WO2013017579A1 - Conditionnement muni d'un bec verseur destiné à des produits pouvant s'écouler - Google Patents

Conditionnement muni d'un bec verseur destiné à des produits pouvant s'écouler Download PDF

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Publication number
WO2013017579A1
WO2013017579A1 PCT/EP2012/064910 EP2012064910W WO2013017579A1 WO 2013017579 A1 WO2013017579 A1 WO 2013017579A1 EP 2012064910 W EP2012064910 W EP 2012064910W WO 2013017579 A1 WO2013017579 A1 WO 2013017579A1
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WO
WIPO (PCT)
Prior art keywords
container
dispensing
opening
deformable
product
Prior art date
Application number
PCT/EP2012/064910
Other languages
English (en)
Inventor
Cyrille Durand
Original Assignee
Nestec S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nestec S.A. filed Critical Nestec S.A.
Priority to EP12740979.5A priority Critical patent/EP2739538A1/fr
Priority to MX2014001266A priority patent/MX340935B/es
Priority to JP2014523300A priority patent/JP2014524872A/ja
Priority to US14/236,570 priority patent/US20140203048A1/en
Priority to CA2842393A priority patent/CA2842393A1/fr
Priority to CN201280038256.0A priority patent/CN103717499B/zh
Publication of WO2013017579A1 publication Critical patent/WO2013017579A1/fr

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/24Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices
    • B65D35/36Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices for applying contents to surfaces
    • B65D35/38Nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/32Containers adapted to be temporarily deformed by external pressure to expel contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/24Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices
    • B65D35/28Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with auxiliary devices for expelling contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/44Closures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/20Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/20Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • B65D47/2018Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/0055Containers or packages provided with a flexible bag or a deformable membrane or diaphragm for expelling the contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2401/00Tamper-indicating means
    • B65D2401/15Tearable part of the closure

Definitions

  • the present invention concerns a container for flowable products, comprising a dispensing spout with openings which prevent leakage when said openings are not closed.
  • liquid or semi-liquid products, having a viscosity below 1 Pa.s at 20°C.
  • the container of the present invention is particularly advantageous for containing edible products.
  • the scope of the present invention is not exclusively limited to such edible products, and can also apply to non-edible products such as fabric and home care products, such as bleach, fabric care liquid products, household detergents.
  • packaging solutions typically comprise containers with a dispensing mouth that is reclosable with a closure elements, like a screw cap for instance.
  • a closure elements like a screw cap for instance.
  • the container is such that when the dispensing mouth is not closed, the contents can be spilled if the container is tilted, or generally if the contents comes in contact with the dispensing mouth. In such case, the contents directly flows out through the dispensing mouth.
  • sports closures comprise a dispensing channel which can be closed easily by pushing a closing element which is generally not detachable from the rest of the closure.
  • Such sports closures are widely know, and different systems are proposed , for instance push-pull closures, hinged closures, etc.
  • Such closures are complex and expensive to manufacture, hence a higher price for the product to the consumer, particularly in case the container is for a nomadic consumption of a product with a limited content volume.
  • they require a large amount of material for their different constitutive parts.
  • one major drawback is that such sports cap leak if the consumer does not close them.
  • valve closures Due to the drawbacks of sports closures, another type of closures was developed which comprise an elastomeric valve, like a slit valve. Such valve closures are reliable and their use in the food packaging industry increases, for instance for packing honey, ketchup, or the like.
  • One particular advantage which is of high importance is that such closures do not necessarily require an additional overcap to seal the valve.
  • the valve itself is sufficiently resilient to reclose after dispensing, so that even if the container is tilted, the contents in contact with the internal surface of the valve does not leak through. This is a clear consumer benefit.
  • the closure body is generally made out of polyethylene or polypropylene
  • the slit valve itself is made of a silicon or other similar resilient material, which must be assembled or co-injected with the closure body.
  • containers which are single-piece flasks made by extrusion-blowing of a thermoplastic such as polyethylene.
  • Such containers comprise a container body, which is manufactured together integrally with a detachable tip. When the tip is torn off by the user, a very tiny dispensing opening is created in the container walls, which allows for dispensing of the contents.
  • Such containers are widely used in the pharmaceutical industry, for providing monodoses (unidoses) for instance for local treatment by a collyrium (i.e. eardrops or eyedrops).
  • collyrium unidoses containers have an advantage that the contents, although liquid or at least very fluid, does not leak through the dispensing opening even if said contents is in contact with the internal surface of the dispensing opening.
  • such a container should allow a sufficient flow rate during dispensing, but at the same time, it should prevent leakage of the contents even when the dispensing opening is not closed by a closure system, and the container is tilted such that the contents is in contact with the internal side of the dispensing opening.
  • a container comprising a deformable container body with at least one compartment, for containing a flowable liquid, semi-liquid, or jellified product having a viscosity lower than 1 Pa.s at 20°C (preferably less than 500 mPa.s, more preferably less than 100 mPa.s), and at least one dispensing opening for dispensing said product, which is located in a spout element, said container having a capacity of at least 1 0ml , preferably at least 50ml , characterized in that the functional cross-section of said at least one opening is fixed and comprised between 0.002 mm 2 and 7 mm 2 , preferably between 0.008 mm 2 and 0.8 mm 2 , more preferably between 0.03 mm 2 and 0.4 mm 2 , and most preferably between 0.07 mm 2 and 0.2 mm 2 , such that said product flows through said opening only after an external force of at least 0.5 kg, preferably at least 1
  • the deformation applied onto the container body surface is expressed as originated from a force exerted thereon, as it is supposed that the pressure applied onto said surface is evenly distributed across said surface.
  • the container comprises a plurality of dispensing openings, whose number is at least 6, preferably at least 12, more preferably at least 18.
  • the container further comprises a closure system associated to said spout element.
  • said closure system advantageously comprises a manually breakable tamper-evident means.
  • Said tamper-evident means can be for instance a laser-scored pre-cutting disposed such that said closure system can be torn-off in order to give access to the container contents through said opening.
  • the deformable container body can be a flexible film pouch, or alternatively it can be a plastic bottle with walls having at least one portion whose thickness is lower than 200 microns, preferably lower than 100 microns.
  • said bottle is preferably made of PET (polyethylene terephtalate) or PEN (polyethylene naphthalate), and manufactured by a stretch blow- moulding process from a PET, respectively a PEN preform.
  • said deformable container body can be a bottle comprising deformable at least one accordion-shaped portion with bellows which can be deformed under force.
  • each of said at least one dispensing opening can take the form of a channel, having a length comprised between 0.1 and 20mm, preferably between 0.5 and 10mm, more preferably between 1 and 7mm.
  • Figure 1 is schematic profile view of a flexible pouch according to the invention
  • Figure 2 is a schematic profile view of a flexible bottle according to the invention.
  • Figure 3 is a schematic top cut view along A-A of figures 1 and 2;
  • Figure 4 is a schematic top cut view similar to figure 3, wherein the dispensing openings have an alternative design to those shown in figure 3,
  • FIGS 5a to 5c are a schematic representation of the closing system
  • Figure 6 represents another embodiment of the closing system.
  • the present invention is directed to a container 1 comprising a dispensing opening that is structured and designed such that:
  • the container 1 as illustrated in figure 1 comprises a deformable container body 2 having one compartment, for containing a flowable liquid, semi-liquid, or jellified product having a viscosity lower than 1 Pa.s at 20°C.
  • the container body shown in figure 1 is a flexible film pouch 2.
  • a spout element 3 is attached to the container pouch body 2.
  • the spout element is an injection moulded element made of a thermoplastic such as polyethylene (PE) or polypropylene (PP).
  • PE polyethylene
  • PP polypropylene
  • the spout element comprises a base which is sealed with the film pouch 2, such that the sealing is leaktight.
  • the spout element 3 comprises a plurality of openi ngs wh ich run through the thickness of said spout, so as to establish a fluid communication between the interior of the pouch, and the exterior.
  • the functional cross-section of the dispensing openings is fixed and comprised between 0.002 mm 2 and 7 mm 2 , preferably between 0.008 mm 2 and 0.8 mm 2 , more preferably between 0.03 mm 2 and 0.4 mm 2 , and most preferably between 0.07 mm 2 and 0.2 mm 2 , such that said product flows through said opening only after an external force of at least 0.5 kg, preferably at least 1 kg, more preferably at least 3 kg, is exerted onto the container body walls which is directed towards the inside of said body.
  • the dispensing openings illustrated in figure 3 are straight channels having a circular functional cross section, and having a length of about 15 mm.
  • the channels can be curved or comprise angled portions.
  • the nu mber of dispensing openings will be chosen accord ing to the viscosity of the product contained in the pouch, and also on the dispensing flow which must be obtained, i.e. depending on the type of use of the contents. For instance the output flow can be slower for viscous products such as culinary sauces for instance, whereas a liquid like mineral water should be able to flow sufficiently rapidly to allow a proper thirst quenching.
  • the number of dispensing openings can be a multiple of six, but not necessarily. In the example illustrated in figure 3, the number of dispensing openings is seven.
  • the container body is a very thin-walled bottle 5 made for instance of a blow-moulded polyethylene terephtalate (PET) material which is obtained by stretch blow-moulding of an injected preform.
  • PET polyethylene terephtalate
  • the bottle walls 6 are flexible and can be deformed by hand squeezing. Therefore, the bottle wall thickness is preferably less than 100 ⁇ .
  • the spout element 3 is clipped, sealed, or similarly attached in a leaktight manner to the bottle body.
  • the material which is used to manufacture the deformable container body is such that flow rates can be obtained which are sufficient to guarantee a proper dispensing of the product to a consumer, and such flow rates values can be obtained by applying a manual force onto the container body walls which is reasonable, i.e. compatible with use of the container by grown-ups, teenagers, adults and elderly people.
  • acceptable flow rates should be comprised within the range of 50-5000 ml/min, preferably 100-1000 ml/min, more preferably 200-500 ml/min.
  • reasonable force to be exerted onto the walls of the container body is defined as follows:
  • minimal force is comprised within the range of 1 -5kgs, preferably within 2-4kgs, more preferably it is set at about 3kgs. With such values, we ensure that for volumes below about 3 litres of very fluid products (e.g. water), flowing does not occur just by gravity, and
  • maximal force is comprised within the range of 20-40kgs, preferably within 25-35kgs, more preferably it is set at about 30kgs. According to tests, 30kgs is a very intense grip to achieve for a teenager or an adult, and certainly not reachable for a baby or a very old person.
  • Forces are measured using testing appliance, method and conditions as follows: the pouch is placed on a flat surface; a force is uniformly applied on the pouch by placing different weights on the support plate.
  • Examples of flow rates, obtained when different forces are applied onto the surface of the container body, are shown in Table 2 below.
  • the product contained in the container body is water, at 20°C (its viscosity is 1 .002 mPa.s).
  • the container body is a flexible pouch having a volume of 250ml, made of a multilayer plastic film having a total thickness of about 150 ⁇ " ⁇ .
  • the dispensing openings have a circular functional cross section (i.e. diameter), similar to the embodiment described above with reference to figure 3.
  • the container 1 is similar to the container described above in reference to figure 3, but for the design of the dispensing openings.
  • the dispensing openings 9 have a non-circular cross section, more particularly a trapezoidal cross section. All openings are disposed in a star-shaped configuration, as can be seen in figure 4, with their short end turned towards the centre of the star.
  • the spout element 3 can be constructed such that it comprises a closing system 7, which closes the dispensing openings 4 at least at the time of manufacture, filling, and during storage. Then, at the time of dispensing the consumer can remove the closing system 7 by tearing it off, by unclipping, unscrewing, or other similar operation as necessary.
  • the closing system 7 is manufactured as an integral distal element of the spout element 3, such that it can be detached along a weakness line 8.
  • the dispensing spout 3 is as shown in figure 3, i.e. with open dispensing openings, ready for dispensing by squeezing the container body.
  • Figures 5a to 5c are presenting a complete view of the spout element meaning a perspective view of the spout element 3 with the closing system 7 as it is once in place on the container (figure 5a), a cross section view of the spout element 3 of figure 5a (figure 5b) and a cross section view of the spout element 3 and closing system 7 of figure 5a once the distal closing system 7 has been broken along its weakness line 8 and showing the dispensing openings 4 (figure 5c).
  • the spout element 3 is manufactured as a two parts component cap having:
  • T h e b i-i njected part is preferably made with Polyethylene (P E) - Polyethylene Terephtalate (PET) but can be made with other material.
  • P E Polyethylene
  • PET Polyethylene Terephtalate
  • the sealing of the spout element on the container is ensured using the elastic properties of the material.
  • the dispensing openings 4 are then accessible and ready for dispensing the product contained in the container to the consumer.
  • the spout element is moulded without any holes to ensure good moulding properties.
  • the holes are made during the assembly step for example by micro perforation with micro needles or using a laser.
  • Figure 6 presents another embodiment of the invention in which the closing system 7 of the spout element 3 is made of a dual laminated lid 12 comprising two layers 13a and 13b.
  • the first layer 13a (top layer) is a peelable layer having protective functions and serves as tamper evidence for the container 1.
  • the first layer 13a has a grasping tab 14 helping in peeling the first layer 13a. This first layer 13a is then defined as the peelable layer.
  • the second layer 13b (bottom layer) is sealed on the container 1 and is perforated with multiples holes as dispensing openings 4.
  • the holes limit the liquid flow of the product as it evacuates out of the container and do not evacuate product under a defined pressure applied on the container.
  • This second layer 13b is then defined as a dispensing layer.
  • the holes are of diameter of 0.2 mm and are spaced from each other of about 1 mm. This is only an example and other diameters can be chosen according to the characteristics of the product to evacuate.
  • the dual laminated lid 12 is sealed on the container neck after it filing and ensures a seal tightness of the packaging.
  • the consumer peels the top layer 13a off, then disclosing the bottom layer 13b which stays on the container's neck and presenting the dispensing openings 4. The product is then ready for consumption.
  • the spout element is meant to be rigid, it could also be envisaged to apply a soft spout element, made of an elastomeric material, or being a spongy material.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Closures For Containers (AREA)
  • Packages (AREA)
  • Bag Frames (AREA)

Abstract

La présente invention concerne un récipient (1) comprenant : un corps de récipient déformable (2) qui est doté d'au moins un compartiment conçu pour contenir un produit liquide, semi-liquide ou gélifié pouvant s'écouler et ayant une viscosité inférieure à 1 Pa.s à 20 °C ; ainsi qu'au moins une ouverture de distribution (4) qui sert à distribuer ledit produit et qui se trouve dans un élément bec verseur (3). Le récipient possède une capacité d'au moins 10 ml, de préférence d'au moins 50 ml, et est caractérisé en ce que la section transversale fonctionnelle de ladite ouverture est fixe et comprise entre 0,002 mm2 et 7 mm2, de préférence entre 0,008 mm2 et 0,8 mm2, plus préférentiellement entre 0,03 mm2 et 0,4 mm2, et idéalement entre 0,07 mm2 et 0,2 mm2, de manière à ce que le produit s'écoule par cette ouverture seulement après qu'une force extérieure d'au moins 0,5 kg, de préférence d'au moins 1 kg, plus préférentiellement d'au moins 3 kg, a été exercée sur les parois du corps de récipient, ladite force étant dirigée vers l'intérieur de ce corps.
PCT/EP2012/064910 2011-08-04 2012-07-31 Conditionnement muni d'un bec verseur destiné à des produits pouvant s'écouler WO2013017579A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP12740979.5A EP2739538A1 (fr) 2011-08-04 2012-07-31 Conditionnement muni d'un bec verseur destiné à des produits pouvant s'écouler
MX2014001266A MX340935B (es) 2011-08-04 2012-07-31 Un envasado con una boquilla para productos capaces de fluir.
JP2014523300A JP2014524872A (ja) 2011-08-04 2012-07-31 注出口を備えた流動性製品用包装
US14/236,570 US20140203048A1 (en) 2011-08-04 2012-07-31 Packaging with a spout for flowable products
CA2842393A CA2842393A1 (fr) 2011-08-04 2012-07-31 Conditionnement muni d'un bec verseur destine a des produits pouvant s'ecouler
CN201280038256.0A CN103717499B (zh) 2011-08-04 2012-07-31 具有用于可流动的产品的管嘴的包装

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11176558.2 2011-08-04
EP11176558A EP2554486A1 (fr) 2011-08-04 2011-08-04 Emballage avec un bec verseur pour produits fluides

Publications (1)

Publication Number Publication Date
WO2013017579A1 true WO2013017579A1 (fr) 2013-02-07

Family

ID=46598526

Family Applications (1)

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PCT/EP2012/064910 WO2013017579A1 (fr) 2011-08-04 2012-07-31 Conditionnement muni d'un bec verseur destiné à des produits pouvant s'écouler

Country Status (7)

Country Link
US (1) US20140203048A1 (fr)
EP (2) EP2554486A1 (fr)
JP (1) JP2014524872A (fr)
CN (1) CN103717499B (fr)
CA (1) CA2842393A1 (fr)
MX (1) MX340935B (fr)
WO (1) WO2013017579A1 (fr)

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EP3074323B1 (fr) * 2013-11-26 2018-06-27 Ecolab USA Inc. Emballage de produit pour un bloc de produit solide
WO2019086262A1 (fr) * 2017-10-30 2019-05-09 Unilever Plc Récipient permettant de mesurer un liquide
FR3085750B1 (fr) * 2018-09-07 2020-11-20 Saipem Sa Procede et dispositif de determination du volume de liquide restant a l'interieur d'une poche souple de distribution de liquide

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MX340935B (es) 2016-08-01
EP2739538A1 (fr) 2014-06-11
CN103717499A (zh) 2014-04-09
CN103717499B (zh) 2016-11-16
EP2554486A1 (fr) 2013-02-06
CA2842393A1 (fr) 2013-02-07
US20140203048A1 (en) 2014-07-24
JP2014524872A (ja) 2014-09-25
MX2014001266A (es) 2014-05-19

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