WO2010014548A3 - Procédé pour la préparation de cis-alcène perfluoré - Google Patents

Procédé pour la préparation de cis-alcène perfluoré Download PDF

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Publication number
WO2010014548A3
WO2010014548A3 PCT/US2009/051847 US2009051847W WO2010014548A3 WO 2010014548 A3 WO2010014548 A3 WO 2010014548A3 US 2009051847 W US2009051847 W US 2009051847W WO 2010014548 A3 WO2010014548 A3 WO 2010014548A3
Authority
WO
WIPO (PCT)
Prior art keywords
perfluorinated
alkene
preparation
cis
alkyne
Prior art date
Application number
PCT/US2009/051847
Other languages
English (en)
Other versions
WO2010014548A2 (fr
Inventor
Michael Van Der Puy
Jing-Ji Ma
Original Assignee
Honeywell International Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell International Inc. filed Critical Honeywell International Inc.
Priority to MX2011000995A priority Critical patent/MX2011000995A/es
Priority to JP2011521221A priority patent/JP2011529893A/ja
Priority to EP09803441A priority patent/EP2310347A4/fr
Priority to CN2009801300180A priority patent/CN102112420A/zh
Publication of WO2010014548A2 publication Critical patent/WO2010014548A2/fr
Publication of WO2010014548A3 publication Critical patent/WO2010014548A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un procédé pour la préparation de cis-alcène perfluoré comprenant: la réduction d’un alcyne perfluoré avec de l’hydrogène sur un catalyseur à base de palladium en présence d’un modificateur de catalyseur à base d’amine non aromatique pour former un produit comportant un cis-alcène perfluoré, l’alcyne perfluoré ayant une structure générale: RfC≡CRf dans laquelle Rf est un groupe alkyle perfluoré ayant un nombre d’atomes de carbone compris entre 1 et 6.
PCT/US2009/051847 2008-07-31 2009-07-27 Procédé pour la préparation de cis-alcène perfluoré WO2010014548A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
MX2011000995A MX2011000995A (es) 2008-07-31 2009-07-27 Proceso para la preparacion de cis-alqueno perfluorado.
JP2011521221A JP2011529893A (ja) 2008-07-31 2009-07-27 ペルフッ素化シス−アルケンの製造方法
EP09803441A EP2310347A4 (fr) 2008-07-31 2009-07-27 Procédé pour la préparation de cis-alcène perfluoré
CN2009801300180A CN102112420A (zh) 2008-07-31 2009-07-27 制备全氟化的顺式烯烃的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8507708P 2008-07-31 2008-07-31
US61/085,077 2008-07-31

Publications (2)

Publication Number Publication Date
WO2010014548A2 WO2010014548A2 (fr) 2010-02-04
WO2010014548A3 true WO2010014548A3 (fr) 2010-04-01

Family

ID=41610923

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/051847 WO2010014548A2 (fr) 2008-07-31 2009-07-27 Procédé pour la préparation de cis-alcène perfluoré

Country Status (6)

Country Link
EP (1) EP2310347A4 (fr)
JP (1) JP2011529893A (fr)
KR (1) KR20110049820A (fr)
CN (1) CN102112420A (fr)
MX (1) MX2011000995A (fr)
WO (1) WO2010014548A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892738A (zh) * 2010-05-21 2013-01-23 霍尼韦尔国际公司 生产氟代烯烃的方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2010012799A (es) * 2008-05-23 2010-12-07 Du Pont Proceso de alta selectividad para elaborar dihidrofluoroalquenos.
US8461401B2 (en) * 2010-03-26 2013-06-11 Honeywell International Inc. Method for making hexafluoro-2-butene
US8524955B2 (en) 2010-05-21 2013-09-03 Honeywell International Inc. Process for the preparation of hexafluoro-2-butyne
US8901360B2 (en) 2010-05-21 2014-12-02 Honeywell International Inc. Process for cis 1,1,1,4,4,4-hexafluoro-2-butene
JP5598910B2 (ja) * 2010-06-14 2014-10-01 独立行政法人産業技術総合研究所 フッ素化合物の製造方法
TW201226368A (en) 2010-12-10 2012-07-01 Du Pont Purification of cis-1,1,1,4,4,4-hexafluoro-2-butene via extractive distillation
CN111018659A (zh) * 2014-02-07 2020-04-17 科慕埃弗西有限公司 用于制备z-1,1,1,4,4,4-六氟-2-丁烯的一体化方法
CN106008147B (zh) * 2016-05-23 2018-11-02 北京宇极科技发展有限公司 Z-1，1，1，4，4，4-六氟-2-丁烯的制备方法
CN116060010B (zh) * 2023-03-31 2023-07-04 北京宇极科技发展有限公司 引发剂、氟化催化剂以及e-1,1,1,4,4,4-六氟-2-丁烯的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process
US5750806A (en) * 1995-07-20 1998-05-12 Basf Aktiengesellschaft Preparation of alkenes by partial hydrogenation of alkynes over fixed-bed palladium catalysts
US20010039368A1 (en) * 1999-12-23 2001-11-08 Klaus Reimer Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6014003B2 (ja) * 1978-11-08 1985-04-11 信越化学工業株式会社 シス−オレフィン化合物の選択的製造方法
JPS56133230A (en) * 1980-03-21 1981-10-19 Otsuka Pharmaceut Co Ltd Preparation of cis-olefin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process
US5750806A (en) * 1995-07-20 1998-05-12 Basf Aktiengesellschaft Preparation of alkenes by partial hydrogenation of alkynes over fixed-bed palladium catalysts
US20010039368A1 (en) * 1999-12-23 2001-11-08 Klaus Reimer Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2310347A4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892738A (zh) * 2010-05-21 2013-01-23 霍尼韦尔国际公司 生产氟代烯烃的方法
CN102892738B (zh) * 2010-05-21 2015-07-15 霍尼韦尔国际公司 生产氟代烯烃的方法

Also Published As

Publication number Publication date
KR20110049820A (ko) 2011-05-12
MX2011000995A (es) 2011-03-04
JP2011529893A (ja) 2011-12-15
WO2010014548A2 (fr) 2010-02-04
EP2310347A4 (fr) 2012-10-31
CN102112420A (zh) 2011-06-29
EP2310347A2 (fr) 2011-04-20

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