WO2011071161A1 - 熱交換器 - Google Patents

熱交換器 Download PDF

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Publication number
WO2011071161A1
WO2011071161A1 PCT/JP2010/072280 JP2010072280W WO2011071161A1 WO 2011071161 A1 WO2011071161 A1 WO 2011071161A1 JP 2010072280 W JP2010072280 W JP 2010072280W WO 2011071161 A1 WO2011071161 A1 WO 2011071161A1
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WO
WIPO (PCT)
Prior art keywords
fluid
honeycomb structure
outer peripheral
honeycomb
heat exchanger
Prior art date
Application number
PCT/JP2010/072280
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
能大 鈴木
竜生 川口
重治 橋本
道夫 高橋
Original Assignee
日本碍子株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本碍子株式会社 filed Critical 日本碍子株式会社
Priority to JP2011545269A priority Critical patent/JP5758811B2/ja
Priority to EP10836080.1A priority patent/EP2511644B1/en
Priority to CN201080056166.5A priority patent/CN102652249B/zh
Publication of WO2011071161A1 publication Critical patent/WO2011071161A1/ja
Priority to US13/491,709 priority patent/US9534856B2/en

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/04—Constructions of heat-exchange apparatus characterised by the selection of particular materials of ceramic; of concrete; of natural stone
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F7/00—Elements not covered by group F28F1/00, F28F3/00 or F28F5/00
    • F28F7/02—Blocks traversed by passages for heat-exchange media

Definitions

  • the present invention relates to a heat exchanger that transfers heat of a first fluid (high temperature side) to a second fluid (low temperature side).
  • Patent Document 1 discloses a ceramic heat exchanger in which a heating body channel is disposed from one end surface to the other end surface, and a heated body channel is formed in a direction orthogonal to the heating body channel. .
  • Patent Document 2 a plurality of ceramic heat exchangers in which a heated fluid channel and a non-heated fluid channel are formed are arranged in a string-like sealing material made of an unfired ceramic material between the joint surfaces. There is disclosed a ceramic heat exchanger disposed in a casing with a gap interposed therebetween.
  • Patent Documents 1 and 2 have high man-hours such as sealing and slit processing, and the productivity is not good, resulting in high costs.
  • the gas / liquid flow paths are arranged in every other row, the piping structure and the fluid sealing structure are complicated.
  • the heat transfer coefficient of liquids is generally 10 to 100 times greater than that of gas, and these technologies lack the heat transfer area on the gas side and are proportional to the heat transfer area of the gas, which controls the heat exchanger performance. The heat exchanger becomes large.
  • Patent Document 5 discloses a honeycomb heat exchanger in which a ceramic honeycomb through which a low-temperature fluid passes is integrally joined to a peripheral portion of the ceramic honeycomb through which a high-temperature fluid passes through a ceramic cylindrical body. A ceramic honeycomb and a ceramic honeycomb are joined, and the heat exchange area of each fluid is widened to achieve a high heat exchange amount.
  • heat is exchanged between the outer peripheral wall of the central honeycomb molded body and the outer peripheral wall of the outer peripheral ceramic honeycomb, and a ceramic cylinder for preventing fluid mixing at the time of breakage is included between them. For this reason, it is considered that the heat exchange route is long, the thermal resistance of the solid portion is increased, and the heat exchange loss is large.
  • Patent Document 6 discloses an apparatus for bonding a ceramic honeycomb and a ceramic honeycomb to vaporize a liquid. Since the liquid passes through the shortest distance of the high-temperature honeycomb, sufficient heat exchange cannot be performed.
  • Patent Document 7 discloses a reaction vessel that performs uniform combustion exothermic reaction with air and fuel with a catalyst on a ceramic honeycomb with low pressure loss. The external fluid to be heated does not flow and the loss of heat exchange is large.
  • Patent Document 8 discloses a heat exchanger in which heat of a ceramic honeycomb is transmitted to the outside to cool the gas temperature and generate water vapor. There is a phase change from liquid to water vapor at the outer periphery, and a strong structure is required to support volume change.
  • Patent Document 9 discloses an exhaust heat recovery device using a ceramic honeycomb. However, this exhaust heat recovery apparatus utilizes a thermoacoustic phenomenon.
  • Patent Document 10 discloses an engine exhaust gas heat exchanger.
  • the catalyst for purifying the exhaust gas is a honeycomb structure, and the heat exchange is performed with the gas jetting portion downstream from the honeycomb structure and the liquid flowing in the outer periphery thereof.
  • the subject of this invention is providing the heat exchanger which implement
  • the present inventors have a configuration in which the honeycomb structure is accommodated in the casing, the first fluid is circulated in the cells of the honeycomb structure, and the second fluid is circulated on the outer peripheral surface of the honeycomb structure in the casing. It has been found that the above-mentioned problems can be solved by the heat exchanger. That is, according to the present invention, the following heat exchanger is provided.
  • a heat exchanger comprising: a second fluid circulation part for receiving heat from the first fluid by circulating in direct contact with or without direct contact with the outer peripheral surface.
  • a metal plate or a ceramic plate is fitted to the entire outer peripheral surface of the honeycomb structure, and the outer peripheral surface of the honeycomb structure and the second fluid are not in direct contact with each other.
  • honeycomb structure according to any one of [1] to [6], wherein the honeycomb structure has an extended outer peripheral wall that extends outward in the axial direction from the end face in the axial direction and is formed in a cylindrical shape.
  • the described heat exchanger is not limited to any one of [1] to [6], wherein the honeycomb structure has an extended outer peripheral wall that extends outward in the axial direction from the end face in the axial direction and is formed in a cylindrical shape.
  • the casing is formed in a cylindrical shape so as to cover a part of the outer peripheral surface outside the outer peripheral surface of the honeycomb structure, and the second fluid flows through the casing, thereby the outer peripheral surface.
  • the honeycomb part which is configured to receive heat from the first fluid in direct contact with the partition and in which the cells are formed by the partition walls, is brought closer to the downstream side in the axial direction with respect to the second fluid circulation part.
  • the casing is formed in a cylindrical shape so as to cover a part of the outer peripheral surface outside the outer peripheral surface of the honeycomb structure, and the second fluid flows through the casing, thereby the outer peripheral surface.
  • the second fluid circulation part is brought close to the downstream side in the axial direction with respect to the honeycomb part in which the cells are formed by the partition walls.
  • the first fluid circulation portion includes a plurality of honeycomb portions in which the cells are formed by the partition walls arranged in the axial direction, and the partition walls of the respective honeycomb portions in a cross section perpendicular to the axial direction.
  • the heat exchanger according to any one of [1] to [11], wherein the honeycomb portions are arranged so that directions are different.
  • the first fluid circulation portion includes a plurality of honeycomb portions in which the cells are formed by the partition walls arranged in the axial direction, and each honeycomb portion has a different cell density.
  • the heat exchanger according to any one of [1] to [11], wherein the honeycomb portion is arranged so that the cell density of the honeycomb portion on the outlet side is larger than that on the inlet side of the first fluid.
  • the structure of the heat exchanger of the present invention is not complicated, and can be reduced in size, weight, and cost as compared with a conventional heat exchanger (heat exchanger or its device). Moreover, it has a heat exchange rate equal to or higher than that.
  • FIG. 6 is a diagram schematically showing an arrangement in which a plurality of honeycomb structures are stacked, and showing another embodiment of the heat exchanger of the present invention in which the first fluid and the second fluid exchange heat in an orthogonal flow. . It is a perspective view showing an embodiment of equilateral triangle staggered arrangement of a plurality of honeycomb structures.
  • FIG. 6 is a schematic diagram showing a heat exchanger in heat exchangers of Comparative Examples 2 to 4.
  • FIG. 5 is a perspective view showing another embodiment of a heat exchanger in which a honeycomb structure having an extended outer peripheral wall is accommodated in a casing.
  • FIG. 6 is a cross-sectional view taken along a cross section parallel to the axial direction, showing another embodiment of a heat exchanger in which a honeycomb structure having an extended outer peripheral wall is accommodated in a casing.
  • FIG. 6 is a cross-sectional view taken along a cross section perpendicular to the axial direction, showing another embodiment of a heat exchanger in which a honeycomb structure having an extended outer peripheral wall is accommodated in a casing. It is sectional drawing cut
  • FIG. 3 is a cross-sectional view cut along a cross section parallel to the axial direction showing an embodiment in which a plurality of honeycomb structures are arranged so that the directions of partition walls of the honeycomb structure are different. It is sectional drawing cut
  • the cell density of the honeycomb structure in the front stage is a diagram showing an embodiment of a heat exchanger having a configuration in which the inner side is dense and the outer peripheral side is rough, and the cell density of the rear stage honeycomb structure is rough on the inner side and dense on the outer peripheral side. is there.
  • a plurality of honeycomb structures are arranged, and each honeycomb structure is formed so that two semicircular regions having different cell densities are formed, and the cell density distributions of the front and rear honeycomb structures are different.
  • FIG. 2 is a view showing an embodiment of a heat exchanger having a configuration in which the outer honeycomb side is plugged on the front honeycomb structure and the inner honeycomb plug is plugged on the inner side. It is a figure which shows embodiment of the heat exchanger which has arrange
  • FIG. 35A It is a figure which shows embodiment of the honeycomb structure which sealed the inlet and outlet of a 1st fluid distribution part alternately. It is AA sectional drawing in FIG. 35A. It is the plane schematic diagram seen from the end surface side which shows an example of the embodiment of the honeycomb structure in which the portion without the partition where the partition corresponding to the partition intersection part does not exist was formed. It is a figure which shows embodiment by which the porous wall was formed in the 1st fluid circulation part, and is sectional drawing of a 1st fluid circulation part. It is a figure which shows embodiment of the honeycomb structure which made the thickness of the partition which forms a 1st fluid distribution part gradually thick from the center to the outer periphery in the cross section perpendicular
  • Embodiment 1 of the fin provided in the cell It is a figure which shows Embodiment 2 of the fin provided in the cell. It is a figure which shows Embodiment 3 of the fin provided in the cell. It is a figure which shows Embodiment 4 of the fin provided in the cell. It is a figure which shows Embodiment 5 of the fin provided in the cell. It is a figure which shows Embodiment 6 of the fin provided in the cell. It is a figure which shows Embodiment 7 of the fin provided in the cell. It is a perspective view which shows embodiment which bent the honeycomb structure in one direction. It is the elements on larger scale showing the embodiment of the honeycomb structure which made the partition of the cell near the peripheral wall thick. Fig.
  • FIG. 3 is a diagram showing a first embodiment of partition walls that become thinner gradually toward the center side of the honeycomb structure. It is a figure which shows Embodiment 2 of the partition which becomes thin gradually toward the center side of a honeycomb structure. It is a figure which shows Embodiment 3 of the partition which becomes thin gradually toward the center side of a honeycomb structure. It is a figure which shows embodiment of the honeycomb structure which made the partition thick about the cell inside an outermost periphery cell. It is a figure which shows other embodiment of the honeycomb structure which made the partition thick about the cell inside an outermost periphery cell.
  • FIG. 3 is a partial cross-sectional explanatory view showing an example in which contact buildup is applied to a honeycomb structure.
  • FIG. 10 is a partial cross-sectional explanatory view showing another embodiment in which contact build-up is applied to the honeycomb structure.
  • FIG. 3 is a cross-sectional view showing an embodiment of a corrugated honeycomb structure.
  • FIG. 53B is a cross-sectional view showing an A-A ′ cross section of the corrugated honeycomb structure shown in FIG. 53A. It is sectional drawing which shows other embodiment of a wave wall honeycomb structure.
  • FIG. 2 is a diagram schematically showing an embodiment of a honeycomb structure having a curved partition wall, and is a schematic parallel sectional view showing a cross section parallel to the axial direction.
  • FIG. 6 is a cross-sectional view schematically showing another embodiment of a honeycomb structure having a curved partition wall.
  • FIG. 3 is a partially enlarged view of a schematic axis-Y section showing an embodiment of a honeycomb structure including partition walls having different heights in the axial direction.
  • FIG. 1A is a schematic view of a heat exchanger 30 of the present invention
  • FIG. 1B is a schematic perspective view.
  • the heat exchanger 30 is partitioned by ceramic partition walls 4 and penetrates from one end face 2 to the other end face 2 in the axial direction, and has a plurality of cells 3 in which a heating body as a first fluid flows.
  • 1 and a casing 21 containing the honeycomb structure 1 therein, and a second fluid inlet 22 and an outlet 23 are formed in the casing 21, and the second fluid Circulates on the outer peripheral surface 7 of the honeycomb structure 1, thereby providing a second fluid circulation part 6 for receiving heat from the first fluid.
  • the fact that the second fluid flows on the outer peripheral surface 7 of the honeycomb structure 1 includes a case where the second fluid directly contacts the outer peripheral surface 7 of the honeycomb structure 1 and a case where the second fluid does not directly contact.
  • the honeycomb structure 1 accommodated in the casing 21 is partitioned by ceramic partition walls 4 and penetrates from one end face 2 to the other end face 2 in the axial direction, and a plurality of heating bodies as the first fluid circulate therethrough. It has a cell 3.
  • the heat exchanger 30 is configured such that a first fluid having a temperature higher than that of the second fluid flows in the cells 3 of the honeycomb structure 1.
  • the second fluid circulation portion 6 is formed by the inner peripheral surface 24 of the casing 21 and the outer peripheral surface 7 of the honeycomb structure 1.
  • the second fluid circulation part 6 is a second fluid circulation part formed by the casing 21 and the outer peripheral surface 7 of the honeycomb structure 1, and is separated by the first fluid circulation part 5 and the partition walls 4 of the honeycomb structure 1.
  • the heat of the first fluid flowing through the first fluid circulation part 5 is received via the partition wall 4 and is transferred to the heated body as the second fluid flowing.
  • the first fluid and the second fluid are completely separated, and these fluids do not mix.
  • the first fluid circulation portion 5 is formed as a honeycomb structure, and in the case of the honeycomb structure, when the fluid passes through the cell 3, the fluid cannot flow into another cell 3 by the partition wall 4, and the honeycomb structure The fluid travels linearly from one inlet to the outlet. Moreover, the honeycomb structure 1 in the heat exchanger 30 of the present invention is not plugged, so that the heat transfer area of the fluid can be increased and the size of the heat exchanger can be reduced. Thereby, the amount of heat transfer per unit volume of the heat exchanger can be increased. Furthermore, since it is not necessary to process the honeycomb structure 1 such as forming plugged portions or forming slits, the manufacturing cost of the heat exchanger 30 can be reduced.
  • the first fluid is circulated at a temperature higher than that of the second fluid to conduct heat from the first fluid to the second fluid.
  • gas is circulated as the first fluid and liquid is circulated as the second fluid, heat exchange between the first fluid and the second fluid can be performed efficiently. That is, the heat exchanger 30 of the present invention can be applied as a gas / liquid heat exchanger.
  • the heat exchanger 30 of the present invention allows the first fluid having a temperature higher than that of the second fluid to flow through the cells of the honeycomb structure 1 to efficiently heat the heat of the first fluid to the honeycomb structure 1. Can be conducted. That is, the total heat transfer resistance is the thermal resistance of the first fluid + the thermal resistance of the partition wall + the thermal resistance of the second fluid, but the rate-limiting factor is the thermal resistance of the first fluid. In the heat exchanger 30, since the first fluid passes through the cell 3, the contact area between the first fluid and the honeycomb structure 1 is large, and the thermal resistance of the first fluid, which is a rate-determining factor, can be reduced. . Therefore, as shown in FIG.
  • the second fluid circulates at the outermost peripheral surface of the honeycomb structure 1 having the largest surface area, so that the residence time can be increased at the same flow rate and flow velocity, resulting in a loss of heat exchange. Few. Furthermore, in the present invention, when the second fluid flowing through the second fluid circulation portion 6 is a liquid, there is almost no volume change, and thus a simple structure that supports the pressure of the fluid is sufficient.
  • FIG. 1A and 1B show a heat exchanger 30 in which a first fluid and a second fluid exchange heat in a counterflow.
  • the counter flow means that the second fluid flows in the opposite direction in parallel with the direction in which the first fluid flows.
  • the direction in which the second fluid is circulated is not limited to the direction opposite to the direction in which the first fluid circulates (opposite flow), but the same direction (parallel flow) or a certain angle (0 ° ⁇ x ⁇ 180 °: However, it is possible to select and design as appropriate.
  • the heat exchanger 30 of the present invention includes a honeycomb structure 1 that is the first fluid circulation portion 5 (high temperature side) of the honeycomb structure through which the first fluid (heating body) circulates, and the second fluid circulation portion 6 inside.
  • the casing 21 is made up of. Since the first fluid circulation part 5 is formed of the honeycomb structure 1, heat exchange can be performed efficiently.
  • a plurality of cells 3 serving as flow paths are defined by partition walls 4, and the cell shape is appropriately set to a desired shape from a circle, an ellipse, a triangle, a quadrangle, and other polygons. Just choose.
  • a module structure in which a plurality of honeycomb structures 1 are joined can be formed (see FIG. 2A).
  • the shape of the honeycomb structure 1 is a quadrangular prism, but the shape is not limited to this, and may be another shape such as a cylinder (see FIG. 3).
  • the cell density of the honeycomb structure 1 (that is, the number of cells per unit cross-sectional area) is not particularly limited and may be appropriately designed according to the purpose, but is 25 to 2000 cells / in 2 (4 to 320 cells / cm 2 ) is preferable.
  • the cell density is smaller than 25 cells / square inch, the strength of the partition walls 4, and consequently the strength of the honeycomb structure 1 itself and the effective GSA (geometric surface area) may be insufficient.
  • the cell density exceeds 2000 cells / square inch, the pressure loss when the heat medium flows may increase.
  • the number of cells per honeycomb structure 1 is preferably 1 to 10,000, and particularly preferably 200 to 2,000. If the number of cells is too large, the honeycomb itself becomes large, so the heat conduction distance from the first fluid side to the second fluid side becomes long, the heat conduction loss becomes large, and the heat flux becomes small. Further, when the number of cells is small, the heat transfer area on the first fluid side becomes small, the heat resistance on the first fluid side cannot be lowered, and the heat flux becomes small.
  • the thickness (wall thickness) of the partition walls 4 of the cells 3 of the honeycomb structure 1 may be appropriately designed according to the purpose, and is not particularly limited.
  • the wall thickness is preferably 50 ⁇ m to 2 mm, and more preferably 60 to 500 ⁇ m. If the wall thickness is less than 50 ⁇ m, the mechanical strength may be reduced, and damage may be caused by impact or thermal stress. On the other hand, if it exceeds 2 mm, there is a possibility that problems such as a decrease in the cell volume ratio on the honeycomb structure side, an increase in fluid pressure loss, and a decrease in the heat exchange rate through which the heat medium permeates may occur.
  • the density of the partition walls 4 of the cells 3 of the honeycomb structure 1 is preferably 0.5 to 5 g / cm 3 .
  • the partition wall 4 has insufficient strength, and the partition wall 4 may be damaged by pressure when the first fluid passes through the flow path.
  • the honeycomb structure 1 itself becomes heavy, and the characteristics of weight reduction may be impaired.
  • the honeycomb structure 1 can be strengthened. Moreover, the effect which improves heat conductivity is also acquired.
  • the honeycomb structure 1 is preferably made of ceramics having excellent heat resistance, and silicon carbide is particularly preferable in consideration of heat transfer properties. However, it is not always necessary that the entire honeycomb structure 1 is made of silicon carbide, and it is sufficient if silicon carbide is contained in the main body. That is, the honeycomb structure 1 is preferably made of a conductive ceramic containing silicon carbide. As the physical properties of the honeycomb structure 1, the thermal conductivity at room temperature is preferably 10 W / mK or more and 300 W / mK or less, but is not limited thereto. Instead of the conductive ceramic, a corrosion-resistant metal material such as an Fe—Cr—Al alloy can be used.
  • the honeycomb structure 1 containing silicon carbide having high thermal conductivity it is more preferable to use the honeycomb structure 1 containing silicon carbide having high thermal conductivity.
  • a high thermal conductivity cannot be obtained in the case of a porous body. Therefore, it is more preferable to impregnate silicon in the manufacturing process of the honeycomb structure 1 to obtain a dense structure.
  • High heat conductivity can be obtained by using a dense structure. For example, in the case of a porous body of silicon carbide, it is about 20 W / mK, but by making it a dense body, it can be about 150 W / mK.
  • Si-impregnated SiC, (Si + Al) -impregnated SiC, metal composite SiC, Si 3 N 4 , SiC, or the like can be used as the ceramic material, but in order to obtain a dense structure for obtaining a high heat exchange rate. It is more desirable to employ Si-impregnated SiC and (Si + Al) -impregnated SiC.
  • Si-impregnated SiC has a structure in which the SiC particle surface is surrounded by solidified metal-silicon melt and SiC is integrally bonded via metal silicon, so that silicon carbide is shielded from an oxygen-containing atmosphere and prevented from oxidation. Is done.
  • SiC has the characteristics of high thermal conductivity and easy heat dissipation, but SiC impregnated with Si is densely formed while exhibiting high thermal conductivity and heat resistance, and has sufficient strength as a heat transfer member.
  • the honeycomb structure 1 made of a Si—SiC-based (Si-impregnated SiC, (Si + Al) -impregnated SiC) material has excellent heat resistance, thermal shock resistance, oxidation resistance, and excellent corrosion resistance against acids and alkalis. And high thermal conductivity.
  • the honeycomb structure 1 is mainly composed of a Si-impregnated SiC composite material or (Si + Al) -impregnated SiC
  • Si content defined by Si / (Si + SiC)
  • Si + SiC Si-impregnated SiC
  • the bonding material is formed. Due to the shortage, the bonding between adjacent SiC particles due to the Si phase becomes insufficient, and not only the thermal conductivity is lowered, but it is difficult to obtain a strength capable of maintaining a thin-walled structure such as a honeycomb structure. Become.
  • the Si content is preferably 5 to 50% by mass, more preferably 10 to 40% by mass.
  • the pores are filled with metal silicon, and the porosity may be 0 or close to 0, which is excellent in oxidation resistance and durability, and can be used in a high-temperature atmosphere. Can be used for a long time.
  • an oxidation protective film is formed, so that no oxidative degradation occurs.
  • the thermal conductivity is as high as that of copper or aluminum metal, the far-infrared emissivity is also high, and since it is electrically conductive, it is difficult to be charged with static electricity.
  • the first fluid (high temperature side) to be circulated through the heat exchanger 30 of the present invention is exhaust gas
  • a catalyst is supported on the wall surface inside the cell 3 of the honeycomb structure 1 through which the first fluid (high temperature side) passes. It is preferable that This is because in addition to the role of exhaust gas purification, reaction heat (exothermic reaction) generated during exhaust gas purification can also be exchanged.
  • the supported amount of the catalyst (catalyst metal + support) supported on the first fluid circulation part 5 of the honeycomb structure 1 through which the first fluid (high temperature side) passes is preferably 10 to 400 g / L.
  • a catalyst is supported on the partition walls 4 of the cells 3 of the honeycomb structure 1.
  • the honeycomb structure 1 is masked so that the catalyst is supported on the honeycomb structure 1.
  • an aqueous solution containing a catalyst component is impregnated into ceramic powder as carrier fine particles, and then dried and fired to obtain catalyst-coated fine particles.
  • a dispersion liquid (water, etc.) and other additives are added to the catalyst-coated fine particles to prepare a coating liquid (slurry).
  • the slurry is coated on the partition walls 4 of the honeycomb structure 1, and then dried and fired.
  • the catalyst is supported on the partition walls 4 of the cells 3 of the honeycomb structure 1. When firing, the masking of the honeycomb structure 1 is peeled off.
  • FIG. 2A shows another embodiment of the heat exchanger 30.
  • a heat exchanger 30 shown in FIG. 2A is arranged in a casing 21 with a plurality of honeycomb structures 1 facing each other with their outer peripheral surfaces 7 facing each other with a gap for allowing the second fluid to flow therethrough.
  • FIG. 2A schematically shows the arrangement of the honeycomb structure 1, and the casing 21 and the like are omitted.
  • the honeycomb structures 1 are stacked with gaps in three rows and four rows. By setting it as such a structure, the cell 3 through which a 1st fluid distribute
  • the plurality of honeycomb structures 1 are arranged with the outer peripheral surface 7 facing each other with a gap, the contact area between the outer peripheral surface 7 of the honeycomb structure 1 and the second fluid is large. The heat exchange between the first fluid and the second fluid can be performed efficiently.
  • FIG. 2B and 2C show an embodiment of a regular triangular staggered arrangement of a plurality of honeycomb structures 1.
  • FIG. 2B is a perspective view
  • FIG. 2C is a view as seen from the inlet side of the first fluid.
  • a plurality of honeycomb structures 1 are arranged such that a line connecting the central axes 1j of the honeycomb structures 1 forms an equilateral triangle.
  • the second fluid can be uniformly distributed between the honeycomb structures 1 (between the modules), and the heat exchange efficiency can be improved.
  • Is preferably a regular triangle staggered arrangement.
  • the equilateral triangle staggered arrangement forms a kind of fin structure, and the flow of the second fluid becomes turbulent, and heat exchange with the first fluid is facilitated.
  • Fig. 2D shows an embodiment in which honeycomb structures 1 having different sizes are included.
  • the replenishment honeycomb structure 1h is arranged in the gap between the honeycomb structures 1 having a regular triangular staggered arrangement.
  • the replenishment honeycomb structure 1h fills in the gaps, and is different in size and shape from other normal honeycomb structures 1. That is, it is not necessary that all the honeycomb structures 1 have the same size and shape.
  • the gap between the casing 21 and the honeycomb structure 1 can be filled, and the heat exchange efficiency can be improved.
  • FIG. 3 shows another embodiment of the honeycomb structure 1 accommodated in the casing 21 of the heat exchanger 30.
  • the honeycomb structure 1 shown in FIG. 3 has a circular cross-sectional shape perpendicular to the axial direction. That is, the honeycomb structure 1 shown in FIG. 3 is formed in a cylindrical shape. Further, as shown in FIG. 3, one columnar honeycomb structure 1 may be accommodated in the casing 21, or a plurality of columnar honeycomb structures 1 may be accommodated.
  • the cross-sectional shape in the cross section perpendicular to the axial direction of the honeycomb structure 1 may be a circle as shown in FIG. 3 or a quadrangle as shown in FIG. Alternatively, it may be hexagonal as will be described later.
  • the second fluid is an orthogonal flow orthogonal to the first fluid. However, the second fluid may be a counterflow with respect to the first fluid.
  • the position of the outlet is not particularly limited.
  • the honeycomb structure 1 shows an embodiment in which the shape of the cross section perpendicular to the axial direction of the honeycomb structure 1 is a hexagon.
  • the honeycomb structure 1 is disposed in a stacked manner in such a manner that the outer peripheral surfaces 7 face each other and have a gap for the second fluid to flow therethrough.
  • the honeycomb structure 1 can have a structure such as a prism, a cylinder, and a hexagonal column, and can be used in combination with each other, and can be used in accordance with the shape of the heat exchanger 30. Can be selected.
  • FIG. 5A and 5B show an embodiment in which the outer peripheral surface 7 of the honeycomb structure 1 has fins 9 for transferring heat to and from the second fluid flowing through the second fluid circulating portion 6.
  • FIG. 5A is an embodiment having a plurality of fins 9 in the axial direction of the honeycomb structure 1.
  • FIG. 5B shows an embodiment having a plurality of fins 9 in a direction perpendicular to the axial direction of the honeycomb structure 1.
  • the heat exchanger 30 may be configured to include a single honeycomb structure 1 or a plurality of the honeycomb structures 1 in the casing 21.
  • the material of the fins 9 is desirably the same material as that of the honeycomb structure 1.
  • FIG. 5A can be manufactured by extrusion with a die having fins 9 attached to the outer periphery of the honeycomb structure 1.
  • the embodiment of FIG. 5B can be manufactured by joining and integrally firing fins 9 separately formed on the outer periphery of the honeycomb structure 1.
  • the embodiment shown in FIG. 5A and the embodiment shown in FIG. 5B differ in the direction in which the second fluid flows.
  • the fins 9 are formed in the form of FIG. 5A in a position orthogonal to the axial direction of the honeycomb structure 1.
  • the fin 9 may be shaped as shown in FIG. 5B.
  • FIG. 6 shows another embodiment of the heat exchanger 30 of the present invention.
  • the heat exchanger 30 of the present invention includes a honeycomb structure 1 and a casing 21 on which the honeycomb structure 1 is placed.
  • the material of the casing 21 is not particularly limited, but it is preferable that the casing 21 is made of a metal having good workability (for example, stainless steel).
  • the material to be configured including the pipe to be connected is not particularly limited.
  • the casing 21 is formed with an inlet 22 for allowing the second fluid to flow into the casing 21 and an outlet 23 for allowing the second fluid inside to flow out.
  • a first fluid inlet 25 for directly flowing the first fluid into the cells 3 of the honeycomb structure 1 from the outside, and a first fluid for directly flowing the first fluid in the cells 3 to the outside.
  • An outlet 26 is formed. That is, the first fluid flowing in from the first fluid inlet 25 exchanges heat with the honeycomb structure 1 without directly contacting the second fluid inside the casing 21, and the first fluid outlet 26. Spill from.
  • the heating element that is the first fluid to be circulated in the heat exchanger 30 of the present invention having the above configuration is not particularly limited as long as it is a medium having heat.
  • the medium to be heated which is the second fluid that takes heat from the heating body (exchanges heat)
  • water is preferable in consideration of handling, it is not particularly limited to water.
  • the honeycomb structure 1 has high thermal conductivity, and a plurality of portions serving as flow paths by the partition walls 4 provide a high heat exchange rate. For this reason, the whole honeycomb structure 1 can be reduced in size and can be mounted on a vehicle.
  • the casing 21 is composed of a plurality of constituent parts, and the constituent parts can be relatively displaced from each other.
  • FIG. 7 shows an embodiment of the casing 21 provided with an elastic member.
  • the casing 21 is divided into a first casing 21a and a second casing 21b, which are a plurality of constituent parts.
  • a spring 28 as the elastic member, the length in the longitudinal direction can be changed.
  • expansion of casing 21 at the time of high temperature can be absorbed by deformation of a spring.
  • contraction at the time of low temperature can be suppressed with the force of a spring.
  • FIG. 8 shows an embodiment of the casing 21 having a bellows.
  • a bellows is formed between the first casing 21a and the second casing 21b, and the first casing 21a, the bellows, and the second casing 21b, which are a plurality of constituent parts, constitute the casing 21 integrally.
  • the length in the longitudinal direction is configured to be variable, and expansion at high temperature and contraction at low temperature can be absorbed by the bellows.
  • the seal between the honeycomb structure 1 and the casing 21 will be described with reference to FIG.
  • a gap between the honeycomb structure 1 and the casing 21 is sealed with a sealing material.
  • the thermal expansion coefficient is different and a gap may be formed in the sealing portion.
  • the casing 21 has a lower temperature and thermal expansion, so that the seal is maintained by tightening from the outer periphery.
  • the honeycomb structure 1 is a ceramic
  • examples of the sealing material include a metal material having heat resistance and elasticity.
  • Fig. 13A is a perspective view of the honeycomb structure 1 having the extended outer peripheral wall 51
  • Fig. 13B is a cross-sectional view cut along a cross section parallel to the axial direction
  • 14A is a perspective view of the heat exchanger 30 in which the honeycomb structure 1 having the extending outer peripheral wall 51 is accommodated in the casing 21, and
  • FIG. 14B is a cross-sectional view cut along a cross section parallel to the axial direction.
  • 14C shows a cross-sectional view cut along a cross section perpendicular to the axial direction.
  • the honeycomb structure 1 has an extended outer peripheral wall 51 that extends from the axial end face 2 of the honeycomb portion 52 outward in the axial direction and is formed in a cylindrical shape.
  • the extended outer peripheral wall 51 is formed continuously and integrally with the outer peripheral wall of the honeycomb portion 52.
  • a thin plate-like body in which the outer peripheral wall of the honeycomb portion 52 and the extended outer peripheral wall 51 are integrated is wound around the honeycomb structure 1 that does not have the extended outer peripheral wall 51, it is press-fitted into the cylindrical one. You may do it.
  • FIG. 13C shows an embodiment in which annular attachment extending outer peripheral walls 51 a are attached to both ends of the honeycomb structure 1.
  • annular attachment extending outer peripheral wall 51 a covering the entire periphery of the honeycomb portion 52 can be used.
  • the mounting extension outer peripheral wall 51a is preferably a metal plate or a ceramic plate.
  • the partition walls 4, the cells 3 and the like are not formed and are hollow.
  • the central honeycomb portion 52 is a heat collecting portion that promotes heat transfer.
  • the casing 21 of the heat exchanger 30 of the present embodiment has a honeycomb structure that forms the first fluid circulation part 5 from the first fluid inlet 25 to the first fluid outlet 25.
  • the first fluid circulation part 5 is formed in a straight line so that the body 1 is fitted, and the second fluid circulation part 6 from the second fluid inlet 22 to the second fluid outlet 23 is also linearly formed.
  • a second fluid circulation part is provided by being fitted to the casing 21, and a seal portion 53 is formed by the outer peripheral surface of the extended outer peripheral wall 51 of the honeycomb structure 1 and the inner peripheral surface of the casing 21.
  • a second fluid inlet 22 and outlet 23 are formed on opposite sides of the honeycomb structure 1.
  • the heat exchanger 30 In order to improve the reliability of the heat exchanger 30, it is effective to suppress heat transfer from the high-temperature fluid (first fluid) side to the seal part 53 and to suppress the temperature rise of the seal part 53.
  • the extended outer peripheral wall 51 is formed and the extended outer peripheral wall 51 serves as the seal portion 53, the performance of the heat exchanger 30 is improved.
  • the vicinity of the end surface 2 on the inlet side of the honeycomb structure 1 that is the inlet of the first fluid is the highest temperature, but a joint with the casing 21 and a seal portion (seal portion 11) are necessary. Therefore, it is difficult to flow the second fluid to the extreme end (see FIG. 9).
  • the end portion of the honeycomb portion 21 (in the vicinity of the end surface 2 on the inlet side) can also be heat-exchanged.
  • the seal portion 53 is formed on the outer side in the axial direction than the honeycomb portion 52, the second fluid can contact the entire outer peripheral surface of the honeycomb portion 21. For this reason, heat exchange efficiency can be improved.
  • FIG. 15A is a perspective view showing another embodiment of the heat exchanger 30 in which the honeycomb structure 1 having the extended outer peripheral wall 51 is accommodated in the casing 21, and FIG. 15B is a cross section parallel to the axial direction.
  • FIG. 15C is a cross-sectional view cut along a cross section perpendicular to the axial direction.
  • the second fluid inlet 22 and the outlet 23 are formed on the same side with respect to the honeycomb structure 1. It is also possible to adopt a structure as in this embodiment according to the installation location of the heat exchanger 30, piping, and the like.
  • the second fluid circulation portion 6 has a circulation structure that circulates around the outer periphery of the honeycomb structure 1. That is, the second fluid flows so as to go around the outer periphery of the honeycomb structure 1.
  • a structure may be adopted in which a metal plate or a ceramic plate is fitted to at least a part of the outer peripheral surface 7 of the honeycomb structure 1. it can. You may comprise so that a part of outer peripheral surface 7 may be covered with a metal plate or a ceramic plate, and you may comprise so that the whole outer peripheral surface 7 may be covered. When configured to cover the entire outer peripheral surface 7, the outer peripheral surface 7 of the honeycomb structure 1 and the second fluid are not in direct contact with each other.
  • FIG. 16 shows an embodiment of a heat exchanger 30 provided with a punching metal 55 which is a perforated metal plate having a plurality of holes on the outer peripheral surface 7 of the honeycomb structure 1 in the second fluid circulation portion 6. Sectional drawing cut
  • the punching metal 55 is a metal plate that is fitted to the outer peripheral surface of the honeycomb structure 1.
  • a honeycomb structure 1 having an extended outer peripheral wall 51 is accommodated in the casing 21.
  • a punching metal 55 is provided so as to be fitted to the outer peripheral surface 7 of the honeycomb structure 1 in the second fluid circulation portion 6.
  • the punching metal 55 is formed by punching a metal plate, and is formed in a cylindrical shape along the shape of the outer peripheral surface 7 of the honeycomb structure 1.
  • the perforated metal plate is a metal plate having a plurality of holes and is not limited to the punching metal 55.
  • FIG. 17A and FIG. 17B show the heat exchanger 30 of the embodiment in which the casing 21 is formed in a tube shape and is provided in a spirally wound shape on the outer peripheral surface 7 of the honeycomb structure 1.
  • FIG. 17A is a schematic diagram for explaining a state in which the casing 21 is spirally wound on the outer peripheral surface 7 of the honeycomb structure 1.
  • FIG. 17B is a schematic view in a direction parallel to the axial direction for explaining a state in which the casing 21 is spirally wound on the outer peripheral surface 7 of the honeycomb structure 1.
  • the inside of the tube serves as the second fluid circulation part 6, and the casing 21 has a shape wound spirally on the outer peripheral surface 7 of the honeycomb structure 1.
  • the second fluid that circulates in the honeycomb structure 1 circulates in a spiral shape on the outer peripheral surface 7 of the honeycomb structure 1 without directly contacting the outer peripheral surface 7 of the honeycomb structure 1 to exchange heat. With such a configuration, even when the honeycomb structure 1 is damaged, the first fluid and the second fluid do not leak or mix.
  • the honeycomb structure 1 may have a form without the extended outer peripheral wall 51.
  • the casing 21 is wound spirally, but may not be spiral. However, it is preferable that the casing 21 is provided in a shape in close contact with the outer peripheral surface 7 of the honeycomb structure 1 in terms of improvement in heat exchange efficiency.
  • Fig. 18 shows an embodiment in which a metal plate or a ceramic plate fitted to the outer peripheral surface 7 of the honeycomb structure 1 and an outer casing portion 21b that forms the second fluid circulation portion 6 on the outside thereof are integrated.
  • the casing 21 has a cylindrical portion 21 a that fits to the outer peripheral surface 7 of the honeycomb structure 1, and the second fluid circulation portion 6 outside the cylindrical portion 21 a.
  • the outer casing portion 21b to be formed is integrally provided.
  • the tubular portion 21a has a shape corresponding to the shape of the outer peripheral surface 7 of the honeycomb structure 1, and the outer casing portion 21b has a space for the second fluid to flow outside the tubular portion 21a. It has a cylindrical shape.
  • a second fluid inlet 22 and outlet 23 are formed in a part of the outer casing portion 21b.
  • the second fluid circulation part 6 is formed to be surrounded by the cylindrical part 21a and the outer casing part 21b, and the second fluid that circulates through the second fluid circulation part 6 is a honeycomb structure.
  • the heat is exchanged by circulating in the circumferential direction on the outer peripheral surface 1 of the honeycomb structure 1 without directly contacting the outer peripheral surface 7 of the honeycomb structure 1.
  • the honeycomb structure 1 may have a form without the extended outer peripheral wall 51.
  • the honeycomb structure 1 is joined so as to form an outer casing portion 21b on the outer side where the outer peripheral wall 51 and the cylindrical portion 21a integrated on the thin plate are wound or pressed into the cylindrical structure. Also good.
  • FIG. 19 shows that the casing 21 is integrally formed with a cylindrical portion 21 a that fits to the outer peripheral surface 7 of the honeycomb structure 1 and an outer casing portion 21 b that forms the second fluid circulation portion 6 outside the cylindrical portion 21 a.
  • the first fluid circulation part 5 is composed of a plurality of honeycomb parts 52, and the honeycomb parts 52 are arranged so that the directions of the partition walls 4 of the honeycomb structures 1 are different in a cross section perpendicular to the axial direction. That is, in the present embodiment, the plurality of honeycomb portions 52 are arranged in the casing 21 while changing the mesh direction (direction of the partition walls 4).
  • the honeycomb structure 1 may have a form without the extended outer peripheral wall 51.
  • FIG. 20 shows that the casing 21 is integrally formed with a cylindrical portion 21a that fits to the outer peripheral surface 7 of the honeycomb structure 1 and an outer casing portion 21b that forms the second fluid circulation portion 6 outside the cylindrical portion 21a.
  • the first fluid circulation part 5 is composed of a plurality of honeycomb parts 52, each of which has a different cell density, and the cells of the honeycomb part 52 on the outlet side of the first fluid are closer to the outlet side.
  • the honeycomb portion 52 is arranged so that the density is high. By arranging a plurality of meshes (cell density) of the honeycomb portion 52 so as to go downstream of the first fluid, the heat transfer area is large even if the temperature of the first fluid is lowered. As a result, the heat exchange efficiency is improved.
  • the honeycomb structure 1 may have a form without the extended outer peripheral wall 51.
  • FIG. 21A shows an embodiment in which the honeycomb portion 52 of the honeycomb structure 1 is arranged close to the second fluid circulation portion 6 toward the downstream side in the axial direction, and is cut in a cross section perpendicular to the axial direction. It is sectional drawing.
  • the honeycomb structure 1 of the present embodiment has an extended outer peripheral wall 51 that extends outward in the axial direction from the end surface 2 in the axial direction and is formed in a cylindrical shape.
  • the casing 21 is formed in a cylindrical shape so as to cover a part of the outer peripheral surface 7 outside the outer peripheral surface 7 of the honeycomb structure 1, and the second fluid directly contacts the outer peripheral surface 7 by flowing through the casing. And is configured to receive heat from the first fluid.
  • the honeycomb part 52 in which the cells 3 are formed by the partition walls 4 is arranged closer to the downstream side in the axial direction (downstream side in the flow direction of the first fluid) with respect to the second fluid circulation part 6. Since the honeycomb portion 52 is arranged close to the downstream side, the distance from the inlet of the first fluid to the end surface 2 is long, and the distance at which the first fluid is in contact with the second fluid circulation portion 6 is long. Since the maximum temperature of the contact surface between the structure 1 and the casing 21 can be lowered and the temperature of the contact portion between the casing 21 and the casing 21 can be lowered, the breakage due to heat can be suppressed. Further, heat released by radiation from the honeycomb structure 1 can also be recovered by the casing 21.
  • FIG. 21B is a cross-sectional view taken along a cross section perpendicular to the axial direction, showing an embodiment in which the second fluid circulation portion 6 is arranged close to the honeycomb portion 52 on the downstream side in the axial direction.
  • the honeycomb structure 1 of the present embodiment has an extended outer peripheral wall 51 that extends outward in the axial direction from the end surface 2 in the axial direction and is formed in a cylindrical shape.
  • a casing 21 is formed in a cylindrical shape so as to cover a part of the outer peripheral surface 7 outside the outer peripheral surface 7 of the honeycomb structure 1.
  • the second fluid is configured to receive heat from the first fluid in direct contact with the outer peripheral surface 7 by flowing through the casing 21.
  • the inlet 25 of the first fluid is at a high temperature, and if the temperature difference from the second fluid flowing through the casing 21 is large, a high thermal stress may be generated and the honeycomb structure 1 may be damaged.
  • the second fluid circulation portion 6 is arranged close to the downstream side in the axial direction with respect to the honeycomb portion 52, the temperature difference between the center and the outer periphery of the honeycomb portion 52 becomes small and is generated in the honeycomb. The thermal stress to be made can be reduced.
  • FIG. 21C is a cross-sectional view taken along a cross section perpendicular to the axial direction, showing an embodiment in which a casing is fitted to the honeycomb structure 1 that does not have the extended outer peripheral wall 51 (or the attached extended outer peripheral wall 51a).
  • the casing 21 is formed in an annular shape, and the outer peripheral surface 7 of the honeycomb structure 1 is fitted to the inner peripheral surface thereof.
  • the casing 21 is preferably formed of metal or ceramics. That is, a metal plate or a ceramic plate constituting the casing 21 is fitted to a part of the outer peripheral surface 7 of the honeycomb structure 1.
  • the second fluid flowing through the casing 21 directly contacts the outer peripheral surface 7 of the honeycomb structure 1 to exchange heat.
  • Fig. 22 shows another embodiment of the honeycomb structure 1, and is a view of the honeycomb structure 1 as viewed from one end face 2 on the inlet side of the first fluid.
  • the honeycomb structure 1 is partitioned by ceramic partition walls 4 and penetrates from one end surface 2 to the other end surface 2 in the axial direction (see FIG. 1B), and is a heating body that is the first fluid.
  • the partition wall 4 is formed to have a thick part and a thin part.
  • the configuration other than the thickness of the partition walls 4 is the same as that of the honeycomb structure 1 of FIG.
  • the second fluid is formed so as to circulate perpendicularly to the first fluid.
  • the pressure loss can be reduced by providing the wall thickness with variation.
  • the thick wall portion and the thin wall portion may be regularly arranged, or may be randomly arranged as shown in FIG. 22, and the same effect can be obtained.
  • FIG. 23A shows an embodiment in which the axial end face 2 of the partition wall 4 of the honeycomb structure 1 is a tapered face 2t, and one end face 2 of the honeycomb structure 1 is viewed from the inlet side of the first fluid. is there.
  • FIG. 23B is a cross-sectional view taken along a plane parallel to the axial direction, showing an embodiment in which the end face 2 in the axial direction of the partition walls 4 of the honeycomb structure 1 is a tapered surface 2t.
  • the honeycomb structure 1 is partitioned by ceramic partition walls 4 and penetrates in the axial direction from one end face 2 to the other end face 2 (see FIG. 1B).
  • a plurality of cells 3 through which a certain heating body circulates are provided, and the end surface 2 is a tapered surface 2t.
  • Fig. 24A is a view of the honeycomb structure 1 as viewed from one end face 2 from the inlet side of the first fluid, and is an embodiment in which cells 3 of different sizes are formed.
  • the first fluid flowing through the central portion has a high temperature, a large volume and a large pressure loss because of a high flow velocity. Therefore, the pressure loss can be reduced by enlarging the central cell 3.
  • Fig. 24B shows an embodiment of a cylindrical honeycomb structure 1 in which cells 3 of different sizes are formed.
  • the inner columnar honeycomb structure and the outer columnar honeycomb structure are integrated, and the cells 3 of the columnar honeycomb structure form a first fluid circulation portion 5.
  • FIG. 24C is an embodiment in which the size of the cell 3 is changed, and is a view of one end face 2 viewed from the inlet side of the first fluid.
  • the cells 3 are formed so as to gradually increase from the right side to the left side of the figure.
  • the right side of the figure is the inlet side of the second fluid, and is configured to flow from the right side to the left side along the outer peripheral surface 7 of the honeycomb structure 1. That is, the cell 3 on the inlet side of the second fluid is formed small and the cell 3 on the outlet side is formed large.
  • the downstream side of the second fluid FIG. 6
  • FIG. 24D is an embodiment in which the thickness of the partition wall 4 of the cell 3 is changed, and is a view of one end face 2 on the inlet side of the first fluid.
  • the partition walls 4 of the cells 3 are formed so as to gradually become thinner from the right side to the left side of the figure.
  • the right side of the figure is the inlet side of the second fluid, and the pressure loss can be reduced similarly to FIG. 24C by thinning the partition wall 4 of the cell 3 on the downstream side of the second fluid.
  • FIG. 25A is a cross-sectional view taken along a cross section parallel to the axial direction, and the partition wall 4 is formed thicker from the inlet side to the outlet side of the first fluid (from the upstream side to the downstream side).
  • 1 is an embodiment of the honeycomb structure 1.
  • FIG. 25B shows an embodiment of the honeycomb structure 1 in which the first fluid circulation portion 5 gradually narrows from the first fluid inlet side to the outlet side (from the upstream side to the downstream side).
  • the temperature of the first fluid decreases as it goes downstream, and heat transfer decreases due to volume contraction of the first fluid.
  • the shape of the cell 3 serving as the first fluid circulation part 5 can be a hexagonal shape as shown in FIG. 26A.
  • circulation part 5 can also be made into an octagon shape. By doing so, the angle of the corners is widened, so that the stagnation of the fluid is reduced and the boundary film thickness (temperature boundary layer thickness of the first fluid) can be reduced, and the first fluid and the wall surface of the partition wall The heat transfer coefficient increases.
  • the corner portion of the cell 3 that becomes the first fluid circulation portion 5 can be formed into an R shape to form the R portion 3 r.
  • the angle of the corner is widened, so that the stagnation of the fluid is reduced, the boundary film thickness can be reduced, and the heat transfer coefficient between the first fluid and the wall surface of the partition wall is increased.
  • a fin structure having fins 3f protruding into the cells 3 to be the first fluid circulation portions 5 can be formed.
  • the fin 3f is formed to extend in the axial direction (the direction in which the first fluid flows) on the wall surface of the partition wall 4 forming the cell 3, and the fin 3f has a plate-like shape in a cross section perpendicular to the axial direction.
  • a hemispherical shape, a triangular shape, a polygonal shape, or the like can be used.
  • the fins 3 f may be only the cells 3 that are not plugged or may be formed in the cells 3 that are plugged.
  • a structure in which fins 3f are provided in the partition walls 4 of the cells 3 at the center of the honeycomb structure 1 can also be employed. By doing so, not only the heat exchange efficiency can be increased because the gas contact area can be increased, but also the disadvantage that the first fluid is concentrated in the central portion and the deterioration of the central portion is accelerated.
  • the shape of the cell 3 is not limited to a square shape, and may be any of a polygon such as a triangle and a hexagon, and a circle.
  • the arrangement of the fins 3f may be on the partition 4 or at the intersection of the partitions 4 and can be determined by the number of fins 3f.
  • the thickness of the fin 3f is preferably equal to or less than the thickness of the partition wall from the viewpoint of thermal shock resistance and manufacturing conditions.
  • FIG. 29A shows an embodiment of the honeycomb structure 1 in which a part of the cell structure is dense.
  • the first fluid flowing through the cell 3 in the center of the honeycomb structure 1 has a high temperature because of its high flow velocity. It is preferable that the cell in the center of the honeycomb structure 1 is narrowed and the cell 3 on the outer side of the honeycomb structure 1 is widened.
  • FIG. 29B shows an embodiment of a cylindrical honeycomb structure 1 in which cells 3 having different sizes are formed.
  • the inner columnar honeycomb structure and the outer columnar honeycomb structure are integrated, and the cells 3 of the columnar honeycomb structure form a first fluid circulation portion 5.
  • FIG. 29C is an embodiment in which a part of the cell structure is dense, and is a view seen from one end face 2 on the inlet side of the first fluid.
  • the cell density is gradually increased from the right side to the left side of the figure.
  • the right side of the figure is the inlet side of the second fluid, and is configured to flow from the right side to the left side along the outer peripheral surface 7 of the honeycomb structure 1. That is, the cell 3 which becomes the first fluid circulation part 5 is formed such that the cell density on the inlet side of the second fluid is small and the cell density on the outlet side is large.
  • FIG. 29D shows an embodiment of the honeycomb structure 1 in which the cell structure is changed by changing the thickness (wall thickness) of the partition walls 4.
  • the cell 3 serving as the first fluid circulation part 5 is formed such that the cell density on the inlet side of the second fluid on the right side of the figure is small and the cell density on the outlet side on the left side of the figure is large.
  • the first fluid circulation part 5 is formed as shown in FIG. 29C (or FIG. 29D) and the second fluid is circulated from the right side to the left side in FIG. 29C (or FIG. 29D).
  • the first fluid flowing on the downstream side of the second fluid (the left side of FIG. 29C (or FIG. 29D)) has a high pressure loss due to the high temperature of the second fluid.
  • the heat transfer area can be increased by increasing the cell density on the downstream side of the second fluid of the five cells 3.
  • the total heat transfer amount can be increased by increasing the thickness of the partition wall 4.
  • FIG. 30 shows an embodiment of the heat exchanger 30 in which the position of the partition wall 4 is offset.
  • a plurality of honeycomb structures 1 are arranged in series in the direction in which the first fluid flows, and the downstream (downstream) honeycomb structure 1 is higher than the cell density of the upstream (upstream) honeycomb structure 1.
  • 1 shows an embodiment of a heat exchanger 30 having a dense cell density. The temperature of the first fluid flowing through the first fluid circulation portion 5 decreases as it goes downstream, and heat transfer decreases due to volume contraction of the first fluid.
  • the heat transfer area is increased by arranging the downstream (downstream) honeycomb structure 1 so that the cell density is high, and the heat transfer between the first fluid and the wall surface of the partition wall 4 is increased. be able to.
  • Fig. 32 shows an embodiment of a heat exchanger 30 in which a plurality of honeycomb structures 1 in which regions having different cell density distributions are formed are arranged in series in the direction in which the first fluid flows. Specifically, two regions are formed in the circumferential direction, the inner side (center side) and the outer peripheral side, and the cell density of the honeycomb structure 1 in the front stage (upstream) is dense on the inner side, coarse on the outer peripheral side, and downstream (downstream side).
  • the cell density of the honeycomb structure 1 is an embodiment in which the inner side is rough and the outer peripheral side is dense.
  • the film thickness can be reduced, and the heat transfer coefficient between the first fluid and the wall surface of the partition wall 4 can be increased.
  • the regions having different cell densities are not limited to two regions, and may be three or more regions.
  • Fig. 33A is an embodiment of the heat exchanger 30 in which a plurality of honeycomb structures 1 in which regions having different cell density distributions are formed are arranged in series in the direction in which the first fluid flows. Specifically, two semicircular regions are formed, and when the honeycomb structures that are the honeycomb structures 1 are arranged in series, the left and right (or the right and left (or the downstream) honeycomb structures (or the downstream structure) The cell density distribution (upper and lower) is changed.
  • the cell density of the first honeycomb structure 1 is dense on one side (right side in the figure), and the other side (left side in the figure) is rough, and the cell density of the second honeycomb structure 1 is on the other side (left side in the figure).
  • the honeycomb structure 1 at the front stage and the honeycomb structure 1 at the rear stage have different cell densities at the corresponding positions.
  • the cell structures have different cell density distributions at the front stage and the rear stage. Can be disturbed. For this reason, the film thickness can be reduced, and the heat transfer coefficient between the first fluid and the wall surface of the partition wall 4 can be increased.
  • the honeycomb structure 1 in which two square regions are formed has a cell density distribution on the left and right (or top and bottom) of the honeycomb structure 1 at the front stage (upstream side) and the rear stage (downstream side). By changing and arranging in series, the fluid flow can be disturbed and the heat transfer coefficient can be increased.
  • a plurality of honeycomb structures 1 are arranged in series in the flow direction of the first fluid, and the heat exchanger 30 is configured such that the flow path of the first fluid in the front stage and the rear stage changes.
  • the embodiment of is shown. Specifically, two regions, the inner side (center side) and the outer peripheral side, are formed in the circumferential direction, and the honeycomb structure 1 in the front stage is all plugged on the outer peripheral side by the plugging portions 13, and the honeycomb structure in the rear stage is formed.
  • the body 1 is an embodiment having a configuration in which the inside is all plugged by the plugging portions 13. By comprising in this way, the flow of the fluid can be disturbed.
  • FIG. 34B is a diagram showing an embodiment of a heat exchanger in which the honeycomb structure 1 in which the prisms whose one side is all plugged is combined is arranged in the front stage and the rear stage. In the former stage, the lower region is all plugged by the plugging portion 13, and in the rear stage, the upper region is entirely plugged by the plugging portion 13. Thereby, the flow of the first fluid can be changed.
  • FIG. 35A shows an embodiment of the honeycomb structure 1 in which the inlets and outlets of the first fluid circulation part 5 are alternately plugged by the plugging parts 13.
  • FIG. 35B is a cross-sectional view taken along line AA in FIG. 35A.
  • the material of the partition wall 4 is made different depending on the location of the partition wall 4 so that the first fluid flowing in from the inlet passes through the partition wall 4 and flows out of the outlet port. Thereby, the heat collection of the first fluid is performed not inside the wall surface but inside the porous partition wall 4. Since heat can be collected three-dimensionally instead of a two-dimensional surface, the heat transfer area can be increased.
  • Fig. 35C is a schematic plan view as seen from the end face side showing an example of the embodiment of the honeycomb structure 1 in which the no-intersection portion 19 where the partition wall 4 corresponding to the partition wall intersection portion does not exist is formed.
  • the basic structure of the honeycomb structure 1 has a plurality of cells 3 penetrating in the axial direction partitioned by the porous partition walls 4, and seals one end of a predetermined cell 3a by a plugging portion 13.
  • the remaining cell 3b is formed by sealing the other end opposite to the predetermined cell 3a.
  • the honeycomb structure 1 has a characteristic structure in which at least a part of the partition wall intersection where the partition walls 4 and the partition walls 4 intersect with each other, where there is no partition wall 4 corresponding to the partition wall intersection part. 19 is formed.
  • the honeycomb structure 1 has such a structure, the gas pressure loss can be reduced while maintaining the heat exchange efficiency because a part of the exhaust gas passes through the intersectionless portion 19.
  • FIG. 36 shows an embodiment in which the porous wall 17 is formed in the first fluid circulation part 5 which is the flow path of the first fluid.
  • FIG. 36 is a cross-sectional view of the first fluid circulation part 5.
  • the porosity of the porous wall 17 in the first fluid circulation part 5 is formed larger than the porosity of the partition wall 4 forming the cell 3. Therefore, in this embodiment, the first fluid passes through the porous wall 17 and is discharged from the outlet. Since heat can be collected three-dimensionally rather than on a two-dimensional surface, the heat transfer area can be increased even with the same volume. Alternatively, the honeycomb structure 1 can be reduced in size.
  • FIG. 37 shows an embodiment of the honeycomb structure 1 in which the thickness (wall thickness) of the partition walls 4 forming the first fluid circulation portion 5 is gradually increased from the center toward the outer periphery in a cross section perpendicular to the axial direction. .
  • the honeycomb structure 1 has the same size, the fin efficiency increases as the wall thickness increases. By increasing the thickness of the path that conducts heat collected from the center of the cell, the heat conduction in the wall can be increased.
  • Fig. 38 shows an embodiment of the honeycomb structure 1 having an elliptical outer shape.
  • the partition wall 4 extending toward the short axis side is formed thick.
  • the fin efficiency increases as the thickness of the partition wall 4 increases. Therefore, by arranging a thick wall thickness on the orthogonal side of the second fluid, the heat of the first fluid can be transferred to the second fluid as a whole. Increases heat conduction. In addition, the pressure loss can be reduced as compared with making the whole thicker. It is also possible to form the honeycomb structure 1 in a rectangular shape.
  • 39A and 39B show an embodiment of the honeycomb structure 1 in which the thickness of the partition walls 4 is partially changed.
  • a heat path to the outer peripheral wall 7h can be created, and the temperature of the outer peripheral wall 7h can be increased. The same effect can be obtained even if the thickness of the partition walls 4 is regularly or randomly arranged.
  • 40A and 40B show an embodiment provided with a heat conductor 58 along the central axis direction. Since the first fluid flowing through the center of the cell is far from the outer peripheral wall 7h that is in contact with the second fluid, it is difficult to sufficiently recover the heat. By disposing the heat conductor 58 along the axial direction in the center of the cell and conducting the high temperature on the inlet side to the downstream position, heat can be recovered in the entire honeycomb structure 1. Further, the transmission distance to the outer peripheral wall 7h can be shortened.
  • FIG. 41 shows an embodiment in which the outer peripheral wall 7h of the honeycomb structure 1 is made thicker than the partition walls 4 forming the cells 3.
  • the honeycomb structure forming the honeycomb structure 1 has a flat outer shape. Compared to a circle, the heat transfer path can be shortened in the short shaft portion, and the water channel pressure loss is smaller than when the outer shape of the honeycomb structure 1 is a square structure.
  • 43A to 43C show an embodiment in which the end face 2 on the inlet side of the first fluid of the honeycomb structure 1 is formed obliquely.
  • the contact area of the high temperature portion of the first fluid is increased and the total heat transfer area is increased.
  • the end face on the outlet side can be formed obliquely, and in this case, pressure loss can be reduced.
  • FIG. 44 shows an embodiment in which the end face 2 on the inlet side of the first fluid of the honeycomb structure 1 is formed in a concave shape.
  • FIG. 45A shows an embodiment in which the nozzle 59 is installed so that the second fluid turns on the second fluid inlet side of the second fluid circulation portion 6.
  • FIG. 45B shows an embodiment in which the flow path shape of the second fluid circulation part 6 is changed. Since the shape of the flow path is a sawtooth shape having a plurality of steps in the cross section along the axial direction, the heat transfer area increases. Further, the fluid flow can be disturbed, the film thickness can be reduced, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased.
  • FIG. 45C shows an embodiment in which the flow path shape of the second fluid circulation part 6 is changed so as to become smaller toward the downstream side of the first fluid circulation part 5. Further, the fluid flow can be disturbed, the film thickness can be reduced, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased. Furthermore, the flow velocity of the second fluid on the downstream side of the first fluid circulation portion 5 can be increased, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased even in the low temperature portion, and the heat can be increased. It can be recovered more.
  • FIG. 45D shows an embodiment in which the flow path shape of the second fluid circulation part 6 is changed so as to increase toward the downstream side of the first fluid circulation part 5. Further, the fluid flow can be disturbed, the film thickness can be reduced, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased. Furthermore, the flow velocity of the second fluid upstream of the first fluid circulation portion 5 can be increased, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased even in the high temperature portion, and the heat can be increased. It can be recovered more.
  • FIG. 45E shows an embodiment in which a plurality of second fluid inlets 22 are provided in the high temperature part.
  • the fluid flow can be disturbed, the film thickness can be reduced, and the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased. it can.
  • the heat transfer coefficient between the second fluid and the outer peripheral wall 7h can be increased, and heat can be recovered more.
  • Fig. 46 shows an embodiment of the heat exchanger 30 in which the same shape as the cells 3 forming the first fluid circulation part 5 and the heat insulating plate 18 are arranged on the first fluid inlet side of the honeycomb structure 1. Since the opening ratio of the first fluid-side inlet is small, when the heat insulating plate is not arranged, heat is lost at the inlet wall surface when the first fluid contacts the inlet-side end surface. By arranging a heat insulating plate having the same shape in accordance with the inlet, the first fluid enters the inside of the honeycomb while maintaining heat, and the heat of the first fluid is not lost.
  • FIG. 49 shows an embodiment in which the honeycomb structure 1 through which the first fluid flows is bent in one direction.
  • the longitudinal direction axial direction
  • the cell 3 penetrating from one end face 2 to the other end face 2 is similarly curved.
  • the first fluid gas
  • the casing 21 is produced in accordance with the shape of the honeycomb structure 1, the heat exchanger 30 can be installed in a space that cannot be installed in the normal shape.
  • Fig. 50 shows an embodiment of the honeycomb structure 1 in which the partition walls 4 of the cells 3 in the vicinity of the outer peripheral wall 7h are thickened.
  • FIGS. 51A to 51C show an embodiment of the honeycomb structure 1 in which the thickness of the partition walls 4 of the cells 3 is changed so as to gradually become thinner toward the center in a cross section perpendicular to the axial direction.
  • 51A is an embodiment in which the partition 4 is linearly thinned toward the center
  • FIG. 51B is an embodiment in which the partition 4 is thinned while being curved toward the center
  • FIG. 51C is an embodiment in which the partition 4 is at the center. It is embodiment which becomes thin in steps toward it.
  • the heat collected near the center of the honeycomb structure 1 can be efficiently transmitted to the outer peripheral wall 7h, so that the heat exchange amount is increased. Further, it is possible to improve the isostatic strength while suppressing an increase in heat capacity and pressure loss.
  • Fig. 52A and Fig. 52B show an embodiment of a honeycomb structure in which the partition walls are thickened for the cells inside the outermost peripheral cell. Only a few cells are thickened from the outermost peripheral cell, and the partition wall thickness is gradually decreased toward the center side to match the basic partition wall thickness. More specifically, in the embodiment of FIG. 52A, the thickness tb of the basic cell partition 4b inside the boundary 4m is 0.7 to 0.9 of the thickness ta of the outermost peripheral cell partition 4a on the outer peripheral side from the boundary 4m. Double the range. Since heat collected near the center of the honeycomb structure 1 can be efficiently transmitted to the outer peripheral wall 7h, the amount of heat exchange is increased. Moreover, isostatic strength can be satisfied.
  • the thickness ta of the outermost peripheral cell partition wall 4a is in the range of 0.3 to 0.7 times the thickness th of the outer peripheral wall 7h of the honeycomb structure. Since heat collected near the center of the honeycomb structure 1 can be efficiently transmitted to the outer peripheral wall 7h, the amount of heat exchange is increased. Moreover, isostatic strength can be satisfied.
  • the partition wall thickness is sequentially increased from the inner cell to the outermost peripheral cell within the range of 3 cells from the outermost periphery to the inner side of the honeycomb structure 1 in the order of 0.7 ⁇ tb / ta ⁇ .
  • the partition wall thickness is sequentially increased from the inner cell to the outermost peripheral cell within the range of 3 cells from the outermost periphery to the inner side of the honeycomb structure 1 in the order of 0.7 ⁇ tb / ta ⁇ .
  • FIG. 52C is a partial cross-sectional explanatory view showing an embodiment in which contact buildup 8 is applied to the honeycomb structure 1
  • FIG. 52D is a partial cross section showing another embodiment in which contact buildup 8 is applied to the honeycomb structure 1. It is explanatory drawing. In these embodiments, an example in which the portion where the outermost peripheral cell partition wall 4a of the honeycomb structure 1 is in contact with the outer peripheral wall 7h is built up is shown. With such a configuration, it is possible to avoid excessive thickening of the outer peripheral wall thickness and to suppress deformation of the partition 4 of the cell 3.
  • FIG. 53A shows a cell passage cross section of the honeycomb structure 1 having a wave wall.
  • the corrugated honeycomb structure 1 is obtained by forming the partition walls 4 of a normal honeycomb structure 1 in which the shape of the cell 3 is a quadrangle (square) in a cross section perpendicular to the axial direction in a wave shape.
  • the corrugated honeycomb structure 1 includes a honeycomb structure in which all the partition walls 4 are formed of wave walls and has wave walls.
  • the Z-axis direction is the cell passage (axial direction), and the planes perpendicular to this are the X-axis and Y-axis, which are orthogonal coordinate axes.
  • FIG. 53A shows a cell passage cross section of the honeycomb structure 1 having a wave wall.
  • the corrugated honeycomb structure 1 is obtained by forming the partition walls 4 of a normal honeycomb structure 1 in which the shape of the cell 3 is a quadrangle (square) in a cross section perpendicular to the axial direction in
  • FIG. 53A is a cross-sectional view taken along the line A-A ′ in FIG. 53A and shows a cross section (YZ plane) parallel to the cell passage (axial direction).
  • the wall surfaces of the partition walls 4 in both the cell passage direction (axial direction) and the cell passage cross-sectional direction are deformed in a wave shape like the honeycomb structure 1 of the wave wall, the surface area of the partition walls 4 is increased, The interaction between one fluid and the partition can be enhanced.
  • the cross-sectional area of the cell passage is almost constant, but the cross-sectional shape changes, thereby making the flow of the first fluid in the cell passage unsteady and further enhancing the interaction between the first fluid and the partition wall. Is possible.
  • the heat exchange rate can be improved.
  • Fig. 54 shows another embodiment of the honeycomb structure 1 having a wave wall. 53A and 53B, of two pairs of opposing wall surfaces forming the cell channel, a pair of wall surfaces face each other convex surfaces, and another pair of wall surface portions face each other concave surfaces. .
  • the corrugated honeycomb structure 1 shown in FIG. 54 has a structure in which the two convex surfaces or the concave surfaces face each other in two opposing wall surfaces forming the cell passage.
  • FIG. 55A and 55B are views schematically showing an embodiment of the honeycomb structure 1 having a shape in which the partition walls 4 are curved.
  • FIG. 55A is a schematic parallel sectional view showing a cross section parallel to the axial direction
  • FIG. 55B is a schematic vertical sectional view.
  • the honeycomb structure 1 includes a plurality of partition walls 4 each defining a plurality of cells 3 extending in the axial direction. As shown in FIG. 55B, the partition walls 4 project outward from the central axis 1j (in the direction of the outer peripheral wall 7h).
  • a shape curved in a shape hereinafter referred to as “positive curve”.
  • the partition wall 4 exhibits a positive curvature, so that the cell density at the center is smaller than the cell density at the outer periphery. Accordingly, the aperture ratio is larger in the central portion than in the outer peripheral portion.
  • the honeycomb structure 1 having a relatively high cell density the heat exchange efficiency is high, but the pressure loss is large.
  • the first fluid can easily flow in the central portion, so that the pressure loss is reduced.
  • FIG. 56 is a cross-sectional view schematically showing another embodiment of the honeycomb structure 1 having a curved partition wall 4.
  • the honeycomb structure 1 of the embodiment shown in FIG. 56 has a shape in which the partition walls 4 are curved in a convex shape from the outside (outer peripheral wall 7h side) toward the central axis 1j (hereinafter referred to as negative curvature).
  • negative curvature By providing the partition wall 4 exhibiting a negative curvature, the following effects can be obtained.
  • the partition wall 4 exhibits a negative curvature, so that the cell density in the central portion is larger than the cell density in the outer peripheral portion. Accordingly, the aperture ratio is smaller in the central portion than in the outer peripheral portion.
  • the honeycomb structure 1 having a relatively small cell density the pressure loss is small, but the heat exchange rate is lowered.
  • the partition walls 4 exhibiting a negative curve the cell density in the central portion is larger than that in the outer peripheral portion, so that the heat exchange rate is improved.
  • the resistance to the external pressure in the diagonal direction of the cell 3 is increased, so that the strength of the honeycomb structure 1 is also improved.
  • FIG. 57 shows an embodiment of the honeycomb structure 1 including partition walls 4 having different heights in the axial direction at one end 62.
  • the honeycomb structure 1 includes partition walls 4 arranged so as to form a plurality of cells 3 penetrating in an axial direction from one end 62 to the other end 62.
  • the part 62 includes the partition walls 4 having different axial heights.
  • the partition walls 4 having different heights are formed. The existence of the partition walls 4 having different heights at the one end 62 makes the flow of the fluid to be processed at the one end 62 smooth, thereby reducing the pressure loss of the first fluid (gas). it can.
  • the heating body which is the first fluid to be circulated through the ceramic heat exchanger 30 of the present invention including the honeycomb structure 1 having the above configuration, is not particularly limited as long as it is a medium having heat. .
  • the medium to be heated which is the second fluid that takes heat from the heating body (exchanges heat)
  • water is preferable in consideration of handling, it is not particularly limited to water.
  • the honeycomb structure 1 has high thermal conductivity, and a plurality of portions serving as flow paths by the partition walls 4 provide a high heat exchange rate. For this reason, the whole honeycomb structure 1 can be reduced in size and can be mounted on a vehicle. Further, the pressure loss is small with respect to the first fluid (high temperature side) and the second fluid (low temperature side).
  • a honeycomb forming material is formed by extruding a ceramic forming raw material, and partitioned by ceramic partition walls 4 and penetrating in an axial direction from one end face 2 to the other end face 2 to form a plurality of cells 3 serving as fluid flow paths. Shape the body.
  • a honeycomb structure 1 in which a plurality of cells 3 serving as gas flow paths are partitioned by partition walls 4 is formed by extruding a clay containing ceramic powder into a desired shape to form a honeycomb formed body, followed by drying and firing. Can be obtained.
  • the above-described ceramics can be used.
  • a honeycomb structure mainly composed of a Si-impregnated SiC composite material first, a predetermined amount of C powder, SiC powder, A honeycomb formed body having a desired shape is obtained by kneading and forming a binder, water or an organic solvent. Next, the honeycomb formed body is placed in a reduced pressure inert gas or vacuum under a metal Si atmosphere, and the formed body is impregnated with metal Si.
  • the molding raw material is converted into clay, and the clay is extruded in the molding process, thereby forming a plurality of exhaust gas flow paths partitioned by the partition walls 4.
  • a honeycomb formed body having the cells 3 can be formed.
  • the honeycomb structure 1 can be obtained by drying and firing this.
  • the heat exchanger 30 is producible by accommodating the honeycomb structure 1 in the casing 21.
  • the heat exchanger 30 of the present invention exhibits higher heat exchange efficiency than the conventional one, the heat exchanger 30 itself can be downsized. Furthermore, since it can manufacture from the integral type by extrusion molding, it can reduce cost.
  • the heat exchanger 30 can be suitably used when the first fluid is a gas and the second fluid is a liquid.
  • the heat exchanger 30 is suitable for use such as exhaust heat recovery as an improvement in automobile fuel efficiency. Can be used.
  • honeycomb structure 1 After extruding the clay containing the ceramic powder into a desired shape, drying and firing, a honeycomb structure 1 having a material of silicon carbide and a main body size of 33 ⁇ 33 ⁇ 60 mm was manufactured.
  • a casing 21 made of stainless steel As an outer container of the honeycomb structure 1, a casing 21 made of stainless steel was used. In Examples 1 to 4, one honeycomb structure 1 was disposed in the casing 21 (see FIGS. 1A and 1B). As shown in FIG. 10, the interval 15 b between the honeycomb structure 1 and the casing was set to be the same as the cell length 15 a of the honeycomb structure 1.
  • the first fluid circulation part 5 is formed in a honeycomb structure
  • the second fluid circulation part 6 is formed so as to circulate (outside structure) the outer periphery of the honeycomb structure 1 in the casing 21.
  • piping for introducing and discharging the first fluid to the honeycomb structure 1 and the second fluid to the casing 21 was attached to the casing 21. Note that these two paths are completely isolated so that the first fluid and the second fluid do not mix (peripheral flow structure). Further, the external structures of the honeycomb structures 1 of Examples 1 to 4 were all the same.
  • Comparative Example 1 Comparative Example 1 was produced in which the first fluid circulation part was formed of SUS304 piping, and the second fluid circulation part was formed so that the second fluid circulated outside the piping.
  • the heat exchangers of Comparative Examples 2 to 4 having the heat exchanger 41 shown in FIG. 11 in the container were produced.
  • the heat exchange element 41 is partitioned by a ceramic partition wall 44 and penetrates from one end face 42 to the other end face 42 in the axial direction, and has a honeycomb structure having a plurality of cells through which a heating body as a first fluid flows.
  • the first fluid is distributed by a fluid circulation part 45 and a ceramic partition wall 44 and penetrates in a direction orthogonal to the axial direction.
  • the second fluid circulates and heat is transferred to the heated body that is the second fluid that circulates.
  • a plurality of two fluid circulation portions 46 are alternately formed as a single unit (cross flow structure). Inside the plugged cells 43, the partition walls 44 separating the plugged cells 43 are removed to form a slit (slit structure).
  • Example 2 For comparison of the respective manufacturing processes, the manufacturing processes of Example 2, Comparative Example 1, and Comparative Example 3 are shown in FIG. Example 2 has fewer manufacturing steps than Comparative Example 3. In addition, since the comparative example 1 uses piping, a manufacturing method differs greatly compared with an Example.
  • the pipe has a double structure, and a pipe having a second fluid flow path is provided at the outer periphery of the pipe serving as the first fluid flow path.
  • the second fluid flows outside the piping of the first fluid.
  • the (cooling) water flowed outside the pipe (gap 5 mm).
  • the pipe volume of Comparative Example 1 refers to a pipe serving as a first fluid flow path.
  • Table 1 shows the heat exchange rate.
  • Example 1 showed higher heat exchange efficiency than Comparative Example 1.
  • Comparative Example 1 although the side close to the (cooling) water is easy to exchange heat with the first fluid (nitrogen gas), the central portion of the pipe is not easily exchanged heat, and the heat exchange rate as a whole is low. It is thought that it was low.
  • the present invention since the present invention has a honeycomb structure, the wall area where the first fluid (nitrogen gas) and (cooling) water are in contact with each other is larger than that in Comparative Example 1, and this is considered to have resulted in high heat exchange efficiency. .
  • Example 5 A heat exchanger 30 in which the first fluid circulation part 5 and the second fluid circulation part 6 were formed by the honeycomb structure 1 and the casing 21 was produced as follows.
  • honeycomb structure 1 having a material of silicon carbide and a main body size of 52 ⁇ diameter (length) 120 mm is extruded by extruding a clay containing ceramic powder into a desired shape, drying, and firing and impregnating with Si. Manufactured.
  • FIGS. 1A and 1B A covering material was disposed outside the honeycomb structure 1, and a casing 21 made of stainless steel was used as the outer container. Stainless steel was used as the coating material, and a structure in which a punching metal, a plate without holes, and a honeycomb were extended was used. The distance between the coating material and the casing 21 was 5 mm, and in Examples 5 to 8, one honeycomb structure 1 was disposed in the casing 21 (see FIGS. 1A and 1B). As shown in FIG. 10, the interval 15b between the honeycomb structure 1 in which the covering material is disposed and the casing is set to 1 mm (note that the covering material is not drawn in FIG. 10).
  • the first fluid circulation part 5 is formed in a honeycomb structure
  • the second fluid circulation part 6 is formed so as to circulate (outside structure) the outer periphery of the honeycomb structure 1 in the casing 21.
  • piping for introducing and discharging the first fluid to the honeycomb structure 1 and the second fluid to the casing 21 was attached to the casing 21. Note that these two paths are completely isolated so that the first fluid and the second fluid do not mix (peripheral flow structure). Further, the external structures of the honeycomb structures 1 of Examples 5 to 8 were all the same.
  • the heat exchanger of the present invention is not particularly limited even in the automotive field and the industrial field as long as it is used for heat exchange between a heating body (high temperature side) and a heated body (low temperature side). When used for exhaust heat recovery from exhaust gas in the automobile field, it can be used to improve the fuel efficiency of automobiles.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
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CN201080056166.5A CN102652249B (zh) 2009-12-11 2010-12-10 热交换器
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