WO2010034480A3 - Catalyseur d'oxydation de méthanol en formaldéhyde - Google Patents

Catalyseur d'oxydation de méthanol en formaldéhyde Download PDF

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Publication number
WO2010034480A3
WO2010034480A3 PCT/EP2009/006877 EP2009006877W WO2010034480A3 WO 2010034480 A3 WO2010034480 A3 WO 2010034480A3 EP 2009006877 W EP2009006877 W EP 2009006877W WO 2010034480 A3 WO2010034480 A3 WO 2010034480A3
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WO
WIPO (PCT)
Prior art keywords
catalyst
formaldehyde
layer
individual particles
oxidizing methanol
Prior art date
Application number
PCT/EP2009/006877
Other languages
German (de)
English (en)
Other versions
WO2010034480A2 (fr
Inventor
Inga Walzel
Gerhard Mestl
Original Assignee
Süd-Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Süd-Chemie AG filed Critical Süd-Chemie AG
Priority to EP09778677A priority Critical patent/EP2349968A2/fr
Publication of WO2010034480A2 publication Critical patent/WO2010034480A2/fr
Publication of WO2010034480A3 publication Critical patent/WO2010034480A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un catalyseur supporté comprenant un corps moulé de support sur lequel se trouve une couche formée de particules individuelles en oxyde d'un métal de groupe principal, d'un métal de transition précoce ou d'un lanthanoïde, ladite couche ou lesdites particules individuelles étant recouverte(s) d'une composition oxydique contenant du molybdène et/ou du vanadium et/ou du fer, la densité surfacique de ladite composition correspondant au moins à une monocouche. L'invention concerne également l'utilisation du catalyseur lors de la conversion de méthanol en formaldéhyde.
PCT/EP2009/006877 2008-09-24 2009-09-23 Catalyseur d'oxydation de méthanol en formaldéhyde WO2010034480A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09778677A EP2349968A2 (fr) 2008-09-24 2009-09-23 Catalyseur d'oxydation de méthanol en formaldéhyde

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008048698.1 2008-09-24
DE102008048698A DE102008048698A1 (de) 2008-09-24 2008-09-24 Katalysator zur Oxidation von Methanol zu Formaldehyd

Publications (2)

Publication Number Publication Date
WO2010034480A2 WO2010034480A2 (fr) 2010-04-01
WO2010034480A3 true WO2010034480A3 (fr) 2010-05-27

Family

ID=41571410

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/006877 WO2010034480A2 (fr) 2008-09-24 2009-09-23 Catalyseur d'oxydation de méthanol en formaldéhyde

Country Status (3)

Country Link
EP (1) EP2349968A2 (fr)
DE (1) DE102008048698A1 (fr)
WO (1) WO2010034480A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE534233C2 (sv) 2010-01-26 2011-06-07 Formox Ab Katalysator för framställning av aldehyd
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
US20140121403A1 (en) 2012-10-31 2014-05-01 Celanese International Corporation Integrated Process for the Production of Acrylic Acids and Acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
CN114618506A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种3d打印辅助的甲醇氧化制甲醛铁钼催化剂的制备方法及应用
CN112827496B (zh) * 2020-12-29 2022-04-12 上海华谊新材料有限公司 负载型复合氧化物催化剂及其制备和应用
CN115845865B (zh) * 2022-12-13 2024-04-30 西南化工研究设计院有限公司 一种甲醇氧化制甲醛的铁钼催化剂及制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640900A (en) * 1969-03-06 1972-02-08 Du Pont Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts
DE2145851A1 (de) * 1971-09-14 1973-03-22 Degussa Verfahren zur herstellung eines katalysators zur oxydation von methanol zu formaldehyd
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
WO2002022540A2 (fr) * 2000-09-14 2002-03-21 Lehigh University Reacteur a double lit catalytique pour oxydation du methanol
US20040220429A1 (en) * 2002-02-20 2004-11-04 Regents Of The University Of California Process and catalyst for production of formaldehyde from dimethyl ether
WO2007059974A1 (fr) * 2005-11-23 2007-05-31 Süd-Chemie AG Catalyseur sous forme de coque, notamment pour l'oxydation de methanol en formaldehyde, et son procede de production
WO2009126547A1 (fr) * 2008-04-07 2009-10-15 Velocys Inc. Appareil à microcanaux comprenant des parois structurées, processus chimiques, procédés de préparation de formaldéhyde

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DE1280756B (de) 1965-06-14 1968-10-17 Glatt Werner Wirbelbettwanne zur Behandlung, z. B. Trocknen, koernigen Gutes
DE1932892A1 (de) 1969-06-28 1971-01-07 Basf Ag Verfahren zur Herstellung von Formaldehyd
FR2243021B1 (fr) 1973-09-12 1978-02-17 Inst Francais Du Petrole
DE2747581A1 (de) 1977-10-24 1979-04-26 Basf Ag Verfahren zur herstellung von formaldehyd
US4181629A (en) 1978-06-19 1980-01-01 Euteco S.P.A. Catalyst for the oxidation of methanol to formaldehyde and a method of preparing the catalyst
SK279333B6 (sk) 1989-10-16 1998-10-07 Haldor Topsoe A/S Katalyzátor na výrobu aldehydov
DE4006935A1 (de) 1990-03-06 1991-09-12 Wacker Chemie Gmbh Fliessbettapparatur zum mischen, trocknen und beschichten von pulvrigem, koernigem und geformtem schuettgut
DE19709589C2 (de) 1997-03-08 2000-03-30 Bwi Huettlin Gmbh Fließbettapparatur zum Behandeln von partikelförmigem Gut
US6245708B1 (en) * 1998-04-15 2001-06-12 Lehigh University Formation of alcohol conversion catalysts
DE10009017A1 (de) 2000-02-25 2001-09-06 Basf Ag Geformte Katalysatoren
CN1859973B (zh) 2003-09-26 2010-06-16 巴斯福股份公司 通过在流化床装置中涂覆载体材料生产气相氧化催化剂的方法
DE10344845A1 (de) 2003-09-26 2005-04-14 Basf Ag Vorrichtung zum Mischen, Trocknen und Beschichten von pulvrigem, körnigem oder geformtem Schüttgut in einem Fließbett und Verfahren zur Herstellung von Trägerkatalysatoren unter Verwendung einer solchen Vorrichtung
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DE102004014918A1 (de) 2004-03-26 2005-10-13 Basf Ag Katalysator mit einer Silber-Vanadiumoxidphase und einer Promotorphase

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640900A (en) * 1969-03-06 1972-02-08 Du Pont Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts
DE2145851A1 (de) * 1971-09-14 1973-03-22 Degussa Verfahren zur herstellung eines katalysators zur oxydation von methanol zu formaldehyd
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
WO2002022540A2 (fr) * 2000-09-14 2002-03-21 Lehigh University Reacteur a double lit catalytique pour oxydation du methanol
US20040220429A1 (en) * 2002-02-20 2004-11-04 Regents Of The University Of California Process and catalyst for production of formaldehyde from dimethyl ether
WO2007059974A1 (fr) * 2005-11-23 2007-05-31 Süd-Chemie AG Catalyseur sous forme de coque, notamment pour l'oxydation de methanol en formaldehyde, et son procede de production
WO2009126547A1 (fr) * 2008-04-07 2009-10-15 Velocys Inc. Appareil à microcanaux comprenant des parois structurées, processus chimiques, procédés de préparation de formaldéhyde

Also Published As

Publication number Publication date
DE102008048698A1 (de) 2010-04-08
EP2349968A2 (fr) 2011-08-03
WO2010034480A2 (fr) 2010-04-01

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