WO2013015531A3 - Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé - Google Patents

Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé Download PDF

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Publication number
WO2013015531A3
WO2013015531A3 PCT/KR2012/005031 KR2012005031W WO2013015531A3 WO 2013015531 A3 WO2013015531 A3 WO 2013015531A3 KR 2012005031 W KR2012005031 W KR 2012005031W WO 2013015531 A3 WO2013015531 A3 WO 2013015531A3
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
porous
absorbent
manganese oxide
manganese
Prior art date
Application number
PCT/KR2012/005031
Other languages
English (en)
Korean (ko)
Other versions
WO2013015531A2 (fr
Inventor
정강섭
류태공
김병규
류정호
Original Assignee
한국지질자원연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020110072917A external-priority patent/KR101182271B1/ko
Application filed by 한국지질자원연구원 filed Critical 한국지질자원연구원
Priority to US13/640,085 priority Critical patent/US8926874B2/en
Publication of WO2013015531A2 publication Critical patent/WO2013015531A2/fr
Publication of WO2013015531A3 publication Critical patent/WO2013015531A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne un procédé de fabrication d'un absorbant de lithium à base d'oxyde de manganèse poreux. Le procédé de fabrication dudit absorbant comprend une étape de mélange d'une matière de réaction pour synthétiser des précurseurs de manganèse-lithium avec un liant inorganique afin de préparer un mélange ; une étape de moulage du mélange ; une étape de traitement thermique du mélange moulé pour fabriquer un produit moulé à base du précurseur lithium-manganèse poreux ; et une étape d'acidification du produit moulé à base du précurseur lithium-manganèse poreux pour modifier des ions lithium en ions hydrogène. Lors du processus de traitement thermique, un gaz peut être généré pour former des pores dans le produit moulé à base du précurseur lithium-manganèse. L'absorbant de lithium à base d'oxyde de manganèse poreux selon la présente invention peut être facilement manipulé et engendre plus de sites de réaction d'absorption qu'un absorbant moulé existant pour améliorer l'efficacité d'absorption du lithium.
PCT/KR2012/005031 2011-04-28 2012-06-26 Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé WO2013015531A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/640,085 US8926874B2 (en) 2011-04-28 2012-06-26 Porous manganese oxide absorbent for lithium having spinel type structure and a method of manufacturing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0072917 2011-07-22
KR1020110072917A KR101182271B1 (ko) 2011-04-28 2011-07-22 스피넬형 구조를 갖는 다공성 망간산화물계 리튬 흡착제 및 그 제조방법

Publications (2)

Publication Number Publication Date
WO2013015531A2 WO2013015531A2 (fr) 2013-01-31
WO2013015531A3 true WO2013015531A3 (fr) 2013-03-21

Family

ID=47602057

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/005031 WO2013015531A2 (fr) 2011-04-28 2012-06-26 Absorbant au lithium à base d'oxyde de manganèse poreux possédant une structure de type spinelle, et procédé de fabrication associé

Country Status (1)

Country Link
WO (1) WO2013015531A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9800945B2 (en) 2012-04-03 2017-10-24 Activevideo Networks, Inc. Class-based intelligent multiplexing over unmanaged networks
JP2015116551A (ja) * 2013-12-19 2015-06-25 国立研究開発法人産業技術総合研究所 リチウム回収剤用リチウムマンガン鉄複合酸化物及びそれからなるリチウム回収剤、並びに該リチウム回収剤を用いたリチウム回収方法
CN112473616B (zh) * 2020-11-04 2022-05-31 中国科学院青海盐湖研究所 多孔C-MnOx/Sn-Al-H2TiO3离子筛、其制备方法及应用
JP2023006193A (ja) * 2021-06-30 2023-01-18 住友金属鉱山株式会社 リチウム吸着用造粒体の製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198081A (en) * 1991-03-04 1993-03-30 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Method and electrode for electrochemical recovery of lithium value from aqueous solution
KR100536957B1 (ko) * 2003-11-10 2005-12-14 한국지질자원연구원 허니컴 형태의 이온 교환형 리튬-망간산화물 흡착제 및그의 제조 방법
KR20080045626A (ko) * 2006-11-20 2008-05-23 한국지질자원연구원 세라믹 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법
KR100972140B1 (ko) * 2006-11-20 2010-07-23 한국지질자원연구원 가수분해 및 용매교환법에 의한 리튬 망간 산화물의제조방법 및 상기 리튬 망간 산화물을 이용한 이온교환형리튬 흡착제 제조 방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198081A (en) * 1991-03-04 1993-03-30 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Method and electrode for electrochemical recovery of lithium value from aqueous solution
KR100536957B1 (ko) * 2003-11-10 2005-12-14 한국지질자원연구원 허니컴 형태의 이온 교환형 리튬-망간산화물 흡착제 및그의 제조 방법
KR20080045626A (ko) * 2006-11-20 2008-05-23 한국지질자원연구원 세라믹 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법
KR100972140B1 (ko) * 2006-11-20 2010-07-23 한국지질자원연구원 가수분해 및 용매교환법에 의한 리튬 망간 산화물의제조방법 및 상기 리튬 망간 산화물을 이용한 이온교환형리튬 흡착제 제조 방법

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