WO2008140118A1 - アクロレインの製造方法 - Google Patents

アクロレインの製造方法 Download PDF

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Publication number
WO2008140118A1
WO2008140118A1 PCT/JP2008/058948 JP2008058948W WO2008140118A1 WO 2008140118 A1 WO2008140118 A1 WO 2008140118A1 JP 2008058948 W JP2008058948 W JP 2008058948W WO 2008140118 A1 WO2008140118 A1 WO 2008140118A1
Authority
WO
WIPO (PCT)
Prior art keywords
glycerin
acrolein
dehydration
hydroxide
rare earth
Prior art date
Application number
PCT/JP2008/058948
Other languages
English (en)
French (fr)
Inventor
Yoshitaka Arita
Tsukasa Takahashi
Masaki Okada
Toshimitsu Moriguchi
Original Assignee
Nippon Shokubai Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co., Ltd. filed Critical Nippon Shokubai Co., Ltd.
Priority to US12/451,498 priority Critical patent/US7847131B2/en
Priority to CN2008800144814A priority patent/CN101679174B/zh
Priority to EP08752806A priority patent/EP2157074A4/en
Publication of WO2008140118A1 publication Critical patent/WO2008140118A1/ja

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1804—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/285—Regeneration or reactivation of catalysts comprising compounds of phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　グリセリンの脱水によってアクロレインを高収率で得ることができるアクロレインの製造方法の提供。水と希土類金属の水酸化物および／または当該水酸化物の脱水縮合物とを含有する液にリン酸イオンを含ませることで生じた固形分を焼成して得られるリン酸の希土類金属塩結晶を有する触媒と、グリセリンとを共存させて、このグリセリンを脱水させる。
PCT/JP2008/058948 2007-05-16 2008-05-15 アクロレインの製造方法 WO2008140118A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/451,498 US7847131B2 (en) 2007-05-16 2008-05-15 Process for producing acrolein
CN2008800144814A CN101679174B (zh) 2007-05-16 2008-05-15 丙烯醛的制备方法
EP08752806A EP2157074A4 (en) 2007-05-16 2008-05-15 PROCESS FOR THE PRODUCTION OF ACROLEINE

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-130938 2007-05-16
JP2007130938 2007-05-16
JP2007-255727 2007-09-28
JP2007255727A JP4991471B2 (ja) 2007-05-16 2007-09-28 グリセリン脱水用触媒、およびアクロレインの製造方法

Publications (1)

Publication Number Publication Date
WO2008140118A1 true WO2008140118A1 (ja) 2008-11-20

Family

ID=40002305

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/058948 WO2008140118A1 (ja) 2007-05-16 2008-05-15 アクロレインの製造方法

Country Status (5)

Country Link
US (1) US7847131B2 (ja)
EP (1) EP2157074A4 (ja)
JP (1) JP4991471B2 (ja)
CN (1) CN101679174B (ja)
WO (1) WO2008140118A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009027420A1 (de) 2009-07-02 2011-01-05 Evonik Degussa Gmbh Verfahren zur Herstellung von Acrolein
WO2011125623A1 (ja) * 2010-03-31 2011-10-13 株式会社日本触媒 グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
JP2012091158A (ja) * 2010-09-30 2012-05-17 Nippon Shokubai Co Ltd グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
JP2012091157A (ja) * 2010-09-30 2012-05-17 Nippon Shokubai Co Ltd グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
CN102482187A (zh) * 2009-07-22 2012-05-30 阿肯马法国公司 从丙三醇制备生物来源化的丙烯酸的方法
CN102482189A (zh) * 2009-07-22 2012-05-30 阿肯马法国公司 从丙三醇制备生物来源化的丙烯酸的方法
CN105566083A (zh) * 2009-12-18 2016-05-11 巴特勒纪念研究院 多羟基化合物脱水系统、催化剂组合物、和方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5130107B2 (ja) * 2008-04-25 2013-01-30 株式会社日本触媒 アクリル酸の製造方法
JP5130113B2 (ja) * 2008-05-14 2013-01-30 株式会社日本触媒 アクロレインの製造方法
JP4505046B2 (ja) * 2008-05-22 2010-07-14 三井金属鉱業株式会社 排気ガス浄化用触媒及びその製造方法
EP2179981A1 (en) * 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
WO2012035540A1 (en) 2010-09-16 2012-03-22 Ganapati Dadasaheb Yadav Process for the production of acrolein and reusable catalyst thereof
MY161241A (en) * 2011-05-11 2017-04-14 Archer Daniels Midland Co Processes for making acrylic-type monomers and products made therefrom
KR102132676B1 (ko) * 2012-08-08 2020-07-14 로께뜨프레르 수소화 당의 내부 탈수 생성물 1종 이상을 함유하는 조성물의 불균일 촉매 작용에 의한 합성 방법
FR3001728B1 (fr) * 2013-02-04 2015-11-13 Adisseo France Sas Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool
KR20150055402A (ko) 2013-11-13 2015-05-21 주식회사 엘지화학 글리세린 탈수반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법
KR101774543B1 (ko) 2014-12-19 2017-09-04 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102055927B1 (ko) * 2015-11-17 2019-12-13 주식회사 엘지화학 아크롤레인의 제조 방법
KR102146094B1 (ko) 2016-08-24 2020-08-19 주식회사 엘지화학 N-치환 말레이미드 제조용 탈수 반응 촉매, 이의 제조 방법, 및 n-치환 말레이미드의 제조 방법

Citations (3)

* Cited by examiner, † Cited by third party
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JPH06211724A (ja) * 1992-11-14 1994-08-02 Degussa Ag アクロレインまたはアクロレイン水溶液の製造方法および１，３−プロパンジオールの製造方法
WO2007119528A1 (ja) * 2006-03-30 2007-10-25 Nippon Shokubai Co., Ltd. アクロレインの製造方法

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1916743A (en) * 1929-06-15 1933-07-04 Schering Kahlbaum Ag Production of acrolein
JPH06211724A (ja) * 1992-11-14 1994-08-02 Degussa Ag アクロレインまたはアクロレイン水溶液の製造方法および１，３−プロパンジオールの製造方法
WO2007119528A1 (ja) * 2006-03-30 2007-10-25 Nippon Shokubai Co., Ltd. アクロレインの製造方法

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009027420A1 (de) 2009-07-02 2011-01-05 Evonik Degussa Gmbh Verfahren zur Herstellung von Acrolein
CN102482187A (zh) * 2009-07-22 2012-05-30 阿肯马法国公司 从丙三醇制备生物来源化的丙烯酸的方法
CN102482189A (zh) * 2009-07-22 2012-05-30 阿肯马法国公司 从丙三醇制备生物来源化的丙烯酸的方法
CN105566083A (zh) * 2009-12-18 2016-05-11 巴特勒纪念研究院 多羟基化合物脱水系统、催化剂组合物、和方法
WO2011125623A1 (ja) * 2010-03-31 2011-10-13 株式会社日本触媒 グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
CN102781579A (zh) * 2010-03-31 2012-11-14 株式会社日本触媒 甘油脱水用催化剂以及使用该催化剂的丙烯醛的制备方法和丙烯酸的制备方法及亲水性树脂的制备方法
US20130018161A1 (en) * 2010-03-31 2013-01-17 Takayuki Ezawa Catalyst for glycerin dehydration, and process for producing acrolein, process for producing acrylic acid, and process for producing hydrophilic resin each using the catalyst
EP2886193A3 (en) * 2010-03-31 2015-09-30 Nippon Shokubai Co., Ltd. Catalyst for glycerin dehydration, and process for producing acrolein, process for producing acrylic acid, and process for producing hydrophilic resin each using the catalyst
JP2012091158A (ja) * 2010-09-30 2012-05-17 Nippon Shokubai Co Ltd グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
JP2012091157A (ja) * 2010-09-30 2012-05-17 Nippon Shokubai Co Ltd グリセリン脱水用触媒、ならびに、この触媒を用いたアクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法

Also Published As

Publication number Publication date
JP4991471B2 (ja) 2012-08-01
CN101679174A (zh) 2010-03-24
EP2157074A4 (en) 2011-09-14
US20100113838A1 (en) 2010-05-06
CN101679174B (zh) 2013-01-16
JP2008307521A (ja) 2008-12-25
US7847131B2 (en) 2010-12-07
EP2157074A1 (en) 2010-02-24

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