WO2009083092A1 - Balle de mèche pour filtre, dispositif et procédé de production d'une balle de mèche pour filtre ainsi que de bandes de mèche pour filtre - Google Patents

Balle de mèche pour filtre, dispositif et procédé de production d'une balle de mèche pour filtre ainsi que de bandes de mèche pour filtre Download PDF

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Publication number
WO2009083092A1
WO2009083092A1 PCT/EP2008/010296 EP2008010296W WO2009083092A1 WO 2009083092 A1 WO2009083092 A1 WO 2009083092A1 EP 2008010296 W EP2008010296 W EP 2008010296W WO 2009083092 A1 WO2009083092 A1 WO 2009083092A1
Authority
WO
WIPO (PCT)
Prior art keywords
filter tow
strips
bale
filter
strip
Prior art date
Application number
PCT/EP2008/010296
Other languages
German (de)
English (en)
Inventor
Paul Rustemeyer
Original Assignee
Rhodia Acetow Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Acetow Gmbh filed Critical Rhodia Acetow Gmbh
Priority to BRPI0819590 priority Critical patent/BRPI0819590A2/pt
Priority to US12/809,976 priority patent/US20100300468A1/en
Priority to EP08866006A priority patent/EP2227103A1/fr
Priority to CN2008801252816A priority patent/CN101925311A/zh
Priority to JP2010538398A priority patent/JP5415447B2/ja
Priority to CA2710315A priority patent/CA2710315A1/fr
Publication of WO2009083092A1 publication Critical patent/WO2009083092A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H45/00—Folding thin material
    • B65H45/02—Folding limp material without application of pressure to define or form crease lines
    • B65H45/06—Folding webs
    • B65H45/08—Folding webs longitudinally
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02—Manufacture of tobacco smoke filters
    • A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02—Manufacture of tobacco smoke filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H45/00—Folding thin material
    • B65H45/12—Folding articles or webs with application of pressure to define or form crease lines
    • B65H45/20—Zig-zag folders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H45/00—Folding thin material
    • B65H45/12—Folding articles or webs with application of pressure to define or form crease lines
    • B65H45/24—Interfolding sheets, e.g. cigarette or toilet papers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H54/00—Winding, coiling, or depositing filamentary material
    • B65H54/76—Depositing materials in cans or receptacles
    • B65H54/78—Apparatus in which the depositing device or the receptacle is reciprocated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2801/00—Application field
    • B65H2801/54—Cigarette making

Definitions

  • the present invention relates to a filter tow bale having the features of the preamble of claim 1, an apparatus and a method for producing a filter tow bale and a filter tow strip.
  • a filter tow bale of the type mentioned is for example manufactured and sold by the applicant.
  • filters are used, which are made of a band or a continuous strand of crimped cellulose acetate fibers, the so-called filter tow.
  • spun filaments of cellulose acetate are crimped in a stuffer box, whereby the impressed crimp structure is fixed while passing through a dryer.
  • the filter tow After the filter tow has been brought to a constant final moisture content, it is laid loosely into jugs of several meters in regular patterns. The loose tow layer is then compacted in bale presses into a filter tow bale and finally packed, which is provided for further processing into filters.
  • filter tow to filter rods The processing of filter tow to filter rods is carried out on a filter rod machine on which the filter tow in a processing section as strong as possible to develop its maximum filling power, which is then gathered on the format of the future cigarette filter and coated with paper.
  • a filter rod machine On which the filter tow in a processing section as strong as possible to develop its maximum filling power, which is then gathered on the format of the future cigarette filter and coated with paper.
  • To buckle the filter tow it is pulled apart by means of compressed air driven spreader nozzles and stretched by a system of draw rolls with threaded or screwed surfaces. Thereafter, the spread filter tow is fed to a spray box to triacetin ⁇ in which the Acetatober Structure is solubilized and made tacky.
  • the filter tow band In the format part of the filter rod machine, the filter tow band is shirred and on the cross section of the compressed future filter rod. The filaments stick together and form a three-dimensional spatial network structure
  • the filter tow strips should have similar properties and, on the other hand, should run as evenly as possible from the filter tow bale as well as run into the double filter rod machine.
  • the invention has for its object to provide a filter tow bale, which allows the most uniform drainage of filter tow strip and is suitable for use in a double filter rod machine. Furthermore, an apparatus and a method for producing a filter tow bale and a filter tow strip for such a filter tow bales are to be specified.
  • this object is achieved with respect to the filter tow bale by the subject-matter of claim 1, with regard to the device by the subject-matter of claim 10, with regard to the method by the subject-matter of claim 18 and with respect to the filter tow strip solved the subject of claim 21.
  • the invention has the advantage that spontaneous voltage increases of the filter Tows on the double filter rod machine are largely avoided by the separate filter tow strips, whereby the associated density fluctuations are minimized in the filter produced.
  • the filters Tows can be made simultaneously and stored so that their properties are similar or identical, resulting in the production on the double filter rod machine to improved filter uniformity of both strands.
  • the identical run lengths of the two filters reduce Tows production waste. For different filter tow lengths, for example due to the drainage of two different filters Tow bales, the process of inserting a new filter tow causes increased waste and machine downtime.
  • the bale according to the invention also makes it possible to insert different filters Tows in the bales, so that, for example, filter rod machines for special filters can be supplied with two different Tows.
  • the at least two filter tow strips are chaotically piled in insertion paths, in particular in substantially parallel paths or in acute-angled zigzag paths in the bale.
  • This embodiment is based on the general idea to arrange the two filter tow strips directed in bales, wherein the two strips form a web pattern.
  • the web pattern can be constructed, for example, from essentially parallel webs or from acute-angled zigzag webs.
  • the two filter tow strips are chaotically heaped along and within the webs, respectively. This means that in this embodiment, the chaotically piled filter tow strips each have a preferred direction or a dominant direction, which runs in batches in the web.
  • the tracks thus each form imaginary lateral boundaries within which the chaotically heaped filter tow strips are arranged. Due to the web-like arrangement of the layered filter tow strips, the flow behavior of the strip is advantageously influenced by the bale.
  • the two filter tow strips can be arranged side by side in the filter tow bale substantially in parallel paths and have a distance which is at least 0 cm and at most less than half the bale width. At a distance of 0 cm, the filter tow strips or the webs within which the filter tow strips are arranged abut each other directly. The distance between the parallel tracks or the parallel strips can be> 0 cm and at most less than half the bale width. In a particularly preferred embodiment, at least two filter tow strips are arranged overlapping at least in sections and have an overlapping region. The overlap area may have an overlap degree of 100% to> 0%. Subareas of this overlap area are also possible.
  • the filter tow strips or the webs within which the filter tow strips are arranged are completely superimposed.
  • the filter tow strips can be stored in such a way in the bale, that the strips are arranged alternately at the top and bottom.
  • the strip arranged below in a strip at the end of the bale has an inflection reversal in such a way that the strip, which is initially arranged below, is arranged on top of the returning path after the inflection point reversal.
  • the invention is based on the idea of providing an insertion device which cooperates with a can for depositing the filter tow and means for simultaneously producing or providing at least two separate filter tow strips.
  • the separate filter tow strips by a single or a double insertion device layered together in the pot can be stored.
  • the inventive method for producing a filter tow bale in particular for processing in a double filter rod machine, at least two separate filter tow strips are produced or provided simultaneously, layered together in a can and pressed into a bale shape.
  • the filter tow bale according to the invention can be produced in a simple manner.
  • a filter tow strip of crosslinked and crimped filaments which is particularly suitable for a filter according to the invention, has at least two partial strips on, wherein the partial strips at least partially, in particular completely overlapping arranged and connected in the overlapping area by applying a mechanical surface force. Due to the easy connection between the two partial strips, which are otherwise considered as separate partial strips in the context of the invention, the flow behavior of the filter tow strip from the bale is positively influenced.
  • FIG. 1 shows a schematic cross section of two filter tow strips in different combinations A - E in the region of the insert
  • FIG. 2 shows a filter tow bale according to the invention during the course of the
  • Fig. 3 shows a filter tow bale according to the invention during the expiration of
  • Fig. 4 is a schematic representation of the top of the bale surface, wherein the insertion track of two superimposed filter tow strip is shown.
  • Fig. 1 shows schematically different variants A - E for the combination of two filter tow strips 1, 1 ', whereby the combination of the two filter tow strips 1, 1' takes place before or during the insertion into a jug.
  • the filter tow located in the pot is then pressed into a double tow bale 2.
  • the combined filter tow strips shown in FIG. 1 are located in the insert (not shown), in particular between the conveyor rollers of an inserter.
  • This illustration is chosen for reasons of clarity, since the arrangement of the two filter tow strips 1, 1 'relative to each other there is particularly well clear.
  • the Arrangement of the two filter tow strips 1, 1 'in the insert determines the arrangement of the two strips 1, 1' in the filter tow bale 2. This means that the strips 1, 1 'arranged parallel in the insert, as shown in the filter tow bale 2 are also arranged substantially parallel or in parallel paths.
  • the superimposed strips 1, 1 'according to illustration B are also arranged one above the other in the bale or are stored in superimposed webs.
  • the filing of the filter tow strips in the pot and thus the arrangement of the filter strips in the pressed bale takes place in layers.
  • the webs are arranged in a predetermined pattern, which results from the arrangement of the filter tow strip 1, 1 'in the insert and the leadership of the filter tow strip 1, 1' when inserting.
  • the filter tow strips 1, 1 ' are each chaotically heaped.
  • the tracks follow a given pattern.
  • the webs are arranged parallel, completely overlapping or partially overlapping.
  • the arrangement of the filter tow strips 1, V and the associated webs is explained in more detail with reference to the variants A - E according to FIG.
  • the two filter tow strips 1, 1 ' are arranged at a distance next to one another.
  • the filter tow strips 1, 1 ' may have a distance of 0 cm from one another, so that the filter tow strips 1, 1' directly touch.
  • the distance between the two filter tow strips 1, 1 'to correspond to half the width of the double tow bale 2, so that one filter tow strip 1, V is assigned one half of the double tow bale 2.
  • all distance values between 0 cm and half the bale width or less than half the bale width are possible, in particular in the range between 0.5 cm and 20 cm, between 5 cm and 20 cm or between 5 cm and 10 cm.
  • the two filter tow strips 1, 1 'in length are completely overlapping combined. In this way, over the entire strip width forms a light connection between the two filter tow strip 1, 1 ', which allows a particularly uniform, synchronous running of the filter tow strip 1, 1' of the invention double tow bale 2.
  • the two filter tow strips 1, 1 ' can also, as shown in variant C, partially overlapping each other be combined, wherein the degree of overlap of the two filter tow strip 1, 1 'between 0% (variant A) and 100% (variant B) may vary. Even if a slight connection is established by the compression of the strips 1, 1 'arranged one above the other, the strips are regarded as separate strips 1, 1' in the sense of the invention.
  • the combined strip essentially consists of four filter tow layers.
  • the first filter tow strip 1 has a degree of overlap of 50% with the second filter tow strip 1 ', whereby the non-overlapping part of the first filter tow strip 1 is folded so that it overlaps on the overlapping part of the second filter tow strip 1 ', in particular with the overlap area congruent, rests.
  • the outer, non-overlapping part of the second filter tow strip 1 ' is also folded so that it comes to rest on the folded first filter tow strip 1.
  • the connecting surface between the two filter tow strips 1, 1 ' is particularly large, so that a relatively intensive and yet easy-to-release connection between the two filter tow strips 1, 1' is formed and thus to a particularly advantageous, uniform and synchronous running of the combined strip or the two filter tow strip 1, 1 'of the invention Double Tow bale 2 leads.
  • FIGS. 2 and 3 each show a double tow bale 2 according to the invention, wherein the two filter tow strips 1, 1 'according to variant A from FIG. 1 are arranged next to one another.
  • a bale 2 with superimposed strips 1, 1 'or webs according to variant B would be handled according to FIG. 2.
  • the distance between the two filter tow strips 1, 1 'in FIG. 2 is less than half the bale width, while the distance between the two filter tow strips 1, 1 'in the double tow bale 2 according to FIG. 3 corresponds exactly to half the bale width.
  • FIGS. 2 and 3 a drain device 3 with guide rings 4 is schematically illustrated in FIGS. 2 and 3, via which the first filter tow strip 1 and the second filter tow strip 1 'run off the bale 2 and are fed to a double filter rod machine (not shown).
  • the two filter tow strips 1, 1 ' are respectively arranged meandering in a plane in the double tow bale 2, wherein the distance between the two filter tow strips 1, 1' to one another is substantially constant.
  • the embodiment according to FIG. 3 differs from FIG. 2 in that one half of the double tow bale 2 is assigned to a respective filter tow strip 1, 1 '.
  • the first filter tow strip 1 When inserting the filter tow strip 1, 1 'in the bale 2 so for example, the first filter tow strip 1 is inserted in the middle of the bale 2 starting meandering toward an outer edge in parallel paths, while the second filter tow strip 1' of a Beginning opposite outer edge, parallel to the first filter tow strip 1 meandering towards the center of the double tow bale 2 is inserted.
  • the two first laid webs have a distance to each other, which corresponds to half the bale width. Since the two filter tow strips 1, 1 'are arranged parallel to one another, the other respectively corresponding, parallel paths are spaced from each other by the amount of half the bale width.
  • a filter tow bale 2 of compressed filter tow comprises at least 2 separate filter tow strips 1, 1 ', which are arranged in layers, preferably in the same layer.
  • a filter tow bale with exactly two filter tow strips is also known as a double tow bale.
  • the strips are each arranged together, in particular in pairs in a layer and together form a plane.
  • a surface is considered to be the surface which is swept once by the filter tow or the corresponding inserter as part of a laying cycle.
  • the filter tow bale is constructed of a plurality of corresponding layers or levels arranged one above the other, each by jointly depositing the two Filter tow strips are formed in a jug with subsequent pressing of the strips.
  • the stripes over several layers are ideally formed throughout the entire bale throughout.
  • the arrangement of the filter tow strips is carried out according to a predetermined pattern, which may vary depending on the process engineering requirements. The pattern results from the arrangement of the webs in which the filter tow strips are deposited in the pot and which can also be found in the bale 2 after pressing.
  • the webs correspond to the preferred directions of the filter tow strips, which are chaotically piled within the webs or stored statistically rearranged. An example of a corresponding accumulation track is shown in FIG.
  • two filter tow strips 1, 1 ' are arranged substantially one above the other.
  • the arrangement of the filter tow strips 1, 1 'does not mean that the two traces of accumulation are arranged exactly one above the other.
  • the accumulation track shown in FIG. 4 results, with the two filter tow strips 1, 1' having a common preferred direction.
  • the insertion paths resulting from this preferred direction are arranged one above another in the example according to FIG. 4 and have an overlap degree of 100%.
  • the two webs, within which the accumulation traces of the two strips 1, 1 'are arranged, are offset from each other in such a way that the splitting traces essentially overlap only in half. It is clear that in the case of statistically rearranged hemming, there are larger or smaller degrees of overlap in certain areas. However, it is important that, for example, at an overlap degree of 50%, the accumulation tracks or tracks at least predominantly run so that they lie in about half of each other.
  • the arrangement of the tracks or accumulation marks in the bale is essentially determined by how the filter tow strips 1, 1 'are arranged in the insert, in particular in the rollers of the insert. This arrangement is shown in the variants A - E according to FIG. 1. For example, in variant C (about 50% degree of overlap) results in a corresponding arrangement of the accumulation tracks or tracks in the compressed bale.
  • the invention also includes bales with more than two separate filter tow strips, for example with 3 or 4 strips.
  • the parallel arrangement of the filter tow strips 1, 1 ' means that the webs in which the filter tow strips 1, 1' are arranged are arranged in pairs directly adjacent to each other or directly adjacent to each other in the bale.
  • the tracks of the first and second filter tow strips 1, 1 ' may be overlapping, directly adjacent, i. be arranged in abutment or parallel with a distance from each other.
  • the two filter tow strips 1, 1 'arranged overlapping in the bale 2 are inserted so that they enter into a light connection.
  • the simultaneously produced separate filter tow strips are combined by a single and a double, or generally multiple insertion device (not shown) placed in the pot.
  • the loading device is coupled to a correspondingly programmed control.
  • the control of the loading device allows the storage of the two filter tow strips in the pot according to a predetermined pattern, for example in superimposed webs.
  • the apparatus for producing a filter tow bale further comprises, in addition to the means for simultaneous production described above, a spinner for producing filaments, a crimping device for crimping the filaments, a dryer and the loading device which cooperates with the can for depositing the filter tow.
  • the separating device may comprise two guide rings spaced transversely to the conveying direction of the filter tow strip and a guide ring arranged upstream of the guide rings in the conveying direction.
  • the separating device may comprise at least one separating wedge.
  • a jug can be charged with two separate filter tow strips, which are provided in the form of two individual bales.
  • the individual bales can be provided for example in the form of broke bales. From the single bales, two strips are withdrawn and transferred together into a jug.
  • the separate filter tow strips 1, 1 ' can be produced in various ways, with no restriction on the number of filter tow strips, but more than two, for example three or four filter tow strips can be prepared or provided.
  • the particular advantages of the exemplary embodiments according to the invention result from the fact that the filter tow strips 1, 1 'are deposited together in layers in the pot and pressed into bales.
  • These filter tow bales have at least two separate filter tow strips which are arranged in batches together in layers.
  • the insertion of the filter tow strips in the double tow bales in such a way that the filter tow strips overlap, furthermore offers the advantage that the filter tow strips make a light connection with each other, which is achieved by pressing, ie by applying mechanical Pressure is effected. It has been found that such a loose connection between the filter tow strips allows a particularly uniform and synchronous running of the strips from the bale, so that density fluctuations in the manufactured filter strand are avoided.
  • a connected from partial strips filter tow strip is claimed, the relative low strength of the compound is determined by the fact that this is generated by applying mechanical pressure to the sub-strips, in particular during pressing of the bale.

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  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Filtering Materials (AREA)
  • Auxiliary Devices For And Details Of Packaging Control (AREA)

Abstract

L'invention concerne une balle de mèche pour filtre (2) composée d'une mèche de filtre comprimée et caractérisée en ce que la balle de mèche pour filtre (2) comporte au moins deux bandes de mèche pour filtre séparées (1, 1'), disposées ensemble en couches.
PCT/EP2008/010296 2007-12-21 2008-12-04 Balle de mèche pour filtre, dispositif et procédé de production d'une balle de mèche pour filtre ainsi que de bandes de mèche pour filtre WO2009083092A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BRPI0819590 BRPI0819590A2 (pt) 2007-12-21 2008-12-04 Fardo de cabo de acetato, dispositivo para a fabricação de um fardo de cabo de acetato com um dispositivo de deposição, método para a fabricação de um fardo de cabo de acetato e fita de cabo de acetato
US12/809,976 US20100300468A1 (en) 2007-12-21 2008-12-04 Filter tow bale, method and device for producing a filter tow bale and filter tow strips
EP08866006A EP2227103A1 (fr) 2007-12-21 2008-12-04 Balle de mèche pour filtre, dispositif et procédé de production d'une balle de mèche pour filtre ainsi que de bandes de mèche pour filtre
CN2008801252816A CN101925311A (zh) 2007-12-21 2008-12-04 滤嘴丝束捆包、用于制造滤嘴丝束捆包以及滤嘴丝束条的设备和方法
JP2010538398A JP5415447B2 (ja) 2007-12-21 2008-12-04 フィルタートウベール、フィルタートウベールの製造装置及び製造方法、並びにフィルタートウストリップ
CA2710315A CA2710315A1 (fr) 2007-12-21 2008-12-04 Balle de meche pour filtre, dispositif et procede de production d'une balle de meche pour filtre ainsi que de bandes de meche pour filtre

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007061933A DE102007061933A1 (de) 2007-12-21 2007-12-21 Filter Tow Ballen, Vorrichtung und Verfahren zur Herstellung eines Filter Tow Ballens sowie Filter Tow Streifen
DE102007061933.4 2007-12-21

Publications (1)

Publication Number Publication Date
WO2009083092A1 true WO2009083092A1 (fr) 2009-07-09

Family

ID=40451081

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/010296 WO2009083092A1 (fr) 2007-12-21 2008-12-04 Balle de mèche pour filtre, dispositif et procédé de production d'une balle de mèche pour filtre ainsi que de bandes de mèche pour filtre

Country Status (13)

Country Link
US (1) US20100300468A1 (fr)
EP (1) EP2227103A1 (fr)
JP (1) JP5415447B2 (fr)
KR (1) KR20100101658A (fr)
CN (1) CN101925311A (fr)
AR (1) AR069805A1 (fr)
BR (1) BRPI0819590A2 (fr)
CA (1) CA2710315A1 (fr)
DE (1) DE102007061933A1 (fr)
RU (1) RU2446725C2 (fr)
TW (1) TW200927001A (fr)
UA (1) UA100134C2 (fr)
WO (1) WO2009083092A1 (fr)

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Publication number Priority date Publication date Assignee Title
KR200482558Y1 (ko) * 2011-10-12 2017-02-22 코오롱글로텍주식회사 단섬유 제조용 토우가이드
GB2503644A (en) * 2012-05-03 2014-01-08 British American Tobacco Co Filter
US9119419B2 (en) 2012-10-10 2015-09-01 R.J. Reynolds Tobacco Company Filter material for a filter element of a smoking article, and associated system and method
CN111328262B (zh) * 2017-11-28 2022-10-18 菲利普莫里斯生产公司 具有改进的嘴端腔的气溶胶生成制品

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JP2011510614A (ja) 2011-04-07
DE102007061933A1 (de) 2009-07-02
JP5415447B2 (ja) 2014-02-12
CA2710315A1 (fr) 2009-07-09
AR069805A1 (es) 2010-02-17
EP2227103A1 (fr) 2010-09-15
BRPI0819590A2 (pt) 2015-05-05
RU2446725C2 (ru) 2012-04-10
CN101925311A (zh) 2010-12-22
UA100134C2 (ru) 2012-11-26
KR20100101658A (ko) 2010-09-17
TW200927001A (en) 2009-07-01
RU2010130478A (ru) 2012-01-27
US20100300468A1 (en) 2010-12-02

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