WO2011158665A1 - Film miroir et dispositif réfléchissant pour la production d'énergie thermique solaire - Google Patents

Film miroir et dispositif réfléchissant pour la production d'énergie thermique solaire Download PDF

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Publication number
WO2011158665A1
WO2011158665A1 PCT/JP2011/062777 JP2011062777W WO2011158665A1 WO 2011158665 A1 WO2011158665 A1 WO 2011158665A1 JP 2011062777 W JP2011062777 W JP 2011062777W WO 2011158665 A1 WO2011158665 A1 WO 2011158665A1
Authority
WO
WIPO (PCT)
Prior art keywords
compound
silver
film
film mirror
layer
Prior art date
Application number
PCT/JP2011/062777
Other languages
English (en)
Japanese (ja)
Inventor
鈴木　隆行
Original Assignee
コニカミノルタオプト株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by コニカミノルタオプト株式会社 filed Critical コニカミノルタオプト株式会社
Publication of WO2011158665A1 publication Critical patent/WO2011158665A1/fr

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/08—Mirrors
    • G02B5/0808—Mirrors having a single reflecting layer
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S23/81—Arrangements for concentrating solar-rays for solar heat collectors with reflectors flexible
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S23/82—Arrangements for concentrating solar-rays for solar heat collectors with reflectors characterised by the material or the construction of the reflector
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0547—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/40—Solar thermal energy, e.g. solar towers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/52—PV systems with concentrators

Definitions

  • the amount of such a stabilizer used is not particularly limited as long as it matches the ink characteristics of the present invention.
  • the content is preferably 0.1% to 90% in terms of molar ratio with respect to the silver compound.
  • the sulfone compound examples include ⁇ -ketosulfone compounds, ⁇ -sulfonylsulfone compounds, diaryldisulfone compounds, and the like.
  • Preferred examples of the sulfone compound include 4-trisphenacyl sulfone, mesitylphenacyl sulfone, bis (phenylsulfonyl) methane, 4-chlorophenyl-4-methylphenyl disulfone compound, and the like.
  • Metal epoxy compounds such as those conventionally utilized in and together with vinyl chloride polymer compositions
  • epoxidized ether condensation products diglycidyl ethers of bisphenol A (ie, 4,4'- Dihydroxydiphenyldimethylmethane)
  • epoxidized unsaturated fatty acid esters especially esters of alkyls of about 2 to 2 carbon atoms of fatty acids of 2 to 22 carbon atoms, such as butyl epoxy stearate
  • various epoxies Long chain fatty acid triglyceride
  • Epoxidized vegetable oils and other unsaturated natural oils which are sometimes referred to as epoxidized natural glycerides or unsaturated fatty acids, which can be represented and exemplified by compositions of Lido etc.
  • a silver mirror surface can be formed on the base material coated in this manner through oxidation or reduction treatment other than heat treatment and irradiation treatment such as infrared rays, ultraviolet rays, electron beams, and lasers. Further, these processes may be combined.
  • thiol-based antioxidant examples include distearyl-3,3'-thiodipropionate, pentaerythritol-tetrakis- ( ⁇ -lauryl-thiopropionate), and the like.
  • a hindered amine light stabilizer containing only a tertiary amine is preferable.
  • bis (1,2,2,6,6-pentamethyl-4-piperidyl) is preferable.
  • a condensate of 1,2,2,6,6-pentamethyl-4-piperidinol / tridecyl alcohol and 1,2,3,4-butanetetracarboxylic acid is preferred.
  • the film mirror of the present invention preferably has a barrier layer.
  • the barrier layer there is no particular limitation on the formation method thereof, but a method of forming an inorganic oxide film by applying a ceramic precursor of an inorganic oxide film and then heating and / or irradiating ultraviolet rays is preferably used. It is done.
  • the thickness of the adhesive layer is preferably from 0.01 to 20 ⁇ m, more preferably from 0.1 to 10 ⁇ m, from the viewpoints of adhesiveness, smoothness, reflectance of the reflecting material, and the like.
  • a coating solution for a scratch-preventing layer having the following composition was prepared as a coating solution, applied on the transparent acrylic film using a microgravure coater so that the film thickness after curing was 3 ⁇ m, and the solvent was evaporated and dried. It hardened

Abstract

L'invention concerne un film miroir léger et flexible qui possède une excellente résistance aux intempéries et un bon facteur de réflexion spéculaire de la chaleur solaire, et qui permet d'éviter la diminution du facteur de réflexion spéculaire même dans les cas où le film miroir est utilisé dans un environnement hostile pendant une longue période. Le film miroir peut être produit en masse à moindre coût et possède une plus grande surface. L'invention concerne également un dispositif réfléchissant pour la production d'énergie thermique solaire qui utilise le film miroir. Ledit film miroir comprend une base en résine et au moins une couche réfléchissante en argent disposée sur la base en résine. Le film miroir est caractérisé en ce qu'il comprend une couche qui contient un composé qui capture une amine et une autre couche qui contient un composé complexe de l'argent qui est obtenu en faisant réagir un ou plusieurs composés d'argent représentés par la formule générale AgnX (1) et au moins un composé aminé.
PCT/JP2011/062777 2010-06-18 2011-06-03 Film miroir et dispositif réfléchissant pour la production d'énergie thermique solaire WO2011158665A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010139136 2010-06-18
JP2010-139136 2010-06-18

Publications (1)

Publication Number Publication Date
WO2011158665A1 true WO2011158665A1 (fr) 2011-12-22

Family

ID=45348072

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2011/062777 WO2011158665A1 (fr) 2010-06-18 2011-06-03 Film miroir et dispositif réfléchissant pour la production d'énergie thermique solaire

Country Status (1)

Country Link
WO (1) WO2011158665A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013141304A1 (fr) * 2012-03-22 2013-09-26 コニカミノルタ株式会社 Miroir à film, et dispositif de réflexion pour la génération d'énergie solaire
EP2952611A4 (fr) * 2013-04-05 2016-11-30 Kyb Corp Structure plaquée d'argent
JP2021053964A (ja) * 2019-09-30 2021-04-08 トッパン・フォームズ株式会社 積層体

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58169102A (ja) * 1982-03-30 1983-10-05 Agency Of Ind Science & Technol 反射鏡の製造方法
JP2003154610A (ja) * 2001-11-20 2003-05-27 Fuji Photo Film Co Ltd 親水性部材
JP2009535661A (ja) * 2006-04-29 2009-10-01 インクテック カンパニー リミテッド 有機銀錯体化合物を含む反射膜コーティング液組成物及びこれを用いた反射膜の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58169102A (ja) * 1982-03-30 1983-10-05 Agency Of Ind Science & Technol 反射鏡の製造方法
JP2003154610A (ja) * 2001-11-20 2003-05-27 Fuji Photo Film Co Ltd 親水性部材
JP2009535661A (ja) * 2006-04-29 2009-10-01 インクテック カンパニー リミテッド 有機銀錯体化合物を含む反射膜コーティング液組成物及びこれを用いた反射膜の製造方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013141304A1 (fr) * 2012-03-22 2013-09-26 コニカミノルタ株式会社 Miroir à film, et dispositif de réflexion pour la génération d'énergie solaire
JPWO2013141304A1 (ja) * 2012-03-22 2015-08-03 コニカミノルタ株式会社 フィルムミラー及び太陽熱発電用反射装置
EP2952611A4 (fr) * 2013-04-05 2016-11-30 Kyb Corp Structure plaquée d'argent
JP2021053964A (ja) * 2019-09-30 2021-04-08 トッパン・フォームズ株式会社 積層体
JP7344737B2 (ja) 2019-09-30 2023-09-14 Ｔｏｐｐａｎエッジ株式会社 積層体

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