WO2010108438A1 - 石材勾缝胶 - Google Patents
石材勾缝胶 Download PDFInfo
- Publication number
- WO2010108438A1 WO2010108438A1 PCT/CN2010/071283 CN2010071283W WO2010108438A1 WO 2010108438 A1 WO2010108438 A1 WO 2010108438A1 CN 2010071283 W CN2010071283 W CN 2010071283W WO 2010108438 A1 WO2010108438 A1 WO 2010108438A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- parts
- weight
- polyester resin
- unsaturated polyester
- air
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Definitions
- Marble glue is an unsaturated resin glue. Since it is mainly used on marble, it is commonly known in the country as marble glue.
- the bonding of stone includes structural bonding and non-structural bonding.
- Marble glue is mainly used for stone filling bonding, also known as non-structural bonding. It is based on the structural bonding (bearing load bonding). It is the use of organic chemical adhesives to repair, fill, and strengthen the defects of the stone, such as cracks, cracks, holes, sand holes, product defects, decoration positioning, etc. , a fixed process.
- the effect of filling is to beautify the visual beauty of the stone appearance and regulate the size of the product.
- Stone joint glue as its name suggests, is mainly suitable for stone joints. Therefore, as a joint glue, the following properties are required:
- Permeability is better (usually expressed by viscosity): Better permeability means that the colloid is fine and easy to adjust. It has a certain fluidity after being mixed with the curing agent, and can penetrate into the gap of fine stone; and because the colloid is fine and sticky The seams can be very thin and add aesthetics. 2. Do not stick to the hands after curing (air drying is better): After the gel is cured, it should be sticky immediately, and the air drying is better. For the renovation of the stone floor of the hotel, it is required to be polished immediately after the joint is glued. If the colloid is sticky, the abrasive disc on the polishing machine will directly form a black seam on the bonding seam when it is thrown or thrown dry, which will affect the appearance. 3.
- the glue should have brightness (hardness can be used to indicate that the hardness is good, then the brightness is high after grinding), which can be consistent with the polishing brightness of stone.
- the above technical solution comprises at least 100 parts by weight of the air-drying unsaturated polyester resin, 1-5 parts by weight of the hydrogenated castor oil, 10-60 parts by weight of the micron-sized silica, and 1 to 15 parts by weight of the anti-shrinkage agent.
- the air-drying unsaturated polyester resin is 100 parts by weight
- the hydrogenated castor oil is 2-4 parts by weight
- the micron-sized silica is 30-50 parts by weight
- the anti-shrinking agent is 5-10. Parts by weight.
- the air-drying unsaturated polyester resin is 100 parts by weight
- the hydrogenated linseed oil is 3 parts by weight
- the micron-sized silica is 40 parts by weight
- the anti-shrinkage agent is 8 parts by weight.
- the air-drying unsaturated polyester resin is: a modified unsaturated polyester resin which synthesizes dicyclopentadiene by a half esterification method, an allyl glycidyl ether modified unsaturated polyester resin , trimethylhydrinyl propane diallyl ether modified air-drying unsaturated polyester resin, the above air-drying unsaturated polyester resin is added with a diluent, a promoter and a polymerization inhibitor in a constant manner (commercially available A saturated polyester resin product is already provided with a diluent, a promoter and a polymerization inhibitor).
- it further comprises from 1 to 5 parts by weight of the reactive diluent.
- the micron-sized silica has an average of 300-1000 mesh.
- the reactive diluent is styrene, ⁇ -mercaptobenzene, glycerol diallyl adipate, diallyl phthalate, o-chlorostyrene, One or more of t-butyl styrene.
- the anti-shrinkage agent comprises polypropyl acetate, polyglycolic acid glyceride, polyvinyl acetate, polyacrylate, polystyrene, polyethylene, polyvinyl chloride, polydecyl methacrylate. One or several of them.
- the stone joint glue of the invention has the following advantages: 1. good permeability; fine colloid, easy to adjust, has certain fluidity after being mixed with the curing agent, can penetrate into the small stone gap; and because the colloid is fine, the joint is glued It can be very fine and enhances the appearance (the joint glue uses reactive diluent, so it is easy to adjust, has good permeability, and does not affect the bonding strength). 2. Do not stick to the hands after curing (air drying is better); After the colloid is cured, it should not be sticky immediately. Because if it is used in the renovation of the hotel stone floor, it is required to be polished immediately after the joint glue is used up.
- the stone jointing glue of the invention has the following advantages: 1.
- the colloid is fine, easy to adjust, and has good permeability; 2. It is not sticky after curing (good air drying property); 3. Strong anti-shrinking ability, no depression after curing 4. After polishing, the glue has brightness, which is equivalent to the polishing brightness of stone.
- the air-drying unsaturated polyester resin is cured in air to form a film without interference from oxygen, and the surface is not sticky. This property is also known as air drying, and the cylinder is called air drying or air drying.
- Unsaturated polyester resin (called UPR) When cured at room temperature, the surface of the product is usually sticky, which is inconvenient for application. Since the curing mechanism of the unsaturated polyester resin is a radical copolymerization reaction, the activity of the radical determines the polymerization rate and thus the molecular weight of the polymer.
- the initial generated radical R combines with molecular oxygen to form a polymer peroxy radical R0 2 ', and the activity of R- is greater than that of R0 2 .
- the half-life of R. is 10 - 8 s, and R0 2 is 10 - 2 . s, staying at the surface at R (this stage inhibits the increase of the molecular weight of the polymer.
- the peroxy radical R (which easily reacts with the hydrogen atom attached to the electropositive carbon to form a hydroperoxide of the polymer) , which is:
- Polymeric hydroperoxides can generate highly reactive free radicals and should continue to form high molecular weight compounds.
- the anti-shrinkage mechanism of the anti-shrinkage agent is: When the stone joint glue is cured, the anti-shrinkage agent is thermally expanded, and its expansion eliminates the volume shrinkage of the polyester when it is cured. The two are subsequently cooled at the same time. Since the shrinkage resistance of the anti-shrinkage agent is much larger than that of the polyester, many small voids are formed at the boundary of the two phases, and its formation eliminates internal stress and causes the polyester to no longer shrink.
- Air-drying unsaturated polyester resins include, but are not limited to, the following materials: modified unsaturated polyester resin for synthesizing dicyclopentadiene by semi-esterification, allyl glycidyl ether modified unsaturated polyester resin, trihydroxyl A mercaptopropane diallyl ether modified air-drying unsaturated polyester resin (all of which is commercially available), and a gas-drying unsaturated polyester resin having a shrinkage ratio of about 5% to 8%.
- the following reactive diluents also have anti-shrinkage effects: diallyl phthalate, o-chlorostyrene, p-tert-butylstyrene.
- the reactive diluent glycerol diallyl ether adipate can also achieve the purpose of air drying (all of the above materials are commercially available). It should be noted that other commonly used reactive diluents can also be used.
- the stone jointing glue consists of 100 parts of air-dried unsaturated polyester resin, 5 parts of hydrogenated castor oil and 15 parts of polyvinyl acetate (anti-shrinkage agent).
- the air-drying unsaturated polyester resin is a modified unsaturated polyester resin which synthesizes dicyclopentadiene by a half esterification method.
- the compressive shear strength (MPa) is: 14.8, tensile shear strength (MPa): 16.3, bending elastic (MPa): 4435.0, impact toughness (KJ/m 2 ): 2.2, hardness (HSD): 73.4, Shrinkage (%): 0.09.
- the stone joint glue of the invention needs to be mixed with the curing agent and stirred evenly, and the mixing ratio of the stone joint glue and the curing agent is 100: 3
- the stone jointing glue consists of 100 parts of air-dried unsaturated polyester resin, 5 parts of hydrogenated castor oil, an average of 10 parts of silica of 1000 mesh, and 15 parts of polyacetic acid (anti-shrinkage agent).
- the air-drying unsaturated polyester resin is a modified unsaturated polyester resin which synthesizes dicyclopentadiene by a half esterification method.
- the compressive shear strength (MPa) is: 16.4, tensile shear strength (MPa): 17.1, bending elastic (MPa): 4085.6, impact toughness (KJ/m 2 ): 3.0, hardness (HSD): 71.0, Shrinkage (%): 0.05.
- the stone joint glue of the invention needs to be mixed with the curing agent and stirred evenly, and the mixing ratio of the stone joint glue and the curing agent is 100: 3
- the compressive shear strength (MPa) is: 14.7, tensile shear strength (MPa): 15.6, bending elastic (MPa): 4673.2, impact toughness (KJ/m 2 ): 2.61, hardness (HSD): 64.5, Shrinkage (%): 2.63.
- Stone joint glue consists of 100 parts of air-dried unsaturated polyester resin, 3 parts of hydrogenated castor oil, an average of 40 parts of 900-millimeter-scale silica, 8 parts of polyethylene (anti-shrinkage agent), 3 parts of o-chlorostyrene (Reactive diluent) composition.
- the air-drying unsaturated polyester resin is a modified unsaturated polyester resin which synthesizes dicyclopentadiene by a half esterification method.
- the compressive shear strength (MPa) is: 14.6, tensile shear strength (MPa): 15.8, bending elastic (MPa): 4490.5, impact toughness (KJ/m 2 ): 2.89, hardness (HSD): 66.8, Shrinkage (%): 0.85.
- Stone joint glue consists of 100 parts of air-dried unsaturated polyester resin, 3 parts of hydrogenated castor oil, 50 parts of micron-sized silica, 8 parts of polyacrylate (anti-shrinkage agent), 4 parts of p-tert-butyl styrene ( Reactive diluent) composition.
- the micron-sized silica has an average of 800 mesh.
- the air-drying unsaturated polyester resin is a trimethylsulfonylpropane diallyl ether modified air-drying unsaturated polyester resin.
- the compressive shear strength (MPa) is: 15.4, tensile shear strength (MPa): 16.7, bending elastic (MPa): 4583.0, impact toughness (KJ/m 2 ): 2.73, hardness (HSD): 65.2, Shrinkage (%): 0.56.
- the stone jointing glue consists of 100 parts of air-dried unsaturated polyester resin, 3 parts of hydrogenated castor oil, 40 parts of micron-sized silica, and 10 parts of poly-propyl acetate (anti-shrinkage agent). Micron-sized silica has an average of 700 mesh.
- the air-drying unsaturated polyester resin is an allyl glycidyl ether-modified unsaturated polyester resin.
- the compression-shear strength (MPa) is: 15.8, tensile shear strength (MPa): 17.0, bending elastic (MPa): 4364.7, impact toughness (KJ/m 2 ): 2.94, hardness (HSD): 67.0, Shrinkage (%): 0.96.
- Stone joint glue consists of 100 parts of air-dried unsaturated polyester resin, 2 parts of hydrogenated castor oil, 30 parts of micron-sized silica, 2 parts of polyvinyl chloride, 3 parts of polyacrylate, glycerol diallyl ether
- the ester is composed of 1 part.
- the micron-sized silica has an average of 600 mesh.
- the air-drying unsaturated polyester resin is a trimethylhydrinyl propane diallyl ether modified air-drying unsaturated polyester resin.
- Stone joint glue consists of 100 parts of air-dried unsaturated polyester resin, 4 parts of hydrogenated castor oil, 30 parts of micron-sized silica, 2 parts of polyvinyl acetate, 2 parts of polystyrene, and glycerol polyadipate. 1 copy, 2 parts of polydecyl methacrylate, 2 parts of diallyl phthalate, and 1 part of glycerol diallyl ether adipate.
- the micron-sized silica has an average of 500 mesh.
- the air-drying unsaturated polyester resin is a trimethylhydrinyl propane diallyl ether modified air-drying unsaturated polyester resin.
- the compressive shear strength (MPa) is: 14.9, tensile shear strength (MPa): 16.3, bending elastic (MPa): 4250.6, impact toughness (KJ/m 2 ): 2.85, hardness (HSD): 69.7, Shrinkage (%): 0.81.
- Stone joint glue consists of 100 parts of air-drying unsaturated polyester resin, 2 parts of hydrogenated castor oil, 30 parts of micron-sized silica, 3 parts of polystyrene, 1 part of polydecyl methacrylate, phthalic acid 2 parts of diallyl ester and 3 parts of o-chlorostyrene (reactive diluent).
- the micron-sized silica has an average of 400 mesh.
- the air-drying unsaturated polyester resin is a trimethylhydrinyl propane diallyl ether-modified air-drying unsaturated polyester resin.
- the compressive shear strength (MPa) is: 15.1, tensile shear strength (MPa): 15.9, bending elastic (MPa): 4293.8, impact toughness (KJ/m 2 ): 2.78, hardness (HSD): 68.9, Shrinkage (%): 1.07.
- the special transparent stone joint glue of the invention is fully tested to meet the requirements of jointing between stones. It should be noted that those skilled in the art can make appropriate modifications and variations to the present invention without departing from the spirit and scope of the invention.
- the substances exemplified in the present invention such as an anti-shrinkage agent, a reactive diluent, and an air-drying unsaturated polyester resin include, but are not limited to, the above substances.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10755438.8A EP2412778A4 (en) | 2009-03-25 | 2010-03-25 | POINTING AGENT FOR STONE |
AU2010227974A AU2010227974A1 (en) | 2009-03-25 | 2010-03-25 | Pointing agent for stone |
CA2756441A CA2756441A1 (en) | 2009-03-25 | 2010-03-25 | Pointing agent for stone |
RU2011142988/05A RU2495899C2 (ru) | 2009-03-25 | 2010-03-25 | Агент для расшивки швов каменной кладки |
MX2011009995A MX2011009995A (es) | 2009-03-25 | 2010-03-25 | Agente cementador para juntas. |
US13/178,507 US8436082B2 (en) | 2009-03-25 | 2011-07-08 | Gap-filling adhesive of stone |
ZA2011/06972A ZA201106972B (en) | 2009-03-25 | 2011-09-23 | Pointing agent for stone |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910061335 CN101531875A (zh) | 2009-03-25 | 2009-03-25 | 石材勾缝胶 |
CN200910061335.3 | 2009-03-25 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/178,507 Continuation US8436082B2 (en) | 2009-03-25 | 2011-07-08 | Gap-filling adhesive of stone |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010108438A1 true WO2010108438A1 (zh) | 2010-09-30 |
Family
ID=41102744
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2010/071283 WO2010108438A1 (zh) | 2009-03-25 | 2010-03-25 | 石材勾缝胶 |
PCT/CN2010/071282 WO2010108437A1 (zh) | 2009-03-25 | 2010-03-25 | 有色石材勾缝胶 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2010/071282 WO2010108437A1 (zh) | 2009-03-25 | 2010-03-25 | 有色石材勾缝胶 |
Country Status (10)
Country | Link |
---|---|
US (2) | US8937115B2 (zh) |
EP (2) | EP2412777A4 (zh) |
CN (1) | CN101531875A (zh) |
AU (4) | AU2010101512A4 (zh) |
BR (1) | BRPI1015446A2 (zh) |
CA (1) | CA2756441A1 (zh) |
MX (1) | MX2011009995A (zh) |
RU (2) | RU2499017C2 (zh) |
WO (2) | WO2010108438A1 (zh) |
ZA (1) | ZA201106972B (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101531875A (zh) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | 石材勾缝胶 |
CN101805581B (zh) * | 2009-03-25 | 2013-01-23 | 武汉市科达云石护理材料有限公司 | 石材勾缝胶 |
CN101851482B (zh) * | 2009-03-25 | 2012-09-26 | 武汉市科达云石护理材料有限公司 | 石材勾缝胶 |
CN101851483B (zh) * | 2010-06-08 | 2014-06-11 | 武汉市科达云石护理材料有限公司 | 一种石材勾缝胶 |
CN101857790A (zh) * | 2010-06-08 | 2010-10-13 | 武汉市科达云石护理材料有限公司 | 一种专用有色石材勾缝胶 |
CN107574994B (zh) * | 2017-08-23 | 2019-12-24 | 浙江宏恩装饰工程有限公司 | 白色石材拼接工艺 |
CN111253895A (zh) * | 2020-03-04 | 2020-06-09 | 郑州石宝宝科技有限公司 | 一种用于石材修补的云石勾缝胶及其制备方法 |
CN114517080A (zh) * | 2022-03-28 | 2022-05-20 | 中海石油(中国)有限公司 | 一种液体钻井堵漏材料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2617495A1 (fr) * | 1987-07-02 | 1989-01-06 | Bandini Silvio | Colle pour bois a base de resine polyester |
CN1141940A (zh) * | 1994-05-12 | 1997-02-05 | 陈仕廉 | 工程装饰粘合剂 |
CN1587334A (zh) * | 2004-08-05 | 2005-03-02 | 武汉市科达云石护理材料有限公司 | 加强型二氧化硅透明云石胶 |
CN1608092A (zh) * | 2001-12-28 | 2005-04-20 | 伊利诺斯器械工程公司 | 粘合剂组合物 |
CN101531875A (zh) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | 石材勾缝胶 |
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US3267056A (en) * | 1962-03-01 | 1966-08-16 | Nopco Chem Co | Thickening compositions comprising a siliceous amino composition and hydrogenated castor oil |
US3438903A (en) * | 1966-05-17 | 1969-04-15 | Ring Sidney B | Plastic radiation and acoustic barrier compositions containing a thixotropic agent |
US3773886A (en) * | 1971-11-24 | 1973-11-20 | Fabri Netics Ltd | Process for forming simulated marble |
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EP0578245A3 (en) * | 1992-07-10 | 1994-07-27 | Mitsubishi Petrochemical Co | Process for producing a resin compound |
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CN101851483B (zh) * | 2010-06-08 | 2014-06-11 | 武汉市科达云石护理材料有限公司 | 一种石材勾缝胶 |
CN101857790A (zh) * | 2010-06-08 | 2010-10-13 | 武汉市科达云石护理材料有限公司 | 一种专用有色石材勾缝胶 |
-
2009
- 2009-03-25 CN CN 200910061335 patent/CN101531875A/zh active Pending
-
2010
- 2010-03-25 CA CA2756441A patent/CA2756441A1/en not_active Abandoned
- 2010-03-25 AU AU2010101512A patent/AU2010101512A4/en not_active Expired
- 2010-03-25 EP EP10755437.0A patent/EP2412777A4/en not_active Withdrawn
- 2010-03-25 BR BRPI1015446A patent/BRPI1015446A2/pt not_active Application Discontinuation
- 2010-03-25 AU AU2010227973A patent/AU2010227973A1/en active Pending
- 2010-03-25 MX MX2011009995A patent/MX2011009995A/es active IP Right Grant
- 2010-03-25 AU AU2010101511A patent/AU2010101511A4/en not_active Expired
- 2010-03-25 EP EP10755438.8A patent/EP2412778A4/en not_active Withdrawn
- 2010-03-25 WO PCT/CN2010/071283 patent/WO2010108438A1/zh active Application Filing
- 2010-03-25 RU RU2011142897/05A patent/RU2499017C2/ru not_active IP Right Cessation
- 2010-03-25 RU RU2011142988/05A patent/RU2495899C2/ru not_active IP Right Cessation
- 2010-03-25 AU AU2010227974A patent/AU2010227974A1/en active Pending
- 2010-03-25 WO PCT/CN2010/071282 patent/WO2010108437A1/zh active Application Filing
-
2011
- 2011-07-07 US US13/178,482 patent/US8937115B2/en active Active
- 2011-07-08 US US13/178,507 patent/US8436082B2/en active Active
- 2011-09-23 ZA ZA2011/06972A patent/ZA201106972B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2617495A1 (fr) * | 1987-07-02 | 1989-01-06 | Bandini Silvio | Colle pour bois a base de resine polyester |
CN1141940A (zh) * | 1994-05-12 | 1997-02-05 | 陈仕廉 | 工程装饰粘合剂 |
CN1608092A (zh) * | 2001-12-28 | 2005-04-20 | 伊利诺斯器械工程公司 | 粘合剂组合物 |
CN1587334A (zh) * | 2004-08-05 | 2005-03-02 | 武汉市科达云石护理材料有限公司 | 加强型二氧化硅透明云石胶 |
CN101531875A (zh) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | 石材勾缝胶 |
Also Published As
Publication number | Publication date |
---|---|
US20110263771A1 (en) | 2011-10-27 |
EP2412777A4 (en) | 2014-07-09 |
EP2412778A1 (en) | 2012-02-01 |
US8937115B2 (en) | 2015-01-20 |
WO2010108437A1 (zh) | 2010-09-30 |
CN101531875A (zh) | 2009-09-16 |
EP2412778A4 (en) | 2014-07-09 |
RU2499017C2 (ru) | 2013-11-20 |
RU2011142988A (ru) | 2013-04-27 |
RU2011142897A (ru) | 2013-04-27 |
EP2412777A1 (en) | 2012-02-01 |
ZA201106972B (en) | 2012-12-27 |
CA2756441A1 (en) | 2010-09-30 |
AU2010227974A1 (en) | 2011-09-29 |
AU2010227973A1 (en) | 2011-09-29 |
US8436082B2 (en) | 2013-05-07 |
MX2011009995A (es) | 2011-11-18 |
US20110301263A1 (en) | 2011-12-08 |
BRPI1015446A2 (pt) | 2018-12-11 |
RU2495899C2 (ru) | 2013-10-20 |
AU2010101512A4 (en) | 2013-09-19 |
AU2010101511A4 (en) | 2013-09-19 |
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