WO2012128470A3 - Film en fibres creuses à base de polysulfone présentant une très grande résistance et une très bonne perméabilité à l'eau, et son procédé de fabrication - Google Patents
Film en fibres creuses à base de polysulfone présentant une très grande résistance et une très bonne perméabilité à l'eau, et son procédé de fabrication Download PDFInfo
- Publication number
- WO2012128470A3 WO2012128470A3 PCT/KR2012/000789 KR2012000789W WO2012128470A3 WO 2012128470 A3 WO2012128470 A3 WO 2012128470A3 KR 2012000789 W KR2012000789 W KR 2012000789W WO 2012128470 A3 WO2012128470 A3 WO 2012128470A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polysulfone
- hollow fiber
- fiber film
- surface layer
- based hollow
- Prior art date
Links
- 229920002492 poly(sulfone) Polymers 0.000 title abstract 5
- 239000012510 hollow fiber Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000035699 permeability Effects 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 4
- 239000002344 surface layer Substances 0.000 abstract 4
- 238000009987 spinning Methods 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 239000000701 coagulant Substances 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 230000015271 coagulation Effects 0.000 abstract 1
- 238000005345 coagulation Methods 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000004804 winding Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
- B01D69/087—Details relating to the spinning process
- B01D69/0871—Fibre guidance after spinning through the manufacturing apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
- B01D69/087—Details relating to the spinning process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/02—Hydrophilization
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/026—Sponge structure
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Artificial Filaments (AREA)
Abstract
La présente invention concerne un film en fibres creuses à base de polysulfone comportant 20 à 25 % en poids d'une résine de polysulfone (A), 45 à 55 % en poids d'un solvant organique (B) et 30 à 35 % en poids d'un additif hydrophile (C), ledit film en fibres creuses présentant une structure spongieuse asymétrique, dans laquelle la taille des pores augmente sans interruption en allant d'une couche superficielle extérieure vers une couche superficielle intérieure, le rapport entre la taille des pores de la couche superficielle extérieure et celle de la couche superficielle intérieure variant de 1/10 à 1/10 000. L'invention concerne également un procédé de fabrication dudit film en fibres creuses à base de polysulfone comprenant les étapes consistant à préparer une solution non diluée de filage contenant une résine à base de polysulfone (A), un solvant organique (B) et un additif hydrophile (C) ; à préparer un coagulant interne ; à filer la solution non diluée de filage et le coagulant interne ; à former des pores ; et à procéder à un bobinage, l'étape de formation des pores étant achevée lorsque le temps de séjour total dans le bain de coagulation et le bain de lavage dépasse 90 secondes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020110024302A KR101077954B1 (ko) | 2011-03-18 | 2011-03-18 | 강도 및 수투과도가 우수한 폴리설폰계 중공사막 및 그 제조방법 |
KR10-2011-0024302 | 2011-03-18 |
Publications (4)
Publication Number | Publication Date |
---|---|
WO2012128470A2 WO2012128470A2 (fr) | 2012-09-27 |
WO2012128470A3 true WO2012128470A3 (fr) | 2012-11-15 |
WO2012128470A4 WO2012128470A4 (fr) | 2013-01-03 |
WO2012128470A9 WO2012128470A9 (fr) | 2013-02-28 |
Family
ID=45033570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2012/000789 WO2012128470A2 (fr) | 2011-03-18 | 2012-02-01 | Film en fibres creuses à base de polysulfone présentant une très grande résistance et une très bonne perméabilité à l'eau, et son procédé de fabrication |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR101077954B1 (fr) |
WO (1) | WO2012128470A2 (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101483740B1 (ko) * | 2013-06-04 | 2015-01-16 | 주식회사 에코니티 | 비대칭성 폴리비닐리덴플루오라이드 중공사막의 제조방법 및 이로부터 제조된 중공사막 |
KR102160309B1 (ko) * | 2013-12-30 | 2020-09-25 | 도레이첨단소재 주식회사 | 이온 제거능이 우수한 중공사형 나노분리막 및 이의 제조방법 |
KR101763991B1 (ko) * | 2014-09-22 | 2017-08-02 | 주식회사 휴비스워터 | 강도 및 수투과도가 향상된 중공사막 방사용 조성물 및 이를 이용한 중공사막의 제조방법 |
KR101665189B1 (ko) * | 2014-10-02 | 2016-10-24 | 주식회사 휴비스워터 | 내화학성이 우수한 폴리설폰계 중공사막 및 이의 제조방법 |
KR101689440B1 (ko) * | 2014-10-31 | 2016-12-23 | 주식회사 휴비스워터 | 건식 중공사막, 이의 제조방법 및 이를 포함하는 수처리 모듈 |
KR101723904B1 (ko) * | 2014-11-05 | 2017-04-06 | 주식회사 휴비스워터 | 공정효율이 향상된 중공사막의 제조방법 및 방사설비 |
CN113877443B (zh) * | 2021-11-05 | 2024-01-26 | 无锡达魔材料科技有限公司 | 一种制备表皮致密层无缺陷的具有非对称结构的气体分离用中空纤维膜纺丝方法 |
CN113926316B (zh) * | 2021-11-23 | 2024-01-26 | 江苏巨澜纳米科技有限公司 | 一种防漏增湿复合中空纤维膜、制备方法及其应用 |
CN114653219A (zh) * | 2022-04-22 | 2022-06-24 | 佛山市美的清湖净水设备有限公司 | 制备铸膜液的方法、用于制备超滤膜的铸膜液、超滤膜 |
CN115400616B (zh) * | 2022-11-01 | 2023-02-03 | 富海(东营)新材料科技有限公司 | 连续一体化聚砜中空纤维膜的制备工艺及其系统 |
CN115814621B (zh) * | 2022-12-26 | 2023-08-29 | 有研资源环境技术研究院(北京)有限公司 | 一种高强度亲水型中空纤维膜及其制备方法和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001038171A (ja) * | 1999-08-03 | 2001-02-13 | Toyobo Co Ltd | 中空糸膜 |
US6486240B1 (en) * | 1998-10-28 | 2002-11-26 | Korea Institute Of Science And Technology | Method for producing an asymmetric support membrane by physical gelation and the membranes obtained thereby |
JP2004525755A (ja) * | 2001-01-23 | 2004-08-26 | アマシャム・バイオサイエンス・メムブレイン・セパレイションズ・コーポレイション | アシンメトリー中空ファイバー膜 |
KR20090009308A (ko) * | 2006-05-06 | 2009-01-22 | 멤브라나 게엠베하 | 한외여과막 |
KR20090072321A (ko) * | 2007-12-28 | 2009-07-02 | 주식회사 파라 | 수투과성이 향상된 폴리술폰계 중공사막 및 그 제조방법 |
KR101007956B1 (ko) * | 2002-12-20 | 2011-01-14 | 감브로 룬디아 아베 | 선택투과성 막 및 이것의 제조 방법 |
-
2011
- 2011-03-18 KR KR1020110024302A patent/KR101077954B1/ko active IP Right Grant
-
2012
- 2012-02-01 WO PCT/KR2012/000789 patent/WO2012128470A2/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6486240B1 (en) * | 1998-10-28 | 2002-11-26 | Korea Institute Of Science And Technology | Method for producing an asymmetric support membrane by physical gelation and the membranes obtained thereby |
JP2001038171A (ja) * | 1999-08-03 | 2001-02-13 | Toyobo Co Ltd | 中空糸膜 |
JP2004525755A (ja) * | 2001-01-23 | 2004-08-26 | アマシャム・バイオサイエンス・メムブレイン・セパレイションズ・コーポレイション | アシンメトリー中空ファイバー膜 |
KR101007956B1 (ko) * | 2002-12-20 | 2011-01-14 | 감브로 룬디아 아베 | 선택투과성 막 및 이것의 제조 방법 |
KR20090009308A (ko) * | 2006-05-06 | 2009-01-22 | 멤브라나 게엠베하 | 한외여과막 |
KR20090072321A (ko) * | 2007-12-28 | 2009-07-02 | 주식회사 파라 | 수투과성이 향상된 폴리술폰계 중공사막 및 그 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
WO2012128470A9 (fr) | 2013-02-28 |
WO2012128470A2 (fr) | 2012-09-27 |
WO2012128470A4 (fr) | 2013-01-03 |
KR101077954B1 (ko) | 2011-10-28 |
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