Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D5/00—Machines or plants for pig or like casting
  • B22D5/02—Machines or plants for pig or like casting with rotary casting tables
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D25/00—Special casting characterised by the nature of the product
  • B22D25/02—Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
  • B22D25/04—Casting metal electric battery plates or the like
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D30/00—Cooling castings, not restricted to casting processes covered by a single main group
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
  • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
  • C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
  • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
  • C25C7/02—Electrodes; Connections thereof

Definitions

• the invention relates to a method defined in the pre- amble of Claim 1.
• the invention further relates to anode casting equipment defined in the preamble of Claim 10.
• the invention relates to the manufacture of anode plates in the refining process of a metal, such as copper, which is carried out after conversion.
• a product is obtained from a flash smelting furnace, containing iron, sulphur and noble metals in addition to copper, and iron and sulphur are removed in the conversion by means of oxygen-enriched air.
• the converter copper thus obtained is conveyed to an anode furnace, where it is further purified to remove the sulphur.
• the sulphur that possibly remains in the conversion in the anode furnace is oxidized into sulphur dioxide by blowing air into the liquid metal. Then, oxygen is removed from the melt .
• the molten copper of the anode furnace is cast into an- ode plates by the anode casting equipment, their copper content being about 99.5%.
• the size of the anode plate is about 1 m x 1 m, and its thickness is about 5 cm.
• the anode typically comprises lifting lugs, by which it can be lifted and suspended in a vertical position for electrolysis.
• the anode weighs about 300-400 kg.
• the finished anode plates are then purified by electrolysis into copper cathodes, the copper content of which is 99.99%.
• the type of presently known anode casting equipment that is used the most is the one, i which includes a casting table that rotates around a vertical axis and contains a number of open moulds that are arranged in a circle.
• the casting table is rotated periodically, so that each move is followed by a stop of a specific duration.
• the anode casting equipment copper is conveyed from the anode furnace along a launder to a casting machine, and further to the open moulds that are made of copper.
• the molten copper is prevented from sticking to the moulds by painting the moulds, at each cycle, with mould paint or a release agent, which can comprise, e.g., barium sulphate mixed with water.
• mould paint or a release agent which can comprise, e.g., barium sulphate mixed with water.
• the casting comprises the following stages: casting, cooling, releasing from the mould, lifting into a cooling tank, and painting the mould.
• the anode cast in the mould cannot be cooled before its surface is solid enough.
• the temperature of the molten anode in the mould is about 1150 0 C (its melting point is 1084 0 C), and it should normally be cooled in the mould to a temperature of 700-950 °C, where it has solidified enough to be detached from the mould.
• the temperature of the copper mould, in which the anode is cast is not lower than about 60 0 C at the beginning of the casting and, generally, during three cycles of the casting table, it reaches a balance, where its inner temperature is about 200 0 C and the surface temperature of the end face, measured in the middle outside the table, is about 150 0 C.
• the mould does not run too hot for its service life not to be too short.
• the water- dilutable release agent that is sprayed on the mould surface after removing the anode also dries enough for no splinters to develop on the edges of the anode that is cast in the mould.
• the release agent is sprayed on the surface of an excessively cold mould, it has no time to dry before casting is started in the mould in question. It is essential for the entire cooling of the mould and the anode that the mould keeps its optimum temperatures, and anodes with sufficient quality for the electrolysis can be cast.
• the anode should be cooled so that it is sufficiently solid to be lifted out of the mould and into immersion cooling in a cooling tank, where the final cooling takes place.
• excess cooling of the anode causes the anode to shrink in the mould, and a crack may develop between the lugs, making the anode useless.
• the anode temperature is preferably 700-950 0 C when lifted from the mould.
• the known method and equipment comprise cooling the anodes in moulds with the casting table rotating, so that so-called full cone nozzles are arranged in several places on top of the mould path at the stopping posi- tions of and above the anodes, cooling water being sprayed by them on the anode surface by conical sprays.
• On top of the cooling positions there is a hood for collecting water vapour.
• Such upstream cooling positions that are directly focused on the anodes are pro- vided in the area of the steam extractor hood at each stopping position, starting from where the anode is solidified enough for the water spray directed at the anode not to cause sagging of the anode surface.
• a water spray directly focused on the anode is a relatively effective way of removing heat from the anode.
• the cooling capacity of the casting table can be adjusted during momentary changes in the casting capacity, so that the desired amount of heat can be removed from the anodes before they are lifted into the cooling tank.
• the amount of cooling water in the known anode casting equipment has been about 20-30 1/min for an anode per mould position and 210 1/min per mould, and the tem- perature of the mould is adjusted by shutting and opening them by the on/off principle, so that a suitable number is operating according to the casting circumstances.
• the upstream water control has been carried out manually by the program of the control room by means of an operator.
• the present cooling system is constructed so that the casting operator changes the state of the mould in the automa- tion system, and the cooling is discontinued in the mould position, where a mould that is to be kept dry has stopped.
• the problem is that the splinters must be removed at a separate machining stage later on, because if left in place, they may cause a short circuit at the electrolytic stage, where the anode plates are hung in a 1 vertical position at a very short distance from each other.
• the object of the invention is to eliminate the disad- vantages mentioned above.
• the object of the invention is to disclose a method and equipment for casting anodes, which enable an increase in the cooling power and the capac- ity of the anode foundry without increasing the number of moulds.
• a further object of the invention is to disclose a method and equipment for casting anodes, which enable cooling the anode without cooling the mould.
• a further object of the invention is to disclose a method and equipment for anode casting, due to which the anode lugs are not essentially cooled, whereby no splinters are formed and the anode does not crack.
• the method according to the invention is characterized in that, which is disclosed in Claim 1.
• the anode casting equipment according to the invention is futher characterized in that, which is disclosed in Claim 10.
• the method according to the invention comprises: a) casting a predefined amount of liquid metal into an open mould; b) cooling the anode cast in the mould at cooling stages, where water is sprayed on the top surface of the anode; c) removing the solidified anode from the mould; and d) repeating the stages a)-c).
• the cooling stages b) in- elude one or more power cooling stages, wherein water is sprayed on the top surface of the anode at high pressure, using at least one water spray, which is directed obliquely at the top surface of the anode so that the water spray passes by the lifting lugs of the anode and the edge zone of the mould surrounding the lifting lugs without essentially touching them.
• the volume flow and the pressure of the water spray are selected so that the water spray penetrates the layer of steam that is possibly on the surface, gets into contact with the anode surface and bounces from the anode surface over the edge zones of the mould from the opposite side of the mould edge zones, essentially without rinsing and cooling.
• the anode casting equipment includes a feeding device for feeding liquid metal and a number of open moulds for receiving the liquid metal from the feeding device.
• Each mould includes a recess for forming a horizontal plate-like anode.
• the recess is surrounded by an essentially horizontal edge zone of the mould.
• One end of the recess comprises lug areas for forming the lifting lugs of the anode.
• the equipment includes quench condensation equipment for cooling the anode cast in the mould with water sprays.
• the quench condensation equipment includes at least one power cooling device, which is arranged to spray water on the top surface of the anode at high pressure with at least one water spray, which is directed obliquely at the top surface of the anode, so that the water spray passes by the edge zone of the mould and the lifting lugs of the anode without essentially touching them.
• the volume flow and the pressure of the water spray are selected so that the water spray penetrates the layer of steam that is possibly on the anode surface, gets into contact with the anode surface and bounces from the anode surface over the edge zone of the mould, from the opposite side of the mould edge zone with respect to the direction of the spray, essentially without rinsing and cooling.
• An advantage of the invention is that no cooling is directed at the lifting lugs of the anode, which ⁇ m- proves the quality of the anode and makes it possible to spray considerable amounts of water on the anode. In connection with cooling the anode, no excess cooling is directed at the edge zones of the mould, whereby the quality of the anode remains high.
• the in- vention provides a possibility to considerably increase the cooling capacity of the existing anode casting equipment, providing a chance to increase the casting capacity without increasing the number of moulds and the size of the casting table.
• a further advantage of the invention is that large amounts of water can be directed at the anode surface to provide economically significant cooling results (adequate to increase the capacity) .
• the water spray of the power cooling stage is directed at an angle of 5- 80° with respect to the anode top surface.
• the water of the power cooling stage that bounces from the anode is collected and directed downwards past the anode, without essentially touching the mould.
• the water spray of the power cooling stage that is sprayed on the anode is formed into a so-called flat water spray.
• water is sprayed at the power cooling stage at a volume flow that is in the order of 100-3000 1/min/m 2 and at a pressure of 2- 7 bar.
• water is sprayed on the anode surface at the power cooling stage for 5-40 sec.
• the pattern of impact of the water spray on the anode surface at the power cooling stage is essentially elongated, such as rectangular, linear, elliptical or the like.
• water is sprayed at the power cooling stage with several water sprays, the impact patterns of which on the anode surface are essentially adjacent, covering the entire area of the anode top surface.
• the residual water is prevented from running on the anode and the mould.
• the anode casting equipment includes at least one spraying nozzle, which is directed to spray water at an angle of 5-80° with respect to the top surface of the anode.
• the power cooling device includes a guide, which is adapted, in the vicinity of and above the end of the mould, to collect and guide the splashing power cooling water downwards past the mould, essentially without touching the mould.
• the guide is mainly shaped as a downwards-opening chute.
• the spraying nozzle is adapted to form a so-called flat water spray.
• the spraying nozzle is arranged to form a water spray, the impact pattern of which on the anode surface is essentially elongated, such as linear, rectangular or el- liptical.
• the power cooling device is arranged to spray water on the anode surface at a volume flow that is in the order of 100-3000 1/min/m 2 , and at a pressure of 2-7 bar.
• the power cooling device is arranged to spray water for 5- 40 sec at a time during the power cooling stage.
• the power cooling device includes a number of spraying nozzles for directing several water sprays at the anode, so that the impact patterns of the water sprays on the anode surface are essentially adjacent, covering the entire area of the anode top surface.
• the power cooling device includes a bypass manifold for distributing the power cooling water to several spraying nozzles.
• the spraying nozzles are arranged in the longitudinal direction at a distance from each other.
• the bypass manifold extends at least partly on top of the anode that is to be cooled.
• Each spraying nozzle is connected to the bypass manifold by a bended tube, which opens in the upper part of the bypass manifold to prevent the residual water from running.
• the bypass manifold is vertical and arranged, with respect to the mould, so that the spraying nozzles extend to a vertical plane that is at a distance from the mould, whereby after the power cooling spraying, the residual water that possibly runs from the spraying nozzles runs past the mould without touching and cooling it.
• FIG. 1 shows a schematic top view of an application of the anode casting equipment according to the invention
• Fig. 2 shows the section II-II of Fig. 1;
• Fig. 3 is an axonometric drawing of an anode manufactured by the anode casting equipment of Fig. 1;
• Fig. 4 shows one mould of the anode casting equipment of Fig. 1;
• Fig. 5 is an axonometric drawing of one power cooling device of the anode casting equipment of Fig. 1;
• Fig. 6 shows a side view of the power cooling device of Fig. 5, and the cross sections of the mould and the anode.
• Fig. 7 shows a side view of another application of the power cooling device.
• Fig. 8 shows a top view of the device of Fig. 7.
• Figs. 1 and 2 show the anode casting equipment, which includes a number of open moulds 2, in which liquid metal, such as copper, is cast from the casting chute of the feeding device 1 for forming anodes 4.
• the moulds 2 are arranged in a horizontal circle around the vertical axis on top of the rotatable casting table 15.
• the casting table 15 is rotated periodically, so that each move is followed by a stop of a specific duration.
• Fig. 4 shows that each mould 2 includes a recess 3 for forming the horizontal plate-like anode 4.
• the recess 3 is surrounded by an essentially horizontal edge zone 5 of the mould.
• One end of the recess 3 comprises lug areas 6 for forming the lifting lugs 7 of the anode.
• Fig. 3 shows the anode 4 of Fig. 4, which is to be formed, comprising lifting lugs 7.
• the size of the anode 4 is about 1 m x 1 m, its thickness is about 5 cm and its weight about 300
• the temperature of the metal is about 1150 0 C.
• the casting table 15 moves it to the cooling stage, which is carried out by cooling equipment 8.
• the anode is cooled by the cooling equipment 8 by spraying the anode surface with water sprays in several sequential stopping positions.
• the cooling equipment 7 includes a hood 16, by which the steam generated during cooling is re- moved.
• the cooling equipment I 1 the water sprays are sprayed by upstream nozzles, which are placed directly on top of the anodes, forming a full conical spray.
• the cooling equipment 8 comprises, in the rotation direction of the casting table, three power cooling devices 9, which carry out the power cooling stages.
• one end of the anode is raised off the mould by push pins 17 provided in the bottom of the mould 2 (see Figs. 2 and 4) .
• An ejector 18 grips the anode and takes it to final cooling. When removed from the mould, the temperature of the anode is about 700-950 °C.
• the cooling equipment 8 preferably comprises about 3-4 power cooling devices 9.
• the power cooling stages can be initiated immediately, when the anode surface is cool enough to endure cooling without sagging.
• the power cooling is preferably distributed to as many power cooling devices 9 as possible, as then the cooling is easier and more exact to control than when implemented in one position.
• the spraying time at a sin- gle power cooling device 9 may be, for example, about 10 seconds, and it takes time at the first power cooling stage for the surface temperature of the anode to decrease to a temperature, where the anode no longer emits a yellow glow.
• the mould advances to a painting stage 19, wherein a release agent, e.g., barium sulphate mixed with water is painted on the surface of the mould recess and dried for a while, when the mould moves ahead. After this, the mould 2 is ready for casting another anode.
• a release agent e.g., barium sulphate mixed with water
• Fig. 5 shows the power cooling device 9, which is arranged to spray water on the top surface of the anode 4 at high pressure and with twenty water sprays 10, at the most, each of them being directed obliguely at the top surface of the anode 4, so that the water spray passes by the edge zone 5 of the mould and the lifting lugs 7 of the anode without touching them, whereby the water spray does not essentially cool the mould.
• the volume flow and the pressure of the water spray 10 are selected so that the water spray penetrates the layer of steam, which is formed by water that is left on the anode surface from the previous spraying stages, and gets into contact with the surface of the anode 4.
• the impact patterns of the water sprays 10 on the anode surface are essentially adjacent, covering the entire area of the top surface of the anode 4.
• the water that is fed at high pressure bounces from the surface of the anode 4 over the edge zone 5 of the mould, from the opposite side of the edge zone of the mould with respect to the direction of the spray, without essentially rinsing and cooling.
• the anodes lie in the moulds so that the lifting lugs 7 are on the side of the periphery of the casting table 15 and the water sprays 10 are directed towards the centre of the casting table.
• a guide 12 is adapted in the vicinity of and above the end of the mould 4 to collect and guide the upwards- splashing power cooling water downwards past the mould, so that the water does not essentially touch and cool the mould.
• the guide 12 is shaped as a mainly downwards-opening chute, which is closed by end walls at both ends.
• the spraying nozzles 11 are directed so as to spray water at an angle of 5-80° with respect to the anode top surface.
• the spraying nozzle 11 forms a water spray 10, the impact pattern of which on the anode surface is essentially elongated, such as linear, rectangular, or has ⁇ a flat elliptical shape.
• the spraying nozzle 11 is the head of a tube that is pressed flat. Shaping nozzles can also be used to provide fan or flat water sprays of a preferable shape .
• the power cooling device 9 sprays water on the surface of the anode 4 at a volume flow rate of 100-3000 1/min/m 2 and a pressure of 2-7 bar.
• the maximum spraying time, during which this amount of water should be sprayed on the anode, depends on the time of the stopping cycle of the casting table; accordingly, the power cooling device 9 can be arranged so as to spray water on the anode for 5-40 sec at a time.
• the power cooling device 9 includes a bypass manifold 13, which distributes the power cooling water at the same pressure to several spraying nozzles 11.
• the bypass manifold 13 comprises spraying nozzles 11 at a distance from each other.
• the bypass manifold 13 is bifurcated, each branch extending in a parallel relationship on top of the anode 4 that is to be cooled.
• the spraying nozzles 11 are connected to the bypass manifold 13 by bended tubes 14, which open in the upper part of the bypass manifold 13.
• a quick discharge conduit can be arranged in the connecting part of the bypass manifold 13, through which conduit the residual water is removed.
• the bypass manifold 13 is vertical and arranged, with respect to the mould 2, so that the spraying nozzles 11 extend not higher than to a vertical plane that is at a distance S from the mould 2. After ending the power cooling spraying from the nozzles 11, any running residual water runs past the mould without touching and cooling it.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Electrochemistry (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Continuous Casting (AREA)
• Molds, Cores, And Manufacturing Methods Thereof (AREA)
• Electrolytic Production Of Metals (AREA)

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Citations (5)

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• 2008
  • 2008-02-29 FI FI20085191A patent/FI120931B/fi not_active IP Right Cessation
• 2009
  • 2009-02-20 PE PE2009000256A patent/PE20100042A1/es not_active Application Discontinuation
  • 2009-02-26 CN CN2009801130033A patent/CN102036769B/zh active Active
  • 2009-02-26 JP JP2010548137A patent/JP5391210B2/ja not_active Expired - Fee Related
  • 2009-02-26 EA EA201001182A patent/EA018136B9/ru not_active IP Right Cessation
  • 2009-02-26 WO PCT/FI2009/050164 patent/WO2009106690A1/en not_active Ceased
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