WO2011081405A3 - 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법 - Google Patents

폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법 Download PDF

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Publication number
WO2011081405A3
WO2011081405A3 PCT/KR2010/009420 KR2010009420W WO2011081405A3 WO 2011081405 A3 WO2011081405 A3 WO 2011081405A3 KR 2010009420 W KR2010009420 W KR 2010009420W WO 2011081405 A3 WO2011081405 A3 WO 2011081405A3
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WO
WIPO (PCT)
Prior art keywords
production method
catalyst
same
magnesium
compound
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Application number
PCT/KR2010/009420
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English (en)
French (fr)
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WO2011081405A2 (ko
Inventor
최영헌
임성수
김영국
Original Assignee
호남석유화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 호남석유화학 주식회사 filed Critical 호남석유화학 주식회사
Priority to JP2012547014A priority Critical patent/JP5478736B2/ja
Priority to EP10841237.0A priority patent/EP2520592B8/en
Priority to US13/519,545 priority patent/US20120289398A1/en
Priority to CN201080059669.8A priority patent/CN102741298B/zh
Publication of WO2011081405A2 publication Critical patent/WO2011081405A2/ko
Publication of WO2011081405A3 publication Critical patent/WO2011081405A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명은 폴리올레핀 중합용 촉매의 제조방법에 관한 것으로, 본 발명에 따른 제조방법은 a) 마그네슘 할라이드 화합물을 제1알코올과 제1탄화수소에 용해시킨 후 알콕시실란 화합물을 첨가하여 마그네슘 할라이드 전구체 용액을 제조하는 단계; b) 할로겐 화합물 존재 하에 금속 마그네슘과 제2알코올을 반응시켜 디알콕시마그네슘 담체를 제조하는 단계; 및 c) 제2탄화수소 존재 하에 상기 마그네슘 할라이드 전구체 용액과 상기 디알콕시마그네슘 담체를 사염화티타늄 및 내부전자공여체와 반응시키는 단계를 포함한다. 이러한 본 발명은 고활성을 나타내는 2성분계 마그네슘 화합물 담지형 폴리올레핀 중합용 촉매를 제공할 수 있다.
PCT/KR2010/009420 2009-12-28 2010-12-28 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법 WO2011081405A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2012547014A JP5478736B2 (ja) 2009-12-28 2010-12-28 ポリオレフィン重合用触媒の製造方法及びこれにより製造される触媒、並びにこれを用いたポリオレフィンの製造方法
EP10841237.0A EP2520592B8 (en) 2009-12-28 2010-12-28 Production method for a catalyst for polyolefin polymerisation, a catalyst obtained by means of the same, and a production method for polyolefins by using the same
US13/519,545 US20120289398A1 (en) 2009-12-28 2010-12-28 Preparation method of catalyst for polymerization of polyolefin, catalyst prepared thereby and preparation method of polyolefin using the catalyst
CN201080059669.8A CN102741298B (zh) 2009-12-28 2010-12-28 聚烯烃聚合用催化剂的制备方法、根据其的催化剂及利用其的聚烯烃的制备方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090132240A KR101126918B1 (ko) 2009-12-28 2009-12-28 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법
KR10-2009-0132240 2009-12-28

Publications (2)

Publication Number Publication Date
WO2011081405A2 WO2011081405A2 (ko) 2011-07-07
WO2011081405A3 true WO2011081405A3 (ko) 2011-11-10

Family

ID=44227010

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/009420 WO2011081405A2 (ko) 2009-12-28 2010-12-28 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법

Country Status (6)

Country Link
US (1) US20120289398A1 (ko)
EP (1) EP2520592B8 (ko)
JP (1) JP5478736B2 (ko)
KR (1) KR101126918B1 (ko)
CN (1) CN102741298B (ko)
WO (1) WO2011081405A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101373775B1 (ko) 2012-11-23 2014-03-13 롯데케미칼 주식회사 폴리올레핀 합성용 촉매의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
JP6914095B2 (ja) * 2017-05-01 2021-08-04 東邦チタニウム株式会社 ジアルコキシマグネシウムの製造方法、オレフィン類重合用触媒成分の製造方法、オレフィン類重合用触媒の製造方法、及びオレフィン類重合体の製造方法
KR102327008B1 (ko) * 2017-11-30 2021-11-16 롯데케미칼 주식회사 폴리에틸렌 접착제
KR102539409B1 (ko) * 2021-01-25 2023-06-05 에쓰대시오일 주식회사 자일렌 용해도가 향상된 호모 폴리프로필렌 수지 조성물 및 그 제조방법
CN116041577A (zh) * 2021-10-28 2023-05-02 中国石油化工股份有限公司 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5028671A (en) * 1987-03-13 1991-07-02 Mitsui Petrochemical Industries, Ltd. Process for polymerization of olefins and polymerization catalyst
KR20010033585A (ko) * 1997-12-23 2001-04-25 보레알리스 테크놀로지 오와이. 마그네슘, 티타늄, 할로겐 원소 및 전자 주게 물질을함유하는 촉매 성분 및 그의 제조 방법과 용도
WO2005040231A1 (en) * 2003-10-23 2005-05-06 Dnf Solution Co.,Ltd. High activity olefin polymerization silica supported catalyst
KR20100007076A (ko) * 2008-07-11 2010-01-22 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

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JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
US5108972A (en) * 1989-10-16 1992-04-28 Akzo Nv Process of making halide/alkoxy-containing magnesium complex
US6410663B2 (en) * 1992-06-08 2002-06-25 Fina Technology, Inc. Electron donors in a Ziegler-Natta catalyst for the production of high melt flow copolymers
US5459116A (en) * 1993-05-07 1995-10-17 Samsung General Chemicals Co., Ltd. Highly active catalyst for the polymerization of olefins and method for the preparation of the same
FI991069A0 (fi) * 1999-05-10 1999-05-10 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
JP4170667B2 (ja) * 2002-05-24 2008-10-22 出光興産株式会社 マグネシウム化合物、オレフィン重合用固体触媒成分、オレフィン重合用触媒及びポリオレフィンの製造方法
KR100640275B1 (ko) * 2004-10-14 2006-11-01 대한유화공업 주식회사 에틸렌 중합 및/또는 에틸렌 공중합용 고체 촉매의 제조방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5028671A (en) * 1987-03-13 1991-07-02 Mitsui Petrochemical Industries, Ltd. Process for polymerization of olefins and polymerization catalyst
KR20010033585A (ko) * 1997-12-23 2001-04-25 보레알리스 테크놀로지 오와이. 마그네슘, 티타늄, 할로겐 원소 및 전자 주게 물질을함유하는 촉매 성분 및 그의 제조 방법과 용도
WO2005040231A1 (en) * 2003-10-23 2005-05-06 Dnf Solution Co.,Ltd. High activity olefin polymerization silica supported catalyst
KR20100007076A (ko) * 2008-07-11 2010-01-22 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

Also Published As

Publication number Publication date
US20120289398A1 (en) 2012-11-15
WO2011081405A2 (ko) 2011-07-07
JP5478736B2 (ja) 2014-04-23
KR20110075716A (ko) 2011-07-06
CN102741298B (zh) 2014-07-09
JP2013515832A (ja) 2013-05-09
EP2520592A4 (en) 2013-10-09
CN102741298A (zh) 2012-10-17
EP2520592A2 (en) 2012-11-07
EP2520592B1 (en) 2015-04-01
EP2520592B8 (en) 2015-06-03
KR101126918B1 (ko) 2012-03-20

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