emitting layer may be disposed adjacent to a region where the first light emitting layer, the second light emitting layer, and the fifth light emitting layer overlap.
- FIG. 1 shows a plan view of a light emitting device according to the present embodiment.
- the light emitting device includes a substrate 10.
- the substrate 10 includes a first light emitting layer region 101, a second light emitting layer region 102, a third light emitting layer region 103, and a fourth light emitting layer region 104 that are arranged apart from each other.
- a red light emitting layer that emits red R light, which is an example of light of the first spectrum
- a green light emitting layer that emits green G light, which is an example of light having a second spectrum different from the first spectrum, is formed.
- a blue light emitting layer that emits blue B light which is an example of light having a third spectrum different from the first spectrum and the second spectrum
- a white light emitting layer that emits white W light which is an example of light in which the light of the first spectrum, the second spectrum, and the third spectrum is mixed, is formed.
- the first light-emitting layer region 101, the second light-emitting layer region 102, the third light-emitting layer region 103, and the fourth light-emitting layer region 104 each constitute one subpixel, and the first light-emitting layer region 101 and the second light-emitting layer region 102, the third light emitting layer region 103, and the fourth light emitting layer region 104 constitute one pixel.
- the light emitting device causes the light emitting layers of the first light emitting layer region 101, the second light emitting layer region 102, the third light emitting layer region 103, and the fourth light emitting layer region 104 to emit light simultaneously.
- the light emitting device makes the person who receives the light irradiated from each light emitting layer recognize that white light having a predetermined color temperature is irradiated.
- FIG. 2A shows a luminescent material in each of the first light emitting layer region 101, the second light emitting layer region 102, the third light emitting layer region 103, and the fourth light emitting layer region 104 above the substrate 10 of the light emitting device according to this embodiment.
- the top view of the mask 200 used when depositing is shown.
- the mask 200 has a first opening 201 and a plurality of second openings formed along the longitudinal direction X of the first opening 201.
- the center-to-center distances of the plurality of second openings 202 are the same as the center-to-center distances between the plurality of first light-emitting layer regions 101, the plurality of second light-emitting layer regions 102, or the plurality of third light-emitting layer regions 103.
- the distance between the centers of the plurality of second openings 202 is the distance between the centers of one first light emitting layer region 101 and one second light emitting layer region 102 adjacent to one first light emitting layer region 101. Three times the distance.
- a red light emitting layer, a green light emitting layer, and a blue light emitting are formed in each light emitting layer region above the substrate 10. And a white light emitting layer are formed.
- the first opening 201 and the plurality of second openings 202 included in the mask 200 may form one opening as shown in FIG. 2B.
- the mask 200 only needs to have at least one second opening 202.
- FIG. 3A, FIG. 3B, FIG. 3C, FIG. 3D, FIG. 3E, FIG. 3F, FIG. 3G, and FIG. 3H are explanatory views of each step of the method for manufacturing the light emitting device according to this embodiment.
- the mask 200 is placed in a predetermined position on the substrate 10, for example, in FIG. 3A, the leftmost second opening 202 has the first leftmost light emitting layer among the plurality of first light emitting layer regions 101 of the substrate 10. It arrange
- a first light emitting material that emits light of the first spectrum corresponding to the red R through the first opening 201 and the plurality of second openings 202 of the mask 200 is deposited by, for example, mask vapor deposition.
- a pattern is formed on the substrate 10 with one light emitting material. Thereby, a plurality of red light emitting layers 32 a and red light emitting layers 32 b are formed on the substrate 10.
- the red light emitting layer 32a is an example of a “third light emitting layer”.
- the red light emitting layer 32b is an example of a “first light emitting layer”.
- the mask 200 is placed in the short direction 300 of the first opening by a distance w3 longer than the sum of the width w2 of the first opening and the width w1 of the plurality of second openings 202 in the short direction 300 of the first opening 201.
- the pattern is again formed on the substrate 10 with the first light emitting material through the first opening 201 and the plurality of second openings 202 of the mask 200 (FIG. 3C).
- a plurality of red light emitting layers 32a and a plurality of red light emitting layers 32b are formed on the substrate 10 by repeatedly moving the mask 200 in the lateral direction 300 and mask vapor deposition of the first light emitting material (FIG. 3D).
- the longitudinal direction of the first opening 201 is shorter than the width D of the first opening 201 in the longitudinal direction 302 of the first opening 201 by a distance equal to or greater than the width of the plurality of second openings 202 in the longitudinal direction 302 of the first opening 201.
- the mask 200 is moved to 302 (FIG. 3E). More specifically, the mask 200 is arranged in the longitudinal direction 302 of the first opening 201 by a distance d / 3 that is approximately 1/3 of the center distance d between two adjacent second openings of the plurality of second openings 202. Move.
- the second light that emits light having a second spectrum different from the first spectrum corresponding to green is emitted through the first opening 201 and the plurality of second openings 202 of the mask 200.
- the light emitting material is mask-deposited to form a pattern on the substrate 10 with the second light emitting material (FIG. 3F). Thereby, a plurality of green light emitting layers 33 a and green light emitting layers 33 b are formed on the substrate 10.
- the green light emitting layer 33a is an example of a “fourth light emitting layer”.
- the green light emitting layer 33b is an example of a “second light emitting layer”.
- the mask 200 is moved in the short direction 300 of the first opening by a distance w3 longer than the sum of the width w2 of the first opening and the width w1 of the plurality of second openings 202 in the short direction 300 of the first opening 201,
- the step of patterning the substrate 10 with the second light emitting material through the first opening 201 and the plurality of second openings 202 of the mask 200 is repeated, and a plurality of green light emitting layers 33 a and a plurality of green light emitting layers are formed on the substrate 10.
- 33b is formed (FIG. 3G).
- the plurality of first light emitting layers 33a in the longitudinal direction of the first opening 201 are shorter than the width of the first opening 201 in the longitudinal direction of the first opening 201.
- the mask 200 is moved in the longitudinal direction of the first opening 201 by a distance d / 3 that is equal to or larger than the width of the two openings 202.
- a third light-emitting material that emits light having a third spectrum different from the first spectrum and the second spectrum corresponding to blue is mask-deposited through the first opening 201 and the plurality of second openings 202 of the mask 200.
- a pattern is formed with the third light emitting material.
- the mask 200 is moved in the short direction 300 of the first opening by a distance w3 longer than the sum of the width w2 of the first opening and the width w1 of the plurality of second openings 202 in the short direction 300 of the first opening 201.
- a pattern is formed with the third light emitting material through the first opening 201 and the plurality of second openings 202 of the mask 200.
- the movement of the mask 200 in the short direction and the pattern formation of the third light emitting material using the mask 200 are repeated to form a plurality of blue light emitting layers 34a and a plurality of blue light emitting layers 34b on the substrate (FIG. 3H).
- the blue light emitting layer 34a is an example of a “sixth light emitting layer”.
- the blue light emitting layer 34b is an example of a “fifth light emitting layer”.
- a light emitting layer can be formed above the substrate 10.
- a single-layer light-emitting layer that emits single-color light to different regions above the substrate 10 and multi-layer light-emitting that emits multiple colors of light Layers can be formed simultaneously. Therefore, the manufacturing process of the light emitting device can be made efficient and the manufacturing cost of the light emitting device can be suppressed.
- FIG. 4A is a cross-sectional view taken along line AA shown in FIG. 3H of the light emitting device according to the present embodiment.
- FIG. 4B shows a cross-sectional view of the light emitting device according to the present embodiment taken along the line BB shown in FIG. 3H.
- the light emitting device includes a substrate 10, a first electrode layer 20, a light emitting material layer 30, and a second electrode layer 40.
- the light emitting material layer 30 is disposed between the first electrode layer 20 and the second electrode layer 40.
- the light emitting device is a so-called bottom emission type organic EL light emitting device.
- the light emitting device may be a so-called top emission type organic EL light emitting device or a double-sided light extraction type organic EL light emitting device.
- the substrate 10 can be a light-transmitting plate material such as glass or a polymer film.
- the first electrode layer 20 is an anode and may be a transparent conductive film.
- the first electrode layer 20 may be made of a light transmissive conductive material.
- “light transmissive” means having a property of transmitting light.
- the light-transmitting conductive material refers to a material having a property that light transmittance in the visible light region (350 nm to 780 nm) exceeds approximately 50% and a surface resistance value of 10 7 ⁇ or less.
- indium-doped tin oxide ITO
- indium-doped zinc oxide IZO
- tin oxide zinc oxide, or the like
- the first electrode layer 20 is formed, for example, by forming an ITO thin film on the substrate 10 by sputtering, vapor deposition, pulse laser deposition, or the like.
- the first electrode layer 20 has a plurality of first electrodes 22 arranged in a strip shape along the first direction (longitudinal direction of the mask 200).
- the first electrode layer 20 may have one first electrode 22 that is a common electrode.
- the second electrode layer 40 is a cathode and is disposed above the light emitting material layer 30.
- the second electrode layer 40 is formed on the light emitting material layer 30 by a method such as vapor deposition or sputtering using a conductive material such as Al or Ag.
- a conductive material such as Al or Ag.
- the second electrode layer 40 does not need to be light transmissive.
- the second electrode layer 40 is made of a light-transmitting conductive material. In this case, the second electrode layer 40 may be made of the same material as that used for the first electrode layer 20.
- the second electrode layer 40 is disposed on the light emitting material layer 30.
- the second electrode is formed on the outermost surface (interface with the second electrode layer 40) of the light emitting material layer 30 from the viewpoint of suppressing deterioration of each layer constituting the light emitting material layer 30 due to moisture absorption.
- another conductive layer may be formed as a buffer layer.
- the second electrode layer 40 has a plurality of second electrodes 42 arranged in a strip shape along a second direction (short direction of the mask 200) perpendicular to the first direction.
- the drive voltage is applied to each of the plurality of first electrodes 22 and the plurality of second electrodes 42 individually or simultaneously so that the drive voltage is applied to each of the plurality of first electrodes 22 and the plurality of second electrodes 42.
- the light emitting material layer 30 emits light in each region where the first electrode and the second electrode intersect.
- the light emitting material layer 30 is a portion sandwiched between an anode and a cathode in a general organic EL element, and includes an electron injection layer, an electron transport layer, a light emitting layer, a hole injection layer, a hole transport layer, and the like.
- the light emitting material layer 30 may be configured using a thin-film alkali metal or inorganic material in addition to the organic compound.
- the light emitting material layer 30 includes a hole injection layer and a hole transport layer 31, and an electron injection layer and an electron transport layer 35.
- the light emitting material layer 30 includes a red light emitting layer 32a, a green light emitting layer 33a, a blue light emitting layer 34a, or a white light emitting layer 36 between the hole injection layer / hole transport layer 31 and the electron injection layer / electron transport layer 35.
- Have The white light emitting layer 36 includes a red light emitting layer 32b, a green light emitting layer 33b, and a blue light emitting layer 34b.
- the red light emitting layer 32b is formed of a first light emitting material that emits light of the first spectrum corresponding to red.
- the green light-emitting layer 33b has substantially the same shape as the red light-emitting layer 32b when viewed from the cathode side, and is shifted from the red light-emitting layer 32b by a predetermined distance d / 3 in the plane direction from the red light-emitting layer 32b. It is laminated in the range up to the same plane as the light emitting layer 32b, and is formed of a second light emitting material that emits light of the second spectrum.
- the blue light-emitting layer 34b has substantially the same shape as the red light-emitting layer 32b and the green light-emitting layer 33b when viewed from the cathode side, and emits green light with a predetermined distance d / 3 deviation from the green light-emitting layer 33b in the plane direction. It is laminated in the range from the top of the layer 33b to the same plane as the red light emitting layer 32b, and is formed of a third light emitting material that emits light of the third spectrum.
- the red light emitting layer 32a is formed of the first light emitting material in the first light emitting layer region 101 in the same plane as the red light emitting layer 32b.
- the green light emitting layer 33a is formed of the second light emitting material in the second light emitting layer region 102 in the same plane as the red light emitting layer 32a.
- the blue light emitting layer 34a is formed of the third light emitting material in the third light emitting layer region 103 in the same plane as the red light emitting layer 32b.
- the distance between the centers of the red light emitting layer 32a and the green light emitting layer 33a and the intermediate distance between the green light emitting layer 33a and the blue light emitting layer 34a are a predetermined distance d / 3.
- the red light emitting layer 32a and the green light emitting layer 33a are arranged along the longitudinal direction of the red light emitting layer 32b and the green light emitting layer 33b.
- the red light emitting layer 32a and the green light emitting layer 33a are disposed adjacent to a region where the red light emitting layer 32b and the green light emitting layer 33b overlap.
- the blue light emitting layer 34a is disposed alongside the red light emitting layer 32a and the green light emitting layer 33a along the longitudinal direction of the red light emitting layer 32b, the green light emitting layer 33b, and the blue light emitting layer 34b.
- the red light emitting layer 32a, the green light emitting layer 33a, and the blue light emitting layer 34a are disposed adjacent to the region where the red light emitting layer 32b, the green light emitting layer 33b, and the blue light emitting layer 34b overlap.
- the red light emitting layers 32a and 32b, the green light emitting layers 33a and 33b, and the blue light emitting layers 34a and 34b are caused to emit light simultaneously, thereby being irradiated from the respective light emitting layers. It is possible to make a person who has received the light recognize it as being irradiated with white light having a predetermined color temperature.
- the light-emitting device may include a plurality of pixels including a first light-emitting layer region 101, a third light-emitting layer region 103, and a fourth light-emitting layer region 104, as shown in FIG.
- the distance between the centers of the plurality of second openings 202 included in the mask 200 is the distance between the centers of the plurality of first light emitting layer regions 101 or the plurality of third light emitting layer regions 103 as shown in FIG.
- the distance between the centers of the plurality of second openings 202 is the distance between the centers of one first light emitting layer region 101 and one third light emitting layer region 103 adjacent to one first light emitting layer region 101.
- the distance d is twice the distance d / 2.
- the mask 200 may be moved in the longitudinal direction of the first opening 201 by a distance d / 2 that is approximately a half of the distance between the centers of the two second openings.
- the mask 200 includes a plurality of first openings 201 corresponding to a plurality of columns of pixels arranged on the substrate 10 and a plurality of first openings 201 corresponding to the plurality of first openings 201.
- the second opening 202 may be included. According to such a mask 200, the movement of the first opening 201 in the short direction can be reduced. Therefore, the efficiency of the manufacturing process can be further increased.
- the first light emitting layer region 101, the second light emitting layer region 102, and the third light emitting light such as red R or green G blue B other than the large light emitting fourth region 104 that emits white W light.
- the area of the light emitting layer region 101 or the like is not necessarily the same area from the viewpoint of luminous efficiency or light emission efficiency, and even if each light emitting layer is formed with the same area, it corresponds to each light emitting region.
- the area as the light emitting layer region can be adjusted by adjusting the area of the anode or the cathode, that is, the area of the first electrode layer 20 or the second electrode layer 40.
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Abstract
Description
特許文献1 特開2011-165581号公報
特許文献2 特開2010-40529号公報
20 第1電極層
30 発光材料層
32a,32b 赤色発光層
33a,33b 緑色発光層
34a,34b 青色発光層
36 白色発光層
40 第2電極層
101 発光層領域
102 発光層領域
103 発光層領域
104 発光層領域
200 マスク
201 第1開口
202 第2開口
Claims (14)
- 第1開口と、前記第1開口の長手方向に沿って配置されている少なくとも1つの第2開口とを有するマスクを、基板上に配置するマスク配置工程と、
前記マスク配置工程の後に、前記マスクの前記第1開口および前記少なくとも1つの第2開口を介して、第1スペクトルの光を発光する第1発光材料で前記基板上にパターン形成する第1パターン形成工程と、
前記第1パターン形成工程の後に、前記第1開口の長手方向における前記第1開口の幅より短く前記第1開口の長手方向における前記少なくとも1つの第2開口の幅以上の距離だけ、前記第1開口の長手方向に前記マスクを移動させる第1マスク移動工程と、
前記第1マスク移動工程の後に、前記マスクの前記第1開口および前記少なくとも1つの第2開口を介して、前記第1スペクトルとは異なる第2スペクトルの光を発光する第2発光材料で前記基板上にパターン形成する第2パターン形成工程と
を含む発光デバイスの製造方法。 - 前記第1マスク移動工程において、等間隔で配置された前記少なくとも1つの第2開口のうちの隣接する2つの第2開口の中心間距離の略1/2の距離だけ、前記第1開口の長手方向に前記マスクを移動させる請求項1に記載の発光デバイスの製造方法。
- 前記第2パターン形成工程の後に、前記第1開口の長手方向における前記第1開口の幅より短く前記第1開口の長手方向における前記少なくとも1つの第2開口の幅以上の距離だけ、前記第1開口の長手方向に前記マスクを移動させる第2マスク移動工程と、
前記第2マスク移動工程の後に、前記マスクの前記第1開口および前記少なくとも1つの第2開口を介して、前記第1スペクトルおよび前記第2スペクトルとは異なる第3スペクトルの光を発光する第3発光材料でパターン形成する第3パターン形成工程と
をさらに含む請求項1に記載の発光デバイスの製造方法。 - 前記第1マスク移動工程において、前記少なくとも1つの第2開口のうちの隣接する2つの第2開口の中心間距離の略1/3の距離だけ、前記第1開口の長手方向に前記マスクを移動させ、
前記第2マスク移動工程において、前記中心間距離の略1/3の距離だけ、前記第1開口の長手方向に前記マスクを移動させる請求項3に記載の発光デバイスの製造方法。 - 前記第1開口の短手方向における前記第1開口の幅と前記少なくとも1つの第2開口の幅との和より長い距離だけ、前記第1開口の短手方向に前記マスクを移動させる第4マスク移動工程と、
前記第4マスク移動工程の後に、前記マスクの前記第1開口および前記少なくとも1つの第2開口を介して、前記第1発光材料で前記基板上にパターン形成する第4パターン形成工程と
をさらに含む請求項1から4のいずれか一項に記載の発光デバイスの製造方法。 - 前記第4パターン形成工程の後に、前記第1開口の長手方向における前記第1開口の幅より短く前記第1開口の長手方向における前記少なくとも1つの第2開口の幅以上の距離だけ、前記第1開口の長手方向に前記マスクを移動させる第5マスク移動工程と、
前記第5マスク移動工程の後に、前記マスクの前記第1開口および前記少なくとも1つの第2開口を介して、前記第2発光材料で前記基板上にパターン形成する第5パターン形成工程と
をさらに含む請求項5に記載の発光デバイスの製造方法。 - 第1電極層および第2電極層と、
前記第1電極層と前記第2電極層との間に配置されている発光材料層と
を備え、
前記発光材料層は、
第1スペクトルの光を発光する第1発光材料で形成されている第1発光層と、
前記第1発光層と略同一の形状であり、前記第1発光層に対して面方向に予め定められた距離ずれて前記第1発光層上から前記第1発光層と同一面内までの範囲に積層されており、前記第1スペクトルとは異なる第2スペクトルの光を発光する第2発光材料で形成されている第2発光層と
を有する発光デバイス。 - 前記発光材料層は、
前記第1発光層と同一面内の第1領域に、前記第1発光材料で形成されている第3発光層と、
前記第1発光層と同一面内の第2領域に、前記第2発光材料で形成されている第4発光層と
をさらに有し、
前記第3発光層と前記第4発光層との中心間距離は、前記予め定められた距離である請求項7に記載の発光デバイス。 - 前記第3発光層および前記第4発光層は、前記第1発光層および前記第2発光層の長手方向に沿って配置されている請求項8に記載の発光デバイス。
- 前記第3発光層および前記第4発光層は、前記第1発光層と前記第2発光層とが重なっている領域に隣接して配置されている請求項9に記載の発光デバイス。
- 前記発光材料層は、前記第1発光層および前記第2発光層と略同一の形状であり、前記第2発光層に対して前記面方向に前記予め定められた距離ずれて前記第2発光層上から前記第1発光層と同一面内までの範囲に積層されており、前記第1スペクトルおよび前記第2スペクトルとは異なる第3スペクトルの光を発光する第3発光材料で形成されている第5発光層をさらに有する請求項8から10のいずれか一項に記載の発光デバイス。
- 前記発光材料層は、前記第1発光層と同一面内の第3領域に、前記第3発光材料で形成されている第6発光層をさらに有する請求項11に記載の発光デバイス。
- 前記第6発光層は、前記第1発光層、前記第2発光層、および前記第5発光層の長手方向に沿って、前記第3発光層および前記第4発光層と並んで配置されている請求項12に記載の発光デバイス。
- 前記第6発光層は、前記第1発光層と前記第2発光層と前記第5発光層とが重なっている領域に隣接して配置されている請求項13に記載の発光デバイス。
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EP2824995A4 (en) | 2015-10-28 |
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