WO2012001744A1 - 有機発光素子用インク、有機発光素子の製造方法、有機表示パネル、有機表示装置、有機発光装置、インク、機能層の形成方法、および有機発光素子 - Google Patents
有機発光素子用インク、有機発光素子の製造方法、有機表示パネル、有機表示装置、有機発光装置、インク、機能層の形成方法、および有機発光素子 Download PDFInfo
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
- H10K71/15—Deposition of organic active material using liquid deposition, e.g. spin coating characterised by the solvent used
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
Definitions
- the present invention relates to an ink for an organic light emitting device, a method for producing an organic light emitting device, an organic display panel, an organic display device, an organic light emitting device, ink, a method for forming a functional layer, and an organic light emitting device.
- organic light-emitting elements that have been researched and developed are light-emitting elements that utilize the electroluminescence phenomenon of functional materials, and a functional layer composed of a functional material is interposed between an anode and a cathode. Has a structure.
- a functional layer is formed by vapor-depositing a functional material on a substrate by a vapor deposition method using a mask.
- a functional material is dissolved in a solvent to form an ink, and the ink is ejected from an ink jet apparatus to apply the ink onto the substrate. After the application, the solvent is volatilized from the ink.
- Patent Document 1 An application method for forming a functional layer is proposed (Patent Document 1).
- ink ejection properties and flatness are contradictory characteristics, and low viscosity is required for inks to improve ejection properties, while high viscosity is required for inks to improve flatness. .
- an ink having both good ejection properties and flatness has not been realized.
- an object of the present invention is to provide an ink for an organic light-emitting element that is excellent in both ejectability and flatness.
- an ink for an organic light-emitting device includes a functional material that forms a functional layer of the organic light-emitting device, a first solvent that dissolves the functional material, and the first solvent.
- a second solvent having a boiling point which is not higher than the boiling point of the solvent or a boiling point which is higher than the boiling point of the first solvent and which is different from the boiling point of the first solvent by not more than 20 ° C. and having a diester skeleton;
- a third solvent having a boiling point lower than the boiling points of the first solvent and the second solvent and being an aliphatic alcohol.
- the ink for an organic light emitting device includes a second solvent having a predetermined viscosity and a third solvent having an action of lowering the viscosity of the second solvent, and the third solvent includes Until the second solvent evaporates, the second solvent has a lower viscosity than the predetermined viscosity, so that the ink maintains a low viscosity. However, after the third solvent evaporates, the second solvent becomes the original solvent. Since the viscosity returns, the ink becomes highly viscous. Therefore, for example, until the ink is ejected from the ink jet apparatus, it is possible to suppress the evaporation of the third solvent and maintain the ink at a low viscosity and improve the ejectability. After the ink is ejected from the ink jet apparatus, The third solvent is evaporated to increase the viscosity of the ink and improve the flatness.
- FIG. 1 is a diagram illustrating an entire configuration of a display device according to one embodiment of the present invention. 1 is a perspective view illustrating a television system using a display device according to one embodiment of the present invention. It is a figure which shows the organic light-emitting device which concerns on 1 aspect of this invention.
- an ink for an organic light-emitting device a method for manufacturing an organic light-emitting device, an organic display panel, an organic display device, an organic light-emitting device, an ink, a method for forming a functional layer, and an organic light-emitting device according to an embodiment of the present invention
- an ink for an organic light-emitting device a method for manufacturing an organic light-emitting device, an organic display panel, an organic display device, an organic light-emitting device, an ink, a method for forming a functional layer, and an organic light-emitting device according to an embodiment of the present invention
- the ink for an organic light-emitting device includes a functional material constituting a functional layer of the organic light-emitting device, a first solvent that dissolves the functional material, and a boiling point that is equal to or lower than the boiling point of the first solvent.
- a second solvent having a boiling point higher than the boiling point of the first solvent and having a difference from the boiling point of the first solvent of 20 ° C. or less and having a diester skeleton, and the boiling point of the first solvent.
- a third solvent having a boiling point lower than that of the second solvent and being an aliphatic alcohol.
- the third solvent from the first state including the first solvent, the second solvent, and the third solvent according to an atmospheric environment. Evaporates to a second state including the first solvent and the second solvent, and subsequently to the third solvent, the second solvent evaporates to a third state including the first solvent.
- the viscosity in a state including the first solvent, the second solvent, and the third solvent is 3 mPa ⁇ s or more and 20 mPa ⁇ s or less. It is.
- the viscosity in a state including the first solvent, the second solvent, and the third solvent is 3 mPa ⁇ s or more and 13 mPa ⁇ s or less. It is.
- the viscosity in a state where the third solvent evaporates and includes the first solvent and the second solvent is 20 mPa ⁇ s or more and 200 mPa. -S or less.
- the viscosity in a state where the third solvent evaporates and the first solvent and the second solvent are included is 30 mPa ⁇ s or more and 200 mPa. -S or less.
- the mixing ratio of the second solvent with respect to the sum of the second solvent and the third solvent is 30 mol% or more and 70 mol% or less.
- the total mixing ratio is 3 mol% or more and 20 mol% or less.
- the first solvent is phenoxytoluene
- the second solvent is dimethyl phthalate
- the third solvent is 1- Nonanol and the functional material is F8-F6.
- the boiling point of the first solvent is 260 ° C. or higher and 350 ° C. or lower
- the boiling point of the second solvent is 280 ° C. or higher and 350 ° C.
- the boiling point of the third solvent is 80 ° C. or higher and 250 ° C. or lower.
- the ink for an organic light-emitting element includes a functional material that forms a functional layer of the organic light-emitting element, a first solvent that dissolves the functional material, and a boiling point of the first solvent or less.
- the second solvent has a boiling point lower than the boiling point of the first solvent and the second solvent, dissociates part of the chemical bond between the molecules constituting the second solvent, and the viscosity of the second solvent
- a third solvent having a function of lowering.
- a part of the molecules constituting the second solvent is capable of hydrogen bonding, and the molecule constituting the third solvent is the second solvent.
- the second solvent has a diester skeleton
- the third solvent is an aliphatic alcohol
- the third solvent from the first state including the first solvent, the second solvent, and the third solvent according to an atmospheric environment. Evaporates to a second state including the first solvent and the second solvent, and subsequently to the third solvent, the second solvent evaporates to a third state including the first solvent.
- the viscosity in a state including the first solvent, the second solvent, and the third solvent is 3 mPa ⁇ s or more and 20 mPa ⁇ s or less. It is.
- the viscosity in a state including the first solvent, the second solvent, and the third solvent is 3 mPa ⁇ s or more and 13 mPa ⁇ s or less. It is.
- the viscosity in a state where the third solvent evaporates and includes the first solvent and the second solvent is 20 mPa ⁇ s or more and 200 mPa. -S or less.
- the viscosity in a state where the third solvent evaporates and the first solvent and the second solvent are included is 30 mPa ⁇ s or more and 200 mPa. -S or less.
- the mixing ratio of the second solvent with respect to the sum of the second solvent and the third solvent is 30 mol% or more and 70 mol% or less.
- the total mixing ratio is 3 mol% or more and 20 mol% or less.
- the first solvent is phenoxytoluene
- the second solvent is dimethyl phthalate
- the third solvent is 1- Nonanol and the functional material is F8-F6.
- the boiling point of the first solvent is 260 ° C. or higher and 350 ° C. or lower
- the boiling point of the second solvent is 280 ° C. or higher and 350 ° C.
- the boiling point of the third solvent is 80 ° C. or higher and 250 ° C. or lower.
- the concentration of the functional material is 0.1 wt% or more and less than 4 wt%.
- the method for producing an organic light emitting device is a first step of preparing ink for forming a functional layer of the organic light emitting device, the functional material constituting the functional layer, and the functionality
- the first solvent that dissolves the material has a boiling point that is lower than the boiling point of the first solvent, or a boiling point that is higher than the boiling point of the first solvent and that is different from the boiling point of the first solvent by 20 ° C. or less.
- a fifth step of forming a functional layer and a sixth step of forming a second electrode having a polarity different from that of the first electrode above the functional layer.
- the method for producing an organic light emitting device is a first step of preparing ink for forming a functional layer of the organic light emitting device, the functional material constituting the functional layer, and the functionality
- the first solvent that dissolves the material has a boiling point that is lower than the boiling point of the first solvent, or a boiling point that is higher than the boiling point of the first solvent and that is different from the boiling point of the first solvent by 20 ° C. or less.
- Substrate having an underlayer including a first electrode A second step of preparing, a third step of discharging the ink droplets from the ink jet apparatus to the underlayer, and applying the ink droplets discharged in the third step to the underlayer, A fourth step of forming an ink droplet film, a fifth step of drying the ink droplet film to form a functional layer including an organic light emitting layer, and a polarity different from that of the first electrode above the functional layer And a sixth step of forming a second electrode having the characteristics.
- the third step evaporates the third solvent from the ejected ink droplets, and determines the viscosity of the ink. Make it larger than the first step.
- the fourth step evaporates the third solvent from the applied ink droplets, and determines the viscosity of the ink. Make it larger than one step.
- the fourth step evaporates the second solvent following the third solvent from the applied ink droplets, The viscosity of the ink is further increased than in the first step.
- the fifth step dries the ink droplet film, evaporates the third solvent from the ink droplet film, The viscosity of the ink is made larger than that in the first step.
- the fifth step includes drying the ink droplet film, and continuing from the ink droplet film to the third solvent, The second solvent and the first solvent are evaporated in this order, and the viscosity of the ink is further increased than in the first step.
- An organic display panel according to one embodiment of the present invention is characterized by using an organic light emitting element manufactured by the method for manufacturing an organic light emitting element described above.
- An organic display device is characterized by using an organic light-emitting element manufactured by the method for manufacturing an organic light-emitting element described above.
- An organic light-emitting device is characterized by using an organic light-emitting element manufactured by the method for manufacturing an organic light-emitting element described above.
- the ink according to one embodiment of the present invention includes a functional material, a first solvent that dissolves the functional material, a boiling point that is equal to or lower than the boiling point of the first solvent, or higher than the boiling point of the first solvent.
- the ink according to one embodiment of the present invention includes a functional material, a first solvent that dissolves the functional material, a boiling point that is equal to or lower than the boiling point of the first solvent, or higher than the boiling point of the first solvent, A second solvent having a boiling point that is 20 ° C. or less different from the boiling point of the first solvent and having a viscosity higher than the viscosity of the first solvent; the boiling point of the first solvent; and the boiling point of the second solvent And a third solvent having a lower boiling point and having a function of dissociating part of chemical bonds between molecules constituting the second solvent and lowering the viscosity of the second solvent. And
- the third solvent evaporates, whereby the viscosity of 3 mPa ⁇ s to 20 mPa ⁇ s becomes 30 mPa ⁇ s to 200 mPa ⁇ s.
- a mixing ratio of a sum of the second solvent and the third solvent with respect to a sum of the first solvent, the second solvent, and the third solvent Is 3 mol% or more and 20 mol% or less.
- the concentration of the functional material is 0.1 wt% or more and less than 4 wt%.
- the method for forming a functional layer is a first step of preparing an ink for forming a functional layer, wherein the functional material constituting the functional layer and the functional material are dissolved.
- An ink is prepared by mixing a second solvent having a skeleton, a boiling point of the first solvent, a boiling point lower than the boiling point of the second solvent, and a third solvent that is an aliphatic alcohol.
- the method for forming a functional layer according to one aspect of the present invention is a first step of preparing an ink for forming a functional layer, wherein the functional material constituting the functional layer and the functional material are dissolved.
- 1 solvent and a boiling point that is lower than the boiling point of the first solvent, or a boiling point that is higher than the boiling point of the first solvent and that is different from the boiling point of the first solvent is 20 ° C. or less
- Forming a functional layer by preparing an ink mixed with a third solvent having a function of lowering the viscosity of the second solvent and dissociating the second solvent, and filling an ink jet apparatus having an ink discharge nozzle A second step of preparing a substrate for the above, A third step of ejecting the ink droplets from the ink jet device to the plate; and a fourth step of applying the ink droplets ejected in the third step to the substrate to form an ink droplet film. And a fifth step of drying the ink droplet film and forming a functional layer.
- the third step evaporates the third solvent from the ejected ink droplets, and determines the viscosity of the ink. Make it larger than one step.
- the fourth step evaporates the third solvent from the applied ink droplets, and determines the viscosity of the ink. Make it larger than the process.
- the fourth step includes evaporating the second solvent from the applied ink droplets to the third solvent, and The viscosity is further increased than in the first step.
- the fifth step includes drying the ink droplet film, evaporating the third solvent from the ink droplet film, The viscosity of the ink is made larger than that in the first step.
- the fifth step includes drying the ink droplet film, and continuing from the ink droplet film to the third solvent, The two solvents and the first solvent are evaporated in this order, and the viscosity of the ink is further increased than in the first step.
- An organic light-emitting device is provided with a functional layer formed by any one of the functional layer forming methods described above.
- An organic display panel according to one embodiment of the present invention is characterized by using the above organic light emitting element.
- An organic display device is characterized by using the above organic light emitting element.
- An organic light-emitting device is characterized by using the above organic light-emitting element.
- the present inventor first investigated how the viscosity of the ink affects the ink ejection performance.
- FIG. 1 is a graph showing the relationship between the viscosity of ink and the discharge angle ⁇ .
- the portion surrounded by a broken line indicates the viscosity region (II) of the conventional ink
- the left side of the viscosity region (II) is the viscosity region (I) of the ink having a lower viscosity than the conventional ink.
- the right side of the viscosity region (II) shows the viscosity region (III) of the ink having a higher viscosity than the ink of the conventional example.
- the discharge angle ⁇ increases (the landing accuracy decreases) as the ink viscosity increases. That is, the higher the ink viscosity, the worse the ejectability.
- the discharge angle ⁇ was evaluated with a standard deviation of 6 ⁇ .
- FIG. 2 is a diagram for explaining the influence of the ink viscosity on the ejection angle ⁇ .
- the solid line arrow A 1 indicates the actual ejection direction of the ink droplet
- the alternate long and short dash line arrow A 2 indicates the ideal ejection direction
- the angle formed by these directions is the ejection angle ⁇ .
- the reason why the discharge angle ⁇ increases as the viscosity of the ink increases is that the ligament length of the ink droplet increases as the viscosity increases. That is, as shown in FIG. 2 (a), if the ligament length is long, the ejection direction tends to shift due to the reaction when the ink droplet leaves the nozzle of the inkjet apparatus, and as shown in FIG. 2 (b) It is considered that the angle ⁇ is likely to increase. In addition, if the ligament length is long, the ink droplets are likely to flow due to the influence of the air flow, and it is considered that the discharge angle ⁇ is likely to increase.
- the present inventors investigated how the viscosity of the ink affects the flatness of the ink.
- FIG. 3 is a diagram showing the relationship between the viscosity of the ink and the flatness of the upper surface of the functional layer.
- the portion surrounded by the broken line indicates the viscosity region (II) of the conventional ink
- the left side of the viscosity region (II) indicates the viscosity region (I) of the ink having a lower viscosity than the conventional ink.
- the right side of the viscosity region (II) shows the viscosity region (III) of the ink having a higher viscosity than the ink of the conventional example.
- the flatness of the upper surface of the functional layer tended to decrease as the viscosity of the ink increased.
- FIG. 4 is a diagram for explaining a method of calculating the flat rate.
- the flatness ratio is determined by measuring the thickness distribution of the functional layer using an atomic force microscope (AFM), and based on the result, the maximum thickness value and the minimum thickness of the effective pixel range in the functional layer. It calculated by calculating
- the effective pixel range is a portion where voltage is applied when driving the organic light emitting element, and is a range between a position P 2 where the film thickness of the functional layer is 7.5 ⁇ m away from the position P 1 where the film thickness of the functional layer is 200 nm. .
- FIG. 5 is a diagram for explaining the influence of the viscosity of the ink on the flatness.
- the vapor concentration of the solvent is higher on the pixel central area than on the bank vicinity area. Because the pixel central area is surrounded on both sides by the bank vicinity area where solvent vapor is generated, the solvent vapor generated in the pixel central area can only diffuse upward, whereas the bank vicinity area is Since the solvent vapor is not generated from the region where the bank 5 on one side is present and a space with a low solvent vapor pressure is spread on the bank 5, the solvent vapor generated in the region near the bank is not only upward but also the bank. This is because it also diffuses to the 5 side.
- the viscosity of the ink 7a When the viscosity of the ink 7a is low, the ink 7a flows easily, so that the amount of the functional material 7b deposited increases in the vicinity of the bank, and the film thickness increases. On the other hand, if the viscosity of the ink 7a is high, the braking force that suppresses the flow of the ink 7a becomes strong, so that the film thickness does not increase and the flatness ratio decreases.
- FIG. 6 is a diagram summarizing the effects of ink viscosity on ejection properties and flatness.
- the result shown in FIG. 6 is obtained. That is, in the case of the viscosity of the conventional ink, the ejectability is good, but “ ⁇ ”, the flatness is not good “ ⁇ ”, and in the case of a lower viscosity, the ejectability is very good, but “ ⁇ ”.
- the flatness is poor, “X”, and when the viscosity is higher than that, the flatness is good, but “ ⁇ ”, and the ejection property is bad, “X”.
- the inks of the examples both have good ejection characteristics and flatness “ ⁇ ”.
- the discharge property and flatness of the ink are not always compatible with each other.
- composition changes in viscosity over time, specifically, it has a low viscosity until it is ejected and becomes a high viscosity after it is ejected, both the ejectability and flatness are good. I came to the idea.
- FIG. 7 is a conceptual diagram showing the composition of the ink according to one embodiment of the present invention.
- the ink according to one embodiment of the present invention includes a functional material, a first solvent, a second solvent, and a third solvent.
- the first solvent is a solvent for dissolving the functional material into an ink
- the second solvent is a solvent for increasing the viscosity of the ink
- the third solvent is used until the ink is ejected from the ink jet apparatus. It is a solvent for reducing the viscosity of two solvents. With this configuration, the ink has a low viscosity to ensure good ejection properties until it is ejected, and after ejection, has a high viscosity to ensure good flatness.
- the ink evaporates from the first state including the first solvent, the second solvent, and the third solvent, and includes only the first solvent and the second solvent, according to the atmospheric environment. Then, the second solvent evaporates following the third solvent, resulting in a third state including only the first solvent. The first state containing the third solvent is maintained until the ink is ejected from the ink jet apparatus. However, after the ink is ejected, the third solvent quickly evaporates to the second state. When the third solvent evaporates, that is, by changing from the first state to the second state, the ink changes from a low viscosity to a high viscosity.
- FIG. 8 is a diagram showing the viscosity of the solvent. As shown in FIG. 8, the solvent having a diester skeleton has a much higher viscosity due to the multimer effect than the solvent having a monoester skeleton. Because of such high viscosity, a solvent having a diester skeleton is preferable as the second solvent for increasing the viscosity of the ink.
- FIG. 9 is a diagram for explaining the viscosity of a solvent having a diester skeleton.
- the solvent having a diester skeleton has a higher viscosity than the solvent having a monoester skeleton, as shown in FIG. 9A, in the case of a solvent having a monoester skeleton, one ester bond per molecule. Even if an intermolecular hydrogen bond occurs at the position of the ester bond, only a dimer is formed. Therefore, the viscosity of the solvent does not become so high.
- the aliphatic alcohol molecules preferentially hydrogen bond with the solvent molecules having a diester skeleton.
- the hydrogen bond between the molecules of the solvent having a diester skeleton is dissociated and the multimer becomes a monomer, so that the solvent having a diester skeleton has a low viscosity.
- the aliphatic alcohol has two molecular hydrogen bonds. Therefore, if 2 mol or more of aliphatic alcohol is present per 1 mol of the solvent having a diester skeleton, all hydrogen bonds between molecules of the solvent having a diester skeleton are theoretically dissociated. Become.
- the aliphatic alcohol is preferable as the third solvent because it has an action of dissociating hydrogen bonds between molecules of the solvent having a diester skeleton. Moreover, if only the aliphatic alcohol is evaporated from the mixed solvent of the solvent having the diester skeleton and the aliphatic alcohol, hydrogen bonds are generated again between the molecules of the solvent having the diester skeleton, so that the solvent having the diester skeleton is again highly viscous. become.
- FIG. 10 is a diagram showing the influence of the mixing ratio of the solvent on the viscosity.
- the solvent A is a solvent having a diester skeleton
- the solvent B is a solvent having a viscosity lower than that of the solvent having a diester skeleton.
- various mixed solutions of the solvent A and the solvent B were prepared, and the viscosity gradient was confirmed by measuring the viscosity of the mixed solution.
- an alcohol-based solvent was used as the solvent B
- ether solvent, ketone solvent, alkylbenzene solvent Compared with the case where a solvent other than the alcohol solvent (ether solvent, ketone solvent, alkylbenzene solvent) was used as the solvent B, different tendencies in the viscosity gradient were observed.
- the viscosity of the mixed solvent is the solvent A itself, and when the mixing ratio of the solvent A is 0 mol%, the viscosity is the solvent B itself.
- the mixing ratio of the solvent A exceeds 0 mol% and less than 100 mol%, the viscosity of the mixed solvent is an intermediate viscosity between the solvent A and the solvent B, and the viscosity of the mixed solvent decreases as the mixing ratio of the solvent A decreases. Tend to be lower. Such a tendency is observed because the solvent A is simply diluted by mixing the solvent A and the solvent B, and the viscosity of the mixed solvent is lowered.
- the viscosity of the mixing solvent is not necessarily an intermediate viscosity between the solvent A and the solvent B, and the viscosity of the solvent B itself is within a specific range of mixing ratio. Less viscosity.
- the third solvent is a solvent having an effect of reducing the viscosity of the second solvent.
- the third solvent is mixed with the second solvent, chemical bonds between molecules of the second solvent are partially dissociated and the viscosity of the second solvent is lowered.
- the boiling point of the solvent In order to increase the viscosity after the ink is ejected from the ink jet apparatus, it is necessary to evaporate the third solvent before the second solvent. In addition, if the first solvent evaporates before the second solvent, the functional material dissolved in the first solvent may be precipitated. Therefore, the second solvent is put before the first solvent. It needs to be evaporated. Therefore, it is preferable that the boiling point of each solvent is set so that only the third solvent evaporates, then only the second solvent evaporates, and finally the first solvent evaporates. That is, the relationship between the boiling points of the solvents is preferably first solvent> second solvent> third solvent.
- FIG. 11 is a diagram summarizing the influence of the boiling point of the solvent on the dischargeability and flatness.
- the relationship between the boiling points of the solvents is preferably the relationship of the first solvent> the second solvent> the third solvent, but is not limited to this relationship.
- first solvent ⁇ second solvent> third solvent as a specific example of “first solvent ⁇ second solvent”, FIG. Even when the boiling point of the solvent is 20 ° C. higher than the boiling point of the first solvent), good flatness was obtained.
- the relationship between the boiling points of the respective solvents is as follows.
- the boiling point of the second solvent is equal to or lower than the boiling point of the first solvent or higher than the boiling point of the first solvent.
- the difference from the boiling point is preferably 20 ° C. or less.
- the boiling point of the third solvent is preferably lower than the boiling points of the first solvent and the second solvent.
- FIG. 12 is a diagram for explaining preferable conditions for the composition of the ink.
- specific preferred boiling points of the respective solvents are 260 to 350 ° C. for the first solvent, 280 to 350 ° C. for the second solvent, and 80 to 250 ° C. for the third solvent. With such a boiling point relationship, it is possible to obtain an ink suitable for an ink jet method having appropriate volatility and good film forming properties.
- a preferable range of the boiling point difference between the second solvent and the third solvent is 80 to 180 ° C. If the difference between the boiling points of the second solvent and the third solvent is within this range, after the ink is ejected from the ink jet apparatus, the viscosity of the ink can be quickly increased, and a flatter functional layer can be formed. it can.
- the viscosity of each solvent is not particularly limited, but the viscosity before the third solvent evaporates, that is, the ink contains the first solvent, the second solvent, and the third solvent.
- the viscosity in the first state is preferably 3 mPa ⁇ s or more and 20 mPa ⁇ s or less, and more preferably 3 mPa ⁇ s or more and 13 mPa ⁇ s or less.
- the viscosity after the third solvent has evaporated is 20 mPa ⁇ s or more and 200 mPa ⁇ s. s or less is preferable, and 30 mPa ⁇ s or more and 200 mPa ⁇ s or less is more preferable. Thereby, preferable flatness can be obtained.
- the concentration of the functional material in the ink is preferably 0.1% by weight or more and less than 4% by weight.
- FIG. 13 is a diagram showing the relationship between the concentration of the functional material and the film thickness of the functional layer.
- “Over spill” means that a droplet overflows from the bank
- “Dewet” means that a soaking area is generated in the bank.
- the concentration of the functional material is preferably 0.1% by weight or more, as shown in FIG. 13, when the concentration of the functional material is less than 0.1% by weight, the minimum film thickness value of the functional layer It is because there exists a possibility that may be less than 5 nm which is a practical range.
- FIG. 14 is a diagram showing the relationship between the concentration of the functional material and the ink viscosity.
- the reason why the concentration of the functional material in the ink is preferably less than 4% by weight is that, as shown in FIG. 14, when the concentration of the functional material is 4% by weight or more, the viscosity of the ink is applied to the nozzle of the ink jet apparatus. This is because the viscosity reaches 300 mPa ⁇ s.
- the ink according to one embodiment of the present invention includes a functional material, a first solvent, a second solvent, and a third solvent.
- the functional material is, for example, a material constituting the light emitting layer of the organic light emitting device, and specifically, F8-F6 (a copolymer of F8 (polydioctylfluorene) and F6 (polydihexylfluorene)) is preferable. .
- fluorene compounds other than F8-F6 such as F8 and F6, oxinoid compounds, perylene compounds, coumarin compounds, azacoumarin compounds, oxazole compounds, oxadiazole compounds, perinone compounds, pyrrolopyrrole compounds, naphthalene compounds, Anthracene compound, fluoranthene compound, tetracene compound, pyrene compound, coronene compound, quinolone compound and azaquinolone compound, pyrazoline derivative and pyrazolone derivative, rhodamine compound, chrysene compound, phenanthrene compound, cyclopentadiene compound, stilbene compound, diphenylquinone compound, styryl compound, Butadiene compounds, dicyanomethylenepyran compounds, dicyanomethylenethiopyran compounds, fluorescein compounds, pyrylium , Thiapyrylium compound, serenapyrylium compound
- the first solvent is a solvent that dissolves the functional material, and specifically, phenoxytoluene is preferable.
- phenoxytoluene cyclohexylbenzene, diethylbenzene, decahydronaphthalene, methylbenzoate, acetophenone, phenylbenzene, benzyl alcohol, tetrahydronaphthalene, isophorone, n-dodecane, dicyclohexyl, p-xylene glycol dimethyl ether and the like can be mentioned.
- These solvents may be used alone or in combination.
- the second solvent is a solvent having a thickening action, and specifically, dimethyl phthalate is preferable.
- dimethyl phthalate solvents having a diester skeleton such as diethyl phthalate and dipropyl phthalate are preferred. Further, it may be other than a solvent having a diester skeleton.
- the substituent may be in any positional relationship of ortho, meta, and para.
- a part of the constituent molecules can be chemically bonded, and the molecules constituting the third solvent preferentially form chemical bonds with the part of the constituent molecules, whereby the second solvent It is preferable that the chemical bond is dissociated and the viscosity of the second solvent is lowered.
- a solvent having a diester skeleton a part of the constituent molecules can be hydrogen-bonded, and when mixed with an alcohol solvent, the alcohol solvent molecules are preferential to the part of the constituent molecules.
- the chemical bond is not limited to a hydrogen bond.
- the third solvent is a solvent having an action of decreasing the viscosity of the second solvent, and specifically, 1-nonanol is preferable.
- 1-nonanol alcohol solvents such as aliphatic alcohols such as 2-ethylhexanol, decanol, 2-nonanol and 2-methyl-2-nonanol, and aromatic alcohols such as benzyl alcohol are preferred.
- the aliphatic alcohol is preferable because the molecule is not bulky and is likely to preferentially hydrogen bond with a solvent having a diester skeleton.
- FIG. 15 is a schematic diagram illustrating a stacked state of each layer of the organic display panel according to one embodiment of the present invention.
- an organic display panel 110 according to one embodiment of the present invention has a structure in which a color filter substrate 113 is bonded to the organic light emitting element 111 according to one embodiment of the present invention with a sealant 112 interposed therebetween. .
- the organic light emitting element 111 is a top emission type organic light emitting element in which RGB pixels are arranged in a matrix or a line, and each pixel has a stacked structure in which each layer is stacked on the TFT substrate 1.
- the first anode electrode 2 and the second anode electrode 3 constituting the first electrode are formed in a matrix shape or a line shape, and a hole injection layer 4 is laminated on the anode electrodes 2 and 3.
- a bank 5 defining pixels is formed on the hole injection layer 4, and a hole transport layer 6 and an organic light emitting layer 7 are laminated in this order in a region defined by the bank 5.
- an electron transport layer 8 on the organic light emitting layer 7, an electron transport layer 8, a cathode electrode 9 as a second electrode, and a sealing layer 10 are connected to the adjacent pixels beyond the area defined by the bank 5. It is formed to do.
- the region defined by the bank 5 has a multilayer laminated structure in which a hole injection layer 4, a hole transport layer 6, an organic light emitting layer 7 and an electron transport layer 8 are laminated in that order. Is configured.
- the functional layer may include other layers such as an electron injection layer.
- Typical functional layer configurations include (1) hole injection layer / organic light emitting layer, (2) hole injection layer / hole transport layer / organic light emitting layer, and (3) hole injection layer / organic light emitting layer / electron injection layer. (4) hole injection layer / hole transport layer / organic light emitting layer / electron injection layer, (5) hole injection layer / organic light emitting layer / hole blocking layer / electron injection layer, (6) hole injection layer / hole transport layer / Examples include organic light emitting layer / hole blocking layer / electron injection layer, (7) organic light emitting layer / hole blocking layer / electron injection layer, and (8) organic light emitting layer / electron injection layer.
- the TFT substrate 1 is, for example, alkali-free glass, soda glass, non-fluorescent glass, phosphoric acid glass, boric acid glass, quartz, acrylic resin, styrene resin, polycarbonate resin, epoxy resin, polyethylene, polyester, silicone type.
- An amorphous TFT (EL element drive circuit) is formed on a base substrate made of an insulating material such as resin or alumina.
- the first anode electrode 2 is made of, for example, Ag (silver), APC (silver, palladium, copper alloy), ARA (silver, rubidium, gold alloy), MoCr (molybdenum and chromium alloy), or NiCr (nickel and nickel). Chrome alloy) or the like.
- Ag silver
- APC silver, palladium, copper alloy
- ARA silver, rubidium, gold alloy
- MoCr molybdenum and chromium alloy
- NiCr nickel and nickel. Chrome alloy
- the second anode electrode 3 is interposed between the first anode electrode 2 and the hole injection layer 4 and has a function of improving the bonding property between the respective layers.
- the hole injection layer 4 is preferably formed of a metal compound such as metal oxide, metal nitride, or metal oxynitride.
- a metal compound such as metal oxide, metal nitride, or metal oxynitride.
- the metal oxide examples include Cr (chromium), Mo (molybdenum), W (tungsten), V (vanadium), Nb (niobium), Ta (tantalum), Ti (titanium), Zr (zirconium), and Hf ( Hafnium), Sc (scandium), Y (yttrium), Th (thorium), Mn (manganese), Fe (iron), Ru (ruthenium), Os (osmium), Co (cobalt), Ni (nickel), Cu ( Copper), Zn (zinc), Cd (cadmium), Al (aluminum), Ga (gallium), In (indium), Si (silicon), Ge (germanium), Sn (tin), Pb (lead), Sb ( Antimony), Bi (bismuth), and oxides such as so-called rare earth elements from La (lanthanum) to Lu (lutetium).
- Al 2 O 3 (aluminum oxide), CuO (copper oxide), and SiO (silicon oxide) are particularly
- the bank 5 is preferably formed of, for example, an organic material such as resin or an inorganic material such as glass.
- organic materials include acrylic resins, polyimide resins, novolac type phenol resins, and examples of inorganic materials include SiO 2 (silicon oxide), Si 3 N 4 (silicon nitride), and the like. It is done.
- the bank 5 preferably has resistance to organic solvents, preferably transmits visible light to a certain degree, and preferably has insulating properties. In addition, an etching process or a baking process may be performed. It is preferable to form with the material highly resistant to those processes.
- the bank 5 may be a pixel bank or a line bank.
- the bank 5 is formed so as to surround the entire circumference of the organic light emitting layer 7 for each pixel.
- the bank 5 is formed so as to divide a plurality of pixels into columns or rows, and the bank 5 exists only on both sides in the row direction or both sides in the column direction of the organic light emitting layer 7. Are in the same row or row.
- the hole transport layer 6 has a function of transporting holes injected from the anode electrodes 2 and 3 to the organic light emitting layer 7.
- PEDOT poly (3,4-ethylenedioxythiophene)
- -PSS polystyrene sulfonic acid
- a derivative thereof such as a copolymer
- the organic light emitting layer 7 has a function of emitting light using an electroluminescence phenomenon, and is preferably composed of, for example, a functional material included in the ink according to one embodiment of the present invention.
- the electron transport layer 8 has a function of transporting electrons injected from the cathode electrode 9 to the organic light emitting layer 7, and is preferably formed of, for example, barium, phthalocyanine, lithium fluoride, or a mixture thereof. .
- the cathode electrode 9 is made of, for example, ITO, IZO (indium zinc oxide) or the like. In the case of a top emission type organic light emitting device, it is preferably formed of a light transmissive material.
- the sealing layer 10 has a function of preventing the organic light emitting layer 7 or the like from being exposed to moisture or air, for example, a material such as SiN (silicon nitride) or SiON (silicon oxynitride). Formed with.
- a top emission type organic light emitting device it is preferably formed of a light transmissive material.
- the organic light emitting device 111 and the organic display panel 110 having the above-described configuration have good light emission characteristics because the organic light emitting layer 7 is formed using ink having good ejection properties and flatness.
- FIGS. 16 and 17 are process diagrams for describing a method for manufacturing an organic light-emitting element according to one embodiment of the present invention.
- the protective resist covering the TFT substrate 1 is peeled off, an organic resin is spin-coated on the TFT substrate 1, and patterning is performed by PR / PE (photoresist / photoetching).
- PR / PE photoresist / photoetching
- a planarizing film 1a (for example, 4 ⁇ m thick) is formed.
- the first anode electrode 2 is formed on the planarizing film 1a.
- the first anode electrode 2 is formed, for example, by forming a thin film by APC by sputtering and patterning the thin film in a matrix form by PR / PE (for example, a thickness of 150 nm).
- the first anode electrode 2 may be formed by vacuum deposition or the like.
- the second anode electrode 3 is formed in a matrix.
- the second anode electrode 3 is formed, for example, by forming an ITO thin film by a plasma vapor deposition method and patterning the ITO thin film by PR / PE (for example, a thickness of 110 nm).
- the hole injection layer 4 is formed on the second anode electrode 3.
- the hole injection layer 4 is formed by sputtering a material that performs a hole injection function and patterning the material by PR / PE (for example, a thickness of 40 nm).
- the hole injection layer 4 is formed not only on the anode electrode 3 but also over the entire upper surface of the TFT substrate 1.
- a bank 5 is formed on the hole injection layer 4.
- a region where the bank 5 is formed on the hole injection layer 4 is a region corresponding to a boundary between adjacent light emitting layer formation scheduled regions.
- the bank 5 is formed by forming a bank material layer so as to cover the whole of the hole injection layer 4 and removing a part of the formed bank material layer by PR / PE (for example, a thickness of 1 ⁇ m).
- the bank 5 may be a striped line bank that extends only in the vertical direction, or may be a pixel bank that extends in the vertical and horizontal directions and has a cross-sectional shape in the form of a cross.
- the hole transport layer 6 is formed by filling the recesses between the banks 5 with ink containing the material of the hole transport layer and drying (for example, a thickness of 20 nm). .
- the ink for the organic light emitting device is applied to the recesses between the banks 5 over the entire TFT substrate 1 by an ink jet method (droplet discharge method).
- the organic light emitting layer 7 is formed (for example, thickness 60 to 90 nm) by drying and baking the filled ink under reduced pressure.
- the method of filling the ink between the banks 5 is not limited to the ink jet method, and may be a dispenser method, a nozzle coating method, a spin coating method, intaglio printing, letterpress printing, or the like.
- the organic light emitting layer 7 is formed by sequentially performing the following first to fifth steps.
- ink is prepared and filled into an ink jet apparatus having ink ejection nozzles.
- a substrate having a base layer including the first electrode is prepared.
- this corresponds to the TFT substrate 1 on which the first anode electrode 2, the second anode electrode 3, the hole injection layer 4, the bank 5 and the hole transport layer 6 are formed.
- ink droplets are ejected from the inkjet device to the hole transport layer 6.
- the third solvent is evaporated from the ejected ink droplets to increase the viscosity of the ink.
- the ink droplets ejected in the third step are applied to the hole transport layer 6 to form an ink droplet film.
- the second solvent is evaporated to further increase the viscosity of the ink.
- the ink droplet film is dried to form the organic light emitting layer 7.
- the third solvent may be evaporated in the fourth step instead of the third step.
- the viscosity of the ink may be increased by evaporating the third solvent from the ink droplets applied to the hole transport layer 6.
- the third solvent may be evaporated in the fifth step instead of the third step.
- the ink droplet film may be dried, and the third solvent may be evaporated from the ink droplet film to increase the viscosity of the ink.
- the ink droplet film may be dried, and the second solvent and the first solvent may be evaporated in this order from the ink droplet to the third solvent to further increase the viscosity of the ink.
- the timing of evaporating the first solvent, the second solvent, and the third solvent can be controlled by the atmospheric environment.
- the electron transport layer 8 is formed by ETL deposition so as to cover the bank 5 and the organic light emitting layer 7 (thickness 20 nm).
- a second electrode having a polarity different from that of the first electrode is formed above the functional layer (sixth step).
- the cathode electrode 9 is formed from above the electron transport layer 8 by plasma deposition of a light transmissive material (thickness: 100 nm).
- a sealing layer 10 is formed by CVD from above the cathode electrode 9 (thickness: 1 ⁇ m).
- FIG. 18 illustrates an entire structure of a display device according to one embodiment of the present invention.
- FIG. 19 is a perspective view illustrating a television system using a display device according to one embodiment of the present invention.
- the organic display device 100 includes an organic display panel 110 according to an aspect of the present invention, and a drive control unit 120 connected thereto.
- the drive control unit 120 is composed of four drive circuits 121 to 124 and a control circuit 125.
- the arrangement and connection relationship of the drive control unit 120 with respect to the organic display panel 110 are not limited thereto.
- the organic display device 100 having the above configuration is excellent in image quality because it uses an organic light emitting element having good light emission characteristics.
- an organic light emitting device 200 includes a plurality of organic light emitting elements 210 according to one embodiment of the present invention, a base 220 on which the organic light emitting elements 210 are mounted, and organic light emission on the base 220. And a pair of reflecting members 230 attached so as to sandwich the element 210 therebetween.
- Each organic light emitting element 210 is electrically connected to a conductive pattern (not shown) formed on the base 220, and emits light by driving power supplied by the conductive pattern.
- the light distribution of a part of the light emitted from each organic light emitting element 210 is controlled by the reflecting member 230.
- the organic light emitting device 200 having the above configuration is excellent in image quality because it uses an organic light emitting element having good light emission characteristics.
- the ink for an organic light emitting device is not limited to the ink for forming the organic light emitting layer, and may be an organic material such as a hole transport layer, an electron transport layer, a hole injection layer, an electron injection layer, or a blocking layer. Ink for forming a functional layer other than the light emitting layer may be used.
- the organic light emitting device is not limited to the top emission type, and may be a bottom emission type.
- the organic light-emitting layer according to one embodiment of the present invention is not described with respect to the light emission color of the organic light-emitting layer.
- the present invention can be applied not only to a single color display but also to a full color display.
- the organic light emitting elements correspond to RGB sub-pixels, and adjacent RGB sub-pixels are combined to form one pixel, and the pixels are arranged in a matrix to form an image display area. Is formed.
- the ink according to one embodiment of the present invention is not limited to an organic light emitting element, and may be an inorganic light emitting element.
- the ink for an organic light emitting device can be widely used in a manufacturing process of an organic light emitting device by a wet process. Further, the organic light-emitting element according to one embodiment of the present invention can be widely used, for example, in the general fields of passive matrix or active matrix organic display devices and organic light-emitting devices.
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Abstract
Description
本発明の一態様に係る有機発光素子用インクは、有機発光素子の機能層を構成する機能性材料と、前記機能性材料を溶解する第1溶媒と、前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、ジエステル骨格を有する第2溶媒と、前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒とを含む、ことを特徴とする。
前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒とを含む、ことを特徴とする。
を有する、ことを特徴とする。
吐出性および平坦性の両方が良好なインクを得るに至った経緯を以下に説明する。
なお、有効画素範囲は、有機発光素子の駆動時において電圧がかかる箇所であり、機能層の膜厚が200nmの位置P1から画素中央側に7.5μm離れた位置P2間の範囲である。
本発明の一態様に係るインクは、機能性材料、第1溶媒、第2溶媒および第3溶媒を含む。
機能性材料は、例えば有機発光素子の発光層を構成する材料であって、具体的には、F8-F6(F8(ポリジオクチルフルオレン)とF6(ポリジヘキシルフルオレン)との共重合体)が好ましい。F8-F6以外には、F8、F6等のF8-F6以外のフルオレン化合物、オキシノイド化合物、ペリレン化合物、クマリン化合物、アザクマリン化合物、オキサゾール化合物、オキサジアゾール化合物、ペリノン化合物、ピロロピロール化合物、ナフタレン化合物、アントラセン化合物、フルオランテン化合物、テトラセン化合物、ピレン化合物、コロネン化合物、キノロン化合物およびアザキノロン化合物、ピラゾリン誘導体およびピラゾロン誘導体、ローダミン化合物、クリセン化合物、フェナントレン化合物、シクロペンタジエン化合物、スチルベン化合物、ジフェニルキノン化合物、スチリル化合物、ブタジエン化合物、ジシアノメチレンピラン化合物、ジシアノメチレンチオピラン化合物、フルオレセイン化合物、ピリリウム化合物、チアピリリウム化合物、セレナピリリウム化合物、テルロピリリウム化合物、芳香族アルダジエン化合物、オリゴフェニレン化合物、チオキサンテン化合物、アンスラセン化合物、シアニン化合物、アクリジン化合物、8-ヒドロキシキノリン化合物の金属錯体、2-ビピリジン化合物の金属錯体、シッフ塩とIII族金属との鎖体、オキシン金属錯体、希土類錯体、等が挙げられる(特開平5-163488号公報参照)。これら化合物や錯体は、単独で用いても良いし、複数を混合して用いても良い。
第1溶媒は、機能性材料を溶解する溶媒であって、具体的には、フェノキシトルエンが好ましい。フェノキシトルエン以外には、シクロヘキシルベンゼン、ジエチルベンゼン、デカハイドロナフタレン、メチルベンゾエート、アセトフェノン、フェニルベンゼン、ベンジルアルコール、テトラハイドロナフタレン、イソフォロン、n-ドデカン、ジシクロヘキシル、p-キシレングリコールジメチルエーテル等が挙げられる。これら溶媒は、単独で用いても良いし、複数を混合して用いても良い。
第2溶媒は、増粘作用を有する溶媒であって、具体的には、ジメチルフタレートが好ましい。ジメチルフタレート以外には、ジエチルフタレート、ジプロピルフタレート等ジエステル骨格を有する溶媒が好ましい。また、ジエステル骨格を有する溶媒以外であっても良い。なお、ジエステル骨格を有する溶媒に位置異性体が存在し得る場合において、置換基はオルト、メタ、パラのいずれの位置関係であっても良い。
第3溶媒は、第2溶媒の粘度を低下させる作用を有する溶媒であって、具体的には、1-ノナノールが好ましい。1-ノナノール以外には、2-エチルヘキサノール、デカノール、2-ノナノール、2-メチル-2-ノナノール等の脂肪族アルコールや、ベンジルアルコール等の芳香族アルコールなど、アルコール系の溶媒が好ましい。特に、脂肪族アルコールは分子が嵩高くないためジエステル骨格を有する溶媒とより優先的に水素結合し易いため好ましい。
図15は、本発明の一態様に係る有機表示パネルの各層の積層状態を示す模式図である。図15に示すように、本発明の一態様に係る有機表示パネル110は、本発明の一態様に係る有機発光素子111上にシール材112を介してカラーフィルター基板113を貼り合わせた構成を有する。
図16および図17に基づいて、本発明の一態様に係る有機発光素子の製造方法を説明する。図16および図17は、本発明の一態様に係る有機発光素子の製造方法を説明するための工程図である。
図18および図19に基づいて、本発明の一態様に係る有機表示装置について説明する。図18は、本発明の一態様に係る表示装置の全体構成を示す図である。図19は、本発明の一態様に係る表示装置を用いたテレビシステムを示す斜視図である。
図20は、本発明の一態様に係る有機発光装置を示す図であって、(a)は縦断面図、(b)は横断面図である。図20に示すように、有機発光装置200は、本発明の一態様に係る複数の有機発光素子210と、それら有機発光素子210が上面に実装されたベース220と、当該ベース220にそれら有機発光素子210を挟むようにして取り付けられた一対の反射部材230と、から構成されている。各有機発光素子210は、ベース220上に形成された導電パターン(不図示)に電気的に接続されており、前記導電パターンにより供給された駆動電力によって発光する。各有機発光素子210から出射された光の一部は、反射部材230によって配光が制御される。
以上、本発明の一態様に係る有機発光素子用インク、有機発光素子の製造方法、有機表示パネル、有機表示装置、有機発光装置、インク、機能層の形成方法、および有機発光素子を具体的に説明してきたが、上記実施の形態は、本発明の構成および作用・効果を分かり易く説明するために用いた例であって、本発明の内容は、上記の実施の形態に限定されない。
2,3 第1電極
7 有機発光層
7a インク
7b 機能性材料
9 第2電極
100 有機発光装置
110 有機表示パネル
111 有機発光素子
200 有機表示装置
Claims (49)
- 有機発光素子の機能層を構成する機能性材料と、
前記機能性材料を溶解する第1溶媒と、
前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、ジエステル骨格を有する第2溶媒と、
前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒と
を含む、ことを特徴とする有機発光素子用インク。 - 雰囲気環境に応じ、
前記第1溶媒、前記第2溶媒および前記第3溶媒を含む第1状態から、
前記第3溶媒が蒸発し、前記第1溶媒および第2溶媒を含む第2状態となり、
前記第3溶媒に引き続き前記第2溶媒が蒸発し、前記第1溶媒を含む第3状態となる、請求項1記載の有機発光素子用インク。 - 前記第1溶媒と前記第2溶媒と前記第3溶媒とを含む状態の粘度は、3mPa・s以上20mPa・s以下である、請求項1記載の有機発光素子用インク。
- 前記第1溶媒と前記第2溶媒と前記第3溶媒とを含む状態の粘度は、3mPa・s以上13mPa・s以下である、請求項3記載の有機発光素子用インク。
- 前記第3溶媒が蒸発し、前記第1溶媒と前記第2溶媒とを含む状態の粘度は、20mPa・s以上200mPa・s以下である、請求項1記載の有機発光素子用インク。
- 前記第3溶媒が蒸発し、前記第1溶媒と前記第2溶媒とを含む状態の粘度は、30mPa・s以上200mPa・s以下である、請求項5記載の有機発光素子用インク。
- 前記第2溶媒と前記第3溶媒との総和に対する前記第2溶媒の混合率は30mol%以上70mol%以下である、請求項1記載の有機発光素子用インク。
- 前記第1溶媒と前記第2溶媒と前記第3溶媒との総和に対する、前記第2溶媒と前記第3溶媒との総和の混合率は3mol%以上20mol%以下である、請求項1記載の有機発光素子用インク。
- 前記第1溶媒は、フェノキシトルエンであり、
前記第2溶媒は、ジメチルフタレートであり、
前記第3溶媒は、1-ノナノールであり、
前記機能性材料は、F8-F6である、
請求項1記載の有機発光素子用インク。 - 前記第1溶媒の沸点は、260℃以上350℃以下であり、
前記第2溶媒の沸点は、280℃以上350℃以下であり、
前記第3溶媒の沸点は、80℃以上250℃以下である、
請求項1記載の有機発光素子用インク。 - 有機発光素子の機能層を構成する機能性材料と、
前記機能性材料を溶解する第1溶媒と、
前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、前記第1溶媒の粘度よりも高い粘度を有する第2溶媒と、
前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し かつ、前記第2溶媒を構成する分子間における化学結合の一部を解離し、前記第2溶媒の粘度を低下させる作用を有する第3溶媒と
を含む、ことを特徴とする有機発光素子用インク。 - 第2溶媒を構成する分子の一部は水素結合可能であって、第3溶媒を構成する分子が、前記第2溶媒の構成分子の一部に対し優先的に水素結合を形成していることにより、前記第2溶媒の水素結合が解離し、前記第2溶媒の粘度が低下した状態である、
請求項11記載の有機発光素子用インク。 - 前記第2溶媒はジエステル骨格を有し、前記第3溶媒は脂肪族アルコールである、請求項11記載の有機発光素子用インク。
- 雰囲気環境に応じ、
前記第1溶媒、前記第2溶媒および前記第3溶媒を含む第1状態から、
前記第3溶媒が蒸発し、前記第1溶媒および第2溶媒を含む第2状態となり、
前記第3溶媒に引き続き前記第2溶媒が蒸発し、前記第1溶媒を含む第3状態となる、請求項11記載の有機発光素子用インク。 - 前記第1溶媒と前記第2溶媒と前記第3溶媒とを含む状態の粘度は、3mPa・s以上20mPa・s以下である、請求項11記載の有機発光素子用インク。
- 前記第1溶媒と前記第2溶媒と前記第3溶媒とを含む状態の粘度は、3mPa・s以上13mPa・s以下である、請求項15記載の有機発光素子用インク。
- 前記第3溶媒が蒸発し、前記第1溶媒と前記第2溶媒とを含む状態の粘度は、20mPa・s以上200mPa・s以下である、請求項11記載の有機発光素子用インク。
- 前記第3溶媒が蒸発し、前記第1溶媒と前記第2溶媒とを含む状態の粘度は、30mPa・s以上200mPa・s以下である、請求項17記載の有機発光素子用インク。
- 前記第2溶媒と前記第3溶媒との総和に対する前記第2溶媒の混合率は30mol%以上70mol%以下である、請求項11記載の有機発光素子用インク。
- 前記第1溶媒と前記第2溶媒と前記第3溶媒との総和に対する、前記第2溶媒と前記第3溶媒との総和の混合率は3mol%以上20mol%以下である、請求項11記載の有機発光素子用インク。
- 前記第1溶媒は、フェノキシトルエンであり、
前記第2溶媒は、ジメチルフタレートであり、
前記第3溶媒は、1-ノナノールであり、
前記機能性材料は、F8-F6である、
請求項11記載の有機発光素子用インク。 - 前記第1溶媒の沸点は、260℃以上350℃以下であり、
前記第2溶媒の沸点は、280℃以上350℃以下であり、
前記第3溶媒の沸点は、80℃以上250℃以下である、
請求項11記載の有機発光素子用インク。 - 前記機能性材料の濃度が0.1重量%以上4重量%未満である、請求項1または11記載の有機発光素子用インク。
- 有機発光素子の機能層を形成するためのインクを準備する第1工程であって、
機能層を構成する機能性材料と、前記機能性材料を溶解する第1溶媒と、前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、ジエステル骨格を有する第2溶媒と、前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒と、を混合させたインクを準備し、インク吐出ノズルを有するインクジェット装置に充填する第1工程と、
第1電極を含む下地層を有する基板を準備する第2工程と、
前記下地層に対し、前記インクジェット装置から前記インクの液滴を吐出させる第3工程と、
前記第3工程により吐出させた前記インク液滴を前記下地層に塗布し、インク液滴膜を形成する第4工程と、
前記インク液滴膜を乾燥させ、有機発光層を含む機能層を形成する第5工程と、
前記機能層の上方に、前記第1電極と異なる極性を有する第2電極を形成する第6工程と、を有する、
ことを特徴とする有機発光素子の製造方法。 - 有機発光素子の機能層を形成するためのインクを準備する第1工程であって、
機能層を構成する機能性材料と、前記機能性材料を溶解する第1溶媒と、前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ前記第1溶媒の粘度よりも高い粘度を有する第2溶媒と、前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し かつ、前記第2溶媒を構成する分子間における化学結合の一部を解離し、前記第2溶媒の粘度を低下させる作用を有する第3溶媒とを混合させたインクを準備し、インク吐出ノズルを有するインクジェット装置に充填する第1工程と、
第1電極を含む下地層を有する基板を準備する第2工程と、
前記下地層に対し、前記インクジェット装置から前記インクの液滴を吐出させる第3工程と、
前記第3工程により吐出させた前記インク液滴を前記下地層に塗布し、インク液滴膜を形成する第4工程と、
前記インク液滴膜を乾燥させ、有機発光層を含む機能層を形成する第5工程と、
前記機能層の上方に、前記第1電極と異なる極性を有する第2電極を形成する第6工程と、
を有する、ことを特徴とする有機発光素子の製造方法。 - 前記第3工程は、吐出させた前記インク液滴から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項24または25記載の有機発光素子の製造方法。 - 前記第4工程は、塗布した前記インク液滴から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項24または25記載の有機発光素子の製造方法。 - 前記第4工程は、塗布した前記インク液滴から前記第3溶媒に引き続き、前記第2溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりもさらに大きくする、
請求項27記載の有機発光素子の製造方法。 - 前記第5工程は、前記インク液滴膜を乾燥させ、前記インク液滴膜から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項24または25記載の有機発光素子の製造方法。 - 前記第5工程は、前記インク液滴膜を乾燥させ、前記インク液滴膜から前記第3溶媒に引き続き、前記第2溶媒および前記第1溶媒をこの順に蒸発させ、前記インクの粘度を、前記第1工程よりもさらに大きくする、請求項29記載の有機発光素子の製造方法。
- 請求項24~30のいずれかに記載された有機発光素子の製造方法により製造された有機発光素子を用いた、ことを特徴とする有機表示パネル。
- 請求項24~30のいずれかに記載された有機発光素子の製造方法により製造された有機発光素子を用いた、ことを特徴とする有機表示装置。
- 請求項24~30のいずれかに記載された有機発光素子の製造方法により製造された有機発光素子を用いた、ことを特徴とする有機発光装置。
- 機能性材料と、
前記機能性材料を溶解する第1溶媒と、
前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、ジエステル骨格を有する第2溶媒と、
前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒と
を含む、
ことを特徴とするインク。 - 機能性材料と、
前記機能性材料を溶解する第1溶媒と、
前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ前記第1溶媒の粘度よりも高い粘度を有する第2溶媒と、
前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し かつ、前記第2溶媒を構成する分子間における化学結合の一部を解離し、前記第2溶媒の粘度を低下させる作用を有する第3溶媒と
を含む、ことを特徴とするインク。 - 前記第3溶媒が蒸発することにより、3mPa・s以上20mPa・s以下であった粘度が30mPa・s以上200mPa・s以下になる、請求項34または35記載のインク。
- 前記第1溶媒と前記第2溶媒と前記第3溶媒との総和に対する、前記第2溶媒と前記第3溶媒との総和の混合率は3mol%以上20mol%以下である、請求項34または35記載のインク。
- 前記機能性材料の濃度が0.1重量%以上4重量%未満である、請求項34または35記載のインク。
- 機能層を形成するためのインクを準備する第1工程であって、
機能層を構成する機能性材料と、前記機能性材料を溶解する第1溶媒と、前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ、ジエステル骨格を有する第2溶媒と、前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し、かつ、脂肪族アルコールである第3溶媒とを混合させたインクを準備し、インク吐出ノズルを有するインクジェット装置に充填する第1工程と、
機能層を形成するための基板を準備する第2工程と、
前記基板に対し、前記インクジェット装置から前記インクの液滴を吐出させる第3工程と、
前記第3工程により吐出させた前記インク液滴を前記基板に塗布し、インク液滴膜を形成する第4工程と、
前記インク液滴膜を乾燥させ、機能層を形成する第5工程と、
を有する、
ことを特徴とする機能層の形成方法。 - 機能層を形成するためのインクを準備する第1工程であって、
機能層を構成する機能性材料と、前記機能性材料を溶解する第1溶媒と、前記第1溶媒の沸点以下である沸点、または、前記第1溶媒の沸点よりも高く、第1溶媒との沸点との差が20℃以下である沸点を有し、かつ前記第1溶媒の粘度よりも高い粘度を有する第2溶媒と、前記第1溶媒の沸点および第2溶媒の沸点よりも低い沸点を有し かつ、前記第2溶媒を構成する分子間における化学結合の一部を解離し、前記第2溶媒の粘度を低下させる作用を有する第3溶媒とを混合させたインクを準備し、インク吐出ノズルを有するインクジェット装置に充填する第1工程と、
機能層を形成するための基板を準備する第2工程と、
前記基板に対し、前記インクジェット装置から前記インクの液滴を吐出させる第3工程と、
前記第3工程により吐出させた前記インク液滴を前記基板に塗布し、インク液滴膜を形成する第4工程と、
前記インク液滴膜を乾燥させ、機能層を形成する第5工程と、
を有する、ことを特徴とする機能層の形成方法。 - 前記第3工程は、吐出させた前記インク液滴から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項39または40記載の機能層の形成方法。 - 前記第4工程は、塗布した前記インク液滴から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項39または40記載の機能層の形成方法。 - 前記第4工程は、塗布した前記インク液滴から前記第3溶媒に引き続き、前記第2溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりもさらに大きくする、
請求項42記載の機能層の形成方法。 - 前記第5工程は、前記インク液滴膜を乾燥させ、前記インク液滴膜から前記第3溶媒を蒸発させ、前記インクの粘度を、前記第1工程よりも大きくする、
請求項39または40記載の機能層の形成方法。 - 前記第5工程は、前記インク液滴膜を乾燥させ、前記インク液滴膜から前記第3溶媒に引き続き、前記第2溶媒および前記第1溶媒をこの順に蒸発させ、前記インクの粘度を、前記第1工程よりもさらに大きくする、請求項44記載の機能層の形成方法。
- 請求項39~45のいずれかに記載された機能層の形成方法により形成された機能層を備えた、ことを特徴とする有機発光素子。
- 請求項46記載の有機発光素子を用いた、ことを特徴とする有機表示パネル。
- 請求項46記載の有機発光素子を用いた、ことを特徴とする有機表示装置。
- 請求項46記載の有機発光素子を用いた、ことを特徴とする有機発光装置。
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JP2014102878A (ja) * | 2012-11-16 | 2014-06-05 | Seiko Epson Corp | 機能層形成用インク、インク容器、吐出装置、機能層の形成方法、有機el素子の製造方法、発光装置、電子機器 |
JP2015050095A (ja) * | 2013-09-03 | 2015-03-16 | セイコーエプソン株式会社 | 機能層形成用インクの製造方法、有機el素子の製造方法 |
JP2018016681A (ja) * | 2016-07-26 | 2018-02-01 | セイコーエプソン株式会社 | インク組成物、有機半導体素子の製造方法、有機半導体装置、および光学素子の製造方法 |
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Also Published As
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EP2590481A4 (en) | 2017-12-20 |
EP2590481A1 (en) | 2013-05-08 |
EP2590481B1 (en) | 2021-11-24 |
KR101646799B1 (ko) | 2016-08-08 |
KR20130044116A (ko) | 2013-05-02 |
CN102369249B (zh) | 2014-11-12 |
US20120001124A1 (en) | 2012-01-05 |
JP5543440B2 (ja) | 2014-07-09 |
CN102369249A (zh) | 2012-03-07 |
US8308979B2 (en) | 2012-11-13 |
JPWO2012001744A1 (ja) | 2013-08-22 |
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