WO2012127811A1 - 鋼管の焼入方法 - Google Patents
鋼管の焼入方法 Download PDFInfo
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- WO2012127811A1 WO2012127811A1 PCT/JP2012/001708 JP2012001708W WO2012127811A1 WO 2012127811 A1 WO2012127811 A1 WO 2012127811A1 JP 2012001708 W JP2012001708 W JP 2012001708W WO 2012127811 A1 WO2012127811 A1 WO 2012127811A1
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- C—CHEMISTRY; METALLURGY
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2221/00—Treating localised areas of an article
Definitions
- the present invention relates to a method for quenching steel pipes made of medium and high carbon content steel, and more specifically, conventionally, it is said that quenching is likely to occur when quenching is performed by quenching means such as water quenching.
- quenching means such as water quenching.
- -It is related with the hardening method of the steel pipe which can prevent the quench crack of the steel pipe of a high carbon low alloy steel and medium alloy steel, or a martensitic stainless steel pipe.
- % Represents the mass percentage of each component contained in the object such as medium / high carbon content steel, martensitic stainless steel, etc.
- Low alloy steel Here, steel having a total alloy component content of 5% or less.
- Medium alloy steel Here, steel having a total amount of alloy components of more than 5% and 10% or less.
- a method using a phase transformation by heat treatment, particularly a martensitic transformation is widely performed.
- Strengthening steel materials by quenching and tempering because steel pipes (generally steel tubes made of low-alloy steel or medium-alloy steel) made of medium-carbon steel or high-carbon steel exhibit excellent strength and toughness.
- the method has been used as a material strengthening method in many applications such as mechanical structural members and oil well steel.
- the strength of the steel can be remarkably increased by quenching, and this strength improvement effect depends on the C content in the steel.
- as-quenched martensite structure is generally brittle
- toughness is improved by tempering at a temperature below the Ac1 transformation point after quenching.
- the steel material to be quenched is in the shape of a steel pipe, it exhibits an extremely complicated stress state as compared with the case of a steel plate shape product or a bar / wire product. For this reason, when a steel pipe-shaped product having a high C content is subjected to a quenching treatment such as water quenching, the sensitivity to fire cracking is remarkably increased, causing frequent cracking, resulting in a very low product yield.
- martensitic structures are used in low alloy steels and medium alloy steel pipes.
- martensitic stainless steel pipes that can easily obtain high strength are required to have strength and corrosion resistance. It is widely used for various applications.
- martensitic stainless steel pipes have been widely used as oil well pipes for oil and natural gas extraction due to energy circumstances.
- martensitic stainless steel does not have sufficient resistance to sulfide stress corrosion cracking due to hydrogen sulfide in some cases, but has excellent resistance to carbon dioxide corrosion. Therefore, it is widely used in an environment containing relatively low temperature wet carbon dioxide.
- a typical example is an oil well pipe of L80 grade 13Cr type (Cr content: 12 to 14%) defined by API (American Petroleum Institute).
- martensitic stainless steel has been subjected to quenching and tempering treatment, and the above APIL80 grade 13Cr steel is no exception.
- the martensitic transformation start temperature (Ms point) of the 13Cr steel is about 300 ° C., which is lower than that of the low alloy steel.
- Ms point martensitic transformation start temperature
- this method has a problem that although the cracking can be prevented, the cooling rate is small and the productivity is low, and various properties such as resistance to sulfide stress corrosion cracking are deteriorated.
- Patent Document 1 As a quenching method for preventing quench cracking of a steel pipe containing 0.2 to 1.2% of C, cooling in quenching is performed only from the inner surface of the steel pipe. A method of quenching a medium / high carbon content steel pipe characterized by rotating the steel pipe is disclosed.
- Patent Document 2 discloses a method of manufacturing a steel pipe having a martensite-based structure by quenching and tempering a Cr-based stainless steel pipe containing 0.1 to 0.3% C and 11.0 to 15.0% Cr.
- quenching is performed at an average cooling rate in the temperature range from the Ms point to the Mf point (martensitic transformation completion temperature) at 8 ° C./second or more and then tempering. Is disclosed. By ensuring the cooling rate, formation of retained austenite can be prevented, and a martensite-based structure can be obtained.
- Patent Document 2 requires cooling only from the inner surface of the steel pipe and, if necessary, rotating the steel pipe in order to prevent quench cracking even in a quenching process such as water quenching. Therefore, in industrialization, there is a problem similar to that in the quenching method described in Patent Document 1.
- Patent Document 3 in the quenching of a stainless steel pipe containing C: 0.1 to 0.3% and Cr: 11 to 15%, the outer surface temperature is lower than [Ms point ⁇ 30 ° C.] from the quenching start temperature [ Intermediate temperature between Ms point and Mf point]
- the first cooling that is air-cooled to an arbitrary temperature higher than the Ms point and the temperature range until the outer surface temperature subsequently falls below the Mf point is 8 ° C.
- a method of manufacturing a martensitic stainless steel pipe that performs two-stage cooling comprising second cooling that strongly cools the outer surface of the pipe so as to be more than 1 second, makes 80% or more of the structure martensite, and then tempers. It is disclosed.
- Patent Document 4 as a method for producing a seamless steel pipe of C: 0.30 to 0.60% medium / high carbon low alloy steel, it is immediately cooled to 400 to 600 ° C. after rolling.
- a method of performing isothermal transformation heat treatment (austempering) in a furnace heated to 400 to 600 ° C. after stopping water cooling is disclosed.
- the structure of the steel pipe manufactured by the isothermal transformation heat treatment described in Patent Document 4 is generally bainite having a lower strength than martensite, and it may be difficult to cope with the case where high strength is required.
- JP-A-9-104925 Japanese Laid-Open Patent Publication No. 8-18827 Japanese Laid-Open Patent Publication No. 10-17934 Japanese Laid-Open Patent Publication No. 2006-265657
- martensite when manufacturing martensitic stainless steel pipes, martensite can be formed even if the quenching cooling rate is low, but the productivity is poor due to the slow cooling rate, including resistance to sulfide stress corrosion cracking. Various characteristics deteriorate. If water quenching is performed to increase productivity, quench cracking occurs.
- the present invention has been made in view of such problems, and it is possible to prevent fire cracking in a medium / high carbon content steel pipe (mainly a steel pipe of low alloy steel or medium alloy steel), or a martensitic stainless steel pipe. It aims at providing the hardening method of the steel pipe which can be performed.
- a medium / high carbon content steel pipe mainly a steel pipe of low alloy steel or medium alloy steel
- a martensitic stainless steel pipe aims at providing the hardening method of the steel pipe which can be performed.
- the gist of the present invention is as follows. (1) A quenching method in which a steel pipe is quenched by water cooling from the outer surface, and at least a part of the portion other than the pipe end is water cooled without water cooling of the pipe end. How to enter.
- a medium or high carbon content steel pipe (mainly a low alloy steel or a medium alloy steel pipe) or a Cr-based stainless steel pipe is rapidly cooled without causing cracking (water Quenching can be performed.
- a high-strength steel pipe having a structure with a high martensite ratio (specifically, a martensite ratio of 80% or more) can be stably produced.
- FIG. 1 is a diagram for explaining a method for quenching a steel pipe according to the present invention, wherein (a) is a diagram showing a cooling method during quenching, and (b) is a structure after quenching (however, a low alloy) It is explanatory drawing of the case of steel is illustrated.
- FIG. 2 is a diagram for explaining another embodiment of the steel pipe quenching method of the present invention.
- FIG. 2 (a) is a diagram showing a cooling method during quenching
- FIG. 2 (b) is a structure after quenching ( However, it is explanatory drawing of the case of a low alloy steel.
- FIG. 1 is a diagram for explaining a method for quenching a steel pipe according to the present invention, wherein (a) is a diagram showing a cooling method during quenching, and (b) is a structure after quenching (however, a low alloy) It is explanatory drawing of the case of steel is illustrated.
- FIG. 2 is a diagram for
- FIG. 3 is a diagram showing a schematic configuration example of a main part of an apparatus capable of carrying out the steel pipe quenching method of the present invention.
- FIG. 4 is a diagram illustrating a schematic configuration of the cooling device used in the example.
- FIG. It is a figure which shows the measurement result of the inner surface temperature of the steel pipe center part at the time of cooling the full length of the steel pipe of low alloy steel on 1 water cooling conditions. 6 shows the test No. in Table 2. It is a figure which shows the measurement result of the outer surface temperature of the steel pipe center part at the time of cooling the full length of the steel pipe of low alloy steel on the water cooling conditions of 2. 7 shows the test No. in Table 2.
- FIG. 9 is a diagram showing an FEM analysis model in which a steel pipe two-dimensional cross section is an analysis target.
- FIG. 10 is a diagram showing the relationship between the circumferential maximum stress of the steel pipe and the wall thickness, which is an analysis result based on the FEM analysis model in which the two-dimensional cross section of the steel pipe is an analysis target.
- FIG. 11 is a diagram showing an analysis result by an FEM analysis model in which a two-dimensional longitudinal section of a steel pipe is an analysis target.
- FIG. 11A shows a case where the entire outer periphery of the steel pipe is water-cooled, and FIG. This is the case.
- the present inventors have carried out water quenching in which a steel tube specimen of a high carbon content low alloy steel and a Cr-based stainless steel is heated to an Ar3 transformation point temperature or higher and water-cooled from the outer surface of the steel tube. The experiment was repeated. As a result, the following findings (a) to (f) were obtained.
- Mf point martensite transformation stop temperature
- B Since the crack at the time of fire cracking extends approximately in the axial direction of the steel pipe, it is considered that the main force for expanding the crack is the tensile stress in the circumferential direction.
- the source of the tensile stress in the circumferential direction is that the martensitic transformation timing is shifted between the outer surface side and the inner surface side of the steel pipe due to a temperature difference (temperature unevenness) in the thickness direction generated in the cooling process. Conceivable.
- cracks originate from cracks that occur at the end of a steel pipe with a free surface, and these cracks are surrounded by thermal stress due to temperature unevenness in the thickness direction that occurs during the cooling process, as well as transformation stress. It is considered that this occurs as a result of the development of micro-cracks generated in the vicinity of the cooling surface due to the action of tensile stress in the direction (hereinafter, “tensile stress” is also simply referred to as “stress”).
- the present inventors further calculated the maximum stress generated in the circumferential direction of the steel pipe by FEM (finite element method) analysis in consideration of thermal stress and transformation stress.
- FEM finite element method
- FIG. 9 is a diagram showing an FEM analysis model in which a steel pipe two-dimensional cross section is an analysis target.
- the outer surface of the steel pipe 1 C: 0.6%) It was assumed that water was cooled from three directions by the air-water nozzle 9 and the inner surface was air-cooled by air blow. Although the heat transfer coefficient of the outer surface of the steel pipe 1 varies depending on the temperature, the maximum is 12700 W / (m 2 ⁇ K).
- FIG. 10 is a diagram showing the relationship between the circumferential maximum stress of the steel pipe and the wall thickness, as an analysis result by the above model.
- the ⁇ mark water cooling only indicates the cooling state when an air cooling part is appropriately provided during water cooling when the water cooling is performed under the conditions shown in FIG. 9 above (control quenching). 2), and sprayed at a low water pressure only from the air-water nozzle arranged at the top of the steel pipe, and the sprayed water is not directly injected into the steel pipe, and fine water droplets are in the air. This is the case when it is in a floating state.
- the broken line parallel to the horizontal axis in the figure is the limit stress at which no burning crack occurs, and in this case, it is 200 MPa.
- FIG. 11 is a diagram showing an analysis result by an FEM analysis model in which a two-dimensional longitudinal section of a steel pipe is an analysis target.
- (A) is a case where the entire outer periphery of the steel pipe is water-cooled, and (b) is a central portion of the steel pipe (described later). This is a case where only the water cooling was performed, and the end of the steel pipe was not water cooled.
- FIG. 11 represents the one-side cross section of the steel pipe 1 cut
- the maximum heat transfer coefficient of the outer surface of the steel pipe was 12700 W / (m 2 ⁇ K).
- the inventors of the present invention have obtained the following ideas (g) and (h) from the above knowledge and consideration, and have made the present invention.
- G Even for a steel pipe made of low alloy steel or medium alloy steel that easily undergoes cracking in water quenching, a sufficient martensite ratio can be secured in the portion excluding the end without water cooling the end of the steel pipe. If water cooling is performed at a cooling rate, water quenching can be stably performed without causing cracking.
- H Even when the above water quenching method is applied to a steel pipe made of martensitic stainless steel, high performance can be ensured without causing cracking.
- the present invention is a quenching method in which a steel pipe is water-cooled from the outer surface and quenched, and at least a part of the portion other than the pipe end is water-cooled without water-cooling the pipe end.
- This is a method for quenching steel pipes.
- the “pipe end portion” refers to both end portions of the steel pipe.
- FIG. 1 is a diagram for explaining a method for quenching a steel pipe according to the present invention, wherein (a) is a diagram showing a cooling method during quenching, and (b) is a structure after quenching (however, a low alloy) It is explanatory drawing of the case of steel is illustrated.
- 1 (a) corresponds to the part denoted by reference numeral (1) in FIG. 1 (b), and the air-cooled part in FIG. 1 (a) corresponds to reference numerals (2) and (2) in FIG. 1 (b). Corresponds to the part marked with (3).
- the pipe end portion when the steel pipe 1 is cooled with water from the outer surface and quenched, the pipe end portion is not cooled with water, and the portion excluding the pipe end portion (hereinafter referred to as “central portion”) is also used. At least a part of the water is cooled. In the example shown in FIG. 1A, the entire central portion is water-cooled. However, as shown in FIG. 2A, there may be a portion that is not water-cooled in the central portion. This is because the non-water-cooled portion present in the central portion is adjacent to the water-cooled portion, and is thus cooled by conduction heat transfer and undergoes martensitic transformation.
- the tube end portion that is not water-cooled is air-cooled, for example, as shown in FIG. “Air cooling” includes both natural air cooling and forced air cooling.
- a steel structure as shown in FIG. 1B is obtained after the quenching process. That is, since the central portion (1) of the steel pipe 1 is water-cooled at a cooling rate at which martensite necessary for obtaining required mechanical properties and corrosion resistance is formed, the steel structure is a structure mainly composed of martensite. . Of the pipe ends (2) and (3) of the steel pipe 1, (3) on the pipe end side is not water-cooled, and since the cooling rate is low, a bainite-based structure is formed, and cracks and cracks occur at the pipe ends. Extension is suppressed.
- the steel pipe quenching method of the present invention is a method in which the steel structure is martensite by quenching, and the martensite generation ratio is not particularly limited. However, in a low alloy steel or a medium alloy steel, generally, if 80% or more of the structure is martensite, a desired strength can be obtained. When the object of the quenching treatment is a Cr-based stainless steel pipe, martensite is formed even when the cooling rate is low, but the desired corrosion resistance is ensured by the quenching method of the present invention. In any case, in the present invention, it is assumed that a steel pipe having a martensite ratio of at least 80% is obtained.
- an embodiment in which a portion that is not directly water-cooled over the entire circumference may be provided in at least a part of the axial direction in a portion other than the tube end portion (center portion of the tube).
- FIG. 2 is a diagram for explaining this embodiment.
- (A) is a diagram showing a cooling method during quenching
- (b) is a structure after quenching (however, in the case of low alloy steel). It is explanatory drawing of illustration.
- the central portion (1) of the steel pipe 1 is not uniformly cooled by water, but a water-cooled portion and a portion not cooled by water (air-cooled portion) are appropriately provided in the longitudinal direction of the steel pipe 1. In this air cooling section, water cooling is not performed directly over the entire circumference.
- This embodiment is particularly effective when, for example, the steel pipe is thin.
- the thickness of the steel pipe is thin, as shown in FIG. 1, when the entire center part (1) is water-cooled, the pipe end part (2) against the circumferential stress generated in the center part (1), The strength of (3) cannot be resisted and there is a possibility that burning cracks may occur.
- FIG. 3 is a diagram showing a schematic configuration example of a main part of an apparatus capable of carrying out the steel pipe quenching method of the present invention.
- the steel pipe 1 carried out from the heating furnace 2 is carried into the cooling device 3, held by the roll 4, and rotated and attached to the device 3 and injected from the nozzle 5.
- the outer surface is cooled by water spray.
- an air jet nozzle 6 for forced air cooling of the inner surface of the steel pipe 1 is disposed on one side of the cooling device 3 as necessary.
- the water-cooling and the water-cooling stop are repeated intermittently in at least a part of the quenching process.
- the entire water cooling time becomes longer than that of continuous water cooling, thereby reducing the difference between the internal temperature and the surface temperature and reducing the residual stress.
- the intermittent water cooling may be performed consistently from the initial stage of quenching where the temperature of the steel pipe is at or above the Ar 3 point until the inner and outer surfaces of the steel pipe are below the Ms point, preferably below the Mf point. It can be used as part of the quenching process.
- the outer surface side of the steel pipe is heated from the inner surface side by cooling to a temperature higher than the Ms point near the Ms point by strong water cooling and then switching to weak water cooling or air cooling. It is desirable to reheat by conduction so that the temperature difference between the inner surface and the outer surface of the steel pipe is as small as possible, and then cooled to a temperature below the Ms point, preferably below the Mf point, by forced air cooling or the like.
- This embodiment is particularly effective when the steel pipe is thick, for example.
- the temperature unevenness in the thickness direction increases during water cooling from the outer surface, and a brittle fracture occurs where the outer surface becomes the starting point of cracking due to a large tensile stress due to expansion accompanying martensitic transformation of the outer surface.
- the above-described embodiment that delays the start of the martensitic transformation on the outer surface and reduces the difference in the start time of the martensitic transformation on the inner and outer surfaces is effective.
- the temperature gradient in the thickness direction can be relaxed and the tensile stress generated in the circumferential direction can be reduced.
- the cooling rate of strong water cooling varies depending on the steel type, but in the case of low alloy steel, if the cooling rate in the first cooling stage is too low, bainite transformation occurs and it is impossible to secure a sufficient martensite ratio. Therefore, it is desirable to determine an appropriate cooling rate based on the CCT diagram of the target steel.
- the outer surface side of the steel pipe is reheated by heat conduction from the inner surface side by cooling to a temperature higher than the Ms point near the Ms point by strong water cooling and then switching to weak water cooling or air cooling.
- a cooling process comprising minimizing the temperature difference between the inner surface and the outer surface of the steel pipe is included, but the same effect can be obtained by using the above-described intermittent water cooling instead of this cooling process.
- the intermittent water cooling described in the present invention (3) (operation to intermittently repeat execution and stop of water cooling) is stopped at a temperature higher than the Ms point near the Ms point, and then forced air cooling or the like is performed. Strong cooling can also be performed.
- this embodiment belongs to the category of the present invention (3).
- a conventionally used method such as laminar cooling, jet cooling, or mist cooling may be appropriately selected and employed as the water cooling method.
- the object of the treatment of the present invention is a steel pipe that is easily cracked during quenching.
- the object to be treated according to the invention is (A) a steel pipe containing 0.20 to 1.20% C, in particular a low alloy steel or medium alloy steel pipe, or (B) 0.
- the effect of the present invention is remarkable in the case of a Cr-based stainless steel pipe containing 10 to 0.30% C and 11 to 18% Cr, especially 13Cr stainless steel pipe.
- the steel pipe containing 0.20 to 1.20% of C in (A) is a steel pipe made of a material containing C in this range, and is generally a steel pipe of low alloy steel or medium alloy steel. It is. When the content of C is less than 0.20%, the volume expansion due to martensite formation is relatively small, so that the burning crack is hardly a problem.
- the C content is preferably 0.20 to 1.20% from the viewpoint of exerting the effects of the present invention.
- a more desirable C content is 0.25 to 1.00%, and further desirably 0.30 to 0.65%.
- the entire central portion of the steel pipe is water-cooled and the pipe end is not water-cooled.
- the vicinity of the pipe end can be a bainite-based structure that does not cause burning cracks.
- the low alloy steel or medium alloy steel for example, C: 0.20 to 1.20, Si: 2.0% or less, Mn: 0.01 to 2.0%, and Cr: 7.0 %: Mo: 2.0% or less, Ni: 2.0% or less, Al: 0.001 to 0.1%, N: 0.1% or less, Nb: 0.5% or less, Ti: 0.00%. 5% or less, V: 0.8% or less, Cu: 2.0% or less, Zr: 0.5% or less, Ca: 0.01% or less, Mg: 0.01% or less, B: 0.01%
- the steel include one or more of the following, the balance being Fe and impurities, and P: 0.04% or less and S: 0.02% or less as impurities. If the Cr content exceeds 7.0%, martensite is liable to occur at the end of the tube that is not water-cooled, so it is preferably 7.0% or less.
- the Cr-based stainless steel pipe containing 0.10 to 0.30% C and 11 to 18% Cr of (B) is made of Cr-based stainless steel containing C and Cr in this range. It is a steel pipe (martensitic stainless steel pipe). If the C content is less than 0.10%, sufficient strength cannot be obtained even if quenching is performed. On the other hand, if C exceeds 0.30%, austenite remains difficult to avoid, and a martensite ratio of 80 It becomes difficult to secure more than%. Therefore, the C content is preferably 0.10 to 0.30% from the viewpoint of exerting the effects of the present invention.
- the Cr content of 11 to 18% is preferably Cr of 11% or more in order to improve the corrosion resistance. On the other hand, if Cr exceeds 18%, ⁇ ferrite is likely to be generated. This is because workability is lowered. More desirably, Cr is 10.5 to 16.5%.
- Examples of Cr-based stainless steel containing 0.10 to 0.30% C and 11 to 18% Cr include C: 0.10 to 0.30, Si: 1.0% or less, Mn: 0 0.01 to 1.0%, Cr: 11 to 18% (more desirably 10.5 to 16.5%), Mo: 2.0% or less, Ni: 1.0% or less, Al: 0.001 to 0.1%, N: 0.1% or less, Nb: 0.5% or less, Ti: 0.5% or less, V: 0.8% or less, Cu: 2.0% or less, Zr : 0.5% or less, Ca: 0.01% or less, Mg: 0.01% or less, B: contain at least one of 0.01% or less, with the balance being Fe and impurities, P: 0.04% or less, S: 0.02% or less steel.
- 13Cr stainless steel pipe is widely used in many industrial fields and is suitable as a target for the treatment of the present invention.
- the quenching method of the present invention can be applied to so-called reheating quenching, in which the steel pipe is reheated from room temperature, but in the production of a seamless steel pipe, the steel pipe immediately after hot rolling is made of Ar 3.
- So-called direct quenching in which quenching is performed from the above-mentioned temperature, and further, after hot rolling, at the stage where the amount of heat retained in the steel pipe does not drop significantly, after soaking (supplementing) at a temperature of 3 points or more, quenching is performed. It can be applied as a quenching method of so-called in-line heat treatment (in-line quenching). According to the quenching method of the present invention, quenching cracks can be effectively prevented, so that a high-strength steel pipe having a structure with a high martensite ratio can be stably produced.
- a tubular test material was cut out from a seamless steel pipe of the material shown in Table 1 and quenched under various cooling conditions to observe the presence or absence of quench cracking and the steel structure.
- steel type A is a low alloy steel
- steel type B is a high Cr steel (martensitic stainless steel).
- the shape of the test material is a straight pipe having an outer diameter of 114 mm, a wall thickness of 15 mm, and a length of 300 mm.
- the test material was heated to a temperature about 50 ° C. higher than the Ac3 point in an electric heating furnace, held for about 15 minutes, then unloaded from the furnace, transported to a cooling device within 30 seconds, and water cooling was started.
- FIG. 4 is a diagram showing a schematic configuration of the cooling device used in the test.
- This cooling device includes a method of quenching with a water spray in which the steel pipe 1 is ejected from the nozzle 5 and a method of quenching by immersing in a water tank 8 containing water 7 (shown in the figure). (Displayed by a broken line) can be selected. In quenching by water spray, the amount of sprayed water can be changed by a flow rate adjusting valve (not shown).
- the steel pipe 1 was held by the lower roll 4b and the upper roll 4a. Lid prevention lids were attached to both ends of the steel pipe 1, and only the outer surface was cooled. During cooling, the steel pipe 1 was rotated at 60 rpm by the lower roll 4b.
- Table 2 shows the water cooling conditions.
- water cooling condition A the inner surface temperature of the steel pipe center part was measured with the thermocouple weld-bonded to the inner wall of the steel pipe.
- water cooling conditions B to E the outer surface temperature of the steel pipe central part, or the steel pipe central part and both the left and right ends of the steel pipe was measured with a thermotracer.
- Table 3 shows the occurrence of fire cracks and the observation results of the steel structure.
- FIG. 5 shows the test No. in Table 2. It is a figure which shows the measurement result of the inner surface temperature of the steel pipe center part at the time of cooling the whole steel pipe of the steel type A (low alloy steel) on the water cooling conditions A (immersion water cooling) of 1.
- steel type B is a material that can be martensitic even under slow cooling. Even when the cooling method of No. 5 was applied, no heat generation (see FIG. 8) was observed near 400 ° C. at the end of the tube. Regarding steel cracking, in the case of steel grade B, no. Although quenching cracks occurred in the quenching methods 1 and 2, no. In the cases of 3 to 5 according to the method of the present invention, no occurrence of burning cracks was observed.
- the steel pipe quenching method of the present invention does not cause quench cracking even when applied to medium and high carbon content steel pipes (low alloy steel or medium alloy steel pipes) or Cr stainless steel pipes that are susceptible to quench cracking. Therefore, it can utilize suitably for the quenching process of these steel pipes.
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Abstract
Description
「%」:中・高炭素含有鋼、マルテンサイト系ステンレス鋼等、対象物に含まれる各成分の質量百分率を表す。
「低合金鋼」:ここでは、合金成分の総量が5%以下の鋼をいう。
「中合金鋼」:ここでは、合金成分の総量が5%超10%以下の鋼をいう。
(1)鋼管を外面から水冷して焼入れる焼入方法であって、管端部を水冷することなく、前記管端部以外の部分の少なくとも一部を水冷することを特徴とする鋼管の焼入方法。
(a)鋼管全体を強い水焼入れでマルテンサイト変態停止温度(Mf点)以下まで冷却すると、高い確率で焼割れが発生する。
(b)焼割れ時の亀裂は、おおよそ鋼管の軸方向に伸展することから、割れを拡大する主な力は周方向の引張応力であると考えられる。
(c)前記の周方向の引張応力の発生源は、冷却過程で生じる肉厚方向における温度差(温度ムラ)により鋼管の外面側と内面側とでマルテンサイト変態のタイミングがずれるためであると考えられる。
(e)亀裂は、ほとんどの場合、鋼管端部を起点として伸展する。その理由は、自由表面を持つ端部の応力拡大係数が端部以外のそれに比べて大きいためと考えられる。
(f)水冷を行わず、冷却速度を抑制した場合は、高炭素含有低合金鋼およびCr系ステンレス鋼のいずれの場合においても焼割れは生じない。なお、高炭素含有低合金鋼においては、マルテンサイト化を抑制し、ベイナイト主体の組織とした場合は焼割れは生じない。
(g)水焼入れにおいて焼割れを生じやすい低合金鋼もしくは中合金鋼からなる鋼管であっても、鋼管の端部を水冷することなく、端部を除く部分で十分なマルテンサイト比率を確保できる冷却速度で水冷することとすれば、焼割れを生じさせずに安定的に水焼入できる。
(h)上記の水焼入れ方法を、マルテンサイト系ステンレス鋼からなる鋼管に適用した場合も、焼割れを生じることなく、高性能を確保できる。
4:ロール、 4a:上ロール、 4b:下ロール、
5:ノズル、 6:送気管、 7:水、 8:水槽、
9:気水ノズル、 10a:外面、 10b:内面
Claims (6)
- 鋼管を外面から水冷して焼入れる焼入方法であって、管端部を水冷することなく、前記管端部以外の部分の少なくとも一部を水冷することを特徴とする鋼管の焼入方法。
- 前記管端部以外の部分における軸方向の少なくとも一部において、全周にわたり直接水冷されない部分を設けることを特徴とする請求項1に記載の鋼管の焼入方法。
- 焼入過程の少なくとも一部において、水冷の実施と水冷の停止を間欠的に繰り返すことを特徴とする請求項1または2に記載の鋼管の焼入方法。
- 鋼管の外面を水冷するに当たり、鋼管の外面の温度がMs点より高い温度範囲において強水冷を行い、その後弱水冷または空冷に切り替えて外面を強制冷却し、Ms点以下に冷却することを特徴とする請求項1または請求項2に記載の鋼管の焼入方法。
- 前記鋼管が、質量%で、0.2~1.2%のCを含有する鋼管であることを特徴とする請求項1~請求項4の何れかに記載の鋼管の焼入方法。
- 前記鋼管が、質量%で、0.10~0.30%のCおよび11~18%のCrを含有するCr系ステンレス鋼管であることを特徴とする請求項1~請求項4の何れかに記載の鋼管の焼入方法。
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BR112013022381-2A BR112013022381B1 (pt) | 2011-03-18 | 2012-03-13 | método de têmpera para tubo de aço |
RU2013146541/02A RU2552801C2 (ru) | 2011-03-18 | 2012-03-13 | Способ закалки стальной трубы |
KR1020137027274A KR20130135354A (ko) | 2011-03-18 | 2012-03-13 | 강관의 담금질 방법 |
JP2012520617A JP5252131B2 (ja) | 2011-03-18 | 2012-03-13 | 鋼管の焼入方法 |
EP12760243.1A EP2687612B1 (en) | 2011-03-18 | 2012-03-13 | Steel pipe quenching method |
MX2013010422A MX352402B (es) | 2011-03-18 | 2012-03-13 | Metodo de enfriamiento de tuberia de acero. |
US14/005,853 US9546408B2 (en) | 2011-03-18 | 2012-03-13 | Quenching method for steel pipe |
CN201280014264.1A CN103443302B (zh) | 2011-03-18 | 2012-03-13 | 钢管的淬火方法 |
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JP2020139200A (ja) * | 2019-02-28 | 2020-09-03 | Jfeスチール株式会社 | 鋳片の冷却カバー及び冷却方法 |
JP2022126743A (ja) * | 2019-02-28 | 2022-08-30 | Jfeスチール株式会社 | 鋳片の冷却方法 |
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EP2687612A4 (en) | 2014-11-26 |
BR112013022381B1 (pt) | 2019-01-15 |
EP2687612A1 (en) | 2014-01-22 |
KR20130135354A (ko) | 2013-12-10 |
JPWO2012127811A1 (ja) | 2014-07-24 |
RU2552801C2 (ru) | 2015-06-10 |
EP2687612B1 (en) | 2018-09-26 |
BR112013022381A2 (pt) | 2016-12-06 |
CN103443302A (zh) | 2013-12-11 |
US20140007994A1 (en) | 2014-01-09 |
US9546408B2 (en) | 2017-01-17 |
MX2013010422A (es) | 2013-10-17 |
MX352402B (es) | 2017-11-23 |
CN103443302B (zh) | 2015-04-15 |
JP5252131B2 (ja) | 2013-07-31 |
RU2013146541A (ru) | 2015-04-27 |
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