WO2013073849A1 - 기포력이 우수한 설페이트-프리 샴푸 조성물 - Google Patents

기포력이 우수한 설페이트-프리 샴푸 조성물 Download PDF

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Publication number
WO2013073849A1
WO2013073849A1 PCT/KR2012/009627 KR2012009627W WO2013073849A1 WO 2013073849 A1 WO2013073849 A1 WO 2013073849A1 KR 2012009627 W KR2012009627 W KR 2012009627W WO 2013073849 A1 WO2013073849 A1 WO 2013073849A1
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WO
WIPO (PCT)
Prior art keywords
sulfate
shampoo composition
hydroxysulfane
betaine
surfactant
Prior art date
Application number
PCT/KR2012/009627
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English (en)
French (fr)
Korean (ko)
Inventor
배우리
강병하
이존환
Original Assignee
(주)아모레퍼시픽
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by (주)아모레퍼시픽 filed Critical (주)아모레퍼시픽
Priority to JP2014542235A priority Critical patent/JP2014533683A/ja
Priority to CN201280067407.5A priority patent/CN104244915A/zh
Priority to AU2012337567A priority patent/AU2012337567B2/en
Publication of WO2013073849A1 publication Critical patent/WO2013073849A1/ko

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

Definitions

  • the present invention relates to a sulfate-free shampoo composition that does not contain a sulfate-type surfactant, and more specifically, does not contain a sulfate-based surfactant, so that hair damage or water drainage of hair dye ( It relates to a sulfate-free shampoo composition having a good foaming power, including a sulfane type zwitterionic surfactant while minimizing color omission.
  • the shampoo composition comprises a surfactant as the main component. And additives such as preservatives, paints and the like, the balance of which is composed of water.
  • a surfactant anionic surfactants are basically used for detergency and foaming power, and nonionic surfactants for solubilizing and emulsifying dispersion function may be further used.
  • the surfactant is essentially used a sulfate type (sulfate type).
  • sulfate type is essentially contained as an anionic surfactant.
  • a sulfate system such as ammonium lauryl sulfate, ammonium laureth sulfate, or the Republic of Korea Patent Registration No. 10-0845393
  • sulfate systems such as sodium lauryl sulfate are used.
  • Such a sulfate-based anionic surfactant is useful in shampoo compositions because it is very excellent in detergency and foaming power than other anionic surfactants.
  • the sulfate system has a strong stimulus to promote hair damage, and has a problem of accelerating the water drainage (color loss) of the hair (dyed hair), especially dyed hair with excessive cleaning power.
  • Patent Document 1 Republic of Korea Patent Publication No. 10-2009-0056321
  • Patent Document 2 Republic of Korea Patent No. 10-0845393
  • Patent Document 3 Republic of Korea Patent Publication No. 10-2010-0082931
  • the present invention improves the problems described above, and is a sulfate-free shampoo composition containing no sulfate-based surfactant, and has excellent bubbles while minimizing hair damage or water drainage (color loss) of the dyed hair. It is an object to provide a sulfate-free shampoo composition having a force.
  • a sulfate-free shampoo composition which does not contain a sulfate-based anionic surfactant, the sulfate-free shampoo composition comprising a sulfate-based zwitterionic surfactant having SO 3 ⁇ at the anionic end.
  • the shampoo composition according to the invention further comprises a betaine zwitterionic surfactant having COO ⁇ at the anionic end.
  • the present invention does not contain a sulfate-based, while minimizing hair damage and water drainage (color fall-off) of the dyed hair, including a sulfane-based zwitterionic surfactant has an excellent foaming effect. And when the betaine further comprises a zwitterionic surfactant has the effect of further improving the foaming force.
  • 1 is a graph showing the results of measuring the bubble height of the shampoo composition according to an embodiment of the present invention.
  • the shampoo composition according to the present invention is a sulfate-free composition containing a surfactant as usual as an active ingredient for detergency, and containing no sulfate-based anionic surfactant in the surfactant.
  • the shampoo composition according to the present invention is a new zwitterionic surfactant, and includes at least a sulfur-type zwitterionic surfactant having a SO 3 ⁇ (sulfo group) at an anionic end. According to the present invention, it has excellent foaming force by the sultaine system.
  • the sulfane system is zwitterionic, which is not limited as long as it has SO 3 ⁇ (sulfo group) at the anionic end.
  • Such betaines are preferably Cocamidopropyl Hydroxysultaine, Coco-Hydroxysultaine, Coco-Sultaine, Erucamidopropyl Hydroxyl Erucamidopropyl Hydroxysultaine, Hydroxysultaines, Lauramidopropyl Hydroxysultaine, Lauryl Hydroxysultaine, Lauryl Sultaine, Lauryl Sultaine, Methoxycinamido Methoxycinnamidopropyl Hydroxysultaine, Myristamidopropyl Hydroxysultaine, Oleamidopropyl Hydroxysultaine and Tallowamidopropyl Hydroxysultaine, etc. It is better to use one or more selected from a crowd consisting of.
  • Formula 1 shows the structural formula of Cocamidopropyl Hydroxysultaine among the above-mentioned sulfanes.
  • the sulfane system may be one having SO 3 ⁇ (sulfo group) at an anionic end as in the following Chemical Formula 1.
  • R is hydrogen or a hydrocarbon.
  • R in the formula (1) when R in the formula (1) is a hydrocarbon, it may be selected from, for example, an alkyl group or an aryl group.
  • the salt system is not particularly limited, but may be included in an amount of 1 to 30 wt% based on the total weight of the shampoo composition according to the present invention.
  • the sulfane system is contained in an amount of 5 to 20 wt% based on the total weight of the shampoo composition according to the present invention.
  • the shampoo composition according to the invention preferably further comprises a betaine type (betaine type) as zwitterionic surfactant.
  • the shampoo composition according to the present invention includes at least a sulfane system as described above as an amphoteric ionic surfactant, and further includes a betaine system, and preferably includes a sulfane system and a betaine system at the same time.
  • the foaming force is further improved by the synergy effect.
  • the betaine system is zwitterionic, which is not limited as long as it has COO ⁇ at the anionic end.
  • Such betaines include, for example, cocamidopropyl betaine, coco-betaine, cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethyl-alpha-carboxyethylbetaine, cetyldimethyl-carboxymethylbeta Phosphorus, lauryl-bis- (2-hydroxyethyl) carboxymethylbetaine, stearyl-bis- (2-hydroxypropyl) carboxymethylbetaine, oleyldimethyl-gamma-carboxypropylbetaine, lauryl- Bis- (2-hydroxypropyl) alpha-carboxyethylbetaine, cocodimethylsulfopropylbetaine, stearyldimethylsulfopropylbetaine, cocoamidodimethylcarboxymethylbetaine, coco
  • Formula 2 shows a structural formula of cocamidopropyl betaine among the betaines listed above.
  • the betaine system which can be used in the present invention may be one having COO ⁇ at the anion end as in the following formula (2).
  • R is hydrogen or a hydrocarbon.
  • R in the formula (2) is a hydrocarbon, it may be selected from, for example, an alkyl group or an aryl group.
  • the betaine system is not particularly limited, but may be included in 0.1 to 30% by weight based on the total weight of the shampoo composition according to the present invention. At this time, if the content of the betaine system is less than 0.1% by weight, the synergistic effect of improving the foaming force due to its inclusion may be insignificant. And when the content of betaine exceeds 30% by weight, the synergistic effect of excessive use is not so large and may be undesirable in terms of cost. In consideration of this point, the betaine system is preferably included in 0.5 to 20% by weight based on the total weight of the shampoo composition according to the present invention.
  • the synergistic synergistic effect may have a very good foaming force.
  • the shampoo composition according to the present invention may further include a nonionic surfactant for aiding in cleaning power, solubilization and emulsion dispersion function.
  • the nonionic surfactant is not particularly limited but may be selected from, for example, sorbitan, amides, amines and derivatives thereof.
  • Specific examples of the nonionic surfactants include sorbitan monooleate, sorbitan monolaurate, lauryl diethyl amine oxide, palm oil oil alkyldimethylamine oxide, palm oil fatty acid diethanol amide, palm oil fatty acid monoethanol amide, and cocoamide.
  • diethanol amines and derivatives thereof and the like can be used.
  • Such a nonionic surfactant may be included in an amount of 0.1 to 20% by weight based on the total weight of the shampoo composition according to the present invention.
  • the aid of solubility, solubilization, and emulsion dispersion functions may be insignificant, and when it exceeds 20% by weight, the viscosity may be increased.
  • the shampoo composition according to the present invention may include additives commonly used in the art.
  • it may include one or more additives selected from preservatives, perfumes, pH adjusting agents, viscosity adjusting agents, humectants, conditioning agents and bactericides.
  • additives may be included, for example, within the range of 0.001 to 10% by weight, depending on the type of each additive based on the total weight of the shampoo composition according to the present invention. The remaining amount is water (purified water, etc.).
  • solvents such as alcohols and ketones, herbal extracts, fruit extracts, vitamins and pigments may be further optionally included.
  • the preservative may be selected from methyl paraoxybenzoate, paraoxybenzoate, methyl paraben, methylchloroisothiazolinone, methylisothiazolinone, and the like, and the fragrance may be a natural flavor (fruit flavor, herbal flavor, mint flavor, etc.). ) Or combination fragrance.
  • the pH adjusting agent may be selected from inorganic acids, organic acids and salts thereof, for example, citric acid, sodium citrate, phosphoric acid, sodium phosphate and disodium phosphate.
  • the viscosity modifier may be used cocaamide (CME), geukkoamide (CDE), sodium chloride and ammonium chloride, the moisturizing agent is carboxy vinyl polymer, glycols (propylene glycol, etc.) and oils (natural oil) And animal or vegetable oils).
  • the conditioning agent may be selected from lanolin alcohol, polyoxyethylene lanolin, polyquaternium-7, polyquaternium-10 and ethylene glycol monostearic acid, and the like, and the fungicide is chlorohexadine, triclosan, sulfur and conazole derivatives. And the like.
  • the sulfate-free composition which does not contain the sulfate system as an anionic surfactant, and does not contain the sulfate system, thereby minimizing hair damage and water drainage (color loss) of the dyed hair. And it has excellent foaming power, including a sulfate-based zwitterionic surfactant as an alternative component of the sulfate-based.
  • foaming power including a sulfate-based zwitterionic surfactant as an alternative component of the sulfate-based.
  • the sultaine and the betaine at the same time, it has a very excellent foaming force by the synergistic effect.
  • Example and comparative example of this invention are illustrated.
  • the following examples are illustrative and are provided only to assist in understanding the present invention, and the technical scope of the present invention is not limited thereto.
  • a wash-off type shampoo formulation was prepared with the ingredients and contents as shown in Table 1 below.
  • Example 1 As the anionic surfactant for the cleaning power, dissodium lauryl sulfosuccinate and disodium laureth sulfosuccinate were used in common without using a sulfate system. And in the case of Example 1 was further used sultaine-based (cocamidopropyl hydroxide sulphate), in the case of Example 2 sultaine-based (cocamidopropyl hydroxide sulphate) and betaine (cocamidopropyl betaine) was further used in the same amount. At this time, in the case of the comparative example, betaine (cocamidopropyl betaine) was used instead of the sultaine in order to compare with Example 1. In addition, in order to accurately compare the foaming force, the total amount of the surfactant was equally used by 18% by weight in each Example and Comparative Example.
  • a shampoo diluent of 1% by weight was prepared by mixing the shampoo compositions according to the above Examples and Comparative Examples with tap water.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
PCT/KR2012/009627 2011-11-18 2012-11-15 기포력이 우수한 설페이트-프리 샴푸 조성물 WO2013073849A1 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2014542235A JP2014533683A (ja) 2011-11-18 2012-11-15 泡立ちに優れたサルフェートフリーシャンプー組成物
CN201280067407.5A CN104244915A (zh) 2011-11-18 2012-11-15 具有优异的起泡能力的无硫酸盐洗发剂组合物
AU2012337567A AU2012337567B2 (en) 2011-11-18 2012-11-15 Composition having superior foaming ability for sulfate-free shampoo

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110121104A KR101921630B1 (ko) 2011-11-18 2011-11-18 기포력이 우수한 설페이트-프리 샴푸 조성물
KR10-2011-0121104 2011-11-18

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WO2013073849A1 true WO2013073849A1 (ko) 2013-05-23

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JP (1) JP2014533683A (zh)
KR (1) KR101921630B1 (zh)
CN (1) CN104244915A (zh)
AU (1) AU2012337567B2 (zh)
WO (1) WO2013073849A1 (zh)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103789096A (zh) * 2014-03-10 2014-05-14 天津澳锐泰环保科技有限公司 一种高效环保固型食品级无毒玻璃清洗剂及其制备方法
US11497691B2 (en) 2018-12-14 2022-11-15 The Procter & Gamble Company Shampoo composition comprising sheet-like microcapsules
US11628126B2 (en) 2018-06-05 2023-04-18 The Procter & Gamble Company Clear cleansing composition
US11633072B2 (en) 2021-02-12 2023-04-25 The Procter & Gamble Company Multi-phase shampoo composition with an aesthetic design
US11896689B2 (en) 2019-06-28 2024-02-13 The Procter & Gamble Company Method of making a clear personal care comprising microcapsules
US11932448B2 (en) 2020-02-14 2024-03-19 The Procter & Gamble Company Bottle adapted for storing a liquid composition with an aesthetic design suspended therein
US12053130B2 (en) 2021-02-12 2024-08-06 The Procter & Gamble Company Container containing a shampoo composition with an aesthetic design formed by bubbles

Families Citing this family (9)

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Publication number Priority date Publication date Assignee Title
BR112018015557B1 (pt) * 2016-02-16 2022-03-22 Rhodia Operations Composições de cuidados pessoais aquosa sem sulfato e uso de tais composições
KR101999121B1 (ko) * 2016-04-07 2019-07-11 주식회사 엘지생활건강 기포력 및 안정성이 우수한 저자극성의 인체 세정제 조성물
KR102327219B1 (ko) * 2016-04-07 2021-11-15 주식회사 엘지생활건강 기포력 및 안정성이 우수한 저자극성의 인체 세정제 조성물
US10945935B2 (en) 2016-06-27 2021-03-16 The Procter And Gamble Company Shampoo composition containing a gel network
US20180098923A1 (en) * 2016-10-10 2018-04-12 The Procter & Gamble Company Personal care compositions substantially free of sulfated surfactants and containing a gel network
CN106634930B (zh) * 2016-12-28 2019-04-19 陕西省石油化工研究设计院 一种耐高温高效泡排剂
CN112566700A (zh) * 2018-08-13 2021-03-26 帝斯曼知识产权资产管理有限公司 包含超支化共聚物且不含硫酸酯盐的洗去型化妆品组合物
KR20220154429A (ko) 2021-05-13 2022-11-22 건국대학교 글로컬산학협력단 분꽃(Mirabilis jalapa), 단풍(Acer palmatum) 추출물 등을 포함하는 탈모 예방 및 두피 상태 개선용 설페이트 프리 샴푸 조성물
KR20220159534A (ko) 2021-05-25 2022-12-05 (주)아모레퍼시픽 설페이트-프리 세정제 조성물

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US20060135392A1 (en) * 2004-11-26 2006-06-22 Delphine Ribery Cleansing composition in the form of an aerosol foam without anionic surfactant, and uses in cosmetics
KR20070032338A (ko) * 2004-07-20 2007-03-21 유니레버 엔.브이. 순한 보습 세정 조성물
US20110139170A1 (en) * 2008-08-18 2011-06-16 Thomas Hippe Non-sulfate mild surfactant system for skin and hair cleaning

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KR960014787B1 (ko) * 1991-11-12 1996-10-19 에이치. 드 로이 피부 크린싱 조성물
KR20070032338A (ko) * 2004-07-20 2007-03-21 유니레버 엔.브이. 순한 보습 세정 조성물
US20060135392A1 (en) * 2004-11-26 2006-06-22 Delphine Ribery Cleansing composition in the form of an aerosol foam without anionic surfactant, and uses in cosmetics
US20110139170A1 (en) * 2008-08-18 2011-06-16 Thomas Hippe Non-sulfate mild surfactant system for skin and hair cleaning

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103789096A (zh) * 2014-03-10 2014-05-14 天津澳锐泰环保科技有限公司 一种高效环保固型食品级无毒玻璃清洗剂及其制备方法
US11628126B2 (en) 2018-06-05 2023-04-18 The Procter & Gamble Company Clear cleansing composition
US11497691B2 (en) 2018-12-14 2022-11-15 The Procter & Gamble Company Shampoo composition comprising sheet-like microcapsules
US11896689B2 (en) 2019-06-28 2024-02-13 The Procter & Gamble Company Method of making a clear personal care comprising microcapsules
US11932448B2 (en) 2020-02-14 2024-03-19 The Procter & Gamble Company Bottle adapted for storing a liquid composition with an aesthetic design suspended therein
US11633072B2 (en) 2021-02-12 2023-04-25 The Procter & Gamble Company Multi-phase shampoo composition with an aesthetic design
US12053130B2 (en) 2021-02-12 2024-08-06 The Procter & Gamble Company Container containing a shampoo composition with an aesthetic design formed by bubbles

Also Published As

Publication number Publication date
KR101921630B1 (ko) 2018-11-26
AU2012337567A1 (en) 2014-06-12
AU2012337567B2 (en) 2017-04-20
KR20130055387A (ko) 2013-05-28
CN104244915A (zh) 2014-12-24
JP2014533683A (ja) 2014-12-15

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