WO2009044878A1 - 変性金属酸化物複合ゾル、コーティング組成物及び光学部材 - Google Patents

変性金属酸化物複合ゾル、コーティング組成物及び光学部材 Download PDF

Info

Publication number
WO2009044878A1
WO2009044878A1 PCT/JP2008/068086 JP2008068086W WO2009044878A1 WO 2009044878 A1 WO2009044878 A1 WO 2009044878A1 JP 2008068086 W JP2008068086 W JP 2008068086W WO 2009044878 A1 WO2009044878 A1 WO 2009044878A1
Authority
WO
WIPO (PCT)
Prior art keywords
oxide
modified metal
colloidal particles
oxide composite
composite colloidal
Prior art date
Application number
PCT/JP2008/068086
Other languages
English (en)
French (fr)
Inventor
Yoshinari Koyama
Motoko Asada
Original Assignee
Nissan Chemical Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Industries, Ltd. filed Critical Nissan Chemical Industries, Ltd.
Priority to CN200880110000XA priority Critical patent/CN101815676B/zh
Priority to JP2009536117A priority patent/JP5182532B2/ja
Priority to US12/681,460 priority patent/US20100221556A1/en
Priority to EP08835948.4A priority patent/EP2216297B1/en
Publication of WO2009044878A1 publication Critical patent/WO2009044878A1/ja

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00Compounds of tungsten
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00Compounds of tungsten
    • C01G41/006Compounds containing, besides tungsten, two or more other elements, with the exception of oxygen or hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00Compounds of zirconium
    • C01G25/006Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G30/00Compounds of antimony
    • C01G30/004Oxides; Hydroxides; Oxyacids
    • C01G30/005Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00Compounds of tungsten
    • C01G41/02Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/22Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/60Optical properties, e.g. expressed in CIELAB-values
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • C01P2006/82Compositional purity water content

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Optics & Photonics (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Colloid Chemistry (AREA)

Abstract

【課題】光励起によるコロイド粒子の変色がほぼ完全に抑制され、耐光性、耐候性に優れた酸化チタンを含む高い屈折率の変性金属酸化物複合コロイド粒子のゾルを提供する。 【解決手段】2~50nmの一次粒子径を有し、SnO2/TiO2モル比として0.1~1.0、ZrO2/TiO2モル比として0.1~0.4、及びWO3/TiO2モル比として0.03~0.15である酸化チタン-酸化スズ-酸化ジルコニウム-酸化タングステン複合コロイド粒子(A)を核として、その表面が1~7nmの一次粒子径を有する酸化タングステン-酸化スズ-二酸化珪素複合コロイド粒子(B)により被覆された変性金属酸化物複合コロイド粒子による。
PCT/JP2008/068086 2007-10-03 2008-10-03 変性金属酸化物複合ゾル、コーティング組成物及び光学部材 WO2009044878A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200880110000XA CN101815676B (zh) 2007-10-03 2008-10-03 改性金属氧化物复合溶胶、涂布组合物和光学部件
JP2009536117A JP5182532B2 (ja) 2007-10-03 2008-10-03 変性金属酸化物複合ゾル、コーティング組成物及び光学部材
US12/681,460 US20100221556A1 (en) 2007-10-03 2008-10-03 Modified metal-oxide composite sol, coating composition, and optical member
EP08835948.4A EP2216297B1 (en) 2007-10-03 2008-10-03 Modified metal-oxide composite sol, coating composition, and optical member

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007260150 2007-10-03
JP2007-260150 2007-10-03
JP2007260151 2007-10-03
JP2007-260151 2007-10-03
JP2008213905 2008-08-22
JP2008-213905 2008-08-22

Publications (1)

Publication Number Publication Date
WO2009044878A1 true WO2009044878A1 (ja) 2009-04-09

Family

ID=40526298

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068086 WO2009044878A1 (ja) 2007-10-03 2008-10-03 変性金属酸化物複合ゾル、コーティング組成物及び光学部材

Country Status (7)

Country Link
US (1) US20100221556A1 (ja)
EP (1) EP2216297B1 (ja)
JP (1) JP5182532B2 (ja)
KR (1) KR20100075999A (ja)
CN (1) CN101815676B (ja)
TW (1) TWI433816B (ja)
WO (1) WO2009044878A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011090085A1 (ja) * 2010-01-19 2011-07-28 日産化学工業株式会社 変性酸化第二セリウムコロイド粒子及びその製造方法
WO2011090084A1 (ja) * 2010-01-19 2011-07-28 日産化学工業株式会社 シラン表面処理金属酸化物微粒子およびその製造方法
JP2016074867A (ja) * 2014-10-03 2016-05-12 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
JP2016074797A (ja) * 2014-10-03 2016-05-12 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
WO2016121263A1 (ja) * 2015-01-29 2016-08-04 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2724984B1 (en) * 2011-06-03 2016-08-17 Nissan Chemical Industries, Ltd. Metal oxide particles containing titanium oxide coated with silicon dioxide-tin(iv) oxide complex oxide
DE102011107335A1 (de) * 2011-07-14 2013-01-17 Süd-Chemie AG Oxidationskatalysator mit erhöhter Wasserdampf- und Staubbeständigkeit
JP5889261B2 (ja) * 2013-10-18 2016-03-22 第一稀元素化学工業株式会社 酸化ジルコニウム−酸化チタン複合ゾル及びその製造方法
CN105980500B (zh) * 2014-01-30 2018-09-11 日产化学工业株式会社 涂料组合物和光学构件
CN103969707B (zh) * 2014-05-09 2015-11-18 宁波东旭成新材料科技有限公司 一种具有阻燃效果的反射膜
CN105457572B (zh) * 2014-09-10 2019-01-18 北京化工大学 一种二氧化硅包覆金属掺杂氧化锡材料及其制备方法、分散体及其制备方法
GB201523156D0 (en) * 2015-12-31 2016-02-17 Pilkington Group Ltd High strength glass containers
JP6236643B1 (ja) * 2016-03-11 2017-11-29 パナソニックIpマネジメント株式会社 帯電防止材料、その製造方法および帯電防止膜
KR101941573B1 (ko) * 2016-11-28 2019-01-23 동우 화인켐 주식회사 자발광 감광성 수지 조성물, 이를 이용하여 제조된 컬러필터 및 화상 표시 장치
US11679990B2 (en) 2017-03-31 2023-06-20 Jgc Catalysts And Chemicals Ltd. Method for producing dispersion of iron-containing rutile titanium oxide fine particles, iron-containing rutile titanium oxide fine particles, and use thereof
CN111273513B (zh) * 2020-03-27 2021-09-24 宁波华显智能科技有限公司 一种直流电解法制得的透明显示膜及其制备方法和应用
CN111994957A (zh) * 2020-08-20 2020-11-27 临沂大学 一种wo3气敏材料及其制备方法和应用

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53111336A (en) * 1977-03-11 1978-09-28 Toray Ind Inc Coating composition
JPH10310429A (ja) * 1997-03-04 1998-11-24 Nissan Chem Ind Ltd 酸化チタン−酸化ジルコニウム−酸化スズ複合ゾルの製造方法
JP2000063119A (ja) * 1998-08-10 2000-02-29 Nissan Chem Ind Ltd 変性された酸化チタン−酸化ジルコニウム−酸化第二スズ複合ゾル及びその製造方法
JP2001123115A (ja) * 1999-08-16 2001-05-08 Nissan Chem Ind Ltd コーティング組成物及び光学部材
JP2001122621A (ja) * 1999-08-16 2001-05-08 Nissan Chem Ind Ltd 変性金属酸化物ゾル及びその製造方法
JP2002363442A (ja) * 2001-06-08 2002-12-18 Catalysts & Chem Ind Co Ltd アンチモン酸化物被覆酸化チタン含有複合酸化物粒子および該粒子分散ゾル、該微粒子含有透明被膜形成用塗布液、透明被膜付基材。
JP2005231935A (ja) * 2004-02-18 2005-09-02 Taki Chem Co Ltd 酸化タングステン含有酸化チタンゾル及びその製造方法並びにコーティング剤及び光機能体
JP2005263854A (ja) * 2004-03-16 2005-09-29 Hoya Corp コーティング組成物の製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US64665A (en) * 1867-05-14 Freeman hanson
EP0992456B1 (en) * 1997-03-03 2010-09-08 Nissan Chemical Industries, Ltd. Process for producing composite sols, coating composition, and optical member
EP1077236B1 (en) * 1999-08-16 2004-05-26 Nissan Chemical Industries Ltd. Modified metal oxide sol, coating composition and optical element
JP3526439B2 (ja) * 2000-09-29 2004-05-17 Hoya株式会社 眼鏡レンズ用コーティング組成物の製造方法
EP1253444B1 (en) * 2001-04-24 2005-01-26 Hoya Corporation Coating composition, process for producing optical element using the same, and optical element
US7593346B2 (en) * 2003-07-31 2009-09-22 Cisco Technology, Inc. Distributing and balancing traffic flow in a virtual gateway
US7476695B2 (en) * 2004-03-16 2009-01-13 Nissan Chemical Industries, Ltd. Modified stannic oxide-zirconium oxide complex sol and method for preparing same
CN100489041C (zh) * 2005-05-26 2009-05-20 财团法人工业技术研究院 抗反射涂布组合物、其所形成的膜层及其制造方法
EP1930298B1 (en) * 2005-08-09 2017-10-04 Nissan Chemical Industries, Ltd. Zirconium oxide-tin oxide composite sol, coating composition and optical member

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53111336A (en) * 1977-03-11 1978-09-28 Toray Ind Inc Coating composition
JPH10310429A (ja) * 1997-03-04 1998-11-24 Nissan Chem Ind Ltd 酸化チタン−酸化ジルコニウム−酸化スズ複合ゾルの製造方法
JP2000063119A (ja) * 1998-08-10 2000-02-29 Nissan Chem Ind Ltd 変性された酸化チタン−酸化ジルコニウム−酸化第二スズ複合ゾル及びその製造方法
JP2001123115A (ja) * 1999-08-16 2001-05-08 Nissan Chem Ind Ltd コーティング組成物及び光学部材
JP2001122621A (ja) * 1999-08-16 2001-05-08 Nissan Chem Ind Ltd 変性金属酸化物ゾル及びその製造方法
JP2002363442A (ja) * 2001-06-08 2002-12-18 Catalysts & Chem Ind Co Ltd アンチモン酸化物被覆酸化チタン含有複合酸化物粒子および該粒子分散ゾル、該微粒子含有透明被膜形成用塗布液、透明被膜付基材。
JP2005231935A (ja) * 2004-02-18 2005-09-02 Taki Chem Co Ltd 酸化タングステン含有酸化チタンゾル及びその製造方法並びにコーティング剤及び光機能体
JP2005263854A (ja) * 2004-03-16 2005-09-29 Hoya Corp コーティング組成物の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2216297A4 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011090085A1 (ja) * 2010-01-19 2011-07-28 日産化学工業株式会社 変性酸化第二セリウムコロイド粒子及びその製造方法
WO2011090084A1 (ja) * 2010-01-19 2011-07-28 日産化学工業株式会社 シラン表面処理金属酸化物微粒子およびその製造方法
JPWO2011090084A1 (ja) * 2010-01-19 2013-05-23 日産化学工業株式会社 シラン表面処理金属酸化物微粒子およびその製造方法
JP5704345B2 (ja) * 2010-01-19 2015-04-22 日産化学工業株式会社 シラン表面処理金属酸化物微粒子およびその製造方法
US9150421B2 (en) 2010-01-19 2015-10-06 Nissan Chemical Industries, Ltd. Silane surface-treated metal oxide fine particles and production method for same
JP2016074867A (ja) * 2014-10-03 2016-05-12 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
JP2016074797A (ja) * 2014-10-03 2016-05-12 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
WO2016121263A1 (ja) * 2015-01-29 2016-08-04 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
JPWO2016121263A1 (ja) * 2015-01-29 2017-08-03 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子
JP2019173016A (ja) * 2015-01-29 2019-10-10 富士フイルム株式会社 シロキサン樹脂組成物、これを用いた透明硬化物、透明画素、マイクロレンズ、固体撮像素子

Also Published As

Publication number Publication date
EP2216297B1 (en) 2013-12-04
EP2216297A4 (en) 2012-12-05
TW200934732A (en) 2009-08-16
JPWO2009044878A1 (ja) 2011-02-10
CN101815676A (zh) 2010-08-25
CN101815676B (zh) 2013-12-18
EP2216297A1 (en) 2010-08-11
KR20100075999A (ko) 2010-07-05
JP5182532B2 (ja) 2013-04-17
TWI433816B (zh) 2014-04-11
US20100221556A1 (en) 2010-09-02

Similar Documents

Publication Publication Date Title
WO2009044878A1 (ja) 変性金属酸化物複合ゾル、コーティング組成物及び光学部材
WO2009044879A1 (ja) 金属酸化物複合ゾル、コーティング組成物及び光学部材
WO2007098897A3 (de) Wetterstabile perlglanzpigmente auf basis dünner glasplättchen und verfahren zu deren herstellung
DE602007001237D1 (de) Effektpigmente mit einem Substrat aus Glasplättchen
TW200604298A (en) Weather resistant titanium dioxide pigment and a process for its production
CN102985499B (zh) 防反射膜及其制备方法
ATE399820T1 (de) Effektpigmente mit titanoxyd enthaltenden glasschuppen
US8324129B2 (en) Photocatalytically active coating
WO2006093748A3 (en) Inorganic-organic hybrid nanocomposite antiglare and antireflection coatings
ES2682042T3 (es) Partículas de óxido de cinc de tipo placa hexagonal, y cosmético, carga, composición de resina, material reflectante de infrarrojos, y composición de recubrimiento que contiene las mismas
EP2431423A3 (en) Anti-reflective coatings
EP2347896A4 (en) LOW BREAKING INDEX FILM AND METHOD FOR THE PRODUCTION, ANTI-REFLECTIONS AND PRODUCTION METHOD THEREFOR, COATING LIQUID FOR LOW BREAKING INDEX, SUBSTRATE WITH MICROPARTICELLAMINATED THIN LAYER AND METHOD FOR THE PRODUCTION THEREOF, AND OPTICAL ELEMENT
WO2013066545A3 (en) Infrared-reflective coatings
WO2010005642A3 (en) Coatings
WO2010079923A3 (ko) 나노 크기로 분산된 안료를 포함하는 유색 투명 코팅 도료 조성물, 코팅된 기재 및 그 제조방법
MX351849B (es) Composicion para recubrimiento que comprende submicroparticulas que comprenden carbonato de calcio, proceso para prepararlas, y uso de submicroparticulas que comprenden carbonato de calcio en composiciones para revestimiento.
WO2006072849A3 (en) Wavelength conversion layers with embedded crystallites
WO2009044066A3 (fr) Materiau a proprietes photocatalytiques
JP2010510671A5 (ja)
WO2009127406A8 (de) Perlglanzpigmente auf basis von feinen und dünnen substraten
EP1273639A4 (en) OPTICAL ELEMENT
MX351708B (es) Articulo revestido de color bronce con recubrimiento de baja-e.
WO2010013452A1 (ja) 赤外線反射性黒色系顔料、該赤外線反射性黒色系顔料を用いた塗料及び樹脂組成物
WO2009117029A3 (en) Bilayer anti-reflective films containing nanoparticles in both layers
JP2015049319A (ja) 透明基材と防汚性反射防止膜とを備える物品およびその製造方法

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880110000.X

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08835948

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2009536117

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 12681460

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008835948

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 20107009829

Country of ref document: KR

Kind code of ref document: A