WO2011001285A1 - Carburants combustibles constitués d'un mélange de butanols - Google Patents

Carburants combustibles constitués d'un mélange de butanols Download PDF

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Publication number
WO2011001285A1
WO2011001285A1 PCT/IB2010/001760 IB2010001760W WO2011001285A1 WO 2011001285 A1 WO2011001285 A1 WO 2011001285A1 IB 2010001760 W IB2010001760 W IB 2010001760W WO 2011001285 A1 WO2011001285 A1 WO 2011001285A1
Authority
WO
WIPO (PCT)
Prior art keywords
butanol
fuel
vol
fuel composition
present
Prior art date
Application number
PCT/IB2010/001760
Other languages
English (en)
Inventor
Wei Xu
Stephan Ralf Vogel
Original Assignee
Saudi Arabian Oil Company
Aramco Services Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Company, Aramco Services Company filed Critical Saudi Arabian Oil Company
Priority to JP2012519077A priority Critical patent/JP2012532241A/ja
Priority to CA2767100A priority patent/CA2767100A1/fr
Priority to EP10749683A priority patent/EP2449064A1/fr
Publication of WO2011001285A1 publication Critical patent/WO2011001285A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number

Definitions

  • fuel additives and fuel compositions are provided as embodiments of the present invention.
  • a fuel composition that is environmentally friendly and has comparable performance properties to ethanol-based or MTBE-based fuels is provided.
  • the fuel composition includes a fuel component and a fuel additive.
  • the fuel composition consists essentially of a fuel component and a fuel additive.
  • the fuel component being present in an amount sufficient to provide adequate BTU content for use in combustion or compression engines.
  • the fuel additive includes at least two isomers of butanols and is present in an amount sufficient to improve an octane rating for the fuel composition.
  • the current invention encompasses any combination of butanol isomers to create the mixed butanols.
  • One preferred embodiment includes the mixed butanols being 5-95 volume % 2-butanol and 5-95 volume % tert-butanol; or alternatively, being 40-60 volume % 2- butanol and 40-60 volume % tert-butanol.
  • This mixed butanol is preferably 1-60 vol % of the butanol enhanced fuel.
  • the presence of any substantial amounts of methanol, ethanol, and propanol in the combustible neat fuel and the butanol enhanced fuel is also possible.
  • lower ketones such as acetone
  • the current invention is practiced substantially in the absence of such lower ketones.
  • Another advantage of the invention and the exclusion of the use of methanol and ethanol is the ability to also exclude long chain alkyl esters and fatty acids that are often used with methanol/ethanol to maintain a minimum Cetane number of about 40 and to assure that dies el bums efficiently.

Abstract

L'invention concerne une composition de carburant comprenant un mélange de butanols tels que, par exemple, 2-butanol, iso-butanol et tert-butanol, de préférence 2-butanol et tert-butanol. Elle concerne également des méthodes de préparation et d'utilisation de la composition à base de mélange de butanols en tant que carburants purs combustibles et/ou constituants de carburant oxygéné présents dans l'essence, le diesel, le carburant aviation, l'essence aviation, l'huile de chauffage, le combustible de soute et analogues.
PCT/IB2010/001760 2009-07-01 2010-06-29 Carburants combustibles constitués d'un mélange de butanols WO2011001285A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2012519077A JP2012532241A (ja) 2009-07-01 2010-06-29 可燃性混合ブタノール燃料
CA2767100A CA2767100A1 (fr) 2009-07-01 2010-06-29 Carburants combustibles constitues d'un melange de butanols
EP10749683A EP2449064A1 (fr) 2009-07-01 2010-06-29 Carburants combustibles constitués d'un mélange de butanols

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US22237409P 2009-07-01 2009-07-01
US61/222,374 2009-07-01
US12/824,432 US20110023355A1 (en) 2009-07-01 2010-06-28 Combustible Mixed Butanol Fuels
US12/824,432 2010-06-28

Publications (1)

Publication Number Publication Date
WO2011001285A1 true WO2011001285A1 (fr) 2011-01-06

Family

ID=43066976

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2010/001760 WO2011001285A1 (fr) 2009-07-01 2010-06-29 Carburants combustibles constitués d'un mélange de butanols

Country Status (5)

Country Link
US (1) US20110023355A1 (fr)
EP (1) EP2449064A1 (fr)
JP (1) JP2012532241A (fr)
CA (1) CA2767100A1 (fr)
WO (1) WO2011001285A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012061909A1 (fr) * 2010-11-12 2012-05-18 Falquete, Marco Antonio Composition combustible à base d'alcools à quatre atomes de carbone et d'additifs pour moteurs à cycle diesel
WO2012095744A3 (fr) * 2011-01-10 2012-09-07 Saudi Arabian Oil Company Procédé pour l'hydratation de butènes mélangés pour produire des alcools mélangés
US8921619B2 (en) 2011-12-05 2014-12-30 Saudi Arabian Oil Company Hydrophilic membrane integrated olefin hydration process
GB2516769A (en) * 2013-10-31 2015-02-04 Shell Int Research High octane unleaded aviation gasoline
US20190185773A1 (en) * 2017-12-18 2019-06-20 Korea Petroleum Quality & Distribution Authority Composite Additive for Fuel

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5699033B2 (ja) * 2011-05-02 2015-04-08 出光興産株式会社 ガソリン組成物
JP5699034B2 (ja) * 2011-05-02 2015-04-08 出光興産株式会社 ガソリン組成物
JP5699032B2 (ja) * 2011-05-02 2015-04-08 出光興産株式会社 ガソリン組成物
US8999013B2 (en) * 2011-11-01 2015-04-07 Saudi Arabian Oil Company Method for contemporaneously dimerizing and hydrating a feed having butene
EP2868735B1 (fr) * 2013-10-31 2017-01-11 Shell Internationale Research Maatschappij B.V. Carburant aviation sans plomb à indice d'octane élevé
US20190390127A1 (en) * 2018-06-20 2019-12-26 Saudi Arabian Oil Company Light-fraction based fuel composition for compression ignited engines
WO2020201964A1 (fr) 2019-04-02 2020-10-08 Sabic Global Technologies B.V. Mélange d'essence sans plomb

Citations (6)

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US3560173A (en) * 1966-12-09 1971-02-02 Lockheed Aircraft Corp Additive for gas turbine,jet propulsion and diesel engine fuels
US4154580A (en) * 1974-03-22 1979-05-15 Mobil Oil Corporation Method for producing a stabilized gasoline-alcohol fuel
DE2832738A1 (de) * 1978-07-26 1980-02-14 Basf Ag Mitteldestillate des erdoels, die als dieseltreibstoffe oder leichtes heizoel geeignet sind, mit verbesserter filtrierbarkeit
US4242101A (en) * 1978-06-26 1980-12-30 Basf Aktiengesellschaft Fuels for gasoline engines
EP1505143A1 (fr) * 2002-05-15 2005-02-09 Kawaguchi, Makoto Carburant pour moteur a combustion interne
US20060137243A1 (en) * 2002-12-24 2006-06-29 Takashi Tsuchida Liquid fuel for internal combustion engine

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CA1224628A (fr) * 1982-12-09 1987-07-28 Union Carbide Corporation Carburants diesel
JP2002038166A (ja) * 2000-05-16 2002-02-06 Jenesu Kk 燃料組成物
US7559961B2 (en) * 2001-04-18 2009-07-14 Standard Alcohol Company Of America, Inc. Mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers
JP2005298530A (ja) * 2002-02-05 2005-10-27 Mipo:Kk 内燃機関用低公害液体燃料
AU2003296971A1 (en) * 2002-12-13 2004-07-09 Eco-Performance Products Ltd. Alcohol enhanced alternative fuels
JP2004197061A (ja) * 2002-12-19 2004-07-15 Hirata Junichi ディーゼル機関用燃料
JP2006037064A (ja) * 2004-07-26 2006-02-09 Nabeshima Masao ディーゼル機関用燃料
CN101932715B (zh) * 2007-02-26 2014-11-12 韩国生产技术研究院 使用海藻生产生物燃料的方法
BRPI0721439A2 (pt) * 2007-03-21 2013-07-23 David Bradin produÇço de mistura de Álcoois étil em veÍculos de combustÍvel flexÍvel por meio de sÍntese de fischer-tropsch

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3560173A (en) * 1966-12-09 1971-02-02 Lockheed Aircraft Corp Additive for gas turbine,jet propulsion and diesel engine fuels
US4154580A (en) * 1974-03-22 1979-05-15 Mobil Oil Corporation Method for producing a stabilized gasoline-alcohol fuel
US4242101A (en) * 1978-06-26 1980-12-30 Basf Aktiengesellschaft Fuels for gasoline engines
DE2832738A1 (de) * 1978-07-26 1980-02-14 Basf Ag Mitteldestillate des erdoels, die als dieseltreibstoffe oder leichtes heizoel geeignet sind, mit verbesserter filtrierbarkeit
EP1505143A1 (fr) * 2002-05-15 2005-02-09 Kawaguchi, Makoto Carburant pour moteur a combustion interne
US20060137243A1 (en) * 2002-12-24 2006-06-29 Takashi Tsuchida Liquid fuel for internal combustion engine

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ANONYMOUS: "Argonne Investigating Butanol/Diesel Blends in Light-Duty Vehicles", GREEN CAR CONGRESS, 12 August 2008 (2008-08-12), pages 1 - 2, XP002610573, Retrieved from the Internet <URL:http://www.greencarcongress.com/2008/08/argonne-investi.html> [retrieved on 20101122] *
KRISTIN BREKKE: "Butanol - An Energy Alternative?", ETHANOL TODAY, March 2007 (2007-03-01), pages 36 - 39, XP002610572, Retrieved from the Internet <URL:http://web.archive.org/web/20070713020720/http://www.ethanol.org/pdf/contentmgmt/March_07_ET_secondary.pdf> [retrieved on 20101122] *
MICHAEL ASH, IRENE ASH: "HANDBOOK OF GREEN CHEMICALS", 1 June 2004, SYNAPSE INFORMATION RESOURCES, pages: 643 - 646, XP001525635 *
See also references of EP2449064A1 *

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9315749B2 (en) 2010-11-12 2016-04-19 Jose Antonio Fabre Liquid fuel composition with alcohols of four carbon atoms and additives, with ignition by compression
WO2012061909A1 (fr) * 2010-11-12 2012-05-18 Falquete, Marco Antonio Composition combustible à base d'alcools à quatre atomes de carbone et d'additifs pour moteurs à cycle diesel
WO2012095744A3 (fr) * 2011-01-10 2012-09-07 Saudi Arabian Oil Company Procédé pour l'hydratation de butènes mélangés pour produire des alcools mélangés
CN103459358A (zh) * 2011-01-10 2013-12-18 沙特阿拉伯石油公司 混合丁烯水合制备混合醇的方法
KR20140040695A (ko) * 2011-01-10 2014-04-03 사우디 아라비안 오일 컴퍼니 혼합 알코올을 생성하기 위한 혼합 부텐의 수산화 공정
JP2014510025A (ja) * 2011-01-10 2014-04-24 サウジ アラビアン オイル カンパニー 混合アルコールを生産する混合ブテンの水和のプロセス
US9593059B2 (en) 2011-01-10 2017-03-14 Saudi Arabian Oil Company Process for the hydration of mixed butenes to produce mixed alcohols
KR101695057B1 (ko) * 2011-01-10 2017-01-10 사우디 아라비안 오일 컴퍼니 혼합 알코올을 생성하기 위한 혼합 부텐의 수산화 공정
US9393540B2 (en) 2011-12-05 2016-07-19 Saudi Arabian Oil Company Hydrophilic membrane integrated olefin hydration process
US9199214B2 (en) 2011-12-05 2015-12-01 Saudi Arabian Oil Company Hydrophilic membrane integrated olefin hydration process
US8921619B2 (en) 2011-12-05 2014-12-30 Saudi Arabian Oil Company Hydrophilic membrane integrated olefin hydration process
GB2516769B (en) * 2013-10-31 2016-03-23 Shell Int Research High octane unleaded aviation gasoline
AU2014206207B2 (en) * 2013-10-31 2015-11-12 Shell Internationale Research Maatschappij B.V. High octane unleaded aviation gasoline
US9127225B2 (en) 2013-10-31 2015-09-08 Shell Oil Company High octane unleaded aviation gasoline
GB2516769A (en) * 2013-10-31 2015-02-04 Shell Int Research High octane unleaded aviation gasoline
US20190185773A1 (en) * 2017-12-18 2019-06-20 Korea Petroleum Quality & Distribution Authority Composite Additive for Fuel

Also Published As

Publication number Publication date
EP2449064A1 (fr) 2012-05-09
US20110023355A1 (en) 2011-02-03
CA2767100A1 (fr) 2011-01-06
JP2012532241A (ja) 2012-12-13

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