WO2010055949A1 - モルトエキス及びその調製方法 - Google Patents
モルトエキス及びその調製方法 Download PDFInfo
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- WO2010055949A1 WO2010055949A1 PCT/JP2009/069508 JP2009069508W WO2010055949A1 WO 2010055949 A1 WO2010055949 A1 WO 2010055949A1 JP 2009069508 W JP2009069508 W JP 2009069508W WO 2010055949 A1 WO2010055949 A1 WO 2010055949A1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/58—Colouring agents
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/68—Acidifying substances
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/70—Clarifying or fining of non-alcoholic beverages; Removing unwanted matter
- A23L2/72—Clarifying or fining of non-alcoholic beverages; Removing unwanted matter by filtration
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/40—Colouring or decolouring of foods
- A23L5/42—Addition of dyes or pigments, e.g. in combination with optical brighteners
- A23L5/43—Addition of dyes or pigments, e.g. in combination with optical brighteners using naturally occurring organic dyes or pigments, their artificial duplicates or their derivatives
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/20—Malt products
Definitions
- the present invention relates to a malt extract that can be used as a natural tea pigment and a preparation method thereof.
- the present invention relates to a malt extract suitable as a natural tea pigment for coloring foods and drinks such as beverages clearly without floating or precipitation of insoluble matter and a method for preparing the same.
- this invention relates to the acid-resistant malt extract used suitably for coloring of acidic food-drinks whose pH is 2 or more and less than 4.6, and its preparation method.
- caramel pigments that can color various foods such as beverages in tea-based colors
- caramel pigments caramel I, caramel II, caramel III, caramel IV
- cucumber pigments onion pigments, cacao pigments, tamarind pigments, etc.
- caramel pigments obtained by heat-treating edible carbohydrates of starch hydrolyzate, molasses or saccharides have type I, type II, type III, type IV depending on the production method, but those with acid resistance are type IV Only.
- type IV caramel pigment is produced by adding a sulfite compound and an ammonium compound during heat treatment of edible carbohydrates, and therefore tends to be avoided from safety issues.
- insoluble matters are precipitated in cuery pigments, onion pigments and cacao pigments under acidic conditions, and inconveniences such as precipitation and turbidity occur when used in acidic foods and drinks.
- Malt extract is obtained by concentrating and saccharifying malt juice, and has been conventionally used for flavoring of beer flavor to carbonated beverages (Patent Documents 1 and 2) or sweeteners (Patent Document 3). ).
- Patent Document 4 discloses that roasted malt extract can be suitably used for flavor and coloring of noodles.
- JP 2003-250503 A JP-T 63-501193 JP 2004-350570 A JP-A-11-266809
- the malt extract dissolves under acidic conditions, so conventional natural tea pigments (caramel pigments (caramel I, caramel II, caramel III), cucumber pigments, onion pigments, cacao pigments, tamarind pigments) ) Is superior in stability (acid resistance) under acidic conditions. Furthermore, since the malt extract is a natural pigment obtained from wort, it has the advantage of high safety.
- malt extract is mainly used for flavoring. In this case, those adjusted so that the absorbance at a wavelength of 500 nm is about 10 and at most 30 are used.
- an addition amount of 1% by mass or more is required for a malt extract having an absorbance of about 30.
- the amount of malt extract added is increased, suspended matter and precipitation occur during the manufacturing process and over time, and the commercial value of the target food and drink is significantly reduced. There was a problem that the flavor adversely affects the taste of the target food or drink.
- Patent Document 1 also describes that adding malt extract (malt extract) exceeding 0.1 w / v% is not preferable because the miscellaneous taste and gummy taste become strong.
- Patent Documents 1 and 3 even in Patent Documents 1 and 3, the malt extract is only used for the purpose of sweetening and flavoring. Furthermore, the addition amount of the malt extract in Patent Document 1 is 0.55 g / 1000 ml, which is a very low concentration. That is, Patent Documents 1 and 3 do not have a problem itself of suppressing insoluble matters generated when the target food or drink is colored using a high-concentration malt extract.
- Patent Document 4 does not disclose any prevention of precipitation that occurs when a high concentration of malt extract is blended.
- Patent Document 2 discloses a process in which a malt extract diluted during the production process of a hop malt beverage is heated, and the aggregated protein is separated together with a precipitant in a centrifuge or a separator. In such a method, even if turbidity can be temporarily removed at the time of production, precipitation of insoluble matters occurring with time cannot be prevented.
- an object of the present invention is to provide a malt extract that has high safety and can be used as a natural tea pigment in foods and drinks.
- an object of the present invention is to provide a malt extract as a tea-based pigment having acid resistance that can be substituted for a caramel pigment (type IV) that has been used as a natural tea-based pigment.
- a malt extract as a tea-based pigment having acid resistance that can be substituted for a caramel pigment (type IV) that has been used as a natural tea-based pigment.
- the inventors of the present invention have made extensive studies in view of the above-described problems of the prior art.
- the insoluble particles remaining in the malt extract are removed by performing filtration using a filter having a pore size of 0.9 ⁇ m or less. It has been found that by making the particle diameter less than 0.9 ⁇ m, precipitation of insoluble matter generated during the production of colored products and over time can be suppressed, and products such as beverages can be clearly colored.
- Such malt extract can be observed with the naked eye even when dissolved in water adjusted to have a pH of 2 or more and less than 4.6 so that the absorbance is 0.1 or more, further 0.5 or more, or 1.0 or more. From this fact, it was found that acidic foods such as carbonated drinks can be clearly colored without precipitation of insoluble matter.
- the present invention has been completed based on these findings and has the following aspects;
- a malt extract, wherein the insoluble particles contained have a particle size of less than 0.9 ⁇ m.
- the above malt extract stock solution is a malt extract stock solution, a malt extract stock solution or its diluted solution dried, and then re-dissolved in a solvent, or a malt extract stock solution or its diluted solution is centrifuged.
- a method for preparing a malt extract comprising a step of removing an insoluble matter having a particle size of 0.9 ⁇ m or more from a malt extract stock solution or a treatment solution thereof.
- a method for preparing a malt extract comprising obtaining a malt extract by removing an insoluble matter having a particle size of 0.9 ⁇ m or more from a malt extract stock solution or a treatment solution thereof.
- a method for preparing a malt extract comprising a step of filtering a malt extract stock solution or a treatment liquid thereof using a filter having a pore size of 0.9 ⁇ m or less.
- a method for preparing a malt extract comprising obtaining a malt extract by removing an insoluble matter having a particle size of 0.9 ⁇ m or more from a malt extract stock solution or a treatment solution thereof.
- the malt extract prepared in (I-7) to (I-10) is one in which precipitation over time is suppressed, and in this sense, it is referred to as “malt extract in which precipitation over time is suppressed”. it can.
- the above malt extract stock solution is a malt extract stock solution, a malt extract stock solution or its diluted solution dried, and then re-dissolved in a solvent, or a malt extract stock solution or its diluted solution is centrifuged.
- (II-2) A colored product colored with the malt extract according to any one of (I-1) to (I-5).
- (II-5) A method for coloring a food or drink, comprising adding the malt extract according to any one of (I-1) to (I-5) to the food or drink.
- the present invention provides an acid-resistant malt extract and a preparation method thereof.
- the target product is colored using the malt extract of the present invention, particularly when an acidic product having a pH of 2 or more and less than 4.6 is colored, precipitation of insoluble matter generated when the target product is colored or with time. It can be significantly suppressed.
- the malt extract of the present invention can be used as a tea-based pigment that can replace caramel pigment (type IV), which is a conventional acid-resistant natural tea pigment.
- caramel pigment type IV
- the malt extract of the present invention is obtained by removing insoluble matters having a particle size of 0.9 ⁇ m or more, in other words, the particle size of insoluble particles remaining in the malt extract is 0.9 ⁇ m. It is characterized by being less than.
- the malt extract has a particle size of insoluble particles remaining in the malt extract of less than 0.8 ⁇ m, more preferably less than 0.6 ⁇ m.
- whether or not the particle size of the insoluble particles remaining in the malt extract is less than 0.9 ⁇ m is prepared by preparing the target malt extract as an aqueous solution having an absorbance at a wavelength of 500 nm of 0.1.
- the target malt extract As an aqueous solution having an absorbance at a wavelength of 500 nm of 0.1.
- the particle size of the insoluble particles remaining in the malt extract is less than 0.8 ⁇ m or less than 0.6 ⁇ m depends on whether the target malt extract has an absorbance of 0.1 at a wavelength of 500 nm.
- this was filtered using a filter with a pore size of 0.8 ⁇ m or 0.6 ⁇ m, respectively, no insoluble matter that could be observed with the naked eye remained on the filter, and the collected filtrate was subjected to laser diffraction.
- it is used in the formula particle size distribution measuring apparatus it is evaluated that there is no insoluble particle having an average particle diameter of 0.8 ⁇ m or more or 0.6 ⁇ m or more in the filtrate.
- the filter used for the filtration may be made of any material regardless of the material.
- materials whether natural, synthetic or semi-synthetic, include cellulose mixed esters such as cellulose, cellulose diacetate or triacetate: polytetrafluoroethylene, polyamide, polysulfone, polystyrene, polyimide, and polyacrylonitrile.
- cellulose mixed esters such as cellulose, cellulose diacetate or triacetate: polytetrafluoroethylene, polyamide, polysulfone, polystyrene, polyimide, and polyacrylonitrile.
- Preferred is cellulose, cellulose mixed ester such as cellulose diacetate or triacetate, or polytetrafluoroethylene.
- the pore size of the filter can be evaluated based on the bubble point method (JIS K 3832). Specifically, this method measures the pressure of a membrane filter by measuring the pressure (Babble ⁇ ⁇ point) when air is pushed out through the hole of the membrane filter completely infiltrated with liquid (water or isopropyl alcohol). The maximum pore diameter can be determined.
- the malt extract in which the particle size of the insoluble particles remaining in the malt extract is less than 0.9 ⁇ m includes the malt extract in which the particle size of the insoluble particles contained therein is less than 0.9 ⁇ m at least during production. It is.
- the malt extract of the present invention can suppress the precipitation of insoluble matter over a long period of several months to 1 year or more.
- insoluble particles having a particle size of less than 0.9 ⁇ m at the time of production are also It is conceivable that the particle diameter grows gradually as time elapses and the particle size becomes 0.9 ⁇ m or more before insoluble matter is not precipitated. Even in this case, as described above, if the particle size of the insoluble particles contained in the malt extract is less than 0.9 ⁇ m at least immediately after production, it corresponds to the malt extract of the present invention.
- the malt extract of the present invention can be prepared by removing insoluble matter having a particle size of 0.9 ⁇ m or more.
- the particle size is preferably 0.00. It is preferable to prepare by removing insolubles having a particle diameter of 8 ⁇ m or more, and further having a particle diameter of 0.6 ⁇ m or more. As a result, insoluble matter precipitation can be remarkably suppressed, and insoluble matter precipitation can be suppressed over a long period of time, for example, several months to one year or more.
- the malt extract of the present invention is more preferably an insoluble matter even when it is prepared in a high concentration state so that the absorbance at a wavelength of 500 nm is 10 to 1000, more preferably the absorbance is 50 to 1000.
- the precipitation over time is suppressed.
- absorbance when simply described as “absorbance”, it means absorbance at a wavelength of 500 nm.
- the malt extract of the present invention is insoluble even when dissolved in water adjusted to have a pH of 2 or more and less than 4.6 so that the absorbance is 0.1 or more, further 0.5 or more, or 1.0 or more. Precipitation is not observed with the naked eye, and precipitation of insoluble matter over time is suppressed.
- whether or not the precipitation of insoluble matter over time is suppressed depends on whether the malt extract stock solution or the treatment liquid from which the insoluble matter having a particle diameter of 0.9 ⁇ m or more has not been removed is pH 2 or more as described above. This can be judged by the fact that precipitation with time is less than that in a case where the absorbance is adjusted to 0.1 or more in water adjusted to less than 4.6 (control product).
- the malt extract of the present invention has acid resistance and suppresses precipitation over time, and is therefore suitable for coloring acidic products, particularly acidic products having a pH of 2 or more and less than 4.6.
- the malt extract of the present invention can clearly color acidic products having a pH of 2 or more and less than 4.6, and is particularly suitable for coloring acidic products such as acidic beverages that require clarity.
- the conventional natural tea-based pigments such as mulberry pigment, onion pigment, cacao pigment and tamarind pigment are insoluble in the acidic condition and cannot be used for acidic products.
- Natural tea pigments that can be used under acidic conditions include caramel pigments (type IV), but they are manufactured with the addition of sulfites and ammonium compounds during heat treatment of edible carbohydrates, so they are avoided from safety issues.
- the malt extract of the present invention can be prepared by a simple method in which the particle size of insoluble particles remaining in the malt extract is less than 0.9 ⁇ m. According to the malt extract of the present invention thus obtained, Therefore, it is highly useful in that an acidic product can be clearly colored in a tea color without the problem of insolubilizing the pigment component.
- the malt extract of the present invention having the characteristics described above can be prepared by removing insolubles having a particle diameter of 0.9 ⁇ m or more.
- the insoluble matter removal method is not particularly limited as long as the insoluble matter is removed as a result, and can be prepared using various treatment methods. Filtration or centrifugation is preferred.
- malt extract stock solution used in the preparation of the malt extract of the present invention is obtained by saccharifying malt or malt extract obtained by roasting the malt. It is not particularly limited as long as it is a malt extract.
- malt juice obtained by extracting malt or a roasted product thereof with water is saccharified.
- malt or a roasted product thereof is immersed in 0.5 to 100 times, preferably 5 to 20 times the amount of water at room temperature to 100 ° C. for about 30 minutes to 15 hours.
- the malt extract stock solution can be obtained by extracting the mixture by stirring and then saccharifying it.
- Saccharification can be carried out, for example, by heating the wort at 50 to 70 ° C. for 30 minutes to 5 hours, preferably at 60 to 70 ° C. for about 1 to 3 hours, and stirring as necessary. Thereby, saccharide
- High-concentration malt extract stock solution is a method of increasing the roasting degree of malt itself, a method of using Kunststoff malt, roasted malt, chocolate malt, caramel malt, etc. as malt raw materials, or repeated concentration of malt extract using a UF membrane or the like It can be obtained by appropriately selecting a method and the like.
- the present invention has one feature in that a malt extract having a particularly high pigment concentration can be used as a natural tea pigment.
- malt extract from which insoluble matter of 0.9 ⁇ m or more has not been removed that is, malt extract containing insoluble matter of 0.9 ⁇ m or more, produces an insoluble matter over time when prepared at a high concentration.
- malt extract containing insoluble matter of 0.9 ⁇ m or more produces an insoluble matter over time when prepared at a high concentration.
- a malt extract from which insolubles of 0.9 ⁇ m or more have not been removed cannot be adjusted to a high concentration and used as a tea pigment.
- the insoluble particles remaining in the malt extract can be made to have a particle size of less than 0.9 ⁇ m by removing insoluble matters of 0.9 ⁇ m or more.
- the malt extract itself does not precipitate insoluble during storage, and the absorbance of the malt extract in water adjusted to a pH of 2 or more and less than 4.6 is 0.1 or more, further 0.5 or more, or 1 Even when dissolved so as to be 0.0 or more, precipitation of insoluble matter that can be observed with the naked eye is suppressed.
- whether or not precipitation of insoluble matter is suppressed is preferably determined by dissolving the target malt extract in water adjusted to pH 2 or more and less than 4.6 so that the absorbance is 0.1 or more. Even in this case, it can be determined using an index that insoluble precipitates are not observed with the naked eye, and that insoluble precipitates are significantly suppressed over time.
- an acidic product having a pH of 2 or more and less than 4.6 for example, an acidic beverage such as a carbonated beverage can be clearly colored in a state where precipitation of insoluble matter is suppressed.
- malt extract of the present invention may be in any final product form such as liquid, solid, paste product.
- filtration can be used without any distinction between natural filtration, vacuum filtration, pressure filtration, centrifugal filtration, hot filtration, and ultrafiltration.
- the filter used for filtration will not be specifically limited if it is a filter which can remove the insoluble matter which has a particle diameter of 0.9 micrometer or more. From the viewpoint of suppressing the precipitation of insoluble matter that occurs over time, it is desirable to use a filter that can remove insoluble matter having a particle diameter of preferably 0.8 ⁇ m or more, more preferably 0.6 ⁇ m or more. Examples of such a filter include those having a filter pore size of 0.9 ⁇ m or less, preferably 0.8 ⁇ m or less, more preferably 0.6 ⁇ m or less.
- the filter used for the filtration may be made of any material regardless of the material.
- a material regardless of whether it is natural, synthetic or semi-synthetic, those described in the section (I) can be widely used, but preferably cellulose mixed esters such as cellulose, cellulose diacetate or triacetate, Or it is polytetrafluoroethylene.
- the pore diameter of the filter can be evaluated based on the bubble point method (JIS K 3832) as described in the section (I).
- the filtration treatment may be performed directly on the malt extract stock solution, or may be performed on a solution obtained by diluting the malt extract stock solution with a solvent such as water (malt extract diluted solution), or the malt extract stock solution or its dilution.
- a solvent such as water
- malt extract diluted solution a solvent such as water
- malt extract diluted solution a solvent such as water
- malt extract diluted solution a solvent such as water
- malt extract diluted solution a solvent
- a solvent such as water
- the malt extract diluted solution, the malt extract redissolved solution, and the treatment solution in the decanter or centrifugation of the malt extract are collectively referred to as “malt extract treatment solution”.
- centrifugal force When removing an insoluble matter having a particle size of 0.9 ⁇ m or more by centrifugation, it is preferable to apply a centrifugal force of 12000 G or more.
- the processing conditions for centrifugation generally used are about 3000 G, but with such centrifugal force, a minute insoluble matter having a particle diameter of 0.9 ⁇ m or more, specifically 0.9 to 5 ⁇ m is used. It cannot be separated and removed, and as a result, it is not possible to prevent the precipitation of insoluble matters in the malt extract and the precipitation of insoluble matters in acidic products colored using the malt extract.
- the centrifuge used for removing insoluble matter having a particle diameter of 0.9 ⁇ m or more is not particularly limited as long as it is capable of applying a centrifugal force of 12000 G or more, and various centrifuges can be used as long as the centrifuge is used. it can.
- the capacity of a centrifuge is indicated by the value of the centrifugal force generated by G (gravity acceleration), which can be applied to several thousand G, centrifuge, and those that can apply tens of thousands of G or more to ultracentrifuge. It is distinguished from the machine (ultracentrifuge).
- the preparation of the malt extract of the present invention it is preferable to perform a centrifugation treatment using an ultracentrifuge capable of giving a centrifugal force of 12000 G or more.
- the centrifugal separation treatment may be performed directly on the malt extract stock solution as in the filtration treatment, but may also be performed on a malt extract treatment solution such as a malt extract diluent or a redissolved solution.
- centrifugal force can be obtained from the following equation.
- acid-resistant natural pigment production methods and natural pigment purification methods include acid treatment exposed to acidic conditions of pH 4 or lower; adsorption treatment using activated carbon, silica gel, porous ceramic or synthetic adsorption resin; cation exchange resin
- adsorption treatment using activated carbon, silica gel, porous ceramic or synthetic adsorption resin There was a need to perform each treatment such as ion exchange treatment using enzyme or anion exchange resin; enzyme treatment.
- single processing is insufficient, and there is a need to manufacture a final product by combining a plurality of processing steps.
- the present invention is an extremely simple process of removing 0.9 ⁇ m or more of insoluble matter from the malt extract stock solution or its treatment solution, which suppresses the precipitation of insoluble matter that occurs over time, and is further an acidic product.
- a malt extract applicable to the coloring of can be prepared.
- the preparation method of the malt extract of the present invention does not exclude the above-described various treatments. Treatment, adsorption treatment, ion
- the thus obtained malt extract of the present invention has an absorbance of 10 to 1000, more preferably 50 to 1000, and the precipitation of insoluble matter is remarkably suppressed even when the absorbance is adjusted to a high concentration.
- Various products, especially beverages, can be clearly colored.
- the malt extract since the malt extract has acid resistance, it can be suitably used particularly in an acidic region where the pH is less than 4.6 and further the pH is 3 or less.
- the only natural brown pigment that can be used at pH less than 4.6 without precipitating insolubles was caramel pigment (type IV), but the malt extract of the present invention can be substituted for such caramel pigment (type IV). It can be used as a natural brown pigment.
- the present invention provides the use of the aforementioned malt extract of the present invention (hereinafter referred to as “the present invention malt extract”) as a tea-based dye. That is, the tea pigment of the present invention is a pigment containing the aforementioned malt extract of the present invention as a component.
- the tea pigment of the present invention may be the malt extract of the present invention itself, or the malt extract of the present invention is dissolved or dispersed (emulsified) in water, an alcohol such as ethanol or propylene glycol, or other polar solvent. It may have a liquid shape. Or you may have the form of the dry solid state (powder form, granular form, a tablet, etc.) prepared by drying this invention malt extract or the said liquid substance.
- one of the advantages of the tea-based pigment of the present invention is that it is a highly safe natural pigment derived from a malt extract, which is a natural food material, so that additives, particularly artificial additives, are used. It is preferable to prepare without.
- the tea pigment of the present invention is useful as a natural tea pigment for various products such as foods and drinks, pharmaceuticals, quasi drugs, cosmetics, and feeds.
- the target food and drink is not limited, but ice cream, ice milk, lacto ice, sherbet, ice confectionery and other frozen confectionery; milk beverage, lactic acid bacteria beverage, soft drink (including fruit juice), carbonated drink, fruit juice drink, Beverages such as vegetable beverages, vegetable / fruit beverages, sports beverages, powdered beverages; alcoholic beverages such as liqueurs; tea beverages such as coffee beverages and tea beverages; soups such as consomme soup and potage soup; custard pudding, milk pudding Puddings such as pudding with fruit juice, desserts such as jelly, bavaroa and yogurt; gums such as chewing gum and bubble gum (board gum, sugar-coated grain gum); strawberry chocolate, blueberry in addition to coated chocolate such as marble chocolate Chi with flavors such as chocolate and melon chocolate Chocolate such as collate; hard candy (including
- the tea-based pigment of the present invention is applied to an acidic food or drink, the precipitation of insoluble matter is suppressed, and a clear and highly transparent colored food or drink can be provided.
- it can be used for coloring an acidic food or drink having a pH of 2 or more and less than 4.6.
- Such acidic foods and drinks include frozen desserts such as sherbet and ice confectionery; milk drinks, lactic acid bacteria drinks, soft drinks (including fruit juice), carbonated drinks, fruit juice drinks, vegetable drinks, vegetable / fruit drinks, sports drinks, powdered drinks Beverages such as jelly; desserts such as jelly; caramels such as hard candy (including bonbons, butterballs, marbles, etc.) and drops; , Pickled cucumber, pickled moromi, pickled ume, pickled in Fukujin pickled, shiba pickled, ginger pickled, pickled in Korea, pickled ume vinegar; sauces such as separate dressing, non-oil dressing, sauce; strawberry jam, blueberry jam, marmalade, apple jam , Jams such as apricot jam, presaber; fruit wines such as red wine; dairy products such as cheese It is possible.
- frozen desserts such as sherbet and ice confectionery
- milk drinks lactic acid bacteria drinks, soft drinks (including fruit juice), carbonated drinks, fruit juice drinks, vegetable drinks, vegetable
- it can be suitably used for foods and beverages in which turbidity and precipitation due to precipitation of insoluble matter lead to a decrease in commercial value, particularly soft drinks, carbonated drinks and sports drinks characterized by a clear appearance.
- it can be suitably used for acidic beverages having a pH of 2 or more and 3.4 or less.
- the tea pigment of the present invention is used as a coloring agent such as various tablets, capsules, drinks, troches, and mouthwashes in medicines, and as an example in toothpastes and cools in the mouth in quasi drugs.
- a colorant for cosmetics and anti-breathing agents for cosmetics, as a colorant for lipsticks and make-up cosmetics, for feed, for example, various pet foods such as cat food and dog food, food for ornamental fish or cultured fish Can be used as a colorant. It can also be used to color daily necessities such as soap and shampoo.
- the ratio of the tea-based pigment of the present invention to be blended in these products varies depending on the type and purpose of the product, and cannot be specified unconditionally. Among them, it can be appropriately selected and adjusted in the range of usually 0.1 to 5% by mass, preferably 0.2 to 1% by mass.
- Coloring can be performed by adding and mixing the malt extract of the present invention to the target product to be colored. Since the malt extract of the present invention has heat resistance in addition to acid resistance, there is no particular limitation on the timing of addition, and the target product can be colored by a method similar to or more flexible than conventional natural pigments. .
- the malt extract of the present invention is added together with saccharides such as fructose-glucose liquid sugar, raw materials such as acids, fruit juice, etc., and the beverage is colored after sterilization to fill the beverage with a brown color. Can do.
- parts means “parts by mass” and “%” means “% by mass”.
- Products marked with “*” in the text indicate that they are manufactured by San-Ei Gen FFI Co., Ltd., and trademarks marked with “*” in the text indicate that they are registered trademarks of San-Ei Gen FFI Co., Ltd.
- Example 1 Filtration treatment> A filter made of cellulose mixed ester having a diameter of 11 cm (Example 1: pore size 0.6 ⁇ m, Example 2: pore size 0) using 4 g of Celite (calcined diatomaceous earth, particle size: 1 to 100 ⁇ m, source: Celite Corporation) as a filter aid. 0.8 ⁇ m, Comparative Example 1: Pore diameter 1.0 ⁇ m; Advantech Toyo Co., Ltd.) was laid down, and 300 g of the 20% malt extract (standard product) prepared above was filtered. The above pore diameter of the filter means the maximum pore diameter measured by the bubble point method (JIS K 3832, using water). The obtained filtrate was concentrated until the absorbance reached 250, and this was used as a filtered malt extract (Examples 1 and 2, Comparative Example 1).
- the obtained filtrate was concentrated until the absorbance reached 250, and this was used as a cation exchange resin-treated malt extract (Comparative Example 2).
- the retained particle diameter of the qualitative filter paper is obtained from the leaked particle diameter when barium sulfate or the like specified by JIS P 3801 (filter paper (for chemical analysis)) is naturally filtered.
- ⁇ Comparative example 4 Centrifugal treatment (centrifugal effect 3000G)> 300 g of the 20% malt extract (standard product) prepared above was treated with a centrifuge (centrifugal effect 3000 G) for 30 minutes. Next, it is filtered through a qualitative filter paper with a diameter of 11 cm (material: cotton linter pulp, retained particle size: 5 ⁇ m, JIS P 3801: 2 types, manufactured by Advantech Toyo Co., Ltd.), and the obtained filtrate is concentrated until the absorbance is 250. This was used as a centrifuged malt extract.
- the centrifugal force can be obtained by the following formula:
- an acidic carbonated beverage prepared using a malt extract (Comparative Example 1) filtered using a filter having a pore size of 1 ⁇ m is less precipitated or cloudy on the first day after preparation, but after 7 days to 1 month. As a result, precipitation occurred and the commercial value of the beverage was extremely lowered.
- the various natural tea pigments were added to citric acid and trisodium citrate buffer solutions adjusted to pH 2, 3, 4, 5, and 6, respectively, and mixed with stirring. This was preserve
- the amount of each natural tea pigment added was such that the absorbance at a wavelength of 500 nm was 0.5 when dissolved in ion-exchanged water.
- Tables 3 and 4 show the results of observation of the presence or absence of precipitation in each solution (samples 1 to 5) on the day of solution preparation (1 hour after preparation) and after storage for 7 days, respectively.
- malt extract in which precipitation of a visible insoluble matter with time is significantly suppressed even when the target product is darkly colored so that the absorbance is about 0.1. it can.
- malt extract is a natural material, safe and has acid resistance, so it can be used with other natural tea pigments (caramel pigments I, II, III, cuolian pigments, onion pigments, cacao pigments, tamarind pigments)
- the dye itself is not insolubilized under acidic conditions, and can be used as an acid-resistant brown dye that can be substituted for the conventional acid-resistant caramel dye (type IV).
- the malt extract of the present invention can color various acidic products such as carbonated drinks in a safe and clear tea color.
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Abstract
Description
(I)モルトエキス及びその調製方法
(I-1).含有する不溶性粒子の粒子径が0.9μm未満であることを特徴とするモルトエキス。
(II-1).(I-1)乃至(I-5)のいずれかに記載するモルトエキスを含有する茶色系色素。
本発明のモルトエキスは、0.9μm以上の粒子径を有する不溶物が除去されてなること、言い換えればモルトエキス中に残存する不溶性粒子の粒子径が0.9μm未満であることを特徴とする。好ましくは、モルトエキス中に残存する不溶性粒子の粒子径が0.8μm未満、より好ましくは0.6μm未満であるモルトエキスである。
前述する特徴を有する本発明のモルトエキスは、0.9μm以上の粒子径を有する不溶物を除去することで調製することができる。かかる不溶物の除去方法は、結果的に上記不溶物が除去される方法であれば特に限定されず、各種の処理方法を用いて調製することが可能である。好ましくはろ過処理または遠心分離処理である。
本発明は、前述する本発明のモルトエキス(以下、「本発明モルトエキス」という)の茶系色素としての用途を提供するものである。すなわち、本発明の茶系色素は前述する本発明モルトエキスを成分として含有する色素である。
(1)モルトエキスの調製
波長500nmにおける吸光度(以下、同じ)が500である原料のモルトエキス(モルトエキス原液)40gをイオン交換水160gに添加し、20%モルトエキス(標準品)を調製した。なお、当該モルトエキス原液は、麦芽又はこれを焙煎したものを5~20倍量の水に、室温~100℃で30分間~15時間浸漬し、抽出した麦芽汁を糖化することによって調製した。これを以下に説明する各種の処理(ろ過処理、カチオン交換樹脂処理、酵素処理、遠心分離処理)に供して、処理モルトエキスを調製した。
セライト(焼成珪藻土、粒径:1~100μm、入手先:Celite Corporation)4gをろ過補助剤として、直径11cmのセルロース混合エステル製のフィルター(実施例1:孔径0.6μm、実施例2:孔径0.8μm、比較例1:孔径1.0μm;アドバンテック東洋株式会社製)の上に敷き詰め、上記で調製した20%モルトエキス(標準品)300gをろ過した。なお、フィルターの上記孔径は、バブルポイント法(JIS K 3832、水を使用)によって測定される最大孔径を意味する。得られたろ液を吸光度が250となるまで濃縮して、これをろ過処理モルトエキス(実施例1~2、比較例1)とした。
上記で調製した20%モルトエキス(標準品)1000gをカチオン交換樹脂(ダイヤイオンWK-10:三菱化学(株)製)500mLを充填したカラム(カラムサイズφ内径60mm、長さ2000mm)にSV=3で通し、多糖類及びたんぱく質等を除いた。得られた溶出液を直径11cmの定性濾紙(素材:コットンリンターパルプ、保留粒子径:5μm、JIS P 3801:2種レベル、アドバンテック東洋株式会社製)でろ過した。得られたろ液を吸光度が250になるまで濃縮して、これをカチオン交換樹脂処理モルトエキス(比較例2)とした。なお、当該定性濾紙の保留粒子径は、JIS P 3801(ろ紙(化学分析用))で規定された硫酸バリウムなどを自然濾過したときの漏洩粒子径により求めたものである。
上記で調製した20%モルトエキス(標準品)250gにペクチナーゼ(ペクチナーゼG「アマノ」(天野エンザイム(株)製))0.08gを添加し、50℃にて16時間攪拌した。その後、80℃まで加熱しその状態で30分間保持し酵素を失活させた。次いで直径11cmの定性濾紙(素材:コットンリンターパルプ、保留粒子径:5μm、JIS P 3801:2種レベル、アドバンテック東洋株式会社製)でろ過し、得られたろ液を吸光度が250になるまで濃縮して、これを酵素処理モルトエキス(比較例3)とした。
上記で調製した20%モルトエキス(標準品)300gを遠心分離機(遠心効果3000G)で30分間処理した。次いで直径11cmの定性濾紙(素材:コットンリンターパルプ、保留粒子径:5μm、JIS P 3801:2種レベル、アドバンテック東洋株式会社製)でろ過し、得られたろ液を吸光度が250になるまで濃縮して、これを遠心分離処理モルトエキスとした。なお、遠心力は下記の式で求めることができる:
(1)で調製した各種処理モルトエキス(実施例1~2、比較例1~4)を用いて酸性炭酸飲料(コーラ風飲料)を調製した。詳細には、まず各種処理モルトエキス(実施例1~2、比較例1~4)を用いて、表1に示す処方に従ってシロップを調製し、得られたシロップ20部に対して炭酸水80部を加え、酸性炭酸飲料(コーラ風飲料)を調製した(吸光度1.1、pH2.4)。調製後、これを1ヶ月間冷所(5℃)に保管し、飲料中の沈殿物の生成を目視にて観察した。結果を表2に示す。
実施例1のろ過処理モルトエキス並びに各種天然茶系色素(タマネギ色素、コウリャン色素、タマリンド色素、カカオ色素、カラメル色素(IV型))を用いて耐酸性試験(酸性条件下での不溶物析出の有無の検討)を行った。
-:沈殿を認めない
±:沈殿生成を認めるが、少ない
+<++<+++<++++<+++++:明らかな沈殿生成を認める
(+の数が多いほど沈殿生成量が多いことを示す)
Claims (14)
- 含有する不溶性粒子の粒子径が0.9μm未満であることを特徴とするモルトエキス。
- モルトエキス原液またはその処理液を0.9μm以下の孔径を有するフィルターを用いてろ過処理して調製される、請求項1に記載するモルトエキス。
- 上記モルトエキス原液またはその処理液が、波長500nmにおける吸光度が10~1000である、請求項2に記載するモルトエキス。
- 上記モルトエキス原液が、麦芽又はその焙煎物から抽出した麦芽汁を加熱することによって糖化したものであり、上記処理液が、モルトエキス原液の希釈液、モルトエキス原液またはその希釈液を乾燥後、溶媒に再溶解したモルトエキス再溶解液、またはモルトエキス原液またはその希釈液を遠心分離処理した処理液である、請求項2に記載するモルトエキス。
- 請求項1乃至4のいずれかに記載するモルトエキスを含有する茶系色素。
- 請求項1乃至4のいずれかに記載するモルトエキスにより着色された着色製品。
- pHが2以上4.6未満の酸性製品である、請求項6に記載の着色製品。
- 上記酸性製品が酸性飲料である、請求項7に記載の着色製品。
- 請求項1乃至4のいずれかに記載するモルトエキスを飲食品に添加することを特徴とする、飲食物の着色方法。
- 上記飲食品がpH2以上4.6未満の酸性飲食品である、請求項9に記載する着色方法。
- 上記酸性飲食品が酸性飲料である、請求項10に記載する着色方法。
- モルトエキス原液またはその処理液を0.9μm以下の孔径を有するフィルターを用いてろ過処理する工程を有する、耐酸性モルトエキスの調製方法。
- 上記モルトエキス原液またはその処理液が、波長500nmにおける吸光度が10~1000である、請求項12に記載する調製方法。
- 上記モルトエキス原液が、麦芽又はその焙煎物から抽出した麦芽汁を加熱することによって糖化したものであり、上記処理液が、モルトエキス原液の希釈液、モルトエキス原液またはその希釈液を乾燥後、溶媒に再溶解したモルトエキス再溶解液、またはモルトエキス原液またはその希釈液を遠心分離処理した処理液である、請求項12に記載する調製方法。
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JP2010537829A JPWO2010055949A1 (ja) | 2008-11-17 | 2009-11-17 | モルトエキス及びその調製方法 |
US13/129,162 US20110212233A1 (en) | 2008-11-17 | 2009-11-17 | Malt extract and manufacturing method therefor |
EP09826194A EP2353404A4 (en) | 2008-11-17 | 2009-11-17 | MALT EXTRACT AND MANUFACTURING METHOD THEREOF |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5162051B2 (ja) * | 2010-05-19 | 2013-03-13 | サントリーホールディングス株式会社 | 泡の安定化されたビールテイスト飲料 |
JP2013099297A (ja) * | 2011-11-09 | 2013-05-23 | Sanei Gen Ffi Inc | 濃色モルトエキス、及びその製造方法、並びにモルトエキス由来の、味又は臭いのマスキング剤、及びその製造方法 |
JP2013159579A (ja) * | 2012-02-06 | 2013-08-19 | Kao Corp | Ppar活性化剤 |
JP2017046663A (ja) * | 2015-09-04 | 2017-03-09 | キリンビバレッジ株式会社 | 酸味劣化の抑制された容器詰コーヒー飲料 |
Families Citing this family (1)
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EP4051773A1 (en) * | 2019-10-30 | 2022-09-07 | Cargill, Incorporated | Light-colored malt extracts |
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- 2009-11-17 US US13/129,162 patent/US20110212233A1/en not_active Abandoned
- 2009-11-17 JP JP2010537829A patent/JPWO2010055949A1/ja active Pending
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5162051B2 (ja) * | 2010-05-19 | 2013-03-13 | サントリーホールディングス株式会社 | 泡の安定化されたビールテイスト飲料 |
JPWO2011145671A1 (ja) * | 2010-05-19 | 2013-07-22 | サントリーホールディングス株式会社 | 泡の安定化されたビールテイスト飲料 |
JP2013099297A (ja) * | 2011-11-09 | 2013-05-23 | Sanei Gen Ffi Inc | 濃色モルトエキス、及びその製造方法、並びにモルトエキス由来の、味又は臭いのマスキング剤、及びその製造方法 |
JP2013159579A (ja) * | 2012-02-06 | 2013-08-19 | Kao Corp | Ppar活性化剤 |
JP2017046663A (ja) * | 2015-09-04 | 2017-03-09 | キリンビバレッジ株式会社 | 酸味劣化の抑制された容器詰コーヒー飲料 |
Also Published As
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EP2353404A4 (en) | 2012-05-23 |
JPWO2010055949A1 (ja) | 2012-04-12 |
US20110212233A1 (en) | 2011-09-01 |
EP2353404A1 (en) | 2011-08-10 |
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