WO2009016989A1 - 水中油型乳化組成物及びその製造方法 - Google Patents

水中油型乳化組成物及びその製造方法 Download PDF

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Publication number
WO2009016989A1
WO2009016989A1 PCT/JP2008/063106 JP2008063106W WO2009016989A1 WO 2009016989 A1 WO2009016989 A1 WO 2009016989A1 JP 2008063106 W JP2008063106 W JP 2008063106W WO 2009016989 A1 WO2009016989 A1 WO 2009016989A1
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Prior art keywords
oil
emulsion composition
water emulsion
producing
disclosed
Prior art date
Application number
PCT/JP2008/063106
Other languages
English (en)
French (fr)
Inventor
Takashi Oka
Reiji Miyahara
Takashi Teshigawara
Original Assignee
Shiseido Company Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Company Ltd. filed Critical Shiseido Company Ltd.
Priority to ES08791387.7T priority Critical patent/ES2574983T3/es
Priority to CN2008801007867A priority patent/CN101772339B/zh
Priority to BRPI0813092A priority patent/BRPI0813092B1/pt
Priority to AU2008283520A priority patent/AU2008283520B2/en
Priority to EP08791387.7A priority patent/EP2177201B1/en
Priority to US12/670,895 priority patent/US8216597B2/en
Publication of WO2009016989A1 publication Critical patent/WO2009016989A1/ja
Priority to HK10109852.6A priority patent/HK1143319A1/xx

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0295—Liquid crystals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/10—Alcohols; Phenols; Salts thereof, e.g. glycerol; Polyethylene glycols [PEG]; Poloxamers; PEG/POE alkyl ethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/12—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/14—Esters of carboxylic acids, e.g. fatty acid monoglycerides, medium-chain triglycerides, parabens or PEG fatty acid esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0254—Platelets; Flakes
    • A61K8/0258—Layered structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/553—Phospholipids, e.g. lecithin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63—Steroids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/107—Emulsions ; Emulsion preconcentrates; Micelles
    • A61K9/1075—Microemulsions or submicron emulsions; Preconcentrates or solids thereof; Micelles, e.g. made of phospholipids or block copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P29/00—Non-central analgesic, antipyretic or antiinflammatory agents, e.g. antirheumatic agents; Non-steroidal antiinflammatory drugs [NSAID]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00—Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
    • B01J13/046—Making microcapsules or microballoons by physical processes, e.g. drying, spraying combined with gelification or coagulation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/21—Emulsions characterized by droplet sizes below 1 micron

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
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  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Biophysics (AREA)
  • Molecular Biology (AREA)
  • Dermatology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Rheumatology (AREA)
  • Pain & Pain Management (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Colloid Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

　油溶性薬剤を安定に配合し、且つ使用感触に優れた水中油型乳化組成物、及び煩雑な操作を必要としない同組成物の製造方法を提供する。 　（Ａ）ポリオキシエチレンフィトステロールと、（Ｂ）グリセリン脂肪酸ジエステルと、（Ｃ）ポリオキシエチレン・ポリオキシプロピレンランダム共重合体ジアルキルエーテルと、（Ｄ）油溶性薬剤と、（Ｅ）油分と、（Ｆ）水とを含有し、乳化粒子内部に該（Ａ）及び（Ｂ）成分から構成される層状のゲル構造体が存在することを特徴とする水中油型乳化組成物。
PCT/JP2008/063106 2007-07-27 2008-07-22 水中油型乳化組成物及びその製造方法 WO2009016989A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES08791387.7T ES2574983T3 (es) 2007-07-27 2008-07-22 Composición de emulsión de aceite en agua y un procedimiento para producir la misma
CN2008801007867A CN101772339B (zh) 2007-07-27 2008-07-22 水包油型乳化组合物及其制造方法
BRPI0813092A BRPI0813092B1 (pt) 2007-07-27 2008-07-22 composição de emulsão óleo em água e método para produzir a mesma.
AU2008283520A AU2008283520B2 (en) 2007-07-27 2008-07-22 Oil-in-water emulsion composition and method for producing the same
EP08791387.7A EP2177201B1 (en) 2007-07-27 2008-07-22 Oil-in-water emulsion composition and method for producing the same
US12/670,895 US8216597B2 (en) 2007-07-27 2008-07-22 Oil-in-water emulsion composition and method for producing the same
HK10109852.6A HK1143319A1 (en) 2007-07-27 2010-10-18 Oil-in-water emulsion composition and method for producing the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-195719 2007-07-27
JP2007195719 2007-07-27
JP2008049393A JP5508682B2 (ja) 2007-07-27 2008-02-29 水中油型乳化組成物及びその製造方法
JP2008-049393 2008-02-29

Publications (1)

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WO2009016989A1 true WO2009016989A1 (ja) 2009-02-05

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PCT/JP2008/063106 WO2009016989A1 (ja) 2007-07-27 2008-07-22 水中油型乳化組成物及びその製造方法

Country Status (10)

Country Link
US (1) US8216597B2 (ja)
EP (1) EP2177201B1 (ja)
JP (1) JP5508682B2 (ja)
KR (1) KR101576692B1 (ja)
CN (1) CN101772339B (ja)
AU (1) AU2008283520B2 (ja)
BR (1) BRPI0813092B1 (ja)
HK (1) HK1143319A1 (ja)
RU (1) RU2459613C2 (ja)
WO (1) WO2009016989A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009084588A1 (ja) * 2007-12-27 2009-07-09 Shiseido Company, Ltd. 外用組成物として用いることのできる含水組成物
JP2013513550A (ja) * 2009-12-15 2013-04-22 ロレアル 水和能力が強化された組成物
WO2013108513A1 (ja) * 2012-01-17 2013-07-25 株式会社 資生堂 液状化粧料
JP2016000745A (ja) * 2015-08-06 2016-01-07 ロレアル 水和能力が強化された組成物
JP2016013507A (ja) * 2014-07-01 2016-01-28 株式会社タイホーコーザイ 水中油型エマルション消泡剤組成物
WO2016210226A1 (en) * 2015-06-26 2016-12-29 Stc.Unm Coenzyme q10 aerosol
WO2021106657A1 (ja) 2019-11-29 2021-06-03 株式会社タイキ ルテインのブルーライトカット能増強剤および、化粧品組成物

Families Citing this family (16)

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Publication number Priority date Publication date Assignee Title
JP2010280632A (ja) * 2009-06-05 2010-12-16 Shiseido Co Ltd 水中油型乳化毛髪化粧料
JP5074637B2 (ja) * 2010-10-29 2012-11-14 株式会社コーセー ベシクル組成物、それを含有する皮膚外用剤及び化粧料
FR2969924B1 (fr) * 2010-12-30 2013-11-15 Lvmh Rech Composition comprenant un phosphate de tocopherol
JP5753466B2 (ja) * 2011-09-14 2015-07-22 株式会社 資生堂 液状化粧料
US9549891B2 (en) 2012-03-19 2017-01-24 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
CN103445975B (zh) 2012-05-30 2017-08-22 花王株式会社 乳化化妆品组合物
JP6260538B2 (ja) * 2012-09-27 2018-01-17 大正製薬株式会社 内服液体組成物
JP2016079513A (ja) * 2014-10-10 2016-05-16 株式会社 資生堂 繊維およびそれを用いた繊維構造物
CA2988808C (en) 2015-06-29 2021-05-25 The Procter & Gamble Company Superabsorbent polymers, waxes, oils, and starch powders for use in skincare compositions
EP3165216A1 (de) * 2015-11-05 2017-05-10 Basf Se Texturierte zusammensetzung
CN105664786B (zh) * 2016-01-04 2018-12-21 陕西科技大学 阴离子型妥尔油双子表面活性剂及其制备方法
US10898426B2 (en) 2016-01-27 2021-01-26 Shiseido Company, Ltd. Alpha-gel formation composition, external skin care composition using alpha-gel formation composition, and alpha-gel composition using alpha-gel formation composition
US20190029932A1 (en) * 2016-01-27 2019-01-31 Shiseido Company, Ltd. Ripple-phase containing composition, alpha-gel formation composition, external skin care composition using alpha-gel formation composition, and alpha-gel composition using alpha-gel formation composition
JP6426635B2 (ja) * 2016-01-27 2018-11-21 株式会社 資生堂 αゲル形成用組成物及びαゲル組成物
JP6801980B2 (ja) * 2016-04-28 2020-12-16 株式会社 資生堂 水中油型乳化化粧料
KR20240009111A (ko) 2022-07-13 2024-01-22 (주)아모레퍼시픽 베타 아미노산 유도체를 포함하는 유중수 유화 조성물

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JPH01199462A (ja) 1988-02-04 1989-08-10 Seiko Epson Corp 半導体装置
JPH04193814A (ja) 1990-11-26 1992-07-13 Kao Corp 透明ないし半透明の化粧料
JPH04243806A (ja) * 1991-01-28 1992-08-31 Mikimoto Pharmaceut Co Ltd 液晶を含む２層型化粧水
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JP2007254405A (ja) * 2006-03-24 2007-10-04 Shiseido Co Ltd 白濁状水中油型乳化化粧料の製造方法
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JP2008137966A (ja) * 2006-12-04 2008-06-19 Shiseido Co Ltd 水中油型微細乳化組成物及びその製造方法

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JPS60166604A (ja) * 1984-02-09 1985-08-29 Kobayashi Kooc:Kk 弱酸性ｗ／ｏ／ｗ型乳化化粧料の製造方法
DE4206732A1 (de) * 1992-03-04 1993-09-09 Goldschmidt Ag Th Fluessige, lagerstabile, multiple emulsion des typs o/w/o
EP0988854B1 (en) * 1998-09-21 2004-07-14 Shiseido Company Limited Composition for external use containing succinoglucan, clay mineral and an alkyl acrylate/methacrylate copolymer
JP2007014866A (ja) * 2005-07-06 2007-01-25 Shiseido Co Ltd 水中油型微細乳化組成物の製造方法
US7790701B2 (en) * 2006-04-19 2010-09-07 Gelest Technologies, Inc. Silicon-based tocopherol derivatives

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JPH01199462A (ja) 1988-02-04 1989-08-10 Seiko Epson Corp 半導体装置
JPH04193814A (ja) 1990-11-26 1992-07-13 Kao Corp 透明ないし半透明の化粧料
JPH04243806A (ja) * 1991-01-28 1992-08-31 Mikimoto Pharmaceut Co Ltd 液晶を含む２層型化粧水
JPH06345633A (ja) 1993-06-08 1994-12-20 Kao Corp 皮膚外用剤
JP2002029915A (ja) * 2000-07-10 2002-01-29 Lion Corp 皮膚化粧料
JP2006111620A (ja) * 2004-09-16 2006-04-27 Kose Corp 水中油型液状組成物
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CN101772339B (zh) 2013-11-06
CN101772339A (zh) 2010-07-07
BRPI0813092A2 (pt) 2014-12-23
EP2177201A1 (en) 2010-04-21
RU2459613C2 (ru) 2012-08-27
AU2008283520A1 (en) 2009-02-05
KR101576692B1 (ko) 2015-12-10
JP2009051810A (ja) 2009-03-12
EP2177201A4 (en) 2013-01-23
BRPI0813092A8 (pt) 2016-05-03
RU2010104979A (ru) 2011-09-10
AU2008283520B2 (en) 2013-01-31
US20100196429A1 (en) 2010-08-05
BRPI0813092B1 (pt) 2016-09-20
HK1143319A1 (en) 2010-12-31
EP2177201B1 (en) 2016-03-09
KR20100052479A (ko) 2010-05-19
US8216597B2 (en) 2012-07-10

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