WO2012036525A2 - 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법 및 이를 이용하여 제조한 초친수 유리 코팅층 - Google Patents
표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법 및 이를 이용하여 제조한 초친수 유리 코팅층 Download PDFInfo
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- WO2012036525A2 WO2012036525A2 PCT/KR2011/006888 KR2011006888W WO2012036525A2 WO 2012036525 A2 WO2012036525 A2 WO 2012036525A2 KR 2011006888 W KR2011006888 W KR 2011006888W WO 2012036525 A2 WO2012036525 A2 WO 2012036525A2
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- Prior art keywords
- oxide
- material layer
- photocatalytic material
- hydrophilicity
- treatment
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 239000011247 coating layer Substances 0.000 title claims abstract description 34
- 239000011521 glass Substances 0.000 title claims abstract description 34
- 238000000576 coating method Methods 0.000 title claims abstract description 26
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 46
- 239000010410 layer Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 34
- 230000001699 photocatalysis Effects 0.000 claims abstract description 21
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 230000003746 surface roughness Effects 0.000 claims abstract description 20
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 230000004888 barrier function Effects 0.000 claims description 5
- 238000004544 sputter deposition Methods 0.000 claims description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 3
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 3
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910001923 silver oxide Inorganic materials 0.000 claims description 3
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 3
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 3
- 239000011941 photocatalyst Substances 0.000 description 13
- 230000008859 change Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
Images
Classifications
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5806—Thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/75—Hydrophilic and oleophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/77—Coatings having a rough surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
Definitions
- the present invention relates to a method for improving the hydrophilicity of the coating film through the surface morphology treatment, and a super-hydrophilic glass coating layer prepared by using the same, and superhydrophilic coating treatment to facilitate the maintenance and maintenance of a clean appearance of buildings and outdoor advertising materials, etc. And a technique for imparting a midnight effect.
- hydrophilic coating is performed on the glass for exterior finishing of the building.
- the conventional hydrophilic coating glass is designed to realize hydrophilicity under conditions in which a photocatalytic material is coated on a surface and UV is irradiated.
- the coating method applying the fractal structure theory applied a wet coating process such as a spray method, a dip method, and a slit coating method.
- This wet coating method has a technical difficulty in obtaining a uniform quality of the coating film during the large-area production, and is mainly used a method of constructing a site directly on a building after glass is constructed.
- the present invention forms a photocatalytic material layer at room temperature and then performs a heat treatment for a short time at an optimized temperature, thereby providing a super hydrophilic property with a transparent and low UV dependency so that the superhydrophilic property of the surface contact angle of 30 degrees or less can always be achieved. It is an object of the present invention to provide a coating film hydrophilicity improving method.
- Method for improving the hydrophilicity of the coating film through the surface morphology treatment comprises the steps of forming a photocatalytic material layer on the substrate, performing a post-heat treatment by heating the substrate on which the photocatalytic material layer is formed to 500 ⁇ 600 °C And increasing the surface roughness of the photocatalyst material layer such that the surface contact angle of the photocatalyst material layer is 30 degrees or less.
- the step of forming the photocatalytic material layer is characterized by performing at room temperature RF magnetron sputter deposition method, the photocatalytic material layer is titanium oxide, silicon oxide, aluminum oxide, iron oxide, silver oxide, copper oxide, It is preferably an oxide layer of at least one of tungsten oxide, zinc / tin alloy oxide, zinc stannate, molybdenum oxide, zinc oxide, strontium titanate, cobalt oxide and chromium oxide.
- the barrier layer may be further formed between the substrate and the photocatalytic material layer.
- the step of performing the post-heat treatment is characterized in that performed for 1 to 10 minutes.
- the superhydrophilic glass coating layer according to an embodiment of the present invention is characterized in that the surface morphology treatment is performed such that the surface roughness (RMS) is 1.5 nm or more using the above-described hydrophilicity improving method.
- RMS surface roughness
- the pencil hardness of the superhydrophilic glass coating layer is characterized in that 7 ⁇ 9H.
- the surface hardness does not change even after the hydrophilization treatment, it provides an effect that can exhibit a high-strength characteristic of maintaining 7H or more.
- the super hydrophilic glass coating layer according to the present invention can be easily extended to a range of applications such as exterior materials that can ensure a clean appearance, such as buildings and outdoor advertising materials, and the midnight effect as a super hydrophilic coating layer for easy maintenance. Can be represented.
- FIG. 1 is a cross-sectional view showing a superhydrophilic glass coating layer according to an embodiment of the present invention.
- FIG. 2 is a graph showing a change in water contact angle and pencil hardness according to heat treatment temperature in the method for improving hydrophilicity according to the present invention.
- FIG 3 is a graph showing a change in water contact angle according to UV irradiation according to heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- 4 to 6 are cross-sectional photographs showing surface roughness changes according to an increase in heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- 11 is a graph showing the surface roughness value according to the heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- Method for improving the hydrophilicity of the coating film through the surface morphology treatment comprises the steps of forming a photocatalytic material layer on the substrate, by heating the substrate on which the photocatalytic material layer is formed to 500 ⁇ 600 °C to perform a post-heat treatment And increasing the surface roughness of the photocatalyst material layer such that the surface contact angle of the photocatalyst material layer is 30 degrees or less.
- a photocatalytic material layer is first formed on a substrate for hydrophilization treatment.
- a vacuum thin film deposition process such as a room temperature RF magnetron sputter is used to form a large-area coating layer having a high transmittance and uniform thickness.
- the RF magnetron sputter according to the present invention is preferably such that the operation is performed at room temperature.
- the temperature range of the room temperature is generally in accordance with the commonly used range, but in the present invention shall be 18 to 25 °C range.
- the sputtering method is formed in a range exceeding room temperature.
- the photocatalyst coating layer is coated on a substrate, it is difficult to expect a high hydrophilic effect only by increasing the crystallinity of the photocatalyst material.
- the present invention by performing the sputtering process at room temperature conditions, it is economical and easy to form a photocatalyst coating layer, it is possible to easily control the morphology control according to the increase in crystallinity and surface roughness through subsequent heat treatment Excellent hydrophilicity can be achieved.
- FIG. 1 is a cross-sectional view showing a superhydrophilic glass coating layer according to an embodiment of the present invention.
- the superhydrophilized coating layer 120 is formed on the substrate glass 100.
- the barrier layer 110 may be further formed between the substrate glass 100 and the superhydrophilic coating layer 120.
- the barrier layer 110 is used to prevent the alkali materials in the substrate glass 100 from diffusing to the superhydrophilized coating layer 120 and act as impurities as time passes after coating.
- the substrate glass may be used as an example of a substrate according to the present invention, such as automotive interior, exterior materials or building window glass products.
- titanium oxide silicon oxide, aluminum oxide, iron oxide, silver oxide, copper oxide, tungsten oxide, zinc / tin alloy oxide, zinc stannate, molybdenum oxide, zinc oxide, strontium titanate,
- titanium oxide layer it is preferable to use a titanium oxide layer.
- one or more of the listed materials may be used as the barrier layer.
- the photocatalyst coating layer having the above structure is formed by RF magnetron sputter deposition, and the superhydrophilized coating layer 120 may be formed through the following heat treatment.
- the most important core process in the present invention may be referred to as heat treatment and time for surface morphology improvement, referring to the following experimental results it can be seen that the optimum hydrophilicity in the temperature range of 500 ⁇ 600 °C.
- the substrate used in the experiment for the optimized embodiment of the super-hydrophilized glass coating layer according to the present invention used soda-lime glass (Soda-Lime glass) having an area of 100mm x 100mm and has a thickness of 0.7t.
- TiO 2 titanium oxide layer
- room temperature (Room temp. Or RT), 200 ° C, 300 ° C, 400 ° C, 500 ° C, 600 ° C is increased while increasing the temperature at an elevated temperature rate of 10 ° C / min in an air atmosphere under a plastic heat treatment condition.
- the heat treatment holding time was 5 minutes, the following experimental results were obtained.
- FIG. 2 is a graph showing a change in water contact angle and pencil hardness according to heat treatment temperature in the method for improving hydrophilicity according to the present invention.
- a heat contact temperature (Poat-Annealingtemp. (° C.)) is in a water contact angle of 30 degrees or less in a temperature range of 500 to 600 ° C.
- the heat treatment temperature range exceeding 600 ° C. is not economical.
- 500 to 600 ° C may be referred to as an optimized annealing condition.
- FIG 3 is a graph showing a change in water contact angle according to UV irradiation according to heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- the general photocatalyst material was not observed hydrophilic under UV irradiation time and low light amount.
- the (water) contact angle is shown to be less than 30 degrees when the heat treatment temperature conditions 500 ° C according to the present invention. Therefore, it can be seen that the surface morphology treatment according to the present invention provides excellent superhydrophilicity even under room conditions (UV 0hr) where UV is not irradiated.
- 4 to 6 are cross-sectional photographs showing surface roughness changes according to an increase in heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- the superhydrophilic property is observed according to the change of the surface morphology, and it can be seen that the contact angle decrease is analyzed according to the increase of the roughness and the characteristic of the porous structure.
- the surface thicknesses of the titanium oxide coating layer not subjected to the heat treatment process are shown as 97.3 nm and 98.3 nm.
- the heat treatment at 400 ° C. shows a difference in thickness between 109 nm and 105 nm in a relatively wide region, indicating that hydrophilicity is hardly exhibited.
- 11 is a graph showing the surface roughness value according to the heat treatment temperature in the method of improving hydrophilicity according to the present invention.
- the surface roughness (RMS) of the superhydrophilic glass coating layer appears in the range of 1.5nm or more.
- the superhydrophilic glass coating layer is usually surface roughness (RMS) is less than 1.5nm, referring to Figure 11, when the heat treatment at 400 °C, superhydrophilic glass coating layer Although the surface roughness (RMS) of 1.5nm or more, but does not affect the degree of excellent hydrophilicity, when the heat treatment at 700 °C, it can be seen that the surface roughness (RMS) of the superhydrophilic glass coating layer is 1.5nm or less.
- the super hydrophilic glass coating layer according to the present invention can easily extend the scope of application to an exterior material that can ensure a clean appearance such as buildings or outdoor advertisements, and is midnight as a super hydrophilic coating layer for easy maintenance. Can be effective.
Abstract
Description
Claims (7)
- 기판에 광촉매 물질층을 형성하는 단계;상기 광촉매 물질층이 형성된 기판을 500 ~ 600℃로 가열하여 후열처리를 수행하고, 상기 광촉매 물질층 표면 거칠기를 증가시키는 단계;를 포함하여 상기 광촉매 물질층의 표면 접촉각이 30도 이하가 되도록 하는 것을 특징으로 하는 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법.
- 제1항에 있어서,상기 광촉매 물질층을 형성하는 단계는 상온 RF 마그네트론 스퍼터(Magnetron sputter) 증착 방식으로 수행하는 것 을 특징으로 하는 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법.
- 제1항에 있어서,상기 광촉매 물질층은 산화티타늄, 산화규소, 산화알루미늄, 산화철, 산화은, 산화구리, 산화텅스텐, 아연/주석 합금 산화물, 아연 스타네이트, 산화몰리브덴, 산화아연, 스트론튬티타네이트, 산화코발트 및 산화크로뮴 중 하나 이상의 산화층인 것을 특징으로 하는 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법.
- 제1항에 있어서,상기 기판 및 상기 광촉매 물질층 사이에 배리어층을 더 형성하는 것을 특징으로 하는 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법.
- 제1항에 있어서,상기 후열처리를 수행하는 단계는 1 ~ 10분 동안 수행하는 것을 특징으로 하는 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법.
- 제1항 내지 제5항 중 어느 한 항의 친수성 개선 방법을 이용하여, 표면 거칠기(RMS)가 1.5nm 이상이 되도록 표면 모폴로지 처리가 수행된 것을 특징으로 하는 초친수 유리 코팅층.
- 제6항에 있어서,상기 초친수 유리 코팅층의 연필 경도는 7 ~ 9H인 것을 특징으로 하는 초친수 유리 코팅층.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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CN201180044749.0A CN103108979B (zh) | 2010-09-17 | 2011-09-16 | 通过表面形态处理来改善涂膜的亲水性的方法及利用该方法制备的超亲水玻璃涂层 |
EP11825485.3A EP2617864A4 (en) | 2010-09-17 | 2011-09-16 | METHOD FOR IMPROVING THE HYDROPHILITY OF A COATING FILM BY TREATMENT ON SURFACE MORPHOLOGY AND SUPERHYDRAULIC GLASS COATING LAYER MANUFACTURED BY THE METHOD |
JP2013529075A JP2013543054A (ja) | 2010-09-17 | 2011-09-16 | 表面モルフォロジー処理によるコーティング膜の親水性改善方法及びこれを用いて製造した超親水ガラスコーティング層 |
US13/814,430 US20130142995A1 (en) | 2010-09-17 | 2011-09-16 | Method for improving hydrophilicity of a coating film through treatment on a surface morphology and super-hydrophilic glass coating layer produced by the same |
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KR10-2010-0091975 | 2010-09-17 | ||
KR1020100091975A KR20120029872A (ko) | 2010-09-17 | 2010-09-17 | 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법 및 이를 이용하여 제조한 초친수 유리 코팅층 |
Publications (2)
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WO2012036525A2 true WO2012036525A2 (ko) | 2012-03-22 |
WO2012036525A3 WO2012036525A3 (ko) | 2012-05-31 |
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PCT/KR2011/006888 WO2012036525A2 (ko) | 2010-09-17 | 2011-09-16 | 표면 모폴로지 처리를 통한 코팅막의 친수성 개선 방법 및 이를 이용하여 제조한 초친수 유리 코팅층 |
Country Status (6)
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US (1) | US20130142995A1 (ko) |
EP (1) | EP2617864A4 (ko) |
JP (1) | JP2013543054A (ko) |
KR (1) | KR20120029872A (ko) |
CN (1) | CN103108979B (ko) |
WO (1) | WO2012036525A2 (ko) |
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US10867887B2 (en) * | 2014-07-29 | 2020-12-15 | Massachusetts Institute Of Technology | Enhanced flow boiling heat transfer in microchannels with structured surfaces |
KR101891369B1 (ko) | 2014-08-06 | 2018-08-27 | (주)엘지하우시스 | 광촉매 기능성 필름 및 이의 제조방법 |
CN105177503B (zh) * | 2015-09-19 | 2018-04-27 | 苏州柯利达集团有限公司 | 一种用于改善狭缝式涂布模具表面润湿性能的镀膜方法 |
CN109012221B (zh) * | 2018-08-28 | 2021-06-18 | 重庆大学 | 利用磁控溅射SiO2纳米粒子制备高亲水性PVDF滤膜的方法及其产品 |
CN109133669A (zh) * | 2018-09-11 | 2019-01-04 | 大连理工大学 | 一种Ag/AgCl/WO3纳米薄膜材料及其制备方法 |
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US6830785B1 (en) * | 1995-03-20 | 2004-12-14 | Toto Ltd. | Method for photocatalytically rendering a surface of a substrate superhydrophilic, a substrate with a superhydrophilic photocatalytic surface, and method of making thereof |
JP3190984B2 (ja) * | 1998-06-24 | 2001-07-23 | 経済産業省産業技術総合研究所長 | 二酸化珪素を含有する二酸化チタン薄膜及びその製造方法 |
JP3912976B2 (ja) * | 2000-06-20 | 2007-05-09 | 三菱重工業株式会社 | 光触媒膜を有するチタン基材の製造方法及びチタン基材表面の親水化方法 |
JP2002320917A (ja) * | 2001-04-27 | 2002-11-05 | Toto Ltd | 光触媒性塗膜の製造方法、および光触媒性部材 |
JP2003027039A (ja) * | 2001-07-12 | 2003-01-29 | Central Glass Co Ltd | 光触媒親水膜およびその製造方法 |
JP4261353B2 (ja) * | 2001-09-28 | 2009-04-30 | 芝浦メカトロニクス株式会社 | 光触媒体、光触媒体の製造方法及び光触媒体の製造装置 |
CN101695655B (zh) * | 2001-11-29 | 2012-11-21 | 芝浦机械电子装置股份有限公司 | 光催化剂的制造装置 |
EP1466665B1 (en) * | 2001-12-21 | 2012-10-10 | Nippon Sheet Glass Co., Ltd. | Member having photocatalytic function and method for manufacture thereof |
JP2003231966A (ja) * | 2002-02-08 | 2003-08-19 | Central Glass Co Ltd | 酸化チタン膜の成膜方法 |
JP4030045B2 (ja) * | 2002-03-08 | 2008-01-09 | 株式会社村上開明堂 | 親水性複合材 |
FR2868770B1 (fr) * | 2004-04-09 | 2006-06-02 | Saint Gobain | Substrat, notamment substrat verrier, portant une couche a propriete photocatalytique modifiee pour pouvoir absorber des photons du visible |
DE102007025577B4 (de) * | 2007-06-01 | 2011-08-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 | Verfahren zur Herstellung von Titanoxidschichten mit hoher photokatalytischer Aktivität |
US8318589B2 (en) * | 2009-06-08 | 2012-11-27 | Applied Materials, Inc. | Method for forming transparent conductive oxide |
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2010
- 2010-09-17 KR KR1020100091975A patent/KR20120029872A/ko not_active Application Discontinuation
-
2011
- 2011-09-16 JP JP2013529075A patent/JP2013543054A/ja active Pending
- 2011-09-16 US US13/814,430 patent/US20130142995A1/en not_active Abandoned
- 2011-09-16 EP EP11825485.3A patent/EP2617864A4/en not_active Withdrawn
- 2011-09-16 WO PCT/KR2011/006888 patent/WO2012036525A2/ko active Application Filing
- 2011-09-16 CN CN201180044749.0A patent/CN103108979B/zh active Active
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See also references of EP2617864A4 |
Also Published As
Publication number | Publication date |
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JP2013543054A (ja) | 2013-11-28 |
EP2617864A4 (en) | 2014-07-09 |
KR20120029872A (ko) | 2012-03-27 |
US20130142995A1 (en) | 2013-06-06 |
EP2617864A2 (en) | 2013-07-24 |
CN103108979A (zh) | 2013-05-15 |
WO2012036525A3 (ko) | 2012-05-31 |
CN103108979B (zh) | 2015-07-15 |
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