WO2009008287A1 - ４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４－（トリフルオロメチルチオ）アニリン類の製造方法 - Google Patents

４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４－（トリフルオロメチルチオ）アニリン類の製造方法 Download PDF

Info

Publication number
WO2009008287A1
WO2009008287A1 PCT/JP2008/061901 JP2008061901W WO2009008287A1 WO 2009008287 A1 WO2009008287 A1 WO 2009008287A1 JP 2008061901 W JP2008061901 W JP 2008061901W WO 2009008287 A1 WO2009008287 A1 WO 2009008287A1
Authority
WO
WIPO (PCT)
Prior art keywords
aniline
producing
trichloromethylthio
trifluoromethylthio
group
Prior art date
Application number
PCT/JP2008/061901
Other languages
English (en)
French (fr)
Inventor
Yoshitomo Tohyama
Kengo Kanematsu
Original Assignee
Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Priority to KR1020107002387A priority Critical patent/KR101435703B1/ko
Priority to US12/667,543 priority patent/US8399707B2/en
Priority to CN2008800236267A priority patent/CN101687783B/zh
Priority to BRPI0813581-9A2A priority patent/BRPI0813581A2/pt
Priority to EP08790764A priority patent/EP2174929B1/en
Publication of WO2009008287A1 publication Critical patent/WO2009008287A1/ja
Priority to IL203023A priority patent/IL203023A/en
Priority to US13/492,307 priority patent/US8466321B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
    • C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
    • C07C323/36—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/39—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
    • C07C323/40—Y being a hydrogen or a carbon atom
    • C07C323/41—Y being a hydrogen or an acyclic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

　一般式（ＩＩ）： 　　【化１】 （式中、Ｒ1は、水素原子または炭素数１～３のアルキル基を表わす。Ｒ2は、各々独立して、ハロゲン原子、炭素数１～３のアルキル基または炭素数１～３のパーフルオロアルキル基を表わす。Ｒ3は、ホルミル基、アセチル基またはトリフルオロアセチル基を表わす。ｍは、０～４の整数を表わす。）で示される４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに該化合物を用いた４－（トリフルオロメチルチオ）アニリン類の製造方法が提供される。工業的に入手が容易な原料を用い、汎用的な製造設備を用いて、４－（トリフルオロメチルチオ）アニリン類を高収率で製造することが可能となる。
PCT/JP2008/061901 2007-07-06 2008-07-01 ４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４－（トリフルオロメチルチオ）アニリン類の製造方法 WO2009008287A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1020107002387A KR101435703B1 (ko) 2007-07-06 2008-07-01 4-(트리클로로메틸티오)아닐린류 및 그 제조 방법, 그리고 4-(트리플루오로메틸티오)아닐린류의 제조 방법
US12/667,543 US8399707B2 (en) 2007-07-06 2008-07-01 4-(trichloromethylthio) anilines, method for production thereof, and method for producing 4-(trifluoromethylthio) anilines
CN2008800236267A CN101687783B (zh) 2007-07-06 2008-07-01 4-(三氯甲硫基)苯胺类及其制造方法、以及4-(三氟甲硫基)苯胺类的制造方法
BRPI0813581-9A2A BRPI0813581A2 (pt) 2007-07-06 2008-07-01 Métodos para produzir uma 4-(triclorometiltio)anilina e o referido composto
EP08790764A EP2174929B1 (en) 2007-07-06 2008-07-01 4-(trichloromethylthio)aniline, method for producing the same, and method for producing 4-(trifluoromethylthio)aniline
IL203023A IL203023A (en) 2007-07-06 2009-12-29 4- (Trichloromethylthio) -anilines, a method of making them, and a method of producing 4- (Trifluoromethylthio) anilines
US13/492,307 US8466321B2 (en) 2007-07-06 2012-06-08 4-(trichloromethylthio) anilines, method for production thereof, and method for producing 4-(trifluoromethylthio) anilines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007178577A JP5158327B2 (ja) 2007-07-06 2007-07-06 ４−（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４−（トリフルオロメチルチオ）アニリン類の製造方法
JP2007-178577 2007-07-06

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/667,543 A-371-Of-International US8399707B2 (en) 2007-07-06 2008-07-01 4-(trichloromethylthio) anilines, method for production thereof, and method for producing 4-(trifluoromethylthio) anilines
US13/492,307 Division US8466321B2 (en) 2007-07-06 2012-06-08 4-(trichloromethylthio) anilines, method for production thereof, and method for producing 4-(trifluoromethylthio) anilines

Publications (1)

Publication Number Publication Date
WO2009008287A1 true WO2009008287A1 (ja) 2009-01-15

Family

ID=40228465

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/061901 WO2009008287A1 (ja) 2007-07-06 2008-07-01 ４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４－（トリフルオロメチルチオ）アニリン類の製造方法

Country Status (8)

Country Link
US (2) US8399707B2 (ja)
EP (1) EP2174929B1 (ja)
JP (1) JP5158327B2 (ja)
KR (1) KR101435703B1 (ja)
CN (1) CN101687783B (ja)
BR (1) BRPI0813581A2 (ja)
IL (1) IL203023A (ja)
WO (1) WO2009008287A1 (ja)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102459403B (zh) * 2009-06-26 2014-07-16 出光兴产株式会社 聚碳酸酯共聚物、使用其的涂布液以及电子照相感光体
JP5642394B2 (ja) * 2010-01-07 2014-12-17 日本曹達株式会社 フッ化ジスルフィド化合物の製造方法
CN112300441B (zh) * 2020-10-27 2022-07-12 江苏金发科技新材料有限公司 一种高表面极性聚丙烯复合物及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63192772A (ja) * 1987-01-30 1988-08-10 シエーリング・アクチエンゲゼルシヤフト ２−イミノ−１，３−ジチエタン、その製法及びこれを含有する害虫駆除剤
JPH06316518A (ja) * 1992-12-30 1994-11-15 Eli Lilly & Co 寄生生物の抑制のためのジスルホニルメタンの使用
WO2007046513A2 (en) * 2005-10-20 2007-04-26 Sumitomo Chemical Company, Limited Benzoylurea compounds and use thereof
WO2007066496A1 (en) * 2005-12-07 2007-06-14 Sumitomo Chemical Company, Limited Benzoylurea compound and use thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2042526B (en) 1979-01-29 1983-06-15 Minnesota Mining & Mfg N-alkylsulphonyl- and n-alkoxy-carbonyl-substituted alkanesulphonanilides and derivatives thereof useful as plant growth modifiers
IL85066A0 (en) 1987-01-30 1988-06-30 Schering Ag 2-imino-1,3-dithietane derivatives and pesticidal compositions containing them
US5449681A (en) 1992-12-30 1995-09-12 Eli Lilly And Company Use of disulfonyl methanes for the control of parasites
JPH1149742A (ja) 1997-08-01 1999-02-23 Daikin Ind Ltd ２−（トリフルオロメチルチオ）ビフェニルの製造方法、及びその合成中間体とその製造方法
BR0307740A (pt) 2002-03-05 2005-01-25 Sumitomo Chem Takeda Agro Co Composto, processo para a produção do mesmo, e, controlador de peste
JP2006265209A (ja) 2005-03-25 2006-10-05 Bayer Cropscience Ag 殺虫性アニリノトリアゾール類

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63192772A (ja) * 1987-01-30 1988-08-10 シエーリング・アクチエンゲゼルシヤフト ２−イミノ−１，３−ジチエタン、その製法及びこれを含有する害虫駆除剤
JPH06316518A (ja) * 1992-12-30 1994-11-15 Eli Lilly & Co 寄生生物の抑制のためのジスルホニルメタンの使用
WO2007046513A2 (en) * 2005-10-20 2007-04-26 Sumitomo Chemical Company, Limited Benzoylurea compounds and use thereof
WO2007066496A1 (en) * 2005-12-07 2007-06-14 Sumitomo Chemical Company, Limited Benzoylurea compound and use thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BARUFFINI A. ET AL.: "4-Aminothiophenol derivatives of antifungal activity", FARMACO EDIZIONE SCIENTIFICIA, vol. 13, 1958, pages 911 - 921, XP008129146 *
LAURENT S.J. ET AL.: "Selective aliphatic fluorination by halogen exchange in mild conditions", JOURNAL OF FLUORINE CHEMISTRY, vol. 127, no. 1, 2006, pages 85 - 90, XP025184737 *
See also references of EP2174929A4 *

Also Published As

Publication number Publication date
EP2174929A1 (en) 2010-04-14
JP2009013130A (ja) 2009-01-22
KR20100044808A (ko) 2010-04-30
IL203023A (en) 2014-02-27
CN101687783B (zh) 2013-05-08
US8399707B2 (en) 2013-03-19
KR101435703B1 (ko) 2014-09-01
US20100331578A1 (en) 2010-12-30
CN101687783A (zh) 2010-03-31
EP2174929A4 (en) 2011-11-23
JP5158327B2 (ja) 2013-03-06
EP2174929B1 (en) 2013-03-27
US20120245388A1 (en) 2012-09-27
BRPI0813581A2 (pt) 2014-12-30
US8466321B2 (en) 2013-06-18

Similar Documents

Publication Publication Date Title
MX2009008858A (es) Derivado de pirazolcarbonitrilo que contiene fluor y el metodo para producirlo y derivado del acido pirazolcarboxilico que contiene fluor obtenido utilizando el derivado de pirazolcarbonitrilo que contiene fluor y el método para producirlo.
TW200745076A (en) Process for production of methylene disulfonate compound
EP1935893A4 (en) TOTAL SYNTHESIS OF PLADIENOLIDE B AND PLADIENOLIDE D
MY147440A (en) Process for making 3-substituted 2-amino-5-halobenzamides
MX2009003257A (es) Procedimiento para la sintesis de derivados de fenoxi diaminopirimidina.
EP0846693A4 (en) N-BENZYLDIOXOTHIAZOLIDYLBENZAMIDE DERIVATIVES AND THEIR PRODUCTION METHOD
TW200640949A (en) Hyper-branched polymer and process for producing the same
IN2012DN01815A (ja)
TW200635939A (en) Tantalum compound, method for producing the same, tantalum-containing thin film and method for forming the same
UA101712C2 (ru) Способ производства производных замещенной метоксиметилпиридин-2,3-дикарбоновой кислоты
WO2009154754A3 (en) Synthesis of deuterated morpholine derivatives
WO2008105138A1 (ja) ポリチオウレタン系光学材料用重合触媒、それを含む重合性組成物、それより得られる光学材料、およびその製造方法
WO2009008287A1 (ja) ４－（トリクロロメチルチオ）アニリン類およびその製造方法、ならびに４－（トリフルオロメチルチオ）アニリン類の製造方法
TWI371449B (en) Conversion of 2-pyrazolines to ryrazoles using bromine
TW200738650A (en) Process for synthesis of aryloxy diaminopyrimidines
MX2010001961A (es) Procedimiento para la preparacion de derivados de 2,2-difluoroetilamina mediante hidrogenacion de amida.
WO2008093702A1 (ja) アゾジカルボン酸ビス（２－アルコキシエチル）エステル化合物、その製造中間体
TW200740763A (en) A method for preparing 5-hydroxy-1-alkyl pyrazole derivatives
MX2009004928A (es) Metodo para la produccion del derivado de 2-alquilo-3-aminotiofeno .
MX2009007029A (es) Derivado de acil-3-aminoacrilonitrilo 2-fluorado y metodo para producir el mismo.
WO2008120800A1 (ja) ２－ハロイミダゾール化合物の製造方法
MX2009013336A (es) Sintesis de 3-aminopirazoles sustituidos.
TW200700370A (en) Producing method of haloalkylether compounds
NZ589496A (en) Processes and compounds for the preparation of normorphinans
TW200833653A (en) Novel chlorofluorosulfonimide and method for producing the same

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880023626.7

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08790764

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 12667543

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 395/KOLNP/2010

Country of ref document: IN

ENP Entry into the national phase

Ref document number: 20107002387

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2008790764

Country of ref document: EP

ENP Entry into the national phase

Ref document number: PI0813581

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20100106