WO2013104385A1 - Kunststoffbehälter für einen deoroller - Google Patents
Kunststoffbehälter für einen deoroller Download PDFInfo
- Publication number
- WO2013104385A1 WO2013104385A1 PCT/EP2012/004985 EP2012004985W WO2013104385A1 WO 2013104385 A1 WO2013104385 A1 WO 2013104385A1 EP 2012004985 W EP2012004985 W EP 2012004985W WO 2013104385 A1 WO2013104385 A1 WO 2013104385A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plastic container
- receptacle
- cage
- plastic
- roller
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
- A45D34/041—Appliances specially adapted for applying liquid, e.g. using roller or ball using a roller, a disc or a ball
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D33/00—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
- A45D33/02—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances with dispensing means, e.g. sprinkling means
- A45D33/12—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances with dispensing means, e.g. sprinkling means with rollers
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
- A45D40/261—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a ball, a roller or the like
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
Definitions
- the invention relates to a plastic container for a deodorant roller according to the preamble of patent claim 1.
- plastic containers made of white or stained, glass or ceramic are increasingly being replaced by plastic containers.
- plastic containers are used for the packaging of fluid substances, such as beverages, household products, care products, etc.
- the low weight and the lower costs certainly play a significant role in this substitution.
- the use of recyclable plastic materials and the generally more favorable overall energy balance during their production also contribute to promoting consumer acceptance of plastic containers, in particular plastic bottles.
- the usual glass containers are increasingly replaced by those made of plastic.
- a Deoroller consists of a receptacle for a deodorant, which has at its upper, provided with the outlet opening a roller cage for an application ball. The ball is rotatably held in the cage. When screwing the closure, usually a rotary closure, on the receptacle, the ball is pressed against an annular peripheral sealing area and prevents leakage of the deodorant contained inside.
- the gap makes it possible for the portion of the ball wetted with the deodorant to pass to the body site to be treated, for example the armpit, during the rotation of the ball, where it emits a thin deodorant film.
- sealing on the other hand dispensing deodorant, there are relatively high demands on the dimensional accuracy of the cage and the ball.
- the roll cages are therefore manufactured in an injection molding process, which ensures the required accuracy.
- the receptacles were often made of glass, to which the injection-molded plastic roll cage was pressed or screwed.
- deo scooters which have a receptacle made of plastic.
- the plastic container can be produced in a stretch blow molding process or in an extrusion blow molding process.
- the injection-molded roller cage is in turn pressed onto the neck of the receptacle or screwed and welded, for example, additionally for fixing and sealing.
- the roller cage and the receptacle must have exactly matched tying sections, so that tightness problems can be avoided.
- the known Deoroller usually consist of four components, the receptacle, the roll cage, the application ball and the cap, which are each made separately and must be coordinated with each other in terms of dimensional accuracy.
- the logistical effort for the production, storage and merging of the coordinated components of the Deoroller is not insignificant.
- the manufacture of the roll cage by injection molding is relatively complicated and expensive because of the undercut required for the rotatable and at the same time captive retention of the application ball.
- the tool costs for the injection mold for the roller cage and the tool costs for the tool for the production of the receptacle play a significant role.
- even a separate assembly and fixation of the roll cage on the plastic container is required, which increases the cost and cost of the production of deo scooters.
- the solution to these problems consists in a plastic container for a Deoroller having the features listed in claim 1. Further developments and / or advantageous embodiments of the invention are the subject of the dependent claims.
- the invention proposes a plastic container for a deodorant roller which has a receptacle and a roller cage for the captive rotatable mounting of an application ball.
- the roll cage is formed in an extrusion blown from an extruded tube integral with the receptacle. This eliminates the need for separate tools for the production of the roll cage and for the production of the receptacle. For the integrally formed plastic container only a single tool is required, which has an advantageous effect on the tool costs.
- the roll cage is formed integrally with the receptacle for the deodorant, eliminates the assembly step for a separate roll cage. Leakage problems at Anbindeabêten the receptacle and the roller cage can not occur at all.
- the one-piece design also increases the degrees of freedom in terms of the design of the receptacle forming portion of the plastic container and designed as a roll cage section, since not two separately manufactured components must be equipped with coordinated tethers.
- the simplified production and the simplified handling also reduces the costs for producing the plastic container for the deodorant.
- the production of the plastic container with integrally formed receptacle and roll cage in an extrusion blown from an extruded plastic tube is very convenient and inexpensive.
- the extrusion blow molding process in which a single-layer or multi-layer plastic hose is extruded, inserted into a blow mold and finally inflated by a blowing medium introduced with excess pressure according to the blow mold cavity, has been sufficiently tested, can be carried out inexpensively and permits short production cycles.
- the plastic container with integrally formed receptacle and roll cage can be inflated from a continuously or discontinuously extruded plastic tube.
- a continuously extruded plastic tube since the equipment required for this purpose are simpler in construction.
- a stagnation head is eliminated.
- a variant of the extrusion blow-molding process proves to be useful, which is known as the "lost-head method.”
- This "lost-head method” An excess plastic portion is separated in the region of the roll cage by the extrusion blown by cutting. This ensures that the section of the roller cage which is critical for holding the application ball has the required tolerances with regard to dimensional accuracy, wall thickness and rigidity.
- the roller cage is provided at least in this sealing area with an inner layer which is softer than an outer layer of the roller cage.
- an inner layer which is softer than an outer layer of the roller cage.
- the application ball inserted into the roller cage which usually consists of a harder material, for example polypropylene, polyamide, polyethylene terephthalate (PET), etc., produces an adequate seal when pressed against the sealing area of the roller cage.
- the adjacent surface of the roll cage is HDPE, for example.
- the entire roll cage can be designed in one layer and consist of HDPE.
- the sealing area is formed as a circumferential annular shoulder, the contact between the application ball and the ring cage in the sealing area is approximately a line contact. As a result, a relatively low contact pressure is sufficient to achieve a sufficient seal. Due to the formation of a facet or the like in the sealing area, a surface seal between the application ball and the ring cage can be achieved.
- a further embodiment of the invention provides that the plastic container is formed in the region of the roller basket at least two layers.
- the inner layer of the roll cage is softer than its outer layer.
- the inner layer of the roll cage is advantageously made by coextrusion. Coextrusion is particularly used in the extrusion blow molding process to produce multilayer containers or articles. It allows a very exact arrangement and dosing of the additional layer (s) to adjust their wall thickness accurately.
- the inner layer of the roll cage expediently has a hardness which is about 35 Shore to 90 Shore, according to ASTM D-2240 (or to ISO 868 or DIN53505). These hardness values for the inner layer ensure that it is in any case softer than the surface of the application balls used in deo rollers.
- Suitable materials for the inner layer of the roll cage are all extrudable and expandable in a blow molding plastics, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, copolymers and material mixtures containing the above materials are used.
- the hardness properties of the materials used can be adjusted by the addition of plasticizers to the desired extent.
- the plastic container is expediently designed to be multi-layered overall.
- For the outer layer are also all extrudable and in one
- Blowing process expandable plastics such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, co-polymers and material mixtures containing the above materials for use.
- the hardness properties of the materials used can be adjusted to the desired extent by the addition of plasticizers.
- the outer layer has a greater hardness than the inner layer of the roll cage.
- the invention also provides a deodorant roller which has a plastic container equipped according to the invention, which has a roller cage formed in one piece with the receptacle.
- An application ball is rotatable and captive mounted inside the roller cage.
- the deodorant has a closure cap, the height of which is dimensioned such that an extension projecting from an inner side of a cover surface of the closure cap presses against the application ball when it is fastened to the plastic container and seals the receptacle.
- the deodorant roller according to the invention has a smaller number of components, namely the plastic container with receptacle section and roller cage section, the application ball and the closure cap.
- the Deoroller is simpler and cheaper to manufacture.
- the closure cap of Deoreollers is conveniently designed as a rotary closure.
- the rotary closure is designed such that when screwing The cap must be overcome before reaching the end position increased resistance. Due to the increased resistance that he has to overcome when screwing, the user of the Deoroller is signaled that he has sufficiently sealed this.
- the closure cap and / or the plastic container are expediently designed in such a way that a minimum torque of 30 Nm to 250 Nm, preferably 60 Nm to 140 Nm, must be applied for the sealing closure of the plastic container with the closure cap.
- the cap can also be connected via a bayonet connection with the plastic container.
- the invention also extends to a deodorant containing a deodorant.
- Figure 1 is a perspective view of an inventively designed plastic container with a receptacle and an integrally molded roller cage.
- Fig. 2 is an axial sectional view of the plastic container of Fig. 1;
- Fig. 3 is an axial sectional view of a composite Deorollers with screwed cap.
- the plastic container 1 has a receptacle 2 and an integrally molded roller cage 3.
- the section forming the receptacle 2 extends up to a constriction 4.
- a thread 5 is formed on the outside of the region of the receptacle 2 adjoining the constriction 4.
- the roller cage 3 adjoins the constriction 4 and has an approximately spherical segment-shaped or toroidal outer contour.
- annular circulating de shoulder 7 formed at the transition from the roll cage 3 to the constriction 4 is on the inner wall 6 of the rolling cage 3 is an annular circulating de shoulder 7 formed.
- the shoulder 7 borders an opening 8 in the receptacle 2 and forms a sealing area in cooperation with an application ball held in the roller cage 3 (FIG. 3).
- the plastic container 1 with an integrally formed receptacle 2 and roll cage 3 is produced in an extrusion blow molding process.
- a single-layer or multi-layer plastic hose is preferably extruded continuously, inserted into a blow molding tool and finally inflated and demolded by a blowing medium introduced with excess pressure according to the blow mold cavity.
- the roll cage 3 is produced in a so-called "lost-head process.” In the "lost-head process", an excess plastic section in the region of the roll cage 3 is cut off by extrusion following the extrusion blow molding process. This ensures that the critical for the holder of an application ball portion of the rolling cage 3 has the required tolerances in terms of dimensional accuracy, wall thickness and rigidity.
- a layer is provided on the inner wall of the roller cage, which has a lower hardness than the usually usable application balls.
- the entire roll cage 3 and optionally also the receptacle 2 has an inner layer which is usually softer than an outer layer of the plastic container 1.
- a hardness of the inner layer measured according to ASTM Standard D-2240 is about 35 Shore to 90 Shore ,
- Suitable materials for the inner layer of the roll cage 3 are all extrudable and expandable in a blow molding plastics, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, copolymers and material mixtures containing the above materials are used.
- the hardness properties of the materials used can be adjusted by the addition of plasticizers to the desired extent.
- the plastic container 1 is expediently designed to be multi-layered overall.
- For the outer layer are also all extrudable and expandable in a blown plastic materials, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, co-polymers and material mixtures containing the above materials are used.
- the hardness properties of the materials used are by the addition of plasticizers in the desired Circumference adjustable.
- the outer layer usually has a greater hardness than the inner layer of the roll cage 3.
- FIG. 3 shows an axially sectioned representation of a de-scooter, which bears the reference numeral 10 as a whole.
- the deodorant roller 10 according to the invention consists of only three individual components, namely the plastic container 1 with integrally formed receptacle 2 and roller cage 3, an application roller 13 which is rotatably and captively held in the roller cage 3 is, and a closure cap 14, whose internal thread 15 cooperates with the external thread 5 of the plastic container 1.
- the plastic container 1 with integrally formed receptacle 2 and roll cage 3 is manufactured in an extrusion blow molding technology.
- the closure cap 14 embodied as a rotary closure has a height which is dimensioned such that when the closure cap 14 is screwed on, an extension 16 protruding from an inside of a top surface of the closure cap 14 presses against the application ball 13.
- the application ball 13 is pressed against the annular peripheral shoulder 7 and the receptacle is sealed.
- the sealing is also assisted by the fact that the roller cage 3 has a surface or layer at least in the region of the annular peripheral shoulder 7, which is softer than the material of the application ball 13, which is usually made of a harder material, for example polypropylene, polyamide, Polyethylene terephthalate or a polyamide exists.
- a harder material for example polypropylene, polyamide, Polyethylene terephthalate or a polyamide exists.
- the plastic container 1 and / or the closure cap 14 embodied as a rotary closure are designed such that an increased resistance must be overcome when the closure cap 14 is screwed on before reaching the end position.
- an increased resistance must be overcome when the closure cap 14 is screwed on before reaching the end position.
- one or more oversized areas are provided which must be overcome. This gives the user a feedback signal that indicates that the deodorant is now correctly and leak-proof.
- a minimum torque of 30 Nm to 250 Nm, preferably 60 Nm to 140 Nm, must be applied to overcome the increased resistance.
- the invention is not limited to the described embodiment, but also includes equivalent embodiments within the scope of the general inventive concept.
Landscapes
- Containers Having Bodies Formed In One Piece (AREA)
- Closures For Containers (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Packages (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Pens And Brushes (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201280066684.4A CN104203040B (zh) | 2012-01-11 | 2012-12-03 | 用于体香剂走珠的塑料容器 |
BR112014016955A BR112014016955B8 (pt) | 2012-01-11 | 2012-12-03 | Recipiente de plástico para um desodorante roll-on, e, desodorante roll-on |
PL12797718T PL2802235T3 (pl) | 2012-01-11 | 2012-12-03 | Pojemnik z tworzywa sztucznego na dezodorant w kulce |
EP12797718.9A EP2802235B1 (de) | 2012-01-11 | 2012-12-03 | Kunststoffbehälter für einen deoroller |
ES12797718.9T ES2688810T3 (es) | 2012-01-11 | 2012-12-03 | Contenedor de plástico para un desodorante de bola |
RU2014132704A RU2608293C2 (ru) | 2012-01-11 | 2012-12-03 | Пластиковая емкость для шарикового дезодоранта |
MX2014008368A MX347809B (es) | 2012-01-11 | 2012-12-03 | Contenedor de plástico para un rodador de desodorante. |
IN5798DEN2014 IN2014DN05798A (de) | 2012-01-11 | 2014-07-11 | |
US14/329,103 US9456677B2 (en) | 2012-01-11 | 2014-07-11 | Plastic container for a roll-on deodorant |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH00053/12A CH706012A1 (de) | 2012-01-11 | 2012-01-11 | Kunststoffbehälter für einen Deoroller. |
CH00053/12 | 2012-01-11 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/329,103 Continuation US9456677B2 (en) | 2012-01-11 | 2014-07-11 | Plastic container for a roll-on deodorant |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013104385A1 true WO2013104385A1 (de) | 2013-07-18 |
Family
ID=47297103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/004985 WO2013104385A1 (de) | 2012-01-11 | 2012-12-03 | Kunststoffbehälter für einen deoroller |
Country Status (12)
Country | Link |
---|---|
US (1) | US9456677B2 (de) |
EP (1) | EP2802235B1 (de) |
CN (1) | CN104203040B (de) |
AR (1) | AR089689A1 (de) |
BR (1) | BR112014016955B8 (de) |
CH (1) | CH706012A1 (de) |
ES (1) | ES2688810T3 (de) |
IN (1) | IN2014DN05798A (de) |
MX (1) | MX347809B (de) |
PL (1) | PL2802235T3 (de) |
RU (1) | RU2608293C2 (de) |
WO (1) | WO2013104385A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103462347A (zh) * | 2013-10-08 | 2013-12-25 | 苏州新区华士达工程塑胶有限公司 | 多功能便利化妆瓶 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5905297B2 (ja) * | 2012-02-27 | 2016-04-20 | 株式会社パイロットコーポレーション | 筆記具 |
US20170173314A1 (en) * | 2015-12-17 | 2017-06-22 | Shanna NELSON | Nasal applicator |
USD859527S1 (en) * | 2016-11-15 | 2019-09-10 | Crayola Llc | Rollerball marker |
CN109892693A (zh) * | 2017-12-07 | 2019-06-18 | 上海新型烟草制品研究院有限公司 | 一种口服烟烟具 |
US11957229B2 (en) * | 2019-12-09 | 2024-04-16 | Ball Corporation | Metallic roll-on container |
RU199827U1 (ru) * | 2020-02-04 | 2020-09-22 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Астраханский государственный технический университет" (ФГБОУ ВО "АГТУ") | Роликовый контейнер для пищевого ароматизатора |
DE102020113258A1 (de) | 2020-05-15 | 2021-11-18 | QOIS GmbH | Flüssigkeitsdosierroller |
DE102021108267A1 (de) * | 2021-03-31 | 2022-10-06 | Nussbaum Matzingen Ag | Behältnis mit einem Gewinde |
KR102511951B1 (ko) * | 2021-12-29 | 2023-03-20 | 주식회사 태을 | 롤온 형식의 화장품 용기 |
Citations (3)
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WO2000064302A1 (en) * | 1999-04-23 | 2000-11-02 | Unilever Plc | Package for dispensing a flowable cosmetic composition and product |
EP1673998A1 (de) * | 2004-12-23 | 2006-06-28 | L'oreal | Vorrichtung zum Aufbewahren und Auftragen eines kosmetischen Produkts |
WO2009006713A2 (en) * | 2006-03-21 | 2009-01-15 | Leonardo Arcuri Neto | Sealing system for package |
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US4948641A (en) * | 1987-06-01 | 1990-08-14 | Olin Corporation | Multiple layer container for storage of high purity chemicals |
GB9012041D0 (en) * | 1990-05-30 | 1990-07-18 | Beeson & Sons Ltd | Improvements in or relating to containers |
BR9609378A (pt) * | 1995-06-26 | 1999-12-21 | Emery I Valyi | Recipiente de plástico moldado para bebidas e alimentos e processo de fabricação do mesmo. |
DE19953258C2 (de) * | 1999-11-04 | 2003-04-10 | Henkel Kgaa | Vorrichtung zur Ausgabe eines fließfähigen Produktes aus einem Behälter |
MXPA02001429A (es) * | 2002-02-08 | 2003-08-13 | Huerta Benjamin Contreras | Envase con esfera giratoria para la aplicacion de liquidos y proceso de produccion. |
FR2853276B1 (fr) * | 2003-04-02 | 2007-05-18 | Plastohm Sa | Procede de realisation d'une reprise d'air dans un recipient multiparois |
US20070071547A1 (en) * | 2005-09-27 | 2007-03-29 | Graham Packaging Company, L.P. | Tube with ball socket |
EP2337664A4 (de) * | 2008-10-10 | 2012-05-09 | Py Daniel C | Co-extrusionsblasformvorrichtung und verfahren und verschlossene leere vorrichtungen |
DE202013000328U1 (de) * | 2013-01-14 | 2013-01-23 | Jürgen Schmidt | Austragvorrichtung für fließfähige Medien |
-
2012
- 2012-01-11 CH CH00053/12A patent/CH706012A1/de not_active Application Discontinuation
- 2012-12-03 ES ES12797718.9T patent/ES2688810T3/es active Active
- 2012-12-03 CN CN201280066684.4A patent/CN104203040B/zh active Active
- 2012-12-03 WO PCT/EP2012/004985 patent/WO2013104385A1/de active Application Filing
- 2012-12-03 MX MX2014008368A patent/MX347809B/es active IP Right Grant
- 2012-12-03 RU RU2014132704A patent/RU2608293C2/ru active
- 2012-12-03 EP EP12797718.9A patent/EP2802235B1/de active Active
- 2012-12-03 BR BR112014016955A patent/BR112014016955B8/pt active IP Right Grant
- 2012-12-03 PL PL12797718T patent/PL2802235T3/pl unknown
-
2013
- 2013-01-09 AR ARP130100071A patent/AR089689A1/es active IP Right Grant
-
2014
- 2014-07-11 IN IN5798DEN2014 patent/IN2014DN05798A/en unknown
- 2014-07-11 US US14/329,103 patent/US9456677B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000064302A1 (en) * | 1999-04-23 | 2000-11-02 | Unilever Plc | Package for dispensing a flowable cosmetic composition and product |
EP1673998A1 (de) * | 2004-12-23 | 2006-06-28 | L'oreal | Vorrichtung zum Aufbewahren und Auftragen eines kosmetischen Produkts |
WO2009006713A2 (en) * | 2006-03-21 | 2009-01-15 | Leonardo Arcuri Neto | Sealing system for package |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103462347A (zh) * | 2013-10-08 | 2013-12-25 | 苏州新区华士达工程塑胶有限公司 | 多功能便利化妆瓶 |
Also Published As
Publication number | Publication date |
---|---|
US9456677B2 (en) | 2016-10-04 |
US20140321898A1 (en) | 2014-10-30 |
ES2688810T3 (es) | 2018-11-07 |
MX347809B (es) | 2017-05-15 |
MX2014008368A (es) | 2014-10-14 |
EP2802235B1 (de) | 2018-07-25 |
CN104203040B (zh) | 2017-08-04 |
CN104203040A (zh) | 2014-12-10 |
RU2608293C2 (ru) | 2017-01-17 |
PL2802235T3 (pl) | 2018-12-31 |
BR112014016955A8 (pt) | 2017-07-04 |
RU2014132704A (ru) | 2016-02-27 |
IN2014DN05798A (de) | 2015-05-15 |
AR089689A1 (es) | 2014-09-10 |
CH706012A1 (de) | 2013-07-15 |
BR112014016955B1 (pt) | 2021-04-06 |
BR112014016955B8 (pt) | 2022-12-13 |
EP2802235A1 (de) | 2014-11-19 |
BR112014016955A2 (pt) | 2017-06-13 |
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