WO2011081404A3 - 폴리올레핀 중합용 촉매 및 이의 제조방법 - Google Patents

폴리올레핀 중합용 촉매 및 이의 제조방법 Download PDF

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Publication number
WO2011081404A3
WO2011081404A3 PCT/KR2010/009418 KR2010009418W WO2011081404A3 WO 2011081404 A3 WO2011081404 A3 WO 2011081404A3 KR 2010009418 W KR2010009418 W KR 2010009418W WO 2011081404 A3 WO2011081404 A3 WO 2011081404A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
magnesium
production method
polyolefin
polymerisation
Prior art date
Application number
PCT/KR2010/009418
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English (en)
French (fr)
Other versions
WO2011081404A2 (ko
Inventor
최영헌
임성수
김영국
Original Assignee
호남석유화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 호남석유화학 주식회사 filed Critical 호남석유화학 주식회사
Priority to EP10841236.2A priority Critical patent/EP2520591B8/en
Priority to CN201080059670.0A priority patent/CN102741299B/zh
Priority to US13/519,530 priority patent/US20120296056A1/en
Priority to JP2012547013A priority patent/JP2013515831A/ja
Publication of WO2011081404A2 publication Critical patent/WO2011081404A2/ko
Publication of WO2011081404A3 publication Critical patent/WO2011081404A3/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Abstract

본 발명은 폴리올레핀 중합용 촉매의 제조방법 및 이에 따른 폴리올레핀 중합용 촉매에 관한 것으로, 특히 마그네슘 할라이드를 제1알코올과 제1탄화수소에 용해시켜서 얻은 마그네슘 할라이드 전구체 용액과, 금속 마그네슘에 할로겐 화합물과 제2알코올을 반응시켜서 얻은 디알콕시마그네슘 담체를 제2탄화수소의 존재 하에 사염화티타늄 및 내부전자공여체와 반응시키는 것을 포함하는 폴리올레핀 중합용 촉매의 제조방법에 관한 것이다. 이러한 본 발명은 상기한 디알콕시 마그네슘 담지 촉매를 이용함으로써, 고활성을 나타내는 2성분계 마그네슘 화합물 담지형 폴리올레핀 중합용 촉매를 제공할 수 있다.
PCT/KR2010/009418 2009-12-28 2010-12-28 폴리올레핀 중합용 촉매 및 이의 제조방법 WO2011081404A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP10841236.2A EP2520591B8 (en) 2009-12-28 2010-12-28 Catalyst for polyolefin polymerisation and a production method for the same
CN201080059670.0A CN102741299B (zh) 2009-12-28 2010-12-28 聚烯烃聚合用催化剂及其制备方法
US13/519,530 US20120296056A1 (en) 2009-12-28 2010-12-28 Catalyst for polymerization of polyolefin and preparation method thereof
JP2012547013A JP2013515831A (ja) 2009-12-28 2010-12-28 ポリオレフィン重合用触媒及びその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090132229A KR101126946B1 (ko) 2009-12-28 2009-12-28 폴리올레핀 중합용 촉매 및 이의 제조방법
KR10-2009-0132229 2009-12-28

Publications (2)

Publication Number Publication Date
WO2011081404A2 WO2011081404A2 (ko) 2011-07-07
WO2011081404A3 true WO2011081404A3 (ko) 2011-12-01

Family

ID=44227009

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/009418 WO2011081404A2 (ko) 2009-12-28 2010-12-28 폴리올레핀 중합용 촉매 및 이의 제조방법

Country Status (6)

Country Link
US (1) US20120296056A1 (ko)
EP (1) EP2520591B8 (ko)
JP (1) JP2013515831A (ko)
KR (1) KR101126946B1 (ko)
CN (1) CN102741299B (ko)
WO (1) WO2011081404A2 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101309457B1 (ko) * 2011-07-15 2013-09-23 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법 및 이를 이용한 고체 촉매 및 프로필렌 중합체의 제조방법
KR102126599B1 (ko) 2012-11-08 2020-06-24 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. 조절된 촉매 특성을 갖는 중합 촉매의 제조 방법 및 올레핀 중합에서의 그의 용도
KR101373775B1 (ko) * 2012-11-23 2014-03-13 롯데케미칼 주식회사 폴리올레핀 합성용 촉매의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
KR101526480B1 (ko) * 2013-11-29 2015-06-05 롯데케미칼 주식회사 폴리올레핀 합성용 고체 촉매 조성물, 고체 촉매의 제조방법, 및 이를 이용한 폴리올레핀의 제조방법
KR102122133B1 (ko) 2018-11-13 2020-06-11 한화토탈 주식회사 Voc 저감을 위한 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조방법
CN112707449B (zh) * 2019-10-24 2023-02-28 中国石油化工股份有限公司 一种处理含钛废液的方法
CN116041576A (zh) * 2021-10-28 2023-05-02 中国石油化工股份有限公司 烯烃聚合催化剂前体和烯烃聚合催化剂载体及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010033585A (ko) * 1997-12-23 2001-04-25 보레알리스 테크놀로지 오와이. 마그네슘, 티타늄, 할로겐 원소 및 전자 주게 물질을함유하는 촉매 성분 및 그의 제조 방법과 용도
US6693058B1 (en) * 1997-01-28 2004-02-17 Fina Technology, Inc. Ziegler-natta catalyst for narrow to broad MWD of polyoefins, method of making, method of using, and polyolefins made therewith
WO2005040231A1 (en) * 2003-10-23 2005-05-06 Dnf Solution Co.,Ltd. High activity olefin polymerization silica supported catalyst
KR20100007076A (ko) * 2008-07-11 2010-01-22 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
CA1310955C (en) 1987-03-13 1992-12-01 Mamoru Kioka Process for polymerization of olefins and polymerization catalyst
US5108972A (en) * 1989-10-16 1992-04-28 Akzo Nv Process of making halide/alkoxy-containing magnesium complex
EP1114070B1 (en) * 1999-06-04 2003-12-10 LG Chemical Ltd. Process for preparing polyolefin polymerization catalysts
JP2001114812A (ja) * 1999-10-15 2001-04-24 Toho Titanium Co Ltd オレフィン類重合用固体触媒成分及び触媒
JP4170667B2 (ja) * 2002-05-24 2008-10-22 出光興産株式会社 マグネシウム化合物、オレフィン重合用固体触媒成分、オレフィン重合用触媒及びポリオレフィンの製造方法
EP1508559A4 (en) * 2002-05-24 2006-08-02 Idemitsu Kosan Co MAGNESIUM COMPOUND, SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEIN POLYMERIZATION, AND METHOD FOR PRODUCING POLYOLEFIN

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6693058B1 (en) * 1997-01-28 2004-02-17 Fina Technology, Inc. Ziegler-natta catalyst for narrow to broad MWD of polyoefins, method of making, method of using, and polyolefins made therewith
KR20010033585A (ko) * 1997-12-23 2001-04-25 보레알리스 테크놀로지 오와이. 마그네슘, 티타늄, 할로겐 원소 및 전자 주게 물질을함유하는 촉매 성분 및 그의 제조 방법과 용도
WO2005040231A1 (en) * 2003-10-23 2005-05-06 Dnf Solution Co.,Ltd. High activity olefin polymerization silica supported catalyst
KR20100007076A (ko) * 2008-07-11 2010-01-22 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

Also Published As

Publication number Publication date
KR20110075706A (ko) 2011-07-06
WO2011081404A2 (ko) 2011-07-07
KR101126946B1 (ko) 2012-03-20
JP2013515831A (ja) 2013-05-09
EP2520591B8 (en) 2015-06-10
CN102741299B (zh) 2014-07-09
EP2520591A4 (en) 2013-10-09
EP2520591A2 (en) 2012-11-07
CN102741299A (zh) 2012-10-17
EP2520591B1 (en) 2015-04-01
US20120296056A1 (en) 2012-11-22

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