WO2011104896A1 - 液晶表示装置、液晶表示装置の製造方法及び液晶表示装置の製造装置 - Google Patents
液晶表示装置、液晶表示装置の製造方法及び液晶表示装置の製造装置 Download PDFInfo
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- WO2011104896A1 WO2011104896A1 PCT/JP2010/053516 JP2010053516W WO2011104896A1 WO 2011104896 A1 WO2011104896 A1 WO 2011104896A1 JP 2010053516 W JP2010053516 W JP 2010053516W WO 2011104896 A1 WO2011104896 A1 WO 2011104896A1
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- plastic film
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Definitions
- the present invention particularly relates to a liquid crystal display device using a plastic film substrate, a method for manufacturing the liquid crystal display device, and a manufacturing apparatus for the liquid crystal display device.
- liquid crystal display devices have been mounted on various portable information devices such as mobile phones and PDAs (Personal Digital Assistants).
- portable information devices it is necessary to reduce power consumption as much as possible. Therefore, as a liquid crystal display device, a reflective liquid crystal display device or a transflective liquid crystal display device that uses external light as much as possible and suppresses the use of a backlight is used. It is preferable to use it.
- a liquid crystal is sandwiched between a first substrate and a second substrate which are arranged to face each other, and the opposite surface side where electrodes are provided on the first substrate and the second substrate. Are each covered with an alignment film, and the alignment state of the liquid crystal molecules contained in the liquid crystal is controlled by these alignment films. Further, the space between the first substrate and the second substrate is sealed with a sealing agent provided at the peripheral portion thereof, whereby the liquid crystal is filled and sealed between the first substrate and the second substrate. (Patent Document 1).
- a pair of glass substrates are used as the first substrate and the second substrate, the liquid crystal is sandwiched between the pair of glass substrates, the absorption polarizing plate disposed on one glass substrate side of the liquid crystal, and the other glass of the liquid crystal
- a reflection type polarizing plate arranged on the substrate side and one that applies a voltage to the liquid crystal by using external light to prevent a decrease in contrast due to external light reflection (Patent Document 2).
- the liquid crystal display devices In response to the recent demand for smaller and more compact liquid crystal display devices, the liquid crystal display devices have been designed to be thinner.
- a pair of glass substrates is used as a first substrate and a second substrate that are arranged opposite to each other, and a liquid crystal is sandwiched between the pair of glass substrates. Since a light shielding layer, a colored layer, a common electrode layer, an active element, and the like are formed, there is a certain limit in reducing the size and thickness of the device.
- the present invention has been made in view of the above circumstances, and a liquid crystal display device, a liquid crystal display device manufacturing method, and a liquid crystal display device that prevent a reduction in contrast due to reflection of external light and that can reduce the size and thickness of the device.
- An object is to provide a manufacturing apparatus.
- the present invention is configured as follows.
- the invention according to claim 1 is a liquid crystal display device in which an alignment film and a liquid crystal are sandwiched between a first substrate and a second substrate, and are bonded via a gap holding material and a sealant,
- the first substrate is a substrate in which a light shielding layer, a colored layer, and a common electrode layer are formed on a plastic film substrate
- the second substrate is a glass substrate in which active elements are formed in advance. It is a substrate bonded on a plastic film substrate
- the liquid crystal display device is characterized in that a barrier film is formed on one side or both sides of at least one of the plastic film substrates.
- the invention according to claim 2 is the liquid crystal display device according to claim 1, wherein the alignment film is a photo-alignment control type alignment film.
- the invention according to claim 3 is the liquid crystal display device according to claim 1, wherein the sealant is a photo-curing sealant.
- the invention according to claim 4 is the liquid crystal display device according to claim 1, wherein the gap retaining material is a columnar spacer formed in a light shielding layer region on the first substrate side.
- the invention according to claim 5 is a spherical spacer in which the gap retaining material is disposed between the first substrate and the second substrate and is disposed in a light shielding layer region on the first substrate side.
- the invention according to claim 6 is the liquid crystal display device according to claim 1, wherein the first substrate and the second substrate have a polarizing layer on a surface different from the bonding surface. It is.
- the invention according to claim 7 is the liquid crystal display device according to claim 1, wherein the second substrate is a substrate in which an active element is directly formed on a plastic film substrate.
- the active element of the second substrate is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 0.
- the invention according to claim 9 is the liquid crystal display device according to claim 1, wherein the light-shielding layer on the first substrate side is disposed above the active layer.
- the invention according to claim 10 is the liquid crystal display device according to claim 9, wherein the light-shielding layer on the first substrate side is formed immediately above the active layer.
- the invention according to claim 11 is a method of manufacturing a liquid crystal display device in which an alignment film and a liquid crystal are sandwiched between a first substrate and a second substrate and bonded via a gap holding material and a sealant.
- the first substrate includes a step of forming a light shielding layer on a plastic film substrate, a step of forming a colored layer, and a step of forming a common electrode.
- the second substrate includes a step of forming an active element on a glass substrate, and a step of bonding the glass substrate on a plastic film substrate.
- At least one of the plastic film substrates has a step of forming a barrier film on one side or both sides, Forming alignment films on the bonding surfaces of the first substrate and the second substrate,
- a method for manufacturing a liquid crystal display device comprising: a sealing agent drawing step by an ODF process, a liquid crystal filling step, a bonding step through the drawn sealing agent, and a step of curing the sealing agent. is there.
- At least one of the plastic film substrate of the first substrate and the plastic film substrate of the second substrate is in a roll shape. It is a manufacturing method of a display device.
- a columnar spacer disposed in the light shielding layer region on the first substrate side is formed by the photolithography method as the gap retaining material. This is a manufacturing method of the liquid crystal display device.
- a spherical spacer disposed between the first substrate and the second substrate and disposed in a light shielding layer region on the first substrate side, 12.
- the invention described in claim 15 is characterized in that a polarizing layer is formed by a bonding method on a surface different from the bonding surface of the first substrate and the second substrate. This is a manufacturing method of the liquid crystal display device.
- the invention described in claim 16 is characterized in that a polarizing layer is formed by a coating method on a surface different from the bonding surface of the first substrate and the second substrate.
- a method for manufacturing a liquid crystal display device is characterized in that a polarizing layer is formed by a coating method on a surface different from the bonding surface of the first substrate and the second substrate.
- the invention described in claim 17 is the method for manufacturing a liquid crystal display device according to claim 11, wherein the second substrate is manufactured by a method of directly forming an active element on a plastic film substrate. is there.
- the active element of the second substrate is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 18.
- the invention according to claim 19 is characterized in that the first substrate and the second substrate are bonded together so that the light shielding layer on the first substrate side is disposed above the active layer.
- Item 19 A method for producing a liquid crystal display device according to Item 18.
- the invention according to claim 20 is the method for manufacturing a liquid crystal display device according to claim 18, wherein the light-shielding layer on the first substrate side is formed just above the active layer by a photolithography method. is there.
- a liquid crystal display device manufacturing apparatus that executes the liquid crystal display device manufacturing method according to any one of the eleventh to seventeenth aspects of the present invention to manufacture the liquid crystal display device. It is.
- the present invention has the following effects.
- the first substrate is a substrate in which a light shielding layer, a colored layer, and a common electrode layer are formed on a plastic film substrate, and an active element is formed in advance on the second substrate.
- the glass substrate thus bonded is a substrate bonded onto a plastic film substrate, a barrier film is formed on one side or both sides of at least one of the plastic film substrates, and the plastic film is formed on the first substrate and the second substrate.
- the alignment film is a photo-alignment control type alignment film and does not require rubbing treatment. Therefore, no dust is generated due to scraping of the alignment film, and static electricity due to friction is not generated.
- optical alignment control since it is a non-contact method called optical alignment control, uniform alignment treatment can be performed on the entire surface without being affected by the unevenness of the underlying film.
- the sealing agent is a photo-curing type sealing agent, and the curing time can be shortened as compared with the conventional thermosetting type. Moreover, since heat is not used, the expansion of the plastic film substrate as a base material can be suppressed, and the liquid crystal display device to be cured can be downsized.
- the gap holding material is a columnar spacer formed in the light shielding layer region on the first substrate side, the columnar spacer is formed only in the light shielding layer region of the first substrate, and the opening Since no spacers are present and alignment disorder does not occur, the contrast is high.
- the gap retaining material is a spherical spacer disposed between the first substrate and the second substrate and disposed in the light shielding layer region on the first substrate side. Since the spherical spacer is disposed only in the light-shielding layer region of the substrate, the spacer does not exist in the opening and alignment disorder does not occur, so the contrast is high. In addition, since the spherical spacer is more elastically deformed and less plastically deformed than the columnar spacer, the liquid crystal display device can flexibly cope with external pressure.
- the first substrate and the second substrate have a polarizing layer on a surface different from the bonding surface, and enable transmission control of backlight light passing through the liquid crystal display device. Yes.
- the second substrate is a substrate in which an active element is directly formed on a plastic film substrate, and by directly forming the active element, the liquid crystal display device is light and thin, It becomes difficult to break.
- the active element of the second substrate is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 2 Since the active layer containing a non-metallic element is transparent to visible light, the transmittance of the display device is increased, and the power consumption of the backlight can be reduced. Moreover, since it has flexibility, it bends well and a performance characteristic improves.
- the light shielding layer on the first substrate side is disposed above the active layer, and when the external light from the viewing direction enters the display device, the incident light does not hit the active layer. For this reason, malfunctions and characteristic changes of the active layer are less likely to occur.
- the light shielding layer on the first substrate side is formed immediately above the active layer, and when the external light from the viewing direction enters the display device, the incident light does not hit the active layer. It is possible to suppress malfunctions and characteristic changes of the active layer. Further, since the light shielding layer is disposed immediately above the active layer, the internally scattered light of the backlight light entering the display device does not hit the active layer, and the characteristic change is further less likely to occur.
- the first substrate forms a light shielding layer, a colored layer, and a common electrode on a plastic film substrate
- the second substrate forms an active element on a glass substrate.
- a glass substrate is bonded onto a plastic film substrate, and at least one of the plastic film substrates is formed with a barrier film on one or both sides, so that transmission of impurities such as water vapor and gas from the outside can be suppressed, and a liquid crystal display The reliability of the device is improved.
- alignment films are formed on the bonding surfaces of the first substrate and the second substrate, respectively, drawing of the sealing agent by ODF process, filling of the liquid crystal, bonding through the drawn sealing agent, and curing the sealing agent
- ODF process drawing of the sealing agent by ODF process
- filling of the liquid crystal bonding through the drawn sealing agent
- curing the sealing agent By using the ODF process, a roll-to-roll paneling process can be realized.
- At least one of the plastic film substrate of the first substrate or the plastic film substrate of the second substrate is in a roll shape, and a panel forming process in a roll-to-roll system is realized.
- the manufactured display panel can be rolled up.
- columnar spacers arranged in the light shielding layer region on the first substrate side as the gap holding material are formed by a photolithography method, and the light shielding layer region on the first substrate side is highly accurate. Since the light shielding layer line width can be reduced, the transmittance of the liquid crystal display device is improved.
- a spherical spacer disposed between the first substrate and the second substrate and disposed in the light-shielding layer region on the first substrate side as the gap holding material is determined by a fixed point arrangement method.
- the light shielding layer region on the first substrate side can be arranged and formed with high accuracy and the light shielding layer line width can be reduced, so that the transmittance of the liquid crystal display device is increased.
- the liquid crystal display device can be made thin, light and difficult to break by manufacturing the second substrate by a method of directly forming an active element on a plastic film substrate.
- the active element of the second substrate is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 2 Since the active layer containing the nonmetallic element is formed by the sputtering method and can be formed by the sputtering method (room temperature) without using the conventional plasma CVD (300 ° C.), a low environmental load and a low temperature process are possible.
- the first substrate and the second substrate are bonded so that the light shielding layer on the first substrate side is disposed above the active layer, and external light from the viewing direction is displayed on the display device.
- the active layer When incident on the active layer, no incident light strikes the active layer, so that the malfunction and characteristic change of the active layer are less likely to occur.
- the light shielding layer on the first substrate side can be formed by photolithography just above the active layer and can be arranged and formed with high accuracy, and the light shielding layer line width can be narrowed.
- the transmittance of the liquid crystal display device is increased.
- the liquid crystal display device is lightweight and thin, It becomes difficult to break.
- Embodiments of a liquid crystal display device, a liquid crystal display device manufacturing method, and a liquid crystal display device manufacturing device according to the present invention will be described below. Although this embodiment shows a preferred embodiment, the present invention is not limited to this.
- FIG. 1 is a schematic configuration diagram of a liquid crystal display device
- FIG. 2 is a schematic configuration diagram of a plastic film substrate as a second substrate.
- the alignment films 12 and 13 and the liquid crystal 14 are sandwiched between the first substrate 10 and the second substrate 11, and the gap holding material 15 and the sealant 16 are provided. It is pasted through.
- the first substrate 10 is a substrate in which a light shielding layer 10b, a colored layer 10c, and a common electrode layer 10d are formed on a plastic film substrate 10a, and an alignment film 12 is formed on the common electrode layer 10.
- the second substrate 11 is a substrate in which a glass substrate 11a on which an active element 17 is previously formed is bonded onto a plastic film substrate 11b.
- the plastic film substrate 10a is provided with inorganic barriers 10e and 10f on both sides, and a resin barrier 10g is provided on the inorganic barrier 10e.
- the plastic film substrate 11b is formed with inorganic barriers 11c and 11d on both sides, and a glass substrate 11a is provided on the inorganic barrier 11c via an adhesive 11e, and on the inorganic barrier 11d.
- a resin barrier 11f is provided.
- the barrier film is formed on one side or both sides of at least one of the plastic film substrates.
- the active element 17 of the second substrate 11 is a mixture of oxygen (O) and nitrogen (N), and includes a nonmetallic element having a ratio of N to O (N number density / O number density) of 0 to 2.
- An active layer 17a is provided.
- the active element 17 of the second substrate 11 is a mixture of oxygen (O) and nitrogen (N), and includes a nonmetallic element having a ratio of N to O (N number density / O number density) of 0 to 2. Since the active layer 17a is included and visible light is transmissive, the transmittance of the display device is increased and low power consumption of the backlight is possible. Moreover, since it has flexibility, it bends well and a performance characteristic improves.
- This active layer 17a is produced from a combination of a metal raw material (In 2 O 3 , SnO 2 ) and an insulator raw material (Si 3 N 4 ). Even if nitride is used as the metal raw material, it is an insulator itself from the beginning. Therefore, no matter how much it is mixed with other insulator raw materials, a semiconductor cannot be formed. For this reason, the metal raw material uses the oxide which is a metal itself. On the other hand, when nitride is used as the insulator raw material, a semiconductor produced by mixing both becomes an oxynitride mixture containing both oxygen (O) and nitrogen (N). The state of mixing is expressed by the following formula. The mixing ratios x and y can be determined under conditions where the positive and negative valences are balanced.
- the mixing ratio x of the main metal raw material In 2 O 3 and the mixing ratio y of the insulator material Si 3 N 4 are set, the mixing ratio of the subordinate metal raw material SnO 2 is 6 ⁇ x from the valence balance.
- N 12-18 (typical value 17)
- N 0 to 24 (typical value 12).
- N 1: 0 to 2
- Number ratio of nitrogen to oxygen 1 that is, ratio of nitrogen (N) to oxygen (O) (N number density / O number density) is 0 to 2.
- an active element having an active layer 17a containing a nonmetallic element having a ratio of N to O (N number density / O number density) of 0 to 2 in a mixture of oxygen (O) and nitrogen (N). 17 can obtain performance equal to or higher than that of the active element 17 using amorphous silicon formed on the glass substrate at 200 ° C. or higher even when formed at a temperature of 200 ° C. or lower. Is also suitable for forming on a plastic substrate having a low heat-resistant temperature. Further, an active element 17 having a high field effect mobility can be easily obtained, and this active element 17 is suitable for a large screen and high-definition display using an organic EL element as a current driving element.
- the ratio of nitrogen (N) to oxygen (O) is in the range of 0 to 2 because the above-mentioned ratio of nitrogen (N) to oxygen (O) (N number density). / O number density) is determined from the balance between the band gap and the valence as described in the section from 0 to 2. If this value becomes 0 (no nitrogen is present at all), depending on the amount of oxygen, the band gap of the active layer 17a is too small to be metallic, and the active element 17 is always on. On the other hand, when this value exceeds 2 (oxygen deficiency, nitrogen excess), the band gap of the active layer becomes too large and becomes insulating, and the active element 17 is always in the OFF state. In either case, a problem occurs as an active element characteristic.
- the first substrate 10 is a substrate in which the light shielding layer 10b, the colored layer 10c, and the common electrode layer 10d are formed on the plastic film substrate 10a
- the second substrate 11 Is a substrate in which a glass substrate 11a on which an active element 17 has been formed in advance is bonded onto a plastic film substrate 11b.
- At least one of the plastic film substrate 11b is provided with a barrier film on one side or both sides.
- the alignment films 12 and 13 are optical alignment control type alignment films and do not require a rubbing process, no dust is generated due to scraping of the alignment films 12 and 13, and static electricity due to friction does not occur.
- it is a non-contact method called optical alignment control, uniform alignment treatment can be performed on the entire surface without being affected by the unevenness of the underlying film.
- the sealing agent 16 is a photo-curing type sealing agent, and the curing time can be shortened as compared with the conventional thermosetting type. Moreover, since the sealing agent 16 does not use heat for curing, the expansion of the plastic film substrates 10a and 11b, which are base materials, can be suppressed, and the curing device can be downsized.
- the gap retaining material 15 is a columnar spacer 15a, and one end portion is formed in contact with the alignment film 12, and the other end portion is formed in contact with the alignment film 13, but the position of the one end portion is the first position. It is formed in the light shielding layer region on the substrate 10a side, and the other end portion is formed in the light shielding active device region on the second substrate 11b side.
- the gap retaining material 15 is a columnar spacer 15a disposed between the first substrate 10a and the second substrate 11b and formed in the light shielding layer region on the first substrate 10a side.
- FIG. 3 is a schematic configuration diagram of the liquid crystal display device according to the second embodiment.
- the same components as those in the first embodiment are denoted by the same reference numerals, and description thereof is omitted.
- the gap retaining member 15 uses a spherical spacer 15b as shown in FIG.
- a part of the spherical spacer 15b is formed in contact with the alignment film 12, and the other part is formed in contact with the alignment film 13.
- a part of the spherical spacer 15b is formed in the light shielding layer region on the first substrate 10a side.
- the other portion is formed in the active element region on the second substrate 11b side.
- the gap retaining material 15 is a spherical spacer 15b disposed between the first substrate 10a and the second substrate 11b and disposed in the light shielding layer region on the first substrate 10a side. Since the spherical spacer 15b is disposed only in the light shielding layer region of the substrate 10a, the spacer does not exist in the opening 12a of the alignment film 12, and the alignment is not disturbed. Therefore, the contrast is high. In addition, since the spherical spacer 15b is more elastically deformed and less plastically deformed than the columnar spacer 15a, the liquid crystal display device can flexibly cope with external pressure.
- FIG. 4 is a schematic configuration diagram of the liquid crystal display device according to the third embodiment.
- the same components as those in the first embodiment are denoted by the same reference numerals, and description thereof is omitted.
- the first substrate 10a and the second substrate 11b have polarizing layers 20 and 21 on a surface different from the bonding surface, and transmit backlight light through the liquid crystal display device. Allows control.
- FIG. 5 is a schematic configuration diagram of a liquid crystal display device according to a fourth embodiment.
- the same components as those in the first embodiment are denoted by the same reference numerals, and description thereof is omitted.
- the second substrate 11 is a substrate in which the active element 17 is directly formed on the plastic film substrate 11b. By forming the active element 17 directly, the second substrate 11 is lighter and thinner. It becomes difficult to break.
- FIG. 6 is a schematic configuration diagram of a liquid crystal display device according to a fifth embodiment.
- the same components as those in the first embodiment are denoted by the same reference numerals, and description thereof is omitted.
- the light shielding layer 22 on the first substrate 10a side is disposed above the active layer 17a, and incident light enters the active layer 17a when external light from the viewing direction enters the liquid crystal display device. Therefore, malfunction and characteristic change of the active layer 17a are less likely to occur.
- the light shielding layer 22 on the first substrate 11b side is formed immediately above the active layer 17a, when the external light from the viewing direction enters the liquid crystal display device, the incident light does not hit the active layer 17a. Thus, malfunctions and characteristic changes of the active layer 17a can be suppressed. Further, since the light shielding layer 22 is disposed immediately above the active layer 17a, the internally scattered light of the backlight light entering the liquid crystal display device does not hit the active layer 17a, and the characteristic change is further less likely to occur.
- FIG. 7 is a schematic configuration diagram of the first substrate manufacturing apparatus
- FIG. 8 is a schematic configuration diagram of the second substrate manufacturing apparatus
- FIG. 9 is a schematic configuration diagram of a bonding apparatus for the first substrate and the second substrate. .
- the manufacturing apparatus of the liquid crystal display device of this embodiment includes a first substrate manufacturing apparatus in FIG. 7, a second substrate manufacturing apparatus in FIG. 8, and a bonding of the first substrate and the second substrate in FIG.
- a liquid crystal display device is manufactured by sandwiching an alignment film and a liquid crystal between a first substrate and a second substrate and bonding them with a gap holding material and a sealant.
- the first substrate manufacturing apparatus in FIG. 7 has a delivery unit 101 and a take-up unit 102, sends out a roll-shaped plastic film substrate 10a from the delivery unit 101, and winds it on the take-up unit 102.
- a barrier film forming part 110 that forms a barrier film on one or both sides of the plastic film substrate 10a and a light shielding layer that forms a light shielding layer 10b on the plastic film substrate 10a Part 103, colored layer forming part 104 for forming colored layer 10c, common electrode forming part 105 for forming common electrode 10d, and alignment film forming part for forming alignment film 12 on the bonding surface of first substrate 10 106, a gap retaining material forming portion 107, and a polarizing layer bonding portion 111 are arranged.
- a columnar spacer 15a disposed in the light shielding layer region on the first substrate 10a side is formed by a photolithography method.
- the columnar spacers 15a can be arranged and formed with high accuracy in the light shielding layer region on the first substrate 10a side by photolithography, and the light shielding layer line width can be narrowed, so that the transmittance of the display panel is improved.
- a spherical spacer 15b disposed between the first substrate 10a and the second substrate 11b and disposed in the light shielding layer region on the first substrate 10a side.
- the spherical spacers 15b can be arranged and formed with high accuracy in the light shielding layer region on the first substrate 10a side by the fixed point arrangement method, and the light shielding layer line width can be reduced, so that the transmittance of the display panel is increased.
- the polarizing layer 20 is formed by a bonding method on a surface different from the bonding surface of the first substrate 10, and the polarizing layer 20 is formed by a bonding method, thereby reducing the thickness. Is possible.
- the polarizing layer 20 can be formed by a coating method, and the thickness can be reduced by forming the polarizing layer 20 by a coating method.
- the plastic film substrate 10a of the first substrate 10 is in a roll shape, and a roll-to-roll panel forming process is realized in which the plastic film substrate is fed from the roll shape and wound into a roll shape.
- the produced display panel can be wound up in a roll shape.
- the second substrate manufacturing apparatus in FIG. 8 has a delivery unit 201 and a take-up unit 202, and feeds the roll-shaped plastic film substrate 11 b from the delivery unit 201 and winds it on the take-up unit 202.
- the part 206 and the polarizing layer bonding part 211 are arrange
- the second substrate 11 is manufactured by a method of directly forming the active element 17 on the plastic film substrate 11b, and the display panel can be made thin, light and difficult to break.
- the active element 17 of the second substrate 11 is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 2.
- An active layer 17a containing is formed by sputtering.
- the sputtering method is performed by the sputtering apparatus shown in FIGS.
- the sputtering apparatus 321 includes roll winding mechanisms 322a and 322b, a feeding mechanism 323, a winding mechanism 324, an alignment mechanism 325, and metal targets 326a and 326b.
- a vacuum chamber 327 for holding is provided.
- This vacuum chamber 327 has opening / closing doors 327a, 327b on the roll winding mechanisms 322a, 322b side, opens / closes the opening / closing door 327a, sets a roll-shaped film substrate P, opens / closes the opening / closing door 327b, and the active layer 17a
- the provided roll-shaped film substrate P is taken out.
- the roll winding mechanism 322a mounts the roll film substrate P on the rotation shaft 322a1, the rotation shaft 322a1 rotates by feeding the roll film substrate P, and the roll winding mechanism 322b causes the roll film substrate P to rotate on the rotation shaft 322b1.
- the rotating shaft 322b1 is rotated by winding the roll-shaped film substrate P.
- the delivery mechanism 323 has a pair of delivery rollers 323a, and feeds the roll-shaped film substrate P from one end along the longitudinal direction by the rotation of the pair of delivery rollers 323a.
- the winding mechanism 324 has a pair of winding rollers 324b, and winds the roll-shaped film substrate P from one end along the longitudinal direction by the rotation of the pair of winding rollers 324b.
- the alignment mechanism 325 includes a detection sensor 325a, a control device 325b, and a roller drive device 325c.
- the detection sensor 325a detects the alignment pattern A of the roll-shaped film substrate P shown in FIG. 11, and controls this detection information.
- the control device 325b controls the delivery mechanism 323 and the winding mechanism 324 via the roller driving device 325c, and performs planar alignment of the roll-shaped film substrate P.
- the vacuum chamber 327 is in a vacuum state by being driven by a vacuum pump 328.
- the vacuum chamber 327 is provided with a gas introduction mechanism 329.
- the gas introduction mechanism 329 supplies an atmospheric gas containing a nonmetallic element to the vacuum chamber 327. To introduce.
- the metal targets 326a and 326b face the semiconductor forming surface of the roll film substrate P and are arranged at linear positions along the length of the roll film substrate P.
- the metal target 326a is a metal element target, and the metal target 326ba is a metalloid element target.
- the sputtering apparatus 321 uses metal targets 326a and 326b, and a mixture of a plurality of elements including at least one of a non-metal element, a metal element, and a metalloid element is used as a single target.
- 326b is a very good target.
- the sputtering apparatus 321 introduces the atmospheric gas containing the nonmetallic element into the vacuum chamber 327 by the gas introduction mechanism 329, and the metal elements or metalloid elements of the metal targets 326a and 326b or these elements into the vacuum chamber 327.
- the metal targets 326a and 326b When a plurality of metal targets including a mixture of the above are arranged and a high voltage is applied to the metal targets 326a and 326b through the electrodes, atoms on the surface of the metal target are repelled, and an atmospheric gas containing a nonmetallic element introduced into the vacuum chamber 327 Then, the active layer 17a can be formed on the roll-shaped film substrate P by reacting with the repelled metal.
- the active layer 17a can be formed by a low temperature process, and a low process cost can be realized.
- the active layer 17a can realize a relatively high field effect mobility and can manufacture a liquid crystal display device having stable characteristics against light and heat.
- the active layer 17a can freely control the band gap, and can manufacture a liquid crystal display device capable of increasing the field effect mobility.
- the sputtering apparatus 321 includes a vacuum chamber 327 that holds all the mechanisms inside, and can be wound from the roll state to the feed roll state at the time of manufacturing to realize a low process cost.
- the sputtering apparatus 321 introduces an atmospheric gas containing a nonmetallic element into the vacuum chamber 327, has a plurality of metal targets 326a and 326b containing a metal element, a metalloid element, or a mixture thereof, and the metal targets 326a and 326b.
- the active layer 17a having a uniform property can be formed in the roll-shaped film substrate P by being arranged at linear positions along the length of the roll-shaped film substrate P.
- the active element 17 of the second substrate 11 is a mixture of oxygen (O) and nitrogen (N), and the ratio of N to O (N number density / O number density) is 0 to 2. Since the active layer 17a containing the metal element is formed by sputtering and can be formed by sputtering (room temperature) without using conventional plasma CVD (300 ° C.), a low environmental load and low-temperature process are possible.
- the light shielding layer 22 on the first substrate 10 side can be formed by photolithography just above the active layer 17a, and can be arranged and formed with high accuracy, and the light shielding layer line width can be reduced.
- the transmittance of the display panel is increased.
- the first substrate 10 and the second substrate 11 are bonded so that the light shielding layer 22 on the first substrate 10 side is disposed above the active layer 17a, and external light from the viewing direction is displayed on the liquid crystal display.
- no incident light hits the active layer, so that the malfunction and characteristic change of the active layer are less likely to occur.
- the polarizing layer 21 is formed by a bonding method on a surface different from the bonding surface of the second substrate 11, and the polarizing layer 21 is formed by a bonding method, thereby reducing the thickness. Is possible.
- the polarizing layer 21 can be formed by a coating method, and the thickness can be reduced by forming the polarizing layer 21 by a coating method.
- the plastic film substrate 11b of the second substrate 11 is in the form of a roll, and a roll-to-roll paneling process is realized in which the plastic film substrate is fed from the roll shape and wound into a roll shape.
- the produced display panel can be wound up in a roll shape.
- the first substrate and the second substrate bonding apparatus in FIG. 9 are formed by the first substrate 10 formed by the first substrate manufacturing apparatus in FIG. 7 and the second substrate manufacturing apparatus in FIG.
- the second substrate 11 is set, and the sealant drawing unit 301 by the ODF process, the liquid crystal filling unit 302, the bonding unit 303 for bonding via the drawn sealant, and the curing unit 304 for curing the sealant. And are arranged.
- a ring-shaped UV curable seal is formed on a transparent substrate without forming a liquid crystal injection port, and then an appropriate amount of liquid crystal is dropped on the inner region of the seal and bonded with a vacuum apparatus. Later, this UV curable seal is cured by irradiating it with ultraviolet rays.
- the sealant drawing unit 301 the sealant drawing is provided on the bonding surface by the sealant 16.
- the portions operated by electricity of the plurality of liquid crystal display devices are provided so as to surround the entire outside, respectively, and further, the entire outside of the portions operated by electricity of the plurality of liquid crystal display devices are surrounded.
- the drawing of the sealant is not limited to one that surrounds the entire exterior, but may be applied so as to surround a part of the exterior.
- a liquid sealant placed in a syringe is ejected from an opening of the dispenser and applied.
- This dispenser uses the one with small variation in the discharge amount of the opening at each position in the width direction of the opening row, and applies the sealing agent in a syringe while pushing it out, so that the sealing agent can be applied easily and reliably. Can be granted.
- the sealing agent that forms the drawing of the sealing agent is composed of an ultraviolet curable resin, a thermosetting resin, an adhesive, and the like, and prevents gaps and in-plane displacement and prevents liquid crystal leakage.
- a ring-shaped ultraviolet curable sealant 16 is formed on the substrate without forming a liquid crystal injection port, and then an appropriate amount of the liquid crystal 15 is dropped on the inner region of the sealant 16.
- a sealing agent 16 used for bonding is provided on the first substrate 10, and the liquid crystal 14 can be dropped onto the first substrate 10 in a portion surrounded and sealed by the sealing agent 16.
- a liquid crystal display device is manufactured by providing the liquid crystal 15. *
- the bonding unit 303 includes a vacuum chamber 303a, a flat stage 303b, and a bonding mechanism 303c.
- the vacuum chamber 303a is closed at the time of bonding, and the inside is made into a vacuum state, and it is separated when transported so that the substrate can be transported.
- a flat stage 303b and a bonding mechanism 303c are disposed inside the vacuum chamber 303a.
- the flat stage 303b holds the substrate in a flat state, and the bonding mechanism 303c bonds the first substrate 10 and the second substrate 11 on the flat stage 303b.
- the sealing agent 16 is an ultraviolet curable resin, and the ultraviolet curable resin is cured by irradiating the sealing agent 16 with ultraviolet rays, and the substrate can be easily and reliably cured without applying heat to the substrate. it can.
- the present invention is particularly applicable to a liquid crystal display device using a plastic film substrate, a liquid crystal display device manufacturing method, and a liquid crystal display device manufacturing apparatus, which prevents a decrease in contrast due to reflection of external light, and further reduces the size of the device. Thinning is possible.
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Abstract
Description
前記第1の基板は、プラスチックフィルム基板上に遮光層と、着色層と、共通電極層が形成された基板であり、 前記第2の基板は、予め能動素子が形成されたガラス基板が、
プラスチックフィルム基板上に貼合された基板であり、
前記プラスチックフィルム基板の少なくとも一方には、片面または両面にバリア膜が形成されていることを特徴とする液晶表示装置である。
前記第1の基板は、プラスチックフィルム基板上に遮光層を形成する工程と、着色層を形成する工程と、共通電極を形成する工程とを有し、
前記第2の基板は、ガラス基板上に能動素子を形成する工程と、前記ガラス基板をプラスチックフィルム基板上に貼合する工程とを有し、
前記プラスチックフィルム基板の少なくとも一方には、片面または両面にバリア膜を形成する工程を有し、
前記第1の基板と前記第2の基板の貼合面にそれぞれ配向膜を形成する工程と、
ODFプロセスによるシール剤描画工程と、液晶充填工程と、描画された前記シール剤を介した貼り合せ工程と、前記シール剤を硬化させる工程とを有することを特徴とする液晶表示装置の製造方法である。
(第1の実施の形態)
この第1の実施の形態の液晶表示装置を、図1及び図2に基づいて説明する。図1は液晶表示装置の概略構成図、図2は第2の基板のプラスチックフィルム基板の概略構成図である。
O=12~18 (典型値17)
N=0~24(典型値12)となる。
図3は第2の実施の形態の液晶表示装置の概略構成図である。この第2の実施の形態は、第1の実施の形態と同じ構成は同じ符号を付して説明を省略する。この第2の実施の形態では、ギャップ保持材15は、図3に示すように、球状スペーサ15bを用いている。この球状スペーサ15bは、一部が配向膜12に接して形成され、他部が配向膜13に接して形成されているが、一部の位置は第1の基板10a側の遮光層領域に形成され、他部の位置は第2の基板11b側の遮能動素子領域に形成されている。
図4は第3の実施の形態の液晶表示装置の概略構成図である。この第3の実施の形態は、第1の実施の形態と同じ構成は同じ符号を付して説明を省略する。この第3の実施の形態では、第1の基板10aと第2の基板11bは、貼合面と異なる面に偏光層20,21を有しており、液晶表示装置を通るバックライト光の透過制御を可能にしている。
図5は第4の実施の形態の液晶表示装置の概略構成図である。この第4の実施の形態は、第1の実施の形態と同じ構成は同じ符号を付して説明を省略する。この第4の実施の形態では、第2の基板11が、プラスチックフィルム基板11b上に能動素子17を直接形成された基板であり、能動素子17を直接形成することで、さらに軽量、薄型で、割れにくくなる。
図6は第5の実施の形態の液晶表示装置の概略構成図である。この第5の実施の形態は、第1の実施の形態と同じ構成は同じ符号を付して説明を省略する。この第5の実施の形態では、第1の基板10a側の遮光層22が、活性層17a上方に配置され、目視方向からの外光が液晶表示装置に入射する際、活性層17aへ入射光が当たらなくなるため、活性層17aの誤動作や特性変化が起きにくくなる。
この実施の形態の液晶表示装置の製造方法及び液晶表示装置の製造装置を、図7乃至図9に基づいて説明する。図7は第1の基板製造装置の概略構成図、図8は第2の基板製造装置の概略構成図、図9は第1の基板と第2の基板の貼合装置の概略構成図である。
10a プラスチックフィルム基板
10b 遮光層
10c 着色層
10d 共通電極層
10e,10f 無機バリア
10g 樹脂バリア
11 第2の基板
11b プラスチックフィルム基板
11c,11d 無機バリア
11e 粘着剤
11f 樹脂バリア
12,13 配向膜
14 液晶
15 ギャップ保持材
16 シール剤
17 能動素子
17a 活性層
22 遮光層
110 バリア膜形成部
103 遮光層形成部
104 着色層形成部
106 配向膜形成部
105 共通電極形成部
107 ギャップ保持材形成部
111 偏光層貼合部
210 バリア膜形成部
203 能動素子形成部
204 ガラス基板貼合部
205 遮光層形成部
206 配向膜形成部
211 偏光層貼合部
321 スパッタ装置
301 シール剤描画部
302 液晶充填部
303 貼合部
304 硬化部
Claims (21)
- 第1の基板と第2の基板間に配向膜及び液晶を挟持させ、ギャップ保持材、及びシール剤を介して貼合された液晶表示装置であり、
前記第1の基板は、プラスチックフィルム基板上に遮光層と、着色層と、共通電極層が形成された基板であり、
前記第2の基板は、予め能動素子が形成されたガラス基板が、プラスチックフィルム基板上に貼合された基板であり、
前記プラスチックフィルム基板の少なくとも一方には、片面または両面にバリア膜が形成されていることを特徴とする液晶表示装置。 - 前記配向膜が、光配向制御型の配向膜であることを特徴とする請求項1に記載の液晶表示装置。
- 前記シール剤が、光硬化型のシール剤であることを特徴とする請求項1に記載の液晶表示装置。
- 前記ギャップ保持材が、前記第1の基板側の遮光層領域に形成された柱状スペーサであることを特徴とする請求項1に記載の液晶表示装置。
- 前記ギャップ保持材が、前記第1の基板と前記第2の基板間に配置され、かつ前記第1の基板側の遮光層領域に配置された球状スペーサであることを特徴とする請求項1に記載の液晶表示装置。
- 前記第1の基板と前記第2の基板は、貼合面と異なる面に偏光層を有していることを特徴とする請求項1に記載の液晶表示装置。
- 前記第2の基板が、プラスチックフィルム基板上に能動素子を直接形成された基板であることを特徴とする請求項1に記載の液晶表示装置。
- 前記第2の基板の能動素子が、酸素(O)と窒素(N)の混合物であり、Oに対するNの比(N数密度/O数密度)が0乃至2である非金属元素を含む活性層を有していることを特徴とする請求項1乃至請求項7のいずれか1項に記載の液晶表示装置。
- 前記第1の基板側の遮光層が、前記活性層上方に配置されていることを特徴とする請求項1に記載の液晶表示装置。
- 前記第1の基板側の遮光層が、前記活性層直上に形成されていることを特徴とする請求項9記載の液晶表示装置。
- 第1の基板と第2の基板間に、配向膜及び液晶を挟持させギャップ保持材及びシール剤を介して貼合する液晶表示装置の製造方法において、
前記第1の基板は、プラスチックフィルム基板上に遮光層を形成する工程と、着色層を形成する工程と、共通電極を形成する工程とを有し、
前記第2の基板は、ガラス基板上に能動素子を形成する工程と、前記ガラス基板をプラスチックフィルム基板上に貼合する工程とを有し、
前記プラスチックフィルム基板の少なくとも一方には、片面または両面にバリア膜を形成する工程を有し、
前記第1の基板と前記第2の基板の貼合面にそれぞれ配向膜を形成する工程と、
ODFプロセスによるシール剤描画工程と、液晶充填工程と、描画された前記シール剤
を介した貼り合せ工程と、前記シール剤を硬化させる工程とを有することを特徴とする液晶表示装置の製造方法。 - 前記第1の基板のプラスチックフィルム基板、もしくは前記第2の基板のプラスチックフィルム基板のうち少なくとも一方がロール状であることを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記ギャップ保持材として、前記第1の基板側の遮光層領域に配置される柱状スペーサが、フォトリソグラフィー法により形成されることを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記ギャップ保持材として、前記第1の基板と前記第2の基板間に配置され、かつ前記第1の基板側の遮光層領域に配置される球状スペーサが、定点配置法により形成されることを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記第1の基板と前記第2の基板との貼合面とは異なる面に、偏光層を貼合方式で形成することを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記第1の基板と前記第2の基板との貼合面とは異なる面に、偏光層を塗布方式で形成することを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記第2の基板が、プラスチックフィルム基板上に能動素子を直接形成する手法で製造されることを特徴とする請求項11に記載の液晶表示装置の製造方法。
- 前記第2の基板の能動素子が、酸素(O)と窒素(N)の混合物であり、Oに対するNの比(N数密度/O数密度)が0乃至2である非金属元素を含む活性層をスパッタ方式により形成することを特徴とする請求項11乃至請求項17のいずれか1項に記載の液晶表示装置の製造方法。
- 前記第1の基板側の遮光層が、前記活性層上方に配置されるように前記第1の基板と前記第2の基板を貼り合せることを特徴とする請求項18に記載の液晶表示装置の製造方法。
- 前記第1の基板側の遮光層が、前記活性層直上にフォトリソグラフィー法により形成されることを特徴とする請求項18に記載の液晶表示装置の製造方法。
- 請求項11乃至請求項17のいずれか1項に記載の表示装置の製造方法を実行し、液晶表示装置を製造することを特徴する液晶表示装置の製造装置。
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US20130050623A1 (en) | 2013-02-28 |
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