WO2012077732A1 - Composition cosmétique capillaire de type gel - Google Patents

Composition cosmétique capillaire de type gel Download PDF

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Publication number
WO2012077732A1
WO2012077732A1 PCT/JP2011/078359 JP2011078359W WO2012077732A1 WO 2012077732 A1 WO2012077732 A1 WO 2012077732A1 JP 2011078359 W JP2011078359 W JP 2011078359W WO 2012077732 A1 WO2012077732 A1 WO 2012077732A1
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Prior art keywords
component
gel
emulsion
hair cosmetic
phase microemulsion
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PCT/JP2011/078359
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English (en)
Japanese (ja)
Inventor
田中　広美
智規 豊田
藤山　泰三
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株式会社資生堂
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Publication of WO2012077732A1 publication Critical patent/WO2012077732A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90—Block copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to a gel hair cosmetic. More specifically, it is a novel gel that can be sprayed in a mist, has no stickiness as a hair cosmetic, has a smooth and high feel, has an excellent straight effect, is stable without creaming, and has a transparent appearance.
  • the present invention relates to a hair cosmetic composition.
  • Patent Document 1 has an excellent effect that a transparent gel-like composition can be sprayed in a mist, and as a component that improves the feel of the hair, a component such as a water-soluble silicone or a humectant is blended. It was. However, in recent years, there has been a demand for even better hair feel. In general, in order to solubilize an oil or the like in a base so that the base becomes transparent, it is necessary to add a large amount of a surfactant, which causes stickiness and deteriorates the touch. Further, when blended as an emulsion, transparency is not obtained, and it gradually creams, so that stable blending has been technically difficult. Furthermore, it is difficult to blend a cationic surfactant, which is generally considered to have a good feeling, into a thickening system of an anionic polymer.
  • Patent Document 2 is further cited as a document disclosing a technique close to the present invention.
  • Patent Document 2 although a method for producing an O / W ultrafine emulsion external preparation is described, it is a transparent gel that can be sprayed in a mist, has no stickiness, and has a smooth and high feel. There is no description that suggests that a hair cosmetic that is excellent in straightening effect and does not cause creaming and that is stable is obtained.
  • the present invention has been made in view of the above circumstances, is capable of stable mist spraying, has no stickiness as a hair cosmetic, has a smooth and high feel, has an excellent straight effect, and causes creaming. It is an object to provide a novel gel-like hair cosmetic that is stable and transparent in appearance.
  • the present invention comprises the following components (a), (b), (c), and (d) in an aqueous solvent, and has a viscosity of 500 to 3000 mPa ⁇ s (30 ° C., A gel-type hair cosmetic that is a B-type viscometer and is used by being sprayed in a mist when used.
  • R 1 and R 6 each independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms;
  • R 2 represents an alkylene group having 1 to 10 carbon atoms;
  • R 3 , R 4 and R 5 each independently represents an alkyl group having 1 to 24 carbon atoms;
  • A represents an oxygen atom, an NH group, or no A.
  • the present invention also includes the following steps: (I) A one-phase micro comprising a component (c), a nonionic surfactant, a polyoxypropylene / polyoxyethylene copolymer dialkyl ether, and water, and having a water content of 40% by mass or less. Preparing an emulsion; (Ii) adding the one-phase microemulsion to an aqueous solvent (part) to prepare an O / W ultrafine emulsion having an emulsified particle size of 10 to 500 nm; and (iii) the O / W ultrafine. Adding and mixing the emulsion into a system in which the component (a), the component (b), and the component (d) are dissolved in an aqueous solvent (remainder); A method for producing the above gel-like hair cosmetic composition, comprising:
  • the present invention also includes the following steps: (I) It contains (c) component, (d) component, nonionic surfactant, polyoxypropylene / polyoxyethylene copolymer dialkyl ether, and water, and has a water content of 40% by mass or less.
  • Preparing a one-phase microemulsion which is (Ii) adding the one-phase microemulsion to an aqueous solvent (part) to prepare an O / W ultrafine emulsion having an emulsified particle size of 10 to 500 nm; and (iii) the O / W ultrafine.
  • a method for producing the above gel-like hair cosmetic composition comprising:
  • a stable mist spray is possible, and there is no stickiness as a hair cosmetic, it has a smooth and high touch, is excellent in straight effect, does not cause creaming, is stable and has a transparent appearance.
  • a gel-like hair cosmetic is provided.
  • POE represents polyoxyethylene
  • POP represents polyoxypropylene
  • a cationic polymer having a structural unit represented by the following formula (I) is used as the component (a).
  • R 1 and R 6 each independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.
  • a methyl group as R 1 and a hydrogen atom as R 6 are particularly preferable.
  • R 2 represents an alkylene group having 1 to 10 carbon atoms, preferably 1 to 5 carbon atoms. In the present invention, a methylene group is particularly preferred.
  • R 3 , R 4 and R 5 each independently represents a hydrogen atom or an alkyl group having 1 to 24 carbon atoms, preferably 1 to 4 carbon atoms. In the present invention, it is particularly preferred that R 3 and R 4 are each a methyl group and R 5 is an ethyl group.
  • A represents an oxygen atom or NH group or does not have A.
  • A is preferably an oxygen atom.
  • X represents a halogen atom and R′SO 4 (where R ′ is an alkyl group having 1 to 6 carbon atoms).
  • R ′ is preferably an alkyl group having 1 to 4 carbon atoms, particularly 1 to 2 carbon atoms. In the present invention, it is particularly preferred that X is C 2 H 5 SO 4 .
  • the molecular weight of the component (a) is preferably about 10,000 to 10,000,000, particularly preferably about 100,000 to 1,000,000. If the molecular weight is less than 10,000, it is difficult to obtain a firm feeling as a hair cosmetic, while if it exceeds 10 million, the solubility becomes poor and it is difficult to blend in the base.
  • the polymer represented by the above formula (I), in particular the polymer represented by the formula (II), is excellent in the flexibility of the film, and has excellent affinity and adhesion to the hair. It is a polymer with the characteristic which gives. In the present invention, it is also preferable in terms of transparency.
  • These polymers are commercially available as “Guff Coat” series from GAF (USA), “HC Polymer” series from Osaka Organic Industry Co., Ltd., etc., and are commercially available.
  • a component can use 1 type (s) or 2 or more types.
  • the blending amount of the component (a) is preferably about 0.02 to 0.5% by mass, and particularly preferably about 0.02 to 0.2% by mass in the hair cosmetic composition of the present invention.
  • a carboxyvinyl polymer is preferably used as the non-spinning anionic polymer having a thickening action as the component (b) used in the present invention.
  • the carboxyvinyl polymer has no spinnability and has a property of increasing the viscosity by neutralization with alkali. However, since it has no spinnability, it has good “crisp” and is suitable for atomized spray.
  • the carboxyvinyl polymer is mainly a polymer of acrylic acid, and is a synthetic polymer having a carboxyl group.
  • a water-soluble cellulose derivative that is a spinnable thickener for example, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, Etc.
  • sodium polyacrylate and the like are not included in the component (b) of the present invention.
  • the component (b) is preferably used by adjusting the pH with an alkali and neutralizing it to increase the viscosity.
  • the alkali as the pH adjusting agent is not particularly limited, but potassium hydroxide, sodium hydroxide, triethanolamine, aminomethylpropanol, aminomethylpropanediol and the like are preferably used.
  • (B) Ingredients are “Sintalen” series (made by V3 SIGMA, Italy), “Carbopol” series (made by BF Goodrich, USA), “Hibiswako” (made by Wako Pure Chemical Industries, Ltd.) Etc., and are commercially available.
  • a component can use 1 type (s) or 2 or more types.
  • the blending amount of the component (b) is preferably about 0.05 to 1.0% by mass, and particularly preferably about 0.1 to 0.5% by mass in the hair cosmetic composition of the present invention.
  • the oil component as the component (c) used in the present invention is not particularly limited, and for example, silicone oil, hydrocarbon oil, ester oil and the like can be appropriately used. Among these, silicone oil is preferable from the viewpoint of usability to give glossiness and smoothness.
  • silicone oil used in the present invention are not particularly limited as long as they can be generally used in cosmetics.
  • examples thereof include dimethylpolysiloxane, cyclomethicone, diphenylpolysiloxane, and alkylpolysiloxane. These two or more types may be mixed or used.
  • the blending amount of the component (c) used in the present invention is not particularly limited, but when the O / W single-phase microemulsion is formed as described later, the total amount of the O / W single-phase microemulsion parts is used. It is preferably 20 to 70% by mass. If it exceeds 70% by mass, it is difficult to obtain a highly stable O / W single-phase microemulsion.
  • the blending amount of component (c) in the hair cosmetic composition of the present invention is preferably 0.001 to 5% by mass.
  • Examples of the cationic surfactant as the component (d) used in the present invention include alkyltrimethylammonium salts such as stearyltrimethylammonium chloride and lauryltrimethylammonium chloride, distearyldimethylammonium chloride dialkyldimethylammonium chloride, poly (N , N'-dimethyl-3,5-methylenepiperidinium), alkylpyridinium salts such as cetylpyridinium chloride, alkyl quaternary ammonium salts, alkyldimethylbenzylammonium salts, alkylisoquinolinium salts, dialkyl morpholiniums Examples thereof include salts, POE alkylamines, alkylamine salts, polyamine fatty acid derivatives, amyl alcohol fatty acid derivatives, benzalkonium chloride, and benzethonium chloride.
  • D 1 type (s) or 2 or more types can be used for a component.
  • the component (a), the component (b), the component (c), and the component (d) are dissolved in an aqueous solvent.
  • the aqueous solvent include water, alcohol solvents such as ethanol, and mixed solvents thereof.
  • a production method including the following steps is mentioned as a preferred example. That is, it is preferable to mix
  • blend (c) component is mixed as an O / W ultrafine emulsion prepared through the one-phase microemulsion preparation process and the O / W ultrafine emulsion preparation process as shown below.
  • the particle size is 10 to 500 nm.
  • Component (c) is added to and mixed with a nonionic surfactant, a polyoxypropylene / polyoxyethylene copolymer dialkyl ether, and an aqueous system having a water content of 40% by mass or less.
  • a phase microemulsion Preparing a phase microemulsion, (Ii) a step of preparing an O / W ultrafine emulsion having an emulsified particle diameter of 10 to 500 nm by adding the above one-phase microemulsion in an aqueous solvent (part); (Iii) A step of adding and mixing the O / W ultrafine emulsion into a system obtained by dissolving the component (a), the component (b), and the component (d) in an aqueous solvent (remainder).
  • an optional additive component for example, a humectant, a neutralizing agent and the like can be blended.
  • the component (d) may be blended in the form of an O / W ultrafine emulsion according to the above process.
  • the amount of component (d) is preferably 0.001 to 1% by mass, particularly preferably 0.001 to 0.3% by mass.
  • the hairdressing cosmetic composition of the present invention has a system viscosity of 500 to 3000 mPa ⁇ s (30 ° C., B-type viscometer), preferably 700 to 1200 mPa ⁇ s.
  • the viscosity of the hairdressing cosmetic composition of the present invention can be adjusted, for example, by controlling the polymerization degree of the copolymer to be blended, increasing or decreasing the amount of polymer added, adjusting the blending amount of the aqueous solvent, and the like.
  • the component (a) and the component (b) form a complex, and adjacent complexes form weak bonds due to cohesive force.
  • cohesive force there is a feeling of elasticity compared to a normal gel-like composition, and a uniform gel can be formed, and the degree of shaking and passage of pores (for example, passage of spray holes of a cosmetic sprayer) is about.
  • the weak force due to aggregation between the composites is easily broken by the external force, so that it can be easily sprayed in the form of a mist during use.
  • the composites have the property of aggregating each other by allowing them to stand after use.
  • a weak bond due to aggregation is made between the bodies, forming a gel with elasticity. Therefore, according to the present invention, the gel is formed at the time of standing, and can be easily sprayed in the form of a mist by spraying with a sprayer at the time of use.
  • An entirely new type of gel composition is provided. This gel-like composition is excellent in the appearance of the appearance (gel feeling), and is also excellent in the touch during use. Also, the transparency is good.
  • the hair cosmetic composition of the present invention is excellent in transparency.
  • the L value which is an index of transparency is preferably 60 or more.
  • the “L value” means a value measured by putting a predetermined amount of hair cosmetic into a quartz cell having an optical path length of 10 mm and transmitting white light having a wavelength of 380 to 770 nm using a transmission color difference meter.
  • the component (c) as an ultrafine emulsion that has undergone the above-mentioned specific steps, it is possible to more effectively achieve both the balance between transparency and usability.
  • the hair cosmetic of the present invention may be blended with other components conventionally used in hair cosmetics, for example, depending on the form thereof, as long as the effects of the present invention are not impaired.
  • components include film-forming polymers, humectants, extracts, powder components, and fragrances.
  • the film-forming polymer is not particularly limited, and any film-forming polymer conventionally used in hair cosmetics such as hair styling agents can be arbitrarily used.
  • acrylic, vinyl, and urethane film-forming polymers are preferably used from the viewpoint of re-styling and the like.
  • anionic polymers include alkyl acrylate / diacetone acrylamide copolymers (plus size L-53P, plus size L-9909B, plus size L-9948B, etc.
  • amphoteric polymers include octylamide acrylate / hydroxypropylpropyl acrylate / butylaminoethyl methacrylate copolymer [AMPHOMER SH30, AMPHOMER LV-71 (both manufactured by Akzo Nobel)], methacryloyloxy Ethylcarboxybetaine / alkyl methacrylate copolymer [Yuka Former R205, Yuka Former 301, Yuka Former SM, Yuka Former 104D, etc.
  • Examples of cationic polymers include vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate [H. C. Polymer 1S (M), H.I. C. Polymer 2 (above, manufactured by Osaka Organic Chemical Co., Ltd.), Guff Coat 755N (manufactured by ISP)], vinylpyrrolidone / dimethylaminopropylmethacrylamide / lauryldimethylaminopropylmethacrylamide copolymer [Styrise W-20 (ISP) Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate / alkyl acrylate / tripropylene glycol diacrylate [Coscut GA467, Coscut GA468 (both manufactured by Osaka Organic Chemical Co., Ltd.)], poly Dimethylmethylenepiperidinium chloride [Mercoat 100 (manufactured by Nalco)],
  • nonionic polymers examples include polyvinylpyrrolidone [rubiscol K17, rubiscol K30, rubiscol K90 (above, manufactured by BASF), PVP K (produced by ISP)], vinylpyrrolidone / vinyl acetate copolymer [ PVP / VA S-630, PVP / VA E-735, PVP / VA E-335 (above, made by ISP), Rubiscor VA73W, Rubiscol 37E (above, made by BASF), PVA-6450 (Osaka Organic Chemical) Kogyo Co., Ltd.)], vinyl methyl ether / alkyl maleate copolymer [Gantrez A-425, Gantrez ES-225, Gantrez ES-335 (all from ISP)], vinylpyrrolidone / methacrylamide / vinylimidazole Copolymer [ruby set clear (manufactured by BASF)] And the like.
  • urethane-based film-forming polymers examples include silicone / polyether-based polyurethane resins (Yodosol PUD; manufactured by Akzo Nobel), “Rubiset PU” (manufactured by BASF), and Japanese Patent Application Laid-Open No. 2006-. Examples thereof include silylated urethane polymers described in Japanese Patent No. 213706. Examples of the acrylic-urethane film-forming polymer include “DynamX” (manufactured by Akzo Nobel Co., Ltd.).
  • the film-forming polymer When the film-forming polymer is blended, it is preferably blended in the hair cosmetic composition of the present invention at about 0.01 to 15% by mass, more preferably 0.01 to 6% by mass.
  • moisturizers examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, hexylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, carolinic acid, atelocollagen, cholesteryl-12-hydroxy
  • examples include stearate, sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiyobara extract, Achillea millefolium extract, Merirot extract, etc. .
  • neutralizing agent examples include 2-amino-2-methyl-1-propanol, potassium hydroxide, sodium hydroxide, triethanolamine and the like.
  • the dosage form of the gel hairdressing cosmetic composition of the present invention is an aerosol hair spray, a non-aerosol hair spray, a hair mist, a hair styling gel, etc., which is sprayed at the time of use.
  • the hair can be easily misted and stored in a normal spray cosmetic container such as a dispenser type, a trigger type, etc., without being soiled. It can be applied easily.
  • the hair cosmetic composition of the present invention is water-based and has a low viscosity, even when sprayed in the form of a mist during use, the spray nozzle of the spray container is not clogged, and excellent usability, appearance (transparency), stability (creaming) Can be applied to the hair widely and uniformly.
  • the spray container is usually filled together with a propellant.
  • a propellant known in the aerosol field such as liquefied gas such as propane, butane, pentane and dimethyl ether, and compressed gas such as nitrogen and compressed air can be arbitrarily used.
  • the blending amount of these propellants is preferably about 30 to 60% by mass with respect to 100% by mass of the hair cosmetic (stock solution).
  • the blending amount is expressed in mass% (actual amount).
  • Each sample is stored in a dispenser-type sprayer (“Y-150” manufactured by Yoshino Kogyo Co., Ltd.), and this is used for usability (ease of familiarity with hair, lack of stickiness during application, The smoothness, straightness effect, smoothness of the finish, gloss of the finish, lightness (after 4 hours of spraying), and hair mass (after 4 hours of spraying) are evaluated in sensory tests by female panelists (10 persons). Evaluation was made based on the following evaluation criteria.
  • Example 1 Using the samples shown in Table 1 below, according to the above evaluation method, viscosity, mist spray, transparency (L value), creaming, usability (ease of familiarity with hair, non-stickiness during application, as per finger The smoothness, the straight effect, the smoothness of the finish, the gloss of the finish, the lightness (after 4 hours of spraying), the hair mass (after 4 hours of spraying)) were evaluated. The results are shown in Table 1.
  • the component (c) is eventually added.
  • An O / W ultrafine emulsion having a particle diameter of 100 nm or less as a phase was obtained. This was mixed and stirred in an aqueous solvent containing the component (a), the component (b), and other compounding components (the remainder of ion-exchanged water and ethanol as constituents of the hair cosmetic) to obtain a sample.
  • Comparative Examples 2 and 3 were blended with component (c) using a non-aqueous emulsification method. That is, a nonionic surfactant shown in Table 1 is added to a water-soluble solvent, and component (c) is added thereto to prepare an oil-in-water emulsion in a water-soluble solvent, and then water is added to the emulsion. Mixed. In this non-aqueous emulsification method, the emulsified particles were about 1 ⁇ m.
  • Comparative Example 1 which is a solubilizing system, the component (c) and the component (d) cannot be blended in order to ensure transparency, so that the touch is heavy and the smoothness cannot be obtained. It was.
  • the emulsion particle size is about 1 ⁇ m, and when blended with a lot of oil (so that a good feel can be realized), like milk It has been confirmed that the appearance becomes whitish, the transparency is lost, and on the other hand, the touch is insufficient when blended in a small amount such that the transparency is not impaired.
  • the gel-like hair cosmetic composition of the present invention is transparent in appearance, can be sprayed stably, has no stickiness as a hair cosmetic composition, has a smooth and high touch, is excellent in a straight effect, and has a creaming effect. It does not occur and has excellent stability.

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Abstract

[Problème] Produire une nouvelle composition cosmétique capillaire de type gel qui peut être pulvérisée de façon stable sous la forme de brouillard et a une texture lisse et satisfaisante pour servir de composition cosmétique capillaire, un excellent effet de défrisage des cheveux et un aspect transparent sans rendre les cheveux graisseux ou causer un crémage. [Solution] La présente invention concerne une composition cosmétique capillaire de type gel qui contient, dans un solvant aqueux, (a) un polymère cationique spécifique (tel qu'un copolymère de diéthylsulfate de vinylpyrrolidone/N,N-diméthylaminoéthylméthacrylique), (b) un polymère anionique non filandreux (tel qu'un polymère de carboxyvinyle) qui a un effet épaississant, (c) une teneur en huile (telle que l'huile de silicone), et (d) un tensioactif cationique. La composition cosmétique capillaire de type gel sans émulsion a une viscosité de 500 à 3 000 mPa∙s (mesurée avec un viscosimètre de type B à 30 °C), et est pulvérisée sous la forme de brouillard en utilisation.
PCT/JP2011/078359 2010-12-08 2011-12-07 Composition cosmétique capillaire de type gel WO2012077732A1 (fr)

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JP2010274099A JP5150712B2 (ja) 2010-12-08 2010-12-08 ジェル状毛髪化粧料
JP2010-274099 2010-12-08

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JP5986847B2 (ja) * 2012-08-24 2016-09-06 ホーユー株式会社 毛髪処理剤組成物及びその使用方法
MX361103B (es) * 2013-04-05 2018-11-27 Procter & Gamble Composición para el cuidado del cabello que comprende una formulación preemulsionada.
US9655821B2 (en) * 2013-04-05 2017-05-23 The Procter & Gamble Company Personal care composition comprising a pre-emulsified formulation
JP6467808B2 (ja) * 2014-08-08 2019-02-13 日本ゼオン株式会社 電気化学素子電極用複合粒子の製造方法、電気化学素子電極材料の製造方法、電気化学素子電極の製造方法及び電気化学素子の製造方法
WO2020203703A1 (fr) * 2019-04-02 2020-10-08 花王株式会社 Composition de produit cosmétique

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