WO2011009657A3 - Verfahren zur herstellung von decancarbonsäuren - Google Patents

Verfahren zur herstellung von decancarbonsäuren Download PDF

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Publication number
WO2011009657A3
WO2011009657A3 PCT/EP2010/057157 EP2010057157W WO2011009657A3 WO 2011009657 A3 WO2011009657 A3 WO 2011009657A3 EP 2010057157 W EP2010057157 W EP 2010057157W WO 2011009657 A3 WO2011009657 A3 WO 2011009657A3
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
aldehydes
aliphatic
acids
decanecarboxylic acids
Prior art date
Application number
PCT/EP2010/057157
Other languages
English (en)
French (fr)
Other versions
WO2011009657A2 (de
Inventor
Michael Grass
Alfred Kaizik
Hans-Gerd Lüken
Wilfried Büschken
Original Assignee
Evonik Oxeno Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oxeno Gmbh filed Critical Evonik Oxeno Gmbh
Priority to MX2012000840A priority Critical patent/MX2012000840A/es
Priority to CN2010800334835A priority patent/CN102548946A/zh
Priority to SG2012004453A priority patent/SG178071A1/en
Priority to CA2768604A priority patent/CA2768604A1/en
Priority to BR112012001274A priority patent/BR112012001274A2/pt
Priority to EP10722067A priority patent/EP2456745A2/de
Priority to JP2012520973A priority patent/JP5787886B2/ja
Priority to US13/386,523 priority patent/US8907129B2/en
Publication of WO2011009657A2 publication Critical patent/WO2011009657A2/de
Publication of WO2011009657A3 publication Critical patent/WO2011009657A3/de
Priority to ZA2012/01237A priority patent/ZA201201237B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/126—Acids containing more than four carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Gegenstand der Erfindung ist ein Verfahren zur Herstellung eines Gemisches isomerer Decancarbonsäuren, wobei folgende Schritte durchlaufen werden: a) Hydroformylierung eines Kohlenwasserstoffgemisches, enthaltend lineare C4-Olefine, unter Verwendung eines Rhodium enthaltenden Katalysatorsystems; b) Aldolkondensation eines Gemisches von aliphatischen C5-Aldehyden, erhalten aus Schritt a); c) Selektivhydrierung des Gemisches der ungesättigten C10-Aldehyde aus Schritt b) zu aliphatischen C10-Aldehyden; d) unkatalysierte Oxidation des Gemisches der aliphatischen C10-Aldehyde aus Schritt c) erhaltend ein Gemisch mit einem Anteil von mindestens 70 Massen-% 2-Propylheptansäure bezogen auf den Gesamtgehalt der isomeren Decancarbonsäuren.
PCT/EP2010/057157 2009-07-23 2010-05-25 Verfahren zur herstellung von decancarbonsäuren WO2011009657A2 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MX2012000840A MX2012000840A (es) 2009-07-23 2010-05-25 Proceso para la preparacion de acidos decanocarboxilicos.
CN2010800334835A CN102548946A (zh) 2009-07-23 2010-05-25 制备癸酸的方法
SG2012004453A SG178071A1 (en) 2009-07-23 2010-05-25 Method for the production of decanecarboxylic acids
CA2768604A CA2768604A1 (en) 2009-07-23 2010-05-25 Process for preparing decanecarboxylic acids
BR112012001274A BR112012001274A2 (pt) 2009-07-23 2010-05-25 processo para produção de ácidos decancarboxílicos
EP10722067A EP2456745A2 (de) 2009-07-23 2010-05-25 Verfahren zur herstellung von decancarbonsäuren
JP2012520973A JP5787886B2 (ja) 2009-07-23 2010-05-25 デカンカルボン酸の製造法
US13/386,523 US8907129B2 (en) 2009-07-23 2010-05-25 Process for preparing decanecarboxylic acids
ZA2012/01237A ZA201201237B (en) 2009-07-23 2012-02-20 Process for preparing decanecarboxylic acids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009027978A DE102009027978A1 (de) 2009-07-23 2009-07-23 Verfahren zur Herstellung von Decancarbonsäuren
DE102009027978.4 2009-07-23

Publications (2)

Publication Number Publication Date
WO2011009657A2 WO2011009657A2 (de) 2011-01-27
WO2011009657A3 true WO2011009657A3 (de) 2011-04-21

Family

ID=43242579

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/057157 WO2011009657A2 (de) 2009-07-23 2010-05-25 Verfahren zur herstellung von decancarbonsäuren

Country Status (13)

Country Link
US (1) US8907129B2 (de)
EP (1) EP2456745A2 (de)
JP (1) JP5787886B2 (de)
KR (1) KR20120038514A (de)
CN (1) CN102548946A (de)
BR (1) BR112012001274A2 (de)
CA (1) CA2768604A1 (de)
DE (1) DE102009027978A1 (de)
MX (1) MX2012000840A (de)
SG (1) SG178071A1 (de)
TW (1) TW201125845A (de)
WO (1) WO2011009657A2 (de)
ZA (1) ZA201201237B (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013020322B4 (de) 2013-12-05 2019-04-18 Oxea Gmbh Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013020323B3 (de) 2013-12-05 2015-01-08 Oxea Gmbh Verfahren zur Herstellung von isomeren Hexansäuren aus den bei der Herstellung von Pentanalen anfallenden Nebenströmen
DE102013113719A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten α,β-ungesättigter Decenale
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
US9688599B2 (en) * 2014-04-18 2017-06-27 Texmark Chemicals, Inc. Production of mixed aldol products from the products of hydroformylation reactions
JP6493829B2 (ja) * 2014-05-30 2019-04-03 Ｋｈネオケム株式会社 ペンタエリスリトールのエステル及びそれに用いるイソトリデカン酸
CN110187026B (zh) * 2019-05-30 2022-10-25 扬子石化－巴斯夫有限责任公司 一种2-丙基庚醇及其杂质的分析方法
SE1930249A1 (en) * 2019-07-18 2020-11-17 Perstorp Ab USE OF A METHOD FOR REDUCTION OF HEAVY END FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS COMPRISING A BIDENTATE PHOSPHITE LIGAND
WO2021006795A1 (en) * 2019-07-05 2021-01-14 Perstorp Ab A method for reducing heavy end formation and catalyst loss in a hydroformylation process

Citations (6)

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Publication number Priority date Publication date Assignee Title
EP0439013A1 (de) * 1990-01-04 1991-07-31 Praxair Technology, Inc. Vergrösserte Gas-Flüssigkeit-Reaktionen
FR2769624A1 (fr) * 1997-10-09 1999-04-16 Atochem Elf Sa Procede de preparation d'acide carboxylique
WO2001046111A1 (en) * 1999-12-22 2001-06-28 Celanese International Corporation Oxidation process
DE10225282A1 (de) * 2002-06-07 2003-12-18 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
WO2004108648A1 (en) * 2003-06-05 2004-12-16 Lg Chem. Ltd. Method for preparing organic acid
DE102008002187A1 (de) * 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil

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US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
JP3517950B2 (ja) * 1993-06-10 2004-04-12 三菱化学株式会社 アルデヒド類の製造方法
DE19617178A1 (de) * 1995-05-04 1996-11-07 Basf Ag Verfahren zur Herstellung von höheren Aldehyden
DE19524971A1 (de) * 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur katalytischen Selektivhydrierung von mehrfach ungesättigten organischen Substanzen
DE19956410A1 (de) 1999-11-24 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Durchführung von Aldolkondensationen
DE19957522A1 (de) * 1999-11-30 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Durchführung von Aldolkondensationen mittels Mehrphasenreaktion
DE10108474A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10108476A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10108475A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE102004011081A1 (de) 2004-03-06 2005-09-22 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von tertiären Carbonsäuren
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MY155650A (en) * 2007-08-21 2015-11-13 Basf Se Process and device for the oxidation of organic compounds
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009045718A1 (de) 2009-10-15 2011-04-21 Evonik Oxeno Gmbh Verfahren zur Herstellung von Decanolen durch Hydrierung von Decenalen

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0439013A1 (de) * 1990-01-04 1991-07-31 Praxair Technology, Inc. Vergrösserte Gas-Flüssigkeit-Reaktionen
FR2769624A1 (fr) * 1997-10-09 1999-04-16 Atochem Elf Sa Procede de preparation d'acide carboxylique
WO2001046111A1 (en) * 1999-12-22 2001-06-28 Celanese International Corporation Oxidation process
DE10225282A1 (de) * 2002-06-07 2003-12-18 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
WO2004108648A1 (en) * 2003-06-05 2004-12-16 Lg Chem. Ltd. Method for preparing organic acid
DE102008002187A1 (de) * 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil

Also Published As

Publication number Publication date
EP2456745A2 (de) 2012-05-30
JP2012533589A (ja) 2012-12-27
JP5787886B2 (ja) 2015-09-30
US8907129B2 (en) 2014-12-09
TW201125845A (en) 2011-08-01
CN102548946A (zh) 2012-07-04
CA2768604A1 (en) 2011-01-27
DE102009027978A1 (de) 2011-01-27
ZA201201237B (en) 2012-10-31
BR112012001274A2 (pt) 2016-02-10
SG178071A1 (en) 2012-03-29
MX2012000840A (es) 2012-02-28
US20120172624A1 (en) 2012-07-05
WO2011009657A2 (de) 2011-01-27
KR20120038514A (ko) 2012-04-23

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