WO2010005164A3 - 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법 - Google Patents

올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법 Download PDF

Info

Publication number
WO2010005164A3
WO2010005164A3 PCT/KR2009/001958 KR2009001958W WO2010005164A3 WO 2010005164 A3 WO2010005164 A3 WO 2010005164A3 KR 2009001958 W KR2009001958 W KR 2009001958W WO 2010005164 A3 WO2010005164 A3 WO 2010005164A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymerization catalyst
olefin polymerization
spherical carrier
magnesium
controlling size
Prior art date
Application number
PCT/KR2009/001958
Other languages
English (en)
French (fr)
Other versions
WO2010005164A2 (ko
Inventor
김은일
김종식
강솔
박준려
Original Assignee
삼성토탈 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 삼성토탈 주식회사 filed Critical 삼성토탈 주식회사
Priority to CN2009801268575A priority Critical patent/CN102089078A/zh
Priority to US13/003,345 priority patent/US20110166394A1/en
Priority to JP2010550611A priority patent/JP2011513576A/ja
Priority to EP09794570A priority patent/EP2301664A2/en
Publication of WO2010005164A2 publication Critical patent/WO2010005164A2/ko
Publication of WO2010005164A3 publication Critical patent/WO2010005164A3/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

본 발명은 올레핀 중합용 촉매의 제조시 사용되는 디알콕시마그네슘 담체의 크기를 조절하는 방법에 관한 것으로서, 보다 상세하게는, 반응개시제로서 마그네슘할라이드 또는 질소할로겐 화합물의 존재하에 금속마그네슘과 알코올을 반응시켜 디알콕시마그네슘 담체를 제조함에 있어서, 상기 금속마그네슘과 알코올을 1~3회로 나누어 투입하여 반응시킴으로써, 올레핀 중합 촉매용 디알콕시마그네슘 담체의 크기를 조절하는 방법에 관한 것이다.
PCT/KR2009/001958 2008-07-11 2009-04-16 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법 WO2010005164A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2009801268575A CN102089078A (zh) 2008-07-11 2009-04-16 调整烯烃聚合催化剂球形载体大小的方法
US13/003,345 US20110166394A1 (en) 2008-07-11 2009-04-16 Method for controlling size of spherical carrier for olefin polymerization catalyst
JP2010550611A JP2011513576A (ja) 2008-07-11 2009-04-16 オレフィン重合触媒用球形担体のサイズを調節する方法
EP09794570A EP2301664A2 (en) 2008-07-11 2009-04-16 Method for controlling size of spherical carrier for olefin polymerization catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2008-0067525 2008-07-11
KR1020080067525A KR20100007076A (ko) 2008-07-11 2008-07-11 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

Publications (2)

Publication Number Publication Date
WO2010005164A2 WO2010005164A2 (ko) 2010-01-14
WO2010005164A3 true WO2010005164A3 (ko) 2010-03-11

Family

ID=41507528

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/001958 WO2010005164A2 (ko) 2008-07-11 2009-04-16 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법

Country Status (6)

Country Link
US (1) US20110166394A1 (ko)
EP (1) EP2301664A2 (ko)
JP (1) JP2011513576A (ko)
KR (1) KR20100007076A (ko)
CN (1) CN102089078A (ko)
WO (1) WO2010005164A2 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100954056B1 (ko) * 2007-12-12 2010-04-20 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법
KR101126946B1 (ko) * 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매 및 이의 제조방법
KR101126918B1 (ko) * 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법
KR101309457B1 (ko) * 2011-07-15 2013-09-23 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법 및 이를 이용한 고체 촉매 및 프로필렌 중합체의 제조방법
CN107098794A (zh) * 2017-05-18 2017-08-29 山西大学 一种固体乙醇镁的制备方法
CN109206545B (zh) * 2017-07-01 2021-07-02 中国石油化工股份有限公司 丙烯类聚合物微粒和用于烯烃聚合的固体催化剂组分及烯烃聚合催化剂
KR102178630B1 (ko) * 2018-12-20 2020-11-13 한화토탈 주식회사 프로필렌 중합용 고체 촉매 및 이를 이용한 블록 공중합체의 제조방법
KR20240056988A (ko) * 2022-10-24 2024-05-02 한화토탈에너지스 주식회사 프로필렌계 중합용 고체 촉매 및 이를 이용한 프로필렌계 중합체의 제조방법
CN115925513A (zh) * 2022-11-22 2023-04-07 任国辉 一种球形二烷氧基镁载体的制备方法和应用
CN115894174A (zh) * 2022-11-22 2023-04-04 任国辉 一种用于烯烃聚合催化剂的二烷氧基镁载体的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060027486A (ko) * 2004-09-23 2006-03-28 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법
KR100807895B1 (ko) * 2006-08-30 2008-02-27 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법
KR100822610B1 (ko) * 2006-12-28 2008-04-16 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0720898B2 (ja) * 1989-08-16 1995-03-08 コルコートエンジニアリング株式会社 球形で粒度分布の狭いマグネシウムアルコラートの合成方法
JP2505326B2 (ja) 1991-06-18 1996-06-05 出光石油化学株式会社 マグネシウムジアルコキシドの製造方法
DE4000697A1 (de) 1990-01-12 1991-07-18 Huels Chemische Werke Ag Verfahren zur herstellung sphaerischer partikel von magnesiumalkoxid
US5162277A (en) * 1990-10-18 1992-11-10 Shell Oil Company Olefin polymerization catalyst
JP3772331B2 (ja) * 1994-09-07 2006-05-10 日本曹達株式会社 マグネシウムエチラート球状微粒品の製造方法
US5955396A (en) 1995-10-17 1999-09-21 Bp Amoco Corporation Morphology-controlled olefin polymerization catalyst formed from an emulsion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060027486A (ko) * 2004-09-23 2006-03-28 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법
KR100807895B1 (ko) * 2006-08-30 2008-02-27 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법
KR100822610B1 (ko) * 2006-12-28 2008-04-16 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법

Also Published As

Publication number Publication date
KR20100007076A (ko) 2010-01-22
WO2010005164A2 (ko) 2010-01-14
US20110166394A1 (en) 2011-07-07
EP2301664A2 (en) 2011-03-30
JP2011513576A (ja) 2011-04-28
CN102089078A (zh) 2011-06-08

Similar Documents

Publication Publication Date Title
WO2010005164A3 (ko) 올레핀 중합 촉매용 구형 담체의 크기를 조절하는 방법
WO2012071358A3 (en) In-situ activation of metal complexes used as hydrosilylation catalysts
WO2009005003A1 (ja) 遷移金属錯体化合物、該化合物を含むオレフィン多量化用触媒および該触媒存在下で行うオレフィン多量体の製造方法
WO2014081623A3 (en) Multilayer pressure-sensitive adhesive assembly
WO2011102990A3 (en) Process for polymerizing an olefin monomer and catalyst therefor
WO2007059200A8 (en) Catalysts for olefin polymerization
HK1113583A1 (en) Catalysts for olefin polymerization
WO2010085622A3 (en) Polymers functionalized with nitrile compounds containing a protected amino group
WO2007149422A3 (en) Curable organosilicon composition
MY150505A (en) Process for stabilizing olefinically unsaturated monomers
WO2008027479A3 (en) Highly active alpha-olefin copolymerization catalyst system
WO2012138556A3 (en) Borehole metal member bonding system and method
WO2011089595A3 (en) Sustained-release nucleic acid matrix compositions
WO2012169812A3 (en) METHOD OF PREPARING ETHYLENE-α-OLEFIN-DIENE COPOLYMER
WO2012161484A3 (ko) 실리콘화합물을 이용하여 제조된 마그네슘계 합금 및 그 제조 방법
IN2012KN02714A (ko)
WO2011139591A3 (en) Process for dehydrohalogenation of halogenated alkanes
WO2013091033A8 (pt) Catalisador suportado em alumina para uso em polimerização de olefinas e método de preparo do mesmo
WO2008135398A3 (en) A process for the preparation of an olefin oxide
WO2011156110A3 (en) Methods for producing telechelic polyolefins from terpene initiators
WO2013098052A3 (en) Metathesis of nitrile rubbers in the presence of transition metal complex catalysts
EP2277236A4 (en) PROCESS FOR IMPROVING THE PERFORMANCE, ANTENNA AND DEVICE
WO2010021978A3 (en) Il-8 biomarker for monitoring cancer treatment
WO2009012982A3 (en) Process
MX2011006513A (es) Polimeros que reducen la resistencia para aplicaciones de liquidos de bajo peso molecular.

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200980126857.5

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09794570

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2010550611

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 2009794570

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE