WO2013015531A2 - Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé - Google Patents

Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé Download PDF

Info

Publication number
WO2013015531A2
WO2013015531A2 PCT/KR2012/005031 KR2012005031W WO2013015531A2 WO 2013015531 A2 WO2013015531 A2 WO 2013015531A2 KR 2012005031 W KR2012005031 W KR 2012005031W WO 2013015531 A2 WO2013015531 A2 WO 2013015531A2
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
manganese oxide
precursor
formula
porous
Prior art date
Application number
PCT/KR2012/005031
Other languages
English (en)
Korean (ko)
Other versions
WO2013015531A3 (fr
Inventor
정강섭
류태공
김병규
류정호
Original Assignee
한국지질자원연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020110072917A external-priority patent/KR101182271B1/ko
Application filed by 한국지질자원연구원 filed Critical 한국지질자원연구원
Priority to US13/640,085 priority Critical patent/US8926874B2/en
Publication of WO2013015531A2 publication Critical patent/WO2013015531A2/fr
Publication of WO2013015531A3 publication Critical patent/WO2013015531A3/fr

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

La présente invention concerne un procédé de fabrication d'un absorbant de lithium à base d'oxyde de manganèse poreux. Le procédé de fabrication dudit absorbant comprend une étape de mélange d'une matière de réaction pour synthétiser des précurseurs de manganèse-lithium avec un liant inorganique afin de préparer un mélange ; une étape de moulage du mélange ; une étape de traitement thermique du mélange moulé pour fabriquer un produit moulé à base du précurseur lithium-manganèse poreux ; et une étape d'acidification du produit moulé à base du précurseur lithium-manganèse poreux pour modifier des ions lithium en ions hydrogène. Lors du processus de traitement thermique, un gaz peut être généré pour former des pores dans le produit moulé à base du précurseur lithium-manganèse. L'absorbant de lithium à base d'oxyde de manganèse poreux selon la présente invention peut être facilement manipulé et engendre plus de sites de réaction d'absorption qu'un absorbant moulé existant pour améliorer l'efficacité d'absorption du lithium.
PCT/KR2012/005031 2011-04-28 2012-06-26 Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé WO2013015531A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/640,085 US8926874B2 (en) 2011-04-28 2012-06-26 Porous manganese oxide absorbent for lithium having spinel type structure and a method of manufacturing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0072917 2011-07-22
KR1020110072917A KR101182271B1 (ko) 2011-04-28 2011-07-22 스피넬형 구조를 갖는 다공성 망간산화물계 리튬 흡착제 및 그 제조방법

Publications (2)

Publication Number Publication Date
WO2013015531A2 true WO2013015531A2 (fr) 2013-01-31
WO2013015531A3 WO2013015531A3 (fr) 2013-03-21

Family

ID=47602057

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/005031 WO2013015531A2 (fr) 2011-04-28 2012-06-26 Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé

Country Status (1)

Country Link
WO (1) WO2013015531A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015116551A (ja) * 2013-12-19 2015-06-25 国立研究開発法人産業技術総合研究所 リチウム回収剤用リチウムマンガン鉄複合酸化物及びそれからなるリチウム回収剤、並びに該リチウム回収剤を用いたリチウム回収方法
US10757481B2 (en) 2012-04-03 2020-08-25 Activevideo Networks, Inc. Class-based intelligent multiplexing over unmanaged networks
CN112473616A (zh) * 2020-11-04 2021-03-12 中国科学院青海盐湖研究所 多孔C-MnOx/Sn-Al-H2TiO3离子筛、其制备方法及应用
EP4134159A4 (fr) * 2021-06-30 2023-12-13 Sumitomo Metal Mining Co., Ltd. Procédé de fabrication d'un corps granulé pour adsorption de lithium

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198081A (en) * 1991-03-04 1993-03-30 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Method and electrode for electrochemical recovery of lithium value from aqueous solution
KR100536957B1 (ko) * 2003-11-10 2005-12-14 한국지질자원연구원 허니컴 형태의 이온 교환형 리튬-망간산화물 흡착제 및그의 제조 방법
KR20080045626A (ko) * 2006-11-20 2008-05-23 한국지질자원연구원 세라믹 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법
KR100972140B1 (ko) * 2006-11-20 2010-07-23 한국지질자원연구원 가수분해 및 용매교환법에 의한 리튬 망간 산화물의제조방법 및 상기 리튬 망간 산화물을 이용한 이온교환형리튬 흡착제 제조 방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198081A (en) * 1991-03-04 1993-03-30 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Method and electrode for electrochemical recovery of lithium value from aqueous solution
KR100536957B1 (ko) * 2003-11-10 2005-12-14 한국지질자원연구원 허니컴 형태의 이온 교환형 리튬-망간산화물 흡착제 및그의 제조 방법
KR20080045626A (ko) * 2006-11-20 2008-05-23 한국지질자원연구원 세라믹 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법
KR100972140B1 (ko) * 2006-11-20 2010-07-23 한국지질자원연구원 가수분해 및 용매교환법에 의한 리튬 망간 산화물의제조방법 및 상기 리튬 망간 산화물을 이용한 이온교환형리튬 흡착제 제조 방법

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10757481B2 (en) 2012-04-03 2020-08-25 Activevideo Networks, Inc. Class-based intelligent multiplexing over unmanaged networks
JP2015116551A (ja) * 2013-12-19 2015-06-25 国立研究開発法人産業技術総合研究所 リチウム回収剤用リチウムマンガン鉄複合酸化物及びそれからなるリチウム回収剤、並びに該リチウム回収剤を用いたリチウム回収方法
CN112473616A (zh) * 2020-11-04 2021-03-12 中国科学院青海盐湖研究所 多孔C-MnOx/Sn-Al-H2TiO3离子筛、其制备方法及应用
CN112473616B (zh) * 2020-11-04 2022-05-31 中国科学院青海盐湖研究所 多孔C-MnOx/Sn-Al-H2TiO3离子筛、其制备方法及应用
EP4134159A4 (fr) * 2021-06-30 2023-12-13 Sumitomo Metal Mining Co., Ltd. Procédé de fabrication d'un corps granulé pour adsorption de lithium

Also Published As

Publication number Publication date
WO2013015531A3 (fr) 2013-03-21

Similar Documents

Publication Publication Date Title
WO2012148040A1 (fr) Adsorbant de lithium à base d'oxyde de manganèse poreux à structure de spinelle et son procédé de fabrication
WO2013002486A2 (fr) Procédé de préparation d'oxydes de manganèse et de lithium par réaction à l'état solide
Xu et al. Study on the annealing phase transformation mechanism and electrochemical properties of carbon submicron fibers loaded with cobalt
Zheng et al. Facile synthesis of MOF-derived Mn 2 O 3 hollow microspheres as anode materials for lithium-ion batteries
WO2016032221A1 (fr) Procédé de préparation de matériau carboné dopé par des hétéroéléments à partir de gaz de fumée contenant du dioxyde de carbone
CN108328706A (zh) 一种mof衍生多孔碳/石墨烯复合电极材料的制备及应用
WO2013015531A2 (fr) Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé
WO2013055135A2 (fr) Procédé de production d'une structure de carbone mésoporeuse
Cai et al. Facile preparation of porous one-dimensional Mn2O3 nanostructures and their application as anode materials for lithium-ion batteries
CN110024175A (zh) 非水电解质电池用无机颗粒及使用其的非水电解质电池
KR100536957B1 (ko) 허니컴 형태의 이온 교환형 리튬-망간산화물 흡착제 및그의 제조 방법
CN115818638A (zh) 一种氮硫掺杂的分级多孔碳及其制备方法
WO2013141487A1 (fr) Procédé de production continue d'oxygène et dispositif d'adsorption et de désorption d'oxygène continu utilisant un agent d'adsorption d'oxygène
WO2014003363A1 (fr) Oxyde composite de lithium-manganèse, précurseur pour un adsorbant de lithium-manganèse, son procédé de préparation, et adsorbant de lithium l'utilisant
WO2019093660A2 (fr) Procédé de fabrication de maghémite
WO2016101315A1 (fr) Procédé de réparation de précurseur de matériau de pile ternaire nickel-cobalt-manganèse
WO2024096397A1 (fr) Matériau d'électrode négative composite silicium-graphène et son procédé de fabrication
KR100557824B1 (ko) 우레탄 발포제를 이용한 이온 교환형 리튬-망간산화물흡착제 및 그의 제조 방법
KR100972140B1 (ko) 가수분해 및 용매교환법에 의한 리튬 망간 산화물의제조방법 및 상기 리튬 망간 산화물을 이용한 이온교환형리튬 흡착제 제조 방법
WO2014069699A1 (fr) Particule de bille absorbante pour récupérer du lithium poreux par carbonisation, et procédé de préparation de celle-ci
CN109786709B (zh) 一种四氧化三铁/碳复合负极材料及其制备方法和用途
WO2020013488A1 (fr) Procédé de préparation d'oxyde de fer
CN106450183B (zh) 一种千层岩结构二硫化钨/碳纳米复合材料及其制备方法与应用
WO2018212374A1 (fr) Matériau actif d'électrode, son procédé de fabrication et batterie secondaire au lithium le comprenant
KR100896054B1 (ko) 세라믹 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 13640085

Country of ref document: US

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12816986

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12816986

Country of ref document: EP

Kind code of ref document: A2