WO2010034480A3 - Catalyst for oxidizing methanol into formaldehyde - Google Patents

Catalyst for oxidizing methanol into formaldehyde Download PDF

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Publication number
WO2010034480A3
WO2010034480A3 PCT/EP2009/006877 EP2009006877W WO2010034480A3 WO 2010034480 A3 WO2010034480 A3 WO 2010034480A3 EP 2009006877 W EP2009006877 W EP 2009006877W WO 2010034480 A3 WO2010034480 A3 WO 2010034480A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
formaldehyde
layer
individual particles
oxidizing methanol
Prior art date
Application number
PCT/EP2009/006877
Other languages
German (de)
French (fr)
Other versions
WO2010034480A2 (en
Inventor
Inga Walzel
Gerhard Mestl
Original Assignee
Süd-Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Süd-Chemie AG filed Critical Süd-Chemie AG
Priority to EP09778677A priority Critical patent/EP2349968A2/en
Publication of WO2010034480A2 publication Critical patent/WO2010034480A2/en
Publication of WO2010034480A3 publication Critical patent/WO2010034480A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J35/50—
    • B01J35/613—

Abstract

The invention relates to a supported catalyst comprising a molded support and a layer that is made of a metal oxide of a main group metal, an early transition metal, or a lanthanoid, is arranged on the molded support, and is composed of individual particles. An oxide composition, the surface density of which corresponds at least to a monolayer and which contains molybdenum and/or vanadium and/or iron, is provided on the layer or on the individual particles. The invention further relates to the use of said catalyst for reacting methanol into formaldehyde.
PCT/EP2009/006877 2008-09-24 2009-09-23 Catalyst for oxidizing methanol into formaldehyde WO2010034480A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09778677A EP2349968A2 (en) 2008-09-24 2009-09-23 Catalyst for oxidizing methanol into formaldehyde

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008048698.1 2008-09-24
DE102008048698A DE102008048698A1 (en) 2008-09-24 2008-09-24 Catalyst for the oxidation of methanol to formaldehyde

Publications (2)

Publication Number Publication Date
WO2010034480A2 WO2010034480A2 (en) 2010-04-01
WO2010034480A3 true WO2010034480A3 (en) 2010-05-27

Family

ID=41571410

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/006877 WO2010034480A2 (en) 2008-09-24 2009-09-23 Catalyst for oxidizing methanol into formaldehyde

Country Status (3)

Country Link
EP (1) EP2349968A2 (en)
DE (1) DE102008048698A1 (en)
WO (1) WO2010034480A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE534233C2 (en) 2010-01-26 2011-06-07 Formox Ab Catalyst for the preparation of aldehyde
DE102010040923A1 (en) 2010-09-16 2012-03-22 Basf Se Process for the preparation of acrylic acid from ethanol and formaldehyde
DE102010040921A1 (en) 2010-09-16 2012-03-22 Basf Se Process for the preparation of acrylic acid from methanol and acetic acid
US20140121403A1 (en) 2012-10-31 2014-05-01 Celanese International Corporation Integrated Process for the Production of Acrylic Acids and Acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
CN114618506A (en) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 Preparation method and application of iron-molybdenum catalyst for preparing formaldehyde through methanol oxidation assisted by 3D printing
CN112827496B (en) * 2020-12-29 2022-04-12 上海华谊新材料有限公司 Supported composite oxide catalyst and preparation and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640900A (en) * 1969-03-06 1972-02-08 Du Pont Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts
DE2145851A1 (en) * 1971-09-14 1973-03-22 Degussa PROCESS FOR MANUFACTURING A CATALYST FOR OXYDATING METHANOL TO FORMALDEHYDE
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
WO2002022540A2 (en) * 2000-09-14 2002-03-21 Lehigh University Dual catalyst bed reactor for methanol oxidation
US20040220429A1 (en) * 2002-02-20 2004-11-04 Regents Of The University Of California Process and catalyst for production of formaldehyde from dimethyl ether
WO2007059974A1 (en) * 2005-11-23 2007-05-31 Süd-Chemie AG Shell catalyst, in particular for oxidation of methanol to formaldehyde, and also method for production thereof
WO2009126547A1 (en) * 2008-04-07 2009-10-15 Velocys Inc. Microchannel apparatus comprising structured walls, chemical processes, methods of making formaldehyde

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1280756B (en) 1965-06-14 1968-10-17 Glatt Werner Fluid bed tub for treatment, e.g. B. Drying, grainy good
DE1932892A1 (en) 1969-06-28 1971-01-07 Basf Ag Process for the production of formaldehyde
FR2243021B1 (en) 1973-09-12 1978-02-17 Inst Francais Du Petrole
DE2747581A1 (en) 1977-10-24 1979-04-26 Basf Ag METHOD FOR MANUFACTURING FORMALDEHYDE
US4181629A (en) 1978-06-19 1980-01-01 Euteco S.P.A. Catalyst for the oxidation of methanol to formaldehyde and a method of preparing the catalyst
SK279333B6 (en) 1989-10-16 1998-10-07 Haldor Topsoe A/S Catalyst for preparing aldehydes
DE4006935A1 (en) 1990-03-06 1991-09-12 Wacker Chemie Gmbh Fluidised bed appts. for mixing, drying and coating bulk solids - has support tube concentrically placed around down pipe to form ring shaped aperture in mixing chamber
DE19709589C2 (en) 1997-03-08 2000-03-30 Bwi Huettlin Gmbh Fluid bed equipment for treating particulate material
US6245708B1 (en) * 1998-04-15 2001-06-12 Lehigh University Formation of alcohol conversion catalysts
DE10009017A1 (en) 2000-02-25 2001-09-06 Basf Ag Molded catalysts
DE10344845A1 (en) 2003-09-26 2005-04-14 Basf Ag Apparatus for mixing, drying and coating powdered, granular or formed bulk material in a fluidized bed and process for the preparation of supported catalysts using such apparatus
EP1670582A1 (en) 2003-09-26 2006-06-21 Basf Aktiengesellschaft Process for preparing a catalyst for use in oxidation reactions in the gas phase by coating carrier material in a fluidised bed apparatus
BRPI0415423A (en) 2003-10-15 2006-12-05 Basf Ag bulk catalytic material, process for producing the same, and use of bulk catalytic materials
DE10361517A1 (en) 2003-12-23 2005-07-28 Basf Ag Process for the preparation of formaldehyde
DE102004014918A1 (en) 2004-03-26 2005-10-13 Basf Ag Catalyst with a silver vanadium oxide phase and a promoter phase

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640900A (en) * 1969-03-06 1972-02-08 Du Pont Heat treated bismuth molybdate and phosphomolybdate-on-titania catalysts
DE2145851A1 (en) * 1971-09-14 1973-03-22 Degussa PROCESS FOR MANUFACTURING A CATALYST FOR OXYDATING METHANOL TO FORMALDEHYDE
US5907066A (en) * 1996-11-27 1999-05-25 Lehigh University Treating methanol-containing waste gas streams
WO2002022540A2 (en) * 2000-09-14 2002-03-21 Lehigh University Dual catalyst bed reactor for methanol oxidation
US20040220429A1 (en) * 2002-02-20 2004-11-04 Regents Of The University Of California Process and catalyst for production of formaldehyde from dimethyl ether
WO2007059974A1 (en) * 2005-11-23 2007-05-31 Süd-Chemie AG Shell catalyst, in particular for oxidation of methanol to formaldehyde, and also method for production thereof
WO2009126547A1 (en) * 2008-04-07 2009-10-15 Velocys Inc. Microchannel apparatus comprising structured walls, chemical processes, methods of making formaldehyde

Also Published As

Publication number Publication date
EP2349968A2 (en) 2011-08-03
WO2010034480A2 (en) 2010-04-01
DE102008048698A1 (en) 2010-04-08

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